Index to Chemical Substances

Index to Chemical Substances

A Acetaldehyde, 8 Acetate ion, 221 Acetic acid, 2,4-dichlorophenoxy-, 85 Acetic anhydride, triphenylplumbyl-, 155 Acetylcholine, see Choline, acetylAcetylcholinesterase, see Cholinesterase, acetylAcrylate esters, 132 Adenosine, a,fJ-methylene-5'-diphosphate, 81 Adenosine diphosphate, 81, 85 Adenosine monophosphate, 79, 80 Adenosine triphosphate, 88, 202 Adenosyltriphosphatase, 53, 54, 78-81, 116, 174 Adenylate cyclase, 53, 77-79 ADP, see Adenosine diphosphate AflatoxinB!, 180 Alafosfalin, see Phosphonic acid, L-alanyl-1 -aminoethylAlanine, 15 L-Alanyl-L-alanine, 15 Alaphosphin, see Phosphonic acid, L-alanyl-1 -aminoethylAlbumen, 23, 81 Alcohol dehydrogenase, 84 Aldolase, 80 Alkanes, 117 Alkyl halides, 237 Alsol, see Silane, 2-chloroethyltris(2-methoxyethoxy)-

Amino acids, 88, 115, 221, 236, see also specific compounds Aminoacyl-tRNA synthetase, 79 Aminolevulinate dehydratase, 54 8-Aminolevulinic acid, 54 Ammonium chlorides, alkyltrimethyl-, 128 Ammonium salts, quaternary, 86, 180 AMP, see Adenosine monophosphate a-Amylase, 149 Antimonate ion, 191, 198, 199 Antimonials, organo-, 5, 15, 110, 198, 199 Antimony, 126, 198, 199 triphenyl-, 91 Antimony compounds aryl-, 5, 14 methyl-, 198, 237, see also Stibine, trimethylphenyl-, 14, 126, 172 Antimony 1 ion, 5 Arginase, 79 Arsanilic acid, 17, 90 Arsazine chloride, phen-, 135 Arsazines, thiocarbamylthiotriphen-, 114 Arsenate ion, 7, 82, 191-194, 198-200, 223, 233 Arsenic, 4, 6, 7, 40, 84, 189-191, 193, 194, 196, 198-204, 217, 221, 223, 227, 230, 232, 233 Arsenic acid, 192, 193, 200, 233 Arsenicals, organo-, 2, 4, 5, 7, 12, 15, 17, 20, 39, 118, 127, 130, 133, 135, 247

248 191-194, 198-202, 223, 229-233, see also Arsine Arsenic compounds methyl-, 2, 40, 191-194, 198-202, 225, 227, 232, 233, see also Arsine, methyl phenyl-, 89 Arsenic dichloride, /?-aminophenyl-, 77 Arsenic dihydroxide, methyl-, 191, 192, 232 Arsenic sulfide, methyl-, 129, 227 Arsenic trioxide, 2, 90, 193, 219 Arsenious acid, dimethyl-, 192 Arsenite ion, 59, 177, 191-194, 199-202, 204, 227, 230, 232, 233 Arsenoacetic acid, 18, 84 Arsenobenzene, 4 3,3'-diamino-4,4'-dihydroxy-, 4, 6, 9, 12, 13, 39, 89, 90 Arsenobetaine, 200-202, 233 Arsenocholine, 200 Arsenolipids, 192, 200, 202, 204, 227, 229, 232 Arsenosugars, 200, 202 Arsenous oxide, see Arsenic trioxide Arsenoxide 4-hydroxy-3-aminophenyl-hydrochloride, 5, 6, 17 phenyl, 91 Arsine, 223, 233 diethyl-, 7 dimethyl-, 191, 192, 194, 223, 233 methyl-, 223, 233 10,10' -oxybisphenox-, 54 trimethyl-, 2, 7, 191, 192, 194, 201, 202, 216, 218, 219, 223, 231, 233 triphenyl-, 219 Arsine oxide trialkyl-, 201 trimethyl-, 191, 192 Arsinic acid, dimethyl-, 192, 233, see also Cacodylic acid Arsonate alkyl-, 90, 117 aryl-, 90, 156 Arsonate ion, methyl-, 82, 191-194, 199, 200, 219, 223-225, 227 Arsonic acid methyl-, 92, 191, 192, 223, 224, 233 disodium salt, 158, 223 iron salt, 128, 193 monosodium salt, 55, 153-155, 158, 177, 179, 225

