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04817 Solvent effects of fractions from coal liquid on the upgrading reaction of coal liquefaction residue
02
Method for regeneration of coal-water slurry 96lQ46QQ Suzuki, Y. et al., (Assigned to) Jgc Corp.; Nippon Kogyo Senjo KK, JAP. Par. JP.O7,286,287, Oct. 1985. The method is carried out by withdrawing precipitates from the slurry, and then adding water and additives into the resulting slurry followed by pulverizing and mixing. Modeling of the phase equlllbrlum 96104001 late8 from coal hydrogenation Kudryavtseva, T. A. 60-66. (In Russian)
er al.,
Molybdenum hexacarbonyl for solvent-free direct coal llquefactlon
as a catalyst precursor
Warzinski, R. P. and Bockrath, B. C. Energy Fuels, 1996, 10, (3), 612-622. Discusses the use of molybdenum hexacarbonyl in solvent-free experiments. The activity of the catalysts formed from Mo(CO),, both for Ii uefaction and a Blind Canyon bituminous coal and for methanation of C 8, In the absence of coal, was a function of activation conditions and reaction parameters. 96/04803
Natural gas to syncrude:
Maklng the process pay
Off
Puskas, I. Chemtech, 1995, 25, (12), 43-49. Discusses the available technology for the manufacture of synthetic crude petroleum and liquid hydrocarbon feedstocks from natural gas. Topics include the manufacture -of synthesis gas, manufacture of ammonia, manufac[ure of MeOH, the Fischer-Tropsch synthesis, the MeOH-to-gasoline process, economic fundamentals, and opportunities for research and development.
96104604
coprocesslng
Performance of of a demlnerallzed
96/04610 Reactlons of dlbenzothlophene presence of selected molybdenum, compounds
the
dlfferent catalysts Catalan llgnlte
on
the
Beneoa. C. et al.. Enerw Fuels. 1996. 10. (31. 679-683. The-w&k studies’ copro&sing df a lignitd @krueda, Catalonia, Spain) with a petroleum vacuum residue in the presence of Fe, Fe-MO, CO-MO, and Ni:Mo catalysts.
Permselectlve composltlons comprlslng a sub96104005 strate, a zeollte or zeollte llke coating, and a selectlvlty-enhancIng coating, and separatlon and catalytic processes uslng the composltlon Deckman, H. W. et al., (Assigned to) Eaxou Research & Engineering Co., PCT Int. WO.96,01,686, Jan. 1996. The compositions, suitable for catalytic and separation processes, comprise a substrate. a zeolite or zeoitelike laver. a selectivitv-enhancine coating in contact wiih the zeolite layer and,‘opiionally, a pkrmeable &ermedTate layer in contact with the substrate, such that the zeolite layer is either in contact with the substrate or with the optional intermediate layer.
Cooke, W. S. et al., Energy Fuels, 1996, 10, (3), 591-596. The paper examines the catalytic effects of several molybdenum-, cobalt-, and iron-containing compounds in the reactions of dibenzothiophene with hydrogen under conditions related to coal liquefaction. 96104811
Reactlons of montan wax fractlons as models of brown coal llquefactlon Bonaers. F. D. et al.. Fuel. Aue. 1996. 75, (101. 1161-1166. Solv&t-defined montan wax’(i.e.-montan wax‘frdm which the resins and asphalts have been removed) was separated into two fractions consisting mainly of esters and acids plus alcohols. The solvent-refined montan wax and the fractions were reacted under coal liauefaction conditions with H,. CO-H,0 or N, at 320 and 405°C. The effectsbf catalysts were also studied; as well as possible catalytic effects of stainless steel walls of the reactor. 96104812 Recent pro resses and unresolved coal water slurry techno eogy
Perspective acln DrObe technloue
In research of coal llqulds by uslng
$iloshenko, T. P. er’ai, Coal Sci. Technol., 1995, 24, (2), 1463-1466. Discusses the use of copper porphyrin-based ESR spin probles for coal structural analvsis based on structural analvsis of water-soluble coal extractions, with theassumption that the parent coal structure is largely preserved in the extraction. 96104807
Physlcochemlcal characterlzatlon of emulsion fuel from fuel all-water-charcoal and surfactants Al-Amrousi. F. A. et al.. Fuel. Aue. 1996. 75. (101. 1193-1198. The paper d&Is with the ‘formaion oyf emulsion’f;el;‘and their evaluation as boiler fuels. The results of this evaluation show that the emulsion fuels are compatible with the corresponding fuel oil. The prepared emulsion fuels were fuel oil-water emulsions with calorific values of 33.9-42.3 MJkg-’ and fuel oil-water-charcoal emulsions with calorific values of 30.637.8 MJkg.‘. These emulsion fuels have relatively low sulphur and wax contents, undergo the water gas shift reaction during combustion and make use of solid charcoal. The results also show that the presence of surfactants in the emulsion fuels acts as an inhibitor of the c&rosion activity of the water and fuel oil.
