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Density of liquid—Inorganic compounds
Chapter 4 DENSITY OF L1aUID - INORGANIC COMPOUNDS
Carl L. Yaws and Ralph W. Pike* Lamar University, Beaumont, Texas / *Louisiana State University, Baton Rouge, Louisiana Tabulation Results
The results are given in Table 4. For the tabulation, the following equation was selected for correlation of liquid density as a function of temperature: density = A B -(1-T/C)"n where
(4)
density = saturated liquid density, g/ml A, B, C, and n = regression coefficients for chemical compound T = temperature, K
The tabulation is arranged by alphabetical order (Ag, AI, Ar, ...... , Zr ) to provide ease of use in quickly locating the data by using the chemical formula. The compound name and CAS No (Chemical Abstracts Registry Number) are next provided. Values for regression coefficients are given in the adjacent columns. The temperature range for use is given in the next columns (TMIN and TMAX). The equation should not be used for temperatures outside this range. The next column provides the code for the tabulation. The last two columns provide a representative temperature and value for liquid density at the representative temperature. In preparing the tabulation, a literature search was conducted to identify data source publications (1-31). Both experimental values for the property under consideration and parameter values for estimation of the property are included in the source publications. The publications were screened and copies of appropriate data were made. These data were then keyed into the computer to provide a database of values for compounds for which experimental data are available. The database also served as a basis to check the accuracy of the estimation methods. Upon completion of data collection, estimation of the values for the remaining compounds was performed. The compilations of CRC (1); Daubert and Danner (3); Janz et. al. (5-6); Landolt and Bornstein (7); Vargaftik (16); and Yaws (17-31) were used extensively for liquid density. Estimates of liquid density were primarily based on Schroeder correlation (12, group contribution), Le Bas method (12, group contribution), and Tyn-Calus equation (12, critical volume). For the high melting compounds, most of the data for liquid density are only available in the region of the melting point. In the absence of data, the estimates at temperature much higher than melting point should be considered rough approximations. A comparison of calculated and data values is shown in Figure 4 for a representative compound. The graph shows favorable agreement of equation and data. Example
In an engineering analysis, the liquid density is needed for nitrogen (N2) at 94.68 K. Determine the liquid density of nitrogen at this temperature. Substitution of the coefficients from the tabulation and temperature into the above equation yields: density = 0.31422*0.28610 - (1-94.681126.20)".29660 density = 0.720 glml References 1. 2. 3. 4.
CRC HANDBOOK OF CHEMISTRY AND PHYSICS, 75th - 86th eds., CRC Press, Inc., Boca Raton, FL (1994-2006). CRC HANDBOOK OF THERMOPHYSICAL AND THERMOCHEMICAL DATA, CRC Press, Boca Raton, FL (1994). Daubert, T. E. and R. P. Danner, DATA COMPII ATION OF PROPERTIES OF PURE COMPOUNDS, Parts 1, 2,3, and 4, Supplements 1 and 2, DIPPR Project, AIChE, New York, NY (1985-1994). ENCYClOPEDIA OF CHEMICAl TECHNOLOGY, 3rd and 4th eds., John Wiley and Sons, Inc., New York, NY (1978-2004).
198
5. 6.
7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31.
Janz, G. J., A. 1. Ward, and R. D. Reeves, MOLTEN SALT DATA, Electrical Conductance, Density, and Viscosity, Technical Bulletin Series, Rensselaer Polytechnic Institute, Troy, NY (1964). Janz, G. J., et. aI., PHYSICAL PROPERTIES DATA COMPILATIONS REVELANT TO ENERGY STORAGE, II Molten Salts, U. S. Dept. of Commerce, National Bureau of Standards, NSRDS-NBS 61, Part II (April, 1979) Landolt, H. and R. Bornstein, ZAHI ENWERTE LJND FLJNKIONEN ANS PHYSIK CHEMEI ASTRONOMIE LJND TECHNIK, Springer-Verlag, Heidelberg, Germany (1971-2005). I ANGE'S HANDBOOK OF CHEMISTRY, 13th, 14th, and 15th eds., McGraw-Hili, New York, NY (1985, 1992, 1999). PERRY'S CHEMICAL ENGINEERING HANDBOOK, 5th ed., McGraw-Hili, New York, NY (1973). PERRY'S CHEMICAl ENGINEERING HANDBOOK, 6th ed., McGraw-Hili, New York, NY (1984). PERRY'S CHEMICAL ENGINEERING HANDBOOK, 7th ed., McGraw-Hili, New York, NY (1997). Poling, B. E., J. M. Prausnitz, and J. P. O'Connell, THE PROPERTIES OF GASES AND L1QLJIDS, 5th ed., McGraw-Hili, New York, NY (2000). Reid, R. C., J. M. Prausnitz, and B. E. Poling, THE PROPERTIES OF GASES AND IIOIJlDS, 4th ed., McGraw-Hili, New York, NY (1987). Reid, R. C. and T. K. Sherwood, THE PROPERTIES OF GASES AND L1QLJIDS, 3rd ed., McGraw-Hili, New York, NY (1977). SAX'S DANGEROLJS PROPERTIES OF INDl JSRTIAI MATERIALS, 10th ed., Vols. 1, 2, and 3, Lewis, R. J.. Lewis, Sr., editor, John Wiley, New York, NY (2000). Vargaftik, N. B., TABI ES ON THE THERMOPHYSICAL PROPERTIES OF IIQIJlDS AND GASES, 2nd ed., English translation, Hemisphere Publishing Corporation, New York, NY (1975, 1983). Yaws, C. L. and Others, "Ammonia and Hydrazine - Phy. and Thermo. Prop. (6)", Chem. Eng., 81 (25), 178 (Nov. 25,1974). Yaws, C. L. and Others, "Major Diatomic Gases (Hydrogen, Nitrogen and Oxygen) - Phy. and Thermo. Prop. (8)", Chem. Eng., 82 (2), 99 (Jan. 20, 1975). Yaws, C. L. and Others, "N-Type Gas Phase Dopants - Physical and Thermodynamic Properties of Arsine, Phosphine and Stibine", Solid State Technology,.1l (1), 47 (1974). Yaws, C. L. and Others, "Oxides of Nitrogen (Nitrous Oxide, Nitric Oxide and Nitrogen Dioxide) - Phy. and Thermo. Prop. (3)", Chem. Eng., 81 (17), 99 (August 19,1974). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silane", Solid State Techn., 21 (1), 43 (January, 1978). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silicon Tetrachloride", Solid State Techn., 22 (No.2), 65 (February, 1979). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silicon Tetrafluoride", J.Ch.I.Ch.E., 12 (1), 33 (1981). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Trichlorosilane", J.Ch.I.Ch.E., 14, 205 (1983). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Dichlorosilane", Ind. Eng. Chem. Process Des. Dev., 23, 48 (1984). Yaws, C. L. and Others, "P-Type Gas Phase Dopants (Diborane and Pentaborane): Physical and Thermodynamic Properties", Solid State Technology,.1l (11),31 (1974). Yaws, C. L., PHYSICAl PROPERTIES, McGraw-Hili, New York, NY (1977). Yaws, C. L., CHEMICAl PROPERTIES HANDBOOK, McGraw-Hili, New York, NY (1999). h Yaws, C. L., MATHESON GAS DATA BOOK, i ed., Matheson Tri-Gas (Parisppany, NJ), McGraw-Hili, New York, NY (2001). Yaws, C. L., YAWS HANDBOOK OF THERMODYNAMIC AND PHYSICAl PROPERTIES OF CHEMICAl COMPOIINDS, electronic edition, www.knovel.com. Knovel, Norwich, NY (2003-present). Yaws, C. L., YAWS HANDBOOK OF PHYSICAL PROPERTIES FOR HYDROCARBONS AND CHEMICAl S, Gulf Publishing Company, Houston, TX (2005).
199
I •
data - - equation
1.00 0.90
~
0.80
E
0.70
OJ
,; 0.60
I
,,
'3
0"
-
:::i 0.50 o
~
0.40
Q
0.30
cQI
~.
\ •
0.20 0.10 0.00
o
20
40
60
80
100
Temperature, K
Figure 4 Liquid Density of Nitrogen
200
120
140
Table 4 Density of liquid - Inorganic Compounds density =A B - (1 10
FORMULA
13 16 35 45 49 77 82 86 88 96 127 134 146 167 200 202 203 228 230 231 234 238 245 256 267 272 283 285 361 363 394 401 404 405 406 413 416 423 454 464 481 530 534
Ag AgBr AgCI Agi AgN03 AlBr3 AlC2H6CI AlC3H9 AlC6H15 AlCI3 AlF3 AlI3 Al203 Ar As AsBr3 AsCI3 AsF3 AsF5 AsH3 Asl3 As203 Au AuCI Aul B BBr3 BCI3 BF3 B2H6 B3N3H6 B4Hl0 B5H9 B5Hll Bl0H14 Ba BaBr2 BaCI2 BaF2 Bal2 Be BeBr2
541 550 562 564 576 626 628 633 637 639 641 642 644 645 646 647 648 651 652 653 654 655 656 661 675 682 713 728 746 776 777 791 798 804 809 830 842
BeCI2 Bel2 Bi BiBr3 BiCI3 BrF3 BrF5 Br2 C C CCI20 CF20 CH4N20 CH4N2S CNBr CNCI CNF CN408 CO COS COSe CO2 CS2 C2N2 Ca CaBr2 CaCI2 CaF2 Cal2 Cd CdBr2 CdCI2 CdF2 Cdl2 CdO Ce CeCI3
AI
NAME silver silver bromide silver (i) chloride silver (i) iodide silver (i) nitrate aluminum aluminum bromide aluminum, dimethyl chloride aluminum, trimethyJ aluminum, triethyl aluminum chloride aluminum fluoride aluminum iodide aluminum oxide argon arsenic arsenic (iii) bromide arsenic trichloride arsenic trifluoride arsenic pentafluoride arsine
arsenic triiodide arsenic trioxide gold gold (i) chloride gold (i) iodide boron boron tribromide boron trichloride boron trifluoride diborane borazine tetraborane pentaborane pentaborane decaborane barium barium bromide barium chloride barium fluoride barium iodide beryllium beryllium bromide beryllium chloride beryllium iodide bismuth bismuth tribromide bismuth trichloride bromine trifluoride bromine pentafluoride bromine carbon (amphorous) graphite carbonyl chloride carbonyl fluoride urea
thiourea cyanogen bromide cyanogen chloride cyanogen fluoride tetranitromethane
carbon monoxide carbonyl sullide carbon oxyselenide carbon dioxide carbon disulfide cyanogen calcium calcium bromide calcium chloride calcium fluoride calcium iodide cadmium cadmium bromide cadmium chloride cadmium fluoride cadmium iodide cadmium oxide cerium cerium (iii) chloride
- T/C)"n
(density - 9 ml, T - K)
CAS No
A
B
C
n
TMIN
TMAX
code
T,K
7440-22-4 7785-23-1 7783-90-6 7783-96-2 7761-88-8 7429-90-5 7727-15-3 1184-58-3 75-24-1 97-93-8 7446-70-0 7784-18-1 7784-23-8 1344-28-1 7440-37-1 7440-38-3 7784-33-0 7784-34-1 7784-35-2 7784-36-3 7784-42-1 7784-45-4 1327-53-3 7440-57-5 10294-29-8 10294-31-2 7440-42-8 10294-33-4 10294-34-5 7637-07-2 19287-45-7 6569-51-3 18283-93-7 19624-22-7 18433-84-6
0.31819 1.66860 1.59790 1.86077 1.18620 0.69200 0.47444 0.28874 0.26569 0.49644 0.51076 0.92305 1.17262 1.26357 0.53120 0.62605 1.06061 0.72432 0.95308 0.87020 0.79658 1.41799 1.27968 8.35557 1.45830 1.67310 0.72680 0.91487 0.79010 0.54855
003098 0.26870 030000 0.30000 0.27101 0.27351 0.14123 0.22535 0.28683 0.48420 0.24312 0.30000 0.27373 0.30000
6410.00 2030.83 2992.10 2897.64 1411.20 9300.00 763.00 619.00 620.00 678.15 629.00 2948.13 983.00 533500 150.86 1673.15 789.01 654.00 530.21 357.73 373.00 1101.22 1189.50 4398.00 2131.20 2390.40 7934.59 581.00 451.95 260.90 289.80 521.20 466.66 568.45 547.13 791.78 357213 325483 3557.23 4726.51 2834.35 5205.00 1216.86 1238.03 1238.03 4620.00 1220.00 1178.00 649.89 470.00
0.13648 0.20000 0.28571 0.28571 0.19000 0.50000 0.28571 0.28571 0.28570 0.58311 0.31426 0.28571 0.39000 0.28571 0.29840 0.28571 0.28571 028571 028571 0.28571 0.43880 0.28571 0.28571 0.28571 0.20000 0.23000 0.28571 0.28571 0.51175 0.22102 0.28790 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.41000 0.40000 0.64000 0.35000 0.28571 0.28571
1234.00 705.15 728.15 825.15 490.00 933.25 39015 252.15 288.43 220.65 465.70 1313.15 464.15 2325.00 8378 1090.15 306.15 255.15 267.25 193.35 156.32 419.15 585.95 1337.33 740.00 830.00 2348.15 228.15 166.15 144.79 107.65 214.95 153.25 22635 230.00 372.75 1000.15 1130.15 1235.15 1641.15 984.15 1556.00 763.15
5769.00 1410.30 928.15 1025.15 98000 8370.00 459.80 619.00 620.00 678.15 629.00 1513.15 561.40 2525.00 150.86 1290.15 399.65 654.00 530.21 357.73 373.00 619.15 658.15 3958.20 1480.00 1660.00 2548.15 581.00 451.95 260.90 289.80 521.20 466.66 568.45 547.13 429.45 1200.15 2260.30 2470.30 3282.30 1968.30 2000.00 919.72 800.00 920.44 4158.00 1098.00 1060.20 649.89 470.00 584.15 4965.00 6129.00 455.00 297.00 505.85 768.60 332.90 449.00 368.51 540.00 132.92 378.80 406.58 304.19 552.00 399.90 2940.30 2030.30 2090.00 3000.00 2112.30 2061.90 1682.30 1200.00 993.15 1100.00 1200.00 1271.15 2180.30
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
1234.00 720.00 728.15 825.15 490.00 1173.15 390.15 252.15 288.43 220.65 465.70 1313.15 471.10 2325.00 83.78 1090.15 306.15 255.15 267.25 193.35 15632 419.15 585.95 1337.33 740.00 83000 2348.15 228.15 166.15 144.79 107.65 214.95 153.25 226.35 230.00 372.75 1000.15 1140.00 1240.00 1650.00 1000.00 1556.00 763.15 74000 761.15 544.54 510.00 560.00 298.15 21175 265.85 4765.00 4765.00 145.37 161.89 405.85 454.15 331.15 266.65 200.00 287.05 68.15 134.30 200.00 216.58 161.11 238.75 1115.00 1020.00 1060.00 1700.00 1060.00 594.05 850.00 841.15 793.15 658.15 1000.00 1071.15 1130.00
--7440-39-3 10553-31-8 10361-37-2 7787-32-8 13718-50-8 7440-41-7 7787-46-4 7787-47-5 7787-53-3 7440-69-9 7787-58-8 7787-60-2 7787-71-5 7789-30-2 7726-95-6 7440-44-0 7782-42-5 75-44-5 353-50-4 57-13-6 62-56-6 506-68-3 506-77-4 1495-50-7 509-14-8 630-08-0 463-58-1 1603-84-5 124-38-9 75-15-0 460-19-5 7440-70-2 7789-41-5 10043-52-4 7789-75-5 10102-68-8 7440-43-9 7789-42-6 10108-64-2 7790-79-6 7790-80-9 1306-19-0 7440-45-1 7790-86-5
201
0.15975 0.32656 0.19485 0.22962 026340 031796 1.11110 1.19460 0.95112 1.23810 1.27350 0.02893 1.28962 0.60000 1.59610 2.01611 1.61236 1.38859 1.08766 0.93371 1.18377 0.31475 0.63887 0.51316 0.46780 0.56982 0.30743 0.73999 0.37713 0.51072 0.44654 0.29818 0.44482 0.71258 0.46382 0.47589 0.36145 0.07756 093240 0.62349 0.33727 103110 3.72607 1.22460 1.20842 2.01691 1.54369 2.20048 2.13760 0.96240
