- Email: [email protected]
Granular detergent compositions
Patent which adsorbs advantageous carbon dioxide
Multiple
the carbon dioxide. The process is particularly when applied to the removal of low levels of from gas streams at temperatures above 20°C.
zeolite
adsorbent
layers
in oxygen
C.F. Watson; RD. Whitley; M.L. Meyer Air Products and Chemicals Inc. U.S. 5529,610, June 25, 1996; Appl. Sept.
separation
7, 1993
An apparatus containing a multilayered zeolite-adsorbent bed and a process for separating oxygen from air by the adsorption of at least nitrogen by the bed are described. The multiple layers of adsorbent are NaX zeolite followed by at least another layer of adsorbent selected from CaX zeolite, LiX zeolite, CaA zeolite followed by CaX zeolite, CaA zeolite followed by LiX zeolite, CaX zeolite followed by LiX zeolite, LiX zeolite followed by CaX zeolite, and MgA zeolite followed by CaX zeolite.
Separation of oxygen lecular sieves
and nitrogen
from
air using
mo-
0. Talu; S.M. Kuznicki Engelhard Corp.; Advanced Manufacturing Center at Cleveland State University PCT Int. Appl. 96,15,842, May 30, 1996; U.S. Appl. Nov. 18, 1994 A process is disclosed for selectively adsorbing nitrogen from another less strongly adsorbed gas (particularly oxygen), involving contacting the gas mixture in an adsorption zone with an adsorbent consisting of a large-pored molecular sieve containing at least one octahedral site comprising titanium and at least silicon as a tetrahedral site. The process is particularly useful in air separation using ETS-10 as the adsorbent.
DETERGENTS High bulk density
granular
detergent
S. Takahashi; T. Sato; M. Shiobara Lion Corp. Jpn. Kokai Tokkyo Koho 96,73,888, 1994
compositions
Mar.
19, 1996;
Appl.
Sept.
9,
High bulk density (20.5 g/cmd3) granular detergent compositions with excellent solubility are manufactured by spray drying and granulation of a slurry of a-sulfofatty ester salts (l-15%), alkylbenzenesulfonates, u-olefinsulfonates, or alkyl sulfates (325%), carbonates (20-45%), and bicarbonates (0.5-8%). or by neutralization of linear alkylbenzenesulfonates with carbonate salts and optionally alkali metal hydroxides, adding u-sulfofatty acid ester and zeolite-containing (lo-25% zeolite) detergents to the resulting salts, and spray drying and granulation.
Granular
detergent
compositions
F.-L.G. Hus; W.J. Lunsmann; J.H.M. Akkermans et al. Unilever P/c; Unilever N. V. PCT Int. Appl. 96,10,071, Apr. 4, 1996; U.S. Appl. Sept.
29, 1994
Highly active granular detergent compositions having 240% surfactant and a bulk density 2650 g/l are obtained by a process involving the single step of higher shear mixing until granular at a temperature range from ambient to 60°C of a binder component (the surfactant and ~20% water), with a crystalline zeolite of initial particle size 0.1 to about 500 km (having 215% of particles with a size of 250 +m and a sufficient amount of smaller particles so that the average surface area of the zeolite is 29 m2/g as measured by the BET method). The binder maintains the mixture in a particulate state throughout the process.
Easy to dispense D.M. Flower Amway Corp. Eur. Pat. Appl.
powder
710,717,
May
detergent
8, 1996;
composition
Appl.
Nov.
the content of fatty acid and fatty alcohol is preferably 9-12% and the ratio of fatty acid to fatty alcohol is preferably 0.91.05:1. Preferably, the builder is a water-insoluble zeolite, the fatty acid is stearic acid, and the fatty alcohol is cetyl alcohol. The surfactant mixture enhances the dispensability of the composition for use in washing machines with side-flush dispensers.
Bleaching detergent sodium percarbonate solubility
4, 1994
A granular detergent composition contains at least one nonionic surfactant, 12.5-60%, a granular base containing at least one builder, IO-85%, impregnated with a mixture of the nonionic surfactant, at least one fatty acid, 0.5-5%, and at least one fatty alcohol, 0.5-5%. The granular base particles are impregnated first with the nonionic surfactant, then with the mixture where
compositions with good
containing coated storage stability and
M. Aoyanagi; Y. Yamaguchi; N. Ogura Kao Corp. Jpn. Kokai Tokkyo Koho 96,92,593; 96,92,594; 1996; Appls. Sept. 22, 1994
96,92,595,
Apr.
9,
The laundry detergent compositions contain 2-30% Cs-,, fatty acid lower alkyl ester sulfonate salts, O&30% Na percarbonate coated with film-forming polymers or inorganic salts, and O.l10% organic peracid precursors (RCO,C,H,SO,),M (R = C,_,, alkyl; M = Na, K, Mg; n is 1 when M is Na or K and n is 2 when M is Mg), and they optionally contain l-50% of crystalline alkali metal silicates and l-50% of aluminosilicate salts (zeolite 4A).
