Solubility parameter and liquid volume—Inorganic compounds

Chapter 14 SOLUBILITY PARAMETER AND LIQUID VOLUME -INORGANIC COMPOUNDS Carl L. Yaws and K. Y. Li Lamar University, Beaumont, Texas Tabulation Results The results are given in Table 14. The tabulation is arranged by alphabetical order (Ag, AI, Ar, , Zr ) to provide ease of use in quickly locating the data by using the chemical formula. The compound name and CAS No (Chemical Abstracts Registry Number) are next provided. Values for solubility parameter and liquid volume are given in the adjacent columns. The next column provides the code for the tabulation. For the tabulation, the results for solubility parameter are ascertained from heat of vaporization and liquid volume sol par = [(~Hvap - RT) / v ]05

(14) 3

sol par = solubility parameter, (joule/cm )0.5 ~Hvap = enthalpy of vaporization, joule/mol R = universal gas constant, joule/(mol K) T = temperature, K 3 v = liquid volume, cm /mol

where

For compounds that are liquids at ambient conditions, the values apply at 25 C. For compounds that are gases at ambient conditions, the values apply at the normal boiling point temperature. For compounds that are solids at ambient conditions, the values apply at the melting point temperature. In preparing the tabulation, a literature search was conducted to identify data source publications (1-36). Both experimental values for the property under consideration and parameter values for estimation of the property are included in the source publications. The publications were screened and copies of appropriate data were made. These data were then keyed into the computer to provide a database of values for compounds for which experimental data are available. The database also served as a basis to check the accuracy of the estimation methods. Upon completion of data collection, estimation of values for the remaining compounds was performed. The compilations of CRC (1-2); Daubert and Danner (3); Janz, Ward, and Reeves (7); Landolt and Bornstein (8); Lange's Handbook (9-10), Vargaftik(18); web sites (19-21), and Yaws (22-36) were used extensively. The Kistiakowsky rule (14) and Riedel method (14) were primarily used for estimates of enthalpy of vaporization at the boiling point. Estimates of liquid density were primarily based on Schroeder correlation (14, group contribution), Le Bas method (14, group contribution), and Tyn-Calus equation (14, critical volume). Liquid volume was ascertained from molecular weight and liquid density (molecular weight/density). For the inorganic compounds, most of the data for enthalpy of vaporization and liquid density are only available for compounds with low boiling points and low melting points. The data available for compounds with high normal boiling points and high melting points are very meager. In the absence of data, the estimates should be considered rough approximations for those compounds with high boiling points and high melting points. Example In an engineering analysis, the solubility parameter and liquid volume are needed for silicon tetrachloride (SiCI4). Determine the solubility parameter and liquid volume for silicon tetrachloride. Inspection of the tabulation yields: sol par v

= 15.342 (joule/cm3)0.5

= 115.581 cm 3/mol

References 1. 2.

CRC HANDBOOK OF CHEMISTRY AND PHYSICS, 75th - 86th eds., eRe Press, Inc., Boca Raton, FL (1994-2006). CRC HANDBOOK OF THERMOPHYSICAI AND THERMOCHEMICAl DATA, eRe Press, Boca Raton, FL (1994).

644

3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36.

