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Program
Reactive Polymers, 10 (1989) 107-112 Elsevier SciencePublishers B.V., Amsterdam - Printed in The Netherlands
107
PROGRAM (Papers selected for publication in this issue are marked with asterisks) OPENING CEREMONY SESSION 1 Chairman: E. Girait *A. Guyot CNRS, Vernaison, France Some Problems of Physical and Chemical Characterization of Functionalized Supports P. Guerin CNRS, Mont-Saint-Aignan, France High Resolution N M R Spectroscopy of Polymers and Copolymers of Malic Acid and its Benzyl- and Methylesters: Assignment and Structural Analysis by using the SINEPT Sequence SESSION 2 Chairman: J.K. Stille
W.T. Ford Oklahoma State University, Stillwater, OK, U.S.A. 13C N M R Spectroscopic Analysis of Vinyl Groups in Styrene-Divinylbenzene Networks *W.K. Fife Indiana University, Indianapolis, IN, U.S.A. Multi-step Functionalization of Solid-State Copolymers of 4-Vinylpyridine. Synthesis and Characterization E. Tsuchida Waseda University, Tokyo, Japan Reversible Oxygenation of Heme Derivatives Embedded in Polymer Matrices G. Gelbard CNRS, Vernaison, France Selective Oxidations and Reductions with Polymer-supported Anionic Reagents SESSION 3 Chairman: J.M.J. Fr~chet K.J. Shea
University of California, Irvine, CA, U.S:A. Characterization of Network Polymers by Fluorescence Techniques
108 SESSION 4
Chairman: F. Gaviha C. Caze Universit$ Sciences et Techniques, Lille, France Influence of a Spacer on the Kinetics of Reduction of Carbonyl Compounds with Macroporous Borohydride Exchange Resin *C. Buttersack Institut fftr Zuckerindustrie, Braunschweig, F.R.G. Catalysis by Strong Acid Exchange Resins in Different Solvents J. Huguet CNRS, Mont-Saint-Aignan, France Solubilization and Catalytic Effects of pH-Dependent Globular Macromolecules on the Hydrolysis of Amino Acid p-Nitrophenyl Esters SESSION 5
Chairman: K.J. Shea *J.K. Stille Colorado State University, Fort Collins, CO, U.S.A. Organic Synthesis via Polymer Supported Transition Metal Catalysis *F. Cunill Universitat de Barcelona, Spain Effect of Crosslinking and Water on the Catalytic Activity of Sulfonic Acid Ion-exchange Resins P. Piet Eindhoven University of Technology, The Netherlands The Promoting Role of Anchored Polycations in the Cobalt(II)Phthalocyanine Tetra-sodium Sulfonate Catalyzed Thiol Oxidation SESSION 6
Chairman: J. Font D. Andreu Universitat de Barcelona, Spain Peptides and Polymers: An Ongoing Affair L. D'Angiuro Stazione Sperimentale Cellulosa e Carta, Milan, Italy Influence of the Support on the Properties of Enzyme-graft Copolymers Used as Catalysts *P. Tundo Universith di Messina, ltaly High Activity in Displacement Reactions by Quaternary Onium Salts Immobilized on Inorganic Matrices
109 SESSION 7 Chairman: J. Rebek
*F. Gaviha
Universidad de Valbncia, Spain Transfer between Solid Phases. Mechanistic Studies SESSION 8 Chairman: F. Camps
*A.M. Costero
Universidad de ValJncia, Spain Generation of Unsaturated/3-Lactame Intermediate from a Polymeric Precursor C.K. Narang
University of Jodhpur, lndia Polymer-immobilized Enzyme Cofactors *D. Roizard
CNRS, Nancy, France Design of Biomimetic Soluble Polyacrylamides: Lateral Introduction of Active Units by Means of Variable Spacer Arm SESSION 9 Chairman: R. Jaequier
*C. Challa
State University Groningen, The Netherlands Catalysis by Polymer-bound Coenzyme Models A. Zitsmanis
Institute of Applied Biochemistry, Olaine, U.S.S.R. Influence of Properties of Polymeric Matrix on Efficiency of Polymeric Catalysts in Acylation and Condensation Reactions P.K. Dhal
University of Diisseidorf F.R.G. Studies on Induced Chirality in Side Chain Chromophores of Optically Active Vinyl Copolymers with Main Chain Chiral Configurations S E S S I O N 10 Chairman: A. Patchornik
Round Table on Polymer Supported Ideas S E S S I O N 11 Chairman: G. Gelbard S. Itsuno
Cornell University, Ithaca, NY, U.S.A.
