Geomechanical constitutive modelling of gas hydrate-bearing sediments by a state-dependent multishear bounding surface model

Geomechanical constitutive modelling of gas hydrate-bearing sediments by a state-dependent multishear bounding surface model

Journal Pre-proof Geomechanical constitutive modelling of gas hydrate-bearing sediments by a statedependent multishear bounding surface model Huolang ...

3MB Sizes 0 Downloads 32 Views

Journal Pre-proof Geomechanical constitutive modelling of gas hydrate-bearing sediments by a statedependent multishear bounding surface model Huolang Fang, Kenan Shi, Yang Yu PII:

S1875-5100(19)30371-3

DOI:

https://doi.org/10.1016/j.jngse.2019.103119

Reference:

JNGSE 103119

To appear in:

Journal of Natural Gas Science and Engineering

Received Date: 14 September 2019 Revised Date:

15 November 2019

Accepted Date: 18 December 2019

Please cite this article as: Fang, H., Shi, K., Yu, Y., Geomechanical constitutive modelling of gas hydrate-bearing sediments by a state-dependent multishear bounding surface model, Journal of Natural Gas Science & Engineering, https://doi.org/10.1016/j.jngse.2019.103119. This is a PDF file of an article that has undergone enhancements after acceptance, such as the addition of a cover page and metadata, and formatting for readability, but it is not yet the definitive version of record. This version will undergo additional copyediting, typesetting and review before it is published in its final form, but we are providing this version to give early visibility of the article. Please note that, during the production process, errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. © 2019 Published by Elsevier B.V.

1

Title of paper

2

Geomechanical constitutive modelling of gas hydrate-bearing sediments by a state-dependent

3

multishear bounding surface model

4 5

Author 1

6

Huolang Fang

7

College of Civil Engineering and Architecture, Zhejiang University, 866 Yuhangtang Road,

8

Hangzhou 310058, China

9

Email: [email protected]

10 11

Author 2

12

Kenan Shi

13

College of Civil Engineering and Architecture, Zhejiang University, 866 Yuhangtang Road,

14

Hangzhou 310058, China

15

Email: [email protected]

16 17

Author 3

18

Yang Yu (Corresponding author)

19

Ocean College, Zhejiang University, 1 Zheda Road, Dinghai District, Zhoushan, Zhejiang 316021,

20

China

21

Email: [email protected]

1

22

Abstract

23

Natural gas hydrate in marine sediments and permafrost areas is considered as an important

24

potential energy source. Since hydrate dissociation will reduce the stability of gas hydrate-bearing

25

sediments (GHBS) and may cause wellbore failures and geological disasters during gas production,

26

it is necessary to reveal the mechanical behavior of GHBS for the safe exploitation of natural gas

27

hydrate. This paper proposes a geomechanical constitutive model of GHBS within the multishear

28

bounding surface framework. Following the slip theory of plasticity, a constitutive formulation is

29

obtained by splitting the macro constitutive response of sediments into a macro volume response

30

and a series of micro shear responses in spatial distributions related to virtual microshear structures.

31

Each microshear structure describes micro shear and dilatancy responses in three orthogonal

32

orientations. A micro stress–strain relationship and a micro stress–dilatancy relationship are

33

established for each orientation of the microshear structure. The model comprehensively describes

34

the consolidation, hardening, softening, dilatation, collapse, and non-coaxial characteristics of gas

35

hydrate-bearing sediments by introducing the multishear concept, state parameter, evolution law of

36

hydrate bonding and debonding, and collapse strain caused by hydrate dissociation. The

37

effectiveness of the model is confirmed by simulating the available published laboratory tests on

38

the samples of synthetic and natural GHBS under different pore pressures, temperatures, initial void

39

ratios, hydrate saturations, and initial effective confining stresses.

40

Keywords

41

gas hydrate, mechanical behavior, constitutive model, dilatancy, collapse deformation

2

42

1. Introduction

43

Natural gas hydrate is the crystalline solid where gas molecules are stored in ice-like crystal

44

lattices and is stable under high pressure and low temperature in marine sediments and permafrost

45

areas. The amount of natural gas trapped inside hydrate is roughly evaluated to be twice the existing

46

reserves of conventional fossil fuels in the earth. As a significant potential energy resource, the

47

exploitation of gas hydrate has attracted wide attention. At present, three possible ways to produce

48

gas from gas hydrate-bearing sediments (GHBS) are decompression, heat injection, and chemical

49

stimulation. Gas hydrate is usually located in unconsolidated sediments with low shear strength.

50

Hydrate dissociation will reduce the stability of GHBS due to hydrate exploitation. Particularly,

51

hydrate dissociation in the deep-sea marine sediments may result in wellbore failures and geological

52

disasters, such as casing damage, seafloor deformation, and submarine landslide. Therefore, it is

53

necessary to reveal the mechanical behavior of GHBS for the safe exploitation of natural gas

54

hydrate.

55

Over the past two decades, many experimental researches in the mechanical behavior of synthetic

56

GHBS have been performed (Ebinuma et al., 2005; Masui et al., 2005; Priest et al., 2005, 2009;

57

Clayton et al., 2005, 2010; Yun et al., 2007; Miyazaki et al., 2011; Ghiassian and Grozic, 2013;

58

Hyodo et al., 2013a, 2013b, 2014, 2017; Santamarina et al., 2015; Liu et al., 2016; Yoneda et al.,

59

2016; Kajiyama et al., 2017a, 2017b; Liu et al., 2017; Sultaniya et al., 2018; and Choi et al., 2018).

60

For example, Masui et al. (2005) performed several triaxial compression tests for samples of

61

synthetic GHBS involving different hydrate saturations, and concluded that the stiffness and

62

strength of samples were proportional to the saturation of hydrate. Priest et al. (2005, 2009) studied

63

the impacts of hydrate formation on the wave velocity in samples, revealing that the contact of

64

hydrate-cemented particles significantly enhanced the wave velocity. Miyazaki et al. (2011)

65

performed a set of creep tests in the triaxial apparatus for samples of synthetic GHBS under loading

66

and unloading at a given strain rate, and found that the samples first contracted and then dilated

67

owing to the existence of hydrate. Hyodo et al. (2013a, 2013b, 2014) conducted some triaxial

68

compression tests for the synthetic GHBS with Toyoura sands, and systematically investigated the

69

impacts of initial effective confining stress, pore pressure, hydrate saturation, temperature, and

70

density on the strength and deformation characteristics of GHBS. Kajiyama et al. (2017a, 2017b)

71

carried out several triaxial compression tests for the synthetic GHBS made with glass beads and

72

Toyoura sands, and studied the impact of grain properties on the strain and stress responses of

73

GHBS as well as the bonding and debonding mechanism of hydrate between particles. Hyodo et al. 3

74

(2017) conducted several triaxial compression tests for studying impacts of fines content as well as

75

density on the shear response of hydrate-free sediments and GHBS, and concluded that the increase

76

of fines content significantly enhanced the peak strength and dilative behavior. Choi et al. (2018)

77

experimentally investigated the mechanical response of synthetic GHBS through the triaxial tests of

78

single-stage and multi-stage, focusing on the strength, stiffness, and dilatancy of GHBS during

79

shearing.

80

In addition to the above experimental studies on synthetic GHBS, only a few experiments have

81

been conducted for samples of natural GHBS extracted from gas hydrate deposits due to the

82

difficulty and high cost of in-situ sampling. Winters et al. (2007) conducted several triaxial

83

compression tests for the GHBS extracted from the Mallik 2 L-38, Mackenzie Delta, Canada, and

84

indicated that the GHBS was higher than the natural hydrate-free sample in shear strength. Masui et

85

al. (2008) and Yoneda et al. (2015a, 2015b) investigated the mechanical behavior of GHBS

86

collected from the Eastern Nankai Trough, Japan. More recently, Yoneda et al. (2019) conducted

87

isotropic consolidation tests and triaxial compression tests on the samples of GHBS taken from the

88

Krishna-Godavari Basin, offshore India.

89

At the same time, the mechanical behaviors of GHBS have been investigated theoretically to

90

evaluate the wellbore stability or the submarine slope failure during hydrate dissociation (Sasaki,et

91

al., 2018; Yan et al., 2018; Malagar et al., 2019; Song et al., 2019; Yu et al., 2019). Up to now,

92

different types of constitutive models for GHBS have been presented, such as the nonlinear models

93

by Dai et al. (2012), Miyazaki et al. (2012), Pinkert and Grozic (2014), Pinkert et al. (2015), and

94

Yan et al. (2017), the elasto-plastic models by Klar et al. (2010), Sultan and Garziglia (2011),

95

Uchida et al. (2012, 2016), Sun et al. (2015), Lin et al. (2015, 2017), Shen et al. (2016), Gai and

96

Sánchez (2017), Sánchez et al. (2017), Yan and Wei (2017), and Zhou et al. (2018), the

97

elasto-visco-plastic model by Kimoto et al. (2010), and the hypoplastic model by Zhang (2017). For

98

example, Miyazaki et al. (2012) developed a nonlinear Duncan-Chang type of model for GHBS.

99

Although this model reasonably predicted the mechanical behavior of GHBS in the stiffness and

100

strength, it did not properly describe the volume variation of GHBS during loading and unloading.

101

Uchida et al. (2012, 2016) presented a Cam-clay type of model for GHBS, and verified its modeling

102

ability by comparing with the published test data. Sun et al. (2015) proposed a

103

thermodynamics-based model of GHBS with the concept of critical state, and confirmed that the

104

model well captured the stress softening and dilation behaviors of GHBS under different

105

morphologies and saturations of hydrate. Lin et al. (2015, 2017) proposed a subloading type of 4

106

model within the framework of spatial mobilized plane. The model capability was verified by

107

comparing with the triaxial compression test data of the synthetic and in-situ core specimens under

108

different hydrate saturations and initial effective confining stresses. Shen et al. (2016) developed a

109

state-dependent constitutive equation for GHBS. The simulation result showed that the model

110

reasonably predicted the constitutive response of GHBS at different hydrate saturations, initial

111

effective confining stresses, and void ratios. Gai and Sánchez (2017) and Sánchez et al. (2017)

112

presented the elasto-plastic model of GHBS in the hierarchical single-surface framework, and

113

concluded that the model had a good performance by comparing with the experimental data for the

114

synthetic and natural core samples with different hydrate morphologies, hydrate saturations, and

115

initial effective confining stresses. More recently, Sánchez et al. (2018) applied their constitutive

116

model and THMC to simulate laboratory experiments and field production tests.

117

The above works on GHBS are similar to the experimental, theoretical, and numerical

118

investigations on the fouling of nanoparticles (Nikkhah et al., 2015a, 2015b; Kamalgharibi et al.,

119

2016; Hemmat Esfe et al., 2018) and the CO2 sequestration (Hajirezaie et al., 2015; Rostamian et al.,

120

2016, 2019; Golkhou et al., 2019). They are closely related in thermodynamic properties. In

121

particular, when CO2 is injected into GHBS, the kinetics of CO2-CH4 hydrate in the reservoir

122

strongly depends on the physical mechanism of gas hydrate at the molecular level (Boswell et al.,

123

2017).

124

The existing constitutive models of GHBS are basically based on the coaxial assumption between

125

the directions of principal stress and plastic strain increment, and are mostly state-independent. To

126

overcome these shortcomings, this study presents a state-dependent multishear bounding surface

127

constitutive relation for GHBS. On the basis of plasticity slip theory, the formulation is obtained by

128

splitting a macro constitutive response into a macro volume response and a series of micro shear

129

responses in spatial distributions related to microshear structures. Each microshear structure

130

describes micro shear and dilatancy responses in three orthogonal orientations. A relation of the

131

micro stress–strain and a relation of the micro stress–dilatancy are established for each orientation

132

of the microshear structure. The hydrate-related state parameter and the evolution law of hydrate

133

bonding and debonding are introduced into the model. Moreover, in order to consider the impact of

134

hydrate dissociation on the deformation of GHBS, a simple collapse calculation method is proposed.

135

The validity of the constitutive relation is verified by comparing the calculated values with the test

136

results of GHBS under pore pressures of 8–15 MPa, temperatures of 1–10 °C, initial void ratios of

137

0.5–1.0, hydrate saturations of 0–0.8, and initial effective confining stresses of 1–5 MPa. 5

138

2. Model description

139

2.1. Formulation of multishear model

140

GHBS are assemblages of soil particles with large amounts of different sizes and shapes as well

141

as hydrates hosted in sediments. Soil particles interact with each other and endure external loads.