Index to Chemical Substances zinc salt, 128 p-aminophenyl, monosodium salt, 4 p-azophenyl, 90 phenyl-, 90, 190, 200 Arsonium ion methyltriphenyl-, 219 tetramethyl-, 191, 233 tetraorgano-, 136, 191, 201 tetraphenyl-, 84, 85, 91, 116 Arsonium lactate O-phosphatidyltrimethyl-, 200 trimethyl-, 200, 201 Arsonomethylphosphonate ion, see Phosphonate ion, arsonomethylArsphenamine, see Arsenobenzene, 3,3' -diamino-4,4' -dihydroxyAspartate carbamoyltransferase, 20, 77-79, 80 Aspartate ion, 84 Aspartic acid, 88 phosphonoacetyl-, see Phosphonoacetyl-L-aspartic acid Atoxyl, see Arsonic acid, /?-aminophenyl, monosodium salt ATP, see Adenosine triphosphate ATPase, see Adenosyltriphosphatase Atropine, 60 Auranofin, see Gold(I) peracetylthioglucose, triethylphosphine Aurothiomalic acid, sodium salt, 23 Auxin, 149 Azobenzene, 4 B BAL, see British Anti-Lewisite Barbituric acid, trimethylsilyl-, 92 Benzamides, alkyl-, 134 Benzene, 117, 134, 206 Betaine, 203 Bialaphos, 154, 199, 204 Bipyridine, 2,2'-, 129 Bismuth, 126 trivinyl-, 49 Bismuth compounds aryl-, 14 organo-, 5, 110 phenyl-, 14, 126, 172 Bismuthyl glycolylarsanilate, 15 Bismuthyl ion, 5 Boraadamantane, 18 Borabetaine, 19

Index to Chemical Substances Borane carboxy-, 23 carboxy ammonia, 19 organo-, 14, 18, 19, 24, 26, 76, 116, 127 phenyldicarbaundeca-, 92 triphenyl-, 14 Borate ion, tetraphenyl-, 84, 85, 88, 91, 117, 156, 180 Bonnie acids, organo-, 114 Boronic acid m-aminophenyl-, 117 p-aminophenyl-, 76 aryl-, 76, 156 organo-, 76, 85, 170 phenyl-, 76, 81,90, 151, 158 Boronophenylalanine, 19 Brestan, see Tin acetate, triphenylBritish Anti-Lewisite, 2, 6, 57, 58, 193, see also Propanol, 2,3-dimercapto Bromide ion, 178 Butarsen, 16 Butyric acid, 7-amino-, 89, 178 C Cacodyl, 8 Cacodylic acid, 4, 92, 152, 154, 155, 158, 177, 179, 191-194, 199-202, 223-225, see also Arsinic acid, dimethylCadmium, dimethyl-, 77 Cadmium chloride, methyl-, 50, 60 Cadmium ion, 177, 178 Calcium ion, 24, 55, 57, 82, 83, 85, 86, 89, 91,92 Camposan, see Phosphonic acid, 2-chloroethylCaptostibone, 16 Carbamate, diethyldithio-, 58 Carbarsone, 15, 17 Carbaryl, 83 Carbenes, iron derivatives of, 205 Carbodiimide, iV,Af'-dicyclohexyl-, 91 Carbohydrates, 116, 149, 171 Carbon, 44, 217, 230 Carbon dioxide, 148, 223, 224 Carbon monoxide, 44, 56 Carbonyls, metal, 6, see also specific compounds Carboranes, 19, 50, see also specific compounds Carboxypeptidase, 53, 78

249 Carotenoids, 149 Catalase, 115 Cepha, see Phosphonic acid, 2-chloroethylCephalexin, 15 Ceresan, see Mercuric chloride, 2-methoxyethylChloramphenicol, 14 Chloride ion, 8, 84-86, 89, 91, 178, 218, 222 Chloromethane, 221 Chlorophyll, 137, 149 Chlorphencyclane, 25 Cholesterol, 24, 57, 83 Choline, 80, 89, 194, 203 Choline acetyltransferase, 58 Choline acetyl-, 52, 55, 80, 88, 89 phosphatidyl-, 80 Cholinesterase, 52 acetyl-, 52, 77, 78, 80, 84, 176 Chromatin, 81 Chromatin protease, 76 Chymotrypsin, 76 Chymotrypsinogen, 76 Ciclonium bromide, 25 Ciliatine, see Phosphonic acid, 2-aminoethylCobalamin, 21, 22, 182, 205 aquo-, 21 cyano-, 21, 117, 198 deoxyadenosyl-, 21, 22, 117, 205, see also Vitamin B 12 hydroxo-, 21, 219 methyl-, 21, 23, 60, 83, 87, 89, 90, 92, 116, 117, 189, 195-198, 205, 219, 220, 232 Cobalt, 198, 204 Cobalt salts, 117 Coenzyme A, acetyl-, 53, 115 Coenzyme B 12 , see Cobalamin, deoxyadenosylColchicine, 56 Collagen, 83 Collagenase, 77, 79 Copper, 56, 177, 193 Copper compounds, aryl-, 135 Copper salts, 135, 136 Creatine kinase, 79, 81 Cyanide ion, 44 P-Cyanin, 149, 150 Cycloalkane diorganostanna-, 155