Nonionic powdered laundry detergent with excellent solubility and dispersibility
compositions
M. Hasumi; J. Sakamoto; Y. Koyama et al. Kao Corp. Jpn. Kokai Tokkyo Koho 96,92,591, Apr. 9, 1996; Appl. Sept. 22, 1994 The title compositions contain nonionic surfactants (m.p. J4O”C) 12-35%, aluminosilicates (zeolite A) IO-60%. and water soluble olefin-unsaturated dicarboxylic anhydride copolymers or their salts O.Ol-5%.
Tablet
et al.
report
detergent
compositions
S.J. Edwards; P. Farnworth; Unilever N. V.; Unilever Pk. Eur. Pat. Appl. 711,827, May Tablet detergent ticulate detergent tive compounds coconut alcohols), (e.g., zeolite A), (e.g., Na citrate). let and dissolution added to water.
Liquid laundry surfactants
PC.
Knight
et al.
15, 1996;
U.K. Appl.
Nov.
14, 1994
compositions are prepared by compacting parcompositions containing 5-60% detergent ac(e.g., coconut primary alkyl sulfate, ethoxylated 15-60% aluminosilicate detergency builders and citrates with solubility in water of 50-100 g/l This improves disintegration of the whole tabof its soluble ingredients when the tablet is
detergent
P.C. Hu; E.W. Liimatta Albemarle Corp. PCT Int. Appl. 96,18,713,
formulations
June
20, 1996;
of zeolites
U.S. Appl.
and
Dec. 15, 1994
Aqueous liquid detergents that do not require polymeric thickeners to attain viscosity 51,000 mPa comprise 5-45% of suspended zeolite particles (zeolite A or X or a mixture of A and X), IO-30% of a C,,,-,, (preferably Na (I,,-,,) alkylbenzene sulfonate/nonionic surfactant admixture, 0.5-4.5% builder (sodium citrate), and 35-80% water. For example, formulations containing Na dodecylbenzenesulfonate, a 7-ethoxylate of C,,_,, alcohols, Na citrate, water and IO-15% suspended zeolite content were stable in storage for 2 months.
Granular leakage
detergent
composition
G.M. Bailelly Procter and Gamble Co. Eur. Pat. Appl. 684,301, Nov.
29, 1995;
with
reduced
U.K. Appl.
perfume
Apr.
28, 1994
A granular detergent composition is disclosed comprising a surfactant, soluble capsules of perfume, and a detergency builder being zeolite P having a silicon to aluminum atomic ratio not greater than 1.33, preferably not greater than 1.07 (zeolite MAP). The composition preferably has a bulk density of at least 650 g/l and may optionally contain percarbonate. The use of
Zeolites
18:417-421,
1997
419
Multiple
the carbon dioxide. The process is particularly when applied to the removal of low levels of from gas streams at temperatures above 20°C.
zeolite
adsorbent
layers
in oxygen
C.F. Watson; RD. Whitley; M.L. Meyer Air Products and Chemicals Inc. U.S. 5529,610, June 25, 1996; Appl. Sept.
separation
7, 1993
An apparatus containing a multilayered zeolite-adsorbent bed and a process for separating oxygen from air by the adsorption of at least nitrogen by the bed are described. The multiple layers of adsorbent are NaX zeolite followed by at least another layer of adsorbent selected from CaX zeolite, LiX zeolite, CaA zeolite followed by CaX zeolite, CaA zeolite followed by LiX zeolite, CaX zeolite followed by LiX zeolite, LiX zeolite followed by CaX zeolite, and MgA zeolite followed by CaX zeolite.
Separation of oxygen lecular sieves
and nitrogen
from
air using
mo-
0. Talu; S.M. Kuznicki Engelhard Corp.; Advanced Manufacturing Center at Cleveland State University PCT Int. Appl. 96,15,842, May 30, 1996; U.S. Appl. Nov. 18, 1994 A process is disclosed for selectively adsorbing nitrogen from another less strongly adsorbed gas (particularly oxygen), involving contacting the gas mixture in an adsorption zone with an adsorbent consisting of a large-pored molecular sieve containing at least one octahedral site comprising titanium and at least silicon as a tetrahedral site. The process is particularly useful in air separation using ETS-10 as the adsorbent.
DETERGENTS High bulk density
granular
detergent
S. Takahashi; T. Sato; M. Shiobara Lion Corp. Jpn. Kokai Tokkyo Koho 96,73,888, 1994
compositions
Mar.
19, 1996;
Appl.
Sept.
9,
High bulk density (20.5 g/cmd3) granular detergent compositions with excellent solubility are manufactured by spray drying and granulation of a slurry of a-sulfofatty ester salts (l-15%), alkylbenzenesulfonates, u-olefinsulfonates, or alkyl sulfates (325%), carbonates (20-45%), and bicarbonates (0.5-8%). or by neutralization of linear alkylbenzenesulfonates with carbonate salts and optionally alkali metal hydroxides, adding u-sulfofatty acid ester and zeolite-containing (lo-25% zeolite) detergents to the resulting salts, and spray drying and granulation.