Daubert, T. E. and R. P. Danner, DATA COMPILATION OF PROPERTIES OF PURE COMPOUNDS, Parts 1, 2,3, and 4, Supplements 1 and 2, DIPPR Project, AIChE, New York, NY (1985-1994). Emsley, J., THE EI EMENTS, 3'd ed., Claredon Press, Oxford, Great Britian (1998). ENCYClOPEDIA OF CHEMICAl TECHNOlOGY, 3rd and 4th eds., John Wiley and Sons, Inc., New York, NY (1978-2004). Hampel, C. A., THE ENCYCLOPEDIA OF THE CHEMICAl EI EMENTS, Reinhold Book Corp., New York, NY (1968). Janz, G. J., A. 1. Ward, and R. D. Reeves, MOLTEN SALT DATA, Electrical Conductance, Density, and Viscosity, Technical Bulletin Series, Rensselaer Polytechnic Institute, Troy, NY (1964). Landolt, H. and R. Bornstein, ZAHL ENWERTE UND EUNKIONEN ANS PHYSIK CHEMEI ASTRONOMIE UND TECHNIK, Springer-Verlag, Heidelberg, Germany (1971-2005). LANGE'S HANDBOOK OF CHEMISTRY, 15th ed., J. A. Dean, ed., McGraw-Hili, New York, NY (1999). LANGE'S HANDBOOK OF CHEMISTRY, 16th ed., J. G. Speight, ed., McGraw-Hili, New York, NY (2005). PERRY'S CHEMICAL ENGINEERING HANDBOOK, 5th ed., McGraw-Hili, New York, NY (1973). PERRY'S CHEMICAL ENGINEERING HANDBOOK, 6th ed., McGraw-Hili, New York, NY (1984). PERRY'S CHEMICAl ENGINEERING HANDBOOK, 7th ed., McGraw-Hili, New York, NY (1997). Poling, B. E., J. M. Prausnitz, and J. P. O'Connell, THE PROPERTIES OF GASES AND LIQUIDS, 5th ed., McGraw-Hili, New York, NY (2000). Reid, R. C., J. M. Prausnitz, and B. E. Poling, THE PROPERTIES OF GASES AND liQUIDS, 4th ed., McGraw-Hili, New York, NY (1987). Reid, R. C. and 1. K. Sherwood, THE PROPERTIES OF GASES AND L1QIJlDS, 3rd ed., McGraw-Hili, New York, NY (1977). Rossotti, H., DIVERSE ATOMS, Profiles of the Chemical Elements, Oxford University Press, Oxford, Great Britian (1998). Vargaftik, N. B., TABI ES ON THE THERMOPHYSICAI PROPERTIES OF IIQIJlDS AND GASES, 2nd ed., English translation, Hemisphere Publishing Corporation, New York, NY (1975, 1983). web site, asia.matweb.com (2007). web site, Wikipedia, the free encyclopedia, en.wikipedia.org (2007). web site, www.webelements.com (2007). Yaws, C. L. and Others, "Ammonia and Hydrazine - Phy. and Thermo. Prop. (6)", Chem. Eng., B.1 (25), 178 (Nov. 25,1974). Yaws, C. L. and Others, "Major Diatomic Gases (Hydrogen, Nitrogen and Oxygen) - Phy. and Thermo. Prop. (8)", Chem. Eng., B2 (2),99 (Jan. 20,1975). Yaws, C. L. and Others, "N-Type Gas Phase Dopants - Physical and Thermodynamic Properties of Arsine, Phosphine and Stibine", Solid State Technology, 11 (1),47 (1974). Yaws, C. L. and Others, "Oxides of Nitrogen (Nitrous Oxide, Nitric Oxide and Nitrogen Dioxide) - Phy. and Thermo. Prop. (3)", Chem. Eng., B.1 (17),99 (August 19,1974). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silane", Solid State Techn., 21 (1), 43 (January, 1978). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silicon Tetrachloride", Solid State Techn., 22 (No.2), 65 (February, 1979). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silicon Tetrafluoride", J.Ch.I.Ch.E., 12 (1), 33 (1981). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Trichlorosilane", J.Ch.I.Ch.E., .14, 205 (1983). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Dichlorosilane", Ind. Eng. Chem. Process Des. Dev., 23, 48 (1984). Yaws, C. L. and Others, "P-Type Gas Phase Dopants (Diborane and Pentaborane): Physical and Thermodynamic Properties", Solid State Technology, 11 (11),31 (1974). Yaws, C. L., PHYSICAl PROPERTIES, McGraw-Hili, New York, NY (1977). Yaws, C. L., CHEMICAL PROPERTIES HANDBOOK, McGraw-Hili, New York, NY (1999). Yaws, C. L., MATHESON GAS DATA BOOK, ylh ed., Matheson Tri-Gas (Parisppany, NJ), McGraw-Hili, New York, NY (2001). Yaws, C. L., YAWS HANDBOOK OF THERMODYNAMIC AND PHYSICAl PROPERTIES OF CHEMICAl COMPOUNDS, electronic edition, www.knovel.com. Knovel, Norwich, NY (2003-present). Yaws, C. L., YAWS HANDBOOK OF PHYSICAl PROPERTIES FOR HYDROCARBONS AND CHEMICALS, Gulf Publishing Company, Houston, TX (2005).