Index to Chemical Substances

250 Cyclohexane 1,1-diethyl-l-germa-, 20, 56 1,1-diethyl-l-stanna-, 170 Cysteine, 58, 115, 137, 176 Cytidine, 203 Cytochrome c reductase, 79 Cytochrome oxidase, 53, 79, 137 Cytochrome P-420, 83 Cytochrome P-450, 54, 56, 83, 205 Cytochrome P-450 monooxygenase, 79, 206 Cytochrome P-450 oxidase, 207 Cytosine, l-(J-D-arabinofuranosyl-, 87 D Daconate, see Arsonic acid, methyl-, monosodium salt Demethylase, 78 Deoxyribonucleic acid, 17, 56, 57, 81-83, 85, 116, 118, 190 Diarsonates, methylene-, 84 Diazepan, demethyl-, 56 Dicarbollide ions, 126 Difenidol, 25 Dihydrofolate reductase, 78 Dihydrolipoamide acetyltransferase, 53 Dimercaprol, see Propanol, 2,3-dimercaptoDimetacrine, 25 Dinitrogen reductase, 76 Diphosphonate guanylylmethylene-, 78 methylene-, 24, 82, 84 Diphosphonic acid ethane-1-hydroxy-1,1-, 88 organo-, 135 Diphosphonium ion, 17 Disilicate ion, 13 Dithionic acid, sodium salt, 114 DNA, see Deoxyribonucleic acid Du-Ter, see Tin hydroxide, triphenylE EC EC EC EC EC EC EC EC

1.1.1.49, 53, 80 1.2.4.1, 78 1.6.1.1, 80 1.14.99.3, 78 2.1.1.45, 20 2.1.3.2, 78 2.3.2.2, 77 2.5.1.18, 79

EC 2.7.1.40, 80 EC 2.7.3.2, 81 EC 3.1.1.3, 78 EC 3.1.1.7, 78 EC 3.1.3.1, 78 EC 3.1.3.2, 78 EC 3.4.-.-, 76 EC 3.4.17.1, 78 EC 3.4.21.1, 76 EC 3.4.21.4, 79 EC 3.4.24.7, 79 EC 4.2.1.28, 77 EDTA, see Ethylenediaminetetraacetic acid Enkephalin, 81 5-Enolpyruvylshikimic acid-3-phosphate synthetase, 116 Epoxide hydratase, 77 Esterase, 79 Estradiol, 81 Estradiol-17p-3-carboranyl methyl ether, 81 Estrogen selena-, 81 trimethylsilyl-, 92 Ethane, 206, 221 Ethanol dimethyloxarsyl-, 200, 201 2-mercapto-, 58 Ethanolamine, phosphatidyl, 203 Ethephon, see Phosphonic acid, 2-chloroethylEthrel, see Phosphonic acid, 2-chloroethylEthylene, 145, 146, 148, 149, 151, 206 Ethylene dichloride, 114 Ethylenediaminetetraacetic acid, 114, 227, 228 F Fatty acid synthetase, 24 Ferribalamin, 205 Ferritin, 24, 83 Ferrocene, 9, 24, 81, 82, 206, 207 derivatives of, 14, 207 l,l'-dibutyl-, 85 hydroxy-, 84, 207 Ferrocenylalanine, 81 Flavenoid, 149 Foschlor, 137 Fosfidomycin, 15 Fosfomycin, see Phosphonic acid, 2-methyl-l ,2-epoxypropylFructose-l,6-biphosphatase, 80 Fructose-1,6-biphosphate, 80

Index to Chemical Substances Fulvic acids, 222 Fumaric acid, tri-w-butylstannyl ester, 127 G Gallium chloride, diphenyl-, 129 Germane, di-rc-butyldichloro-, 87 Germanium, 24, 40, 44, 237 spiro-, see Cyclohexane, 1,1 -diethyl-1 -germaGermanium acetate, tri-n-butyl-, 115 Germanium compounds ethyl-, 206 organo, 14, 26, 77, 110, 115, 127 tri-rt-butyl-, 115 triisobutyl-, 110 triisopropyl-, 110 Germanium imidoacetates, phenyl-, 14, 172 Germanium oxide, dimethyl-, 26 Germanium sesquioxide, carbethoxy-, 13, 20, 90, 151 Glucose, 53, 54, 56, 83, 89, 118, 203, 205, 223 Glucose-6-phosphatase, 53 Glucose-6-phosphate, 15, 80, 137 Glucose-6-phosphate dehydrogenase, 53, 77, 80 Glutamate dehydrogenase, 149 L-Glutamic acid, 81, 88 Glutamine, 115 Glutamine synthetase, 79 Glutamyltransferase, 77 Glutathione, 23, 58, 59, 77, 177, 223 Glutathione peroxidase, 53, 79 Glutathione-5-transferase, 53, 77, 79 Glyceraldehyde-3-phosphate dehydrogenase, 80 L-a-Glycerophosphate, 116 Glycine, 19 boron analog of, 19 2-mercaptopropionyl-, 58 N-phosphonomethyl-, 77, 78, 87, 91, 116, 117, 137, 145, 146, 150, 152-154, 156-158, 223 isopropylammonium salt, 152, 153, 158 Af-nitroso derivative, 153, 154 Af-substituted derivatives, 154 seleno-di-Af-acetyl-, 59 Glycogen, 83 Glyphosate, see Glycine, N-phosphonomethylGold(I) chloride, triethylphosphine, 81