142

The role of hydrate differs from its accumulation habit. Fig. 1 gives the schematic diagram of the

143

multishear model through a unit sphere that represents the elementary volume of GHBS. There are a

144

number of randomly oriented microcontacts in space (Fig. 1(a)), which contribute to the macro

145

response of GHBS under loading. Following the concept of plasticity slip (Taylor, 1938), a macro

146

constitutive response of GHBS is split into a macro volume response and a series of micro shear

147

responses in spatial distributions related to microcontacts in different directions, in which the micro

148

shear contributes mainly to the macro deviatoric response (Fang et al., 2017; Fang et al., 2019). In

149

principle, this splitting approach somewhat resembles the volumetric-deviatoric decomposition used

150

in the microplane model (Caner and Bažant, 2013). Note that the micro shear here is not defined at

151

the real micro scale, but at the virtual equivalent scale smaller than the macro scale. As shown in

152

Fig. 1(b), for any microcontact colored in orange, a unit normal vector n on the sphere can be

153

found, which is consistent with the normal direction of the microcontact. For each microcontact, a

154

virtual microshear structure is assumed, which has the same direction as the microcontact (Fig. 1(c)).

155

The component in n is expressed with ni , in which the subscript i represents the global

156

coordinate xi . l and m refer to the orthogonal unit vectors, defining two tangential orientations

157

of the microshear structure. The components in l and m are denoted by li and mi , respectively.

158

To establish the relation of the micro shear and macro deviatoric responses, a macro strain is split

159

into the volumetric and deviatoric parts, i.e., ε ij = ε v δ ij / 3 + eij , where ε ij represents the macro

160

strain tensor, ε v = ε ijδ ij refers to the macro volumetric strain, eij represents the macro deviator

161

strain tensor, and δ ij denotes the delta of Kronecker. Generally, projecting a macro deviator strain

162

tensor onto the microcontact forms two tangential strain components corresponding to the l and

163

m directions and one deviatoric normal strain component corresponding to the n direction. As the

164

projected strain components of a macro deviator strain tensor, there is no difference among them

165

except for the direction. Hence, they can all be called micro shear strains, expressed as (see

166

Appendix A.1 for details or Fang et al. (2017))

167

γ ( k ) (n)=N ij( k ) (n )ε ij ( k =1, 2, 3) 6

(1)

168

where (k) denotes the kth component in the microshear structure; 1, 2, and 3 in k mean the

169

directions of l , m , and n in the microshear structure, respectively; γ (k ) (n ) refers to the kth

170

component of a micro shear strain in the microshear structure of the n direction; and N ij(k ) (n )

171

represents the projection tensor for the kth component of a micro shear strain in the microshear

172

structure of the n direction, which is given by equation (A4) in the appendix.

173

The kth component of a micro shear stress is expressed as τ (k ) (n ) in the microshear structure of

174

the n direction and its direction is assumed to be consistent with the corresponding micro shear

175

strain. In general, it is not possible for the micro strain and stress on the microcontact to be the

176

tensor projections for the macro strain and stress, respectively. Hence, a static equilibrium between

177

the macro and micro levels is approximately enforced in terms of the virtual work principle for all

178

strains and stresses. With the hypothesis that all microshear structures are mutually independent as

179

well as the micro strain and stress distribute uniformly in each microshear structure, the increment

180

of macro effective stress is derived as (see Appendix A.1 for details or Fang et al. (2017)) M

181

3

dσ ij = dpδij + ∑∑ 2w(m) Nij(mk )dτ (mk )

(2)

m=1 k =1

182

where w ( m ) denotes the weight coefficient in the mth microshear structure; σ ij represents the

183

macro effective stress tensor; p = σ ii /3 refers to the macro mean effective stress; m = 1, 2, ..., M

184

represent a collection of integral points, each of which corresponds to the microshear structure with

185

the direction of n ( m ) ; M denotes the total integral point number, which is set to 21 for an efficient

186

integration formula with an enough accuracy proposed by Bažant and Oh (1985); and (mk)

187

represents the kth component of a variable in the mth microshear structure with the direction of

188

n ( m ) , such as N ij( mk ) = N ij( k ) (n ( m ) ) and τ ( mk ) = τ ( k ) (n ( m ) ) . Equation (2) indicates that the increment

189

of macro stress consists of a direction-independent volumetric part and a deviatoric part of the

190

summation of micro shear stresses for all microshear structures.

191

2.2. Critical state and state parameter

192

The impact of hydrate on the sediment structure is dependent on the saturation and accumulation

193

habit of hydrate. There exist three main kinds of hydrate morphologies in sediments, i.e., the

194

pore-filling hydrate, the cementing hydrate, and the load-bearing hydrate (Masui et al., 2005), as

195

shown in Fig. 2. The pore-filling hydrate can significantly affect the permeability of sediments,

196

which also affects the mechanical behavior of sediments when the saturation of hydrate is high. 7

197

Particularly, the hydrate becomes the load-bearing hydrate if its saturation rises to the order of 0.3–

198

0.4. The cementing hydrate acts as the bonding material at inter-granular contacts and can

199

significantly increase the strength and stiffness of sediments by bonding near particles. The

200

load-bearing hydrate is a part of the sediment skeleton and can strengthen the skeleton structure of

201

sediments.

202

Hyodo et al. (2013a, 2013b) performed a set of triaxial compression tests for samples of synthetic

203

GHBS to study impacts of pore pressure, temperature, initial void ratio, hydrate saturation, and

204

initial effective confining stress on the deformation and strength behaviors of GHBS. The samples

205

with host sands were made through the partial water saturation approach, which belonged to the

206

cementing hydrate. Fig. 3 illustrates the relationship of the critical void ratio against mean effective

207

stress for synthetic GHBS, indicating that the location of critical state line is significantly affected

208

by the saturation of hydrate. Although the experimental data are somewhat scatted, the linear

209

relationship in the e − ln p plane can be approximately described for samples with any hydrate

210

saturation, where e refers to the void ratio. With the increase of the saturation of hydrate, the

211

critical state line moves upward. The relationship of the critical void ratio against mean effective

212

stress is described by

213

ec = eΓ − λc ln( p / pa )

214

where ec represents the void ratio at a critical state; λc refers to the material constant; pa

215

denotes the atmospheric pressure; and eΓ represents the critical void ratio parameter which

216

depends on the saturation of hydrate, defined as (Shen et al., 2016)

(3)

217

eΓ = eΓ 0 + ac Shnc

218

where eΓ 0 refers to the material parameter for host materials; ac and nc denote material

219

parameters; and S h represents the hydrate saturation. Fig. 4 illustrates the variation of eΓ with the

220

hydrate saturation obtained from Fig. 3, in which its fitting curve is also given.

(4)

221

Fig. 5 shows the relation of the critical stress ratio versus hydrate saturation for synthetic GHBS,

222

where pp and T represent the pore pressure and temperature, respectively. It can be seen from

223

this figure that although the test data are relatively scatted, the trend that the critical stress ratio is

224

directly proportional to the hydrate saturation is very obvious. Therefore, for simplicity, it is

225

assumed that the critical stress ratio increases linearly with the hydrate saturation, given by

226

M c = M c0 (1 + aM Sh )

8

(5)

227

where M c0 and M c represent the critical stress ratios of hydrate-free sediments and GHBS,

228

respectively; and aM denotes the material parameter, reflecting the influence of hydrate on the

229

critical stress ratio.

230

Some studies indicated that the stress and density affect the mechanical behavior of granular soils

231

(Been and Jefferies, 1985; Sun et al., 2008; Zhao and Guo, 2013). Similarly, to consider their

232

impacts in the model, the state parameter ψ for sands (Been and Jefferies, 1985) is applied. This

233

state parameter represents the interval of the critical state and current void ratios at the same mean

234

effective stress, expressed as

ψ = e − ec

235 236

(6)

2.3. Evolution law of hydrate bonding and debonding

237

Similar to cemented soils (Nguyen et al., 2014), the inter-particle bonding of hydrate can be

238

defined by a tensile strength of GHBS. This strength is called the bonding strength, which can be

239

calculated in terms of the experimental data. Fig. 6 illustrates the impact of saturation in hydrate on

240

the peak strength line of GHBS in the p − q plane, where q and qf are the deviator stress and

241

peak strength, respectively. From this figure, it can be observed that the mean effective stress at the

242

deviator stress of zero represents the initial value of the bonding strength, which is dependent on the

243

saturation of hydrate. Therefore, the relation of the initial value of the bonding strength and the

244

saturation of hydrate can be obtained from the test results as plotted in Fig. 6, which is

245

approximately expressed as

pt0 = at Sh

246

(7)

247

where pt0 represents the initial bonding strength; and a t denotes the material parameter. Fig. 7

248

shows the fitting result in the relation of the initial bonding strength versus hydrate saturation.

249

To describe the cementation and deterioration of hydrate during deformation, a simple evolution

250

law for the bonding strength is used, expressed as (Uchida et al., 2012, 2016; Sun et al., 2015; Lin

251

et al., 2015, 2017; Shen et al., 2016; Gai and Sánchez, 2017; Sánchez et al., 2017; Yan and Wei,

252

2017)

dpt = −kt pt dε qp

253

(8)

254

where p t refers to the current bonding strength; k t represents the model parameter reflecting the

255

p debonding rate; and ε q denotes the equivalent plastic shear strain. The integral form of equation

256

(8) is written as 9

pt = pt0 exp(−ktε qp )

257 258

(9)

2.4. Characteristic surfaces and lines

259

To consider the effect of bonding strength in the constitutive relation of GHBS, the macro

260

modified effective stress tensor and mean stress are expressed as σˆ ij = σ ij + ptδ ij and

261

pˆ = p + pt , respectively. Following the bounding surface theory, two types of characteristic

262

surfaces are described, one is conical surface and the other is flat cap. The conical surface depends

263

on the elasto-plastic loading owing to a change in the modified stress ratio defined as

264

rˆij = (σˆ ij − pˆ δij ) / pˆ , and the cap depends on the elasto-plastic loading owing to a change in the

265

modified mean effective stress at a unchanged modified stress ratio. Fig. 8 illustrates four

266

cone-shaped characteristic surfaces whose apexes are located at the origin. The bounding surface

267

represents the condition where the modified stress ratio rises to its peak. The surface of critical state

268

denotes the condition where any change in stress and void does not occur while the plastic shear

269

deformation unceasingly increases. The dilatancy surface refers to the condition where the

270

transformation from contraction to dilation takes place. The surface of maximum stress ratio

271

represents the condition where its maximum value occurs in loading histories. The shapes of four

272

conical surfaces are similar, given by the invariant of the modified stress ratio, the yielding shape

273

function, and their stress ratios at triaxial compression as (Fang et al. 2017)

Fi =Rˆ − Mi g (θˆ) = 0 (i=m, b, c, d)

274

(10)

275

where Fm , Fb , Fc , and Fd refer to the macro maximum stress ratio, bounding, critical state,

276

dilatancy surfaces, respectively; Rˆ represents the macro modified stress ratio, given by

277

Rˆ =

278

and dilatancy stress ratios under the condition of triaxial compression, respectively; and g (θˆ )

279

denotes the yielding shape function; θˆ refers to the angle of Lode. According to equation (10),

280

M m is equal to the maximum value of Rˆ / g (θˆ ) during loading. M d and M b are expressed as

281

(Li, 2002)

282 283

3 / 2rˆij rˆij ; M m , M b , M c , and M d mean the macro maximum, bounding, critical state,

M d = M c exp(ndψ ) , M b = M c exp(−nbψ ) where nd and nb are model constants.

10

(11)

284

To involve the influence of the intermediate principal stress in the model, the yielding criterion of

285

Matsuoka and Nakai (1974) or the yielding criterion of Lade and Duncan (1975) is applied. For the

286

yielding criterion of Matsuoka and Nakai, g (θˆ ) is written as (Matsuoka et al., 1999)

(

1 g (θˆ) = Rˆ 3 6

287

( Iˆ Iˆ − Iˆ ) ( Iˆ Iˆ − 9Iˆ ) − 1) 1 2

3

1 2

(12)

3

288

3 / 6 refer to where Iˆ1 = σˆ ij , Iˆ2 = (σˆ ii2 − σˆ rsσˆ sr ) / 2 , and Iˆ3 = σˆ ijσˆ jkσˆ ki / 3 − σˆ rsσˆ srσˆ mm / 2 + σˆ nn

289

invariants of the modified stress tensor. For the yielding criterion of Lade and Duncan, g (θˆ ) is

290

written as (Yao and Sun, 2000)

291 292

Rˆ  1 ˆ 3 g (θˆ) = I 3 /pˆ 1 − 3 pˆ  2

 1 −1 ˆ 3  cos  3 cos ( − I 3 /pˆ )     

−1

  

−1

(13)

The bounding surface of flat cap is expressed as (Fang et al. 2017)

Fp =pˆ − pˆ m = 0

293

(14)

294

where Fp refers to the bounding surface of flat cap; and pˆ m denotes the maximum modified

295

mean effective stress in loading histories.