645

Table 14 Solubility Parameter and Liquid Volume -Inorganic Compounds 3

3

3

13 35 45 77 82 86 88 96 127 134 146 167 200 202 203 228 230 231 234 238 245 256 283 285 361 363 394 401 404 405 406 413 416 530 534 541 550 562 564 576 626 628 633 641 642 644 645 646 647 648 651 652 653 654 655 656 661 675 728 776 791 798 804 809 891 892 893 894 898 899 900 905 916 968 1035 1099 1124 1128 1137 1140

FORMULA Ag AgCI Agi

AI AlBr3 AlC2H6CI AlC3H9 AlC6H15 AlCI3 AlF3 AlI3 Al203 Ar As AsBr3 AsCI3 AsF3 AsF5 AsH3 Asl3 As203 Au B BBr3 BCI3 BF3 B2H6 B3N3H6 B4Hl0 B5H9 B5Hll Bl0H14 Ba Be BeBr2 BeCI2 Bel2 Bi BiBr3 BiCI3 BrF3 BrF5 Br2 CCI20 CF20 CH4N20 CH4N2S CNBr CNCI CNF CN408 CO COS COSe CO2 CS2 C2N2 Ca CaF2 Cd CdCI2 CdF2 Cdl2 CdO CIF CIF03 CIF3 CIF5 CI02 CI2 CI20 CI207 Co CoCI2 Cr Cr02CI2 Cs CsBr CsCI esF

NAME silver silver (i) chloride silver (i) iodide aluminum aluminum bromide aluminum, dimethyl chloride aluminum, trimethyl aluminum, triethyl aluminum chloride aluminum fluoride aluminum iodide aluminum oxide argon arsenic arsenic (iii) bromide arsenic trichloride arsenic trifluoride arsenic pentafluoride arsine arsenic triiodide arsenic trioxide gold boron boron tribromide boron trichloride boron trifluoride diborane borazine tetraborane pentaborane pentaborane decaborane barium beryllium beryllium bromide beryllium chloride beryllium iodide bismuth bismuth tribromide bismuth trichloride bromine trifluoride bromine pentafluoride bromine carbonyl chloride carbonyl fluoride

urea thiourea cyanogen bromide cyanogen chloride cyanogen fluoride tetranitromethane carbon monoxide carbonyl sulfide carbon oxyselenide carbon dioxide

carbon disulfide cyanogen

calcium calcium fluoride cadmium cadmium chloride cadmium fluoride cadmium iodide cadmium oxide chlorine monofluoride perchloryl fluoride chlorine trifluoride chlorine pentafluoride chlorine dioxide chlorine chlorine monoxide chlorine heptoxide cobalt cobalt chloride chromium chromium oxychloride cesium cesium bromide cesium chloride cesium fluoride

CAS No sol par

v

7440-22-4 155.190 11.605 7783-90-6 91.958 29.507 7783-96-2 64.292 42.288 7429-90-5 166.403 11.401

7727-15-3 1184-58-3 75-24-1 97-93-8 7446-70-0 7784-18-1 7784-23-8 1344-28-1 7440-37-1 7440-38-3 7784-33-0 7784-34-1 7784-35-2 7784-36-3 7784-42-1 7784-45-4 1327-53-3 7440-57-5 7440-42-8 10294-33-4 10294-34-5 7637-07-2 19287-45-7 6569-51-3 18283-93-7 19624-22-7 18433-84-6

15.123 20.152 20.407 22.934 18.492 73.767 16.540 152.730 14.138 37.040 22.332 21.091 24.130 16.128 17.504 24.820 31.937 196.846 329.687

18.098 15.679 20.305 14.083 18.726 15.494 15.404 18.891 17.905 --7440-39-3 63.777 7440-41-7 235.733 7787-46-4 42.107 7787-47-5 44.537 7787-53-3 31.639 7440-69-9 87.487 7787-58-8 29.466 7787-60-2 31.542 7787-71-5 32.505 7789-30-2 20.312 7726-95-6 23.794 75-44-5 17.833 353-50-4 15.362 57-13-6 36.540 62-56-6 24.960 506-68-3 22.626 506-77-4 21.831 1495-50·7 24.762 509-14-8 18.378 630-08-0 12.146 463-58-1 18.130 1603-84-5 20.261 124-38-9 19.774 75-15-0 20.319 460-19-5 20.049 7440-70-2 75.664 7789-75-5 107.442 7440-43-9 87.435 10108-84-2 50.592 7790-79-6 94.613 7790-80-9 39.324 1306-19-0 133.585 7790-89-8 25.950 7616-94-6 16.985 7790-91-2 22.282 13637-63-3 17.296 10049-04-4 25.701 7782-50-5 20.190 7791-21-1 20.929 10294-48-1 18.952 7440-48-4 230.037 7646-79-9 58.945 7440-47-3 204.993 14977-61-8 21.400 7440-46-2 7787-69-1 7647-17-8 13400-13-0