110 Asymmetric Synthesis by Use of Polymer-supported Chiral Activating Agents R. Jacquie Universit~ des Sciences et Techniques du Languedoc, Montpellier, France Polymers with Pendant Chirality as a Tool in Supported Asymmetric Synthesis of a-Amino Acids G. Wulff University of Diisseldorf F.R.G. Polymer Assisted Molecular Recognition SESSION 12 Chairman: P. Hodge B. Sellergren University of Lund, Sweden Highly Enantio- and Substrate-selective Polymers Obtained by Molecular Imprinting Based on Non-covalent Interactions *K. Petrak Ciba-Geigy Pharmaceuticals, Horsham, England Pharmaceutical Applications of Functionalized Polymers SESSION 13 Chairman: F.R. Truil T. Shimidzu Kyoto University, Japan Functionalizations of Conducting Polymers with Functional Molecules and by Structural Control in Molecular Level toward Molecular Device SESSION 14 Chairman: F. L6pez-Calahorra Poster Discussion SESSION 15 Chairman: G. Wuiff J.M.J. Fr6chet Cornell University, Ithaca, N¥, U.S.A. Radiation-sensitive Polymers for Microelectronics: Design, Synthesis, and Application *F.R. Trull Universitat de Barcelona, Spain Insoluble Polystyrene-bound Porphyrins as 10 2 Photosensitizers. Bilirubin Photooxidation as a Probe for their Efficiencies J.L. Bourdelande Universitat Autbnoma de Barcelona, Spain Insoluble Polymeric Photosensitizers: Surface Photophysical and Photochemical Studies
111 SESSION 16 Chairman: D.C. Sherrington Summing-up and Closing Session POSTERS *F. Albericio Universitat de Barcelona, Spain On the Use of Polystyrene-l%-Divinylbenzene and Kel-F-g-Styrene for the Simultaneous Synthesis of Peptides F. Bardella Universitat de Barcelona, Spain On the Use of Polystyrene as a Solid Support in Oligodeoxyribonucleotide Synthesis H.J. van den Berg University of Groningen, The Netherlands Polymer-bound Thiamine Models: Influence of Site Isolation on the Catalytic Activity of Polystyrene-bound Thiazolium Salts W.T. Ford Oklahoma State University, Stillwater, OK, U.S.A. Cationic Latexes with Bound Cobalt Phthalocyaninetetrasulfonate Catalyze Autoxidation of 1-Decanethiol A. Guyot CNRS, Vernaison, France Macroporous Gel-type Styrene-Divinylbenzene Supports Z.M. Jaszay Polytechnical University of Budapest, Hungary Preparation and Investigation of Water Soluble Carbodiimides as Immobilizing Reagents of Enzymes *N. Kawabata Kyoto Institute of Technology, Japan Coagulation and Sedimentation of Microbial Cells by Soluble Pyridinium-type Polymers M. Klyavinsh Institute of Applied Biochemistry, Olaine, U.S.S.R. Preparative Aspects and Applications of Polymer-bound Crown Ethers in Catalysis of Condensation Reactions R.M. Laird Newcastle upon Tyne Polytechnic, England Polystyrenesulphonyl Phosphate: a Novel Phosphorylating Agent N.I. Larionova M.V. Lomonosov Moscow State University, U.S.S.R. Polymers as Carriers for Antiproteolytics *F. Lopez-Calahorra Universitat de Barcelona, Spain Solid-phase a3C-NMR Study of Bis(3-Polystyrylthiazolin-2-ylidene)