Propertles of North Bohemlan coals and thelr con96/04808 verslon In coprocesslng of coal/oil mlxtures Cerny, J. ef al., Pet Coal, 1995, 37, (I), 40-42. Presents a study of coal liquefaction in the presence residue (West Siberian). The effect of retrogressive cess is discussed.
Quantltatlve degradatlon 96/04809 fuel using statlstlcal analysls
of petroleum vacuum reactions on the pro-
problems on
Sun, C. and Li, B. Meilan Zhuanhua, 1995, 18, (3). 1-6. (In Chinese) Discusses the recent progress and unsolved probiem;of coil water sluiry (CWS) technology, Including CWS static and dynamic stabilities, the establishment of corresponding standardized analysis methods, the adaptability of different types of additives for various coals and the development of new additives having high viscosity-reducing ability.
Remarkable oil yield from an lndoneslan subbl96104613 tumlnuous coal In llquefactlon uslng NlMo supported on a carbon black under rapld stlrrlng Sakanishi. K. et al.. Enerw Fuels. 1996. 10. (1). 260-261. Catalytic iiquefactioi of anindonesian subbit;r%ous coal, Tanitoharum coal, were performed in a magnetically stirred autoclave of 50 mL capacity using a NiMo catalyst supported on a particular carbon black of hollow sphere (Ketjen Black:KB) and tetralin as a solvent. The higher stirring speed of 1300 rpm at 450 Ae, 90 min, and 13 MPa gave a higher oil yield above 70% based on daf coal due to the better dispersion of the NiMosupported KB catalyst of fine particles. 96104814 Rheologlcal water-coal suspenslons
and thermophyslcal
propetiles
of
Popov, V. 1. er al., Teploenergetika (Moscow), 1995, (8), 39-43. (In Russian) The viscosity characteristics of concentrated aqueous coal slurries are measured as functions of shear stress and temperature. Also, the thermal condition, heat capacity, and density of these slurries are measured for various coal concentrations. 96104815
96/04806
wlth hydrogen In Iron, and cobalt
of coal dlstll-
Khim. Tverd. Topl. (Moscow), 1995, (5),
96104802
Liquid fuels (derived liquid fuels)
Rheology of Colomblan Effect of particle-size dlstrlbutlon
coal-water
slurry fuels.
Pulido, J. I% et al., Coal Sci. Technol., 1995, 24, (2), 1585-1588. Discusses the effect of article size distribution on the rheology monomodal and bimodal E olombian coal-water slurries.
96104616 Role of addltlves In dlarylalkane model reactlon of coal llquefactlon
degradatlon
of
as a
Wei, X. Y. er al., Coal Sci. Technol., 1995, 24, (2), 1415-1418.
Solvent effects of fractions from coal llauld on the 96104617 ’ upgradlng reactlon of coal llquefactlon residue Mashimo, K. et al., Coal Sci. Technol., 1995, 24, (2). 1475-1478 Describes how a coal liquefaction residue, obtained &‘a CH,Cl,-insoluble fraction from primary hydrogenolysis of Muswellbrook coal in Tetralin at 400” and 3.9 MPa HZ, was separated into basic, neutral oil, and acidic fractions by ion-exchange chromatography and subjected to secondary hydrogenolysis at 420’ and 5.9 MPa HZ in decalin and red mud catalyst. Stron promotlng effect of H, on coal llquefactlon 96104818 using water-solub Pe and oll-soluble MO catalyst precursors et al., Coal Sci. Technof., 1995, 24, (Z), i39i-1394. Song;C. For coal liquefaction using dispersed MO sulphide catalyst from either water-soluble or oil-soluble precursors, the addition of water can dramatitally improve coal conversion at temperatures that are much lower than those used in conventional processes. Some important factors affecting water-promoted cataytic conversion include H,O-coal ratio, coal rank, and temperature.
studles of coal derlved jet
Sanghani, P. C. and Boehman, A. L. Prepr.-Am. Chem. Sot., Div. Per. Chem., 1996, 41, (2), 529-533. Presents a study of the deposition process for a coal-derived jet fuel, using statistical methods and quantitative chemical analysis to correlated deposition kinetics.
96104819 Structural characterlstlcs of coal surface and coal slurryablllty Sun, C. G. et al., Coal Sci. Technol., 1995, 24, (2), 1589-1592. The maximum loading of aqueous coal slurries and their rheology depend on coal rank. For low-rank coals, their slurry have a low coal loading and exhibit a shear thinning behaviour.