32.025 50.890 46.039 56.054

111.397 93.173 96.325 137.079 103.448 34.480 126.394 29.029 28.586 14.171 96.172 84.315 49.791 72.924 48.100 112.196 56.428 11.397 5.006 95.446 87.074 43.146 64.533 89.260 102.807 98.202 87.954 140.870 41.301 5.333 53.340 52.731 65.198 20.765 95.984 80.373 48.640 70.923 51.480 70.547 61.524 44.984 90.511 56.537 51.356 32.929 120.267 35.456 50.984 56.187 35.020 60.639 54.341 29.299 31.017 14.022 53.982 26.605 82.960 18.142 33.517 60.457 50.677 69.166 41.852 45.389 53.904 98.881 7.687 44.949 8.049 81.436 71.723 67.956 62.194 41.342

3

Solubility Parameter and Liquid Volume (sol par· Ooulelcm )o.s, v - cm /mol)

Solubility Parameter and Liquid Volume (sol par· Ooulelcm )o.s, v· cm /mol)

10

cod

10

1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2

1144 1169 1173 1229 1230 1255 1302 1303 1369 1406 1409 1412 1420 1434 1502 1505 1575 1578

Csi Cu CuBr CuCI CuCI2 Cui D2 D20 Eu FNO F2 F20 Fe FeC505 FeCI2 FeCI3

1699 1702 1709 1712 1713 1714 1716 1718 1719 1721 1722 1739 1740 1771 1773 1800 1813 1868 1869 1873 1877

HI HN03 H2 H2O H202 H2S H2SO4 H2S2 H2Se H2Te H3NO He Hf Hg HgBr2 HgCI2 Hgl2 IF5 IF7

1917 1960 1972 2009 2018 2035 2047 2162 2168 2203 2213 2253 2261 2270 2316 2335 2392 2429 2464 2495 2548 2573 2585 2607 2608 2613 2619

Ir K KBr KCI KF KI KOH Kr La Li LiBr LiCI LiF Lil Lu Mg MgCI2 MgO Mn MnCI2 Mo MoF6 Mo03 NCIO NCI3 NF3 NH3

646

FORMULA

Ga GaC3H9 1585 GaCI3 1637 Ge 1639 GeBr4 1661 GeCI4 1668 GeHCI3 1675 GeH4 1686 Ge2H6 1687 Ge3H8 1691 HBr 1694 HCN 1695 HCI 1696 HCI03S 1697 HCI04 1698 HF

12 In

NAME cesium iodide copper cuprous bromide cuprous chloride cupric chloride copper iodide deuterium deuterium oxide europium nitrosyl fluoride fluorine fluorine oxide iron iron pentacarbonyl ferrous chloride ferric chloride gallium gallium, trimethyl gallium trichloride germanium germanium bromide germanium chloride germane, trichloro germane digermane trigermane hydrogen bromide hydrogen cyanide hydrogen chloride chlorosulfonic acid perchloric acid hydrogen fluoride hydrogen iodide nitric acid hydrogen water hydrogen peroxide hydrogen sulfide sulfuric acid hydrogen disulfide hydrogen selenide hydrogen telluride hydroxylamine helium-4 hafnium mercury mercuric bromide mercuric chloride mercuric iodide iodine pentafluoride iodine heptafluoride iodine indium iridium potassium potassium bromide potassium chloride potassium fluoride potassium iodide potassium hydroxide krypton lanthanum lithium lithium bromide lithium chloride lithium fluoride lithium iodide lutetium magnesium magnesium chloride magnesium oxide manganese manganese (ii) chloride molybdenum molybdenum fluoride molybdenum oxide nitrosyl chloride nitrogen trichloride nitrogen trifluoride ammonia

