Fire cooling performance by water sprays using medium and small-scale model experiments with scaling relaxation

Fire cooling performance by water sprays using medium and small-scale model experiments with scaling relaxation

Journal Pre-proof Fire cooling performance by water sprays using medium and small-scale model experiments with scaling relaxation Futoshi Tanaka, Wata...

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Journal Pre-proof Fire cooling performance by water sprays using medium and small-scale model experiments with scaling relaxation Futoshi Tanaka, Wataru Mizukami, Khalid A.M. Moinuddin PII:

S0379-7112(19)30079-7

DOI:

https://doi.org/10.1016/j.firesaf.2020.102965

Reference:

FISJ 102965

To appear in:

Fire Safety Journal

Received Date: 11 February 2019 Revised Date:

5 February 2020

Accepted Date: 5 February 2020

Please cite this article as: F. Tanaka, W. Mizukami, K.A.M. Moinuddin, Fire cooling performance by water sprays using medium and small-scale model experiments with scaling relaxation, Fire Safety Journal (2020), doi: https://doi.org/10.1016/j.firesaf.2020.102965. This is a PDF file of an article that has undergone enhancements after acceptance, such as the addition of a cover page and metadata, and formatting for readability, but it is not yet the definitive version of record. This version will undergo additional copyediting, typesetting and review before it is published in its final form, but we are providing this version to give early visibility of the article. Please note that, during the production process, errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. © 2020 Published by Elsevier Ltd.

Futoshi Tanaka: Conceptualization, Methodology, Software, Formal analysis, Data curation, Writing - Original draft, Supervision. Wataru Mizukami: Validation, Investigation, Data curation, Visualization. Khalid A.M. Moinuddin: Conceptualization, Methodology, Writing- Reviewing and Editing.

1

Fire cooling performance by water sprays using medium and

2

small-scale model experiments with scaling relaxation

3

Futoshi Tanakaa*, Wataru Mizukamib, and Khalid A.M. Moinuddinc

4 5 6

a

7

3-9-1 Bunkyo, Fukui-shi, Fukui 910-8507, Japan

Mechanical Engineering, Faculty of Engineering, University of Fukui

8 9 10

b

Mechanical Engineering, Graduate School of Engineering, University of Fukui

3-9-1 Bunkyo, Fukui-shi, Fukui 910-8507, Japan

11 12

c

13

P.O. Box 14428, Melbourne, Victoria 8001, Australia

Center for Environmental Safety and Risk Engineering, Victoria University

14 15

*

16

Tel: +81-776-27-9817, Fax: +81-776-27-8748

17

Email: [email protected]

18

Postal address: Mechanical Engineering, Faculty of Engineering, University of Fukui,

19

3-9-1 Bunkyo, Fukui-shi, Fukui 910-8507, Japan

Corresponding author:

20 21

1

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Abstract

23

The fire cooling performance by water sprays is investigated in medium and small-scale fire cooling

24

experiments. The scaling relationships considered are the fire diameter, spray height, heat release

25

rate, spray angle, flow rate, working pressure, and droplet diameter. Full-cone-type spray nozzles of

26

different sizes are used in both scale experiments. Although spray conditions (spray angle, flow rate,

27

pressure, and droplet diameter) satisfying the scaling relationships are used, when the geometrical

28

scaling of the nozzles is not sufficient, the water spray mass flux distributions generated by the

29

nozzles do not fulfill the scaling relationship. To resolve this problem, we propose a new scaling

30

relaxation for scaling the fire cooling effect of water sprays even under incomplete scaling

31

conditions in the water spray mass flux distributions. In the scaling relaxation, we propose an

32

effective plane in which the group of water droplets collides with the fire plume, and assume that

33

only the water droplets passing through the effective plane contribute to fire cooling. Based on the

34

experimental data, we show that scaling with sufficient accuracy is possible by normalizing with the

35

spray flow rate directly contributing to the fire cooling. The scaling accuracy tends to decrease with

36

the increasing spray angle.

2

37

Keywords:

38

Fire cooling

39

Water sprays

40

Scaling relaxation

41

Model experiments

42

3

43

Nomenclature

44

Acup

opening area of the cup (m2)

45

b

half-width of Gaussian distribution (m)

46

Cpi

specific heat of each gas component species (kJ/(kg·K))

47

Cp_gas

specific heat of mixed exhaust gas (kJ/(kg·K))

48

D

fire source diameter (m)

49

Dd

diameter of the smoke duct (m)

50

Dv

volumetric diameter of droplet (mm)

51

Dv,0.5

median volumetric diameter of droplet (mm)

52

E'

net heat of combustion per unit volume of oxygen (MJ/m3)

53

E"

net heat of combustion per unit volume of oxygen consumed in the burning of carbon

54

monoxide (MJ/m3)

55

g

gravitational acceleration (m/s2)

56

H

relative humidity in percent (%)

57

∆H

heat of combustion (MJ/kg)

58

krad

correction factor for a radiative heat release rate (–)

59

L

length from burning surface of a fire to a spray head, characteristic length (m)

60

Lp

length from burning surface to effective interaction area (m)

61

Lw

length from spray head to effective interaction area (m)

62

Mcup

mass of water received by the cup (kg)

63

Me

molecular weight of the exhaust gas mixture (kg/kmol)

64

ms

mass flow rate of smoke in the smoke duct (kg/s)

65

mwe

actual delivery water spray mass flow rate (kg/s)

66

m″w

water spray mass flux (kg/(m2·s))

67

P

pressure (kPa)

68

PH2O

water vapor pressure (kPa)

69

Pw

working pressure of water spray (MPa)

70

Q

desired heat release rate (kW)

71

Qchem

chemical heat release rate measured by the oxygen consumption method (kW)

72

Qconv

convective heat flow rate (kW)

73

Qcool

rate of fire cooling by water sprays (kW)

74

Qgas

theoretical heat release rate estimated from mass flow rate of fuel (kW)

4

75

Qloss

rate of heat loss (kW)

76

Qrad

radiative heat release rate (kW)

77

qrad

radiative heat flux (kW/m2)

78

R0

universal gas constant (kJ/(kmol·K))

79

Re

gas constant of the exhaust gas mixture (kJ/(kg·K))

80

Red

droplet Reynolds number (–)

81

r

radius coordinate for water mass flux distribution (m)

82

re

radius of effective interaction area (m)

83

rrad

distance from fire center to the face of a radiometer (m)

84

S

scale ratio (–)

85

Se

effective interaction area (m2)

86

T

temperature (K)

87

∆T

rise in temperature (K)

88

t

time (s)

89

∆tcup

discharging time (s)

90

us

velocity in the smoke duct (m/s)

91

Va

volume flow rate of ambient air drawn from the hood (m3/s)

92

Vs

volume flow rate in the smoke duct (m3/s)

93

Vw

spray flow rate (L/min)

94

X

mole (volume) fraction (–)

95

Y

mass fraction (–)

96

Zf0

virtual origin (m)

97

x, y, z

the axes of coordinates (m)

98 99

Greek letters

100



spatial distribution function (–)

101

α

plume angle (°)

102

β

correction factor in the smoke duct (–)

103

γ

empirical constant for drop size distribution (–)

104

η

combustion efficiency (–)

105

θ

spray angle (°)

106

ρs

density of smoke (kg/m3)

5

107

σ

empirical constant for drop size distribution (–)

108



oxygen depletion (–)

109

χrad

radiative fraction (–)

110 111

Superscripts

112

A

gas components without water vapor in the gas analyzer

113

AW

gas components with water vapor in the gas analyzer

114

DT

dew point temperature

115

S

gas components in the smoke duct

116

°

gas components in the ambient air

117 118

Subscripts

119

CO

carbon monoxide

120

CO2

carbon dioxide

121

H 2O

water vapor

122

N2

nitrogen

123

O2

oxygen

124

amb

ambient condition

125

m

medium scale

126

s

small scale

127

6

128

1. Introduction

129

130

In the 1970s, Heskestad derived a set of scaling relationships for the thermo-fluid dynamic

131

interaction of water sprays with fires in geometrically similar spaces based on the Froude modeling

132

concept [1]. Subsequently, the scaling relationships proposed were used to evaluate fire extinction

133

similarity on 1:10, 1:3 and 1:1 scale fire experiments with water sprays in a large space, and the

134

effectiveness of the scaling theory was validated [2–3].

135

136

Yu investigated the effect of droplet size on the scaling relationships derived by Heskestad for

137

applying the scaling relationships to the extinguishment phenomenon by water mist with a low

138

Reynolds number based on the droplet diameter (Red ≤ 1) [4]. The finding from this investigation

139

indicated that droplet size for low Reynolds number conditions should be scaled with the 1/4-power

140

of length scale, instead of the 1/2-power found for high Reynolds number conditions. Later,

141

Jayaweera and Yu confirmed the droplet size scaling requirement for low Reynolds number

142

conditions with a series of fire cooling experiments [5, 6]. This improvement was warranted as the

143

scaling relationships derived by Heskestad were developed for sprinklers with significant inertia

7

144

compared to gas flow (Red > 1). Furthermore, Yu derived a general rule for the scaling of the

145

diameter of a droplet under a wide range of droplet Reynolds numbers, and validated this general

146

rule [7]. After improving the scaling relationships, Yu et al. conducted a series of fire suppression

147

experiments to evaluate the efficacy of physical scaling of water mist suppression of a gas fire, pool

148

fire and solid combustible fire in enclosures [8-10]. These experiments were conducted using full

149

and 1:3 scale enclosures. The results showed that water mist cooling and fire development could be

150

reasonably reproduced during enclosure fires by physical scaling based on Froude modeling.