028600 005595 0.27400 0.27400 0.27400 0.27400 0.35950 0.30000 030000 0.44663 0.26950 0.26499 0.30000 0.27400 0.41142 0.26189 0.27040 0.27400 027400 0.27998 0.27400 0.30000 0.30000 0.23769 0.23952 0.20500 024610 0.01109 0.30000 0.27748 0.40000 0.30000 0.28571 0.18801 0.30873 0.28317 0.33000 027309 0.40000 0.32363 0.28571 027400 0.28571 0.29527 584.15 0.32950 0.10000 6810.00 0.28571 0.27136 6810.00 0.28571 0.27119 455.00 0.27201 0.32913 297.00 0.28570 033700 705.00 0.28571 0.28700 854.00 0.28571 0.30000 545.03 0.28571 0.22974 449.00 0.23860 0.27400 368.51 0.28571 0.21788 540.00 0.20276 0.27655 132.92 0.29053 0.28943 378.80 0.27140 0.27400 406.58 0.28571 0.26160 304.19 0.29030 0.28749 552.00 0.32260 0.27400 399.90 0.28571 004927 3267.00 0.11441 0.26177 2923.63 0.25000 0.24921 3009.60 0.33000 0.11030 4570.85 0.20000 0.24542 3041.71 0.36000 0.43396 2291.00 0.28571 0.21148 2422.51 0.59000 0.30000 2019.79 0.28571 030000 3296.66 0.28571 030000 1741.29 0.28571 0.30000 2983.96 0.28571 0.31027 11993.80 028571 022504 3139.63 0.48000
678.15 761.15 544.54 491.15 503.15 281.92 211.75 265.85 4765.00 4765.00 145.37 161.89 405.85 454.15 331.15 266.65 200.00 287.05 68.15 134.30 200.00 216.58 161.11 238.75 111500 1015.15 1045.00 1691.00 1056.15 594.05 841.15 841.15 793.15 658.15 1000.00 1071.15 1090.15
density
@
9.2955 5.5620 4.8572 5.5568 3.9540 2.3250 2.3387 1.0418 0.7550 0.8836 1.2889 2.5530 32000 3.5124 1.4194 5.2861 3.2674 2.2289 2.7498 2.4539 1.7837 4.0520 3.4502 17.2817 48610 5.5770 2.1598 2.8115 1.5950 1.6818 0.5016 0.9930 0.6187 0.6906 0.7975 0.8676 3.3250 3.9820 3.1704 4.1270 4.2450 1.6900 3.1982 1.4620 3.9920 10.0639 4.6320 3.7850 2.8030 2.7800 3.2136 1.6110 16110 1.6620 1.1362 1.3350 0.8398 1.8598 1.2350 1.4381 1.6494 0.8462 1.3376 2.0710 1.1806 1.4516 0.9811 1.3679 3.1080 2.0783 2.5140 3.4370 8.0169 4.0820 3.3925 6.1380 4.4169 6.4245 6.6800 3.2080
T
Table 4 Density of Liquid - Inorganic Compounds density = A B· (1 10 846 891 892 893 894 898 899 900 905 916 968 1035 1049 1099 1124 1128 1137 1140 1144 1147 1165 1169 1173 1229 1230 1255 1302 1303 1307 1332 1369 1404 1406 1409 1412 1420 1434 1502 1505 1575 1578 1585 1592.1 1610 1637 1639 1661 1668 1669 1670 1671 1672 1675 1686 1687 1691 1694 1695 1696 1697 1698 1699 1702 1709 1712 1713 1714 1716 1718 1719 1721 1722 1723 1725 1738 1739 1740 1771 1773 1800
NAME
FORMULA CeF3 CIF CIF03 CIF3 CIF5 CI02 CI2 CI20 CI207 Co CoCI2 Cr CrC606 Cr02CI2 Cs CsBr CsCI CsF Csi CsN03 Cs2S04 Cu CuBr CuCi CuCI2 Cui 02 020 Oy Er Eu FH03S FNO F2 F20 Fe FeC505 FeCI2 FeCI3 Ga GaC3H9 GaCI3 Gal2 Gd Ge GeBr4 GeCI4 GeHCI3 GeH2Br2 GeH2CI2 GeH3Br GeH3CI GeH4 Ge2H6 Ge3H8 HBr HCN HCI HCI03S HCI04 HF HI HN03 H2 H2O H202 H2S H2SO4 H2S2 H2Se H2Te H3NO H3P02 H3P04 He He Hf Hg HgBr2 HgCI2
cerium (iii) fluoride chlorine mono1luoride perchloryl fluoride chlorine trifluoride chlorine pentafluoride chlorine dioxide chlorine
chlorine monoxide chiorine heptoxide cobalt cobalt chloride chromium chromium carbonyl chromium oxychioride cesium cesium bromide cesium chloride cesium fluoride cesium iodide cesium nitrate cesium sulfate copper cuprous bromide cuprous chloride cupric chloride copper iodide deuterium deuterium oxide dysprosium erbium europium fluorosulfonic acid nitrosyl fluoride fluorine fluorine oxide iron iron pentacarbonyi ferrous chloride ferric chloride gallium gallium, trimethyl gallium trichloride gallium (ii) iodide gadolinium germanium germanium bromide germanium chloride germane, trichloro germane, dibromo germane, dichioro germane, bromo germane, chloro germane
digermane trigermane hydrogen bromide hydrogen cyanide hydrogen chloride chlorosulfonic acid perchloric acid hydrogen fluoride hydrogen iodide nitric acid hydrogen water hydrogen peroxide hydrogen sulfide sulfuric acid hydrogen disulfide hydrogen selenide hydrogen telluride hydroxylamine hypophosphorous acid phosphoric acid helium-3 helium-4 hafnium
mercury
mercuric bromide mercuric chloride
CAS No
A
7758·88·5 7790·89·8 7616·94·6 7790·91·2 13637·63·3 10049·04·4 7782·50·5 7791·21·1 10294·48·1 7440·48·4 7646·79·9 7440·47·3 13007·92·6 14977·61·8 7440·46·2 7787·69·1 7647·17·8 13400·13·0 7789·17·5 7789·18·6 10294·54·9 7440·50·8 7787·70-4 7758·89·6 7447-39·4 7681-65-4 7782-39-0 7789·20·0 7429-91-6 7440·52·0 7440-53-1 7789-21-1 7789-25-5 7782·41·4 7783-41-7 7439-89-6
7783·06·4 7664-93·9 13465-07-1 7783-07-5 7783-09-7
1.38450 0.60386 0.63654 0.68343 0.85421 0.57694 0.56600 0.60356 0.65031 2.51864 1.05823 2.13536 0.63518 0.64832 0.28361 1.05781 0.93727 1.26025 1.07356 0.84483 0.91290 2.63621 1.48318 2.79457 1.08795 1.70575 0.06700 0.35573 2.62400 2.75200 1.57191 0.55594 0.49514 0.57014 0.55240 1.99446 0.49908 1.02146 1.02395 0.47740 0.54374 0.66952 1.20420 2.68561 1.61357 1.02768 0.64888 0.67714 1.09428 0.67735 0.92324 0.65822 0.54904 0.63111 0.75692 0.80283 0.19501 0.44651 0.59672 0.59920 0.29041 1.04638 1.37243 0.03125 0.32500 0.43776 0.34459 1.49150 0.47306 0.67480 0.93431
7803-49-8 6303-21-5 7664-38-2 14762-55-1 7440·59·7 7440-58-6 7439-97-6 7789-47-1 7487-94·7
0.42502 0.43313 1.79505 0.04141 0.06930 3.75257 5.73614 1.93930 1.71179
13463·40·6 7758-94-3 7705·08-0 7440-55-3 1445·79·0 13450-90-3
--7440·54·2 7440-56-4 13450-92-5 10038-98-9 1184-65-2 13769-36-3 15230-48·5 13569-43-2 13637-65·5 7782-65-2 13818-89-8 14691-44-2 10035-10-6 74-90·8 7647-01-0 7790-94-5 7601-90·3 7664-39-3 10034·85-2 7697-37-2 1333-74-0 7732·18-5 7722-84-1
202
B
(density - g/ml, T - K)
• T/Cl'n C
n
0.21699 4905.07 0.54000 0.27400 282.32 0.28571 0.27200 368.40 0.29870 0.27400 459.39 0.28571 0.35050 415.90 0.28571 0.26048 465.00 0.28570 0.27315 417.15 0.28830 0.27400 444.68 0.28571 0.27400 565.78 0.28571 0.25033 7398.48 0.80000 0.30000 2154.97 0.28571 0.30000 8560.93 0.28571 690.80 0.28571 0.30000 0.27400 626.33 0.28571 0.14024 2048.10 0.28571 0.24371 2562.13 0.60000 0.30000 2562.13 0.28571 0.25546 2482.33 0.50000 0.24346 2529.56 0.60000 0.23365 1978.99 0.44000 0.21152 3681.07 0.58500 0.30161 5123.00 0.28571 0.30000 2651.71 0.28571 0.64708 1800.00 0.80000 0.30000 2010.00 0.28571 0.30000 2620.77 0.28571 0.31500 38.35 0.28571 0.27421 643.89 0.21000 0.29728 8561.50 0.28571 0.29872 9714.25 0.28571 0.29797 5150.00 0.28571 0.25067 715.00 0.37039 0.27400 352.67 0.28571 0.28587 144.12 0.28776 0.27016 215.10 0.28571 0.22457 9340.00 0.70000 0.27400 607.20 0.28571 0.30000 2115.88 0.28571 0.30000 964.41 0.28571 0.07625 7620.00 0.28571 0.38646 510.00 0.28570 0.25063 694.00 0.29982 0.25246 1396.80 0.31000 0.34705 11309.81 0.28571 026102 9803.00 0.59646 027400 740.00 0.28571 0.27400 574.00 0.28571 0.27400 559.78 0.28571 0.31186 563.33 0.28571 0.27219 535.61 0.28571 0.30405 515.20 0.28571 0.27464 478.44 0.28571 0.30254 308.00 0.28571 0.27400 491.01 0.28571 0.27400 616.37 0.28571 0.28545 363.15 0.28571 0.18589 456.65 0.28206 0.27290 324.65 0.32170 0.28520 700.00 0.28571 0.26092 631.00 0.34521 0.17660 461.15 0.37330 0.28826 423.85 0.28571 0.83561 520.00 0.19330 034730 33.18 0.27560 0.27000 647.13 0.23000 0.23170 730.15 0.38000 0.27369 373.53 0.29015 0.79186 924.00 0.27130 0.27400 542.39 0.28571 0.26335 411.15 0.26250 0.27400 438.04 0.28571 0.27400 574.00 0.28571 0.23298 627.65 0.25871 0.96491 1030.00 0.15872 0.46660 3.31 0.22300 0.41860 5.20 0.24100 0.30000 21687.96 0.28571 0.40708 1735.00 0.25997 0.30000 964.41 0.28571 0.30000 939.98 0.28571
TMIN
TMAX
code
T,K
density @ T
1703.15 128.15 125.41 190.15 190.00 213.55 172.12 157.15 182.15 1768.15 1008.15 2180.15 423.65 176.65 301.65 909.15 919.15 976.00 894.15 687.15 1278.15 1357.77 777.15 703.00 906.15 878.15 18.73 277.00 1685.15 1802.15 1095.15 184.17 139.15 53.48 49.25 1811.00 252.15 945.15 577.15 302.91 257.45 350.90 485.00 1586.15 1210.40 299.25 223.65 202.05 258.15 205.15 241.15 221.15 107.26 164.15 167.55 185.15 259.83 158.97 193.15 171.95 189.79 222.38 231.55 13.95 290.00 272.74 187.68 283.46 183.45 207.45 224.15 306.15 293.15 315.51 1.01 1.76 2506.15 234.29 510.15 550.15
3406.30 282.32 368.40 459.39 415.90 465.00 417.15 444.68 565.78 6658.63 1208.15 2380.15 690.80 626.33 1843.29 1500.00 1500.00 1500.00 1500.00 1374.30 2556.30 4610.70 977.15 1620.00 1106.15 1078.15 38.35 643.89 1885.15 2002.15 1295.15 715.00 352.67 144.12 215.10 8406.00 607.20 1145.15 584.65 6858.00 510.00 694.00 970.00 1786.15 8822.70 380.70 574.00 559.78 563.33 535.61 515.20 478.44 308.00 491.01 616.37 363.15 456.65 324.65 700.00 631.00 461.15 423.85 373.15 33.18 647.13 730.15 373.53 610.00 542.39 411.15 438.04 574.00
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
1750.00 128.15 125.41 190.15 190.00 213.55 172.12 157.15 182.15 1873.15 1008.15 2180.15 423.65 176.65 301.65 909.15 919.15 1000.00 920.00 690.00 1300.00 1673.15 777.15 710.00 906.15 878.15 18.73 303.20 1685.15 1802.15 1095.15 184.17 139.15 53.48 49.25 1923.15 252.15 945.15 577.15 302.91 257.45 350.90 490.00 1586.15 1210.40 299.25 223.65 202.05 298.15 298.15 298.15 298.15 107.26 164.15 167.55 185.15 259.83 158.97 193.15 171.95 189.79 222.38 231.55 13.95 290.00 298.88 187.68 283.46 183.45 207.45 224.15
4.6150 1.7945 2.0099 2.0766 2.0607 1.7834 1.7229 1.8928 2.0716 7.5400 2.8922 6.4600 1.5903 2.1050 1.8530 3.1316 2.7065 36179 3.1523 2.8161 3.0430 7.6900 4.4131 3.7400 3.0005 4.9802 0.1730 1.1034 8.2000 8.6000 4.8700 1.9194 1.5201 1.7056 1.8618 7.1090 1.5153 2.8233 2.5892 6.0780 1.1835 2.0526 4.0140 7.4000 5.5849 3.1386 1.9973 2.1155 2.8000 1.9000 2.3400 1.7500 1.5814 1.9982 2.4693 2.2322 0.7352 1.2708 1.8733 1.9970 1.2044 2.8608 1.6110 0.0776 0.9990 1.4493 0.9928 1.8424 1.4949 2.0468 2.6830
298.15 393.15 3.31 5.20 2706.15 1561.50 800.00 800.00
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
306.15 295.65 315.51 1.01 1.76 2506.15 234.29 510.15 550.15
1.2040 1.4900 1.8566 0.0836 0.1524 12.0000 13.6299 5.1207 4.3659
Table 4 Density of Liquid - Inorganic Compounds density = A B - (1 - T/C)'n 1813 1841 1868 1869 1873 1877
Hgl2 Ho IF5 IF7 12 In
1881 1890 1891 1892 1901 1917
InBr3 InCI InCI2 InCI3 Inl3 Ir
1960 1972 2009 2018 2035 2042 2047
K KBr KCI KF KI KN03 KOH
2053
KSCN
2064
K2C03
2089
K2Cr207 K2Mo04
2112 2127 2140 2162 2168 2171 2177 2182 2203 2213
K2S04 K2W04 Kr La LaBr3 LaCI3 LaF3 Li LiBr LiCI
2253 2261
LiF
2270 2274
Lil LiN03
2283 2306 2316
Li2C03 Li2S04 Lu Mg
2335 2341
MgBr2
2392
MgCI2
2399 2424 2429 2464 2495 2548 2573
MgF2 Mgl2 MgO Mn MnCI2 Mo MoF6
2585 2607
Mo03 NCIO
2608 2613
NCI3 NF3
2619 2625 2627 2634 2645 2674 2676 2678 2684 2685 2701 2747
NH3 NH4Br NH4CI NH41 NH5S NO N02 N2 N2F4 N2H4 N2H60 N20
2748 2749 2750
N203 N204 N205
2781
Na
2800 2810
NaBr NaCN
2855
NaCI
2864
NaF Nal NaN02
2888 2893 2894 2897 2916 2960 2968
NaN03 NaOH Na2C03 Na2Mo04 Na204W
(density - g/ml, T - K)
CAS No
A
B
C
n
TMIN
TMAX
code
T,K
density @ T
mercuric iodide
7774-29-0 7440-60-0 7783-66-6 16921-96-3
0.29040 0.29781
0.33313 0.07561 0.22168
1,2 1,2 1,2 1,2 1,2 1,2
298.15 278.65 386.75 429.75
3.1900 2.8023
1.63746 0.55791 0.93300
750.00 1947.15 594.33 447.53 737.24 573.15
5.1965 8.3400
7553-56-2 7440-74-6 13465-09-3
0.32000 0.28571 0.28571 0.28571 0.33550 0.28571
540.00 1747.15
iodine indium indium (iii) bromide indium (i) chloride indium (ii) chloride indium (iii) chloride indium (iii) iodide iridium potassium potassium bromide potassium chloride potassium fluoride potassium iodide potassium nitrate potassium hydroxide potassium thiocyanate potassium carbonate potassium dichromate potassium molybdate potassium sulfate potassium tungstate krypton lanthanum lanthanum bromide lanthanum chloride lanthanum fluoride lithium lithium bromide lithium chloride lithium lIuoride lithium iodide lithium nitrate lithium carbonate lithium sulfate lutetium magnesium magnesium bromide magnesium chloride magnesium lIuoride magnesium iodide magnesium oxide manganese manganese (ii) chloride molybdenum molybdenum lIuoride molybdenum oxide nitrosyl chloride nitrogen trichloride nitrogen trilluoride ammonia ammonium bromide ammonium chloride ammonium iodide ammonium hydrogensulfide nitric oxide nitrogen dioxide nitrogen tetrafluorohydrazine hydrazine hydrazine hydrate nitrous oxide nitrogen trioxide nitrogen tetraoxide nitrogen pentoxide sodium sodium bromide sodium cyanide sodium chloride sodium fluoride sodium iodide sodium nitrite sodium nitrate sodium hydroxide sodium carbonate sodium molybdate sodium tungstate
1078.10 9067.21 594.33 447.53 819.15 6730.00
532.15
holmium iodine pentalluoride iodine heptafluoride
1.93098 2.66880 1.24299 1.05176
1,2
1.12200 0.91200 0.10000 1.24500 6.41388 0.18711 0.37889
0.27849 0.23807 002259 0.26103 0.30000 020637 0.12288
710.00 500.00
3.1100
13465-10-6 13465-11-7 10025-82-8 13510-35-5 7439-88-5 7440-09-7 7758-02-3 7447-40-7 7789-23-3 7681-11-0 7757-79-1 1310-58-3
0.11777 0.66025 0.25152 0.55890 0.18547
0.05355 0.24785 0.07215 0.24400 0.09004
FORMULA
10
NAME
0.31663 0.27400
1747.15 282.58 278.65 386.75 429.75 693.15 1386.30