CAS No sol par 7789-17-5 7440-50-8 7787-70-4 7758-89-6 7447-39-4 7681-65-4 7782-39-0 7789-20-0 7440-53-1 7789-25-5 7782-41-4 7783-41-7 7439-89-6 13463-40-6 7758-94-3 7705-08-0 7440-55-3 1445-79-0 13450-90-3 7440-56-4 13450-92-5 10038-98-9 1184-65-2 7782-65-2 13818-89-8 14691-44-2 10035-10-6 74-90-8 7647-01-0 7790-94-5 7601-90-3 7664-39-3 10034-85-2 7697-37-2 1333-74-0 7732-18-5 7722-64-1 7783-06-4 7664-93-9 13465-07-1 7783-07-5 7783-09·7 7803-49-8 7440-59-7 7440-58-6 7439-97-6 7789-47-1 7487-94-7 7774-29-0 7783-66-6 16921-96-3 7553-56-2 7440-74-6 7439-88-5 7440-09-7 7758-02-3 7447-40-7 7789-23-3 7681-11-0 1310-58-3 7439-90-9 7439-91·0 7439-93-2 7550-35-8 7447-41-8 7789-24-4 10377-51-2 7439-94-3 7439-95-4 7786-30-3 1309-48-4 7439-96-5 7773-01-5 7439-98-7 7783-77-9 1313-27-5 2696-92-6 10025-85-1 7783-54-2 7664-41-7

v

46.356 81.571 209.123 8.043 88.011 32.468 52.027 26.431 62.667 44.809 79.319 38.248 6.282 24.978 49.264 18.087 75.750 31.402 21.852 36.662 15.208 25.283 16.774 35.620 212.755 7.751 16.145 134.980 22.214 44949 25.153 62.639 158.422 11.471 17.370 100.788 16.894 85.783 163.332 13.001 19.325 124.968 15.625 115.627 17.551 93.779 15.002 55.645 16.050 88.949 18.184 102.183 20.850 37.597 25.093 39.768 22.004 30.563 26.116 66.941 21.942 57.085 15.602 20.945 19.725 45.718 30.460 39.426 5.067 28.604 47.868 17.969 45.956 23.452 21.753 35.860 34.303 53.305 26.222 49.883 20.846 40.989 18.065 51.928 46.740 27.436 1.223 32.257 197.385 14.874 65.074 14.861 29.093 70.338 30.025 62.143 26.087 87.042 25.067 69.560 14.535 92.635 25.533 63.835 126.778 16.329 245.492 9.611 43.362 47.204 55.231 55.991 53.571 48.891 72.325 30.434 57.528 67.783 73.702 32.592 15.331 34.648 135.870 24.488 116.047 13.547 60.707 34.226 94.205 28.225 109.171 14.196 65.247 43.148 195.641 19.265 95.933 15.396 56.438 56.780 220.608 6.772 161.408 8.544 58.939 48.912 257.605 10.283 18.026 83.198 66.268 33.650 21.832 49.406 20.302 73.370 15.075 45.662 29.179 24.980

cod<

1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2

Table 14 Solubility Parameter and liquid Volume -Inorganic Compounds Solubility Parameter and Liquid Volume (sol par - Ooulelem")"-s, v - em"fmol) 10

FORMULA

2625 NH4Br 2627 NH4CI 2634 NH41 2674 NO 2676 N02 2678 N2 2684 N2F4 2685 N2H4 2747 N20 2748 N203 2749 N204 2750 N205 Na NaBr NaCN NaCI 2864 NaF 2781 2800 2810 2855

2888 Nal 2897 NaOH 3019 Nb 3037 NbF5 3057 Nd 3091 Ne 3092 Ni 3105 NiC404 3198 02 3199 03

NAME

ammonium bromide ammonium chloride ammonium iodide nitric oxide nitrogen dioxide nitrogen tetrafluorohydrazine hydrazine nitrous oxide nitrogen trioxide nitrogen tetraoxide nitrogen pentoxide sodium sodium bromide sodium cyanide sodium chloride sodium fluoride sodium iodide sodium hydroxide niobium niobium (v) fluoride neodymium neon nickel nickel carbonyl oxygen