151

Furthermore, Yu et al. presented an evaluation of the scaling of fire extinguishment by water mist in

152

a large industrial machinery enclosure [11]. Four fire scenarios were selected using full and 1:2 scale

153

enclosures. Based on the obtained results, they concluded that the scaling relationships for water

154

mist fire suppression could be used to determine the fire extinguishing performance of full-scale

155

water mist protection.

156

157

In addition to Yu’s research to evaluate the efficacy of physical scaling of water mist, many model

158

scale experiments have been conducted for fires in large structures with water sprays where

159

full-scale fire experiments were difficult. For example, many model-scale studies have been

8

160

conducted on the influence of water sprays installed in tunnels on fires. Ingason carried out 1:23

161

model scale tunnel fire tests with a water spray system in order to capture the basic behavior of water

162

sprays in a longitudinal tunnel flow [12]. Li and Ingason conducted 1:15 model scale tunnel fire tests

163

to clarify the effectiveness of an automatic sprinkler system in a tunnel with longitudinal ventilation

164

[13]. Furthermore, Li and Ingason examined how the combustion products were released while a

165

water sprinkler system was active, using a 1:4 scale model tunnel [14].

166

167

Heskestad proposed the use of geometrically similar nozzles in order to preserve the spray

168

trajectories [2, 3]. Many model scale experiments with water sprays have been conducted using

169

geometrically similar nozzles following the suggestion of Heskestad in addition to satisfying scaling

170

relationships for the working pressure, spray flow rate, and average diameter of droplets. In principle,

171

when the spray trajectory is preserved, the scaling of the water spray mass flux distribution on a

172

floor is automatically satisfied.

173

174

In model scale fire experiments with water sprays, it is necessary to satisfy the scaling relationships

175

concerning geometric similarity including the nozzle, heat release rate of the fire, working pressure

9

176

of the water spray nozzle (determining the initial speed of water droplets), spray flow rate, average

177

diameter of droplets, and water spray mass flux distribution on a floor, and it is quite challenging to

178

fulfill all scaling relationships. In order to prepare a particularly geometrically accurate scaled-down

179

nozzle, a special nozzle must be developed or selected from a number of existing nozzles. As a result,

180

it is quite challenging, or the geometrical similarity of the nozzles must be compromised.

181

182

If geometrically similar nozzles following the suggestion of Heskestad can’t be used, inconsistency

183

in the scaled water spray mass flux distribution on a floor may occur. In this study, we propose a

184

new scaling relaxation to estimate the fire cooling performance in the medium scale from that in the

185

small scale under the condition of inconsistency in the scaled water spray mass flux distribution in

186

medium and small-scale models. In the new scaling relaxation, the actual delivery water spray mass

187

flow rate is used for evaluating the fire cooling performance at medium and small scales.

188

10

189

2. Experimental method

190

In this study, a series of medium and small-scale fire experiments with water sprays were conducted

191

to evaluate the fire cooling performance by water sprays, and Froude’s scaling relationships were

192

applied to the experiments on both scales to evaluate the performance of similarity. Table 1 shows

193

the scaling relationships based on the Froude modeling [1–7]. As the Reynolds number of the flow

194

around a droplet was greater than unity under our experimental conditions, we chose the 1/2 power

195

of scale ratio as per the scaling of droplets [7].

196

Table 1 Scaling relationships for characteristic parameters [1–7].

Unit

197

Scaling (S = scale ratio)

Heat release rate (HRR)

Q [kW]

Q full

=

S

Velocity

u [m/s]

u

=

S

3

full

5/2

Q model

1/2

u

5/2

model

=

S

t full

=

S

T [K]

T full

=

S T model

Pressure

P [kPa]

P

=

S P

Spray flow rate

V w [L/min]

V w full

=

S

Mass flux

m'' [kg/(m s)]

2

m'' full

=

S

Median diameter

D v,0.5 [mm]

D v,0.5 full =

S

Volume flow rate

V [m /s]

V

Time

t [s]

Temperature

full

full

V

model

1/2

t model

0 1

5/2 1/2 1/2

model

V w model m'' model D v,0.5 model

198

199

2.1. Overview of the experimental apparatus

200

Figure 1 shows the experimental apparatus used for this study. The apparatus was constructed as a 11

201

semi-open space, which was 1.6 m wide, 1.6 m deep, and 2.3 m high, and comprised of a hood, a

202

smoke duct and a suction fan for collecting and exhausting the gas including combustion products, a

203

water tank for receiving water spray droplets, a fire source, a water spray equipment, and a gas

204

analyzer system. The size of the hood was 1.6 m in width, 1.6 m in depth, and 1.1 m in height. The

205

upper part of the hood was made of stainless-steel plate of 1.0 mm in thickness and 0.2 m in height,

206

and the lower part of the hood was made of a calcium silicate board of 5 mm in thickness and 0.9 m

207

in height. The smoke duct connecting the hood with the fan was 0.25 m in diameter and made of

208

galvanized steel plates of 0.5 mm in thickness. The size of the water tank for receiving and

209

collecting water spray droplets was 1.5 m in width, 1.5 m in depth, and 0.6 m in height, and was

210

made of stainless-steel plate of 2.0 mm in thickness.

211

212

In the medium and small-scale experiments, two sizes of propane gas burners with inner diameters

213

of 0.155 and 0.08 m, respectively, were used as the fire source, and the rims of the gas burners were

214

made of steel pipe with thicknesses of 5 and 4.2 mm, respectively. The propane gas burners were

215

filled with many ceramic balls of 5 mm in diameter. The burning surfaces of the fire sources were

216

placed directly below a water spray head. During the experiments, the mass flow rate of propane gas

12

217

was regulated by a mass flow controller (model 3660, KOFLOC) to ensure a constant value.

218

219

The length from the spray head to the burning surface of the fire sources was used as the

220

characteristic length, L, in the scaling theory. Equation (1) is the definition of scale ratio, S. S =

221

Lm Ls

(1)

222

The parameters Lm and Ls indicate the characteristic lengths of medium and small scales measured as

223

Lm = 1.33 m and Ls = 0.67 m, respectively. The scale ratio between the medium and small scales was

224

2:1.

225

226

We used the oxygen consumption method developed by Parker [15] and Janssens [16] to measure

227

the heat release rate (HRR) of a fire during ‘free burning’ and water spray activation. In the

228

preconditioning process, the sampling gas drawn from the smoke duct was passed through the first

229

air tank, a cooling bottle filled with water for removing large soot and dust, a hand-made

230

dehumidifier for reducing the relative humidity of the sampling gas, and a filter for completely

231

removing soot, and then collected in the second air tank. Sensors were installed in the first and

232

second air tanks for measuring the relative humidity and gas temperature in the tanks. Furthermore, a

13

233

sensor was also placed in ambient air for measuring the relative humidity and temperature in the air.

234

The water cooling during the pretreatment process has the problem of CO and CO2 dissolution, so if

235

the smoke includes no large soot and dust, water cooling should not have been used in the

236

pretreatment process. In fact, for the clean-burning propane gas in our study there was no need for

237

the water cooling.

238

239

The hand-made dehumidifier consisted of a gas flow section with many fins cooled with ice water.

240

The gas with high humidity was cooled, and its humidity was reduced by condensation. The dew

241

point temperature of the hand-made dehumidifier incorporated in the preconditioning system was

242

about 5 °C. The O2 gas analyzer (POT8000, Shimadzu Corporation, gas analyzer based on the

243

paramagnetic principle) and CO/CO2 gas analyzer with a built-in thermo-electric dehumidifier

244

having the gas dew point temperature of 3.5 °C (CGT7000, Shimadzu Corporation, gas analyzer

245

based on the infra-red (IR) absorption method and Beer-Lambert law) drew the preconditioned gas

246

from the second air tank and measured the concentration of the sampling gas. The dew point of the

247

sample gas entering the O2 and CO/CO2 analyzers was 5 °C and 3.5 °C, respectively.

248

14

249

The oxygen consumption method developed by Parker [15] assumes that the sampling gas is

250

completely dehumidified before being introduced into a gas analyzer. Unfortunately, our hand-made

251

dehumidifier in the preconditioning process could not completely remove all the water vapor from

252

the sampling gas; the dew point temperature was 5 °C for the O2 gas analyzer and 3.5 °C for the CO2

253

and CO analyzer, so we estimated the volume fractions of the completely dehumidified sampling

254

gases assuming that slight water vapor remained in the sampling gases in the second gas tank after

255

the dehumidifier as follows:

X

Ao O2

=

256

X

Ao CO2

X OAW 2

(1 − X ) DT 5 H 2O

=

257

X = A O2

258

A X CO =

AW X CO 2

(1 − X

(2)

o

DT 3.5 H2O

)

(3)

XOAW 2

(1− X ) DT 5 H2O

A XCO = 2

259

o

AW XCO 2

(1− X

DT 3.5 H2O

AW X CO

(4)

)

(5)

260

(1 − X

261

where

XHDT2O5

262

and 3.5 °C, respectively, and

DT 3.5 H 2O

)

and

(6)

XHDT2O3.5

are the volume fractions of water vapor at dew point temperatures of 5

XkAW is the volume fraction of sampling gases with slight water vapor 15

263

measured by the gas analyzers.

264

265

The transport delay time from the flame location through the exhaust collection and sampling probe

266

to the preconditioning system was several seconds (about 5 seconds or less). In the preconditioning

267

process, as the first and second air tanks with the internal volume of 1.5 L and the water cooling tank

268

with air space of about 0.7–0.8 L were used under the sampling gas flow rate of 5 L/min, a large

269

time delay occurred. The preconditioning process with several air tanks can be modeled as a primary

270

delay system under the assumption that the gas concentration in the air tanks is always uniform.