1996.27 0.51000 1394.35 0.13500 484.15 968.30 1463.47 0.41000 508.15 1016.30 2465.71 0.50000 856.15 1712.30 960.30 1382.83 0.25000 480.15 15035.00 0.28571 2719.15 2919.15 2223.00 0.35970 336.35 2000.70 3520.00 0.57980 1007.00 3168.00 3470.00 0.37353 1044.00 3123.00 2891.12 0.55000 1153.15 1500.00 3610.00 0.47000 1003.00 3249.00 1757.23 0.36400 610.15 1220.30
1,2 1,2 1,2 1,2 1,2
2624.00
1,2
0.25871
679.00
873.15 892.30
1,2 1,2 1,2 1,2 1,2 1,2
510.00 860.00 490.00 2719.15 336.35 1007.00 1044.00 1160.00 1010.00 620.00 679.00
3.9760 7.0314 3.7400 3.0400 2.1300 4.1500 20.0000 0.8283 2.1254 1.5248 1.8907 23941 1.8630 1.7215
333-20-0
0.47943
0.24807
1284.91
0.34000
446.15
1,2
450.00
1.5981
584-08-7
0.56772
0.23558
3372.91
0.42500
1171.15 2342.30
1,2
1180.00
1.8924
7778-50-9
0.68190
1987.20 0.32000 0.51500
2.2730
3433.39
690.00 1380.00 1192.15 2384.30
690.00
0.70020 0.56520
0.25157 0.21870
1,2
13446-49-6
1,2
2.3340
1342.15 2684.30 1194.15 2388.30 115.78 209.35
1,2 1,2 1,2 1,2
1250.00 1350.00 1250.00
7778-80-5 7790-60-5 7439-90-9 7439-91-0 13536-79-3 10099-58-8 13709-38-1 7439-93-2 7550-35-8 7447-41-8
0.20774 0.22946 0.28840
0.93930 0.91799 1.50549 3.40000
0.23941 0.67812
0.95865 1.38000 0.11037 0.85546 0.50679 0.62331
0.23420 0.23902 0.19951 0.28026 0.26862 0.25973
3865.39 0.62000 3439.15 0.44500 209.35 029390 9511.00 0.28571 3056.11 0.10000 3260.59 0.43000 5086.51 0.41000 3503.00 0.35129 2578.42 0.41000 2695.68 0.48000 3182.65 0.52000
0.90000
0.24126 0.26143
1191.15 1061.15 1132.15 1766.15 453.69 820.15 887.15 1143.15
1391.15 2122.30 2284.30 3532.30 3152.70 1500.00 1500.00 1700.00
1,2 1,2 1,2 1,2 1,2 1,2 1,2
2370.00 0.37000 1515.31 0.24000
742.00
1447.00 1052.30
1,2 1,2
0.25150
2868.91
0.31500
1,2
0.59880 3.32517
0.24462 0.29161
3260.59 4128.66
0.36000 0.28571
0.07780 0.75300
0.03010 0.24784
2241.04 2834.35
0.28571 0.26500
1992.30 1132.15 2264.30 1936.15 2136.15 923.15 1023.15 984.15
1,2
0.58060 0.71100
0.30000 0.21707
2754.32 4424.11
0.28571 0.51000
985.15 1536.15 3072.30
1,2 1,2
0.91290 0.19187 2.09497 0.90334 3.14663 093061
0.25450 0.01440 0.30000 0.30000 0.30000 0.27400
2612.59 0.29500 907.15 1814.30 5950.00 0.28571 3105.00 5355.00 6902.82 0.28571 1519.15 1719.15 2382.98 0.28571 923.15 1123.15 9620.00 0.28571 2895.15 3095.15 498.12 0.28571 290.15 49812
1,2 1,2 1,2 1,2 1,2 1,2
1.56112 0.47092
0.30000 0.27083
2319.46 0.28571 440.65 0.24939
10025-85-1 7783-54-2
0.57737
0.27400
564.00
0.59826
0.28170
234.00
7664-41-7 12124-97-9 12125-02-9
0.23684 0.98286 0.75456 1.00871 0.49634 0.51712 0.55409 0.31422 0.54042 0.20285 0.37734 0.44927
0.25443 0.30000 0.30000 0.30000 0.30000 0.30440 0.28287 0.28610 027760 0.12073 0.29390 0.27244 0.18425
405.65 1089.82 882.00 1104.32 49910 180.15 431.15 126.20 309.35 653.15 595.60 309.57 425.00
800.00 391.15 109.50 261.90 63.15 111.65 274.69 221.45 182.30
0.31000 0.27400
431.15 515.51
0.25871 0.30000 028571 0.37200
7789-24-4 10377-51-2 7790-69-4 554-13-2 10377-48-7 7439-94-3 7439-95-4 7789-48-2 7786-30-3 7783-40-6 10377-58-9 1309-48-4 7439-96-5 7773-01-5 7439-98-7 7783-77-9 1313-27-5 2696-92-6
12027-06-4 12124-99-1 10102-43-9 10102-44-0 7727-37-9 10036-47-2 302-01-2 7803-57-8 10024-97-2 10544-73-7 10544-72-6 10102-03-1
0.53040 054780
0.38980 0.63412 0.55485
526.15 996.15
1968.30 1600.00
1,2 1,2 1,2
115.78 1191.15 1070.00 1150.00 1750.00 453.69 840.00 900.00 1150.00 750.00
3.1020 1.7680
1010.00 1150.00 1936.15
1.8260 1.9960 9.3000
923.15
1.5786
1000.00 985.15 1650.00
2.6100 1.6774 23700
920.00 3105.00 1519.15
3.0430 5.9514 6.4300
923.15 2895.15 290.15
2.5729 9.3300
1268.15 440.65
1,2 1,2
1068.15 213.55
293.00
564.00
1,2
293.00
0.29529
66.46
234.00
1,2
0.28880 0.28571 0.28571 0.28571 0.28571 0.24200 0.23882 0.29660 0.28570 0.35000 0.28571 0.28820
195.41 800.00 793.20
1,2 1,2 1,2 1,2
263.15 261.90 303.15
405.65 980.84 793.80 993.89 455.37 180.15 431.15 126.20 309.35 653.15 595.60 309.57 268.15 431.15 311.65
66.46 195.41 800.00 793.20 800.00 391.15 109.50 261.90 63.15 111.65 388.23 298.15 182.30 263.15 299.32 303.15
370.95
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
5.9600 4.9324 3.1955 4.6000 0.5124 2.5246 1.4947 1.8131
550.00
1068.15 213.55
0.28571
1.8840 3.1310 2.4493
2.5518 4.2834 1.4250 1.6500 1.8854 0.7347 2.2420 1.4094 2.3204 1.0799 1.3349 1.5214 0.8702 1.6691 0.9497 1.0300 1.2292 1.4557 1.4409 1.5156
7440-23-5
0.19819
0.19553
2573.00
2573.00
1,2
370.95
0.9276
7647-15-6
0.25853 0.17117
0.07847 0.11000
4287.00 0.53000
1020.00 2500.00
1,2
1030.00
2.3334
2900.00 0.28571
973.15
1173.15
1,2
973.15
1.2200
0.22113 0.22700
0.10591 0.08221
3400.00 0.37527
1073.90 3060.00
1,2
1073.90
1.5497
1,2
1270.00
1.9440
0.29682 0.54030
0.07909 0.24561
2.7352 1.8010
0.25010 0.09705 0.23924 0.24783 0.22453
1,2 1,2 1,2 1,2 1,2 1,2
940.00 570.00
0.57150 0.20000 0.59046 0.82950 1.01760
0.58000 1269.00 2500.00 3950.00 0.49000 933.00 2500.00 1567.15 0.34000 544.15 1088.30 1670.83 0.33000 580.15 1160.30 2820.00 0.27000 596.00 1830.00 3258.00 0.40000 1131.25 2262.50 2765.23 0.32000 960.15 1920.30 2796.48 0.27000 971.00 1942.00
580.00 600.00 1140.00
1.9050 1.7810 1.9682 2.7650 3.7920
143-33-9 7647-14-5 7681-49-4 7681-82-5 7632-00-0 7631-99-4 1310-73-2 497-19-8 7631-95-0 13472-45-2
203
5530.00
1,2
1020.00 1050.00
Table 4 Density of Liquid - Inorganic Compounds density = A B - (1 10 2974 2976 3019 3037 3057 3060 3091 3092 3105 3139 3198 3199 3200 3222 3234 3235 3238 3252 3280 3381 3382 3389 3392 3396 3397 3398 3448 3451 3461 3483 3487 3504 3514 3521 3530 3537 3545 3571 3637 3641 3650 3691 3773 3781 3786 3791 3795 3801 3803 3822 3828 3875 3880 3940 3941 3974 3991 3994 3996 3998 4001 4004 4005 4006 4007 4008 4010 4013 4023 4025 4042 4044 4047 4049 4056 4065 4071 4083 4089 4107
FORMULA Na2S04 Na2S4 Nb NbF5 Nd NdBr3 Ne Ni NiC404 NiF2 02 03 Os Os04 P P PBr3 PC3H904 PC6H1504 PCI3 PCI5 PH3 PH41 POCI3 PSBr3 PSCI3 P203 P2S5 P406 Pb PbBr2 PbC8H20 PbCI2 PbF2 Pbl2 PbO PbS Pd Pm Po Pr
PI Ra Rb RbBr RbCI RbF Rbi RbN03 Rb2S04 Re Re207 Rh Rn Ru RuF5 S SCI2 SCI20 SF4 SF6 SOBr2 SOCI2 SOF2 S02 S02CI2 S03 S2CI2 Sb SbBr3 SbCI3 SbCI5 SbH3 Sbl3 Sb203 Sc ScCI3 Se SeCS SeCI4
NAME sodium sulfate sodium tetrasulfide niobium niobium (v) fluoride neodymium neodymium tribromide
neon nickel nickel carbonyl nickel fluoride oxygen ozone osmium osmium tetroxide phosphorus (white) phosphorus (red) phosphorus tribromide phosphate, trimethyl phosphate, triethyl phosphorus (iii) chloride phosphorus pentachloride phosphine phosphonium iodide phosphorus oxychloride phosphorus thiobromide phosphorus thiochloride phosphorus trioxide phosphorus (v) sulfide phosphorous (iii) oxide lead lead bromide tetraethyl lead lead chloride lead fluoride lead iodide lead oxide lead sulfide palladium promethium polonium praseodymium platinum radium rubidium rubidium bromide rubidium chloride rubidium fluoride rubidium iodide rubidium nitrate rubidium sulfate rhenium rhenium haptoxide rhodium radon ruthenium ruthenium (v) fluoride sulfur sulfur dichloride thionyl chloride sulfur tetrafluoride sulfur hexafluoride thionyl bromide thionyl chloride thionyl fluoride sulfur dioxide sulfuryl chloride sulfur trioxide sulfur monochloride antimony antimony tribromide antimony trichloride antimony pentachloride stibine antimony triiodide antimony (iii) oxide scandium scandium chloride selenium (gray) selenosulfide, carbon selenium tetrachloride
(densitv - ami, T - K)
- T/C)'n
CAS No
A
B
C
n
TMIN
TMAX
code
T,K
density @ T
7757-82-6 12034-39-8 7440-03-1 7783-68-8 7440-00-8 13536-80-6 7440-01-9 7440-02-0 13463-39-3 10028-18-9 7782-44-7 10028-15-6 7440-04-2 20816-12-0 7723-14-0 7723-14-0 7789-60-8 512-56-1 78-40-0 7719-12-2 10026-13-8 7803-51-2 12125-09-6 10025-87-3 3931-89-3 3982-91-0 1314-24-5 1314-80-3 12440-00-5 7439-92-1 10031-22-8 78-00-2 7758-95-4 7783-46-2 10101-63-0 1317-36-8 1314-87-0 7440-05-3 7440-12-2 7440-08-6 7440-10-0 7440-06-4 7440-14-4 7440-17-7 7789-39-1 7791-11-9 13446-74-7 7790-29-6 13126-12-0 7488-54-2 7440-15-5 1314-68-7 7440-16-6 10043-92-2 7440-18-8 14521-18-7 7704-34-9 10545-99-0 7719-09-7 7783-60-0 2551-62-4 507-16-4 7719-09-7 7783-42-8 7446-09-5 7791-25-5 7446-11-9 10025-67-9 7440-36-0 7789-61-9 10025-91-9 7647-18-9 7803-52-3 7790-44-5 1309-64-4 7440-20-2 10361-84-9 7782-49-2 5951-19-9 10026-03-6
0.26141 0.19000 2.48435 1.09002 2.02652 1.26846 0.48504 2.56376 0.47753 152939 0.43600 053954 6.48474 162701 1.02120 0.96106 093428 0.50567 0.31086 0.52827 1.38262 0.30087 1.01597 0.76178 0.94173 0.56545 0.49723 0.63096 0.70154 1.73000 1.92627 0.50856 1.72887 2.79825 2.01004 318209 2.70282 3.31600 2.20800 2.76115 2.10880 6.65186 1.49145 0.34600 0.91773 0.76254 1.19655 0.97769 0.74280 0.76320 6.01402 2.10435 3.40525 1.58779 3.48198 0.90813 0.20468 0.56268 0.57200 068957 073472 0.89295 0.58606 0.60330 0.52210 0.57681 0.63035 0.56169 1.69927 1.42997 0.84488 0.78102 0.90538 1.68384 1.72636 0.90098 0.50100 0.75697 0.69071 0.76605
0.10000 0.06778 0.30000 0.30000 0.28826 0.25875 0.30670 0.25892 0.27400 0.30000 0.29060 0.29884 0.30000 0.30000 0.50058 0.80200 0.27400 0.34496 0.23183 0.25681 0.30000 0.29028 0.27400 0.35087 0.30000 0.28862 0.17857 0.30000 0.27400 0.15282 0.30000 0.25781 0.28860 0.30000 0.30000 0.30000 0.30000 0.26650 0.30571 030000 0.30930 0.26561 0.30000 0.21564 0.23888 0.23646 0.30000 0.24073 0.24581 0.21768 030000 0.30000 0.30000 0.28111 0.30000 0.30000 0.10440 0.27258 0.27016 0.27400 0.27010 0.27400 0.27659 0.27400 0.25842 0.26336 0.19013 0.27400 024231 0.30000 0.25331 0.27400 0.31372 0.30000 0.30000 029526 0.18853 0.16124 0.27400 0.27400
3700.00 3200.00 17904.10 811.32 10665.10 2750.83 44.40 6986.15 508.40 3278.75 154.58 261.00 16878.68 656.60 993.75 993.75 711.00 729.00 757.00 563.15 646.15 324.75 539.70 602.15 729.89 638.82 667.60 1291.00 714.86 5400.00 1933.47 655.00 1998.62 2550.73 1865.07 2842.26 2531.19 10669.07 10228.86 3013.08 12306.26 6983.00 4862.82
0.28571 0.80000 0.28571 0.28571 0.28571 0.27000 0.27860 0.70000 0.28571 0.28571 0.29240 0.28523 0.28571 0.28571 0.66360 0.09118 0.28571 0.39266 0.34137 0.29690 0.28571 0.36975 0.28571 0.42596 0.28571 0.25871 0.28571 0.28571 0.28571 0.28571 0.28571 0.23388 0.34000 0.28571 028571 0.28571 0.28571 0.75000 0.28571 0.28571 0.28571 0.70000 0.28571 0.37000 0.62000 0.63000 0.28571 0.61000 0.35000 0.54000 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.11400 0.26470 0.29906 0.28571 0.29210 0.28571 0.30630 0.28571 0.28950 0.29557 0.43590 0.28571 0.28571 0.28571 0.30257 0.28571 0.28571 0.28571 0.28571 0.28571 0.76500 0.28571 0.28571 0.28571
1157.00 623.00 2750.15 348.65 1294.15 955.15 24.56 1728.15 248.15 1723.15 54.35 80.15 3306.15 329.15 317.55 853.15 233.15 227.00 216.65 181.15 433.15 139.37 291.65 274.33 311.15 242.75 296.95 596.15 295.65 600.64 646.15 139.41 774.15 1128.15 675.15 1163.15 1387.15 1828.05 1315.15 527.15 1204.15 2041.55 973.15 312.46 955.15 988.15 1033.15 915.15 578.15 1323.15 3459.15 569.15 2237.15 202.15 2607.15 359.65 388.36 151.15 168.65 149.15 223.15 220.95 172.00 162.65 197.67 219.00 289.95 193.15 903.78 369.75 346.55 275.95 185.15 440.15 929.15 1814.15 1213.00 494.15 197.95 400.00
2000.00 823.00 2950.15 423.40 1494.15 1910.30 44.40 6287.54 508.40 1923.15 154.58 261.00 3506.15 366.15 894.38 894.38 711.00 729.00 681.30 563.15 504.20 324.75 539.70 602.15 379.65 371.65 667.60 1161.90 714.86 4860.00 1500.00 655.00 1500.00 1328.15 875.15 1363.15 1470.65 9602.16 1515.15 727.15 1404.15 6284.70 1173.15 1883.70 1800.00 1800.00 1233.15 1800.00 1156.30 2646.30 3659.15 602.35 2437.15 377.40 2807.15 559.65 1181.70 542.00 567.00 364.00 318.69 661.75 567.00 371.25 430.75 545.00 490.85 659.37 4563.00 458.95 714.60 662.54 440.35 640.15 1129.15 2014.15 2426.00 694.15 576.53
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
1157.00 623.00 2750.15 348.65 1294.15 960.00 24.56 1873.15 248.15 1723.15 90.15 80.15 3306.15 329.15 317.55 853.15 233.15 227.00 216.65 181.15 433.15 139.37 291.65 274.33 311.15 242.75 298.15 596.15 295.65 923.15 646.15 139.41 780.00 1128.15 675.15 1163.15 1387.15 1973.15 1315.15 527.15 1204.15 2073.15 973.15 312.46 970.00 990.00 1033.15 930.00 590.00 1350.00 3459.15 569.15 2237.15 202.15 2607.15 35965 388.36 151.15 168.65 149.15 223.15 220.95 172.00 162.65 197.67 219.00 289.95 193.15 903.78 369.75 346.55 275.95 185.15 440.15 929.15 1814.15 1213.00 494.15 19795 400.00
2.0688 1.8270 7.8300 3.0394 6.7200 4.2282 1.2470 7.5950 1.3911 4.0465 1.1351 1.6013 201000 4.3653 1.7453 1.1559 2.9674 1.2680 11439 1.7741 3.3228 0.8222 2.8651 1.7096 2.6306 1.6954 2.1300 1.7301 2.1320 10.2650 5.6264 1.8323 4.9420 7.7522 5.7953 8.9658 7.0560 10.3100 6.9000 8.6301 6.5900 18.7450 4.6150 1.4815 2.6994 2.2466 3.4247 2.8864 2.4760 2.5440 18.9000 5.4875 10.6500 4.4000 10.9000 2.6109 1.7944 1.8534 1.8571 2.0999 1.8449 2.8278 1.8518 1.8089 1.6207 1.8148 1.9409 1.8144 6.4910 4.0191 2.6800 2.3698 2.4413 4.7641 50384 2.8000 1.6700 3.9871 2.1771 2.1641
204
2093.00 2646.82 2694.06 2738.03 2568.65 1665.07 3810.67 21482.82 1035.10 12906.61 377.40 15247.14 977.44 1313.00 542.00 567.00 364.00 318.69 66175 567.00 371.25 430.75 545.00 490.85 659.37 5070.00 892.75 794.00 662.54 440.35 1097.96 2765.72 8035.08 3493.44 1766.00 576.53 743.95
