Appendix F

APPENDIX F

T h e following tables list t h e r m o d y n a m i c data for hydrogen, oxygen, water, carbon m o n o x i d e , carbon dioxide, m e t h a n e , and n i t r o g e n for 200 t h r o u g h

1000 K. Hydrogen Thermodynamic Data

T(K) 200 220 240 260 280 298.15 300 320 340 360 380 400 420 440 460 480 500 520 540 560 580 600 620 640 660 680 700 720

~,(T)(kJ/mol) h(T)(kJ/mol) -26.66 -29.07 -31.54 -34.05 -36.61 -38.96 -39.20 -41.84 -44.51 -47.22 -49.96 -52.73 -55.53 -58.35 -61.21 -64.08 -66.99 -69.91 -72.86 -75.83 -78.82 -81.84 -84.87 -87.92 -90.99 -94.07 -97.18 -100.30

-2.77 -2.22 -1.66 -1.09 -0.52 0 0.05 0.63 1.21 1.79 2.38 2.96 3.54 4.13 4.71 5.3 5.88 6.47 7.05 7.64 8.22 8.81 9.4 9.98 10.57 11.16 11.75 12.34

d(T)(J/molK)

Cp(T)(J/molK)

119.42 122.05 124.48 126.75 128.87 130.68 130.86 132.72 134.48 136.14 13 7.72 139.22 140.64 142 143.3 144.54 145.74 146.89 147.99 149.06 150.08 151.08 152.04 152.97 153.87 154.75 155.61 156.44

27.26 27.81 28.21 28.49 28.7 28.84 28.85 28.96 29.04 29.1 29.15 29.18 29.21 29.22 29.24 29.25 29.26 29.27 29.28 29.3 29.31 29.32 29.34 29.36 29.39 29.41 29.44 29.47

420

Appendix F

T(K)

fi,(T)(kJ/mol)

h(T)(kJ/mol)

d(T)(J/mol K)

Cp(T)(J/mol K)

740 760 780 800 820 840 860 880 900 920 940 960 980 1000

-103.43 -106.59 -109.75 -112.94 -116.14 -119.35 -122.58 -125.82 -129.07 -132.34 -135.62 -138.91 -142.22 -145.54

12.93 13.52 14.11 14.7 15.29 15.89 16.48 17.08 17.68 18.27 18.87 19.47 20.08 20.68

157.24 158.03 158.8 159.55 160.28 161 161.7 162.38 163.05 163.71 164.35 164.99 165.61 166.22

29.5 29.54 29.58 29.62 29.67 2972 29.77 29.83 29.88 29.94 30 30.07 30.14 30.2

h(T)(kl/mol)

d(T)(J/mol K)

Cp(T)(J/mol K)

-2.71 -2.19 -1.66 -1.10 -0.54 0.00 0.03 0.62 1.21 1.81 2.41 3.02 3.63 4.25 4.87 5.50 6.13 6.76 7.40 8.04 8.68 9.32 9.97 10.62 11.27 11.93 12.59 13.25

194.16 196.63 198.97 201.18 203.27 205.00 205.25 207.13 208.92 210.63 212.26 213.82 215.32 216.75 218.14 219.47 220.75 221.99 223.20 224.36 225.48 226.58 227.64 228.67 229.68 230.66 231.61 232.54

25.35 26.41 27.25 27.93 28.48 28.91 28.96 29.36 29.71 30.02 30.30 30.56 30.79 31.00 31.20 31.39 31.56 31.73 31.89 32.04 32.19 32.32 32.46 32.59 32.72 32.84 32.96 33.07

Oxygen T h e r m o d y n a m i c Data

T(K) 200 220 240 260 280 298.15 300 320 340 360 380 400 420 440 460 480 500 520 540 560 580 600 620 640 660 680 700 720

~(T)(kJ/mol) -41.54 -45.45 -49.41 -53.41 -57.45 -61.12 -61.54 -65.66 -69.82 -74.02 -78.25 -82.51 -86.80 -91.12 -95.47 -99.85 -104.25 -108.68 -113.13 -117.61 -122.10 -126.62 -131.17 -135.73 -140.31 -144.92 -149.54 -154.18

Appendix F

740 760 780 800 820 840 860 880 900 920 940 960 980 1000

421

~(T)(kJ/mol)

h(T)(kl/mol)

d(T)(J/mol K)

' G(r)(l/mol K)