296 297

Similarly, four characteristic lines for the kth component in the mth microshear structure, as illustrated in Fig. 9, are expressed as (Fang et al. 2017)

Fi ( mk ) =τ ( mk ) − ri( mk ) pˆ = 0 (i=m, b, c, d)

298

(15)

299

where Fm(mk ) , Fb(mk ) , Fc(mk ) , and Fd(mk ) denote the micro maximum stress ratio, bounding, critical

300

state, and dilatancy lines for the kth component in the mth microshear structure, respectively;

301

r (mk ) = τ (mk ) /pˆ represents the kth component of the micro stress ratio in the mth microshear

302

structure; and rm( mk ) , rb( mk ) , rc( mk ) , and rd( mk ) mean the micro maximum, bounding, critical state,

303

and dilatancy stress ratios for the kth component in the mth microshear structure, respectively.

304

These micro stress ratios correspond to different micro stress states. Their physical meanings are

305

similar to those corresponding to the macro modified stress ratios. According to equation (15),

306

rm( mk ) is set to the maximum value of r (mk ) in loading histories. ri ( mk ) (i=b, c, d) is given by

307

equation (A28) in the appendix.

11

308

2.5. Macro volumetric deformation

309

The macro volumetric strain without that due to dilatancy usually consists of elastic and plastic

310

parts, which depends on the modified mean effective stress. The incremental relationship of them is

311

given by (see Appendix A.2 for details or Fang et al. (2017))

dε v − dε vd =

312

dpˆ 1 1 dpˆ + h( pˆ − pˆ m ) dpˆ Ke Kp dpˆ

(16)

313

where K e denotes the elastic bulk modulus; K p represents the plastic bulk modulus; ε vd refers

314

to the macro volumetric strain due to dilatancy; h represents the Heaviside step function; and

315

refers to the Macaulay brackets.

316

The elastic bulk modulus is given by Ke =

317

1+ e

κ

ˆ a ) 0.5 (1 + aG S h )( pp

(17)

318

where aG refers to the material parameter; the term aG S h represents the influence of hydrate on

319

the modulus of GHBS; and κ denotes the material parameter related to the unloading in isotropic

320

compression, expressed as κ = κ 0 [(1 + e) / (2.97 − e)]2 where κ 0 represents the model constant

321

for host materials.

322 323

The plastic bulk modulus is defined as (Wang et al., 1990)

Kp =

Mc g(θˆ) 1+ e ˆ a )0.5 (1+ aGSh )( pp λ −κ Mc g(θˆ) − Rˆ

(18)

324

where λ represents the material parameter related to the isotropic compression, expressed as

325

λ = λ0 [(1 + e ) / (2.97 − e )]2 where λ0 denotes the model constant for host materials.

326 327

The macro volumetric strain due to dilatancy is the sum of the micro volumetric strains due to dilatancy for all microshear structures, written as (Fang et al., 2017) M

328

3

( mk ) dε vd = ∑ ∑ 2 w( m ) dε vd

(19)

m =1 k =1

329

where ε vd( mk ) denotes the kth component of the micro volumetric strain due to dilatancy in the mth

330

microshear structure. Following the cyclic torsional shear test result of sands, the micro stress–

331

dilatancy relation is given by (Fang et al., 2017)

332

dε vd( mk ) = d1 (±rd( mk ) − r ( mk ) )dγ p(mk )

12

(20)

333

where d1 represents the micro dilatancy parameter, which is assumed to be the same for all

334

microshear structures; ± is set as positive for dγ p(mk ) > 0 and negative for d γ p(mk ) < 0 ; and

335

γ p(mk ) denotes the kth component of the micro plastic shear strain in the mth microshear structure,

336

given by equation (A15) in the appendix.

337

2.6. Micro shear deformation

338

The micro shear strain usually consists of elastic and plastic parts. The former depends on the

339

micro shear stress, and the latter depends on the micro shear stress ratio and modified mean

340

effective stress. According to the plasticity theory of bounding surface (Wang et al., 1990), their

341

incremental correlation is expressed as (see Appendix A.3 for details or Fang et al. (2017))

342

dγ ( mk ) =

1

dτ ( mk ) + ( mk )

Ge

1 Gp( mk )

pˆ dr ( mk ) +

1

h( pˆ − pˆ m ) ( mk )

Hp

dpˆ ( mk ) r dpˆ dpˆ

(21)

343

where γ ( mk ) denotes the kth component of the micro shear strain in the mth microshear structure;

344

Gp(mk ) and H p(mk ) refer to the micro plastic shear moduli related to d r ( mk ) and dpˆ for the kth

345

component in the mth microshear structure, respectively; and Ge(mk ) represents the micro elastic

346

modulus for the kth component in the mth microshear structure, which depends on the macro elastic

347

shear modulus and is given by equation (A29) in the appendix. The macro elastic shear modulus

348

Ge is expressed as (Richart et al., 1970)

349

Ge = G0 (1 + aG S h )

(2.97 − e) 2 ˆ a ) 0.5 ( pp 1+ e

(22)

350

where G0 refers to the elastic shear modulus parameter for host materials; and G0 (1 + aG S h ) = Gh0

351

denotes the elastic shear modulus parameter for GHBS. Fig. 10 shows the Gh0 − S h relationship

352

from the experimental data (Hyodo et al., 2013a, 2013b).

353 354

The micro plastic shear modulus Gp(mk ) related to d r ( mk ) is defined as (Fang et al., 2017)

 r ( mk ) ρ ( mk )  Gp( mk ) = h1Ge(mk )  b( mk ) 1( mk ) −1  rm ρ1 

(23)

355

where h1 denotes the model parameter; ρ1( mk ) = r (mk ) − rr(mk ) represents the interval between the

356

current and back values of the kth micro stress ratio in the mth microshear structure; rr(mk ) denotes

357

the back value of the kth micro back stress ratio in the mth microshear structure, defined as the

358

origin during a virgin loading or the latest inflection location during a reverse loading; and

13

359

ρ1( mk ) = ± rm(mk ) − rr(mk ) represents the interval between the maximum and back values of the kth

360

micro stress ratio in the mth microshear structure, where ± is set as positive for d r ( mk ) > 0 and

361

negative for d r ( mk ) < 0 .

362

The micro plastic shear modulus H p(mk ) related to dpˆ is defined as (Fang et al., 2017)

H

363

( mk ) p

( mk ) ( mk ) c e ( mk )

= h2G

r r

ρ2 ρ2

(24)

364

where h2 denotes the model parameter; ρ 2 = pˆ − pˆ r refers to the interval between the current

365

and back values of the modified mean effective stress; pˆ r represents the back value of the

366

modified mean effective stress, defined as the origin during a virgin loading or the latest inflection

367

location during a reverse loading; and ρ 2 = pˆ m − pˆ r denotes the interval between the maximum

368

and back values of the modified mean effective stress where ρ 2 = pˆ r for d pˆ < 0 .

369

2.7. Collapse deformation due to hydrate dissociation

370

Klar et al. (2010) and Sánchez et al. (2017) proposed different methods to predict the collapse

371

deformation caused by hydrate dissociation. The Klar et al.’s method follows the concept of stress

372

relaxation. Due to the dissociation of hydrate, the effective stress in the hydrate skeleton gradually

373

releases, resulting in the decrease of the total effective stress in the skeleton of GHBS under

374

constant strain. In order to restore the released stress, an additional deformation is required. Because

375

the initial elastic modulus is applied in the Klar et al.’s method, the collapse deformation may be

376

underestimated. To overcome this drawback, an improved method is proposed. During hydrate

377

dissociation without external load, it can be assumed that the sediment is self-balanced through its

378

skeleton structure, and the effective stress remains unchanged from the time of t to the time of t+dt,

379

i.e.,

380

σ ijt = ( K eqε vδ ij + 2Geq eij )t = σ ijt +dt = ( K eqε vδ ij + 2Geq eij )t +dt

381

where the superscripts t and t+dt of a variable represent its values at the time of t and the time of

382

t+dt, respectively; and K eq and Geq denote the equivalent bulk and shear moduli, respectively.

383

Since σ ijt , ε vt , and eijt are known at the time of t, K eqt and Geqt can be approximately obtained

384

by using the linear elastic relationship between the stress and strain. By assuming that the

385

increments of the equivalent bulk and shear moduli are proportional to the variation of hydrate

386

saturation during the time increment of dt, K eqt + dt and Geqt + dt are approximately given by

14

(25)

387

K eqt +dt = K eqt +dK eq = K eqt (1+dSh )

(26)

388

Geqt +dt = Geqt +dGeq = Geqt (1+dSh )

(27)

389 390

From equations (25)–(27), the increment of the collapse strain produced by hydrate dissociation is given by

dε ijdis = ε ijt +dt − ε ijt = −[ pt / (3K eqt )δ ij + (σ ijt − p tδ ij ) / (2Geqt )]dSh / (1 + dSh )

391 392

where ε ijdis refers to the collapse strain caused by hydrate dissociation.

393

2.8. Constitutive formulation

394 395

(28)

The incremental relation of the stress and strain, including the effect of hydrate dissociation, is described as

dσ ij = Dijrs (dε rs − dε rsdis ) − dptδij

396

(29)

397

where Dijrs denotes the macro elasto-plastic stiffness tensor related to macro and micro quantities

398

(see Appendix A.4 for details), which enables the model to involve the influence of micro quantities

399

as well as their evolutions at different directions of microshear structures on the constitutive

400

response of GHBS.

401

3. Parameter calibration

402

The model has 17 parameters, 11 of which are associated with the mechanical behavior of host

403

materials, and the remaining 6 are associated with hydrate. The 11 model parameters for host

404

materials include two elastic modulus parameters ( G0 and κ 0 ), three critical state parameters

405

( M c0 , eΓ 0 , and λ c ), four plastic modulus parameters ( h1 , h2 , nb , and λ0 ), and two dilatancy

406

parameters ( d1 and nd ). These parameters for host materials are determined through the following

407

approaches: (1) G 0 is obtained by the relation between the deviator stress and axial strain for

408

triaxial tests. λ0 and κ 0 are determined by the e − p relations for consolidation tests. κ 0 is

409

also set by κ 0 = 3(1 − 2ν ) / [2(1 + ν ) G 0 ] , where ν refers to the ratio of Poisson; (2) M c0 , eΓ 0 ,

410

and

411

nd = ln( M d / M c ) / ψ d , where ψ d and M d take the values of ψ and stress ratio when the phase

412

transformation takes place, respectively. nb is determined by nb = ln( M c / M b ) / ψ b , where ψ b

413

and M b take the values of ψ and stress ratio when the peak of stress ratio occurs, respectively;

λc

are

directly

determined

by

triaxial

15

test

results;

(3)

nd

is

obtained

by

414

(4) d1 is obtained according to the volumetric and deviatoric strain data of triaxial tests; (5) h1

415

and h2 are set by the trial-and-error procedure to match optimally the model predictions with the

416

test results.

417

The additional 6 parameters for GHBS consist of one elastic modulus parameter ( aG ), three

418

critical state parameters ( ac , nc , and aM ), one bonding strength parameter ( a t ), and one strength

419

deterioration parameter ( k t ). aG is determined in terms of a variation in elastic shear modulus

420

with the saturation of hydrate, as shown in Fig. 10. ac and nc are obtained by the regression of

421

the critical void ratio with a variation in hydrate saturation, as illustrated in Fig. 4. aM is set by

422

defining that the critical stress ratio is dependent on the saturation of hydrate, as shown in Fig. 5.

423

a t for the initial bonding strength is given through the experimental peak strength data for GHBS,

424

as illustrated in Figs. 6 and 7. k t is calibrated by the trial-and-error procedure to simulate the

425

mechanical response of GHBS in tests.

426

4. Model performance

427

The model performance is evaluated by simulating the available experimental results published in

428

literatures. Five sets of triaxial compression tests for GHBS are used. Two sets are the tests for the

429

samples of synthetic GHBS (Masui et al., 2005; Hyodo et al., 2013a), and the other three sets are

430

the tests for the samples of natural GHBS taken from the Eastern Nankai Trough, Japan (Masui et

431

al., 2008; Yoneda et al., 2015b) and the samples of natural GHBS extracted from the Krishna–

432

Godavari Basin, offshore India (Yoneda et al., 2019). Moreover, the hypothetical torsional shear

433

tests during principal stress direction rotations are simulated to investigate the model ability for

434

predicting the non-coaxiality of GHBS. The simulation results are described as follows.