ozone

osmium osmium tetroxide phosphorus (white) phosphorus tribromide phosphate, trimethyl 3280 PC6H1504 phosphate, triethyl phosphorus (iii) chloride 3381 PCI3 phosphorus pentachloride 3382 PCI5 phosphine 3389 PH3 phosphonium iodide 3392 PH41 phosphorus oxychloride 3396 POCI3 phosphorus thiochloride 3398 PSCI3 phosphorus (v) sulfide 3451 P2S5 phosphorous (iii) oxide 3461 P406 lead 3483 Pb lead bromide 3487 PbBr2 tetraethyl lead 3504 PbC8H20 lead chloride 3514 PbCI2 lead fluoride 3521 PbF2 lead iodide 3530 Pbl2 lead oxide 3537 PbO lead sulfide 3545 PbS palladium 3571 Pd polonium 3641 Po platinum 3691 PI radium 3773 Ra rubidium 3781 Rb 3786 RbBr rubidium bromide 3791 RbCI rubidium chloride rubidium fluoride 3795 RbF rubidium iodide 3801 Rbi rhenium 3828 Re rhenium heptoxide 3875 Re207 rhodium 3880 Rh radon 3940 Rn ruthenium 3941 Ru ruthenium (v) fluoride 3974 RuF5 sulfur 3991 S 3994 SCI2 sulfur dichloride thionyl chloride 3996 SCI20 sulfur tetrafluoride 3998 SF4 4001 SF6 sulfur hexafluoride thionyl bromide 4004 SOBr2 thionyl chloride 4005 SOCI2 thionyl fluoride 4006 SOF2 sulfur dioxide 4007 S02 4008 S02CI2 sulfuryl chloride sulfur trioxide 4010 S03 sulfur monochloride 4013 S2CI2 antimony 4023 Sb antimony tribromide 4025 SbBr3 antimony trichloride 4042 SbCI3 4044 SbCI5 antimony pentachloride 3200 Os 3222 Os04 3234 P 3238 PBr3 3252 PC3H904

CAS No sol par

Solubility Parameter and Liquid Volume (sol par - Ooulelem")o." v - em"fmol)

cod.

v

10

12124-97-9 12125-02-9 12027-06-4 10102-43-9

36.124 33.207 1,2 4047 23.479 37.952 1,2 4049 19.610 63.691 1,2 4056 23.118 23.427 1,2 4065 10102-44-0 26.441 31.781 1,2 4083 7727-37-9 11.915 34.672 1,2 4089 10036-47-2 12.525 74.077 1,2 4107

FORMULA

NAME

SbH3 Sbl3

stibine antimony triiodide

Sb203

antimony (iii) oxide scandium selenium (gray) selenosulfide, carbon selenium tetrachloride selenium tetrafluoride selenium hexafluoride selenium oxychloride selenium dioxide

Sc

Se SeCS SeCI4 302-01-2 39.052 28.632 1,2 4109 SeF4 10024-97-2 20.308 36.002 1,2 4110 SeF6 10544-73-7 26.321 53.592 1,2 4115 SeOCI2 10544-72-6 23.745 63.269 1,2 4117 Se02 10102-03-1 28.375 72.356 1,2 4140 Si

silicon

7440-23-5 7647-15-6 143-33-9 7647-14-5 7681-49-4

silane, bromodichlorofluoro silane, dibromochlorofluoro tetrabromosilane silane, methyltrichloro silane, methyldichloro

66.717 24.863 61.502 43.939 68.089 38.644 60.677 37.713 90.859 21.593 7681-82-5 68.062 54.663 1310-73-2 98.856 22.434 7440-03-1 244.764 11.865

1,2 1,2 1,2 1,2 1,2

4143 SiBrCI2F 4144 SiBr2CIF 4146 SiBr4 4149 SiCH3CI3 4150 SiCH4CI2

1,2 4152 SiC2H5CI3 1,2 4153 SiC2H6CI2 1,2 4157 SiC3H10

7783-68-8 30.533 61.997 1,2 7440-00-8 117.261 22.306 1,2 7440-01-9 9.440 16.762 1,2 7440-02-0 233.591 7.564 1,2

4187 SiC7H8CI2 4196 SiC8H20 4238 SiCIC3H9

4240 13463-39-3 14.583 130.747 1,2 4241 7782-44-7 14.635 28.196 1,2 4243 10028-15-6 18.745 35.578 1,2 4244 7440-04-2 282.642 9.464 1,2 4245 20816-12-0 27.044 57.503 1,2 4246 7723-14-0 25.964 17.744 1,2 4247 7789-60-8 21.314 95.635 1,2 4248 512-56-1 21.308 116.548 1,2 4250 78-40-0 17.913 170.915 1,2 4251

7719-12-2 18.774 87.684 10026-13-8 26.049 62.669 7803-51-2 16.886 45.730 12125-09-6 23.945 56.955 10025-87-3 19.816 92.010 3982-91-0 18.618 104.197

1,2 1,2 1,2 1,2

4252 4253 4257 4258 1,2 4259 1,2 4260 1314-80-3 20.316 126.660 1,2 4261 12440-00-5 21.738 103.336 1,2 4265 7439-92-1 101.283 19.478 1,2 4274 10031-22-8 49.002 65.199 1,2 4275