251 Gold(I) compounds, 23 organo-, 50 organophosphine-, 89 Gold(I) peracetylthioglucose, triethylphosphine, 23, 26, 88 Gosio-gas, 7, see also Arsine, trimethylGrignard reagent, 1, 9, see also Magnesium iodide, methylH Hafnium dichloride, dicyclopentadienyl-, 20 Heme, 54, 56 Heme oxygenase, 78 Hemin, 115 Hemoglobin, 23 r 49, 56, 81 Hexanal, 149 Hexokinase, 53, 79 Histidine, 55, 176 Histone, 56, 81 Humic acid, 222 Hydrocarbons, 134, 135 Hydrogen sulfide, see Sulfide, hydrogen Hydroxide ion, 85, 91, 115, 222 3-Hydroxybutyrate dehydrogenase, 53 I Immunoglobulin, 83 Indium chloride, diphenyl-, 129 Inezin, 128 Inorganic metals, see specific metal Inosotol, phosphatidyl-, 200 Insulin, 85 Iodine diacetate, phenyl-, 89 Iodomethane, 219, 220, 232-235 Iron, 24, 56, 237 Iron compounds, alkyl-, 237 Isobutyric acid, 2,3-dichloro-, sodium salt, 150 K Kaolinate, 137 Kinetin, 156 L Lactic acid, 115 Lead, 44, 84, 197, 217, 219, 220, 231, 234, 235

Index to Chemical Substances

252 butyltrimethyl-, 221 tetraethyl-, 2, 6, 7, 39, 56, 77, 90, 114, 127, 136, 181, 220, 221, 226-228, 231,234,235 tetramethyl-, 14, 91, 136, 197, 218, 220, 223, 225, 226, 228, 231, 234, 235 Lead acetate tri-/?-butyl-, 56, 89, 136, 176 triethyl-, 116 trimethyl-, 197, 223 triphenyl-, 57, 136, 176, 227 Lead chloride, triethyl-, 56, 81, 87-89, 220, 226-228 Lead compounds alkyl-, 89, 177, 197, 221, 231, 234 ethyl-, 136, 206, 220, 228 inorganic, 54, 197, 206, 219-221, 223, 227, 228, 234, 235 methyl-, 197, 219, 220, 234, 235 organo-, 57, 76, 77, 89, 109-111, 130, 134, 136, 155, 156, 206, 220 phenyl-, 181 tetraalkyl-, 206 triethyl-, 55,77, 116 trimethyl-, 57 triorgano-, 54, 206 triphenyl-, 181 tri-n-propyl-, 116 Lead diacetate dialkyl-, 49 di-n-butyl-, 17, 58 Lead dichloride, diethyl-, 227, 228 Lead ion, 178, 197, 235 trialkyl-, 218 triethyl-, 136 trimethyl-, 235 Lead(II) sulfide, 235 Lead sulfide dimethyl-, 235 trimethyl-, 220 Leucine, 83 Lewisite, 2, 6, 39, 57, 58 Ligandin, 77 Lipase, 78 Lipids, 57, 116, 137, 149, 196, 218, 229, 231 Lipoic acid, 52, 53 Lithium compounds, alkyl-, 1 M Magnesium iodide, methyl-, 158

Magnesium ion, 92 Malformin, 158 Malonic acid, 13 Manganese compounds, aryl-, 207 Manganese tricarbonyl cyclopentadienyl-, 39, 56 methylcyclopentadienyl-, 206, 207 organo-, 91 Mapharsen, see Arsenoxide, 4-hydroxy-3-aminophenyl-hydrochloride Melarsoprol, 16, 78 Mercaprol, 6, see also Propanol, 2,3-dimercaptoMercaptoacetates, alkyl-, 58 Mercurescein, sodium, 116 Mercurials hydroxyphenyl-, 207 organo-, 3, 39, 40, 54, 55, 57, 75-77, 80, 84, 86, 88, 90, 109, 114, 116, 117, 124, 129, 130, 136, 137, 156, 176, 177, 180, 195, 196, 205-207, 221-229, 234 Mercuribenzoic acid p-chloro-, 57, 178 p-hydroxy-, 170 Mercuric acetate p-aminophenyl-, 77, 80, 87 methyl-, 156, 157 phenyl-, 40, 56, 77, 81, 86, 91, 114, 117, 128, 130, 137, 138, 152, 156-158, 179, 205, 207, 222, 226, 234 Mercuric borate, phenyl-, 14, 116 Mercuric chloride, 177, 178, 195, 196, 221, 225, 226 ethyl-, 49, 57, 130, 177, 179, 221 isopropyl-, 221 2-methoxyethyl-, 57, 129 methyl-, 9, 50, 52, 55-59, 77, 81, 85-87, 89-91, 127, 136, 137, 156, 176, 177-181, 195, 196, 205, 218, 221, 222, 225-229 5-nitro-2-hydroxyphenyl-, 80 phenyl-, 80 H-propyl-, 221 Mercuric compounds alkyl-, 89, 221 ethyl-, 180 inorganic, 2, 117, 195, 196, 222, 231, 234 methyl-, 2, 7, 8, 40, 50, 57, 80, 156, 170, 178-180, 190, 195, 196, 205, 216, 219, 221-229, 231, 232, 234