435

4.1. Triaxial compression tests for synthetic GHBS by Masui et al. (2005)

436

Masui et al. (2005) performed drained triaxial compression tests for synthetic cementing and

437

pore-filling types of GHBS, in which the pore-filling type of hydrate formed through the ice-seed

438

approach and the cementing type of hydrate formed through the partial water saturation approach.

439

The host materials were made of Toyoura sands. Tests were carried out under the pore pressure of 8

440

MPa, temperature of 5 °C, initial effective confining stress of 1 MPa. For the pore-filling type of

441

GHBS, the initial void ratio of the samples was 0.736 and the saturation of hydrate was in the extent

442

of 0.264–0.678. For the cementing type of GHBS, the initial void ratio of the samples was 0.605

16

443

and the saturation of hydrate was in the extent of 0.0–0.551. In the tests, the deviator stress response

444

data of all samples were successfully measured, but only the volume change data of the sample with

445

a hydrate saturation of 0.409 for the pore-filling hydrate and the samples with hydrate saturations of

446

0.0 and 0.407 for the cementing hydrate were obtained. The model parameters for host sands and

447

GHBS used in simulations are given in Table 1. Note that ac and nc are set in two regions

448

according to the properties of pore-filling hydrate.

449

Fig. 11 compares the predicted values with the experimental results for the pore-filling type of

450

GHBS, where e0 and p c0 refer to the initial values of the void ratio and effective confining stress,

451

respectively. As can be observed from this figure, most of the predicted deviator stresses and

452

volumetric strains agree well with those of the test data. Only the predicted deviator stress responses

453

for the hydrate saturation of 0.678 are larger than the experimental values when the axial strain

454

exceeds 8%. The experimental deviator stress for the hydrate saturation of 0.678 is quite different

455

from that in other cases. After the axial strain of 8%, its value decreases significantly. The reason

456

for this phenomenon was not explained in the paper of Masui et al. (2005), which may be that the

457

hydrate partially decomposed during the experiment of this case. Fig. 12 compares the calculated

458

values with the test data for the cementing type of GHBS. In the relation of the deviator stress and

459

axial strain, the calculated values are consistent with the test data before the axial strain of 9%, but

460

the calculated values deviate from the test data after the axial strain exceeds 9–12%. In the relation

461

of the volumetric and axial strains, there is a certain difference between the predicted and

462

experimental values, especially for the case with a hydrate saturation of 0.407. Moreover, it can be

463

observed from Figs. 11 and 12 that the peak strength, initial stiffness, and volumetric dilation for

464

the cementing samples are larger than those for the pore-filling samples although their saturations of

465

hydrate are almost the same. The calculated results show that the constitutive relation captures the

466

different behaviors of GHBS for two accumulated types of hydrates, particularly in the deviator

467

stress response, as observed in the tests.

468

4.2. Triaxial compression tests for synthetic GHBS by Hyodo et al. (2013a)

469

Hyodo et al. (2013a) conducted drained triaxial compression tests for synthetic GHBS. Toyoura

470

sands were employed as host materials. The initial void ratio of the samples was in the range of

471

0.629–0.842 and the saturation of hydrate was in the extent of 0.0–0.695. Tests were performed

472

under different pore pressures (5, 10 and 15 MPa), temperatures (1, 5, and 10 °C), and initial

473

effective confining stresses (1, 3, and 5 MPa). The model parameters for host sands and GHBS used

17

474

in simulations are given in Table 1. Fig. 13 compares the predicted values with the test results of

475

GHBS containing different hydrate saturations under the pore pressure of 10 MPa, temperature of

476

5 °C, and initial effective confining stress of 5 MPa. From this figure, it can be observed that the

477

model can generally well predict the variations of the deviator stress and volumetric strain with the

478

axial strain. The simulated and experimental results show that, in addition to the great dilative

479

behavior of the sample containing a high hydrate saturation of 0.531, the samples exhibit the

480

dominant compression in volume and the behavior of strain hardening. Furthermore, the strength

481

and initial stiffness are proportional to the saturation of hydrate.

482

Fig. 14 shows the comparison between the simulated results and test data for GHBS with almost

483

the same hydrate saturation and initial void ratio under different pore pressures (10 and 15 MPa),

484

temperatures (1, 5, and 10 °C), and initial effective confining stresses (1, 3, and 5 MPa). In the

485

relation of the deviator stress and axial strain, the calculated values well consist with the test data

486

for two cases under initial effective confining stresses of 1 and 5 MPa, while the calculated values

487

for the initial effective confining stress of 3 MPa are agreement with the test data under the

488

temperature of 1 °C. In the relation of the volumetric and axial strains, the predicted values are very

489

consistent with the test data under the initial effective confining stress of 1 MPa, while the

490

calculated values are quite different from the test data under initial effective confining stresses of 3

491

and 5 MPa. In addition, when the initial effective confining stress is 3 MPa, the experimental

492

deviator stress responses at 5 and 10 °C are very close, while the experimental deviator stress

493

response at 1 °C is significantly greater than that at other two temperatures; the experimental

494

volume responses at these three temperatures do not change much with temperature. These test

495

results show that the decrease of temperature leads to the nonlinear increase of strength, while the

496

volume deformation is less affected by temperature. In contrast, the simulation results with different

497

temperatures are very close under the same initial effective confining stress because the impact of

498

temperature is not directly considered in this model.

499

4.3. Triaxial compression tests for natural GHBS by Masui et al. (2008)

500

Masui et al. (2008) carried out drained triaxial compression tests for natural GHBS taken from

501

the Eastern Nankai Trough, Japan. The natural GHBS were mainly composed of silty sands. Four

502

samples of the natural GHBS were sheared using the triaxial compression apparatus. The initial

503

void ratios of four samples were 0.792, 0.961, 0.972, and 1.033, respectively. The corresponding

504

saturations of hydrate were 0.376, 0.225, 0.094, and 0.077, respectively. Tests were performed

18

505

under the pore pressure of 9 MPa, temperature of 5 °C, and initial effective confining stress of 1

506

MPa. The model parameters for host sands and GHBS used in simulations are given in Table 1. Fig.

507

15 compares the calculated values with the experimental data at different saturations of hydrate. As

508

can be observed from this figure, the simulated values generally consist with the experimental

509

results in the relation of the deviator stress and axial strain and in the relation of the volumetric and

510

axial strains except for the volumetric strain response of the sample containing a hydrate saturation

511

of 0.094. The experimental and predicted results indicate that the peak value in strength and the

512

initial value in stiffness for natural GHBS are directly proportional to the saturation of hydrate. The

513

higher the saturation of hydrate, the larger the volumetric change of the sample. The sample shows

514

a significant strength reduction and volume change when the saturation of hydrate is equal to 0.376.

515

In contrast, the sample shows a low level of softening and dilative response when the saturation of

516

hydrate is equal to 0.077. For the sample with a constant saturation of hydrate, softening takes place

517

after the peak in strength and its reduction is proportional to the saturation of hydrate.

518

4.4. Triaxial compression tests for natural GHBS by Yoneda et al. (2015b)

519

Yoneda et al. (2015b) performed drained triaxial compression tests for natural GHBS taken from

520

the Eastern Nankai Trough, Japan. The natural GHBS were mainly composed of silty sands. Three

521

samples of the natural GHBS and their reconstituted samples were sheared by using the triaxial

522

compression apparatus. The saturations of hydrate for three samples were 0.38, 0.7, and 0.79,

523

respectively. Two samples with hydrate saturations of 0.38 and 0.79 were successfully tested, but

524

the volume change data for the sample with a hydrate saturation of 0.7 were not obtained due to the

525

liquid leakage in the cell. Therefore, the test for the sample with a hydrate saturation of 0.7 is not

526

simulated because its deviator stress response was also influenced by the liquid leakage. The initial

527

void ratios of all the samples were very similar in the range of 0.645–0.669. Tests were conducted

528

under the pore pressure of about 13 MPa, temperature of 10 °C, and initial effective confining stress

529

of 1.5 or 1.6 MPa. The model parameters for natural GHBS and their reconstituted samples used in

530

simulations are given in Table 1. Fig. 16 compares the calculated values with the experimental data

531

on the responses in deviator stress and volumetric strain for natural GHBS and their reconstituted

532

samples. From this figure, it can be seen that the model performance is generally satisfactory with

533

good predictions in terms of the stiffness and strength behavior as well as in terms of the volume

534

response except for the volumetric strain of the sample containing a hydrate saturation of 0.79. The

535

initial stiffness, peak strength, and residual strength significantly depend on the saturation of

19

536

hydrate. The reconstituted sediments retain the same strength as host silty sands, which is basically

537

consistent with the in-situ strength of hydrate-free sediments. The volumetric strain responses also

538

strongly depend on the saturation of hydrate. The sample with a hydrate saturation of 0.79 exhibits a

539

significant dilative behavior.

540

4.5. Isotropic consolidation tests and triaxial compression tests for natural GHBS by Yoneda et al.

541

(2019a, 2019b)

542

Yoneda et al. (2019a, 2019b) conducted isotropic consolidation tests and drained triaxial

543

compression tests on the natural GHBS extracted from the Krishna–Godavari Basin, offshore India.

544

The natural GHBS were sediments rich in sands. Two types of isotropic consolidation tests for six

545

samples of the natural GHBS with hydrate saturations of 0.321–0.716 were performed by use of a

546

triaxial apparatus. The initial effective confining stress in situ was about 1 MPa. The results of the

547

first type of test are shown in Fig. 17(a), where samples were first loaded from 0.2 to 1 MPa, then

548

hydrates were dissociated, and finally samples were loaded to 12 MPa after hydrate dissociation.

549

The results of the second type of test are shown in Fig. 17(b), where samples were first loaded from

550

0.2 to 5 MPa, then hydrates were dissociated, and finally samples were loaded to 12 MPa after

551

hydrate dissociation. During the tests, unloading and reloading were carried out at different

552

effective confining stresses.

553

The drained triaxial compression tests for five samples of the natural GHBS were performed. The

554

hydrate saturations of five samples were 0.487, 0.552, 0.634, 0.734, and 0.822, respectively. The

555

corresponding initial void ratios were 0.712, 0.634, 0.831, 0.658, and 0.656, respectively. Tests

556

were carried out under the pore pressure of about 10 MPa, temperature of 4 °C, and initial effective

557

confining stress of 1 or 1.1 MPa. The experimental data of the deviator stress response and volume

558

change were successfully measured except for the volume change data of the sample with a hydrate

559

saturation of 0.634. Fig. 18 shows the experimental results of the deviator stress response and

560

volume variation with the axial strain. From this figure, it can be observed that the experimental

561

shear strength and dilation of GHBS were not always proportional to the saturation of hydrate when

562

the saturation of hydrate was relatively high. However, the previous experimental results (Miyazaki

563

et al., 2011; Hyodo et al., 2013a, 2013b) indicated that the strength and dilation of GHBS increased

564

with the enhancement of hydrate saturation. A possible reason for this phenomenon may be the

565

hydrate amount in the samples. The saturations of hydrate in these test samples are relatively high,

566

while the saturations of hydrate in the previous tests samples are usually low. The hydrate particles

20

567

enter into the voids at low saturation of hydrate, while the hydrate particles partially occupy the

568

voids and partially block the contacts of sediment particles at high saturation of hydrate. Therefore,

569

the distribution of hydrate particles in GHBS is related to the amount of hydrate, thereby changing

570

the equivalent skeleton void ratio, which in turn affect the shear strength and dilation of GHBS.

571

Although hydrates and fines are different kinds of materials, this characteristic may be somewhat

572

similar to that of the sand-fines mixtures (Thevanayagam et al., 2002).