600.00
Table 4 Density of Liquid - Inorganic Compounds density =A B - (1 - T/C)An FORMULA
10
NAME
4109 4110 4115 4116 4117 4123 4140 4143 4143.1 4144 4145 4146 4149 4150 4152 4153 4157 4187 4196 4238 4240 4241 4242 4243 4244 4245 4246 4247 4248 4250 4251 4252 4253 4257 4258 4259 4260 4261 4265 4274 4275 4286 4287
SeF4 SeF6 SeOCI2 SeOF2 Se02 Se2C Si SiBrCI2F SiBrF3 SiBr2CIF SiBr3CI SiBr4 SiCH3CI3 SiCH4CI2 SiC2H5CI3 SiC2H6CI2 SiC3Hl0 SiC7H8CI2 SiC8H20 SiCIC3H9 SiCIF3 SiCI2F2 SiCI3Br SiCI3F SiCI4 SiF4 SiHBr3 SiHCI3 SiHF3 SiH2Br2 SiH2CI2 SiH2F2 SiH212 SiH3Br SiH3CI SiH3F SiH31 SiH4 Si02 Si2C6H180 Si2C6H19N Si2CI6 Si2CI60
selenium tetrafluoride selenium hexafluoride selenium oxychloride selenium oxyfluoride selenium dioxide diselenide, carbon silicon silane, bromodichlorofluoro silane, bromotrifluoro silane, dibromochlorofluoro silane, tribromochloro tetrabromosilane silane, methyilrichloro silane, methyldichloro silane, ethyltrichloro silane, dimethyldichloro silane, trimethyl silane, methylphenyldichloro silane, tetraethyl chlorotrimethylsilane siiane, chlorotrifluoro silane, dichlorodifluoro silane, bromotrichloro silane, trichlorofluoro silicon tetrachloride silicon tetrafluoride silane, tribromo silane, trichloro silane, trifluora silane, dibromo silane, dichloro silane, difluoro silane, diiodo silane, monobromo silane, monochloro silane, monofluoro silane, iade silane silicon dioxide (alpha quartz) disiloxane, hexamethyl disilazane, hexamethyl disilane, hexachloro disiloxane, hexachloro
4288 4288.1 4289 4290 4291 4295 4296 4297 4300 4303 4332 4335 4422 4424 4433 4461 4464 4479 4484 4492 4517 4550 4570 4583 4588 4590 4639 4678 4703 4704 4719 4728 4731 4747 4766 4787 4836
Si2F6 Si2H5CI Si2H6 Si2H60 Si20CI3F3 Si3CI8 Si3H8 Si3H9N Si4Hl0 Sm Sn SnBr4 SnCI2 SnCI4 5nl4 Sr SrBr2 SrCI2 SrF2 Srl2 Ta Tb Tc Te TeCI4 TeF6 Ti TiCI4 TI TIBr TICI Til TIN03 Tm
disilane, hexafluoro dislanyl chloride disilane disiloxane disiloxane, trichlorotrifluoro octachlorotrisilane trisilane trisilazane tetrasilane samarium tin (white) stannic bromide stannous chloride stannic chloride stannic iodide strontium strontium bromide strontium chloride strontium fluoride strontium iodide tantalum terbium technetium tellurium tellurium tetrachloride tellurium hexafluoride titanium titanium tetrachloride thallium thallous bromide thallium chloride thallium iodide thallium (i) nitrate thulium uranium uranium fluoride vanadium
U UF6
V
(density - g/ml, T - K)
CAS No
A
B
C
n
TMIN
TMAX
code
T,K
density @ T
13465-66-2 7783·79-1 7791-23-3 7783-43-9 7446-08-4 506-80-9 7440-21-3
1.00046 0.85211 0.79805 0.92879 1.33585 0.90535 1.73001 0.66872 0.72447 0.81945 0.99013 0.91021 0.43982 0.39804 039503 0.36073 0.23858 0.37625 0.24588 0.29484 0.56426 0.55307 0.69835 054467 0.51929 0.51526 1.05904 0.50208 0.51882 0.77365 0.42619 0.44709 0.97501 0.55308 0.35290 0.36018 0.70808 0.24205 1.76380 0.27018 026371 051982 0.53229 0.54778 0.34804 0.27952 0.31264 0.54394 0.51452 0.26010 0.31120 0.26613 2.30412 0.68914 1.09276 1.15953 0.75734 1.51710 0.78222 1.10700 0.81396 1.04100 1.22310 4.78107 2.44800 3.34979 1.83626 0.93555 1.16414 1.38759 0.55691 1.79212 2.55912 1.68450
0.29360 0.27400 0.27400 0.26650 0.30000 0.27844 0.64037 0.27400 0.27400 0.27400 0.32690 0.26374 0.26111 0.28209 0.24246 0.25095 0.26428 0.25350 025676 0.24793 0.27400 0.27400 0.29974 0.27400 0.26466 0.24128 0.32450 0.27817 027400 0.28512 0.26767 0.27400 0.28278 0.26469 0.25554 0.27400 0.25939 0.28405 0.65205 0.26863 0.25980 0.27400 0.27400 0.27400 027400
608.64 368.80 706.80 635.50 961.16 665.03 5159.00 497.17 375.28 535.27 614.74 663.00 517.00 483.00 559.95 520.35 432.00 689.00 606.00 497.75 330.54 390.93 545.50 460.49 507.00 259.00 610.00 479.00 291.02 550.00 459.00 318.21 660.00 454.00 396.65 286.28 515.00 269.70 3780.00 518.70 544.00
0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.30000 0.28571 0.28571 0.28571 0.28571 0.28571 0.27788 022529 0.29509 0.28758 0.29230 0.33126 0.27087 0.29726 0.28571 0.28571 0.28571 0.28571 0.27618 0.16693 0.28571 0.27626 0.28571 0.28571 0.22750 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.39578 0.28571 0.28099 0.28570 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 028571 0.28571 0.28571 0.27000 0.28571 0.32000 0.28571 0.28571 0.28571 028000 0.34000 0.60000 0.24500 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.27260 0.28571 0.28571 0.34500 0.28571 0.25000 0.28571 0.28571 0.28571 0.28571
263.15 238.45 281.65 288.15 613.15 229.45 1685.00 160.85 202.65 173.85 252.35 278.54 195.35 182.55 167.55 197.05 137.26 229.65 190.65 215.45 131.15 133.45 211.15 152.35 204.30 186.35 199.65 144.95 141.75 202.95 151.15 150.00 272.15 179.25 155.05 150.00 216.15 88.48 1696.00 204.93 293.15 271.95 239.95 254.55 250.00 140.65 128.95 150.00 250.00 155.95 167.45 179.55 1347.15 505.08 304.15 519.95 242.95 417.65 1050.15 930.15 1147.15 1750.15 788.15 3290.15 1629.15 2430.15 722.66 497.15 235.35 1941.15 249.05 577.15 733.15 703.15 713.15 479.15 1818.15 1408.15 342.35 2183.15
608.64 368.80 706.80 635.50 736.82 665.03 4643.10 497.17 375.28 535.27 61474
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
298.15 238.45 281.65 29815 613.15 298.15 1687.00 160.85 202.65 173.85 298.15 298.15 195.35 182.55 167.55 197.05 137.26 229.65 190.65 215.45 131.15 133.45 298.15 152.35 204.30 186.35 199.65 144.95 141.75 202.95 151.15 150.00 272.15 179.25 155.05 150.00 216.15 88.48 1696.00 204.93 293.15 271.95 239.95 254.55 250.00 140.65 128.95 150.00 250.00 155.95 167.45 179.55 1347.15 505.08 304.15 520.00 242.95 417.65 1050.15 940.00 1170.00 1750.15 820.00 3290.15 1629.15 2430.15 722.66 497.15 235.35 1941.15 249.05 577.15 733.15 710.00 713.15 490.00 1818.15 1408.15 342.35 2183.15
2.7500 2.2295 2.4450 2.8000 3.2878 2.6626 2.5700 2.1285 2.0436 2.6067 2.4970 2.8000 1.4269 12410 1.4148 1.2045 0.7843 1.2491 0.8390 0.9578 1.7303 1.7450 1.8260 1.7275 1.6446 1.6272 2.8930 1.5988 1.5123 2.3245 1.4200 1.3153 2.8858 1.7494 1.1533 1.0264 2.2477 0.7094 2.5300 0.8459 0.7769 1.5816 1.6587 1.4636 1.0108 0.7783 1.0020 1.7555 1.6386 0.8386 0.9907 0.8569 7.1600 6.9860 3.3493 3.3640 2.3283 4.2668 2.3750 3.6900 27132 3.4700 4.0770 15.0000 7.6500 10.6145 5.7970 2.5692 3.1100 4.1100 1.7877 11.2913 7.1999 5.6150 6.7626 48870 9.0000 17.9070 4.4224 5.5500
------13465-76-4 7789-66-4 75-79-6 75-54-7 115-21-9 75-78-5 933-07-7 149·74-6 631-36-7 75-77-4 14049-36-6 18356-71-3 13465-74-2 14965-52-7 10026-04-7 7783-61-1 7789-57-3 10025-78-2 13465-71-9 13768-94-0 4109-96-0 13824-36-7 13760-02-6 13465-73-1 13465-78-6 13537-33-2 13598-42-0 7803-62-5 14808-60-7 107-46-0 999-97-3 13465-77-5 14986-21-1
----1590-87-0 13597-73-4
----7783-26-8
--7783-29-1 7440-19-9 7440-31-5 7789-67-5 7772-99-8 7646-78-8 7790·47·8 7440-24-6 10476·81·0 10476-85-4 7783-48-4 10476-86-5 7440-25-7 7440-27-9 7440-26-8 13494-80-9 10026-07-0 7783-80-4 7440-32-6 7550-45-0 7440-28-0 7789-40-4 7791-12-0 7790-30-9 10102-45-1 7440-30-4 7440-61-1 7783-81-5 7440-62·2
205
2.38850 1.46610 2.88674 5.57293 1.74575 1.78294
0.31790 0.27400 0.27400 0.27400 0.27400 0.27400 0.27400 0.28994 0.09454 0.27400 0.29336 0.27400 0.30000 0.30000 0.25696 0.24736 0.21117 0.26087 0.30000 0.30358 0.30000 0.30000 0.30000 0.27400 0.30000 0.26324 0.14783 0.30000 0.24725 0.30000 0.26093 0.28545 0.30000 0.27705 0.30000
66096 655.58 411.33 506.89 432.00 416.86 508.78 775.41 525.15 518.20 599.30 5082.92 740000 764.82 1459.53 619.85 1011.64 4267.20 2678.83 3303.79 5040.43 2269.87 19900.93 1113810 1740077 4840.00 1083.31 380.18 6400.00 638.00 4648.06 1778.75 2025.07 1785.26 1379.95 6283.16 13712.62 505.80 1178715
663.00 517.00 483.00 559.95 520.35 432.00 689.00 606.00 497.75 330.54 390.93 545.50 460.49 507.00 259.00 610.00 479.00 291.02 550.00 459.00 318.21 660.00 454.00 396.65 286.28 515.00 269.70 2503.00 518.70 544.00 660.96 655.58 411.33 506.89 432.00 416.86 508.78 697.87 525.15 51820 599.30 1547.15 6660.00 391.00 1200.00 619.85 617.65 1250.15 1860.30 2294.30 3500.30 1576.30 3490.15 1829.15 2630.15 922.66 581.15 380.18 2141.15 638.00 4183.25 933.15 1406.30 913.15 958.30 2018.15 1608.15 401.33 2383.15
1.2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2
Table 4 Density of liquid - Inorganic Compounds density = A B - (1 10
FORMULA
NAME
4860 VCI4 vanadium tetrachloride 4880 VOCI3 vanadium oxytrichloride 4899 W tungsten 4917 WF6 tungsten fluoride 4945 Xe xenon 4960 Y yttrium 4976 YCI3 yttrium chloride 4995 Yb ytterbium 5021 Zn zinc 5024 ZnBr2 zinc bromide 5062 ZnCI2 zinc chloride 5069 ZnF2 zinc fluoride zirconium 5113 Zr zirconium chloride 5142 ZrCI4 5150 Zrl2 zirconium diiodide code: 1 - data, 2 - estimate density - density of liquid, glml A, B, C, and n - regression coefficients of chemical compound T- temperature, K TMAX - maximum temperature, K TMIN - minimum temperature, K
(density· g ml, T - K)
- T/C)'n
CAS No
A
B
C
n
TMIN
TMAX
code
T,K
density @ T
7632-51-1 7727-18-6 7440-33-7 7783-82-6 7440-63-3 7440-65-5 10361-92·9 7440-64-4 7440-66-6 7699-45-8 7646-85-7 7783-49-5 7440-67-7 10026-11-6 15513-85-6
0.71831 0.59758 5.84023 1.28420 1.10648 1.32860 0.75510 2.12198 1.98150 1.04100 0.84382 1.61024 1.90680 1.08375 1.16310
0.33057 0.29177 0.30000 0.27400 0.28552 0.29141 0.25459 0.31165 0.27115 0.25804 0.32317 030000 0.30000 0.30000 0.24116
697.00 636.00 14756.00 468.56 289.74 9381.32 2863.15 4365.92 3170.00 1921.39 1637.05 2882.98 8802.00 983.96 2070.72
0.31162 0.31711 0.28571 0.28571 0.28967 0.28571 0.30500 0.28571 0.34000 0.27500 0.19000 0.28571 0.28571 0.28571 0.39000
247.45 193.65 3695.15 272.65 161.36 1795.15 994.15 1092.15 692.70 667.15 638.15 1145.15 2128.15 710.15 719.00
697.00 636.00 3895.15 468.56 289.74 1995.15 1988.30 1292.15 2853.00 1334.30 1200.00 1345.15 2328.15 836.75 1438.00
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
247.45 193.65 3695.15 272.65 161.36 1795.15 980.00 1092.15 812.15 670.00 720.00 1145.15 2128.15 710.15 72000
1.8864 1.7913 17.7000 3.5228 2.9783 4.2400 2.5170 62100 6.4270 3.4700 2.3210 4.5642 5.8000 2.4989 3.8770
206
Carl L. Yaws and Ralph W. Pike* Lamar University, Beaumont, Texas / *Louisiana State University, Baton Rouge, Louisiana Tabulation Results
The results are given in Table 4. For the tabulation, the following equation was selected for correlation of liquid density as a function of temperature: density = A B -(1-T/C)"n where
(4)
density = saturated liquid density, g/ml A, B, C, and n = regression coefficients for chemical compound T = temperature, K
The tabulation is arranged by alphabetical order (Ag, AI, Ar, ...... , Zr ) to provide ease of use in quickly locating the data by using the chemical formula. The compound name and CAS No (Chemical Abstracts Registry Number) are next provided. Values for regression coefficients are given in the adjacent columns. The temperature range for use is given in the next columns (TMIN and TMAX). The equation should not be used for temperatures outside this range. The next column provides the code for the tabulation. The last two columns provide a representative temperature and value for liquid density at the representative temperature. In preparing the tabulation, a literature search was conducted to identify data source publications (1-31). Both experimental values for the property under consideration and parameter values for estimation of the property are included in the source publications. The publications were screened and copies of appropriate data were made. These data were then keyed into the computer to provide a database of values for compounds for which experimental data are available. The database also served as a basis to check the accuracy of the estimation methods. Upon completion of data collection, estimation of the values for the remaining compounds was performed. The compilations of CRC (1); Daubert and Danner (3); Janz et. al. (5-6); Landolt and Bornstein (7); Vargaftik (16); and Yaws (17-31) were used extensively for liquid density. Estimates of liquid density were primarily based on Schroeder correlation (12, group contribution), Le Bas method (12, group contribution), and Tyn-Calus equation (12, critical volume). For the high melting compounds, most of the data for liquid density are only available in the region of the melting point. In the absence of data, the estimates at temperature much higher than melting point should be considered rough approximations. A comparison of calculated and data values is shown in Figure 4 for a representative compound. The graph shows favorable agreement of equation and data. Example
In an engineering analysis, the liquid density is needed for nitrogen (N2) at 94.68 K. Determine the liquid density of nitrogen at this temperature. Substitution of the coefficients from the tabulation and temperature into the above equation yields: density = 0.31422*0.28610 - (1-94.681126.20)".29660 density = 0.720 glml References 1. 2. 3. 4.