271

Figure 2 indicates the estimated time lag of the preconditioning system and the estimated time lag of

272

the combined preconditioning system and O2 gas analyzer (POT8000). For instance, when gas with a

273

concentration of 100% is introduced to the preconditioning system, the time delay is about 61

274

seconds for reaching a 90% concentration at the output of the preconditioning system. The time

275

delays of the CO2 and CO gas analyzer and the O2 gas analyzer are 30 seconds (CGT7000; 90%

276

response time) and 45 seconds (POT8000; 90% response time), respectively. When we combined the

277

O2 gas analyzer (POT8000) with the preconditioning system during O2 measurement, we found that

278

the time delay for obtaining a 90% response is about 108 seconds. The time delay for obtaining a

16

279

99% response is about 208 seconds. The non-response time from the ignition to the response of the

280

gas analyzers to the gases concentration has been corrected by shifting the time curve of the gas

281

concentration for estimating the chemical heat release rate of fire.

282

283

The mass flow rate of the exhaust gas in the smoke duct was estimated from the rise in temperature

284

in the smoke duct and velocity measured by a thermocouple and a Pitot tube, respectively, installed

285

in the smoke duct as shown in Fig. 1. Leakage or escape of combustion products from the exhaust

286

collection system was not reliably investigated in our system and might have occurred, particularly

287

for the weak fire conditions subjected to spray. Radiative heat flux from the fire was measured by a

288

water-cooled radiometer (RE-4, Tokyo Seiko Co., Ltd.) which was installed 1 m away from the fire.

289

17

290 291

Fig. 1. Schematic of the experimental apparatus: the water spray, fire source, and gas analyzer

292

systems (unit: m).

18

Gas concentration [%]

100 Preconditioning 90% response 61 s

Precon. + O 2 Analyzer 90% response 108 s

50 Input Preconditioning Precon. + O 2 Analyzer

0 0

60

120

180

Time [s] 293 294

Fig. 2. Time delay during gas concentration measurement estimated by the model of a primary delay

295

system.

296

297

2.2. Chemical heat release rate measured by the oxygen consumption method

298

The oxygen consumption method requires the mole (volume) fractions of oxygen, carbon dioxide,

299

carbon monoxide and water vapor to calculate the heat release rate. The mole fractions of the

300

incoming ambient gases and the gases drawn into the analyzers are defined in the same way as those

301

by Parker and Janssen [15, 16]. In Eqs. (7)-(11), the superscripts °, S, and A of the mole fractions

302

indicate the gas components in the ambient air, the smoke duct, and the gas analyzers, respectively.

303 19

304

The chemical heat release rate, Qchem, of the fire source is calculated using Parker’s method as

305

follows [15]:

306

A   E "− E '   1 − φ  X CO Qchem =  φ −    A   E '   2  X O2 

307

  1 − φ  A X Hs 2O   o o A Va = Vs 1 − X O2 φ + X O2  A  X CO2 + X CO +   X O   1 − X Hs 2O    2  

308

where E' is the net heat of combustion per unit volume of oxygen (propane: 16.7 MJ/m3, derived

309

from ∆HO2 = 12.77 MJ/kg referred to 25 °C), and E" is the net heat of combustion per unit volume of

310

oxygen consumed in the burning of carbon monoxide (23.1 MJ/m3, derived from ∆HO2,CO = 17.69

311

MJ/kg referred to 25 °C) [17, 18]. The volumetric flow rate of the ambient air drawn from the hood

312

is estimated by Eq. (8). Va and Vs are the volume flow rate referred to standard conditions (25°C, 1

313

atm). The volume fraction of water vapor,

314

immediately after being sampled from the smoke duct in this study. No condensation was observed

315

in the first gas tank or sampling hose even during water spray activation. Oxygen depletion, , is

316

defined as:

317

o  1 − X CO − X Ho 2O 2 X Oo2 − X OA2  A A  1 − X CO − X CO  2 φ=   X OA2 X Oo2 1 − A A   1 − X CO − X CO   2

 o  E ' X O2 Va  

(7)

XHs 2O

−1

(8)

, in Eq. (8) was measured in the first gas tank

  

(9)

20

X Oo2

o XCO 2

318

The initial volume fractions of oxygen,

319

These were measured as the gas concentration of dehumidified air through the preconditioning o

process. Here,

321

X Oo2

322

X Oo2 = X OA2 1 − X Ho 2O

323

o A X CO = X CO 1 − X Ho 2O 2 2

o XCO 2

o

(

o

(

, refer to the incoming air.

o

X OA2

320

and

, and carbon dioxide,

and

A XCO 2

are defined as the initial concentrations of dehumidified air. Then,

are given by:

)

(10)

)

(11)

324

Equations (10) and (11) are substituted into Eq. (9) for  and into Eqs. (7) and (8) for the heat

325

release rate of a fire when water vapor is trapped in the preconditioning process.

326

327

In this study, the temperature and relative humidity were measured to estimate the volume fraction

328

of water vapor at three locations. The first location was in the ambient air, the second location was in

329

the first gas tank immediately after being sampled from the smoke duct, and the final location was in

330

the second gas tank after dehumidification. The measurements of the temperature and relative

331

humidity were made every minute. A commercially available thermo-hygrometer was used for the

332

measurements. The temperature and relative humidity were measured by a thermistor element and a

333

ceramic resistor, respectively. From the temperature and relative humidity in the ambient air and

21

334

inside the first gas tank, the volume fractions of water vapor in the ambient air,

335

smoke duct,

X H2O = 336

XHs 2O

, and in the

, were estimated using the following equation:

PH2O H Pamb 100

PH2O

XHo2O

(12)

337

where,

338

relative humidity in percent. The saturated vapor pressure of water was estimated by the equation of

339

the vapor pressure-temperature relationship for saturated water vapor developed by Wagner and

340

Pruß as follows [19]:

341

 PH O  T ln  2  = c ( a1Θ + a2 Θ1.5 + a3Θ3 + a4 Θ3.5 + a5Θ4 + a6 Θ7.5 )  Pc  T ,

342

with Θ = 1-T/Tc, Tc = 647.096 K, Pc = 22.064×103 kPa, a1 = -7.85951783, a2 = 1.84408259, a3 =

343

-11.7866497, a4 = 22.6807411, a5 = -15.9618719, a6 = 1.80122502.

is the saturated vapor pressure of water, Pamb is the ambient pressure, and H is the

(13)

344

345

In the steady-state combustion state, both the temperature and the relative humidity in the first gas

346

tank became almost constant in the averaging period, therefore, the precision index of average

347

became small. On the other hand, the bias limits of the thermo-hygrometer were expected to be in

348

the range of B∆T = ±1 K for the thermistor thermometers and B∆H = ±7% for the ceramic resistance

349

hygrometers. Since the precision index of average was small and negligible, uncertainty of the

22

350

volume fraction of water vapor can be estimated from the bias limit only, and it was about

351

±0.2% estimated from Eq. (14):

 ∂X H2O   ∂X H2O  =  B∆H  +  B∆T   ∂H   ∂T  2

U X H O = BXH O 2

2

352

U XH O 2

=

2

(14)

353

354

355

The volume flow rate in the smoke duct, Vs, was defined as follows:

Vs = β

π 4

Dd2us

(15)

356

where us and Dd are the smoke velocity measured by the Pitot tube at the center of the smoke duct

357

and the diameter of the smoke duct, respectively. The volume flow rate in the smoke duct, Vs, was

358

converted to the volume flow rate referred to standard conditions (25°C, 1 atm) and substituted into

359

Eq. (8). A correction factor, β, was used for estimating average velocity in the smoke duct from the

360

center velocity measured by the Pitot tube. The correction factor was estimated from the velocity

361

distribution in the smoke duct as β = 0.852 by separate calibration experiments.

362

363

In the calibration experiments, the velocity distribution consisting of 13 measurement points in the

364

duct was measured under the same ventilation condition of the hood in the medium scale without the

365

fire source. The correction factor was estimated as the ratio of the volume flow rate obtained from

23

366

the velocity profile in the duct and the volume flow rate obtained from the velocity at the center of

367

the duct. In the fire experiments, the flow velocities at the center of the duct were about 4.0 and 2.3

368

m/s in the medium and small scales, respectively. The Reynolds number of the flow in the duct was

369

6.7×104 in the medium scale and 3.8×104 in the small scale, and both Reynolds numbers were of the

370

same order of magnitude and in a sufficiently turbulent state. When the Reynolds number of the flow

371

was in the same order, it could be expected that there was no significant change in the velocity

372

profile in the duct, so the correction factor measured in the medium scale was also used in the small

373

scale. Furthermore, the effect of buoyancy inside the duct under the fire condition on the correction

374

factor was neglected as the flow was in a sufficiently turbulent state.

375

376

2.3. Radiative heat release rate

377

Radiative heat release rate is the radiative component of Qchem. Figure 3 shows a schematic

378

representation of the distribution of radiative heat flux for estimating the radiative heat release rate.

379

If it is assumed that spatial and temporal variations of radiation from a fire can be separated, the

380

distribution of radiative heat flux, qrad (θ, φ, t), measured rrad away from the fire is given by Eq. (16):

381

′ ( t) qrad (θ,ϕ,t) =Ω(θ,ϕ) qrad

(16)

24

382

where, q’rad (t) is the radiative heat flux measured by the water-cooled radiometer installed rrad away

383

from the fire, Ω (θ, φ) indicates the spatial distribution function, and θ and φ are elevation and

384

azimuth angles, respectively. If the fire is assumed to radiate as a point source, the radiative heat

385

release rate can be estimated by Eq. (17), based on the time curve of the radiative heat flux, q’rad (t): 2 2 ′ ( t ) ∫∫ Ω (θ ,ϕ ) rrad Qrad ( t ) = ∫∫ qrad (θ ,ϕ, t ) rrad sinθ dθ dϕ = qrad sinθ dθ dϕ

ϕ ,θ

386

ϕ ,θ

(17)

387

The value of the surface integral of the spatial distribution function Ω (θ, φ) of the radiation can be

388

expressed as follows using a correction factor, krad: 2 2 4π rrad krad = ∫∫ Ω (θ ,ϕ ) rrad sin θ dθ dϕ

ϕ ,θ

389

(18)

390

When the correction factor, the radiative heat flux measured by the water-cooled radiometer, and the

391

distance from the fire to the radiometer were used, the time variation of the radiative heat release rate

392

was estimated as follows:

393

2 ′ ( t) Qrad ( t ) = 4πrrad krad qrad

394

The correction factor, krad, was derived under the assumption that the time integral of the radiative

395

fraction of Qchem over the average period in ‘free burning’ agrees with the time integral of the

396

radiative heat release rate based on the point source assumption over the same period as shown in Eq.

