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Colour that stings I recently made nettle wine using an old recipe. Nettles (genus Urtica) are green, yet when they were boiled, as the recipe suggested, the resulting liquid was red. Why? Was this a property of the plants or of the aluminium pan, or some residue in the apparently clean pan? Nothing else, such as wine-making yeast, had been added at that stage.
anthocyanin pigments from the stem and flowers, to diffuse out into the water. Anthocyanins are natural pH indicators, like litmus. In acidic solutions they turn pink or orange, and in alkaline conditions yellow or green. One of my pupils noticed that nettles growing in full sunlight turned reddish while those in the shade were green. This is significant because anthocyanins accumulate in plants that are adapted for shaded conditions and so need a “sunscreen” in bright conditions. It is the
n Nettle wine is normally slightly greenish-yellow, so the red coloration is probably to do with the aluminium pan. Nettles contain a substance called fisetin, “Anthocyanins found in which will yield a red colour when nettles are natural pH indicators and in acidic it reacts with aluminium ions solutions they turn pink” released in the presence of acidic compounds. Paul Hudgins anthocyanins that act as the sun Jacksonville, Florida, US block. The reason for the colour n To teach my Year 9 classes difference depending on where (children aged 13 and 14) the nettles grow is that anthocyanins principles of scientific build up in vacuoles – chambers investigation, I set them the task inside cells that are also the most of answering this question. acidic part of a cell. If the nettles The question did not say what that your correspondent used recipe to follow, so we simply were from an exposed site, then made an extract of the nettle they could have been somewhat leaves using boiling water. When reddish to start with. we added this extract to solutions Peter Scott at a range of pHs, we found that Classes 9.2 and 9.4 the most acidic ones gave a pink Worth School, Sussex, UK to orange colour. It is therefore likely that the recipe involved Hot in the hay adding an acid, and indeed most I have always assumed that the recipes I have found include belief that haystacks can burst into lemon juice. flames spontaneously was a The colour change occurs because boiling allows substances convenient myth to cover for careless farm workers having a in the nettle cells, including
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crafty cigarette break while forgetting their surroundings, but a friend insists that it can happen. Surely, the only way hay can warm up significantly is if it is wet and bacteria begin to heat the stack as part of the process of biodegradation. But I’d be amazed if this could generate temperatures hotter than about 40 °C. So how else could ignition take place? (Continued)
n It was interesting to read earlier letters discussing how damp hay leads to internal heating in haystacks. As children growing up on a smallholding in west Wales, we had to build hay ricks using either small bales or loose hay. Hay was always carted and baled after the dew had evaporated from the fields, but occasionally rain, or the threat of rain, meant we had to build the ricks sooner than desirable. So occasionally there were some damp bales, and occasionally one got into a rick. If there were any worries about damp hay, the rick was tested every few days for any heating in its centre. This was done by pushing a pole between the bales or through the loose hay, and then someone would stick their arm in to take the temperature of the interior of the rick. Only once did we have cause for concern, when the interior was very hot. All hands immediately pulled the rick apart and removed what appeared to be a smoking bale. It was also damp and had inadvertently been tightly packed in. We discarded the offending
bale, allowed the others to cool, and rebuilt the rick more loosely. I recall that another mishap involving fire and hay occurred in an outlying field by a railway line. The hay had been formed into a continuous row to make baling easier, when a spark from a steam train set it alight. Fortunately it was spotted, the burning hay was isolated and neighbouring householders brought water to damp it down, so only a small amount was lost. Mary Sinclair Narberth, Pembrokeshire, UK n An earlier reply stated that insurance companies in the 18th century were willing to cover farmers’ haystacks, implying that the insurers clearly believed hay could catch fire spontaneously. Actually, it doesn’t imply spontaneous combustion of hay is possible or that insurers believed it to be. Instead, the companies may have offered this insurance in the belief that it was not at all possible for hay to catch fire like this. They would thereby attain insurancecompany nirvana: collecting a premium to cover a non-existent risk. Ian Cargill Leatherhead, Surrey, UK
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