573

To consider the above feature in simulations, the hydrate saturation is divided into two intervals,

574

and the equivalent skeleton void ratio parameters are set respectively. The model parameters of the

575

natural GHBS applied in simulations are illustrated in Table 1. Because the sediments of the sample

576

with a hydrate saturation of 0.321 is classified as silt (Yoneda et al., 2019a), κ 0 and λ 0 for this

577

sample are taken to be 0.01 and 0.03, respectively. Fig. 17 compares the model predictions with the

578

experimental data for isotropic consolidation tests. Note that the experimental void ratio at the mean

579

effective stress of 0.2 MPa for the two cases with hydrate saturations of 0.321 and 0.639 is quite

580

different from that in other cases. Therefore, for the simulations of these two cases, the void ratio

581

corresponding to the mean effective stress of 0.2 MPa is inversely determined according to the void

582

ratio at the mean effective stress of 1.0 or 1.1 MPa. It can be seen from Fig. 17 that the volume

583

response predicted by the model basically agree with that observed in the tests. Particularly, the

584

model can reasonably predict the collapse deformation caused by hydrate dissociation, indicating

585

the effectiveness of the proposed collapse calculation method. Fig. 18 shows the predicted and

586

experimental results for triaxial compression tests. From this figure, it can be seen that the

587

calculated values generally consist with the experimental data in the relation between the deviator

588

stress and axial strain and in the relation between the volumetric and axial strains.

589

4.6. Drained torsional tests during principal stress rotations

590

To investigate the ability of the model for predicting the non-coaxiality of GHBS, the drained

591

torsional shear tests under the pure rotation of principal stress directions are simulated. Since this

592

type of test for GHBS has not been reported, the test conditions for simulations are assumed

593

according to the existing triaxial compression tests of GHBS and torsional shear tests of sands. The

594

schematic diagram of the hollow cylindrical sample is showed in Fig. 19. The hydrate saturations of

595

three samples used in simulations are 0.0, 0.3, and 0.6, respectively. The initial void ratio and

596

effective confining stress are equal to 0.65 and 1 MPa, respectively. The pure stress rotation is

597

achieved by varying only the direction of the principal stress while maintaining the other conditions

21

598

unchanged. The mean effective stress, deviator stress, and intermediate principal stress ratio are

599

taken as 1 MPa, 1 MPa, and 0.5, respectively. The model parameters are set to be the same as those

600

applied in the simulation of the Yoneda et al.’s tests (Yoneda et al., 2015b), which are given in

601

Table 1. Fig. 19 shows the predicted variations of all strain components with the principal stress

602

direction during a cycle of continuous principal stress rotations. From this figure, it can be observed

603

that all strain components decrease with the increase of saturation in hydrate, indicating that the

604

strength and stiffness of sediments increase due to hydrate. Figs. 20 and 21 illustrate the predicated

605

stress paths and vectors of the total strain increment, as well as the predicated stress paths and

606

vectors of the plastic strain increment, respectively. The magnitudes of the increment vectors for

607

total and plastic strains in these two figures are define as

(d(ε a − ε θ )) 2 +(2dε aθ ) 2 / ds and

608

(d(ε ap − ε θp )) 2 +(2dε aθp ) 2 / ds , respectively, in which the stress increment ds is expressed as

609

ds = (d((σ a − σ θ ) / (σ a + σ θ ))) 2 +(d(2σ aθ / (σ a + σ θ ))) 2 . From these two figures, it can be observed

610

that with the enhancement of hydrate saturation, the increment in the plastic strain decreases and

611

inclines to the tangential direction along the circle, indicating that the non-coaxiality of GHBS

612

increases. Therefore, it can be said that the present constitutive relation is able to predict the

613

non-coaxial response of GHBS without new parameters.

614

5. Conclusions

615

This paper presented a state-dependent multishear constitutive formulation for predicting the

616

mechanical response of GHBS. The model follows the plasticity theory of bounding surface and

617

accords with the theory of critical state for granular soils. The effectiveness of the model was

618

confirmed by simulating different laboratory tests for synthetic and natural GHBS published in

619

literatures. The following conclusions are obtained:

620

(1) The model formulation was derived by splitting a macro constitutive response of GHBS into a

621

macro volume response and a series of micro shear responses in spatial distributions related to the

622

microshear structures. This splitting approach can provide a simple and effective means to predict

623

the complex three-dimensional constitutive response of GHBS by superposition of a macro

624

response in volume and individual responses of all microshear structures.

625

(2) A state parameter related to the hydrate saturation was introduced into the model, including

626

the joint impact of the effective confining stress and density on the constitutive responses of GHBS.

627

With this state parameter, the model not only accords with the theory of critical state for granular

22

628

soils, but also can capture the contractive and dilative behaviors for loose and dense GHBS in terms

629

of a single set of model parameters.

630

(3) The evolution law of hydrate bonding and debonding related to the plastic shear strain was

631

used to consider the effect of hydrate on the constitutive response of GHBS. This evolution law

632

characterizes the cementing mechanism of hydrate and the degradation of bonding during plastic

633

deformation, respectively.

634

(4) The simple method to calculate the collapse deformation produced by the dissociation of

635

hydrate was proposed. The validity of this method was verified by predicting the volume

636

compression of GHBS observed in the hydrate dissociation tests under constant stress.

637

(5) The comparisons of the experimental and simulated results for different drained laboratory

638

tests of synthetic and natural GHBS were performed. The result confirmed that the developed

639

model can not only predict the constitutive response of GHBS under isotropic consolidation and

640

triaxial compression, but also predict the non-coaxiality of GHBS during the pure rotation of

641

principal stress directions without new parameters. The model is suitable for the case of pore

642

pressures of 8–15 MPa, temperatures of 1–10 °C, initial void ratios of 0.5–1.0, hydrate saturations

643

of 0–0.8, and initial effective confining stresses of 1–5 MPa. However, since temperature is not

644

taken as an independent variable in the present model, and the influence of temperature on the

645

strength of GHBS cannot be ignored, temperature should be directly introduced into the constitutive

646

model in the future.

647

Acknowledgements

648

The authors would like to thank the reviewers for their creative suggestions and professional

649

comments. This work was financially supported by the National Natural Science Foundation of

650

China (No. 51878605 and No. 41807224) and the Zhejiang Provincial National Science Foundation

651

of China (LQ17D020001).

652

Notation

653

ac , aG , aM , at

654

d1

dilatancy parameter

655

Dijrs

stiffness tensor

656

ds

stress increment

657

e , ec , e0

current, critical, and initial void ratios

model parameters

23

658

eij

deviator strain tensor

659

eΓ , eΓ 0

critical state parameters

660

Fb , Fc , Fd , Fm , Fp

661

Fb( mk ) , Fc( mk ) , Fd( mk ) , Fm( mk ) micro characteristic lines

662

Ge , Geq

663

( mk ) G ( mk ) , Ge( mk ) , Gp

664

G0 , G h0

shear modulus parameters

665

g (θˆ )

yield shape function

666

h

Heaviside step function

667

h1 , h2

model parameters

668

H ( mk ) , H p( mk )

micro total and plastic shear moduli

669

Iˆ1 , Iˆ2 , Iˆ3

stress invariants

670

K , Ke , Keq , K p

671

K1

variable

672

kt

model parameter

673

l, m , n

unit vectors

674

M b , M c , M d , M m bounding, critical, dilatancy, and maximum stress ratios

675

M c0

critical stress ratio for host materials

676

n b , nc , nd

model parameters

677

N ij( mk )

projection tensor

678

p , pˆ

mean effective stress and modified mean effective stress

679

pa

atmospheric pressure

680

pc , pc0

current and initial effective confining stresses

681

pˆ m , pˆ r

maximum and back values of modified mean effective stress

682

pp

pore pressure

683

pt0 , pt

initial and current values of hydrate bonding strength

macro characteristic surfaces

elastic and equivalent shear moduli micro total, elastic, and plastic shear moduli

total, elastic, equivalent, and plastic bulk moduli

24

684

q , qf

deviator stress and peak strength

685

Qij , Q ( mk )

variables

686



macro modified stress ratio

687

rˆij

macro modified stress ratio tensor

688

r ( mk )

micro stress ratio

689

rb( mk ) , rc( mk ) , rd( mk ) , rm( mk )

690

rr( mk )

back value of micro stress ratio

691

Sh

hydrate saturation

692

t

time

693

T

temperature

694

w(m)

weight coefficient

695

α

principal angle

696

δ

variation

697

δ ij

Kronecker delta

698

ε ij , ε ijp

total and plastic strain tensors

699

ε ijdis

collapse strain tensor caused by hydrate dissociation

700

ε qp

equivalent plastic shear strain

701

ε v , ε ve , ε vp

total, elastic, and plastic volumetric strains

702

ε vd

volumetric strain caused by dilatancy

703

ε vd( mk )

micro volumetric strain caused by dilatancy

704

ε a , ε r , ε θ , ε aθ

705

ε ap , ε θp , ε apθ

706

γ (mk ) , γ e( mk ) , γ p( mk )

707

κ , κ0

bulk modulus parameters related to isotropic unloading

708

λ , λ0

bulk modulus parameters related to isotropic loading

709

λc

critical state parameter

710

ν

micro bounding, critical, dilatancy, and maximum stress ratios

total strain components

plastic strain components micro total, elastic, and plastic shear strains

Poisson ratio

25

711

θˆ

712

ρ1( mk ) , ρ1( mk ) mapping intervals for micro stress ratio

713

ρ2 , ρ2

714

σ a , σ r , σ θ , σ aθ stress components

715

σ ij , σˆij

effective stress tensor and modified effective stress tensor

716

σ1 , σ 2 , σ3

effective principal stresses

717

σˆ1 , σˆ 2 , σˆ3

modified effective principal stresses

718

τ ( mk )

micro shear stress

719

ψ

state parameter

720



hemisphere surface

721

Lode angle

mapping intervals for modified mean effective stress

Macaulay bracket

722 723

Appendix. Constitutive relation

724

A.1. Multishear model

725 726

By projecting the tensor of the macro deviator strain onto the microcontact, the strain components in the microshear structure of the n direction can be written as 1 2

1 2

727

γ (1) (n ) = (li n j + l j ni )eij = (li n j + l j ni )(ε ij − ε vδ ij / 3) = N ij(1) (n )ε ij

728

γ (2) (n ) = ( mi n j + m j ni )eij = ( mi n j + m j ni )(ε ij − ε vδ ij / 3) = N ij(2) (n )ε ij

729

1 2

1 2

γ (3) (n) = ni n j eij = ni n j (ε ij − ε vδ ij / 3) = N ij(3) (n )ε ij

(A1) (A2) (A3)

730

where γ (1) (n ) and γ (2) (n ) denote the tangential strain components corresponding to the l and

731

m directions, respectively; γ (3) (n ) represents the deviatoric normal strain corresponding to the

732

n direction; and N ij(1) (n ) , N ij(2) (n ) , and N ij(3) (n ) are expressed as

733 734 735

N ij(1) (n ) =

1 1 1 (li n j + l j ni ) , N ij(2) (n ) = (mi n j + m j ni ) , N ij(3) (n ) = ni n j − δ ij 2 2 3

(A4)

According to the virtual work principle, the stress vectors on all microshear structures and the macro stress tensor are variationally enforced, which is written as

26

736 737 738 739 740 741 742

3 4π 4π 1 dσ ij δε ij = dpδε v + 2∫ ∑ dτ ( k ) (n)δγ ( k ) (n)dΩ Ω 3 3 k =1 3

(A5)

where δ denotes a variation; and Ω represents the surface of hemisphere. By substituting δε v = δ ij δε ij and δγ ( k ) (n) = N ij( k ) (n)δε ij into equation (A5) and holding the variational equation for any variation δ ε ij , the macro effective stress increment is given as

dσ ij = dpδij +

3 M 3 1 (k ) (k ) N ( n )d τ ( n )d Ω ≈ d p δ + 2w(m) Nij(mk )dτ (mk ) ∑ ∑∑ ij ij ∫ 2π Ω k =1 m=1 k =1

(A6)

A.2. Stress–strain relation on macro volumetric deformation The increment of the volumetric strain is the sum of the elastic and plastic parts, i.e., dε v =dε ve +dε vp

743

(A7)

744

where ε ve refers to the elastic volumetric strain; and ε vp denotes the plastic volumetric strain that

745

involves the strain due to a variation in mean effective stress and the strain due to dilatancy.

746

Following the elasticity theory, dε ve is expressed as

748

751 752 753 754 755

756 757

(A8)

Following the plasticity theory of bounding surface, dε vp is given by

dεvp =

749 750

1 dpˆ Ke

dε ve =

747

dpˆ 1 h( pˆ − pˆm ) dpˆ + dεvd Kp dpˆ

(A9)

Combing equations (A7)–(A9) yields dε v =

dpˆ 1 1 dpˆ + h( pˆ − pˆ m ) dpˆ + dε vd Ke Kp dpˆ

(A10)

Equation (A10) is rewritten as

dε v =

1 dpˆ +dε vd K

(A11)

where the total bulk modulus K is expressed as  1 dpˆ  1 K = + h ( pˆ − pˆ m )  K dpˆ   e Kp

−1

A.3. Stress–strain relation on micro shear deformation The increment of micro shear strain is the sum of the elastic and plastic parts, i.e.,

27

(A12)

dγ ( mk ) =dγ e( mk ) +dγ p( mk )

758

(A13)

759

where γ e( mk ) denotes the kth component of the micro elastic shear strain in the mth microshear

760

structure.