397

(20):

(19)

25

krad = 398

χ rad ∫ Qchem ( t ) dt ave 2 rad ave

4π r



′ ( t ) dt qrad

(20)

399

where, the value of the global radiative fraction of a propane fire was selected as χrad = 0.29 [18].

400

The distance from the fire to the radiometer was set as rrad = 1.0 m in all fire experiments.

401

402

The correction factor obtained during ‘free burning’ was used to estimate the radiative heat release

403

rate during water spray activation. For the estimation of the correction factor, it was assumed that the

404

spatial distribution function Ω (θ, φ) of the radiation and the global radiative fraction of fire, χrad, did

405

not change during the water spray activation. However, in reality, the latter assumption was not

406

sufficiently valid during the water spray activation. For example, work by White et al. [20] has

407

suggested that the radiative fraction of fire is not constant and reduces when fires are suppressed

408

with water spray owing to the reduction in flame temperature. Furthermore, they confirmed this by

409

direct measurements of the radiative fraction of fire suppressed by nitrogen dilution of the oxidizer.

410

When the oxygen volume fraction in the ambient air with nitrogen dilution was in the range of 0.155

411

to 0.21, the color of the propane flame was yellow indicating soot incandescence. The radiative

412

fraction corresponding to the yellow flame ranged from 0.19 to 0.32 [21]. In our fire experiments,

413

except for the extinguishing condition, since the flame color was observed to be yellow during the

26

414

water spray activation, it can be assumed that the radiative fraction ranged from 0.19 to 0.32. The

415

measurement system used in our study was unable to sense the changes in the radiative fraction

416

during the water spray activation. Therefore, in the estimation of the radiative component of Qchem

417

during the water spray activation, the decrease in prediction accuracy was considered by widening

418

the range of the bias limit B of the global radiative fraction of a propane fire in the uncertainty

419

analysis. Based on work by White et al. [21], the bias limit Bχ of the global radiative fraction of a

420

propane fire was assumed to be Bχ = 0.10. In other words, the radiative fraction was assumed as χrad

421

= 0.29±0.10. As a result, the range of uncertainty has been significantly broadened in the radiative

422

component of Qchem.

423

424

2.4. Convective heat flow rate and heat loss by heat transfer

425

Convective heat flow rate is the convective component of Qchem. The convective heat flow rate of the

426

fire, Qconv, was measured during the fire experiment with and without water sprays. The convective

427

heat flow rate was estimated by the following equation:

428

Qconv = ms Cp _ gas ∆Tgas

429

where, ms, Cp_gas, and ∆Tgas are the mass flow rate of the smoke flowing through the smoke duct, the

(21)

27

430

specific heat of the mixed exhaust gas at constant pressure, and the rise in temperature of the smoke

431

flow in the smoke duct adjacent to the hood, respectively. The specific heat of the mixed exhaust gas

432

was evaluated by a simple mass weighted average of the specific heat of each gas component species

433

(N2, O2, CO2, CO, H2O) dependent on the temperature of the smoke based on the data in

434

NIST-JANAF Thermochemical Tables [22]:

Cp _ gas = ∑YC i pi i

435 436

(22)

The mass flow rate in the smoke duct was defined as follows:

ms = ρsVs = 437

Pamb Vs Re (Tamb + ∆Td )

(23)

438

The mass flow rate was calculated from the smoke density, ρs, and the smoke volume flow rate, Vs.

439

The molecular weight of the exhaust gas mixture, Me, in the smoke duct can be estimated by the

440

following equation derived by Janssens [16]:

441

M e = 18 + 4 1 − X HS 2O

442

where

443

relative humidity and temperature in the first gas tank immediately after being sampled from the

444

smoke duct. The gas constant of the exhaust gas mixture was calculated from the universal gas

445

constant and the molecular weight of the exhaust gas mixture as:

(

X Hs 2O

)( X

A O2

A + 4 X CO + 2.5 2

)

(24)

is the volume fraction of water vapor in the smoke duct, which is estimated from the

28

Re =

446

R0 Me

(25)

447

448

In this study, we installed three thermocouples on the surface of the hood. The approximate value of

449

the rate of heat loss, Qloss, through the hood could be roughly estimated based on the surface

450

temperature by the classical theory for natural convection. When we estimated the rate of heat loss,

451

Qloss, we found that it was 2% or less of Qchem during water spray activation (Qloss ≤ 5% of Qchem

452

during ‘free burning’), therefore, we ignored the rate of heat loss through the surface of the hood.

453

454

2.5. Size distribution of water spray droplets and estimation of droplet diameter

455

In this study, we measured the size distribution of water spray droplets and evaluated the median

456

volumetric diameter, Dv,0.5, from their size distribution. The diameters of spray droplets were

457

measured by using an immersion method [23, 24]. The spray droplets were captured in a small dish

458

containing castor oil and photographed with a microscope and a digital camera, and the diameters of

459

the spray droplets were measured from the photograph. Figure 4 shows an example of the droplets

460

photographed and the measurement of the radius of the droplets. The location where the spray

461

droplets were captured was the same as the burning surface of the fire source. The number of spray

29

462

droplets measured for spray nozzles TG1 and TG03 (refer to Table 2) were 662 and 622 droplets,

463

respectively, to estimate the size distribution and the median volumetric diameter of the spray

464

droplets.

465

466

Figure 5 shows the size distributions of the water spray droplets in the medium and small-scale

467

experiments. The black and red solid lines show the droplet size distributions by cumulative volume

468

fraction (CVF) as measured and prescribed, respectively. The cumulative volume fraction

469

distribution can be prescribed for a water spray as a combination of log-normal and Rosin-Rammler

470

distributions [25]:

471

  ln Dv′ 2  Dv 1 Dv ,0.5  1   dD′ exp  −  v  2π ∫0 σ Dv′  2σ 2     CVF(Dv ) =  γ    D    1 − exp  −0.693 v   D      v,0.5    

σ= 472

2 2π ( ln 2) γ

=

(D ≤ D ) v

v,0.5

(D > D ) v

v,0.5

(26)

1.15

γ

(27)

473

where Dv,0.5 is the median volumetric droplet diameter and γ and σ are empirical constants.

474

Rosin-Rammler and log-normal distributions are smoothly joined if the relationship between

475

empirical constants γ and σ fulfills the relational expression as shown in Eq. (27). In this study, the

476

parameters γ = 2.6 and σ = 0.442 were determined from the comparison in Fig. 5.

30

Spatial distribution function Ω

qrad (θ, φ, t)

z

y

x Point source χQchem

rrad

q’rad (t) Radiometer

477 478

Fig. 3. Schematic representation of the distribution of radiative heat flux for estimating the radiative

479

component of the chemical heat release rate.

480 481

Fig. 4. Example of the droplets photographed and measured.

482 31

1

CVF [-]

0.8 0.6 0.4 Measured Prescribed γ = 2.6

0.2 0 0

200

400 600 Diameter [µm]

800

1000

483 484

(a) Medium scale: Dv,0.5 = 418 µm

1

CVF [-]

0.8 0.6 0.4 Measured Prescribed γ = 2.6

0.2 0 0

200

400 600 Diameter [µm]

800

485 486

(b) Small scale: Dv,0.5 = 295 µm

487

Fig. 5. Droplet size distributions.

488

489

32

1000

490

3. Experimental conditions

491

Table 2 presents the experimental conditions in the fire cooling experiments. The parameters listed

492

in Table 2 are the fire diameter, D, the desired heat release rate, Q, the water spray conditions in both

493

the medium and small scales, and the nozzle height from the burning surface of a fire source, L,

494

defined as the characteristic length. The heat release rates listed in Table 2 were calculated from the

495

heat of combustion of propane gas (∆H = 46 MJ/kg) [18] and the mass flow rate of propane gas

496

assuming 100% combustion efficiency. However, practically, since the values of the heat release rate

497

measured by the oxygen consumption method were smaller than the values listed in Table 2, the

498

combustion efficiency varied in a range from 83 to 98% in the fire cooling experiments. Water spray

499

nozzles UniJet TG1 and TG03 made by Spraying Systems Co., which can satisfy the scaling

500

relationships of the spray angle, flow rate, working pressure, and droplet diameter, were selected

501

under the medium and small scales. However, it is to be noted that TG1 and TG03 are not

502

geometrically similar and as mentioned earlier, it is challenging to commercially source

503

geometrically similar nozzles. The values in parentheses in Table 2 are ideal values derived from the

504

scaling relationships as shown in Table 1. The ranges of the mass flow rate of the exhaust gas in the

505

smoke duct during ‘free burning’ and water spray activation were from 0.15 to 0.19 kg/s in the

33

506

medium scale and from 0.11 to 0.13 kg/s in the small scale. The mass flow rate of the exhaust gas

507

was determined considering the sensitivities of the gas analyzers and differential pressure gauge for

508

the Pitot tube installed in the smoke duct. Furthermore, the mass flow rate of the exhaust gas was set

509

in a way that the average mass flux of the exhaust gas on the suction area (1.6×1.6 m2) in the hood

510

fulfilled the scaling relationship in the medium and small scales. The lowest possible mass flow rate

511

was chosen so as not to affect the spray transport and fire entrainment behaviors.