CRC HANDBOOK OF CHEMISTRY AND PHYSICS, 75th - 86th eds., CRC Press, Inc., Boca Raton, FL (1994-2006). CRC HANDBOOK OF THERMOPHYSICAL AND THERMOCHEMICAL DATA, CRC Press, Boca Raton, FL (1994). Daubert, T. E. and R. P. Danner, DATA COMPII ATION OF PROPERTIES OF PURE COMPOUNDS, Parts 1, 2,3, and 4, Supplements 1 and 2, DIPPR Project, AIChE, New York, NY (1985-1994). ENCYClOPEDIA OF CHEMICAl TECHNOLOGY, 3rd and 4th eds., John Wiley and Sons, Inc., New York, NY (1978-2004).
198
5. 6.
7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31.
Janz, G. J., A. 1. Ward, and R. D. Reeves, MOLTEN SALT DATA, Electrical Conductance, Density, and Viscosity, Technical Bulletin Series, Rensselaer Polytechnic Institute, Troy, NY (1964). Janz, G. J., et. aI., PHYSICAL PROPERTIES DATA COMPILATIONS REVELANT TO ENERGY STORAGE, II Molten Salts, U. S. Dept. of Commerce, National Bureau of Standards, NSRDS-NBS 61, Part II (April, 1979) Landolt, H. and R. Bornstein, ZAHI ENWERTE LJND FLJNKIONEN ANS PHYSIK CHEMEI ASTRONOMIE LJND TECHNIK, Springer-Verlag, Heidelberg, Germany (1971-2005). I ANGE'S HANDBOOK OF CHEMISTRY, 13th, 14th, and 15th eds., McGraw-Hili, New York, NY (1985, 1992, 1999). PERRY'S CHEMICAL ENGINEERING HANDBOOK, 5th ed., McGraw-Hili, New York, NY (1973). PERRY'S CHEMICAl ENGINEERING HANDBOOK, 6th ed., McGraw-Hili, New York, NY (1984). PERRY'S CHEMICAL ENGINEERING HANDBOOK, 7th ed., McGraw-Hili, New York, NY (1997). Poling, B. E., J. M. Prausnitz, and J. P. O'Connell, THE PROPERTIES OF GASES AND L1QLJIDS, 5th ed., McGraw-Hili, New York, NY (2000). Reid, R. C., J. M. Prausnitz, and B. E. Poling, THE PROPERTIES OF GASES AND IIOIJlDS, 4th ed., McGraw-Hili, New York, NY (1987). Reid, R. C. and T. K. Sherwood, THE PROPERTIES OF GASES AND L1QLJIDS, 3rd ed., McGraw-Hili, New York, NY (1977). SAX'S DANGEROLJS PROPERTIES OF INDl JSRTIAI MATERIALS, 10th ed., Vols. 1, 2, and 3, Lewis, R. J.. Lewis, Sr., editor, John Wiley, New York, NY (2000). Vargaftik, N. B., TABI ES ON THE THERMOPHYSICAL PROPERTIES OF IIQIJlDS AND GASES, 2nd ed., English translation, Hemisphere Publishing Corporation, New York, NY (1975, 1983). Yaws, C. L. and Others, "Ammonia and Hydrazine - Phy. and Thermo. Prop. (6)", Chem. Eng., 81 (25), 178 (Nov. 25,1974). Yaws, C. L. and Others, "Major Diatomic Gases (Hydrogen, Nitrogen and Oxygen) - Phy. and Thermo. Prop. (8)", Chem. Eng., 82 (2), 99 (Jan. 20, 1975). Yaws, C. L. and Others, "N-Type Gas Phase Dopants - Physical and Thermodynamic Properties of Arsine, Phosphine and Stibine", Solid State Technology,.1l (1), 47 (1974). Yaws, C. L. and Others, "Oxides of Nitrogen (Nitrous Oxide, Nitric Oxide and Nitrogen Dioxide) - Phy. and Thermo. Prop. (3)", Chem. Eng., 81 (17), 99 (August 19,1974). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silane", Solid State Techn., 21 (1), 43 (January, 1978). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silicon Tetrachloride", Solid State Techn., 22 (No.2), 65 (February, 1979). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silicon Tetrafluoride", J.Ch.I.Ch.E., 12 (1), 33 (1981). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Trichlorosilane", J.Ch.I.Ch.E., 14, 205 (1983). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Dichlorosilane", Ind. Eng. Chem. Process Des. Dev., 23, 48 (1984). Yaws, C. L. and Others, "P-Type Gas Phase Dopants (Diborane and Pentaborane): Physical and Thermodynamic Properties", Solid State Technology,.1l (11),31 (1974). Yaws, C. L., PHYSICAl PROPERTIES, McGraw-Hili, New York, NY (1977). Yaws, C. L., CHEMICAl PROPERTIES HANDBOOK, McGraw-Hili, New York, NY (1999). h Yaws, C. L., MATHESON GAS DATA BOOK, i ed., Matheson Tri-Gas (Parisppany, NJ), McGraw-Hili, New York, NY (2001). Yaws, C. L., YAWS HANDBOOK OF THERMODYNAMIC AND PHYSICAl PROPERTIES OF CHEMICAl COMPOIINDS, electronic edition, www.knovel.com. Knovel, Norwich, NY (2003-present). Yaws, C. L., YAWS HANDBOOK OF PHYSICAL PROPERTIES FOR HYDROCARBONS AND CHEMICAl S, Gulf Publishing Company, Houston, TX (2005).
199
I •
data - - equation
1.00 0.90
~
0.80
E
0.70
OJ
,; 0.60
I
,,
'3
0"
-
:::i 0.50 o
~
0.40
Q
0.30
cQI
~.
\ •
0.20 0.10 0.00
o
20
40
60
80
100
Temperature, K
Figure 4 Liquid Density of Nitrogen
200
120
140
Table 4 Density of liquid - Inorganic Compounds density =A B - (1 10
FORMULA
13 16 35 45 49 77 82 86 88 96 127 134 146 167 200 202 203 228 230 231 234 238 245 256 267 272 283 285 361 363 394 401 404 405 406 413 416 423 454 464 481 530 534
Ag AgBr AgCI Agi AgN03 AlBr3 AlC2H6CI AlC3H9 AlC6H15 AlCI3 AlF3 AlI3 Al203 Ar As AsBr3 AsCI3 AsF3 AsF5 AsH3 Asl3 As203 Au AuCI Aul B BBr3 BCI3 BF3 B2H6 B3N3H6 B4Hl0 B5H9 B5Hll Bl0H14 Ba BaBr2 BaCI2 BaF2 Bal2 Be BeBr2
541 550 562 564 576 626 628 633 637 639 641 642 644 645 646 647 648 651 652 653 654 655 656 661 675 682 713 728 746 776 777 791 798 804 809 830 842
BeCI2 Bel2 Bi BiBr3 BiCI3 BrF3 BrF5 Br2 C C CCI20 CF20 CH4N20 CH4N2S CNBr CNCI CNF CN408 CO COS COSe CO2 CS2 C2N2 Ca CaBr2 CaCI2 CaF2 Cal2 Cd CdBr2 CdCI2 CdF2 Cdl2 CdO Ce CeCI3
AI
NAME silver silver bromide silver (i) chloride silver (i) iodide silver (i) nitrate aluminum aluminum bromide aluminum, dimethyl chloride aluminum, trimethyJ aluminum, triethyl aluminum chloride aluminum fluoride aluminum iodide aluminum oxide argon arsenic arsenic (iii) bromide arsenic trichloride arsenic trifluoride arsenic pentafluoride arsine
arsenic triiodide arsenic trioxide gold gold (i) chloride gold (i) iodide boron boron tribromide boron trichloride boron trifluoride diborane borazine tetraborane pentaborane pentaborane decaborane barium barium bromide barium chloride barium fluoride barium iodide beryllium beryllium bromide beryllium chloride beryllium iodide bismuth bismuth tribromide bismuth trichloride bromine trifluoride bromine pentafluoride bromine carbon (amphorous) graphite carbonyl chloride carbonyl fluoride urea
thiourea cyanogen bromide cyanogen chloride cyanogen fluoride tetranitromethane
carbon monoxide carbonyl sullide carbon oxyselenide carbon dioxide carbon disulfide cyanogen calcium calcium bromide calcium chloride calcium fluoride calcium iodide cadmium cadmium bromide cadmium chloride cadmium fluoride cadmium iodide cadmium oxide cerium cerium (iii) chloride
- T/C)"n
(density - 9 ml, T - K)
CAS No
A
B
C
n
TMIN
TMAX
code
T,K
7440-22-4 7785-23-1 7783-90-6 7783-96-2 7761-88-8 7429-90-5 7727-15-3 1184-58-3 75-24-1 97-93-8 7446-70-0 7784-18-1 7784-23-8 1344-28-1 7440-37-1 7440-38-3 7784-33-0 7784-34-1 7784-35-2 7784-36-3 7784-42-1 7784-45-4 1327-53-3 7440-57-5 10294-29-8 10294-31-2 7440-42-8 10294-33-4 10294-34-5 7637-07-2 19287-45-7 6569-51-3 18283-93-7 19624-22-7 18433-84-6
0.31819 1.66860 1.59790 1.86077 1.18620 0.69200 0.47444 0.28874 0.26569 0.49644 0.51076 0.92305 1.17262 1.26357 0.53120 0.62605 1.06061 0.72432 0.95308 0.87020 0.79658 1.41799 1.27968 8.35557 1.45830 1.67310 0.72680 0.91487 0.79010 0.54855
003098 0.26870 030000 0.30000 0.27101 0.27351 0.14123 0.22535 0.28683 0.48420 0.24312 0.30000 0.27373 0.30000
6410.00 2030.83 2992.10 2897.64 1411.20 9300.00 763.00 619.00 620.00 678.15 629.00 2948.13 983.00 533500 150.86 1673.15 789.01 654.00 530.21 357.73 373.00 1101.22 1189.50 4398.00 2131.20 2390.40 7934.59 581.00 451.95 260.90 289.80 521.20 466.66 568.45 547.13 791.78 357213 325483 3557.23 4726.51 2834.35 5205.00 1216.86 1238.03 1238.03 4620.00 1220.00 1178.00 649.89 470.00
0.13648 0.20000 0.28571 0.28571 0.19000 0.50000 0.28571 0.28571 0.28570 0.58311 0.31426 0.28571 0.39000 0.28571 0.29840 0.28571 0.28571 028571 028571 0.28571 0.43880 0.28571 0.28571 0.28571 0.20000 0.23000 0.28571 0.28571 0.51175 0.22102 0.28790 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.41000 0.40000 0.64000 0.35000 0.28571 0.28571
1234.00 705.15 728.15 825.15 490.00 933.25 39015 252.15 288.43 220.65 465.70 1313.15 464.15 2325.00 8378 1090.15 306.15 255.15 267.25 193.35 156.32 419.15 585.95 1337.33 740.00 830.00 2348.15 228.15 166.15 144.79 107.65 214.95 153.25 22635 230.00 372.75 1000.15 1130.15 1235.15 1641.15 984.15 1556.00 763.15
5769.00 1410.30 928.15 1025.15 98000 8370.00 459.80 619.00 620.00 678.15 629.00 1513.15 561.40 2525.00 150.86 1290.15 399.65 654.00 530.21 357.73 373.00 619.15 658.15 3958.20 1480.00 1660.00 2548.15 581.00 451.95 260.90 289.80 521.20 466.66 568.45 547.13 429.45 1200.15 2260.30 2470.30 3282.30 1968.30 2000.00 919.72 800.00 920.44 4158.00 1098.00 1060.20 649.89 470.00 584.15 4965.00 6129.00 455.00 297.00 505.85 768.60 332.90 449.00 368.51 540.00 132.92 378.80 406.58 304.19 552.00 399.90 2940.30 2030.30 2090.00 3000.00 2112.30 2061.90 1682.30 1200.00 993.15 1100.00 1200.00 1271.15 2180.30
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
1234.00 720.00 728.15 825.15 490.00 1173.15 390.15 252.15 288.43 220.65 465.70 1313.15 471.10 2325.00 83.78 1090.15 306.15 255.15 267.25 193.35 15632 419.15 585.95 1337.33 740.00 83000 2348.15 228.15 166.15 144.79 107.65 214.95 153.25 226.35 230.00 372.75 1000.15 1140.00 1240.00 1650.00 1000.00 1556.00 763.15 74000 761.15 544.54 510.00 560.00 298.15 21175 265.85 4765.00 4765.00 145.37 161.89 405.85 454.15 331.15 266.65 200.00 287.05 68.15 134.30 200.00 216.58 161.11 238.75 1115.00 1020.00 1060.00 1700.00 1060.00 594.05 850.00 841.15 793.15 658.15 1000.00 1071.15 1130.00
--7440-39-3 10553-31-8 10361-37-2 7787-32-8 13718-50-8 7440-41-7 7787-46-4 7787-47-5 7787-53-3 7440-69-9 7787-58-8 7787-60-2 7787-71-5 7789-30-2 7726-95-6 7440-44-0 7782-42-5 75-44-5 353-50-4 57-13-6 62-56-6 506-68-3 506-77-4 1495-50-7 509-14-8 630-08-0 463-58-1 1603-84-5 124-38-9 75-15-0 460-19-5 7440-70-2 7789-41-5 10043-52-4 7789-75-5 10102-68-8 7440-43-9 7789-42-6 10108-64-2 7790-79-6 7790-80-9 1306-19-0 7440-45-1 7790-86-5
201
0.15975 0.32656 0.19485 0.22962 026340 031796 1.11110 1.19460 0.95112 1.23810 1.27350 0.02893 1.28962 0.60000 1.59610 2.01611 1.61236 1.38859 1.08766 0.93371 1.18377 0.31475 0.63887 0.51316 0.46780 0.56982 0.30743 0.73999 0.37713 0.51072 0.44654 0.29818 0.44482 0.71258 0.46382 0.47589 0.36145 0.07756 093240 0.62349 0.33727 103110 3.72607 1.22460 1.20842 2.01691 1.54369 2.20048 2.13760 0.96240
028600 005595 0.27400 0.27400 0.27400 0.27400 0.35950 0.30000 030000 0.44663 0.26950 0.26499 0.30000 0.27400 0.41142 0.26189 0.27040 0.27400 027400 0.27998 0.27400 0.30000 0.30000 0.23769 0.23952 0.20500 024610 0.01109 0.30000 0.27748 0.40000 0.30000 0.28571 0.18801 0.30873 0.28317 0.33000 027309 0.40000 0.32363 0.28571 027400 0.28571 0.29527 584.15 0.32950 0.10000 6810.00 0.28571 0.27136 6810.00 0.28571 0.27119 455.00 0.27201 0.32913 297.00 0.28570 033700 705.00 0.28571 0.28700 854.00 0.28571 0.30000 545.03 0.28571 0.22974 449.00 0.23860 0.27400 368.51 0.28571 0.21788 540.00 0.20276 0.27655 132.92 0.29053 0.28943 378.80 0.27140 0.27400 406.58 0.28571 0.26160 304.19 0.29030 0.28749 552.00 0.32260 0.27400 399.90 0.28571 004927 3267.00 0.11441 0.26177 2923.63 0.25000 0.24921 3009.60 0.33000 0.11030 4570.85 0.20000 0.24542 3041.71 0.36000 0.43396 2291.00 0.28571 0.21148 2422.51 0.59000 0.30000 2019.79 0.28571 030000 3296.66 0.28571 030000 1741.29 0.28571 0.30000 2983.96 0.28571 0.31027 11993.80 028571 022504 3139.63 0.48000
678.15 761.15 544.54 491.15 503.15 281.92 211.75 265.85 4765.00 4765.00 145.37 161.89 405.85 454.15 331.15 266.65 200.00 287.05 68.15 134.30 200.00 216.58 161.11 238.75 111500 1015.15 1045.00 1691.00 1056.15 594.05 841.15 841.15 793.15 658.15 1000.00 1071.15 1090.15
density
@
