Chlorofluorocarbons

3.8 Chlorofluorocarbons. Chloropentafluoroethane PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Chloropentafluoroethane

CAS #

-

76-15-3

IUPAC name

1-chloro-1,1,2,2,2-pentafluoro-ethane

Common name

flurocarbon 115

Common synonym

Freon 115

Empirical formula

-

C2ClF5

Formula

CF3CF2Cl

Molecular mass

daltons

154.47

RTECS number

-

KH7877500

Chemical category

-

chlorofluorocarbon

Mixture

-

N

EC number

-

200-938-2

PHYSICAL PROPERTIES State

-

G

Odor

-

none

Color

-

colorless

Boiling point

o

C

-39.1

Freezing point

o

C

-106.0

Refractive index at 20 C

-

1.2900

Specific gravity

g cm-3

1.291

Specific gravity temperature

o

Vapor density

air=1

5.33

Vapor pressure

kPa

797

Vapor pressure temperature

o

o

C

-42

C

25 19.41

Enthalpy of vaporization

kJ mol

Enthalpy of vaporization temperature

K

Corrosivity

-

Molar volume

cm mol

Surface tension at 20oC

mN m-1

5.00

Solubility in water at 20 C

mg kg

58

Specific heat at 25oC

kJ K-1 mol-1

184.10

Wm K

0.046

dD

13.9

dP

3.1

dH

0.5

-1

234.0 N 3

o

Thermal conductivity at 25 C o

Hansen solubility parameters, (MPa)

-1

1/2

-1

-1

-1

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312

3.8 Chlorofluorocarbons. Chloropentafluoroethane PARAMETER

UNIT

VALUE

Henry’s law constant

atm/m -mol 3

-1

8.53E+00

HEALTH & SAFETY US safety phrases, S

S36/37/38

UN number

-

UN/NA hazard class

2.2

1020

Proper shipping name

compressed liquified gas

Flash point

o

Threshold limiting value – TWA 8h, ACGIH

mg m-3

6320

Threshold limiting value – TWA 8h, ACGIH

ppm

1000

Threshold limiting value – TWA 8h, OSHA

mg m

Threshold limiting value – TWA 8h, OSHA

ppm

1000

Maximum concentration, any time, NIOSH

mg m-3

6320

Maximum concentration, any time, NIOSH

ppm

1000

Maximum concentration, any time, OSHA

mg m-3

Maximum concentration, any time, OSHA

ppm

Route of entry

Inh, Ing, Con

Skin irritation

Frostbite

Eye irritation

Frostbite

Target organs

CNS,CVS,RspSys

Carcinogenicity IARC

N

Carcinogenicity NTP

N

Carcinogenicity OSHA

N

Mutagenic properties

N

C

70

-3

6320

ECOLOGICAL PROPERTIES Theoretical oxygen demand

g g-1

0.10

Bioconcentration factor

-

1.60

Biodegradation probability

-

weeks

Global warming potential Montreal protocol

9300 -

Y

Partition coefficient

logKow

2.47

Ozone depletion potential

CFC11=1

0.6

Urban ozone formation potential

C2H4=1

0.0

Soil absorption constant

-

2.35

UV absorption

nm

<220

USE & PERFORMANCE Manufacturer

DuPont, Daikin Industries, Ltd, abcr GmbH & Co. KG

Databook of Solvents/Copyrights 2014; ChemTec Publishing

313

Dichlorotetrafluoroethane, 1,2PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Dichlorotetrafluoroethane, 1,2-

CAS #

-

IUPAC name

1,2-dichloro-1,1,2,2-tetrafluoro-ethane

Common name

FLON-114

Common synonym

cryofluorane

76-14-2

Acronym

-

CFC 114

Empirical formula

-

C2Cl2F4

Formula

FF F CC F Cl Cl

Molecular mass

daltons

170.92

RTECS number

-

KI1101000

Chemical category

-

chlorofluorocarbon

Mixture

-

N

EC number

-

200-937-7

PHYSICAL PROPERTIES State

-

G

Odor

-

ether-like

Color

-

colorless

Boiling point

o

C

4.1

Freezing point

o

C

-94.0

Refractive index at 20 C

-

o

1.2860 1.455

Specific gravity

g cm

Specific gravity temperature

o

Vapor density

air=1

5.90

Vapor pressure

kPa

268

Vapor pressure temperature

o

-3

C

25

C

25 23.30

Enthalpy of vaporization

kJ mol

Enthalpy of vaporization temperature

K

Corrosivity

-

Molar volume

cm mol

Coefficients of Antoine equation

coefficient A

4.15162

coefficient B

1031.026

-1

bp N 3

-1

coefficient C C

Temperature range of Antoine equation

o

Viscosity

mPas (cP)