Index to Chemical Substances phenyl-, 156, 180 Mercuric cysteine, methyl-, 82 Mercuric cysteinylglycine, methyl-, 82 Mercuric dicyandiamide, methyl-, 124, 180, 181 Mercuric glutathione, methyl-, 83 Mercuric hydroxide methyl-, 56-58, 81, 82, 87, 92, 155, 206 phenyl-, 206 Mercuric iodide, methyl-, 59 Mercuric ion alkyl-, 218 methyl-, 58, 59, 90, 195, 196, 221, 222, 224, 228, 229 Mercuric nitrate, 196, 222 phenyl-, 114, 116 Mercuric phosphate, ethyl-, 156, 174 Mercuric selenide, 59 methyl-, 59 Mercuric silicate, 2-methoxyethyl-, 180 Mercuric sulfide, 195, 220, 221 methyl-, 220 Mercuric thiomethoxide, methyl-, 236 Mercuric p-toluenesulfonamide methyl-, 179 phenyl-, 179 Mercuriphenylsulfonic acid, p-chloro-, 80 Mercuriphthaleins, hydroxy-, 82 Mercurochrome, 3, 13, 14, 26, 81 Mercurophylline, 24 Mercurous chloride, 221 Mercury, 6, 44, 55, 59, 60, 124, 130, 189, 195, 196, 205, 206, 217, 220-222, 226, 229, 231, 232, 234 diethyl-, 49 dimethyl-, 2, 59, 60, 137, 195, 196, 205, 218, 220, 221, 225, 232, 234 diphenyl-, 137, 226 Mersalyl, 56, 77 Merthiolate, sodium, 3, 49, 77, 88, 90 Mesentericopeptidase, 78 Metallocene dihalides, 20 Metalloenzymes, 56 Metallothionein, 56 Methacrylate, tri-rt-butylstannyl-, see Tin methacrylate, tri-w-butylMethacrylate esters, 132, 134 Methane, 60, 116, 198, 205 Methanol, 117 triphenylsilyl-, 206

253 Methionine, 59, 191, 194, 202 S-adenosyl-, 7, 83, 189, 202 Methylmercury, see Mercuric compounds, methylMethyl radical, 60 Molybdenum dichloride, dicyclopentadienyl-, 20 Monamine, 56 Monamine oxidase, 53, 78 Monooxygenase, 79 Muscarine, 56, 81 Myelin, 54, 55, 89 N NADH oxidase, 86 Neoarsphenamine, see Neosalvarsan Neosalvarsan, 5 Neostibosam, 15 Neurotoxic esterase, 53 Nickel tetracarbonyl, 2, 9, 39, 50, 58 Nicotinamide nucleotide transhydrogenase, 77 Nifedipine, 25 Niobium dichloride, dicyclopentadienyl-, 20 Nitrate ion, 222 Nitrate reductase, 149 Nitrogen, 44, 55, 117, 126, 189, 217, 230 Nitrophenylphosphatase, see Phosphatase, p-nitrophenylNitrous oxide, 182 Noble gases, 217, 230 Nucleic acids, 79, see also Deoxyribonucleic acid; Ribonucleic acid Nucleosides, 18 Nucleotidases, 80 Nucleotide-3'-phosphodiesterase, 54, 80 O Octanol, 1-, 218 Oligomycin, 129 Ovalbumin, 80, 83 Oxophenarsine hydrochloride, see Arsenoxide, 4-hydroxy-3-aminophenyl-hydrochloride Oxygen, 55, 115, 116, 126, 137, 189, 206, 216, 217, 225, 230 P Panogen, see Mercuric dicyandiamide, methylParathion, 170

254 D-Penicillamine, 58 N-acetyl-, 58 Penicillin, 5, 14 phosphono-, see Phosphonopenicillin Peptidoglycans, 14, 15 Peptidyl transferase, 78 Peropal, see Triazole, 1-tricyclohexylstannyl-l ,2,4Peroxidase, 149 Phenanthroline, 1,10-, 129 Phenols, 149 Phenylalanine, 81 Phenylalanine ammonia lyase, 157 Phenylalanine hydroxylase, 81 Phosphatase acid, 78 alkaline, 53, 78-80 p-nitrophenyl-, 77 Phosphate ion, ortho-, 76, 88, 117, 192, 198-200, 202, 237 Phosphatides, 84 Phosphinates dialkyl-, 23 organo-, 117, 170 Phosphine, 199, 237 phenyldibutoxy-, 130 phenyldiethyl-, 56 triethyl-, 23 triorgano-, 154 triphenyl-, 112, 219 Phosphinemethylene, triphenyl-, 50 Phosphine oxide methylbis(p-chlorophenyl)-, 174 triethyl-, 81 triorgano-, 23 Phosphinic acids, organo-, 80, 154, 204 Phosphinothioic acid, diphenyl-, 82 Phosphite ion, 191, 199 Phosphoenol pyruvate, see Pyruvate, phosphonenolPhosphoglycerate kinase, 81 Phospholipids, 84-86, 115, 192, 203 Phosphon D, see Phosphonium chloride, 2,4-dichlorobenzyltri-7z-butylPhosphonate compounds amino-, 150 ethyl-, 129 methyl-, 82 organo-, 79-81, 83, 90, 171, 203, 204 phenyl-, 92