78-00-2 16.528 196.205 7758-95-4 50.754 56.178 7783-46-2 74.897 31.469 10101-63-0 38.883 79.549

SiCIF3 SiCI2F2

1314-68-7 28.862 7440-16-6 229.691 10043-92-2 17.855 7440-18-8 255.612 14521-18-7 29.921

48.971 58.230 60.901 53.784 30.905 73.139 9.852 88.327 9.662 51.256 9.272 75.094 17.870

7704-34-9 52.998 10545-99-0 22.329 63.903 1,2 7719-09-7 20.882 73.005 1,2 7783-60-0 20.284 59.557 1,2 2551-62-4 13.896 76.274 1,2 507-16-4 7719-09-7 7783-42-8 7446-09-5

silane, chlorotrifluoro silane, dichlorodifluoro silane, trichlorofluoro

SiF4 SiHBr3 SiHCI3 SiHF3 SiH2Br2

silicon tetrafluoride silane, tribromo silane, trichloro silane, trifluoro

SiH2CI2 SiH2F2 SiH212 SiH3Br SiH3CI SiH3F SiH31 SiH4 Si02

silane, dibromo silane, dichloro silane, silane, silane, silane,

difluoro diiodo monobromo monochloro

silane, monofluoro silane, iodo silane silicon dioxide (alpha quartz)

Si2C6H180 disiloxane, hexamethyl Si2C6H19N disilazane, hexamethyl

Si4H10 Sm Sn SnBr4 SnCI2 SnCI4 Snl4 Sr Ta Tc Te TeCI4

4703 TI 4704 TIBr

78.188 1,2 4728 20.884 73.010 1,2 4747 19.311 53.348 1,2 4766 22.916 43.823 1,2 4787 7791-25-5 19.733 81.413 1,2 4836 7446-11-9 31.130 42.095 1,2 4860 10025-67-9 21.960 80.821 1,2 4880

Til Tm

7440-36-0 104.811 18.758 1,2 4899 7789-61-9 27.181 89.939 1,2 4917 10025-91-9 24.441 85.118 1,2 4945 7647-18-9 21.027 128.552 1,2 4960

W WF6 Xe

647

silane, tetraethyl chlorotrimethylsilane

silicon tetrachloride

TeF6 4639 Ti 4678 TiCI4

23.211

silane, methylphenyldichloro

SiCI3F

1,2 4286 Si2CI6 1,2 4287 Si2CI60 1,2 4288 Si2F6

1,2 4300 1,2 4303 1,2 4332 1,2 4335 1,2 4422 1,2 4424 1,2 4433 1,2 4461 1,2 4517 1,2 4570 1,2 4583 1,2 4588 1,2 4590

silane, trimethyl

SiCI4

1,2 4289 Si2H6 1317-36-8 96.961 24.886 1,2 4290 Si2H60 1314-87-0 82.836 33.910 1,2 4291 Si20CI3F3 7440-05-3 191.054 10.177 1,2 4295 Si3CI8 7440-08-6 68.162 24.216 1,2 4296 Si3H8 7440-06-4 232.191 10.359 1,2 4297 Si3H9N 7440-14-4 49.303 7440-17-7 38.700 7789-39-1 54.173 7791-11-9 59.816 13446-74-7 80.579 7790-29-6 56.246 7440-15-5 269.338

silane, ethyltrichloro silane, dimethyldichloro

U UF6 V VCI4 VOCI3

Y

disilane, hexachloro disiloxane, hexachloro disilane, hexafluoro disilane disiloxane disiloxane, trichlorotrifluoro octachlorotrisilane trisilane trisllazane tetrasilane

samarium tin (white) stannic bromide stannous chloride stannic chloride

stannic iodide strontium tantalum technetium tellurium tellurium tetrachloride tellurium hexafluoride titanium titanium tetrachloride thallium thallous bromide thallium iodide thulium uranium uranium fluoride vanadium vanadium tetrachloride vanadium oxytrichloride tungsten tungsten fluoride xenon yttrium

CAS No sol par

v

cod

7803-52-3 18.722 55.749 1,2 7790-44-5 27.092 105.470 1,2 1309-64-4 38.101 57.850 1,2 7440-20-2 146.237 16.295 1,2 7782-49-2 74.320 19.800 1,2 5951-19-9 23.975 62.241 1,2 10026-03-6 15.629 124.033 1,2 13465-66-2 29.927 7783-79-1 13.950 7791-23-3 26.564 7446-08-4 50.757 7440-21-3 205.243

56.347 84.599

1,2 1,2

68.698 1,2 33.748 1,2

1,2 1,2 1,2 1,2 1,2 104.287 1,2 133.414 1,2 75·78·5 15.632 121.207 1,2 933-07-7 13.009 116.614 1,2

--...