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117.6

-27.911 276.6 to - 414.0 0.38 314

Dichlorotetrafluoroethane, 1,2PARAMETER

UNIT

Viscosity temperature

o

Surface tension at 20oC

mN m-1

Solubility in water at 20 C

mg kg

Specific heat at 25 C

kJ K mol

Thermal conductivity at 25oC

W m-1 K-1

Coefficient of thermal expansion

10

Hildebrand solubility parameter

(MPa)

Hansen solubility parameters, (MPa)1/2

dD

12.6

dP

1.8

o

o

VALUE

C

25

-1

-4 o

12.00 130

-1

164.01

-1

0.0586

C (K ) -1

-1

0.21 12.89

1/2

dH

0.0

Henry’s law constant

atm/m -mol

Relative permittivity

-

2.26

Flammability

0

Health

2

Reactivity

0

Flammability

0

Health

1

Reactivity

0

3

-1

2.80E+00

HEALTH & SAFETY NFPA classification

HMIS classification

UN risk phrases, R

R59

US safety phrases, S

S59

UN number

-

UN/NA hazard class

2.2

1958

DOT class

2.2

Proper shipping name

NONFLAMMABLE GAS dichlorotetrafluoroethane, R114

Threshold limiting value – TWA 8h, ACGIH

mg m-3

6990

Threshold limiting value – TWA 8h, ACGIH

ppm

1000

Threshold limiting value – TWA 8h, NIOSH

mg m-3

7000

Threshold limiting value – TWA 8h, NIOSH

ppm

1000

Threshold limiting value – TWA 8h, OSHA

mg m-3

7000

Threshold limiting value – TWA 8h, OSHA

ppm

1000

Maximum exposure concentration NIOSH-IDLH

mg m-3

350000

Maximum exposure concentration NIOSH-IDLH

ppm

15000

Animal testing, acute toxicity, Rat oral LD50

mg kg

-1

2250

Animal testing, acute toxicity, Rabbit dermal LD50

mg kg-1

5000

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315

Dichlorotetrafluoroethane, 1,2PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rat inhalation, LC50

ppm

600,000/2H

Route of entry

Inh, Con

Skin irritation

Irritation would result from a defatting action on tissue. Liquid contact could cause frostbite

Eye irritation

Liquid contact can cause severe irritation and frostbite. Mist may irritate

Inhalation

Irritating by inhalation. Prolonged exposure can cause narcotic effect or rapid suffocation

Chronic effects

May produce light-headedness and palpitations

Target organs

RspSys,CVS,CNS

Carcinogenicity IARC

N

Carcinogenicity NTP

N

Carcinogenicity OSHA

N

Mutagenic properties

N

ECOLOGICAL PROPERTIES Theoretical oxygen demand

g g-1

0.09

Bioconcentration factor

-

1.91

Biodegradation probability

-

weeks

Global warming potential Montreal protocol

9300 -

Y

Partition coefficient

logKow

2.82

Urban ozone formation potential

C2H4=1

0.00

Soil absorption constant

-

2.35

USE & PERFORMANCE Manufacturer

Air Liquid-Scott Specialty Gases, National Refrigerants, Inc.

Databook of Solvents/Copyrights 2014; ChemTec Publishing

316

Trichlorofluoromethane PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Trichlorofluoromethane

CAS #

-

IUPAC name

trichloro-fluoro-methane

Common name

fluorotrichloromethane

Common synonym

R 11

75-69-4

Acronym

-

TCFMA

Empirical formula

-

CCl3F

Formula

FCCl3

Molecular mass

daltons

137.36

RTECS number

-

PB1250000

Chemical category

-

chlorofluorocarbon

Mixture

-

N

EC number

-

200-892-3

Product contents

trichlorofluoromethane 100 wt%

PHYSICAL PROPERTIES State

-

G

Odor

-

faint sweetish

Odor threshold

ppm

5.0

Color

-

colorless

Boiling point

o

C

Freezing point

o

C

Refractive index at 20oC

-

1.3790

Specific gravity

g cm-3

1.470

Specific gravity temperature

o

Vapor density

air=1

4.80

Vapor pressure

kPa

107.06

Vapor pressure temperature

o

Evaporation rate

ether=1

Enthalpy of vaporization

kJ mol-1

26.90

Enthalpy of vaporization temperature

K

bp

Corrosivity

-

Molar volume

cm mol

Coefficients of Antoine equation

coefficient A

4.01447

coefficient B

1043.303

coefficient C

-36.602

23.6 -110.50

C

21.1

C

25 >1

N 3

-1

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317

Trichlorofluoromethane PARAMETER

UNIT

Temperature range of Antoine equation

o

VALUE

Viscosity

mPas (cP)