761

Following the elasticity theory, dγ e( mk ) is expressed as

dγe(mk) =

762 763

dγ p(mk ) =

1 Gp(mk )

pˆ dr (mk ) +

765

Combing equations (A13)–(A15) yields

766

dγ ( mk ) =

768

1 ( mk ) e

G

dτ ( mk ) +

1 ( mk ) p

G

1

h pˆ − pˆ m ) ( mk ) (

Hp

pˆ dr ( mk ) +

1 H

( mk ) p

dpˆ (mk ) r dpˆ dpˆ

h( pˆ − pˆ m )

dpˆ (mk ) r dpˆ dpˆ

(A15)

(A16)

A.4. Macro stress–strain relation Following the definition of r (mk ) , dτ ( mk ) is expressed as



769 770

(A14)

Following the plasticity theory of bounding surface, dγ p( mk ) is given by

764

767

1 dτ (mk) G (mk) e

(mk )

 τ (mk )  = d  pˆ = pˆ dr (mk ) + r(mk )dpˆ   pˆ 

(A17)

Combing equations (A16) and (A17) yields

dτ (mk ) = G(mk )dγ (mk ) + (1 − G(mk ) / H (mk ) )r (mk )dpˆ

771

(A18)

772

where H (mk ) and G (mk ) represent the total micro shear moduli related to d r ( mk ) and dpˆ for the

773

kth component in the mth microshear structure, respectively, define as

774

H

775 776

G

( mk )

 1 1 =  ( mk ) + ( mk )  Ge Gp 

3

dε vd = ∑∑ 2w( m ) d1 (± rd( mk ) − r ( mk ) ){(1 − m =1 k =1

778

 1 dpˆ  1 =  ( mk ) + ( mk ) h ( pˆ − pˆ m )   Ge Hp dpˆ     

−1

(A19)

−1

(A20)

From equations (19), (20), (A13), (A14), and (A18), dε vd is expressed as M

777

( mk )

G ( mk ) 1 G ( mk ) ( mk ) ( mk ) )d γ − (1 − )r dpˆ } Ge( mk ) Ge( mk ) H ( mk )

Substituting equations (A21) into equation (A11) yields

28

(A21)

M

3

dpˆ =K1{dε v − ∑∑ 2 w( m ) d1 (± rd( mk ) − r ( mk ) )(1 − G ( mk ) / Ge( mk ) ) d γ ( mk ) }

779

(A22)

m =1 k =1

780

where K1 is expressed as

K1 =

781

K M

3

1 − K ∑∑ 2 w d1 (± r ( m)

( mk ) d

m =1 k =1

782 783

(A23) )r

( mk )

(1 − G

( mk )

/H

( mk )

( mk ) e

)/G

From equations (1), (2), (A18), and (A22), the macro constitutive relation, including the effect of hydrate dissociation, is written as

dσ ij = Dijrs (dε rs − dε rsdis ) − dptδij

784 785

−r

( mk )

(A24)

where Dijrs is expressed as M

3

Dijrs = K1Qijδ rs + ∑∑ 2 w( m ) (−Q ( mk )Qij + G ( mk ) N ij( mk ) ) N rs( mk )

786

(A25)

m =1 k =1

787

in which M

788

3

Qij = δ ij + ∑∑ 2 w( m ) r ( mk ) (1 − G ( mk ) / H ( mk ) ) N ij( mk )

(A26)

Q ( mk ) = K1d1 ( ± rd( mk ) − r ( mk ) )(1 − G ( mk ) / Ge( mk ) )

(A27)

m =1 k =1

789 790 791

A.5. Relations of micro and macro parameters

792

By assuming that rb( mk ) , rc( mk ) , and rd( mk ) are the same for all microshear structures, they can be

793

determined through the macro model constants and yielding shape function as (Fang et al., 2017),

794

given by

ri ( mk ) =

795

2 3

M i g (θˆ) M

(i=b, c, d)

3

∑∑ 2w

(m)

m =1 k =1

N

(A28)

( mk ) 33

796 797 798 799

By assuming that all microshear structures have the same elastic shear modulus, Ge(mk ) is given by (Fang et al., 2017)

Ge( mk ) =

4 3

Ge M

3

∑∑ 2w

(m)

m =1 k =1

800

29

N

( mk ) 2 33

(A29)

Data Availability Datasets related to this article can be found at http.

References Bažant, Z.P., Oh, B.H., 1985. Microplane model for progressive fracture of concrete and rock. J. Eng. Mech. 111(4), 559–582. Boswell, R., Schoderbek, D., Collett, T.S., Ohtsuki, S., White, M., Anderson, B.J., 2017. The Iġnik Sikumi Field Experiment, Alaska North Slope: Design, operations, and implications for CO2-CH4 exchange in gas hydrate reservoirs. Energy & Fuels 31(1), 140–153. Been, K., Jefferies, M.G., 1985. A state parameter for sands. Géotechnique 35(2), 99–112. Caner, F.C., Bažant, Z.P., 2013. Microplane model M7 for plain concrete. I: Formulation. J. Eng. Mech. 139 (12), 1714–1723. Choi, J.H., Dai, S., Lin, J.H., Seol, Y., 2018. Multistage triaxial tests on laboratory-formed methane hydrate-bearing sediments. J. Geophys. Res. Solid Earth 123, 3347–3357. Clayton, C.R.I., Priest, J.A., Best, A.I., 2005. The effects of disseminated methane hydrate on the dynamic stiffness and damping of a sand. Géotechnique 55(6), 423–434. Clayton, C.R.I., Priest, J., Rees, E., 2010. The effects of hydrate cement on the stiffness of some sands. Géotechnique 60(6), 435–45. Dai, S., Santamarina, J.C., Waite, W.F., Kneafsey, T.J., 2012. Hydrate morphology: Physical properties of sands with patchy hydrate saturation. J. Geophys. Res. 117, B11205. Ebinuma, T., Kamata, Y., Minagawa, W., Ohuma, R., Nagao, J., Narita, H., 2005. Mechanical properties of sandy sediment containing methane hydrate. In Proceedings of the 5th International Conference on Gas Hydrate (pp. 958–961). Trondheim, Norway. Fang, H.L., Zheng, H., Zheng, J., 2017. Micromechanics-based multi-mechanism bounding surface model for sands. Int. J. Plast. 90, 242–266. Fang, H., Shen, Y., and Zhao, Y., 2019. Multishear bounding surface modelling of anisotropic sands accounting for fabric and its evolution. Comput. Geotech. 110, 57–70. Gai, X., Sánchez, M., 2017. A geomechanical model for gas hydrate-bearing sediments. Environ. Geotech. 4(2), 143-156. Ghiassian, H., Grozic, J.L.H., 2013. Strength behavior of methane hydrate bearing sand in undrained triaxial testing. Mar. Petrol. Geol. 43, 310–319.

30

Golkhou, F., Haghtalab, A., 2019. Measurement and thermodynamic modeling of carbon dioxide hydrate formation conditions using dry water through hydrophobic nano silica. J. Nat. Gas Sci. Eng. 68, 102906. Hajirezaie, S., Hemmati-Sarapardeh, A., Mohammadi, A.H., Pournik, M., Kamari, A., 2015. A smooth model for the estimation of gas/vapor viscosity of hydrocarbon fluids. J. Nat. Gas Sci. Eng. 26, 1452–1459. Hemmat Esfe, M., Tatar, A., Ahangar, M., Rostamian, H., 2018. A comparison of performance of several artificial intelligence methods for predicting the dynamic viscosity of TiOC2/SAE 50 nano-lubricant. Phys. E 96, 85–93. Hyodo, M., Yoneda, J., Yoshimoto, N., Nakata, Y., 2013a. Mechanical and dissociation properties of methane hydrate-bearing sand in deep seabed. Soils Found. 53, 299–314. Hyodo, M., Li, Y., Yoneda, J., Nakata, Y., Yoshimoto, N., Nishimura, A., Song, Y., 2013b. Mechanical behavior of gas-saturated methane hydrate-bearing sediments. J. Geophys. Res. Solid Earth 118, 5185–5194. Hyodo, M., Li, Y., Yoneda, J., Nakata, Y., Yoshimoto, N., Nishimura, A., 2014. Effects of dissociation on the shear strength and deformation behavior of methane hydrate-bearing sediments. Mar. Petrol. Geol. 51, 52–62. Hyodo, M., Wu, Y., Nakashima, K., Kajiyama, S., Nakata, Y., 2017. Influence of fines content on the mechanical behavior of methane hydrate-bearing sediments. J. Geophys. Res. Solid Earth 122, 7511–7524. Kajiyama, S., Hyodo, M., Nakata, Y., Yoshimoto, N., Wu, Y., Kato, A., 2017a. Shear behaviour of methane hydrate bearing sand with various particle characteristics and fines. Soils Found. 57, 176–193. Kajiyama, S., Wu, Y., Hyodo, M., Nakata, Y., Nakashima, K., Yoshimoto, N., 2017b. Experimental investigation on the mechanical properties of methane hydrate-bearing sand formed with rounded particles. J. Nat. Gas Sci. Eng. 45, 96–107. Kamalgharibi, M., Hormozi, F., Zamzamian, S.A.H., Sarafraz, M.M., 2016. Experimental studies on the stability of CuO nanoparticles dispersed in different base fluids: Influence of stirring, sonication and surface active agents. Heat Mass Transfer 52(1), 55–62. Kimoto, S., Oka, F., Tomohiko, F., 2010. A chemo-thermo-mechanically coupled analysis of ground deformation induced by gas hydrate dissociation. Int. J. Mech. Sci. 52(2), 365–376.

31

Klar, A., Soga, K., Ng, M.Y.A., 2010. Coupled deformation-flow analysis for methane hydrate extraction. Géotechnique 60(10), 765–776. Lade, P.V., Duncan, J.M., 1975. Elasto-plastic stress–strain theory for cohesionless soil. J. Geotech. Eng. 101(10), 1037–1053. Li, X.S., 2002. A sand model with state-dependent dilatancy. Géotechnique 52(3), 173–186. Lin, J.S., Seol, Y., Choi, J.H., 2015. An SMP critical state model for methane hydrate-bearing sands. Int. J. Numer. Anal. Meth. Geomech. 39(9), 969–987. Lin, J.S., Seol, Y., Choi, J.H., 2017. Geomechanical modeling of hydrate-bearing sediments during dissociation under shear. Int. J. Numer. Anal. Meth. Geomech. 41, 1523–1538. Liu, W., Zhao, T, Luo, Y., Li, Y., Song, Y., Zhu, Y., Liu, Y., Zhao, J., Wu, Z., Xu, X., 2016. Experimental study on the mechanical properties of sediments containing CH4 and CO2 hydrate mixtures. J. Nat. Gas Sci. Eng. 32, 20–27. Liu, Z., Dai, S., Ning, F., Peng, L., Wei, H., Wei, C., 2017. Strength estimation for hydrate-bearing sediments from direct shear tests of hydrate-bearing sand and silt. Geophys. Res. Lett. 45, 715– 723. Malagar, B.R.C., Lijith, K.P., Singh, D.N., 2019. Formation & dissociation of methane gas hydrates in sediments: A critical review. J. Nat. Gas Sci. Eng. 65, 168–184. Masui, A., Haneda, H., Ogata, Y., Aoki, K., 2005. The effects of methane hydrate formation on shear strength of synthetic methane hydrate sediments. In Proceedings of the 5th International Conference on Gas Hydrates (pp. 657–663). Trondheim, Norway. Masui, A., Miyazaki, K., Haneda, H., Ogata, Y., Aoki, K., 2008. Mechanical characteristics of natural and artificial gas hydrate bearing sediments. In Proceedings of the 6th International Conference on Gas Hydrates. Chevron, Vancouver, B. C., Canada. Matsuoka, H., Nakai, T., 1974. Stress-deformation and strength characteristics of soil under three difference principal stresses. Proc. JSCE 232, 59–70. Matsuoka, H., Yao, Y.P., Sun, D.A., 1999. The Cam-clay models revised by the SMP criterion. Soils Found. 39(1), 81–95. Miyazaki, K., Masui, A., Sakamoto, Y., Aoki, K., Tenma, N., Yamaguchi, T., 2011. Triaxial compressive properties of artificial methane-hydrate-bearing sediment. J. Geophys. Res. 116, B06102.