Granular
detergent
compositions
F.-L.G. Hus; W.J. Lunsmann; J.H.M. Akkermans et al. Unilever P/c; Unilever N. V. PCT Int. Appl. 96,10,071, Apr. 4, 1996; U.S. Appl. Sept.
29, 1994
Highly active granular detergent compositions having 240% surfactant and a bulk density 2650 g/l are obtained by a process involving the single step of higher shear mixing until granular at a temperature range from ambient to 60°C of a binder component (the surfactant and ~20% water), with a crystalline zeolite of initial particle size 0.1 to about 500 km (having 215% of particles with a size of 250 +m and a sufficient amount of smaller particles so that the average surface area of the zeolite is 29 m2/g as measured by the BET method). The binder maintains the mixture in a particulate state throughout the process.
Easy to dispense D.M. Flower Amway Corp. Eur. Pat. Appl.
powder
710,717,
May
detergent
8, 1996;
composition
Appl.
Nov.
the content of fatty acid and fatty alcohol is preferably 9-12% and the ratio of fatty acid to fatty alcohol is preferably 0.91.05:1. Preferably, the builder is a water-insoluble zeolite, the fatty acid is stearic acid, and the fatty alcohol is cetyl alcohol. The surfactant mixture enhances the dispensability of the composition for use in washing machines with side-flush dispensers.
Bleaching detergent sodium percarbonate solubility
4, 1994
A granular detergent composition contains at least one nonionic surfactant, 12.5-60%, a granular base containing at least one builder, IO-85%, impregnated with a mixture of the nonionic surfactant, at least one fatty acid, 0.5-5%, and at least one fatty alcohol, 0.5-5%. The granular base particles are impregnated first with the nonionic surfactant, then with the mixture where
compositions with good
containing coated storage stability and
M. Aoyanagi; Y. Yamaguchi; N. Ogura Kao Corp. Jpn. Kokai Tokkyo Koho 96,92,593; 96,92,594; 1996; Appls. Sept. 22, 1994
96,92,595,
Apr.
9,
The laundry detergent compositions contain 2-30% Cs-,, fatty acid lower alkyl ester sulfonate salts, O&30% Na percarbonate coated with film-forming polymers or inorganic salts, and O.l10% organic peracid precursors (RCO,C,H,SO,),M (R = C,_,, alkyl; M = Na, K, Mg; n is 1 when M is Na or K and n is 2 when M is Mg), and they optionally contain l-50% of crystalline alkali metal silicates and l-50% of aluminosilicate salts (zeolite 4A).
Nonionic powdered laundry detergent with excellent solubility and dispersibility
compositions
M. Hasumi; J. Sakamoto; Y. Koyama et al. Kao Corp. Jpn. Kokai Tokkyo Koho 96,92,591, Apr. 9, 1996; Appl. Sept. 22, 1994 The title compositions contain nonionic surfactants (m.p. J4O”C) 12-35%, aluminosilicates (zeolite A) IO-60%. and water soluble olefin-unsaturated dicarboxylic anhydride copolymers or their salts O.Ol-5%.
Tablet
et al.
report
detergent
compositions
S.J. Edwards; P. Farnworth; Unilever N. V.; Unilever Pk. Eur. Pat. Appl. 711,827, May Tablet detergent ticulate detergent tive compounds coconut alcohols), (e.g., zeolite A), (e.g., Na citrate). let and dissolution added to water.
Liquid laundry surfactants
PC.
Knight
et al.
15, 1996;
U.K. Appl.
Nov.
14, 1994
compositions are prepared by compacting parcompositions containing 5-60% detergent ac(e.g., coconut primary alkyl sulfate, ethoxylated 15-60% aluminosilicate detergency builders and citrates with solubility in water of 50-100 g/l This improves disintegration of the whole tabof its soluble ingredients when the tablet is
detergent
P.C. Hu; E.W. Liimatta Albemarle Corp. PCT Int. Appl. 96,18,713,
formulations
June
20, 1996;
of zeolites
U.S. Appl.
and
Dec. 15, 1994
Aqueous liquid detergents that do not require polymeric thickeners to attain viscosity 51,000 mPa comprise 5-45% of suspended zeolite particles (zeolite A or X or a mixture of A and X), IO-30% of a C,,,-,, (preferably Na (I,,-,,) alkylbenzene sulfonate/nonionic surfactant admixture, 0.5-4.5% builder (sodium citrate), and 35-80% water. For example, formulations containing Na dodecylbenzenesulfonate, a 7-ethoxylate of C,,_,, alcohols, Na citrate, water and IO-15% suspended zeolite content were stable in storage for 2 months.
Granular leakage
detergent
composition
G.M. Bailelly Procter and Gamble Co. Eur. Pat. Appl. 684,301, Nov.
29, 1995;
with
reduced
U.K. Appl.
perfume
Apr.
28, 1994
A granular detergent composition is disclosed comprising a surfactant, soluble capsules of perfume, and a detergency builder being zeolite P having a silicon to aluminum atomic ratio not greater than 1.33, preferably not greater than 1.07 (zeolite MAP). The composition preferably has a bulk density of at least 650 g/l and may optionally contain percarbonate. The use of
Zeolites
18:417-421,
1997
419