112 L. R~tkos Royal Institute of Technology, Stockholm, Sweden Asymmetric Reduction of Chloroacetylated Polystyrene-Divinylbenzene. Preparation of Polymer-bound ( R)- and ( S)-Styrene Oxide P. Reinholdsson University of Lurid, Sweden Composite Particles for Preparative Chiral Separation G. Sacco CNRS, Nancy, France Phosphorylated Dextrans as Affinity Labelling Polymers of Human Hemoglobin for the Synthesis of Oxygen Carriers M. Tomoi Yokohama National University, Japan Solid-phase Phosphatidylethanolamine Synthesis F.R. Trull Universitat de Barcelona, Spain Synthetic Applications of the Bromomethyl-Nbb Resin. Esters of a Model for the natural Pyrrole Pigments by Transesterification of their ortho-Nitrobenzyl Ester Polystyrene Supported Precursors J. Veciana C.I.D. (C.S.1.C.) de Barcelona, Spain Dynamic HPLC on CSP. A New Analytical Method for Determining Rate Constants and Energy Barriers of Interconverting Enantiomers M. Zupan University of Ljubljana, Yugoslavia Regiospecific Introduction of Iodine into Aromatic Molecules by Crosslinked Poly(Styrene-4vinyl(pyridinium Dichloroiodate(I))) Y. Lukin Shemyakin Institute, Bioorganic Chemistry, Moscow, U.S.S.R. Polyacrolein Lattices as Immunoreagents Xu Zhanghuang Hubei University, Wuhan, China Synthesis of the San Jose Scale's Sex Pheromone Component Using Insoluble Polymer Support Juang Ji Long Hubei University, Wuhan, China Polymer-supported Alkaloid Ammonium Quaternary Salts as Phase-transfer Catalysts
107
PROGRAM (Papers selected for publication in this issue are marked with asterisks) OPENING CEREMONY SESSION 1 Chairman: E. Girait *A. Guyot CNRS, Vernaison, France Some Problems of Physical and Chemical Characterization of Functionalized Supports P. Guerin CNRS, Mont-Saint-Aignan, France High Resolution N M R Spectroscopy of Polymers and Copolymers of Malic Acid and its Benzyl- and Methylesters: Assignment and Structural Analysis by using the SINEPT Sequence SESSION 2 Chairman: J.K. Stille
W.T. Ford Oklahoma State University, Stillwater, OK, U.S.A. 13C N M R Spectroscopic Analysis of Vinyl Groups in Styrene-Divinylbenzene Networks *W.K. Fife Indiana University, Indianapolis, IN, U.S.A. Multi-step Functionalization of Solid-State Copolymers of 4-Vinylpyridine. Synthesis and Characterization E. Tsuchida Waseda University, Tokyo, Japan Reversible Oxygenation of Heme Derivatives Embedded in Polymer Matrices G. Gelbard CNRS, Vernaison, France Selective Oxidations and Reductions with Polymer-supported Anionic Reagents SESSION 3 Chairman: J.M.J. Fr~chet K.J. Shea
University of California, Irvine, CA, U.S:A. Characterization of Network Polymers by Fluorescence Techniques
108 SESSION 4
Chairman: F. Gaviha C. Caze Universit$ Sciences et Techniques, Lille, France Influence of a Spacer on the Kinetics of Reduction of Carbonyl Compounds with Macroporous Borohydride Exchange Resin *C. Buttersack Institut fftr Zuckerindustrie, Braunschweig, F.R.G. Catalysis by Strong Acid Exchange Resins in Different Solvents J. Huguet CNRS, Mont-Saint-Aignan, France Solubilization and Catalytic Effects of pH-Dependent Globular Macromolecules on the Hydrolysis of Amino Acid p-Nitrophenyl Esters SESSION 5