Fuel and Energy
Abstracts
September
1996
341
Method for regeneration of coal-water slurry 96lQ46QQ Suzuki, Y. et al., (Assigned to) Jgc Corp.; Nippon Kogyo Senjo KK, JAP. Par. JP.O7,286,287, Oct. 1985. The method is carried out by withdrawing precipitates from the slurry, and then adding water and additives into the resulting slurry followed by pulverizing and mixing. Modeling of the phase equlllbrlum 96104001 late8 from coal hydrogenation Kudryavtseva, T. A. 60-66. (In Russian)
er al.,
Molybdenum hexacarbonyl for solvent-free direct coal llquefactlon
as a catalyst precursor
Warzinski, R. P. and Bockrath, B. C. Energy Fuels, 1996, 10, (3), 612-622. Discusses the use of molybdenum hexacarbonyl in solvent-free experiments. The activity of the catalysts formed from Mo(CO),, both for Ii uefaction and a Blind Canyon bituminous coal and for methanation of C 8, In the absence of coal, was a function of activation conditions and reaction parameters. 96/04803
Natural gas to syncrude:
Maklng the process pay
Off
Puskas, I. Chemtech, 1995, 25, (12), 43-49. Discusses the available technology for the manufacture of synthetic crude petroleum and liquid hydrocarbon feedstocks from natural gas. Topics include the manufacture -of synthesis gas, manufacture of ammonia, manufac[ure of MeOH, the Fischer-Tropsch synthesis, the MeOH-to-gasoline process, economic fundamentals, and opportunities for research and development.
96104604
coprocesslng
Performance of of a demlnerallzed
96/04610 Reactlons of dlbenzothlophene presence of selected molybdenum, compounds
the
dlfferent catalysts Catalan llgnlte
on
the
Beneoa. C. et al.. Enerw Fuels. 1996. 10. (31. 679-683. The-w&k studies’ copro&sing df a lignitd @krueda, Catalonia, Spain) with a petroleum vacuum residue in the presence of Fe, Fe-MO, CO-MO, and Ni:Mo catalysts.
Permselectlve composltlons comprlslng a sub96104005 strate, a zeollte or zeollte llke coating, and a selectlvlty-enhancIng coating, and separatlon and catalytic processes uslng the composltlon Deckman, H. W. et al., (Assigned to) Eaxou Research & Engineering Co., PCT Int. WO.96,01,686, Jan. 1996. The compositions, suitable for catalytic and separation processes, comprise a substrate. a zeolite or zeoitelike laver. a selectivitv-enhancine coating in contact wiih the zeolite layer and,‘opiionally, a pkrmeable &ermedTate layer in contact with the substrate, such that the zeolite layer is either in contact with the substrate or with the optional intermediate layer.
Cooke, W. S. et al., Energy Fuels, 1996, 10, (3), 591-596. The paper examines the catalytic effects of several molybdenum-, cobalt-, and iron-containing compounds in the reactions of dibenzothiophene with hydrogen under conditions related to coal liquefaction. 96104811
Reactlons of montan wax fractlons as models of brown coal llquefactlon Bonaers. F. D. et al.. Fuel. Aue. 1996. 75, (101. 1161-1166. Solv&t-defined montan wax’(i.e.-montan wax‘frdm which the resins and asphalts have been removed) was separated into two fractions consisting mainly of esters and acids plus alcohols. The solvent-refined montan wax and the fractions were reacted under coal liauefaction conditions with H,. CO-H,0 or N, at 320 and 405°C. The effectsbf catalysts were also studied; as well as possible catalytic effects of stainless steel walls of the reactor. 96104812 Recent pro resses and unresolved coal water slurry techno eogy
Perspective acln DrObe technloue
In research of coal llqulds by uslng
$iloshenko, T. P. er’ai, Coal Sci. Technol., 1995, 24, (2), 1463-1466. Discusses the use of copper porphyrin-based ESR spin probles for coal structural analvsis based on structural analvsis of water-soluble coal extractions, with theassumption that the parent coal structure is largely preserved in the extraction. 96104807
Physlcochemlcal characterlzatlon of emulsion fuel from fuel all-water-charcoal and surfactants Al-Amrousi. F. A. et al.. Fuel. Aue. 1996. 75. (101. 1193-1198. The paper d&Is with the ‘formaion oyf emulsion’f;el;‘and their evaluation as boiler fuels. The results of this evaluation show that the emulsion fuels are compatible with the corresponding fuel oil. The prepared emulsion fuels were fuel oil-water emulsions with calorific values of 33.9-42.3 MJkg-’ and fuel oil-water-charcoal emulsions with calorific values of 30.637.8 MJkg.‘. These emulsion fuels have relatively low sulphur and wax contents, undergo the water gas shift reaction during combustion and make use of solid charcoal. The results also show that the presence of surfactants in the emulsion fuels acts as an inhibitor of the c&rosion activity of the water and fuel oil.