Viscosity temperature

o

C

243.5 to 334.3

C

20

Surface tension at 20 C

mN m

Solubility in water at 20oC

mg kg-1

Specific heat at 25 C

kJ K mol

o

o

0.443 18.00

-1

1100

-1

121.55

-1

Thermal conductivity at 25 C

Wm K

0.0879

Hildebrand solubility parameter

(MPa)1/2

15.55

dD

15.3

dP

2.0

o

Hansen solubility parameters, (MPa)

-1

1/2

-1

dH

0.0

Henry’s law constant

atm/m -mol

Relative permittivity

-

3

-1

9.70E-02 2.30

HEALTH & SAFETY NFPA classification

HMIS classification

Flammability

0

Health

2

Reactivity

0

Flammability

0

Health

1

Reactivity

0

UN risk phrases, R

R36/37/38,R59

US safety phrases, S

S26,S37/39,S59

UN number

-

UN/NA hazard class

not regulated

DOT class

not regulated

Threshold limiting value – TWA 8h, ACGIH

mg m-3

5620

Threshold limiting value – TWA 8h, ACGIH

ppm

1000

Threshold limiting value – TWA 8h, OSHA

mg m-3

5600

Threshold limiting value – TWA 8h, OSHA

ppm

1000

Maximum exposure concentration NIOSH-IDLH

mg m-3

57100

Maximum exposure concentration NIOSH-IDLH

ppm

10000

Maximum concentration, any time, ACGIH

ppm

1000

Maximum concentration, any time, NIOSH

mg m-3

5600

Maximum concentration, any time, NIOSH

ppm

1000

Maximum concentration, any time, OSHA

mg m

Maximum concentration, any time, OSHA

ppm

1017

-3

Databook of Solvents/Copyrights 2014; ChemTec Publishing

5600 1000

318

Trichlorofluoromethane PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rabbit dermal LD50

mg kg

Animal testing, acute toxicity, Rat inhalation, LC50

ppm

Route of entry

Inh, Ing, Con

Ingestion

May cause irritation of the digestive tract.

Skin irritation

Causes skin irritation. Causes redness and pain. May causes frostbite.

Eye irritation

Causes eye irritation. May causes frostbite.

Inhalation

Causes respiratory tract irritation. May cause liver abnormalities.

First aid: eyes

Flush immediately thoroughly with water for several minutes. Remove contact lenses, if present. If irritation persists, get medical attention.

First aid: skin

Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention.

First aid: inhalation

Remove to fresh air. Respiratory support. Call for prompt medical attention.

Target organs

CVS,Skin,CNS

Carcinogenicity IARC

N

Carcinogenicity NTP

N

Carcinogenicity OSHA

N

Mutagenic properties

N

-1

5000 130000/15M

ECOLOGICAL PROPERTIES Bioconcentration factor

-

1.69

Biodegradation probability

-

weeks

Hydroxyl rate constant

cm3 molecule-1 s-1

5.00E-16

Global warming potential

4600

Montreal protocol

-

Y

Partition coefficient

logKow

2.53

Ozone depletion potential

CFC11=1

1

Urban ozone formation potential

C2H4=1

0.0

Soil absorption constant

-

1.97

UV absorption

nm

<230

-

generic

USE & PERFORMANCE Manufacturer

Databook of Solvents/Copyrights 2014; ChemTec Publishing

319

Trichlorotrifluoroethane, 1,1,2PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Trichlorotrifluoroethane, 1,1,2-

CAS #

-

76-13-1

IUPAC name

1,1,2-trichloro-1,2,2-trifluoro-ethane

Common name

trichlorotrifluoroethane

Common synonym

R 113

Acronym

-

TCTFA

Empirical formula

-

C2Cl3F3

Formula

Cl

F

C C Cl

F

Cl

F

Molecular mass

daltons

187.37

RTECS number

-

KJ4000000

Chemical category

-

chlorofluorocarbon

Mixture

-

N

EC number

-

200-936-1

Product contents

1,1,2- trichlorotrifluoroethane 100%

PHYSICAL PROPERTIES State

-

L

Odor

-

faint sweetish

Odor threshold

ppm

45.0

Color

-

colorless

Boiling point

o

C

47.6

Freezing point

o

C

-35.0

Refractive index at 20 C

-

1.3550

Specific gravity

g cm-3

1.470

Specific gravity temperature

o

Vapor density

air=1

6.46

Vapor pressure

kPa

48.266

Vapor pressure temperature

o

Evaporation rate

butyl acetate=1

>1

Enthalpy of vaporization

kJ mol-1

28.4

Enthalpy of vaporization temperature

K

298.2

Corrosivity

-

N

Molar volume

cm3 mol-1

119.2

o

C

C

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21.1

25

320

Trichlorotrifluoroethane, 1,1,2PARAMETER

UNIT

VALUE

Coefficients of Antoine equation

coefficient A

4.02936

coefficient B

1112.856

coefficient C

-44.119

C

247.7 to 356.4

Temperature range of Antoine equation

o

Viscosity

mPas (cP)