Index to Chemical Substances Phosphonate ion 1-adamantyl-, 18 arsonomethyl-, 84 p-nitrophenyl-, 80 organo-, 18, 23, 76, 114 Phosphonic acid 3-(N-acetyl-N-amino)propyl-, 112 L-alany 1-1 -aminoethy 1-, 14 alkyl-, 14, 15, 109, 116, 117, 154, 203, 206, 224 1-aminoethyl-, 15, 80 2-aminoethyl-, 117, 203, 206, 237 aminomethyl-, 153, 154, 158 3-aminopropyl-, 117 aryl-, 117, 128, 206 benzyl-, 174 rt-butyl-, 175 2-chloroethyl-, 82, 145-151, 156, 157 dichloromethyl-, 158 ethane-1 -hydroxy-1,1 -di-, see Diphosphonic acid, ethane-1 -hydroxy-1,1ethyl-, 129 ethylthio-, 172 methyl-, 84, 174, 198, 199, 237 2-methyl-l,2-epoxypropyl-, 14, 15, 17, 111, 112, 116, 117 methylfluoro-, 52, 84 methylthio-, 60 phenyl, 117 n-propyl-, 15, 158, 203 2,2,2-trichloro-1 -hydroxyethyl, dimethyl ester, 146 2-trimethylaminoethyl-, 80 Phosphonium chloride 5-chloro-2-thienyltri-n-butyl, 150 2,4-dichlorobenzyltri-rt-butyl-, 150, 156, 158 Phosphonium ion aklyltriphenyl-, 172, 176 butyltriphenyl-, 84 methyltriphenyl-, 83, 84, 86, 88, 89, 118, 219 tetraorgano-, 114, 136, 150, 151 tetraphenyl-, 84-86, 116-118 Phosphonium salts, aralykyl-, 26 Phosphonium sulfate, tetrakis(hydroxymethyl)-, 117 Phosphonoacetic acid, 12, 13, 17, 18, 87, 92 Phosphonoacetyl-L-aspartic acid, 19, 77, 78, 80, 87, 88, 92 platinum complex, 20 Phosphonoalanine, 203

Index to Chemical Substances Phosphonobutyric acid, 2-amino-4-, 81, 84, 88, 89, 92, 175 Phosphonoformic acid, 18, 90 Phosphonolipids, 203 Phosphonomethylglycine, see Glycine, Af-phosphonomethylPhosphonomycin, see Phosphonic acid, 2-methyl-l ,2-epoxypropylPhosphonopenicillin, 111, 112 Phosphonopeptides, 15 Phosphonopropionic acid, 18 Phosphonovaleric acid, 2-amino-5-, 88 Phosphoric acid ortho-, 170, 203 poly-, 170, 237 thio-, 170 Phosphorus, 40, 117, 151, 190, 198, 199, 202-204, 230, 237 Phosphorus compounds methyl-, 198, 199, 237 organo-, 12, 17, 25, 39, 52, 77, 79, 81, 89, 112, 116, 117, 127, 150, 151, 156, 169, 170, 202-204 Pindolol, 56 Piperidine, 4,4-diphenyl-4-sila-l-alkyl-, 81 Platinum(II), ds-dischlorodiammine-, 20 Platinum(IV) compounds methyl-, 92 organo-, 114 Plictran, see Tin hydroxide, tricyclohexylPlumbyl ion, trimethyl-, 58 Polymers, 26, 27 Polyphenyl oxidase, 149 Polystat, see Tin dicarboxylates, di-n-butylPotassium ion, 84, 91, 180 Pridinol, 25 Primidone, 25 Proline, 115 Propanediol dehydratase, 77 Propanol, 2,3-dimercapto-, 6, 57, see also British Anti-Lewisite Propiolates, trimethylsilyl-3-carbethoxyalkylcarbamoyl-, 112 Puromycin, 80 Pyridine, 155 Pyridine nucleotide transhydrogenase, 80 Pyrophosphate, tetraethyl-, 170 Pyrophosphate ion, 84, 117, 202 Pyruvate, phosphoenol-, 201, 203, 204 Pyruvate dehydrogenase, 78 Pyruvate kinase, 80, 118