512

513

In this study, a full-scale (large-scale) fire was postulated as a fire in a tunnel with the ceiling height

514

of 8 m. It was assumed that a water spray was installed under the ceiling (spray height, L = 8 m) and

515

the heat release rate of a fire ranged from about 1.5 to 3.5 MW (corresponding to a small vehicle fire

516

in the tunnel). The flow rate and the droplet median volumetric diameter of the water spray were

517

assumed to be 80 L/min and about 1 mm, respectively. Based on these conditions in full scale, the

518

experimental conditions in the medium and small scales were determined as shown in Table 2. The

519

scale ratio of the medium and small scales to full scale corresponds to 1:6 and 1:12, respectively.

520

The scale ratio between the medium and small scales was 2:1.

521

34

522

Table 2 Experimental conditions in medium and small-scale fire cooling experiments. Scale

M edium

Small S = 2

Fire diameter, D (m)

0.155

0.08 (0.078)

42.9

7.6 (7.6)

34.7

6.1 (6.2)

26.0

4.6 (4.6)

17.4

3.1 (3.0)

Nozzle type

TG1

TG03

Orifice diameter (mm)

0.94

0.51

Spray angle, θ (°)

54

54 (54)

Spray flow rate, V w (L/min)

0.91

0.16 (0.16)

Working pressure, P w (M Pa)

0.36

0.19 (0.18)

Droplet diameter, D v,0.5 (mm)

0.418

0.295 (0.296)

Spray height, L (m)

1.33

0.67 (0.67)

Heat release rate, Q (kW)

523 524

35

525

4. Results and Discussion

526

527

4.1. Distributions of water spray mass flux

528

To identify the distribution characteristics of the water spray nozzles, the distributions of the water

529

spray mass flux discharged from the nozzles TG1 and TG03 were measured. The conditions of the

530

water sprays are listed in Table 2.

531

532

Figure 6 shows the arrangement of the cups measuring the water spray mass flux distribution.

533

Circular plastic cups with inner and outer diameters of 0.056 and 0.062 m were used in the medium

534

scale. On the other hand, square aluminum cups with outer and inner sides of 0.015 and 0.0126 m

535

were used in the small scale. The cups were arranged on a board set up under the nozzle at intervals

536

of every 0.062 and 0.031 m in the medium and small scales, respectively. The heights between the

537

top surface of the cups and the discharging hole on the nozzle face were set to the same heights from

538

the fire source surface, that is, 1.33 and 0.67 m, respectively. A similar technique was used by

539

Mahmud et al. [26] for the water flux measurements.

540

36

541

In the measurement of the water spray mass flux distribution, the activation periods of water spray

542

discharging were continued for 4 and 10 mins for nozzles TG1 and TG03, respectively. The water

543

spray mass flux, m''w, was estimated from the mass of water received by the cup, Mcup, the opening

544

area of the top surface of the cup, Acup, and discharging time, ∆tcup. Equation (28) defines the water

545

spray mass flux:

mw'' = 546

M cup Acup ∆tcup

(28)

547

The orientation of the nozzle tip incorporated in the spray head was changed 90 degrees clockwise

548

every time and measurements were made four times (0, 90, 180, and 270 degrees, with the x axis as

549

0 degrees). The distributions of the water spray mass flux were evaluated as the average distributions

550

of these four measurements. Figure 7 shows the averaging distributions of the water spray mass flux

551

in the medium and small scales. The intersection of the x and y axes in Fig. 7 indicates the position

552

directly below the spray nozzle and the origin of the coordinates in Fig. 1. The averaging

553

distributions of the water spray mass flux showed concentric distributions in both scales, though the

554

pattern was not fully circular. More non-circular patterns were also observed by Mahmud et al. [26].

555

556

Figure 8 shows a comparison of the curves of the water spray mass flux in the medium and small

37

557

scales. These curves were depicted as the average distribution in the circumferential direction of the

558

water spray mass flux distributions obtained from cups arranged every 45 degrees shown in Fig. 6.

559

The measurement uncertainty at a 95% confidence level of the water spray mass flux at each

560

measurement location was estimated and included as error bars in Fig. 8. In an appendix section, we

561

discuss the details of the uncertainty analysis. The water spray mass flux in the small scale was

562

scaled up to match the medium scale using the scaling relationship shown in Table 1. Even though

563

the water flow rate, working pressure, and droplet diameter were selected to scale satisfactorily, as

564

shown in Table 2, the scaled-up water spray mass flux around the center for the small scale was

565

smaller compared to the medium scale. In model experiments of fire phenomena interacting with

566

water sprays, in addition to the scaling of the nozzle operating conditions, simultaneously satisfying

567

scaling of the water spray mass flux distribution is challenging.

568

38

y

x Cup interval

569 570

Fig. 6. Arrangement of the cups for measuring the water spray mass flux distribution.

571 572

(a) Medium scale (0.91 L/min)

39

573 (b) Small scale (0.16 L/min)

575

Fig. 7. Averaging distributions of the water spray mass flux in the medium and small scales.

Spray mass flux S1/2m''w [kg/m2s]

574

Medium (TG1) Small (TG03) S = 2

0.1

0.05

0

0

0.2

0.4 r-axis Sr [m]

0.6

0.8

576 577

Fig. 8. Averaged water spray mass flux distributions scaled on the radius axis.

40

578

4.2 Time history of heat release rate in fire cooling experiments

579

Figures 9 and 10 show the time curves of the heat release rate in the medium and small scales in the

580

fire cooling experiments. In the case of Q = 7.6 kW, since the water flow rate of the spray nozzle of

581

TG03 was gradually increased after 960 s to examine the water flow rate needed for fire extinction,

582

the time history of data after 960 s is omitted in Fig. 10(a). The omitted data is not required for our

583

further analysis. In these figures, Qchem, Qconv, and Qrad are the chemical heat release rate estimated

584

by the oxygen consumption method, the convective heat flow rate calculated from the rise in

585

temperature and the mass flow rate of smoke flowing in the duct, and the radiative heat release rate

586

estimated from the heat flux measured by the radiometer, respectively. The fire cooling rate by water

587

sprays, Qcool, was defined as follows based on the energy balance:

588

Qcool = Qchem − Qconv − Qrad − Qloss

589

where Qloss denotes the rate of heat loss which was transferred from the smoke flow to the hood and

590

lost to the ambient air. In this study, the rate of heat loss, Qloss, was neglected since its value was

591

small, especially during water spray activation. Qgas, shown by the chain line, indicates the

592

theoretical heat release rate estimated from the mass flow rate of propane gas and its heat of

593

combustion assuming 100% combustion efficiency. In other words, Qgas indicates the desired heat

(29)

41

594

release rate defined as experimental conditions, such as the gas flow rate.

595

596

Table 3 shows multiple respective primary data during ‘free burning’ and water spray activation.

597

The combustion efficiency was defined as η = Qchem/Qgas. Since these values were evaluated as

598

average values, a time range of averaging is also shown in Table 3. The value of η in the case of the

599

heat release rate of 17.4 kW in the medium-scale experiment was measured to be about 4–11%

600

lower than the value of η in the other larger fire cases in the medium scale. Similarly, the value of η

601

in the case of the heat release rate of 7.6 kW in the small-scale experiment was measured to be about

602

4–15% lower than the value of η in the other smaller fire cases in the small scale. As the value of η

603

of 7.6 kW in the period of water spray activation was the same as that of ‘free burning’, we can be

604

confident that it was not due to the influence of water spray. When we considered the range of

605

uncertainty in Qchem, we found that the range in Qchem of 17.4 and 7.6 kW overlaps with Qchem in the

606

other fire cases. Furthermore, since the measurement accuracy of the oxygen consumption method

607

itself is about 10% [16], Qchem in the 17.4- and 7.6-kW cases was judged to be appropriate data.

608

609

In the literature, the value of η in the case of propane gas burning is 0.95 [18]. The average values of

42

610

η in all Qchem during ‘free burning’ were 0.90 and 0.90 in the medium and small scales, respectively,

611

and were close to that in the literature. The uncertainty range of η in the small scale was larger than

612

that in the medium scale. The average values of η in all Qchem cases during the water spray activation

613

were 0.91 and 0.87 in the medium and small scales, respectively, and were close to those during

614

‘free burning’. The convective heat flow rate and radiative heat release rate, Qconv and Qrad,

615

decreased in the period of water spray activation. The convective component, Qconv, decreased

616

because the droplets behaved as a heat sink through heat absorption and evaporation. The radiative

617

component, Qrad, decreased because the small droplets attenuated thermal radiation through a

618

combination of scattering and absorption.

619

620

In the cases of Q = 42.9 and 7.6 kW in the medium and small scales, respectively, the flame on the

621

fire source during the water spray activation continued to burn stably like ‘free burning’. Since the

622

flow rates of water spray were small, the buoyancy produced by the flame was sufficiently stronger

623

than the momentum of the downward flow induced by the droplets discharged during the water

624

spray activation.

625

43

626

In the case of Q = 34.7 kW (medium scale), the tip of the flame was occasionally cracked by the

627

downward flow induced by water sprays. However, after cracking the flame immediately returned to

628

the stable burning condition. In the case of Q = 6.1 kW (small scale), it was observed that the length

629

of the flame was slightly shortened, compared to the case of ‘free burning’, by the downward flow

630

induced by water sprays. Under the above-mentioned spray and burning conditions, the chemical

631

heat release rates, Qchem, were not affected in the period of water spray activation.

632

633

In the case of Q = 26.0 kW (medium scale), the flame was completely cracked and the burning

634

surface of the fire source was exposed by the downward flow induced by water sprays. These

635

cracking and exposing phenomena were periodically observed, but the flame could continue to burn.