-158.84 -163.52 -168.21 -172.93 -177.66 -182.40 -187.16 -191.94 -196.73 -201.54 -206.36 -211.20 -216.05 -220.92

13.91 14.58 15.24 15.91 16.58 17.26 17.93 18.61 19.29 19.97 20.65 21.34 22.03 22.71

233.45 234.33 235.20 236.05 236.88 237.69 238.48 239.26 240.02 240.77 241.51 242.23 242.94 243.63

33.19 33.30 33.41 33.52 33.62 33.72 33.82 33.92 34.02 34.12 34.21 34.30 34.40 34.49

h(T)(kl/mol)

d(T)(J/mol K)

Cp(T)(l/mol K)

-287.73 -287.20 -285.83 -285.69 -284.18 -282.68 -281.17 -280.18

63.28 65.21 69.95 70.42 75.28 79.85 84.16 86.85

76.10 75.81 75.37 75.35 75.27 75.41 75.72 75.99

h(T)(kJ/mol)

d(T)(J/mol K)

Cp(T)(J/mol K)

-242.44 -241.83 -241.77 -241.09 -240.42 -239.74 -239.06 -238.38 -23 7.69 -23 7.00 -236.31 -235.61 -234.91 -234.20 -233.49 -232.77

186.73 188.84 189.04 191.21 193.26 195.20 197.04 198.79 200.47 202.07 203.61 205.10 206.53 207.92 209.26 210.56

33.53 33.59 33.60 33.69 33.81 33.95 34.10 34.26 34.44 34.62 34.81 35.01 35.22 35.43 35.65 35.87

H20(1) Thermodynamic Data

T(K) 273 280 298.15 300 320 340 360 373

~(T)(kJ/mol) -305.01 -305.46 -306.69 -306.82 -308.27 -309.82 -311.46 -312.58

H20(g) Thermodynamic Data

T(K) 280 298.15 300 320 340 360 380 400 420 440 460 480 500 520 540 560

~(T)(kJ/mol) -294.72 -298.13 -298.48 -302.28 -306.13 -310.01 -313.94 -317.89 -321.89 -325.91 -329.97 -334.06 -338.17 -342.32 -346.49 -350.69

422

Appendix F

T(K) 580 600 620 640 660 680 700 720 740 760 780 800 820 840 860 880 900 920 940 960 980 1000

~(T)(kJ/mol) -354.91 -359.16 -363.43 -367.73 -372.05 -376.39 -380.76 -385.14 -389.55 -393.97 -398.42 -402.89 -407.37 -411.88 -416.40 -420.94 -425.51 -430.08 -434.68 -439.29 -443.92 -448.57

h(T)(kJ/mol) -232.05 -231.33 -230.60 -229.87 -229.13 -228.39 -227.64 -226.89 -226.13 -225.37 -224.60 -223.83 -223.05 -222.27 -221.48 -220.69 -219.89 -219.09 -218.28 -217.47 -216.65 -215.83

g(T)(J/mol K)

Cp(T)(J/mol K)

211.82 213.05 214.25 215.41 216.54 217.65 218.74 219.80 220.83 221.85 222.85 223.83 224.78 225.73 226.65 227.56 228.46 229.34 230.21 231.07 231.91 232.74

36.09 36.32 36.55 36.78 37.02 37.26 37.50 37.75 37.99 38.24 38.49 38.74 38.99 39.24 39.49 39.74 40.0O 40.25 40.51 40.76 41.01 41.27

g(T)(J/mol K)

Cp(T)(J/mol K)

185.87 188.73 191.31 193.66 195.83 197.66 197.84 199.72 201.49 203.16 204.73 206.24 207.67 209.04 210.35 211.61 212.83 214.00 215.13 216.23

30.20 29.78 29.50 29.32 29.20 29.15 29.15 29.13 29.14 29.17 29.23 29.30 29.39 29.48 29.59 29.70 29.82 29.94 30.07 30.20

CO Thermodynamic Data

T(K) 200 220 240 260 280 298.15 300 320 340 360 380 400 420 440 460 480 500 520 540 560

~(T)(kJ/mol) -150.60 -154.34 -158.14 -161.99 -165.89 -169.46 -169.83 -173.80 -177.81 -181.86 - 185.94 -190.05 -194.19 - 198.36 -202.55 -206.77 -211.01 -215.28 -219.57 -223.89

h(T)(kJ/mol) -113.42 -112.82 -112.23 -111.64 -111.06 -110.53 -110.47 -109.89 -109.31 -108.72 - 108.14 -107.56 -106.97 - 106.38 -105.79 - 105.20 -104.60 -104.00 -103.40 -102.80