9.2955 5.5620 4.8572 5.5568 3.9540 2.3250 2.3387 1.0418 0.7550 0.8836 1.2889 2.5530 32000 3.5124 1.4194 5.2861 3.2674 2.2289 2.7498 2.4539 1.7837 4.0520 3.4502 17.2817 48610 5.5770 2.1598 2.8115 1.5950 1.6818 0.5016 0.9930 0.6187 0.6906 0.7975 0.8676 3.3250 3.9820 3.1704 4.1270 4.2450 1.6900 3.1982 1.4620 3.9920 10.0639 4.6320 3.7850 2.8030 2.7800 3.2136 1.6110 16110 1.6620 1.1362 1.3350 0.8398 1.8598 1.2350 1.4381 1.6494 0.8462 1.3376 2.0710 1.1806 1.4516 0.9811 1.3679 3.1080 2.0783 2.5140 3.4370 8.0169 4.0820 3.3925 6.1380 4.4169 6.4245 6.6800 3.2080
T
Table 4 Density of Liquid - Inorganic Compounds density = A B· (1 10 846 891 892 893 894 898 899 900 905 916 968 1035 1049 1099 1124 1128 1137 1140 1144 1147 1165 1169 1173 1229 1230 1255 1302 1303 1307 1332 1369 1404 1406 1409 1412 1420 1434 1502 1505 1575 1578 1585 1592.1 1610 1637 1639 1661 1668 1669 1670 1671 1672 1675 1686 1687 1691 1694 1695 1696 1697 1698 1699 1702 1709 1712 1713 1714 1716 1718 1719 1721 1722 1723 1725 1738 1739 1740 1771 1773 1800
NAME
FORMULA CeF3 CIF CIF03 CIF3 CIF5 CI02 CI2 CI20 CI207 Co CoCI2 Cr CrC606 Cr02CI2 Cs CsBr CsCI CsF Csi CsN03 Cs2S04 Cu CuBr CuCi CuCI2 Cui 02 020 Oy Er Eu FH03S FNO F2 F20 Fe FeC505 FeCI2 FeCI3 Ga GaC3H9 GaCI3 Gal2 Gd Ge GeBr4 GeCI4 GeHCI3 GeH2Br2 GeH2CI2 GeH3Br GeH3CI GeH4 Ge2H6 Ge3H8 HBr HCN HCI HCI03S HCI04 HF HI HN03 H2 H2O H202 H2S H2SO4 H2S2 H2Se H2Te H3NO H3P02 H3P04 He He Hf Hg HgBr2 HgCI2
cerium (iii) fluoride chlorine mono1luoride perchloryl fluoride chlorine trifluoride chlorine pentafluoride chlorine dioxide chlorine
chlorine monoxide chiorine heptoxide cobalt cobalt chloride chromium chromium carbonyl chromium oxychioride cesium cesium bromide cesium chloride cesium fluoride cesium iodide cesium nitrate cesium sulfate copper cuprous bromide cuprous chloride cupric chloride copper iodide deuterium deuterium oxide dysprosium erbium europium fluorosulfonic acid nitrosyl fluoride fluorine fluorine oxide iron iron pentacarbonyi ferrous chloride ferric chloride gallium gallium, trimethyl gallium trichloride gallium (ii) iodide gadolinium germanium germanium bromide germanium chloride germane, trichloro germane, dibromo germane, dichioro germane, bromo germane, chloro germane
digermane trigermane hydrogen bromide hydrogen cyanide hydrogen chloride chlorosulfonic acid perchloric acid hydrogen fluoride hydrogen iodide nitric acid hydrogen water hydrogen peroxide hydrogen sulfide sulfuric acid hydrogen disulfide hydrogen selenide hydrogen telluride hydroxylamine hypophosphorous acid phosphoric acid helium-3 helium-4 hafnium
mercury
mercuric bromide mercuric chloride
CAS No
A
7758·88·5 7790·89·8 7616·94·6 7790·91·2 13637·63·3 10049·04·4 7782·50·5 7791·21·1 10294·48·1 7440·48·4 7646·79·9 7440·47·3 13007·92·6 14977·61·8 7440·46·2 7787·69·1 7647·17·8 13400·13·0 7789·17·5 7789·18·6 10294·54·9 7440·50·8 7787·70-4 7758·89·6 7447-39·4 7681-65-4 7782-39-0 7789·20·0 7429-91-6 7440·52·0 7440-53-1 7789-21-1 7789-25-5 7782·41·4 7783-41-7 7439-89-6
7783·06·4 7664-93·9 13465-07-1 7783-07-5 7783-09-7
1.38450 0.60386 0.63654 0.68343 0.85421 0.57694 0.56600 0.60356 0.65031 2.51864 1.05823 2.13536 0.63518 0.64832 0.28361 1.05781 0.93727 1.26025 1.07356 0.84483 0.91290 2.63621 1.48318 2.79457 1.08795 1.70575 0.06700 0.35573 2.62400 2.75200 1.57191 0.55594 0.49514 0.57014 0.55240 1.99446 0.49908 1.02146 1.02395 0.47740 0.54374 0.66952 1.20420 2.68561 1.61357 1.02768 0.64888 0.67714 1.09428 0.67735 0.92324 0.65822 0.54904 0.63111 0.75692 0.80283 0.19501 0.44651 0.59672 0.59920 0.29041 1.04638 1.37243 0.03125 0.32500 0.43776 0.34459 1.49150 0.47306 0.67480 0.93431
7803-49-8 6303-21-5 7664-38-2 14762-55-1 7440·59·7 7440-58-6 7439-97-6 7789-47-1 7487-94·7
0.42502 0.43313 1.79505 0.04141 0.06930 3.75257 5.73614 1.93930 1.71179
13463·40·6 7758-94-3 7705·08-0 7440-55-3 1445·79·0 13450-90-3
--7440·54·2 7440-56-4 13450-92-5 10038-98-9 1184-65-2 13769-36-3 15230-48·5 13569-43-2 13637-65·5 7782-65-2 13818-89-8 14691-44-2 10035-10-6 74-90·8 7647-01-0 7790-94-5 7601-90·3 7664-39-3 10034·85-2 7697-37-2 1333-74-0 7732·18-5 7722-84-1
202
B
(density - g/ml, T - K)
• T/Cl'n C
n
0.21699 4905.07 0.54000 0.27400 282.32 0.28571 0.27200 368.40 0.29870 0.27400 459.39 0.28571 0.35050 415.90 0.28571 0.26048 465.00 0.28570 0.27315 417.15 0.28830 0.27400 444.68 0.28571 0.27400 565.78 0.28571 0.25033 7398.48 0.80000 0.30000 2154.97 0.28571 0.30000 8560.93 0.28571 690.80 0.28571 0.30000 0.27400 626.33 0.28571 0.14024 2048.10 0.28571 0.24371 2562.13 0.60000 0.30000 2562.13 0.28571 0.25546 2482.33 0.50000 0.24346 2529.56 0.60000 0.23365 1978.99 0.44000 0.21152 3681.07 0.58500 0.30161 5123.00 0.28571 0.30000 2651.71 0.28571 0.64708 1800.00 0.80000 0.30000 2010.00 0.28571 0.30000 2620.77 0.28571 0.31500 38.35 0.28571 0.27421 643.89 0.21000 0.29728 8561.50 0.28571 0.29872 9714.25 0.28571 0.29797 5150.00 0.28571 0.25067 715.00 0.37039 0.27400 352.67 0.28571 0.28587 144.12 0.28776 0.27016 215.10 0.28571 0.22457 9340.00 0.70000 0.27400 607.20 0.28571 0.30000 2115.88 0.28571 0.30000 964.41 0.28571 0.07625 7620.00 0.28571 0.38646 510.00 0.28570 0.25063 694.00 0.29982 0.25246 1396.80 0.31000 0.34705 11309.81 0.28571 026102 9803.00 0.59646 027400 740.00 0.28571 0.27400 574.00 0.28571 0.27400 559.78 0.28571 0.31186 563.33 0.28571 0.27219 535.61 0.28571 0.30405 515.20 0.28571 0.27464 478.44 0.28571 0.30254 308.00 0.28571 0.27400 491.01 0.28571 0.27400 616.37 0.28571 0.28545 363.15 0.28571 0.18589 456.65 0.28206 0.27290 324.65 0.32170 0.28520 700.00 0.28571 0.26092 631.00 0.34521 0.17660 461.15 0.37330 0.28826 423.85 0.28571 0.83561 520.00 0.19330 034730 33.18 0.27560 0.27000 647.13 0.23000 0.23170 730.15 0.38000 0.27369 373.53 0.29015 0.79186 924.00 0.27130 0.27400 542.39 0.28571 0.26335 411.15 0.26250 0.27400 438.04 0.28571 0.27400 574.00 0.28571 0.23298 627.65 0.25871 0.96491 1030.00 0.15872 0.46660 3.31 0.22300 0.41860 5.20 0.24100 0.30000 21687.96 0.28571 0.40708 1735.00 0.25997 0.30000 964.41 0.28571 0.30000 939.98 0.28571
TMIN
TMAX
code
T,K
density @ T
1703.15 128.15 125.41 190.15 190.00 213.55 172.12 157.15 182.15 1768.15 1008.15 2180.15 423.65 176.65 301.65 909.15 919.15 976.00 894.15 687.15 1278.15 1357.77 777.15 703.00 906.15 878.15 18.73 277.00 1685.15 1802.15 1095.15 184.17 139.15 53.48 49.25 1811.00 252.15 945.15 577.15 302.91 257.45 350.90 485.00 1586.15 1210.40 299.25 223.65 202.05 258.15 205.15 241.15 221.15 107.26 164.15 167.55 185.15 259.83 158.97 193.15 171.95 189.79 222.38 231.55 13.95 290.00 272.74 187.68 283.46 183.45 207.45 224.15 306.15 293.15 315.51 1.01 1.76 2506.15 234.29 510.15 550.15
3406.30 282.32 368.40 459.39 415.90 465.00 417.15 444.68 565.78 6658.63 1208.15 2380.15 690.80 626.33 1843.29 1500.00 1500.00 1500.00 1500.00 1374.30 2556.30 4610.70 977.15 1620.00 1106.15 1078.15 38.35 643.89 1885.15 2002.15 1295.15 715.00 352.67 144.12 215.10 8406.00 607.20 1145.15 584.65 6858.00 510.00 694.00 970.00 1786.15 8822.70 380.70 574.00 559.78 563.33 535.61 515.20 478.44 308.00 491.01 616.37 363.15 456.65 324.65 700.00 631.00 461.15 423.85 373.15 33.18 647.13 730.15 373.53 610.00 542.39 411.15 438.04 574.00
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
1750.00 128.15 125.41 190.15 190.00 213.55 172.12 157.15 182.15 1873.15 1008.15 2180.15 423.65 176.65 301.65 909.15 919.15 1000.00 920.00 690.00 1300.00 1673.15 777.15 710.00 906.15 878.15 18.73 303.20 1685.15 1802.15 1095.15 184.17 139.15 53.48 49.25 1923.15 252.15 945.15 577.15 302.91 257.45 350.90 490.00 1586.15 1210.40 299.25 223.65 202.05 298.15 298.15 298.15 298.15 107.26 164.15 167.55 185.15 259.83 158.97 193.15 171.95 189.79 222.38 231.55 13.95 290.00 298.88 187.68 283.46 183.45 207.45 224.15
4.6150 1.7945 2.0099 2.0766 2.0607 1.7834 1.7229 1.8928 2.0716 7.5400 2.8922 6.4600 1.5903 2.1050 1.8530 3.1316 2.7065 36179 3.1523 2.8161 3.0430 7.6900 4.4131 3.7400 3.0005 4.9802 0.1730 1.1034 8.2000 8.6000 4.8700 1.9194 1.5201 1.7056 1.8618 7.1090 1.5153 2.8233 2.5892 6.0780 1.1835 2.0526 4.0140 7.4000 5.5849 3.1386 1.9973 2.1155 2.8000 1.9000 2.3400 1.7500 1.5814 1.9982 2.4693 2.2322 0.7352 1.2708 1.8733 1.9970 1.2044 2.8608 1.6110 0.0776 0.9990 1.4493 0.9928 1.8424 1.4949 2.0468 2.6830
298.15 393.15 3.31 5.20 2706.15 1561.50 800.00 800.00
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
306.15 295.65 315.51 1.01 1.76 2506.15 234.29 510.15 550.15
1.2040 1.4900 1.8566 0.0836 0.1524 12.0000 13.6299 5.1207 4.3659
Table 4 Density of Liquid - Inorganic Compounds density = A B - (1 - T/C)'n 1813 1841 1868 1869 1873 1877
Hgl2 Ho IF5 IF7 12 In
1881 1890 1891 1892 1901 1917
InBr3 InCI InCI2 InCI3 Inl3 Ir
1960 1972 2009 2018 2035 2042 2047
K KBr KCI KF KI KN03 KOH
2053
KSCN
2064
K2C03
2089
K2Cr207 K2Mo04
2112 2127 2140 2162 2168 2171 2177 2182 2203 2213
K2S04 K2W04 Kr La LaBr3 LaCI3 LaF3 Li LiBr LiCI
2253 2261
LiF
2270 2274
Lil LiN03
2283 2306 2316
Li2C03 Li2S04 Lu Mg
2335 2341
MgBr2
2392
MgCI2
2399 2424 2429 2464 2495 2548 2573
MgF2 Mgl2 MgO Mn MnCI2 Mo MoF6
2585 2607
Mo03 NCIO
2608 2613
NCI3 NF3
2619 2625 2627 2634 2645 2674 2676 2678 2684 2685 2701 2747
NH3 NH4Br NH4CI NH41 NH5S NO N02 N2 N2F4 N2H4 N2H60 N20
2748 2749 2750
N203 N204 N205
2781
Na
2800 2810
NaBr NaCN
2855
NaCI
2864
NaF Nal NaN02
2888 2893 2894 2897 2916 2960 2968
NaN03 NaOH Na2C03 Na2Mo04 Na204W
(density - g/ml, T - K)
CAS No
A
B
C
n
TMIN
TMAX
code
T,K
density @ T
mercuric iodide
7774-29-0 7440-60-0 7783-66-6 16921-96-3
0.29040 0.29781
0.33313 0.07561 0.22168
1,2 1,2 1,2 1,2 1,2 1,2
298.15 278.65 386.75 429.75
3.1900 2.8023
1.63746 0.55791 0.93300
750.00 1947.15 594.33 447.53 737.24 573.15
5.1965 8.3400
7553-56-2 7440-74-6 13465-09-3
0.32000 0.28571 0.28571 0.28571 0.33550 0.28571
540.00 1747.15
iodine indium indium (iii) bromide indium (i) chloride indium (ii) chloride indium (iii) chloride indium (iii) iodide iridium potassium potassium bromide potassium chloride potassium fluoride potassium iodide potassium nitrate potassium hydroxide potassium thiocyanate potassium carbonate potassium dichromate potassium molybdate potassium sulfate potassium tungstate krypton lanthanum lanthanum bromide lanthanum chloride lanthanum fluoride lithium lithium bromide lithium chloride lithium lIuoride lithium iodide lithium nitrate lithium carbonate lithium sulfate lutetium magnesium magnesium bromide magnesium chloride magnesium lIuoride magnesium iodide magnesium oxide manganese manganese (ii) chloride molybdenum molybdenum lIuoride molybdenum oxide nitrosyl chloride nitrogen trichloride nitrogen trilluoride ammonia ammonium bromide ammonium chloride ammonium iodide ammonium hydrogensulfide nitric oxide nitrogen dioxide nitrogen tetrafluorohydrazine hydrazine hydrazine hydrate nitrous oxide nitrogen trioxide nitrogen tetraoxide nitrogen pentoxide sodium sodium bromide sodium cyanide sodium chloride sodium fluoride sodium iodide sodium nitrite sodium nitrate sodium hydroxide sodium carbonate sodium molybdate sodium tungstate
1078.10 9067.21 594.33 447.53 819.15 6730.00
532.15
holmium iodine pentalluoride iodine heptafluoride
1.93098 2.66880 1.24299 1.05176
1,2
1.12200 0.91200 0.10000 1.24500 6.41388 0.18711 0.37889
0.27849 0.23807 002259 0.26103 0.30000 020637 0.12288
710.00 500.00
3.1100
13465-10-6 13465-11-7 10025-82-8 13510-35-5 7439-88-5 7440-09-7 7758-02-3 7447-40-7 7789-23-3 7681-11-0 7757-79-1 1310-58-3
0.11777 0.66025 0.25152 0.55890 0.18547
0.05355 0.24785 0.07215 0.24400 0.09004
FORMULA
10
NAME
0.31663 0.27400
1747.15 282.58 278.65 386.75 429.75 693.15 1386.30