636

In the case of Q = 4.6 kW (small scale), the length of the flame was shortened by the downward flow

637

induced by water sprays to about half of the case of ‘free burning’.

638

639

In the case of Q = 26.0 kW (medium scale), the flames cracked by the downward flow induced by

640

the water sprays continued burning while adhering to the rim of the gas burner. Part of the cracked

641

flame was occasionally extinguished at the rim, in which case unburned gaseous fuel might leak

44

642

slightly from the unburned rim of the gas burner. Moreover, it is likely that some combustion

643

products might escape from the exhaust collection system since the 26 kW fire was a weak fire

644

condition subjected to water spray. Therefore, Qchem might slightly decrease during the water spray

645

activation. The proof of this phenomenon can be a subject of future works as the attention of this

646

study was focused on scaling, rather than performing highly accurate calorimetry measurements.

647

Furthermore, the decrease in Qchem due to cooling was small and remained within the range of

648

uncertainty. Considering the findings of White [17, 20], which showed no significant reduction in O2

649

consumption or CO2 generation for gaseous fuel flames exposed to extinguishment by either

650

nitrogen dilution of the oxidizer or water mist spray, we can assume that Qchem for a gaseous fuel fire

651

in the case of 26 kW was not affected by water sprays. In the case of Q = 4.6 kW (small scale), Qchem

652

decreased slightly after water spray activation, but gradually recovered from the decrease, therefore,

653

Qchem in time averaging was almost the same as the value during ‘free burning’. Taken together,

654

under these conditions in the medium and small scales (26.0 and 4.6 kW), the chemical heat release

655

rates, Qchem, were not affected in the period of the water spray activation.

656

657

During Q = 17.4 (medium scale) and 3.1 kW (small scale) cases, the flame was immediately and

45

658

completely cracked and extinguished within 30 seconds by the downward flow induced by water

659

sprays. In the case of 17.4 kW (medium scale) as shown in Fig. 9(d), we performed re-ignition with

660

an igniter several times immediately after the flame had been extinguished (while water was

661

discharging from the nozzle), but the flame was extinguished within 30 seconds each time. In cases

662

of the flame being extinguished, Qchem, Qconv, Qrad, and Qcool could not be estimated due to no steady

663

period in Table 3.

664

665

Different qualitative flame burning characteristics were observed as effects of water spray mass flux

666

in the medium and small scales. As the water spray mass flux around the center of the fire source in

667

the small scale was smaller than that in the medium scale, the flame cracking in the small scale was

668

observed only at the lowest heat release rate of 3.1 kW.

669

46

Heat release rate Q (kW)

60 Qchem Qconv Qrad Qcool Qgas

W.S.

50 40 30 20 10 0 0

240

670 671

480 720 Time t (s)

960

1200

(a) Q = 42.9 kW.

Heat release rate Q (kW)

60

40 30 20 10 0 0

672 673

Qchem Qconv Qrad Qcool Qgas

W.S.

50

240

480 720 Time t (s) (b) Q = 34.7 kW.

47

960

1200

Heat release rate Q (kW)

60 Qchem Qconv Qrad Qcool Qgas

W.S.

50 40 30 20 10 0 0

240

674 675

480 720 Time t (s)

960

1200

(c) Q = 26.0 kW.

Heat release rate Q (kW)

60

40 30 20 10 0 0

676 677

678

Qchem Qconv Qrad Qcool Qgas

W.S.

50

240

480 720 Time t (s)

960

1200

(d) Q = 17.4 kW.

Fig. 9. Heat release rates in the medium scale: Vw = 0.91 L/min, Dv,0.5 = 0.418 mm, Lm = 1.33 m.

48

Heat release rate Q (kW)

10 W.S.

8 6

Qchem Qconv Qrad Qcool Qgas

4 2 0 0

240 480 720 960 1200 1440 1680 Time t (s)

679 680

(a) Q = 7.6 kW.

Heat release rate Q (kW)

10 W.S.

8 6 4 2 0 0

240 480 720 960 1200 1440 1680 Time t (s)

681 682

Qchem Qconv Qrad Qcool Qgas

(b) Q = 6.1 kW.

49

Heat release rate Q (kW)

10 W.S.

8 6

Qchem Qconv Qrad Qcool Qgas

4 2 0 0

240 480 720 960 1200 1440 1680 Time t (s)

683 684

(c) Q = 4.6 kW.

Heat release rate Q (kW)

10 W.S.

8 6

Qchem Qconv Qrad Qcool Qgas

4 2 0 0

240 480 720 960 1200 1440 1680 Time t (s)

685 686

687

(d) Q = 3.1 kW.

Fig. 10. Heat release rates in the small scale: Vw = 0.16 L/min, Dv,0.5 = 0.295 mm, Ls = 0.67 m.

688

50

689

Table 3 Primary data and conditions during ‘free burning’ and water spray activation.

Scale

690

Time range (s) m s (kg/s) Q gas (kW) 300 – 420 0.15 42.94 300 – 420 0.16 34.70 Medium 300 – 420 0.17 26.02 300 – 420 0.18 17.35 Average 0.17 300 – 600 0.11 7.59 300 – 600 0.12 6.14 Small 300 – 600 0.11 4.59 300 – 600 0.11 3.06 Average 0.11

Scale

691

Time range (s) m s (kg/s) Q gas (kW) 480 – 600 0.16 42.94 480 – 720 0.17 34.70 Medium 480 – 720 0.18 26.02 – 0.19 17.35 Average 0.18 720 – 960 0.11 7.59 720 – 960 0.13 6.14 Small 720 – 960 0.11 4.59 – 0.12 3.06 Average 0.11

Q chem (kW) 39.04 ± 1.80 32.61 ± 1.87 23.80 ± 1.95 14.47 ± 2.04 6.31 5.68 3.98 3.00

± ± ± ±

1.22 1.41 1.22 1.29

Q chem (kW) 39.56 ± 1.91 32.15 ± 1.96 22.68 ± 2.05 – 6.28 ± 1.23 5.51 ± 1.41 4.01 ± 1.25 –

r e (m) 0.198 0.203 0.210 0.219

m we (kg/s) 0.006724 0.006938 0.007287 0.007738

Water spray Q cool /m we (kJ/kg) 2338 ± 527 1919 ± 430 1321 ± 340 –

Water spray (s) 430-608 428-727 428-720 420-720

0.102 0.103 0.107 0.109

0.000808 0.000826 0.000882 0.000920

1853 ± 1651 1925 ± 1814 1311 ± 1473 –

673-960 673-970 670-960 660-960

Free burning η 0.91 0.94 0.91 0.83 0.90 0.83 0.93 0.87 0.98 0.90

(–) ± 0.04 ± 0.05 ± 0.07 ± 0.12 ± ± ± ±

0.16 0.23 0.27 0.42

Water spray η (–) 0.92 ± 0.04 0.93 ± 0.06 0.87 ± 0.08 – 0.91 0.83 ± 0.16 0.90 ± 0.23 0.87 ± 0.27 – 0.87

692 693

51

Q conv (kW) 23.43 ± 0.48 20.67 ± 0.41 15.84 ± 0.35 11.29 ± 0.27 4.28 3.53 2.69 1.88

± ± ± ±

0.22 0.17 0.16 0.14

Q rad (kW) 11.32 ± 3.90 9.46 ± 3.26 6.90 ± 2.38 4.20 ± 1.45 1.84 1.68 1.17 0.89

± ± ± ±

0.63 0.58 0.40 0.31

k rad (–) 1.06 1.01 1.02 0.91 1.00 0.87 1.01 0.93 1.02 0.96

Q conv (kW) 15.22 ± 0.32 12.37 ± 0.28 9.09 ± 0.25 –

Q rad (kW) 8.62 ± 2.97 6.46 ± 2.23 3.96 ± 1.37 –

Q cool (kW) 15.72 ± 3.54 13.31 ± 2.98 9.62 ± 2.48 –

3.37 ± 0.19 2.52 ± 0.15 1.92 ± 0.14 –

1.41 ± 0.49 1.41 ± 0.49 0.93 ± 0.32 –

1.50 ± 1.33 1.59 ± 1.50 1.16 ± 1.30 –

694

4.3 Fire cooling performance

695

Figure 11 shows a comparison of the fire cooling performance in the medium and small scales. The

696

circles and triangles indicate Qcool in the medium and small scales, respectively. The value of Qcool at

697

the small scale was converted into that at the medium scale with the scaling relationships shown in

698

Table 1. The error bar indicates measurement uncertainty with 95% confidence. Since the

699

measurement uncertainties of Qcool in both scales were of the same order of magnitude, after

700

converting the values at the small scale into those at the medium scale, the ranges of uncertainties at

701

the small scale became larger than those at the medium scale. Figure 11 indicates that the fire

702

cooling performance at the small scale was obviously smaller than that at the medium scale. This is

703

due to the fact that the water spray mass flux distributions in both scales were different, as shown in

704

Figs. 7 and 8. Especially, the water spray mass flux around the center position on the fire source at

705

the small scale was half the value of that at the medium scale. Therefore, at the small scale, the

706

interaction of water sprays with the fire plume and flame on the fire source decreased.

707

52

20

5/2

S Qcool [kW]

15 10 5 0 -5 10

Medium Small S = 2

20

30

40

50

5/2

S Qchem [kW] 708 709

Fig. 11. Relationship between Qcool and Qchem in the medium and small scales with water sprays.

710

Medium: Vw = 0.91 L/min, Dv,0.5 = 0.418 mm, Lm = 1.33 m. Small: Vw = 0.16 L/min, Dv,0.5 = 0.295

711

mm, Ls = 0.67 m.