Viscosity temperature

o

0.711

C

20

Surface tension at 20 C

mN m

Solubility in water at 20oC

mg kg-1

Specific heat at 25 C

kJ K mol

Thermal conductivity at 25oC

W m-1 K-1

0.0659

Hildebrand solubility parameter

(MPa)

14.83

o

o

Hansen solubility parameters, (MPa)

-1

1/2

17.75

-1

170 173.63

-1

1/2

dD

14.7

dP

1.6

dH

0.0

Henry’s law constant

atm/m -mol

Relative permittivity

-

3

-1

5.26E-01 2.41

HEALTH & SAFETY NFPA classification

HMIS classification

Flammability

0

Health

1

Reactivity

0

Flammability

0

Health

2

Reactivity

0

UN risk phrases, R

R51/53,R59

US safety phrases, S

S61

UN number

-

UN/NA hazard class

9

UN packaging group

III

3082

DOT class

9, III

ICAO/IATA class, packaging group

UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (1,1,2-TRICHLOROTRIFLUOROETHANE), 9, III

IMDG class, packaging group

UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (1,1,2-TRICHLOROTRIFLUOROETHANE), 9, III

Databook of Solvents/Copyrights 2014; ChemTec Publishing

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Trichlorotrifluoroethane, 1,1,2PARAMETER

UNIT

VALUE

Proper shipping name

environmentally hazardous substance, liquid, n.o.s. (1,1,2-trichlorotrifluoroethane)

Autoignition temperature

o

C

Flash point

o

C

Threshold limiting value – TWA 8h, ACGIH

mg m

Threshold limiting value – TWA 8h, ACGIH

ppm

1000

Threshold limiting value – TWA 8h, NIOSH

mg m-3

7600

Threshold limiting value – TWA 8h, NIOSH

ppm

1000

Threshold limiting value – TWA 8h, OSHA

mg m

Threshold limiting value – TWA 8h, OSHA

ppm

Maximum exposure concentration NIOSH-IDLH

mg m-3

35055

Maximum exposure concentration NIOSH-IDLH

ppm

2000

Maximum concentration, 15 min., ACGIH

mg m-3

9500

Maximum concentration, 15 min., ACGIH

ppm

1250

Maximum concentration, 15 min., NIOSH

mg m-3

9500

Maximum concentration, 15 min., NIOSH

ppm

1250

Maximum concentration, 15 min., OSHA

mg m

Maximum concentration, 15 min., OSHA

ppm

1250

Animal testing, acute toxicity, Rat oral LD50

mg kg-1

43000

Animal testing, acute toxicity, Rat inhalation, LC50

ppm

110000/2H

Route of entry

Inh, Ing, Con

Ingestion

May cause irritation of the digestive tract.

Skin irritation

Causes skin irritation. Causes redness and pain. May causes frostbite.

Eye irritation

Causes eye irritation. May causes frostbite.

Inhalation

Inhalation causes cardiac arrhythmia, confusion, drowsiness.

First aid: eyes

Flush immediately thoroughly with water for several minutes. Remove contact lenses, if present. If irritation persists, get medical attention.

First aid: skin

Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention.

First aid: inhalation

Remove to fresh air. Respiratory support. Call for prompt medical attention.

770 350 -3

-3

7670

7600 1000

-3

Databook of Solvents/Copyrights 2014; ChemTec Publishing

9500

322

Trichlorotrifluoroethane, 1,1,2PARAMETER

UNIT

VALUE

Target organs

Skin,Hrt,RspSys,Eye,CNS,GI

Carcinogenicity IARC

N

Carcinogenicity NTP

N

Carcinogenicity OSHA

N

Mutagenic properties

N

ECOLOGICAL PROPERTIES Theoretical oxygen demand

g g-1

0.09

Bioconcentration factor

-

2.17

Biodegradation probability

-

weeks

Global warming potential

4000

Montreal protocol

-

Y

Partition coefficient

logKow

3.16

Ozone depletion potential

CFC11=1

0.8

Urban ozone formation potential

C2H4=1

0.0

Soil absorption constant

-

2.57

UV absorption

nm

<231

-

generic

USE & PERFORMANCE Manufacturer

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