Chairman: K.J. Shea *J.K. Stille Colorado State University, Fort Collins, CO, U.S.A. Organic Synthesis via Polymer Supported Transition Metal Catalysis *F. Cunill Universitat de Barcelona, Spain Effect of Crosslinking and Water on the Catalytic Activity of Sulfonic Acid Ion-exchange Resins P. Piet Eindhoven University of Technology, The Netherlands The Promoting Role of Anchored Polycations in the Cobalt(II)Phthalocyanine Tetra-sodium Sulfonate Catalyzed Thiol Oxidation SESSION 6
Chairman: J. Font D. Andreu Universitat de Barcelona, Spain Peptides and Polymers: An Ongoing Affair L. D'Angiuro Stazione Sperimentale Cellulosa e Carta, Milan, Italy Influence of the Support on the Properties of Enzyme-graft Copolymers Used as Catalysts *P. Tundo Universith di Messina, ltaly High Activity in Displacement Reactions by Quaternary Onium Salts Immobilized on Inorganic Matrices
109 SESSION 7 Chairman: J. Rebek
*F. Gaviha
Universidad de Valbncia, Spain Transfer between Solid Phases. Mechanistic Studies SESSION 8 Chairman: F. Camps
*A.M. Costero
Universidad de ValJncia, Spain Generation of Unsaturated/3-Lactame Intermediate from a Polymeric Precursor C.K. Narang
University of Jodhpur, lndia Polymer-immobilized Enzyme Cofactors *D. Roizard
CNRS, Nancy, France Design of Biomimetic Soluble Polyacrylamides: Lateral Introduction of Active Units by Means of Variable Spacer Arm SESSION 9 Chairman: R. Jaequier
*C. Challa
State University Groningen, The Netherlands Catalysis by Polymer-bound Coenzyme Models A. Zitsmanis
Institute of Applied Biochemistry, Olaine, U.S.S.R. Influence of Properties of Polymeric Matrix on Efficiency of Polymeric Catalysts in Acylation and Condensation Reactions P.K. Dhal
University of Diisseidorf F.R.G. Studies on Induced Chirality in Side Chain Chromophores of Optically Active Vinyl Copolymers with Main Chain Chiral Configurations S E S S I O N 10 Chairman: A. Patchornik
Round Table on Polymer Supported Ideas S E S S I O N 11 Chairman: G. Gelbard S. Itsuno
Cornell University, Ithaca, NY, U.S.A.
110 Asymmetric Synthesis by Use of Polymer-supported Chiral Activating Agents R. Jacquie Universit~ des Sciences et Techniques du Languedoc, Montpellier, France Polymers with Pendant Chirality as a Tool in Supported Asymmetric Synthesis of a-Amino Acids G. Wulff University of Diisseldorf F.R.G. Polymer Assisted Molecular Recognition SESSION 12 Chairman: P. Hodge B. Sellergren University of Lund, Sweden Highly Enantio- and Substrate-selective Polymers Obtained by Molecular Imprinting Based on Non-covalent Interactions *K. Petrak Ciba-Geigy Pharmaceuticals, Horsham, England Pharmaceutical Applications of Functionalized Polymers SESSION 13 Chairman: F.R. Truil T. Shimidzu Kyoto University, Japan Functionalizations of Conducting Polymers with Functional Molecules and by Structural Control in Molecular Level toward Molecular Device SESSION 14 Chairman: F. L6pez-Calahorra Poster Discussion SESSION 15 Chairman: G. Wuiff J.M.J. Fr6chet Cornell University, Ithaca, N¥, U.S.A. Radiation-sensitive Polymers for Microelectronics: Design, Synthesis, and Application *F.R. Trull Universitat de Barcelona, Spain Insoluble Polystyrene-bound Porphyrins as 10 2 Photosensitizers. Bilirubin Photooxidation as a Probe for their Efficiencies J.L. Bourdelande Universitat Autbnoma de Barcelona, Spain Insoluble Polymeric Photosensitizers: Surface Photophysical and Photochemical Studies