712

53

713

4.4 Evaluation of cooling performance using effective interaction area

714

In order to reproduce the fire cooling performance in the medium-scale experiment from the

715

small-scale fire experiment, several experimental conditions in both scales (geometry, heat release

716

rate, working pressure, droplet diameter, and water spray mass flux distribution) must sufficiently

717

satisfy the scaling relationships. As shown in Fig. 11, we could not reproduce the fire cooling

718

performance in the medium scale when the result from the small-scale experiment was scaled up.

719

This was due to the insufficient scaling of the water spray mass flux distribution.

720

721

It is obvious that not all the droplets discharged from a water spray nozzle contribute to fire cooling.

722

Especially, in case of the small-scale experiment, it is likely that many droplets with no interaction

723

with the flame fell into the water receiving tank, since the water spray mass flux distribution in the

724

small scale was more uniform than that in the medium scale. Therefore, we introduced the effective

725

interaction area between the water spray and fire plume to take into consideration only the water

726

mass flux that effectively interacted with the fire [27].

727

728

Figure 12 shows a schematic representation of the model of the effective interaction area and the

54

729

physical parameters in the interaction between the water sprays and plume. First, we considered the

730

effective interaction area, Se, formed by the collision of an upward fire plume produced by a fire

731

source and a downward flow induced by water sprays, based on the spray and plume angles, θ and α,

732

as shown in Fig. 12. The radially distributed velocity and temperature profiles were assumed to be of

733

Gaussian distributions [28]. Generally, the relationship between the half-width of a Gaussian

734

distribution, b, and the height of a plume, z, is given by [29]:

735

b = 0.13z

736

In this study, we selected twice the half-width, 2b (95% of the integrated value of the

737

two-dimensional Gaussian distribution), as the radius of the plume that interacted with the water

738

sprays. As a result, it could be assumed that almost all of the upward plume interacted with water

739

sprays when estimating the radius of the effective interaction area:

740

α = 2 tan −1 ( 2b / z ) = 30°

741

As a result, the plume angle was estimated as α = 30°. Then, we estimated the water flow rate

742

formed by the group of water droplets passing through the effective interaction area from the water

743

spray mass flux distribution as shown in Fig. 8. Finally, we defined the water spray mass flow rate as

744

the actual delivery mass flow rate directly contributing to fire cooling. The radius of the effective

(30)

(31)

55

745

interaction area was estimated by:

rw = Lw tan

θ

746

747

2

(32)

rp = ( Lp − Z f 0 ) tan

α 2

(33)

748

where the spray angle, θ, in Table 2 was used for estimating the effective interaction area, and Zf0

749

indicates the virtual origin using the following formula recommended by Heskestad [30]:

750

2/5 Z f 0 = −1.02 D + 0.083Qchem

(34)

751

Taking the condition rw = rp into account, the distance from the nozzle to the effective interaction

752

area and the radius of the effective interaction area are derived as follows:

Lw = 753

( L − Z ) tan α2 f0

θ

re = Lw tan 754

α

tan + tan 2 2

(35)

θ 2

(36)

755

The actual delivery water spray mass flow rate, mwe, on the fire source was estimated by integrating

756

the water spray mass flux distribution as shown in Fig. 8 from the center to the radius of the effective

757

interaction area, re:

758

mwe = 2π ∫ mw′′ rdr

759

When deriving Eq. (37), the spray profile along the distance from the nozzle exit was assumed to be

re

(37)

0

56

760

a cone shape as shown in Fig. 12. In this study, as the effective interaction areas in the medium and

761

small scales were located at about 0.2 and 0.1 m from the nozzle exit, respectively, a cone shape

762

could be expected.

763

764

It was difficult to accurately estimate the effective amount of water that contributed to flame cooling,

765

as the water droplets interact with the flame. In this study, therefore, it was assumed that only water

766

droplets falling in the cylindrical space formed by the space from the effective interaction area to the

767

burning surface of the fire interacted with the flame and plume, and as a result, they evaporated and

768

performed flame cooling. However, some of the water droplets sprayed from the nozzle might pass

769

through the cylindrical space. Although the water droplets interacted with the flame while passing

770

through the cylindrical space, the water droplets fell on the floor in the outer region of the cylindrical

771

space. As a result, the actual delivery water spray mass flow rate estimated from the effective

772

interaction area tends to be underestimated. This error will be high when the spray angle is much

773

larger than the fire plume angle.

774

775

Since the distributions of the water spray mass flux in Fig. 7 were measured under flameless

57

776

conditions, it is likely that the distribution of the water spray mass flux actually changed due to the

777

interaction of sprays with the fire plume. In particular, the falling trajectory of small-diameter

778

droplets (e.g. diameter < 100 µm) is affected by the interaction of sprays with the fire plume.

779

However, as water droplets with small diameters evaporate immediately in the plume region, they

780

contribute to flame cooling although their falling trajectories change. On the other hand, the falling

781

trajectory of the large-diameter droplets is not significantly affected by the interaction. Although the

782

distribution of the water spray mass flux measured under flameless conditions includes the

783

contribution of both small and large diameter droplets, it can be used effectively for estimating the

784

actual delivery water spray mass flow rate contributing to flame cooling under the conditions with

785

flames.

786

787

Figure 13 shows the relationship between Qcool normalized by the actual delivery water spray mass

788

flow rate, mwe, on the effective interaction area and Qchem in the medium and small scales with water

789

sprays. By normalizing the fire cooling rate by the actual delivery water spray mass flow rate, we

790

succeeded in obtaining well-correlated fire cooling performance in both the medium and small scales.

791

It was difficult to completely satisfy the scaling relationships of the water spray and fire conditions

58

792

in both scales; however, introducing the actual delivery water spray mass flow rate could relax the

793

scaling relationship on the water spray mass flux distribution.

794

795

In this study, although the spray working pressure, total water spray flow rate and droplet diameter

796

were scaled correctly, the water spray mass flux distribution near the fire could not be scaled

797

correctly. Therefore, normalizing the fire cooling rate by the actual delivery water spray mass flow

798

rate was introduced for scaling relaxation. On the other hand, if the water spray mass flux

799

distribution near the fire was scaled correctly in addition to the spray working pressure and droplet

800

diameter, the fire cooling rate would have been scaled correctly without normalizing by the actual

801

delivery water spray mass flow rate. In this case, the scaling of the water spray mass flux distribution

802

in areas away from the fire can be relaxed. In the scaling relaxation based on this new perspective,

803

although the spray working pressure, droplet diameter and the water spray mass flux distribution

804

near the fire will be scaled correctly, the total water spray mass flow rate will not be scaled correctly.

805

Scaling relaxation focusing on the scaling of the water spray mass flux distribution near the fire

806

would be also worth investigating as a future research.

807

59

z

Nozzle

2b

Water sprays

Vel. and temp. b profiles

Lw

θ

Se

L α Lp

z

Cylindrical space

D Q r Fire

Zf0

qw’’ Water flux distribution 0

808 809

r

re

Fig. 12. Schematic representation of the model of the effective interaction area.

Qcool /mwe [kJ/kg]

4000 3000

Medium Small S = 2

2000 1000 0

-1000 10

20

30

40

50

5/2

S Qchem [kW] 810 811

Fig. 13. Relationship between Qcool normalized by the actual delivery water spray mass flow rate,

812

mwe, on the effective interaction area and Qchem in the medium and small scales with water sprays.

813 60

814

5. Conclusions

815

Even if the scaling of the water spray flow rate, the droplet diameter, the working pressure, and the

816

heat release rate was satisfactory, when the geometrical scaling of the nozzles was not sufficient, the

817

scaling of the water spray mass flux distributions on the fire sources for both scales was not satisfied.

818

In the scaling of a fire experiment with water sprays, normally, it is quite challenging to sufficiently

819

establish the experimental conditions, especially when nozzles are not geometrically similar. In this

820

study, we conducted a series of medium and small-scale fire cooling experiments and established a

821

new scaling relaxation for scaling of the water spray mass flux distribution. The main conclusions

822

are as follows:

823

(1) The fire cooling performance obtained from the medium-scale experiment could not be

824

reproduced using the small-scale experiment with insufficient scaling of the water spray mass flux

825

distribution.

826

(2) By normalizing the fire cooling rate by the actual delivery water spray mass flow rate, we

827

succeeded in obtaining well-correlated fire cooling performance for both the medium and small

828

scales.

829

(3) Introducing the actual delivery water spray mass flow rate can relax its scaling relationship on

61

830

the water spray mass flux distribution.

831

(4) The actual delivery water spray mass flow rate estimated from the effective interaction area tends

832

to be underestimated when the spray angle is much larger than the fire plume angle.

833

834

The global measurements data with uncertainty described in this paper constitute a useful database

835

for CFD code development and validation for scenarios of fire cooling by water sprays before

836

conducting any parametric or complex study. A number of future experimental studies are also

837

identified.

838

839

Acknowledgments

840

Part of this work was conducted with the support of the JSPS KAKENHI under Grant Number

841

JP16KK0125.

842

62

843

Appendix A. Measurement uncertainty

844

Normally, measurement uncertainty at a 95% confidence level, U, comprises the bias limit, B, the

845

precision index of average, Sx , and Student t value as follows [31]:

846

U = B2 + ( tSx )

847

The bias limit, B, is the estimated value of the upper limit of bias error. The product of the precision

848

index of average and Student t value is the estimated value of the precision error limit. The precision

849

index of average is evaluated as follows:

2

(A.1)

N

x=

∑x

i

i =1

850

N

(A.2) N

Sx = 851

∑( x − x ) i =1

2

i

N ( N − 1)

(A.3)

852

where N is the number of sampling data and x is the sampling data. In the fire experiments, we

853

measured data at 1-s intervals and evaluated the data as the value averaged for 180, 240, and 300

854

seconds. As the number of sampling data was larger than 30, Student t value was evaluated as two.