Propertles of North Bohemlan coals and thelr con96/04808 verslon In coprocesslng of coal/oil mlxtures Cerny, J. ef al., Pet Coal, 1995, 37, (I), 40-42. Presents a study of coal liquefaction in the presence residue (West Siberian). The effect of retrogressive cess is discussed.
Quantltatlve degradatlon 96/04809 fuel using statlstlcal analysls
of petroleum vacuum reactions on the pro-
problems on
Sun, C. and Li, B. Meilan Zhuanhua, 1995, 18, (3). 1-6. (In Chinese) Discusses the recent progress and unsolved probiem;of coil water sluiry (CWS) technology, Including CWS static and dynamic stabilities, the establishment of corresponding standardized analysis methods, the adaptability of different types of additives for various coals and the development of new additives having high viscosity-reducing ability.
Remarkable oil yield from an lndoneslan subbl96104613 tumlnuous coal In llquefactlon uslng NlMo supported on a carbon black under rapld stlrrlng Sakanishi. K. et al.. Enerw Fuels. 1996. 10. (1). 260-261. Catalytic iiquefactioi of anindonesian subbit;r%ous coal, Tanitoharum coal, were performed in a magnetically stirred autoclave of 50 mL capacity using a NiMo catalyst supported on a particular carbon black of hollow sphere (Ketjen Black:KB) and tetralin as a solvent. The higher stirring speed of 1300 rpm at 450 Ae, 90 min, and 13 MPa gave a higher oil yield above 70% based on daf coal due to the better dispersion of the NiMosupported KB catalyst of fine particles. 96104814 Rheologlcal water-coal suspenslons
and thermophyslcal
propetiles
of
Popov, V. 1. er al., Teploenergetika (Moscow), 1995, (8), 39-43. (In Russian) The viscosity characteristics of concentrated aqueous coal slurries are measured as functions of shear stress and temperature. Also, the thermal condition, heat capacity, and density of these slurries are measured for various coal concentrations. 96104815
96/04806
wlth hydrogen In Iron, and cobalt
of coal dlstll-
Khim. Tverd. Topl. (Moscow), 1995, (5),
96104802
Liquid fuels (derived liquid fuels)
Rheology of Colomblan Effect of particle-size dlstrlbutlon
coal-water
slurry fuels.
Pulido, J. I% et al., Coal Sci. Technol., 1995, 24, (2), 1585-1588. Discusses the effect of article size distribution on the rheology monomodal and bimodal E olombian coal-water slurries.
96104616 Role of addltlves In dlarylalkane model reactlon of coal llquefactlon
degradatlon
of
as a
Wei, X. Y. er al., Coal Sci. Technol., 1995, 24, (2), 1415-1418.
Solvent effects of fractions from coal llauld on the 96104617 ’ upgradlng reactlon of coal llquefactlon residue Mashimo, K. et al., Coal Sci. Technol., 1995, 24, (2). 1475-1478 Describes how a coal liquefaction residue, obtained &‘a CH,Cl,-insoluble fraction from primary hydrogenolysis of Muswellbrook coal in Tetralin at 400” and 3.9 MPa HZ, was separated into basic, neutral oil, and acidic fractions by ion-exchange chromatography and subjected to secondary hydrogenolysis at 420’ and 5.9 MPa HZ in decalin and red mud catalyst. Stron promotlng effect of H, on coal llquefactlon 96104818 using water-solub Pe and oll-soluble MO catalyst precursors et al., Coal Sci. Technof., 1995, 24, (Z), i39i-1394. Song;C. For coal liquefaction using dispersed MO sulphide catalyst from either water-soluble or oil-soluble precursors, the addition of water can dramatitally improve coal conversion at temperatures that are much lower than those used in conventional processes. Some important factors affecting water-promoted cataytic conversion include H,O-coal ratio, coal rank, and temperature.
studles of coal derlved jet
Sanghani, P. C. and Boehman, A. L. Prepr.-Am. Chem. Sot., Div. Per. Chem., 1996, 41, (2), 529-533. Presents a study of the deposition process for a coal-derived jet fuel, using statistical methods and quantitative chemical analysis to correlated deposition kinetics.
96104819 Structural characterlstlcs of coal surface and coal slurryablllty Sun, C. G. et al., Coal Sci. Technol., 1995, 24, (2), 1589-1592. The maximum loading of aqueous coal slurries and their rheology depend on coal rank. For low-rank coals, their slurry have a low coal loading and exhibit a shear thinning behaviour.
Fuel and Energy
Abstracts
September
1996
341