111 SESSION 16 Chairman: D.C. Sherrington Summing-up and Closing Session POSTERS *F. Albericio Universitat de Barcelona, Spain On the Use of Polystyrene-l%-Divinylbenzene and Kel-F-g-Styrene for the Simultaneous Synthesis of Peptides F. Bardella Universitat de Barcelona, Spain On the Use of Polystyrene as a Solid Support in Oligodeoxyribonucleotide Synthesis H.J. van den Berg University of Groningen, The Netherlands Polymer-bound Thiamine Models: Influence of Site Isolation on the Catalytic Activity of Polystyrene-bound Thiazolium Salts W.T. Ford Oklahoma State University, Stillwater, OK, U.S.A. Cationic Latexes with Bound Cobalt Phthalocyaninetetrasulfonate Catalyze Autoxidation of 1-Decanethiol A. Guyot CNRS, Vernaison, France Macroporous Gel-type Styrene-Divinylbenzene Supports Z.M. Jaszay Polytechnical University of Budapest, Hungary Preparation and Investigation of Water Soluble Carbodiimides as Immobilizing Reagents of Enzymes *N. Kawabata Kyoto Institute of Technology, Japan Coagulation and Sedimentation of Microbial Cells by Soluble Pyridinium-type Polymers M. Klyavinsh Institute of Applied Biochemistry, Olaine, U.S.S.R. Preparative Aspects and Applications of Polymer-bound Crown Ethers in Catalysis of Condensation Reactions R.M. Laird Newcastle upon Tyne Polytechnic, England Polystyrenesulphonyl Phosphate: a Novel Phosphorylating Agent N.I. Larionova M.V. Lomonosov Moscow State University, U.S.S.R. Polymers as Carriers for Antiproteolytics *F. Lopez-Calahorra Universitat de Barcelona, Spain Solid-phase a3C-NMR Study of Bis(3-Polystyrylthiazolin-2-ylidene)
112 L. R~tkos Royal Institute of Technology, Stockholm, Sweden Asymmetric Reduction of Chloroacetylated Polystyrene-Divinylbenzene. Preparation of Polymer-bound ( R)- and ( S)-Styrene Oxide P. Reinholdsson University of Lurid, Sweden Composite Particles for Preparative Chiral Separation G. Sacco CNRS, Nancy, France Phosphorylated Dextrans as Affinity Labelling Polymers of Human Hemoglobin for the Synthesis of Oxygen Carriers M. Tomoi Yokohama National University, Japan Solid-phase Phosphatidylethanolamine Synthesis F.R. Trull Universitat de Barcelona, Spain Synthetic Applications of the Bromomethyl-Nbb Resin. Esters of a Model for the natural Pyrrole Pigments by Transesterification of their ortho-Nitrobenzyl Ester Polystyrene Supported Precursors J. Veciana C.I.D. (C.S.1.C.) de Barcelona, Spain Dynamic HPLC on CSP. A New Analytical Method for Determining Rate Constants and Energy Barriers of Interconverting Enantiomers M. Zupan University of Ljubljana, Yugoslavia Regiospecific Introduction of Iodine into Aromatic Molecules by Crosslinked Poly(Styrene-4vinyl(pyridinium Dichloroiodate(I))) Y. Lukin Shemyakin Institute, Bioorganic Chemistry, Moscow, U.S.S.R. Polyacrolein Lattices as Immunoreagents Xu Zhanghuang Hubei University, Wuhan, China Synthesis of the San Jose Scale's Sex Pheromone Component Using Insoluble Polymer Support Juang Ji Long Hubei University, Wuhan, China Polymer-supported Alkaloid Ammonium Quaternary Salts as Phase-transfer Catalysts