Appendix F

423

T(K)

~(T)(kJ/mol)

h(T) (kJ/mol)

d(T)(J/mol K)

Cv(T)(J/mol K)

580 600 620 640 660 680 700 720 740 760 780 800 820 840 860 880 900 920 940 960 980 1000

-228.22 -232.58 -236.95 -241.35 -245.77 -250.20 -254.65 -259.12 -263.61 -268.12 -272.64 -277.17 -281.73 -286.30 -290.88 -295.48 -300.09 -304.72 -309.3 7 -314.02 -318.69 -323.38

- 102.19 -101.59 -100.98 - 100.36 -99.75 -99.13 -98.50 -97.88 -97.25 -96.62 -95.99 -95.35 -94.71 -94.07 -93.43 -92.78 -92.13 -91.48 -90.82 -90.17 -89.51 -88.84

217.29 218.32 219.32 220.29 221.24 222.17 223.07 223.95 224.81 225.65 226.47 227.28 228.07 228.84 229.60 230.34 231.07 231.79 232.49 233.18 233.86 234.53

30.34 30.47 30.61 30.75 30.89 31.03 31.17 31.31 31.46 31.60 31.74 31.88 32.01 32.15 32.29 32.42 32.55 32.68 32.81 32.94 33.06 33.18

h(T)(kJ/mol)

d(T)(J/mol K)

Cv(T)(J/mol K)

-396.90 396.25 -395.59 -394.89 -394.18 -393.44 -392.69 -391.92 -391.13 -390.33 -389.51 -388.67 -387.83 -386.96 -386.09 -385.20 -384.31 -383.40 -382.48 -381.54

200.1 203.16 206.07 208.84 211.48 214.02 216.45 218.79 221.04 223.21 225.31 227.35 229.32 231.23 233.09 234.9 236.66 238.38 240.05 241.69

31.33 32.77 34.04 35.19 36.24 3 7.22 38.13 39 39.81 40.59 41.34 42.05 42.73 43.38 44.01 44.61 45.2 45.76 46.3 46.82

CO2 Thermodynamic Data

T(K) 200 220 240 260 280 300 320 340 360 380 400 420 440 460 480 500 520 540 560 580

~(T)(kJ/mol) -436.93 -440.95 -445.04 -449.19 -453.39 -457.65 -461.95 -466.31 -470.71 -475.15 -479.63 -484.16 -488.73 -493.33 -497.98 -502.66 -507.37 512.12 -516.91 -521.72

424

Appendix F

TiK) 600 620 640 660 680 700 720 740 760 780 800 820 840 860 880 900 920 940 960 980 1000

~(T)(kJ/mol) 526.59 -531.46 -536.3 7 -541.31 -546.28 -551.29 -556.31 -561.3 7 -566.45 -571.56 -576.71 581.86 -587.05 -592.26 -597.50 -602.76 -608.05 -613.35 -618.68 624.04 -629.41

h(T)(kJ/mol)

d(T)(l/molK)

Cp(T)(J/molK)

-380.60 -3 79.65 -3 78.69 -3 77.72 -3 76.74 -3 75.76 -3 74.76 -3 73.76 -3 72.75 -371.73 -3 70.70 -369.67 -3 68.63 -367.59 -366.54 3 65.48 -364.42 -363.35 -362.27 -361.19 -360.11

243.28 244.84 246.3 7 247.86 249.32 250.75 252.15 253.53 254.88 256.2 257.5 258.77 260.02 261.25 262.46 263.65 264.82 265.97 267.1 268.21 269.3

47.32 47.8 48.27 48.72 49.15 49.57 49.97 50.36 50.73 51.09 51.44 51.78 52.1 52.41 52.71 53 53.28 53.55 53.81 54.06 54.3

h(T)(kl/mol)

g(T)(J/mol K)

CdT)(J/mol K)

-78.25 -77.53 -76.83 -76.14 -75.44 -74.80 -74.73 -74.01 -73.27 -72.52 -71.74 -70.94 -70.12 -69.27 -68.41 -67.51 -66.60 -65.66 -64.70 -63.71 -62.70