255 Pyruvate oxidase, 79 Pyruvic acid, 53, 115 (3-phosphonyl, 204 R Rhodium compounds, organo-, 114, 198, 205 Rhodobalamin, 198, 205 methyl-, 198 Ribonucleic acid, 55, 57, 80, 83 Ridaura, see Gold(I) peracetylthioglucose, triethylphosphine RNA, see Ribonucleic acid Roundup, see Glycine, Af-phosphonomethylisopropylammonium salt Ruthenocene, 206, 207 Rythmol, 25 S Saccharin, 181 Salvarsan, see Arsenobenzene, 3,3' -diamino-4,4' -dihydroxySarin, 52, 60 Selenate ion, 192, 197-199, 204, 223 Selenide dimethyl-, 197, 198, 236 dimethyldi-, 197, 198, 236 Selenite ion, 59, 60, 137, 156, 191, 197, 199, 204, 205, 223, 236 Selenium, 7, 59, 60, 189, 190, 196-199, 204, 225, 236 Selenium compounds methyl-, 197, 198, 223, 236, see also Selenide, dimethylorgano-, 39, 177, 197, 198, 204, 236 Selenols, organo-, 59, 60 Selenomethionine, 59, 197, 204 Selenomethylcysteine, 204 Selenone, dimethyl-, 197 Serine, 76 Shikimic acid, 116 Silaadamantane, tetra-, 172 Silane 7-aminopropyltriethoxy-, 92 7-aminopropyltriethyl-, 81 2-chloroethyltris(2-methoxyethoxy)- ,151 p-hydroxyphenyltrimethyl-, 206 methylphenyldihalo-, 49 phenyltrimethyl-, 206 tetraethyl-, 181

256 Silanediol, diphenyl-, 25 Silatranes, 12-14, 17, 81 p-tolyl-, 178 Silicate anion, 198 Silicon, 24, 25, 198 Silicon compounds methyl-, 198, 219 organo-, 12-14, 21, 23, 25, 26, 39, 112, 114, 127, 134, 135, 151, 174, 206, 207 Siliconate ethyl-, sodium salt, 135 methyl-, sodium salt, 135 Silicones, 3, 26, 27, 49, 76, 88, 89, 92, 136, 223 Siloxane diphenylhexamethyltetra-, 180 phenylheptamethylcyclotetra-, 180 Siloxanes cyclo-, 26 deca-, 151 methyl-, 49, 133, 134, 151 tris(3,3,3-trifluoropropyl)trimethylcyclotri-, 180 Silver nitrate, 158 Sodium ion, 84, 178 Soman, 52, 60, 175 Spironolactone, 60 Stalinon, 2, 7, 12 Stannane, methacryloxytriethyl-, 134 Stannic oxide, see Tin dioxide Stannoic acid, n-butyl-, 236 Stannoxane, hexa-H-butyl-, see Tin oxide, tri-rt-butylSteroids, 26, 57 Stibamine, 5 Stibanilic acid, 90 Stibine, trimethyl-, 219, 231 Stibinic acid, dimethyl-, 198 Stibonic acid methyl-, 198 phenyl-, 5 Stibonium chloride, 2-hydroxyethyltrimethyl-, 89 Stibonium ion, tetraorgano-, 136, 218 Stibosan, 5 Stilbestrol, 25, 26 Subtilisin BPN, 78 Subtilisin novo, 78 Succinate anion, bromo-, 78 Succinate dehydrogenase, 53

Index to Chemical Substances Succinic acid, 2,3-dimercapto-, 58 Succinic semialdehyde dehydrogenase, 91 Sucrose, 114, 150 Sulfate ion, 199, 237 Sulfide ion, 197, 234-236 Sulfide dimethyl-, 235, 236 hydrogen, 235, 236 Sulfite ion, hydro-, 199 Sulfonic acid p-chloromercuriphenyl-, 80 2,3-dimercapto-1-propyl-, 58 dodecyl-, sodium salt, 115 Sulfonium hexafluorophosphate, trimethyl-, 219 Sulfur, 55, 59, 75, 189, 196, 204, 217, 230, 235, 236 Sulfur compounds, 199 T Technetium compounds, 84 Tellurate ion, 192, 197, 199, 236 Telluride diethyl-, 49 dimethyl-, 197, 198, 236 Tellurite ion, 199, 204, 236 Tellurium, 7, 82, 197, 198, 204, 236 Tellurium compounds, organo-, 39, 82, 198, 204, 236 Telluromethionine, 82, 204 Tetracycline, 19 Tetrahydrofolate, A^-methyl-, 198 Thallic ion dialkyl-, 218 dimethyl-, 198 Thallium, 44, 198, 237 Thallium chloride dimethyl-, 56 diphenyl-, 129 Thallium compounds, methyl-, 198, 219 Thallous ion, 198 Thiols, 57, 58, 77, 80, 81, 91 Thiomalate, sodium, 116 Thiomersal, 114 Thrombin, 81 Thromboplastin, 81 Thymidine, 57, 83, 88 Thymidylate synthetase, 20 Thyrotropin, 88 Tiemonium iodide, 25

