Index of Compounds Group IA Lithium Allyllithium, 91,92 Benzyllithium, 95 p-Bromophenyllithium, 93 n-Butyllithium, 92, 93, 95, 96, 98, 120, 134 2,2'-Dilithiobiphenyl, 134 Diphenylmethyllithium, 97 Methyllithium, 109 Phenoxymethyllithium, 96 Phenylethynyllithium, 130 Phenyllithium, 92, 129, 155, 167, 181 (£")-2-Phenyl-1 -phenylsulfonylvinyllithium, 109 (£)-Stilbenyllithium, 120 (Z)-Stilbenyllithium, 120 (£,£>1,2,3,4-Tetraphenyl-1,3-butadien1,4-ylidenedilithium, 99, 177 Triphenylmethyllithium, 98 Group IIA Magnesium Allylmagnesium bromide, 105,106,175,180 Benzylmagnesium chloride, 143 3-( 1 -Bromomagnesiooxy-1 -cyclohexyl)propylmagnesium bromide, 107 α-Deuteriovinylmagnesium chloride, 104 Diallylmagnesium, 106 Ethylmagnesium bromide, 108, 159, 169 Phenylethynylmagnesium bromide, 159, 169 Phenylmagnesium bromide, 117, 165 (£)-2-Phenyl-1 -phenylsulfonylvinylmagnesium bromide, 110 Vinylmagnesium bromide, 166 Group IIB Zinc Diethylzinc, 113, 114 Ethylzinc bromide, 113 Ethylzinc chloride, 113 193
Ethylzinc iodide, 113 Iodomethylzinc iodide, 170 Mercury Bis(phenylethynyl)mercury, 115 Bis[(£)-stilbenyl]mercury, 120 Bis[(Z)-stilbenyl]mercury, 120 Bis(trimethylsilyl)mercury, 115 Dibenzylmercury, 142 Diphenylmercury, 118, 140, 148, 153 Di-l-propynylmercury, 115 Di-m-tolylmercury, 119 Phenylmercuric bromide, 117, 126
Group IIIA Boron , Ammonium bis(2,2 -biphenylene)borate, 135 l-Chloro-4,5-dihydroborepin, 124 Diethyl phenylboronate, 125 Diphenylboron bromide, 127, 130 Diphenyl(phenylethynyl)borane-pyridine, 130 Heptaphenyl-7-borabicyclo[2.2.1]heptadiene, 132, 133 Heptaphenylborepin, 133 Lithium bis(2,2'-biphenylene)borate, 135 Methylboron dibromide, 123 l-Methyl-4,5-dihydroborepin, 123 Pentaphenylborole, 131, 132 1-Phenylboracyclopentane, 128 Phenylborane-triethylamine, 125, 128 Phenylboron dibromide, 127 Phenylboron dichloride, 125 Phenylboronic acid, 154 , Potassium bis(2,2 -biphenylene)borate, 135 Sodium bis(2,2'-biphenylene)borate-tris(1,2-dimethoxyethane), 135 Tetramethylammonium bis(2,2'-biphenylene)borate, 136 Trimethylammonium tetraphenylborate, 129 Triphenylborane, 129
194
Index of Compounds
Aluminum Diisobutylaluminum chloride, 137 Diisobutylaluminum deuteride, 137 Diisobutylaluminum hydride, 138, 160 Diisobutyl [(Ζ)-1 -trimethylsilyl-2-phenylethenyl] aluminum, 138 Diphenylaluminum chloride, 139 Diphenyl(phenylethynyl)aluminum, 141 Phenylaluminum dichloride, 139 Tribenzylaluminum, 142 Tribenzylaluminum-diethyl ether, 143 Triethylaluminum, 114, 146, 151 Triisobutylaluminum, 147, 149, 152 Triphenylaluminum, 139, 140, 141 Gallium Di-H-decylgallium decoxide, 145 Diethylgallium chloride, 144 Diethylgallium ethoxide, 144, 145 Diisobutylgallium isobutoxide, 145 Tri-H-decylgallium, 149 Triethylgallium, 144, 145 Triisobutylgallium, 147 Triphenylgallium, 148 Indium Diethylindium chloride, 150 Triethylindium, 150, 151 Triisobutylindium, 152 Triphenylindium, 153 Thallium Diphenylthallium bromide, 154, 155 Diphenylthallium chloride, 155 Thallium(I) cyclopentadienide, 153 Triphenylthallium, 155 Group IVA Silicon 1,4-Bis(triphenylsilyl)butane, 163 /7-Bromophenyl(triphenyl)silane, 94 Chloro(trimethyl)silane, 116, 159 Chloro(triphenyl)silane, 92, 94, 104, 162, 163 Dichloro(dimethyl)silane, 159 3,3-Dimethyl-l-butynyl(trimethyl)silane, 160 1,1 -Dimethyl-2,5-dihydrobenzo[c]silole, 157 Hexaphenyldisilane, 161, 163 Trimethyl(3-methyl-3-buten-1 -ynyl)silane, 160 Trimethyl(phenylethynyl)silane, 138, 159
Trimethyl(l-propynyl)silane, 160 1 -(3-Trimethylsilyl-1 -propyl)cyclohexanol, 106 Trimethyl(ds-/?-styryl)silane, 160 Trimethyl(fra«.y-/?-styryl)silane, 160 1,1,1 -Trimethyl-2,2,2-triphenyldisilane, 162 Triphenylsilyllithium, 162 Triphenylsilylpotassium, 161 Triphenyl(vinyl)silane, 104 a-deuterio, 163 Germanium />-Bromophenyl(triphenyl)germane, 94 Bromo(triphenyl)germane, 164, 166 Chloro(triphenyl)germane, 94, 165 Tetraphenylgermane, 164, 167 Triphenyl(vinyl)germane, 166 Tin Allyl(tri->!-butyl)tin, 92 Allyl(triphenyl)tin, 92, 175 Chloro(trimethyl)tin, 168, 169 Chloro(triphenyl)tin, 172, 173, 175 Diallyl(di-«-butyl)tin, 92 Diallyl(diphenyl)tin, 175 Dibromo(di-M-butyl)tin, 123 Di-«-butyl(dichloro)tin, 124, 169 1,1 -Di-«-butyl-4,5-dihydrostannepin, 123, 124, 171 Di-w-butyltin dihydride, 169, 171 Dichloro(dimethyl)tin, 131, 177 Dichloro(diphenyl)tin, 173, 175 1,1 -Dimethyl-2,3,4,5-tetraphenylstannole, 131, 177 Hexamethylditin, 168 Tetraallyltin, 92 Tetra-fl-butyltin, 96 Tetraphenyltin, 172, 173 Tribromo(phenyl)tin, 127 Tri-,i-butyl(chloro)tin, 92, 171 Tri-«-butyl(iodomethyl)tin, 170, 174 Tri-Ai-butyl(phenoxymethyl)tin, 96, 174 Trimethyl(phenylethynyl)tin, 169 Triphenyl(/r0«s-/?-styryl)tin, 176 Triphenyltin hydride, 173, 176 Lead Allyl(triphenyl)lead, 180 Bromo(triphenyl)lead, 179 Chloro(triphenyl)lead, 178, 180 Dibromo(diphenyl)lead, 179 Dichloro(diphenyl)lead, 178 Tetraphenyllead, 178, 179, 180