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Corrigendum to “Solvation energy of metallocenes pilot ions: Beyond the Born approximation” [Electrochim. Acta 53 (2008) 3722–3733]
Electrochimica Acta 54 (2009) 4741
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Electrochimica Acta journal homepage: www.elsevier.com/locate/electacta
Corrigendum
Corrigendum to “Solvation energy of metallocenes pilot ions: Beyond the Born approximation” [Electrochim. Acta 53 (2008) 3722–3733] Lev I. Krishtalik ∗ Russian Academy of Sciences, A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Leninskii prosp. 31, 119071 Moscow, Russian Federation
a r t i c l e
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Article history: Available online 22 April 2009
There is a mistake in Table 2: the value of ˛Fc+ − Fc for DMSO is given as equal to −2.34 eV. However, in Ref. [51], this quantity was determined as −2.16 eV. After entropic correction to ionization potential, it becomes −2.14 eV. Therefore, the point for DMSO in Fig. 3 should be shifted down by 0.2 V, and it will lie practically on the common straight line, only ∼0.01 V below it. Hence, the behavior of DMSO will not differ substantially from that of other aprotic solvents. The corrected estimate of the surface potential of DMSO is −0.17 V. With account of the aforementioned corrections, the transfer energies of monovalent cations from water into DMSO given in Table 3 should be increased by 22.2 kJ mol−1 , the energies for anions should be decreased by the same quantity.
DOI of original article:10.1016/j.electacta.2007.10.026. ∗ Tel.: +7 095 955 4751; fax: +7 095 952 0846. E-mail address: [email protected]. 0013-4686/$ – see front matter © 2008 Elsevier Ltd. All rights reserved. doi:10.1016/j.electacta.2009.03.066
Contents lists available at ScienceDirect
Electrochimica Acta journal homepage: www.elsevier.com/locate/electacta
Corrigendum
Corrigendum to “Solvation energy of metallocenes pilot ions: Beyond the Born approximation” [Electrochim. Acta 53 (2008) 3722–3733] Lev I. Krishtalik ∗ Russian Academy of Sciences, A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Leninskii prosp. 31, 119071 Moscow, Russian Federation
a r t i c l e
i n f o
Article history: Available online 22 April 2009
There is a mistake in Table 2: the value of ˛Fc+ − Fc for DMSO is given as equal to −2.34 eV. However, in Ref. [51], this quantity was determined as −2.16 eV. After entropic correction to ionization potential, it becomes −2.14 eV. Therefore, the point for DMSO in Fig. 3 should be shifted down by 0.2 V, and it will lie practically on the common straight line, only ∼0.01 V below it. Hence, the behavior of DMSO will not differ substantially from that of other aprotic solvents. The corrected estimate of the surface potential of DMSO is −0.17 V. With account of the aforementioned corrections, the transfer energies of monovalent cations from water into DMSO given in Table 3 should be increased by 22.2 kJ mol−1 , the energies for anions should be decreased by the same quantity.
DOI of original article:10.1016/j.electacta.2007.10.026. ∗ Tel.: +7 095 955 4751; fax: +7 095 952 0846. E-mail address: [email protected]. 0013-4686/$ – see front matter © 2008 Elsevier Ltd. All rights reserved. doi:10.1016/j.electacta.2009.03.066