172.23 175.63 178.67 181.45 184.03 186.25 186.48 188.80 191.04 193.20 195.31 197.35 199.36 201.32 203.25 205.15 207.01 208.86 210.67 212.47 214.24

36.30 35.19 34.74 34.77 35.12 35.65 35.71 36.47 37.36 38.35 39.40 40.50 41.64 42.80 43.98 45.16 46.35 47.54 48.73 49.90 51.07

CH4 Thermodynamic Data

T(K) 200 220 240 260 280 298.15 300 320 340 360 380 400 420 440 460 48O 500 520 540 56O 58O

~(T)(kJ/mol) -112.69 -116.17 -119.71 -123.32 -126.97 -130.33 -130.68 -134.43 -138.23 -142.07 -145.95 -149.88 -153.85 -157.86 -161.90 -165.99 -170.11 -174.27 -178.46 -182.69 -186.96

Appendix F T(K) 600 620 640 660 680 700 720 740 760 780 800 820 840 860 880 900 920 940 960 980 1000

~,(T)(kJ/mol) -191.26 - 195.60 - 199.97 -204.38 -208.82 -213.29 -217.79 -222.33 -226.90 -231.51 -236.14 -240.81 -245.50 -250.23 -254.99 -259.78 -264.60 -269.45 -274.33 -279.23 -284.17

h(T)(kJ/mol) -61.67 -60.61 -59.53 -58.43 -57.31 -56.16 -55.00 -53.81 -52.60 -51.37 -50.13 -48.86 -47.57 -46.26 -44.94 -43.60 -42.23 -40.86 -39.46 -38.05 -36.62

425

g(T)(J/mol K)

Cv(T)(J/mol K)

215.99 217.72 219.43 221.13 222.80 224.46 226.10 227.73 229.34 230.94 232.52 234.08 235.64 23 7.17 238.70 240.20 241.70 243.18 244.65 246.11 247.55

52.23 53.3 7 54.50 55.61 56.71 57.79 58.85 59.90 60.93 61.94 62.93 63.90 64.85 65.79 66.70 67.60 68.47 69.33 70.17 70.99 71.79

g(T)(J/mol K)

Cv(T)(J/mol K)

180.08 182.82 185.31 187.61 189.75 191.56 191.74 193.6 195.36 197.02 198.6 200.11 201.54 202.91 204.23 205.5 206.71 207.89 209.02 210.12 211.19

28.77 28.72 28.72 28.76 28.81 28.87 28.88 28.96 29.05 29.14 29.25 29.35 29.46 29.57 29.68 29.79 29.91 30.02 30.13 30.24 30.36

N~ Thermodynamic Data

T(K) 200 220 240 260 280 298.15 300 320 340 360 380 400 420 440 460 480 500 520 540 560 580

~(T)(kJ/mol) -38.85 -42.48 -46.16 -49.89 -53.66 -57.11 -57.48 -61.33 -65.22 -69.15 -73.10 -77.09 -81.11 -85.15 -89.22 -93.32 -97.44 -101.59 -105.76 -109.95 -114.16

h(T)(kJ/mol) -2.83 -2.26 -1.68 -1.11 -0.53 0 0.04 0.62 1.2 1.78 2.37 2.95 3.54 4.13 4.72 5.32 5.92 6.51 7.12 7.72 8.33

426

T~ 600 620 640 660 680 700 720 740 760 780 800 820 840 860 880 900 920 940 960 980 1000

Appendix F ~(T)(kJImol) -118.40 -122.65 -126.92 -131.22 -135.53 -139.86

-144.21 - 148.5 7 -152.96 -157.35 -161.77 -166.20

-170.64 -175.11 -179.58 -184.07 -188.58 -193.10 -19.63 -202.1 -206.3

h(T)(kJImol) 8.93 9.54 10.16 10.77 11.39 12.01 12.63 13.25 13.88 14.51 15.14 15.77 16.4 17.04 17.68 18.32 18.96 19.61 20.25 20.9 21.55

d(T)(J/molK)

Cv(T)(l/mol K)

212.22 213.22 214.19 215.14 216.06 216.96 217.83 218.69 219.52 220.34 221.13 221.91 222.68 223.43 224.16 224.88 225.58 226.28 226.96 227.63 228.28

30.47 30.58 30.69 30.8 30.91 31.02 31.13 31.24 31.34 31.45 31.55 31.66 31.76 31.86 31.96 32.06 32.16 32.25 32.35 32.44 32.54