32

Miyazaki, K., Tenma, N., Aoki, K., Yamaguchi, T., 2012. A nonlinear elastic model for triaxial compressive properties of artificial methane-hydrate-bearing sediment samples. Energies 5(10), 4057–4075. Nikkhah, V., Sarafraz, M.M., Hormozi, F., 2015a. Application of spherical copper oxide (II) water nano-fluid as a potential coolant in a boiling annular heat exchanger. Chem. Biochem. Eng. Q. 29(3), 405–415. Nikkhah, V., Sarafraz, M.M., Hormozi, F., Peyghambarzadeh, S.M., 2015b. Particulate fouling of CuO-water nanofluid at isothermal diffusive condition inside the conventional heat exchanger-experimental and modeling. Exp. Therm. Fluid Sci. 60, 83–95. Nguyen, L.D., Fatahi, B., Khabbaz, H., 2014. A constitutive model for cemented clays capturing cementation degradation. Int. J. Plast. 56, 1–18. Pinkert, S., Grozic, J., 2014. Prediction of the mechanical response of hydrate-bearing sands. J. Geophys. Res. Solid Earth 119(6), 4695–4707. Pinkert, S., Grozic, J., Priest, J., 2015. Strain-softening model for hydrate-bearing sands. Int. J. Geomech. 15(6), 04015007. Priest, J.A., Best, A.I., Clayton, C.R.I., 2005. A laboratory investigation into the seismic velocities of methane gas hydrate-bearing sand. J. Geophys. Res. 110, B04102. Priest, J.A., Rees, E.V.L., Clayton, C.R.I., 2009. Influence of gas hydrate morphology on the seismic velocities of sands. J. Geophys. Res. Solid Earth 114, B11205. Richart, F., Hall, J, Woods, R., 1970. Vibrations of soils and foundations. International Series in Theoretical and Applied Mechanics. Englewood Cliffs, NJ, USA: Prentice-Hall. Rostamian, H., Lotfollahi, M.N., 2016. New functionality for energy parameter of redlich-kwong equation of state for density calculation of pure carbon dioxide and ethane in liquid, vapor and supercritical phases. Period. Polytech., Chem. Eng. 60(2), 93–97. Rostamian, H., Lotfollahi, M.N., 2019. A novel statistical approach for prediction of thermal conductivity of CO2 by response surface methodology. Phys. A 527, 121175. Sánchez, M., Gai, X., Santamarina, J.C., 2017. A constitutive mechanical model for gas hydrate bearing sediments incorporating inelastic mechanisms. Comput. Geotech. 84, 28–46. Sánchez, M., Santamarina, C., Teymouri, M., Gai, X., 2018. Coupled numerical modeling of gas hydrate-bearing sediments: From laboratory to field-scale analyses. J. Geophys. Res. Solid Earth 123(10), 326–348.

33

Santamarina, J.C., Dai, S., Terzariol, M., Jang, J., Waite, W.F., Winters, W.J., Suzuki, K., 2015. Hydro-bio-geomechanical properties of hydrate-bearing sediments from Nankai Trough. Mar. Petrol. Geol. 66, 434–450. Sasaki, T., Soga, K., Elshafie, M.E.B., 2018. Simulation of wellbore construction in offshore unconsolidated methane hydrate-bearing formation. J. Nat. Gas Sci. Eng. 60, 312–326. Shen, J., Chiu, C.F., Ng, C.W.W., Lei, G.H., Xu, J., 2016. A state-dependent critical state model for methane hydrate-bearing sand. Comput. Geotech. 75, 1–11. Song, B., Cheng, Y., Yan, C., Ly, Y., Wei, J., Ding, J., Li, Y., 2019. Seafloor subsidence response and submarine slope stability evaluation in response to hydrate dissociation. J. Nat. Gas Sci. Eng. 65, 197–211. Sultan N., Garziglia S., 2011. Geomechanical constitutive modelling of gas-hydrate bearing sediments. In Proceedings of the 7th International Conference on Gas Hydrates. Edinburgh, Scotland, United Kingdom. Sultaniya, A., Priest, J.A., Clayton, C.R.I., 2018. Impact of formation and dissociation conditions on stiffness of a hydrate-bearing sand. Can. Geotech. J. 55, 988–998. Sun, D., Huang, W., Yao, Y., 2008. An experimental study of failure and softening in sand under three-dimensional stress condition. Granular Matter 10, 187–195. Sun, X., Guo, X., Shao, L., Tang, H., 2015. A thermodynamics-based critical state constitutive model for methane hydrate bearing sediment. J. Nat. Gas Sci. Eng. 27, 1024–1034. Taylor, G.I., 1938. The plastic strain of metals. J. Inst. Metals 62, 307–324. Thevanayagam, S., Shenthan, T., Mohan, S., Liang, J., 2002. Undrained fragility of clean sands, silty sands, and sandy silts. J. Geotech. Geoenviron. Eng. 128(10), 849–859. Uchida, S., Soga, K., Yamamoto, K., 2012. Critical state soil constitutive model for methane hydrate soil. J. Geophys. Res. 117, B03209. Uchida, S., Xie, X.G., Leung, Y.F., 2016. Role of critical state framework in understanding geomechanical behavior of methane hydrate-bearing sediments. J. Geophys. Res. Solid Earth 121(8), 5580–5595. Wang, Z.L., Dafalias, Y.F., Shen, C.K., 1990. Bounding surface hypoplasticity model for sand. J. Eng. Mech. 116(5), 983–1001. Winters, W.J., Waite, W.F., Mason, D.H., Gilbert, L.Y., Pecher, I.A., 2007. Methane gas hydrate effect on sediment acoustic and strength properties. J. Petrol. Sci. Eng. 56(1–3), 127–135.

34

Yan, C., Li, Y., Cheng, Y., Wang, W., Song, B., Deng, F., Feng, Y., 2018. Sand production evaluation during gas production from natural gas hydrates. J. Nat. Gas Sci. Eng. 57, 77–88. Yan, G., Cheng, Y., Li, M., Han, Z., Zhang, H., Li, Q., Teng, F., Ding, J., 2017. Mechanical experiments and constitutive model of natural gas hydrate reservoirs. Int. J. Hydrogen Energy 42, 19810–19818. Yan, Y., Wei, C., 2017. Constitutive model for gas hydrate-bearing soils considering hydrate occurrence habits. Int. J. Geomech. 17(8), 04017032. Yao, Y., Sun, D., 2000. Application of Lade’s criterion to Cam-clay model. J. Eng. Mech. 126(1), 112–119. Yoneda, J., Masui, A., Konno, Y., Jin, Y., Egawa, K., Kidab, M., Ito, T., Nagao, J., Tenma, N., 2015a. Mechanical behavior of hydrate-bearing pressure-core sediments visualized under triaxial compression. Mar. Petrol. Geol. 66(2), 451–459. Yoneda, J., Masui, A., Konno, Y., Jin, Y., Egawa, K., Kida, M., Ito, T., Nagao, J., Tenma, N., 2015b. Mechanical properties of hydrate-bearing turbidite reservoir in the first gas production test site of the Eastern Nankai Trough. Mar. Petrol. Geol. 66(2), 471–486. Yoneda, J., Jin, Y., Katagiri, J., Tenma, N., 2016. Strengthening mechanism of cemented hydrate-bearing sand at microscales. Geophys. Res. Lett. 43(14), 7442–7450. Yoneda, J., Oshima, M., Kida, M., Kato, A., Konno, Y., Jin, Y., Jang, J., Waite, W.F., Kumar, P., Tenma, N., 2019a. Pressure core based onshore laboratory analysis on mechanical properties of hydrate-bearing sediments recovered during India's National Gas Hydrate Program Expedition (NGHP) 02. Mar. Petrol. Geol. (In press) Yoneda, J., Oshima, M., Kida, M., Kato, A., Konno, Y., Jin, Y., Tenma, N., 2019a. Consolidation and hardening behavior of hydrate-bearing pressure-core sediments recovered from the Krishna–Godavari Basin, offshore India. Mar. Petrol. Geol. (In press) Yoneda, J., Oshima, M., Kida, M., Kato, A., Konno, Y., Jin, Y., Jang, J., Waite, W.F., Kumar, P., Tenma, N., 2019b. Pressure core based onshore laboratory analysis on mechanical properties of hydrate-bearing sediments recovered during India's National Gas Hydrate Program Expedition (NGHP) 02. Mar. Petrol. Geol. (In press) Yu, T., Guan, G., Abudula, A., Yoshida, A., Wang, D., Song, Y., 2019. Application of horizontal wells to the oceanic methane hydrate production in the Nankai Trough, Japan. J. Nat. Gas Sci. Eng. 62, 113–131.

35

Yun, T.S., Santamarina, C.J., Ruppel, C., 2007. Mechanical properties of sand, silt, and clay containing tetrahydrofuran hydrate. J. Geophys. Res. 112, B04106. Zhang, X., Lin, J., Lu, X., Liu, L., Liu, C., Li, M., Su, Y., 2017. A hypoplastic model for gas hydrate-bearing sandy sediments. Int. J. Numer. Anal. Meth. Geomech. 42, 931–942. Zhao, J., Guo, N., 2013. Unique critical state characteristics in granular media considering fabric anisotropy. Géotechnique 63(8), 695–704. Zhou, M., Soga, K., Yamamoto, K., 2018. Upscaled anisotropic methane hydrate critical state model for turbidite hydrate-bearing sediments at East Nankai Trough. J. Geophys. Res. Solid Earth 123(8), 6277–6298.

36

Table 1 Model parameters Test name Triaxial compression tests for synthetic pore-filling type of GHBS (Masui et al., 2005)

Parameters for host materials G0 =150, κ0 =0.005

Triaxial compression tests for synthetic cementing type of GHBS (Masui et al., 2005)

G0 =150, κ0 =0.005

Triaxial compression tests for synthetic GHBS (Hyodo et al., 2013a)

G0 =200, κ0 =0.004

M c0 =1.47, eΓ 0 =1.126, λ c =0.132 h1 =0.37, h2 =0.35, nb =1.5, λ0 =0.01 d1 =0.7, nd =2.3 M c0 =1.47, eΓ 0 =1.126, λ c =0.132 h1 =0.66, h2 =0.35, nb =1.5, λ0 =0.01

Additional parameters for GHBS aG =3.5, a M =0.038 ac =0.04, nc =0.53 for S h < 0.3 ac =0.39, nc =0.53 for S h ≥ 0.3 a t =0.15MPa, k t =50

aG =2.66, a M =0.071 ac =0.6, nc =2.0 a t =0.7MPa, k t =50

d1 =0.7, nd =4.0 M c0 =1.20, eΓ 0 =1.126, λ c =0.132 h1 =0.55, h2 =0.35, nb =0.8, λ0 =0.008

aG =2.66, a M =0.226 ac =0.6, nc =2.0 a t =0.43MPa, k t =50

d1 =0.6, nd =3.5 Triaxial compression tests for natural GHBS (Masui et al., 2008)

G0 =200, κ0 =0.004 M c0 =1.48, eΓ 0 =1.126, λ c =0.132 h1 =0.55, h2 =0.35, nb =1.0, λ0 =0.008

aG =2.66, a M =0.071 ac =0.37, nc =0.0 a t =0.6MPa, k t =50

d1 =0.7, nd =1.5 Triaxial compression tests for natural GHBS (Yoneda et al., 2015b)

G0 =100, κ0 =0.0075 M c0 =1.44, eΓ 0 =1.126, λ c =0.132 h1 =0.55, h2 =0.35, nb =3.5, λ0 =0.015

aG =1.5, a M =0.157 ac =0.12, nc =0.3 a t =0.6MPa, k t =80

d1 =0.7, nd =3.0 Triaxial compression tests for natural GHBS (Yoneda et al., 2019a, 2019b )

G0 =100, κ0 =0.0075 M c0 =1.2, eΓ 0 =0.8, λ c =0.12 h1 =0.2, h2 =0.35, nb =1.0, λ0 =0.0225 d1 =2.0, nd =1.0

37

aG =1.4, a M =0.125 ac =452.0, nc =13.5 for S h < 0.6 ac =0.13, nc =-3.4 for S h ≥ 0.6 a t =1.7MPa, k t =100

Fig. 1 Illustration of conceptual framework for multishear model

Fig. 2 Schematic diagram of different morphologies for GHBS

38

1.2

Solid lines: regressions Test (Sh=0) Test (Sh=0.242-0.287) Test (Sh=0.311-0.387) Sh=0.439 (average) Test (Sh=0.419-0.450) ec=0.939-0.132lnp 2 Test (Sh=0.504-0.572) R =0.75