14.140 15.402 7789-66·4 18.447 75-79-6 15.227 75·54·7 15.403 115-21-9 15.979

10.927 109.231 106.012 124.179 118.043

149-74-6 17.771 162.884 631-36-7 14.895 189.288 75-77-4 14.655 127.296 14049-36-6 14.610 79.699

1,2 1,2 1,2

1,2 18356-71-3 14.363 92.565 1,2 14965-52-7 13.548 105.509 1,2 10026-04-7 15.342 115.581 1,2 7783-61·1 7789-57-3 10025-78-2 13465-71-9 13768-94-0

14.380 64.097 1,2 19.143 100.231 1,2 15.489 101.489 1,2

13760-02-6 13465-73-1 13465-78-6 13537-33-2

21.655 100.501 1,2 17.460 72.527 1,2

15.433 61.799 1,2 18.470 89.957 1,2 4109-96-0 16.680 81.957 1,2 13824-36-7 16.074 56.800 1,2

16.882 66.599 1,2 18.278 51.800 1,2 13598-42-0 19.186 77.783 1,2 7803-62-5 13.982 55.126 1,2 14808-60-7 128.200 23.749 1,2 107-46-0 12.575 213.776 1,2 999·97·3 13.632 209.042 1,2 13465-77-5 13.302 173.787 1,2 14986-21-1 12.859 180.194 1,2 11.588 116.199 1,2 1590-87-0 14.378 92.109 1,2 13597-73-4 13.547 93.632 1,2

-_.

-----

11.053 158.294 1,2 12.415 231.660 1,2

7783-26-8 14.643 128.148 1,2 13.149 125.170 1,2 7783-29-1 12.976 158.807 1,2 7440-19-9 88.000 21.666 1,2 7440-31-5 141.989 17.028 1,2 7789-67-5 19.493 130.697 1,2 7772-99-8 42.346 56.371 1,2 7646-78-8 17.739 117.592 1,2 7790-47-8 20.958 146.682 1,2 7440-24-6 61.480 36.893 1,2 7440-25-7 249.522 12.063 1,2 7440-26-8 254.869 9.233 1,2 13494-80-9 72.072 22.011 1,2 10026-07-0 28.136 104.863 1,2 7783-80-4 14.029 77.517 1,2 7440-32-6 204.769 11.646 1,2

---

7550-45-0 18.553 110.669 1,2 7440-28-0 100.507 18.101 1,2 7789-40-4 52.954 39.485 1,2 7790-30-9 49.046 49.011 7440-30-4 110.762 19.636 7440-61-1 184.412 13.292 7783-81-5 18.017 78.937 7440-62-2 226.278 9.181

1,2 1,2 1,2 1,2

1,2 7632-51·1 20.116 105.853 1,2 7727-18-6 19.363 105.846 1,2 7440-33-7 285.129 10.386 1,2 7783-82-6 16.655 86.838 1,2 7440-63-3 15.655 44.449 1,2 7440-65-5 134.572 21.550 1,2

Table 14 Solubility Parameter and Liquid Volume -Inorganic Compounds 3

3

3

10

FORMULA

NAME

CAS No sol par

y

.ado

10

FORMULA

ytterbium 7440-64-4 76.493 26.904 1,2 5069 ZnF2 4995 Vb zinc 7440-66-6 113.746 9.938 1,2 5113 Zr 5021 Zn zinc chloride 7646-85·7 51.231 56.941 1,2 5062 ZnCI2 1 -data, 2 - estimate Code: • Use 10 or CAS No for cOfr4Jlete name (See Chapther 1 of this book).

648

3

Solubility Parameter and Liquid Volume (sol par· Ooulelcm )o." y. cm /mol)

Solubility Parameter and Liquid Volume (sol par· Ooulelcm )o." y. cm /mol)

NAME zinc fluoride zirconium

CAS No sol par

y

[code

7783-49-5 97.627 22.652 1,2 7440-67-7 206.484 15.728 1,2