855

The bias limits were evaluated as half of the measuring precision for each instrument. Table A.1 lists

856

the bias limits for all the instruments, the precision indexes of average for all the measurement

857

values and sensitivity for all the measurements during ‘free burning’ at the heat release rate of 42.9

63

858

kW in the medium scale.

859

860

A1. Convective component of the chemical heat release rate

861

The convective component of the chemical heat release rate was calculated as follows:

862

Qconv = ms Cp _ gas ∆Tgas

863

where ms, Cp_gas, and ∆Tgas are the mass flow rate of the smoke flowing through the smoke duct, the

864

specific heat of mixed exhaust gas at constant pressure, and the rise in temperature of the smoke

865

flow in the duct close to the hood, respectively. The mass flow rate, ms, was estimated from the

866

pressure difference of the Pitot tube installed in the duct and the rise in temperature, ∆Td, in the duct

867

at the installed position of the Pitot tube. The convective component of the chemical heat release rate

868

depended on the input parameters, ∆Tgas, ∆Td, and pressure difference, ∆P, of the Pitot tube as

869

follows:

870

Qconv = Qconv ( ∆Tgas , ∆Td , ∆P)

871

The absolute sensitivity and the relative sensitivity of the convective component to its input

872

quantities are as follows:

θ ∆T = gas

873

(A.4)

(A.5)

∂Qconv ∂∆Tgas

(A.6)

64

∂Qconv ∂∆Td

(A.7)

∂Qconv ∂∆P

(A.8)

θ∆T = d

874

875

θ∆P =

Rθ∆Tgas = 876

Rθ∆Td = 877

Rθ∆P = 878

∂Qconv ∆Tgas ∂∆Tgas Qconv

ave

(A.9)

∂Qconv ∆Td ∂∆Td Qconv

ave

(A.10)

∂Qconv ∆P ∂∆P Qconv

ave

(A.11)

879

Estimating the convective component of the chemical heat release rate based on three parameters,

880

we can represent the bias limit, B, and the precision index of average, Sx , as follows:

881

 B =  θ ∆Tgas B∆Tgas 

882

 Sx =  θ ∆Tgas Sx ∆Tgas 

883

The measurement uncertainty at a 95% confidence level of the convective component of the

884

chemical heat release rate was estimated by using Eq. (A.1).

(

(

) + (θ 2

∆Td

) + (θ

B∆Td

) + (θ

2

∆Td

1/ 2

2

Sx ∆Td

∆P

2 B∆P )  

) + (θ

(A.12) 1/ 2

2

∆P

2 Sx ∆P )  

(A.13)

885

886

A2. Radiative component of the chemical heat release rate

887

The radiative component of the chemical heat release rate was calculated as follows.

888

2 ′ Qrad = 4πrrad krad ( χrad ) qrad

889

where krad is the correction factor obtained from Eq. (20), and q’rad is the radiative heat flux

(A.14)

65

890

measured by the water-cooled radiometer. Furthermore, the correction factor, krad, depended on the

891

radiative fraction of the chemical heat release rate, χrad. The radiative component of the chemical

892

heat release rate depended on the input parameters χrad and q’rad as follows:

893

′ ) Qrad = Qrad ( χrad , qrad

894

The sensitivity of the radiative component to its input quantities can be estimated based on Equation

895

(A.15). The bias limit, B, and the precision index of average, Sx , can be represented as follows:

896

(

(

B = (θχ Bχ ) + θqrad ′ Bqrad ′ 2

(A.15)

))

2 1/2

(A.16)

897

Sx = θqrad ′ Sxqrad ′

898

The measurement uncertainty at a 95% confidence level of the radiative component was estimated

899

by using Eq. (A.1).

(A.17)

900

901

A3. Chemical heat release rate

902

The chemical heat release rate depended on many input parameters, the volume fractions of gases,

903

XO2, XCO2, XCO, XH2O, the rise in temperature of smoke, ∆Td, and the pressure difference of the Pitot

904

tube in the smoke duct, ∆P, as follows:

905

Qchem = Qchem X O2 , X CO2 , X CO , X H2O , ∆Td , ∆P

(

)

(A.18)

66

906

The sensitivity of the chemical heat release rate to its input quantities can be estimated based on

907

Equation (A.18). The bias limit and the precision index of average can be represented as follows:

908

909

((

B = θO2 BO2

((

) ( 2

Sx = θO2 SxO2

+ θCO2 BCO2

) + (θ 2

CO2

)

2

SxCO2

(

+ (θCO BCO ) + θ H2O BH2O 2

) + (θ 2

CO

(

) ( 2

+ θ∆Td B∆Td

SxCO ) + θH2O SxH2O 2

) + (θ 2

∆Td

)

2

+ (θ∆P B∆P )

Sx∆Td

)

2

2

)

1/2

+ (θ∆P Sx∆P )

(A.19) 2

)

1/2

(A.20)

910

The measurement uncertainty at a 95% confidence level of the chemical heat release rate was

911

estimated by using Eq. (A.1).

912

913

Through the fire experiments, we obtained many measurement values: gas concentrations (oxygen,

914

carbon dioxide, carbon monoxide and water vapor), rise in temperature, and pressure difference

915

measured by the Pitot tube in the smoke duct. As the values of the precision index of average of the

916

data measured by instruments were significantly less than the values of the bias limit of the

917

instruments, the measurement uncertainty of the data measured was dominated by the bias limits of

918

the instruments. The chemical heat release rate estimated by the oxygen consumption method was

919

dominated by the bias limit of the oxygen analyzer (POT8000). The effect of other measurement

920

values except for this parameter on the chemical heat release rate was small.

921

67

922

A4. Fire cooling rate

923

The fire cooling rate with uncertainty was estimated from the chemical and radiative heat release

924

rates, the convective heat flow rate, and these uncertainties as follows:

925

Qcool ± UQcool = ( Qchem − Qconv − Qrad ) ± UQ2chem + UQ2conv + UQ2rad

(A.21)

926

927

A5. Water spray mass flux

928

The water spray mass flux, m''w, was estimated as follows:

mw'' = 929

M cup Acup ∆tcup

(A.22)

930

As the contribution of Acup and ∆tcup to uncertainty of water spray mass flux was small compared to

931

Mcup, we only considered the effect of Mcup on the water spray mass flux in the uncertainty analysis.

932

The precision index of average was estimated from 32 data (4×8) except for the center position (4

933

data at the center position), obtained from experiments repeated 4 times and water spray mass flux

934

distributions obtained from cups arranged every 45 degrees as shown in Fig. 6. As the number of

935

data was larger than 30, we could evaluate Student t value as two (Student t value of 3.182 at the

936

center position). The water spray mass flux was dominated by the precision index of average of the

937

mass of water received by the cup, Mcup. The effect of the bias limit of instruments on the water

68

938

spray mass flux was small. The measurement uncertainty at a 95% confidence level of the water

939

spray mass flux was estimated by using Eq. (A.1).

940

941

Table A.1 Uncertainty analysis under the condition of ‘free burning’ (Q = 42.9 kW); parameters,

942

values, absolute sensitivity, relative sensitivity, bias limit, and precision index of average. Note that

943

the values of absolute and relative sensitivities are unique to the specific measurement conditions.

Q

Q conv

Q rad

Parameter

Value

Absolute sensitivity, θ

∆T gas

166 °C

1.6×10

142 °C

−2.8×10

∆P

7.62 Pa

1.5×10

χ q' rad ∆P X X

944

-2

∆T d

∆T d

Q chem

-1

A O2

A

CO2 A X CO S X H2O

0

3.9×10 2

0.85 kW/m 142 °C 7.62 Pa 19.39% 1.15%

Bias limit, B

Precision index of average, ̅ Sx

0

1K

6.79×10 K

-1

1K

4.74×10 K

-1

0.25 Pa

0

0.1

3.24×10 Pa 0

1.1×10

−1.7×10 5.0×10

1

0.29

Relative sensitivity, Rθ

1.0×10

1

0

1.3×10

1.0×10

-2

-1

−4.7×10

−1.7×10

0

-1

2.6×10

5.0×10 3

−2.6×10

2

−5.7×10

1

−1.3×10

-1

−1.7×10

2

−3.1×10

1

−1.1×10

13 ppm

−9.5×10

1.33%

−3.2×10

-4 -2

-1 -1

-4

-2

2

-4

6.25×10

-4

5.0×10

-6

5.0×10

-3

2.0×10

945

946

Appendix B. The model of a primary delay system in the preconditioning process

947

69

-3

2

4.32×10 kW/m 1.25×10 kW/m -1 1K 4.74×10 K -2 0.25 Pa 3.24×10 Pa -5

1.00×10

-6

7.83×10

-6

0.12×10

-5

1.97×10

948

It was assumed that the gas concentration in the air tanks used in the preconditioning process has

949

always spatially uniform distribution. The uniform gas concentration changes over time as an

950

exponential process. The estimation model equation is shown as follows.

951

  w   w    w  X out = 1 − exp  − t  1 − exp  − t   1 − exp  − t   X in      V1    V2    V3   

952

where, Xout and Xin are the volume fractions of input and output gases, V1, V2, and V3 are the internal

953

volume of the first air tank, the air space of the water cooling tank, and the internal volume of the

954

second air tank, w and t are the volume flow rate of gases drawn by the pump and elapsed time,

955

respectively. This equation shows a generic primary delay system [32].

956

70

(B.1)

957

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75

Highlights

1. Fire cooling performance by sprays was examined using model scale experiments.

2. Scaling relaxation was developed for the scaling of the spray mass flux distribution.

3. Scaling relaxation could account for cooling performance under incomplete scaling.

4. Global measurements can be used for CFD validation on the fire cooling by sprays.

Conflict of Interest

There is no conflict of interest in this study.