Sh=0.532 (average) ec=0.993-0.132lnp 2

R =0.23

Void ratio, e

1.0

0.8 Sh=0 ec=0.823-0.132lnp Sh=0.262 (average) ec=0.865-0.132lnp

2

0.6

R =0.76

2

R =0.55

Sh=0.342 (average) ec=0.894-0.132lnp 2

R =0.68 0.4 1

2

3

4

5

6

7

8

9 10

Mean effective stress, p (MPa)

Fig. 3 Critical state line in e − ln p plane (test data from Hyodo et al., 2013a)

2.0

Critical state void ratio parameter, eΓ

Regression Obtained by fitting lines in Fig.3

1.5

1.0

2

eΓ=1.126+0.6Sh 2

R =0.85 0.5

0.0 0.0

0.2

0.4

0.6

0.8

Hydrate saturation, Sh

Fig. 4 Relationship between critical state void ratio parameter and hydrate saturation (test data from Hyodo et al., 2013a)

39

1.6

Regression Test (pp=10MPa, T= 5 Test (pp= 5MPa, T= 5 Test (pp=15MPa, T=10 Test (pp=15MPa, T= 1

Critical stress ratio, Mc

1.4

) ) ) )

1.2 2

Mc=1.2(1+0.226Sh), R =0.32 1.0

0.8 0.0

0.2

0.4

0.6

0.8

Hydrate saturation, Sh

Fig. 5 Relationship between critical stress ratio and hydrate saturation (test data from Hyodo et al., 2013a)

15

Solid lines: regressions Test (Sh=0.242-0.296) Test (Sh=0.414-0.457) Test (Sh=0.504-0.572)

Deviator stress, q (MPa)

12

Sh=0.532 (average) qf=1.42p+0.35

9

Sh=0.432 (average) qf=1.38p+0.26

2

R =0.95

2

R =0.99

6 Sh=0.267 (average) qf=1.29p+0.11 3

2

R =0.92

0 -2

0

2

4

6

8

10

12

Mean effective stress, p (MPa)

Fig. 6 Peak strength lines of GHBS with different hydrate saturations (test data from Hyodo et al., 2013a)

40

0.4

Initial bonding strength, pt0 (MPa)

Regression Obtained by fitting lines in Fig. 6

0.3

2

pt0=0.43Sh, R =0.96 0.2

0.1

0.0 0.0

0.2

0.4

0.6

0.8

Hydrate saturation, Sh

Fig. 7 Relationship between initial bonding strength and hydrate saturation (test data from Hyodo et al., 2013a)

Fig. 8 Characteristic surfaces in macro stress space

41

Fig. 9 Characteristic lines in τ ( mk ) − pˆ plane

Elastic shear modulus parameter, Gh0

800 Regression Test

600

Gh0=200(1+2.66Sh) 2

R =0.61 400

200

0 0.0

0.2

0.4

0.6

0.8

Hydrate saturation, Sh

Fig. 10 Relationship between elastic shear modulus parameter and hydrate saturation (test data from Hyodo et al., 2013a)

42

10 Simulation Test Sh e0 None 0.678 0.736 None 0.501 0.736 0.409 0.736 None 0.264 0.736

Deviator stress, q (MPa)

8

pc0 (MPa) 1.0 1.0 1.0 1.0

6

4

2

Pore pressure: 8 MPa Temperature: 5

0 0

2

4

6

8

10

12

14

16

Axial strain, εa (%)

-10

Simulation Test Sh e0 None 0.678 0.736 None 0.501 0.736 0.409 0.736 None 0.264 0.736

Volumetric strain, εv (%)

-8

-6

pc0 (MPa) 1.0 1.0 1.0 1.0

Pore pressure: 8 MPa Temperature: 5

-4

-2

0

2 0

2

4

6

8

10

12

14

16

Axial strain, εa (%)

Fig. 11 Test and simulation results for triaxial compression tests of synthetic pore-filling type of GHBS (test data from Masui et al., 2005)

43

10

Simulation Test Sh None 0.551 0.407 None 0.257 0.000

Deviator stress, q (MPa)

8

e0 0.605 0.605 0.605 0.605

pc0 (MPa) 1.0 1.0 1.0 1.0

6

4

2

Pore pressure: 8 MPa Temperature: 5

0 0

2

4

6

8

10

12

14

16

Axial strain, εa (%)

-16

Simulation Test Sh None 0.551 0.407 None 0.257 0.000

Volumetric strain, εv (%)

-12

e0 0.605 0.605 0.605 0.605

pc0 (MPa) 1.0 1.0 1.0 1.0

-8

-4

0

Pore pressure: 8 MPa Temperature: 5

4 0

2

4

6

8

10

12

14

16

Axial strain, εa (%)

Fig. 12 Test and simulation results for triaxial compression tests of synthetic cementing type of GHBS (test data from Masui et al., 2005)

44

16

Deviator stress, q (MPa)

14 12 10 8 6 Simulation Test 4 Pore pressure: 10 MPa Temperature: 5

2

Sh 0.531 0.351 0.242 0.000

e0 0.669 0.645 0.565 0.650

pc0 (MPa) 5.0 5.0 5.0 5.0

0 0

2

4

6

8

10

12

14

16

12

14

16

Axial strain, εa (%)

-8 Simulation Test

Volumetric strain, εv (%)

-6 -4

Sh 0.531 0.351 0.242 0.000

e0 0.669 0.645 0.565 0.650

pc0 (MPa) 5.0 5.0 5.0 5.0

-2 0 2 4 Pore pressure: 10 MPa Temperature: 5

6 8 0

2

4

6

8

10

Axial strain, εa (%)

Fig. 13 Test and simulation results for triaxial compression tests of synthetic GHBS (test data from Hyodo et al., 2013a)

45

Simulation Test

20

e0

0.531 0.537 0.543 0.523 0.516

16

Deviator stress, q (MPa)

Sh

pc0 pp T (MPa) (MPa) ( ) 0.669 5.0 10.0 5.0 0.650 3.0 10.0 5.0 0.650 1.0 10.0 5.0 0.645 3.0 15.0 1.0 0.653 3.0 15.0 10.0

12

8

4

0 0

2

4

6

8

10

12

14

16

12

14

16

Axial strain, εa (%)

-10

Simulation Test

e0

0.531 0.537 0.543 0.523 0.516

-8

Volumetric strain, εv (%)

Sh

-6

pc0 pp T (MPa) (MPa) ( ) 0.669 5.0 10.0 5.0 0.650 3.0 10.0 5.0 0.650 1.0 10.0 5.0 0.645 3.0 15.0 1.0 0.653 3.0 15.0 10.0

-4

-2

0

2

4 0

2

4

6

8

10

Axial strain, εa (%)

Fig. 14 Test and simulation results for triaxial compression tests of synthetic GHBS (test data from Hyodo et al., 2013a)

46

7

Deviator stress, q (MPa)

6

5

4

3

2

Simulation Test Pore pressure: 9 MPa Temperature: 5

1

Sh 0.376 0.225 0.094 0.077

e0 0.792 0.961 0.972 1.033

pc0 (MPa) 1.0 1.0 1.0 1.0

0 0

2

4

6

8

10

12

14

16

12

14

16

Axial strain, εa (%)

-8

Simulation Test

Volumetric strain, εv (%)

-6

Sh 0.376 0.225 0.094 0.077

pc0 (MPa) 1.0 1.0 1.0 1.0

e0 0.792 0.961 0.972 1.033

Pore pressure: 9 MPa Temperature: 5

-4

-2

0

2 0

2

4

6

8

10

Axial strain, εa (%)

Fig. 15 Test and simulation results for triaxial compression tests of natural GHBS (test data from Masui et al., 2008)

47

14 Simulation Test Sample No. 9 No. 7 No. 9-2 No. 7-2

Deviator stress, q (MPa)

12

10

Sh 0.79 0.38 0.00 0.00

e0 pc0 (MPa) 0.650 1.6 0.790 1.5 0.748 1.6 0.887 1.5

8

6

4

2

Pore pressure: 13 MPa Temperature: 10

0 0

2

4

6

8

10

12

14

16

12

14

16

Axial strain, εa (%)

-9 Simulation Test Sample No. 9 No. 7 No. 9-2 No. 7-2

Volumetric strain, εv (%)

-6

Sh 0.79 0.38 0.00 0.00

e0 pc0 (MPa) 0.650 1.6 0.790 1.5 0.748 1.6 0.887 1.5

-3

0

3

6

Pore pressure: 13 MPa Temperature: 10

9 0

2

4

6

8

10

Axial strain, εa (%)

Fig. 16 Test and simulation results for triaxial compression tests of natural GHBS (test data from Yoneda et al., 2015b)

48

0.9

Simulation Test Sample Depth (m) Sh 16B-3P 273.81-273.89 0.321 16B-4P 277.22-277.30 0.716 16B-3P 274.13-274.23 0.601

0.8

Before dissociation

Void ratio, e

0.7

During dissociation 0.6

After dissociation

0.5

0.4

0.3 0.1

1

10

100

Effective confining stress, pc (MPa)

(a) Hydrate dissociation under effective confining stress of 1 MPa 0.9

0.8 Before dissociation

Void ratio, e

0.7

0.6

During dissociation After dissociation

0.5

0.4

0.3 0.1

Simulation Test Sample Depth (m) Sh 16B-7P 287.12-277.20 0.639 16B-3P 274.03-274.13 0.606 23C-11P 285.25-285.33 0.556 1

10

100

Effective confining stress, pc (MPa)

(b) Hydrate dissociation under effective confining stress of 5 MPa Fig. 17 Test and simulation results for isotropic consolidation tests of natural GHBS (test data from Yoneda et al., 2019a)

49

5

Pore pressure: 10 MPa Temperature: 4

Deviator stress, q (MPa)

4

3

2 Simulation Test 1

Sh 0.822 0.734 0.634 0.552 0.487

e0 0.656 0.658 0.825 0.634 0.712

pc0 (MPa) 1.1 1.0 1.0 1.0 1.0

0 0

2

4

6

8

10

12

14

16

12

14

16

Axial strain, εa (%)

-12

Simulation Test

Sh 0.822 0.734 None 0.634 0.552 0.487

Volumetric strain, εv (%)

-8

e0 pc0 (MPa) 0.656 1.1 0.658 1.0 0.825 1.0 0.634 1.0 0.712 1.0

-4

0

4

8

Pore pressure: 10 MPa Temperature: 4

12 0

2

4

6

8

10

Axial strain, εa (%)

Fig. 18 Test and simulation results for triaxial compression tests of natural GHBS (test data from Yoneda et al., 2019b)

50

εa

1.5

εθ

εaθ

εr Sh=0.0 Sh=0.3 Sh=0.6

Strains, εa, εθ, εaθ, εr (%)

1.0

0.5

0.0

-0.5 e0=0.65 pc0=1MPa

-1.0

-1.5 0

30

60

90

120

150

180

Principal stress direction, α (°)

Fig. 19 Predicted strain responses with principal stress direction for drained pure rotational shear tests

51

1.0

e0=0.65 pc0=1MPa

Strain increment Sh=0.0 Sh=0.3 Sh=0.6

σaθ (MPa), 2dεaθ/ds (%)

0.5

0.0

-0.5

1% -1.0 -1.0

-0.5

0.0

0.5

1.0

(σa-σθ)/2 (MPa), (dεa-dεθ)/ds (%)

Fig. 20 Predicted stress paths and strain increment vectors for drained pure rotational shear tests

1.0

e0=0.65 pc0=1MPa

Plastic strain increment Sh=0.0 Sh=0.3 Sh=0.6

p

σaθ (MPa), 2dεaθ/ds (%)

0.5

0.0

-0.5

0.2% -1.0 -1.0

-0.5

0.0

0.5

1.0

(σa-σθ)/2 (MPa), (dε -dεθ )/ds (%) p a

p

Fig. 21 Predicted stress paths and plastic strain increment vectors for drained pure rotational shear tests

52

Highlights •

A geomechanical constitutive model in the multishear bounding surface framework is proposed for gas hydrate-bearing sediments.



A macro constitutive response is decomposed into a macro volume response and a series of micro shear responses in spatial distributions.



The model captures the consolidation, hardening, softening, dilatation, collapse, and non-coaxial behavior of gas hydrate-bearing sediments.

1

Declaration of interests ☒ The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. ☒The authors declare the following financial interests/personal relationships which may be considered as potential competing interests:

None