1996.27 0.51000 1394.35 0.13500 484.15 968.30 1463.47 0.41000 508.15 1016.30 2465.71 0.50000 856.15 1712.30 960.30 1382.83 0.25000 480.15 15035.00 0.28571 2719.15 2919.15 2223.00 0.35970 336.35 2000.70 3520.00 0.57980 1007.00 3168.00 3470.00 0.37353 1044.00 3123.00 2891.12 0.55000 1153.15 1500.00 3610.00 0.47000 1003.00 3249.00 1757.23 0.36400 610.15 1220.30
1,2 1,2 1,2 1,2 1,2
2624.00
1,2
0.25871
679.00
873.15 892.30
1,2 1,2 1,2 1,2 1,2 1,2
510.00 860.00 490.00 2719.15 336.35 1007.00 1044.00 1160.00 1010.00 620.00 679.00
3.9760 7.0314 3.7400 3.0400 2.1300 4.1500 20.0000 0.8283 2.1254 1.5248 1.8907 23941 1.8630 1.7215
333-20-0
0.47943
0.24807
1284.91
0.34000
446.15
1,2
450.00
1.5981
584-08-7
0.56772
0.23558
3372.91
0.42500
1171.15 2342.30
1,2
1180.00
1.8924
7778-50-9
0.68190
1987.20 0.32000 0.51500
2.2730
3433.39
690.00 1380.00 1192.15 2384.30
690.00
0.70020 0.56520
0.25157 0.21870
1,2
13446-49-6
1,2
2.3340
1342.15 2684.30 1194.15 2388.30 115.78 209.35
1,2 1,2 1,2 1,2
1250.00 1350.00 1250.00
7778-80-5 7790-60-5 7439-90-9 7439-91-0 13536-79-3 10099-58-8 13709-38-1 7439-93-2 7550-35-8 7447-41-8
0.20774 0.22946 0.28840
0.93930 0.91799 1.50549 3.40000
0.23941 0.67812
0.95865 1.38000 0.11037 0.85546 0.50679 0.62331
0.23420 0.23902 0.19951 0.28026 0.26862 0.25973
3865.39 0.62000 3439.15 0.44500 209.35 029390 9511.00 0.28571 3056.11 0.10000 3260.59 0.43000 5086.51 0.41000 3503.00 0.35129 2578.42 0.41000 2695.68 0.48000 3182.65 0.52000
0.90000
0.24126 0.26143
1191.15 1061.15 1132.15 1766.15 453.69 820.15 887.15 1143.15
1391.15 2122.30 2284.30 3532.30 3152.70 1500.00 1500.00 1700.00
1,2 1,2 1,2 1,2 1,2 1,2 1,2
2370.00 0.37000 1515.31 0.24000
742.00
1447.00 1052.30
1,2 1,2
0.25150
2868.91
0.31500
1,2
0.59880 3.32517
0.24462 0.29161
3260.59 4128.66
0.36000 0.28571
0.07780 0.75300
0.03010 0.24784
2241.04 2834.35
0.28571 0.26500
1992.30 1132.15 2264.30 1936.15 2136.15 923.15 1023.15 984.15
1,2
0.58060 0.71100
0.30000 0.21707
2754.32 4424.11
0.28571 0.51000
985.15 1536.15 3072.30
1,2 1,2
0.91290 0.19187 2.09497 0.90334 3.14663 093061
0.25450 0.01440 0.30000 0.30000 0.30000 0.27400
2612.59 0.29500 907.15 1814.30 5950.00 0.28571 3105.00 5355.00 6902.82 0.28571 1519.15 1719.15 2382.98 0.28571 923.15 1123.15 9620.00 0.28571 2895.15 3095.15 498.12 0.28571 290.15 49812
1,2 1,2 1,2 1,2 1,2 1,2
1.56112 0.47092
0.30000 0.27083
2319.46 0.28571 440.65 0.24939
10025-85-1 7783-54-2
0.57737
0.27400
564.00
0.59826
0.28170
234.00
7664-41-7 12124-97-9 12125-02-9
0.23684 0.98286 0.75456 1.00871 0.49634 0.51712 0.55409 0.31422 0.54042 0.20285 0.37734 0.44927
0.25443 0.30000 0.30000 0.30000 0.30000 0.30440 0.28287 0.28610 027760 0.12073 0.29390 0.27244 0.18425
405.65 1089.82 882.00 1104.32 49910 180.15 431.15 126.20 309.35 653.15 595.60 309.57 425.00
800.00 391.15 109.50 261.90 63.15 111.65 274.69 221.45 182.30
0.31000 0.27400
431.15 515.51
0.25871 0.30000 028571 0.37200
7789-24-4 10377-51-2 7790-69-4 554-13-2 10377-48-7 7439-94-3 7439-95-4 7789-48-2 7786-30-3 7783-40-6 10377-58-9 1309-48-4 7439-96-5 7773-01-5 7439-98-7 7783-77-9 1313-27-5 2696-92-6
12027-06-4 12124-99-1 10102-43-9 10102-44-0 7727-37-9 10036-47-2 302-01-2 7803-57-8 10024-97-2 10544-73-7 10544-72-6 10102-03-1
0.53040 054780
0.38980 0.63412 0.55485
526.15 996.15
1968.30 1600.00
1,2 1,2 1,2
115.78 1191.15 1070.00 1150.00 1750.00 453.69 840.00 900.00 1150.00 750.00
3.1020 1.7680
1010.00 1150.00 1936.15
1.8260 1.9960 9.3000
923.15
1.5786
1000.00 985.15 1650.00
2.6100 1.6774 23700
920.00 3105.00 1519.15
3.0430 5.9514 6.4300
923.15 2895.15 290.15
2.5729 9.3300
1268.15 440.65
1,2 1,2
1068.15 213.55
293.00
564.00
1,2
293.00
0.29529
66.46
234.00
1,2
0.28880 0.28571 0.28571 0.28571 0.28571 0.24200 0.23882 0.29660 0.28570 0.35000 0.28571 0.28820
195.41 800.00 793.20
1,2 1,2 1,2 1,2
263.15 261.90 303.15
405.65 980.84 793.80 993.89 455.37 180.15 431.15 126.20 309.35 653.15 595.60 309.57 268.15 431.15 311.65
66.46 195.41 800.00 793.20 800.00 391.15 109.50 261.90 63.15 111.65 388.23 298.15 182.30 263.15 299.32 303.15
370.95
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
5.9600 4.9324 3.1955 4.6000 0.5124 2.5246 1.4947 1.8131
550.00
1068.15 213.55
0.28571
1.8840 3.1310 2.4493
2.5518 4.2834 1.4250 1.6500 1.8854 0.7347 2.2420 1.4094 2.3204 1.0799 1.3349 1.5214 0.8702 1.6691 0.9497 1.0300 1.2292 1.4557 1.4409 1.5156
7440-23-5
0.19819
0.19553
2573.00
2573.00
1,2
370.95
0.9276
7647-15-6
0.25853 0.17117
0.07847 0.11000
4287.00 0.53000
1020.00 2500.00
1,2
1030.00
2.3334
2900.00 0.28571
973.15
1173.15
1,2
973.15
1.2200
0.22113 0.22700
0.10591 0.08221
3400.00 0.37527
1073.90 3060.00
1,2
1073.90
1.5497
1,2
1270.00
1.9440
0.29682 0.54030
0.07909 0.24561
2.7352 1.8010
0.25010 0.09705 0.23924 0.24783 0.22453
1,2 1,2 1,2 1,2 1,2 1,2
940.00 570.00
0.57150 0.20000 0.59046 0.82950 1.01760
0.58000 1269.00 2500.00 3950.00 0.49000 933.00 2500.00 1567.15 0.34000 544.15 1088.30 1670.83 0.33000 580.15 1160.30 2820.00 0.27000 596.00 1830.00 3258.00 0.40000 1131.25 2262.50 2765.23 0.32000 960.15 1920.30 2796.48 0.27000 971.00 1942.00
580.00 600.00 1140.00
1.9050 1.7810 1.9682 2.7650 3.7920
143-33-9 7647-14-5 7681-49-4 7681-82-5 7632-00-0 7631-99-4 1310-73-2 497-19-8 7631-95-0 13472-45-2
203
5530.00
1,2
1020.00 1050.00
Table 4 Density of Liquid - Inorganic Compounds density = A B - (1 10 2974 2976 3019 3037 3057 3060 3091 3092 3105 3139 3198 3199 3200 3222 3234 3235 3238 3252 3280 3381 3382 3389 3392 3396 3397 3398 3448 3451 3461 3483 3487 3504 3514 3521 3530 3537 3545 3571 3637 3641 3650 3691 3773 3781 3786 3791 3795 3801 3803 3822 3828 3875 3880 3940 3941 3974 3991 3994 3996 3998 4001 4004 4005 4006 4007 4008 4010 4013 4023 4025 4042 4044 4047 4049 4056 4065 4071 4083 4089 4107
FORMULA Na2S04 Na2S4 Nb NbF5 Nd NdBr3 Ne Ni NiC404 NiF2 02 03 Os Os04 P P PBr3 PC3H904 PC6H1504 PCI3 PCI5 PH3 PH41 POCI3 PSBr3 PSCI3 P203 P2S5 P406 Pb PbBr2 PbC8H20 PbCI2 PbF2 Pbl2 PbO PbS Pd Pm Po Pr
PI Ra Rb RbBr RbCI RbF Rbi RbN03 Rb2S04 Re Re207 Rh Rn Ru RuF5 S SCI2 SCI20 SF4 SF6 SOBr2 SOCI2 SOF2 S02 S02CI2 S03 S2CI2 Sb SbBr3 SbCI3 SbCI5 SbH3 Sbl3 Sb203 Sc ScCI3 Se SeCS SeCI4
NAME sodium sulfate sodium tetrasulfide niobium niobium (v) fluoride neodymium neodymium tribromide
neon nickel nickel carbonyl nickel fluoride oxygen ozone osmium osmium tetroxide phosphorus (white) phosphorus (red) phosphorus tribromide phosphate, trimethyl phosphate, triethyl phosphorus (iii) chloride phosphorus pentachloride phosphine phosphonium iodide phosphorus oxychloride phosphorus thiobromide phosphorus thiochloride phosphorus trioxide phosphorus (v) sulfide phosphorous (iii) oxide lead lead bromide tetraethyl lead lead chloride lead fluoride lead iodide lead oxide lead sulfide palladium promethium polonium praseodymium platinum radium rubidium rubidium bromide rubidium chloride rubidium fluoride rubidium iodide rubidium nitrate rubidium sulfate rhenium rhenium haptoxide rhodium radon ruthenium ruthenium (v) fluoride sulfur sulfur dichloride thionyl chloride sulfur tetrafluoride sulfur hexafluoride thionyl bromide thionyl chloride thionyl fluoride sulfur dioxide sulfuryl chloride sulfur trioxide sulfur monochloride antimony antimony tribromide antimony trichloride antimony pentachloride stibine antimony triiodide antimony (iii) oxide scandium scandium chloride selenium (gray) selenosulfide, carbon selenium tetrachloride
(densitv - ami, T - K)
- T/C)'n
CAS No
A
B
C
n
TMIN
TMAX
code
T,K
density @ T
7757-82-6 12034-39-8 7440-03-1 7783-68-8 7440-00-8 13536-80-6 7440-01-9 7440-02-0 13463-39-3 10028-18-9 7782-44-7 10028-15-6 7440-04-2 20816-12-0 7723-14-0 7723-14-0 7789-60-8 512-56-1 78-40-0 7719-12-2 10026-13-8 7803-51-2 12125-09-6 10025-87-3 3931-89-3 3982-91-0 1314-24-5 1314-80-3 12440-00-5 7439-92-1 10031-22-8 78-00-2 7758-95-4 7783-46-2 10101-63-0 1317-36-8 1314-87-0 7440-05-3 7440-12-2 7440-08-6 7440-10-0 7440-06-4 7440-14-4 7440-17-7 7789-39-1 7791-11-9 13446-74-7 7790-29-6 13126-12-0 7488-54-2 7440-15-5 1314-68-7 7440-16-6 10043-92-2 7440-18-8 14521-18-7 7704-34-9 10545-99-0 7719-09-7 7783-60-0 2551-62-4 507-16-4 7719-09-7 7783-42-8 7446-09-5 7791-25-5 7446-11-9 10025-67-9 7440-36-0 7789-61-9 10025-91-9 7647-18-9 7803-52-3 7790-44-5 1309-64-4 7440-20-2 10361-84-9 7782-49-2 5951-19-9 10026-03-6
0.26141 0.19000 2.48435 1.09002 2.02652 1.26846 0.48504 2.56376 0.47753 152939 0.43600 053954 6.48474 162701 1.02120 0.96106 093428 0.50567 0.31086 0.52827 1.38262 0.30087 1.01597 0.76178 0.94173 0.56545 0.49723 0.63096 0.70154 1.73000 1.92627 0.50856 1.72887 2.79825 2.01004 318209 2.70282 3.31600 2.20800 2.76115 2.10880 6.65186 1.49145 0.34600 0.91773 0.76254 1.19655 0.97769 0.74280 0.76320 6.01402 2.10435 3.40525 1.58779 3.48198 0.90813 0.20468 0.56268 0.57200 068957 073472 0.89295 0.58606 0.60330 0.52210 0.57681 0.63035 0.56169 1.69927 1.42997 0.84488 0.78102 0.90538 1.68384 1.72636 0.90098 0.50100 0.75697 0.69071 0.76605
0.10000 0.06778 0.30000 0.30000 0.28826 0.25875 0.30670 0.25892 0.27400 0.30000 0.29060 0.29884 0.30000 0.30000 0.50058 0.80200 0.27400 0.34496 0.23183 0.25681 0.30000 0.29028 0.27400 0.35087 0.30000 0.28862 0.17857 0.30000 0.27400 0.15282 0.30000 0.25781 0.28860 0.30000 0.30000 0.30000 0.30000 0.26650 0.30571 030000 0.30930 0.26561 0.30000 0.21564 0.23888 0.23646 0.30000 0.24073 0.24581 0.21768 030000 0.30000 0.30000 0.28111 0.30000 0.30000 0.10440 0.27258 0.27016 0.27400 0.27010 0.27400 0.27659 0.27400 0.25842 0.26336 0.19013 0.27400 024231 0.30000 0.25331 0.27400 0.31372 0.30000 0.30000 029526 0.18853 0.16124 0.27400 0.27400
3700.00 3200.00 17904.10 811.32 10665.10 2750.83 44.40 6986.15 508.40 3278.75 154.58 261.00 16878.68 656.60 993.75 993.75 711.00 729.00 757.00 563.15 646.15 324.75 539.70 602.15 729.89 638.82 667.60 1291.00 714.86 5400.00 1933.47 655.00 1998.62 2550.73 1865.07 2842.26 2531.19 10669.07 10228.86 3013.08 12306.26 6983.00 4862.82
0.28571 0.80000 0.28571 0.28571 0.28571 0.27000 0.27860 0.70000 0.28571 0.28571 0.29240 0.28523 0.28571 0.28571 0.66360 0.09118 0.28571 0.39266 0.34137 0.29690 0.28571 0.36975 0.28571 0.42596 0.28571 0.25871 0.28571 0.28571 0.28571 0.28571 0.28571 0.23388 0.34000 0.28571 028571 0.28571 0.28571 0.75000 0.28571 0.28571 0.28571 0.70000 0.28571 0.37000 0.62000 0.63000 0.28571 0.61000 0.35000 0.54000 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.11400 0.26470 0.29906 0.28571 0.29210 0.28571 0.30630 0.28571 0.28950 0.29557 0.43590 0.28571 0.28571 0.28571 0.30257 0.28571 0.28571 0.28571 0.28571 0.28571 0.76500 0.28571 0.28571 0.28571
1157.00 623.00 2750.15 348.65 1294.15 955.15 24.56 1728.15 248.15 1723.15 54.35 80.15 3306.15 329.15 317.55 853.15 233.15 227.00 216.65 181.15 433.15 139.37 291.65 274.33 311.15 242.75 296.95 596.15 295.65 600.64 646.15 139.41 774.15 1128.15 675.15 1163.15 1387.15 1828.05 1315.15 527.15 1204.15 2041.55 973.15 312.46 955.15 988.15 1033.15 915.15 578.15 1323.15 3459.15 569.15 2237.15 202.15 2607.15 359.65 388.36 151.15 168.65 149.15 223.15 220.95 172.00 162.65 197.67 219.00 289.95 193.15 903.78 369.75 346.55 275.95 185.15 440.15 929.15 1814.15 1213.00 494.15 197.95 400.00
2000.00 823.00 2950.15 423.40 1494.15 1910.30 44.40 6287.54 508.40 1923.15 154.58 261.00 3506.15 366.15 894.38 894.38 711.00 729.00 681.30 563.15 504.20 324.75 539.70 602.15 379.65 371.65 667.60 1161.90 714.86 4860.00 1500.00 655.00 1500.00 1328.15 875.15 1363.15 1470.65 9602.16 1515.15 727.15 1404.15 6284.70 1173.15 1883.70 1800.00 1800.00 1233.15 1800.00 1156.30 2646.30 3659.15 602.35 2437.15 377.40 2807.15 559.65 1181.70 542.00 567.00 364.00 318.69 661.75 567.00 371.25 430.75 545.00 490.85 659.37 4563.00 458.95 714.60 662.54 440.35 640.15 1129.15 2014.15 2426.00 694.15 576.53