Index to Chemical Substances Tin, 40, 44, 126, 129, 197, 206, 217, 220, 221, 223, 228, 230, 232, 234, 235 cyclohexyltriphenyl-, 206 tetra-rt-butyl-, 49 tetraethyl-, 206 tetramethyl-, 218, 220, 235, 236 Tin acetate rt-butyldimethyl-, 125 rt-octyldimethyl-, 125 trialkyl-, 125 trimethyl-, 125 tri-rt-pentyl-, 126 triphenyl-, 26, 127, 129, 170, 171-173, 221, 223 Tin aerylate, tri-H-butyl-, 156 Tin bromide, triethyl, 54, 206 Tin chloride chloromethyldi-rt-butyl-, 81 methyldi-AZ-butyl-, 91, 118 trwz-butyl-, 85, 91, 115, 135, 176, 179, 218, 231, 236 triethyl-, 56, 89, 115, 179, 181, 226 trimethyl-, 56, 181, 236 trineopentyl-, 132 trinorbornyl-, 174 triphenyl-, 81, 85, 91, 118, 137, 172, 176 tri-H-propyl-, 84, 85, 91, 115, 135, 176 Tin(II) compounds, 197, 223, 235, 236 Tin(IV) compounds, 197, 223, 235 Tin compounds alkyl-, 89 cyclohexyl, 174, 206 dialkyl-, 21,53 di-/i-butyl-, 57, 91 di-w-octyl-, 226 diphenyl-, 221 methyl-, 90, 127, 197, 219, 223, 224, 230, 232, 235, 236 mono-w-butyl-, 206 organo-, 7, 17, 39, 40, 56, 57, 76, 77, 84, 85,90, 109-111, 114, 115, 117, 127, 129, 134-136, 155, 169-172, 174, 175, 180, 181, 206, 221, 223, 234 phenyl-, 172, 221 tetraalkyl-, 155, 206, 226 trialkyl-, 21, 44, 49, 54, 91, 115, 118, 125, 206, 226 triaryl-, 110 tri-n-butyl-, 14, 91, 110, 132-136, 170, 172, 175-177

257 tricyclohexyl-, 49, 78, 135, 171, 174 triethyl-, 54, 55, 57, 81, 85, 110, 181 triisopropyl-, 110 trimethyl-, 181 triphenyl-, 49, 129, 135, 136, 176 Tin dicarboxylates, di-H-butyl-, 17 Tin dichloride di-Ai-butyk 87, 90 diethyl-, 88, 115 dimethyl-, 235 diphenyl, 129 Tin dihalides, dialkyl-, 111 Tin diiodide, diethyl-, 7 Tin dilaurate, di-/i-butyl-, 49, 56 Tin dioxide, 218, 235, 236 Tin fluoride tri-rt-butyl, 155, 172, 176, 177, 179, 223, 231 triphenyl-, 56, 131, 223 Tin halides, triethyl-, 49, 50 Tin hydroxide tricyclohexyl-, 158, 170, 171, 174 triisobutyl-, 135 trimethyl-, 197, 235 triphenyl-, 78, 128, 130, 152, 155, 170, 171, 178 Tin imidoacetates diphenyl-, 14 tri-/z-butyl-, 112 Tin ion tri-rt-butyl-, 225 triorgano-, 85, 91 Tin isooctylmercaptoacetate dibenzyl-, 50 di-w-octyl-, 50 Tin isoselenocyanate, triphenyl-, 111 Tin laurate, tri-/i-butyl-, 170 Tin methacrylate, tri-n-butyl-, 49, 131, 132, 134, 135 Tin methylsulfate, tri-w-propyl, 134 Tin oxide, di-n-butyl-, 49 trwz-butyl-, 49, 114, 132, 134-136, 175-177, 179, 181, 206, 228, 231, 235 tris(2-phenyl-2-methylpropyl)-, 170, 174 Tin sulfate, triethyl-, 54-56, 85, 87, 91, 118, 181 Tin sulfide di-rt-butyl-, 49 trimethyl-, 220, 235 Tin sulfide trimer, dimethyl-, 220, 236

Index to Chemical Substances

258 Tin thiocyanatophenylcarboxylates, triphenyl-, 127 Tin thiolates, trialkyltin-, 112 Tin trichloride H-butyl-, 206, 235 methyl-, 236 Tinostat, see Tin dicarboxylates, di-n-butylTiopronin, see Glycine, 2-mercaptopropionylTitanium dichloride, dicyclopentadienyl-, 20 Transhydrogenase, 79, 91 Triazole, l-tricyclohexylstannyl-1,2,4-, 170, 174 Triton X-100, 115 Trypsin, 79 Tungsten dichloride, dicyclopentadienyl-, 20 Tyrosine hydroxylase, 53 U Uracil, 5-fluoro-, 20 Uridine, 20, 88 Uridylic acid, 2'-deoxy-5-fluoro, phosphonate analog of, 87

V Vanadium dichloride, dicyclopentadienyl-, 20 Vendex, see Tin oxide, tris(2-phenyl-2-methylpropyl)Verdasan, see Mercuric acetate, phenylVitamin B 12 , 2, 21-23, 82, 117, 195, 196, 198, 204, see also Cobalamin, deoxyadenosylVitamin B 12s , 198 Vitamin E, 60 W Water, 1, 54, 131, 151, 196, 216, 218, 220, 221, 235-237 Z Zinc, diethyl-, 9 Zinc ion, 56, 177, 178 Zirconium dichloride, dicyclopentadienyl-, 20