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
1157.00 623.00 2750.15 348.65 1294.15 960.00 24.56 1873.15 248.15 1723.15 90.15 80.15 3306.15 329.15 317.55 853.15 233.15 227.00 216.65 181.15 433.15 139.37 291.65 274.33 311.15 242.75 298.15 596.15 295.65 923.15 646.15 139.41 780.00 1128.15 675.15 1163.15 1387.15 1973.15 1315.15 527.15 1204.15 2073.15 973.15 312.46 970.00 990.00 1033.15 930.00 590.00 1350.00 3459.15 569.15 2237.15 202.15 2607.15 35965 388.36 151.15 168.65 149.15 223.15 220.95 172.00 162.65 197.67 219.00 289.95 193.15 903.78 369.75 346.55 275.95 185.15 440.15 929.15 1814.15 1213.00 494.15 19795 400.00
2.0688 1.8270 7.8300 3.0394 6.7200 4.2282 1.2470 7.5950 1.3911 4.0465 1.1351 1.6013 201000 4.3653 1.7453 1.1559 2.9674 1.2680 11439 1.7741 3.3228 0.8222 2.8651 1.7096 2.6306 1.6954 2.1300 1.7301 2.1320 10.2650 5.6264 1.8323 4.9420 7.7522 5.7953 8.9658 7.0560 10.3100 6.9000 8.6301 6.5900 18.7450 4.6150 1.4815 2.6994 2.2466 3.4247 2.8864 2.4760 2.5440 18.9000 5.4875 10.6500 4.4000 10.9000 2.6109 1.7944 1.8534 1.8571 2.0999 1.8449 2.8278 1.8518 1.8089 1.6207 1.8148 1.9409 1.8144 6.4910 4.0191 2.6800 2.3698 2.4413 4.7641 50384 2.8000 1.6700 3.9871 2.1771 2.1641
204
2093.00 2646.82 2694.06 2738.03 2568.65 1665.07 3810.67 21482.82 1035.10 12906.61 377.40 15247.14 977.44 1313.00 542.00 567.00 364.00 318.69 66175 567.00 371.25 430.75 545.00 490.85 659.37 5070.00 892.75 794.00 662.54 440.35 1097.96 2765.72 8035.08 3493.44 1766.00 576.53 743.95
600.00
Table 4 Density of Liquid - Inorganic Compounds density =A B - (1 - T/C)An FORMULA
10
NAME
4109 4110 4115 4116 4117 4123 4140 4143 4143.1 4144 4145 4146 4149 4150 4152 4153 4157 4187 4196 4238 4240 4241 4242 4243 4244 4245 4246 4247 4248 4250 4251 4252 4253 4257 4258 4259 4260 4261 4265 4274 4275 4286 4287
SeF4 SeF6 SeOCI2 SeOF2 Se02 Se2C Si SiBrCI2F SiBrF3 SiBr2CIF SiBr3CI SiBr4 SiCH3CI3 SiCH4CI2 SiC2H5CI3 SiC2H6CI2 SiC3Hl0 SiC7H8CI2 SiC8H20 SiCIC3H9 SiCIF3 SiCI2F2 SiCI3Br SiCI3F SiCI4 SiF4 SiHBr3 SiHCI3 SiHF3 SiH2Br2 SiH2CI2 SiH2F2 SiH212 SiH3Br SiH3CI SiH3F SiH31 SiH4 Si02 Si2C6H180 Si2C6H19N Si2CI6 Si2CI60
selenium tetrafluoride selenium hexafluoride selenium oxychloride selenium oxyfluoride selenium dioxide diselenide, carbon silicon silane, bromodichlorofluoro silane, bromotrifluoro silane, dibromochlorofluoro silane, tribromochloro tetrabromosilane silane, methyilrichloro silane, methyldichloro silane, ethyltrichloro silane, dimethyldichloro silane, trimethyl silane, methylphenyldichloro silane, tetraethyl chlorotrimethylsilane siiane, chlorotrifluoro silane, dichlorodifluoro silane, bromotrichloro silane, trichlorofluoro silicon tetrachloride silicon tetrafluoride silane, tribromo silane, trichloro silane, trifluora silane, dibromo silane, dichloro silane, difluoro silane, diiodo silane, monobromo silane, monochloro silane, monofluoro silane, iade silane silicon dioxide (alpha quartz) disiloxane, hexamethyl disilazane, hexamethyl disilane, hexachloro disiloxane, hexachloro
4288 4288.1 4289 4290 4291 4295 4296 4297 4300 4303 4332 4335 4422 4424 4433 4461 4464 4479 4484 4492 4517 4550 4570 4583 4588 4590 4639 4678 4703 4704 4719 4728 4731 4747 4766 4787 4836
Si2F6 Si2H5CI Si2H6 Si2H60 Si20CI3F3 Si3CI8 Si3H8 Si3H9N Si4Hl0 Sm Sn SnBr4 SnCI2 SnCI4 5nl4 Sr SrBr2 SrCI2 SrF2 Srl2 Ta Tb Tc Te TeCI4 TeF6 Ti TiCI4 TI TIBr TICI Til TIN03 Tm
disilane, hexafluoro dislanyl chloride disilane disiloxane disiloxane, trichlorotrifluoro octachlorotrisilane trisilane trisilazane tetrasilane samarium tin (white) stannic bromide stannous chloride stannic chloride stannic iodide strontium strontium bromide strontium chloride strontium fluoride strontium iodide tantalum terbium technetium tellurium tellurium tetrachloride tellurium hexafluoride titanium titanium tetrachloride thallium thallous bromide thallium chloride thallium iodide thallium (i) nitrate thulium uranium uranium fluoride vanadium
U UF6
V
(density - g/ml, T - K)
CAS No
A
B
C
n
TMIN
TMAX
code
T,K
density @ T
13465-66-2 7783·79-1 7791-23-3 7783-43-9 7446-08-4 506-80-9 7440-21-3
1.00046 0.85211 0.79805 0.92879 1.33585 0.90535 1.73001 0.66872 0.72447 0.81945 0.99013 0.91021 0.43982 0.39804 039503 0.36073 0.23858 0.37625 0.24588 0.29484 0.56426 0.55307 0.69835 054467 0.51929 0.51526 1.05904 0.50208 0.51882 0.77365 0.42619 0.44709 0.97501 0.55308 0.35290 0.36018 0.70808 0.24205 1.76380 0.27018 026371 051982 0.53229 0.54778 0.34804 0.27952 0.31264 0.54394 0.51452 0.26010 0.31120 0.26613 2.30412 0.68914 1.09276 1.15953 0.75734 1.51710 0.78222 1.10700 0.81396 1.04100 1.22310 4.78107 2.44800 3.34979 1.83626 0.93555 1.16414 1.38759 0.55691 1.79212 2.55912 1.68450
0.29360 0.27400 0.27400 0.26650 0.30000 0.27844 0.64037 0.27400 0.27400 0.27400 0.32690 0.26374 0.26111 0.28209 0.24246 0.25095 0.26428 0.25350 025676 0.24793 0.27400 0.27400 0.29974 0.27400 0.26466 0.24128 0.32450 0.27817 027400 0.28512 0.26767 0.27400 0.28278 0.26469 0.25554 0.27400 0.25939 0.28405 0.65205 0.26863 0.25980 0.27400 0.27400 0.27400 027400
608.64 368.80 706.80 635.50 961.16 665.03 5159.00 497.17 375.28 535.27 614.74 663.00 517.00 483.00 559.95 520.35 432.00 689.00 606.00 497.75 330.54 390.93 545.50 460.49 507.00 259.00 610.00 479.00 291.02 550.00 459.00 318.21 660.00 454.00 396.65 286.28 515.00 269.70 3780.00 518.70 544.00
0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.30000 0.28571 0.28571 0.28571 0.28571 0.28571 0.27788 022529 0.29509 0.28758 0.29230 0.33126 0.27087 0.29726 0.28571 0.28571 0.28571 0.28571 0.27618 0.16693 0.28571 0.27626 0.28571 0.28571 0.22750 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.39578 0.28571 0.28099 0.28570 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 028571 0.28571 0.28571 0.27000 0.28571 0.32000 0.28571 0.28571 0.28571 028000 0.34000 0.60000 0.24500 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.28571 0.27260 0.28571 0.28571 0.34500 0.28571 0.25000 0.28571 0.28571 0.28571 0.28571
263.15 238.45 281.65 288.15 613.15 229.45 1685.00 160.85 202.65 173.85 252.35 278.54 195.35 182.55 167.55 197.05 137.26 229.65 190.65 215.45 131.15 133.45 211.15 152.35 204.30 186.35 199.65 144.95 141.75 202.95 151.15 150.00 272.15 179.25 155.05 150.00 216.15 88.48 1696.00 204.93 293.15 271.95 239.95 254.55 250.00 140.65 128.95 150.00 250.00 155.95 167.45 179.55 1347.15 505.08 304.15 519.95 242.95 417.65 1050.15 930.15 1147.15 1750.15 788.15 3290.15 1629.15 2430.15 722.66 497.15 235.35 1941.15 249.05 577.15 733.15 703.15 713.15 479.15 1818.15 1408.15 342.35 2183.15
608.64 368.80 706.80 635.50 736.82 665.03 4643.10 497.17 375.28 535.27 61474
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
298.15 238.45 281.65 29815 613.15 298.15 1687.00 160.85 202.65 173.85 298.15 298.15 195.35 182.55 167.55 197.05 137.26 229.65 190.65 215.45 131.15 133.45 298.15 152.35 204.30 186.35 199.65 144.95 141.75 202.95 151.15 150.00 272.15 179.25 155.05 150.00 216.15 88.48 1696.00 204.93 293.15 271.95 239.95 254.55 250.00 140.65 128.95 150.00 250.00 155.95 167.45 179.55 1347.15 505.08 304.15 520.00 242.95 417.65 1050.15 940.00 1170.00 1750.15 820.00 3290.15 1629.15 2430.15 722.66 497.15 235.35 1941.15 249.05 577.15 733.15 710.00 713.15 490.00 1818.15 1408.15 342.35 2183.15
2.7500 2.2295 2.4450 2.8000 3.2878 2.6626 2.5700 2.1285 2.0436 2.6067 2.4970 2.8000 1.4269 12410 1.4148 1.2045 0.7843 1.2491 0.8390 0.9578 1.7303 1.7450 1.8260 1.7275 1.6446 1.6272 2.8930 1.5988 1.5123 2.3245 1.4200 1.3153 2.8858 1.7494 1.1533 1.0264 2.2477 0.7094 2.5300 0.8459 0.7769 1.5816 1.6587 1.4636 1.0108 0.7783 1.0020 1.7555 1.6386 0.8386 0.9907 0.8569 7.1600 6.9860 3.3493 3.3640 2.3283 4.2668 2.3750 3.6900 27132 3.4700 4.0770 15.0000 7.6500 10.6145 5.7970 2.5692 3.1100 4.1100 1.7877 11.2913 7.1999 5.6150 6.7626 48870 9.0000 17.9070 4.4224 5.5500
------13465-76-4 7789-66-4 75-79-6 75-54-7 115-21-9 75-78-5 933-07-7 149·74-6 631-36-7 75-77-4 14049-36-6 18356-71-3 13465-74-2 14965-52-7 10026-04-7 7783-61-1 7789-57-3 10025-78-2 13465-71-9 13768-94-0 4109-96-0 13824-36-7 13760-02-6 13465-73-1 13465-78-6 13537-33-2 13598-42-0 7803-62-5 14808-60-7 107-46-0 999-97-3 13465-77-5 14986-21-1
----1590-87-0 13597-73-4
----7783-26-8
--7783-29-1 7440-19-9 7440-31-5 7789-67-5 7772-99-8 7646-78-8 7790·47·8 7440-24-6 10476·81·0 10476-85-4 7783-48-4 10476-86-5 7440-25-7 7440-27-9 7440-26-8 13494-80-9 10026-07-0 7783-80-4 7440-32-6 7550-45-0 7440-28-0 7789-40-4 7791-12-0 7790-30-9 10102-45-1 7440-30-4 7440-61-1 7783-81-5 7440-62·2
205
2.38850 1.46610 2.88674 5.57293 1.74575 1.78294
0.31790 0.27400 0.27400 0.27400 0.27400 0.27400 0.27400 0.28994 0.09454 0.27400 0.29336 0.27400 0.30000 0.30000 0.25696 0.24736 0.21117 0.26087 0.30000 0.30358 0.30000 0.30000 0.30000 0.27400 0.30000 0.26324 0.14783 0.30000 0.24725 0.30000 0.26093 0.28545 0.30000 0.27705 0.30000
66096 655.58 411.33 506.89 432.00 416.86 508.78 775.41 525.15 518.20 599.30 5082.92 740000 764.82 1459.53 619.85 1011.64 4267.20 2678.83 3303.79 5040.43 2269.87 19900.93 1113810 1740077 4840.00 1083.31 380.18 6400.00 638.00 4648.06 1778.75 2025.07 1785.26 1379.95 6283.16 13712.62 505.80 1178715
663.00 517.00 483.00 559.95 520.35 432.00 689.00 606.00 497.75 330.54 390.93 545.50 460.49 507.00 259.00 610.00 479.00 291.02 550.00 459.00 318.21 660.00 454.00 396.65 286.28 515.00 269.70 2503.00 518.70 544.00 660.96 655.58 411.33 506.89 432.00 416.86 508.78 697.87 525.15 51820 599.30 1547.15 6660.00 391.00 1200.00 619.85 617.65 1250.15 1860.30 2294.30 3500.30 1576.30 3490.15 1829.15 2630.15 922.66 581.15 380.18 2141.15 638.00 4183.25 933.15 1406.30 913.15 958.30 2018.15 1608.15 401.33 2383.15
1.2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2
Table 4 Density of liquid - Inorganic Compounds density = A B - (1 10
FORMULA
NAME
4860 VCI4 vanadium tetrachloride 4880 VOCI3 vanadium oxytrichloride 4899 W tungsten 4917 WF6 tungsten fluoride 4945 Xe xenon 4960 Y yttrium 4976 YCI3 yttrium chloride 4995 Yb ytterbium 5021 Zn zinc 5024 ZnBr2 zinc bromide 5062 ZnCI2 zinc chloride 5069 ZnF2 zinc fluoride zirconium 5113 Zr zirconium chloride 5142 ZrCI4 5150 Zrl2 zirconium diiodide code: 1 - data, 2 - estimate density - density of liquid, glml A, B, C, and n - regression coefficients of chemical compound T- temperature, K TMAX - maximum temperature, K TMIN - minimum temperature, K
(density· g ml, T - K)
- T/C)'n
CAS No
A
B
C
n
TMIN
TMAX
code
T,K
density @ T
7632-51-1 7727-18-6 7440-33-7 7783-82-6 7440-63-3 7440-65-5 10361-92·9 7440-64-4 7440-66-6 7699-45-8 7646-85-7 7783-49-5 7440-67-7 10026-11-6 15513-85-6
0.71831 0.59758 5.84023 1.28420 1.10648 1.32860 0.75510 2.12198 1.98150 1.04100 0.84382 1.61024 1.90680 1.08375 1.16310
0.33057 0.29177 0.30000 0.27400 0.28552 0.29141 0.25459 0.31165 0.27115 0.25804 0.32317 030000 0.30000 0.30000 0.24116
697.00 636.00 14756.00 468.56 289.74 9381.32 2863.15 4365.92 3170.00 1921.39 1637.05 2882.98 8802.00 983.96 2070.72
0.31162 0.31711 0.28571 0.28571 0.28967 0.28571 0.30500 0.28571 0.34000 0.27500 0.19000 0.28571 0.28571 0.28571 0.39000
247.45 193.65 3695.15 272.65 161.36 1795.15 994.15 1092.15 692.70 667.15 638.15 1145.15 2128.15 710.15 719.00
697.00 636.00 3895.15 468.56 289.74 1995.15 1988.30 1292.15 2853.00 1334.30 1200.00 1345.15 2328.15 836.75 1438.00
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
247.45 193.65 3695.15 272.65 161.36 1795.15 980.00 1092.15 812.15 670.00 720.00 1145.15 2128.15 710.15 72000
1.8864 1.7913 17.7000 3.5228 2.9783 4.2400 2.5170 62100 6.4270 3.4700 2.3210 4.5642 5.8000 2.4989 3.8770
206