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INTENSITIES AND COLLISION-BROADENING PARAMETERS FROM INFRARED SPECTRA: AN UPDATE
INTENSITIES AND COLLISION-BROADENING PARAMETERS FROM INFRARED SPECTRA: A N UPDATE
TAT Mary Ann H. Smith and Curtis P. Rinsland NASA Langley Research Center Hampton, Virginia
V. Malathy Devi The College of William and Mary Williamsburg, Virginia
Laurence S. Rothman Geophysics Laboratory Hanscom AFB, Massachusetts and
K. Narahari Rao The Ohio State University Columbus, Ohio I. II. III. IV. V.
Introduction Intensities Collision Broadening Pressure-Induced Line Shifts Explanation of Tables and Table References Acknowledgments References
153 154 155 157 157 159 260
I. INTRODUCTION This chapter is the third in a series of periodic compilations of experimentally determined infrared vibration-rotation band intensity values for molecules in the gas phase. The first two works in this series were by Pugh and Rao [1] and Smith et al. [2]. The second of these works also included, for the first time, a bibliography for measurements of collision broadening in infrared vibrationrotation spectra. In the present chapter we continue the bibliographies for band 153
Copyright © 1992 by Academic Press Inc. All rights of reproduction in any form reserved. ISBN 0-12-580645-0
154 ψ SMITH, RINSLAND, DEVI, ROTHMAN, RAO
intensities and collision broadening, and we include a new bibliography for measurements of pressure-induced line shifts in infrared spectra. We have attempted to make these bibliographies as complete and comprehensive as possible. The intensity and broadening compilations cover the published literature from November 1983 through June 1990, and they include several earlier references overlooked in the previous compilations. The pressure-induced line shift compilation includes all references published through June 1990 that were available to us. We have also added a number of more recent references as they came to our attention in the course of preparing the present bibliography.
II. INTENSITIES Detailed discussions of intensity parameters, units, and measurement techniques have been given in Refs. [1-2] and will not be repeated here. However, in order to properly interpret the values given in Tables II and III and in the individual references, we must discuss the difference between the vibrational band intensity, Sv, and the integrated band intensity SBand. Sv is related to the squared vibrational transition moment by
s
»=(f£) v °§ iwr
(i)
where h is Planck's constant, c is the speed of light, v0 is the wavenumber of the band center, N is the total number of molecules of the absorbing gas per cubic centimeter per atmosphere, Qv is the vibrational partition function, and Κμ^)! is the vibrational transition moment. SBand is defined as the summation of individual line intensities S% for all possible rotational transitions within the vibrational band; that is, Sßand = Σ $A = Σ SvR*kF = Sv 2 RAF
(2)
where RA is the rotational factor, given by RBA = SXB exp {-hcEJkT)
(Wv 0 Q r ) [1 - exp (-hcv^/kT)]
(3)
where S'AB is the dimensionless quantity called the line strength by Herzberg [3], EA is the energy of the lower state A, k is Boltzmann's constant, T is the gas temperature in degrees Kelvin, v^ is the wavenumber of the transition from lower state A to upper state B, and Qr is the rotational partition function. In Eqs. (1-3) we are using the approximation Qv · Qr = Q, where Q is the total internal partition sum; this approximation is valid except at very high temperatures. The F-factor in Eq. (2) accounts for the effects of centrifugal distortion, Fermiand Coriolis-type interactions, and other perturbations. For a rigid rotor, the F-factor would be 1, and Sv and 5Band would be equal (assuming all possible rotational transitions are included in the summation). However, if the F-factor
INTENSITIES AND COLLISION-BROADENING PARAMETERS T
155
is significantly different from 1 for most of the rotational transitions, as the case for many C0 2 bands, SBand is usually larger than Sv. SBand values determined from the summation of individual line-intensity measurements using high-resolution techniques are more appropriate for comparison to low-resolution band intensity measurements (e.g., [4]). Therefore, where a given reference reports both Sv and SBand values, (e.g., [5]) we have chosen to include only the SBand values in Table 2. Unless the reported intensity is designated as Sv or SBand in the footnotes to the table, the reader should obtain more detailed information from the original reference. Table I gives the various units in which band intensities have been reported in our literature survey, along with the multiplicative factors used to convert these units to our standard units (cm-2 aim"1 at 300K) for comparison purposes. However, because these multiplicative factors do not account for the temperature dependence of the partition functions or the exponential factors shown in Eq. (3), the converted values may not represent the true band intensity at 300K, particularly for transitions whose lower state is not the ground state. Goldman, Dang-Nhu and Bouanich [6] give an excellent brief discussion of the temperature dependence of line intensities. Several of the references reporting intensity measurements of bands of CHC13, CDC13, CHC12F, CHC1F2, CHD2F, CHF3, and CDF3 give the results not as Sv or SBand as defined in Eqs. (1-3), but as a quantity denoted as G. This G is identical to the Γ originally defined by Golike et al. [7] and is usually reported in units of (length)2 mole-1 or (length)2 molecule-1. As previously stated in [2], G (or Γ) may be related to 5Band approximately by SBand = Gv0, where v0 is the wavenumber of the observed band center. To compare measurements by investigators in different laboratories and apply their results to atmospheric or astrophysical measurements, we must also understand the corrections applied for the isotopic composition of the measured gas samples. Unfortunately, in many papers, the isotopic composition is not specified, and the interpretation of "natural abundance" is left to the reader. Johns [8] discussed in detail the difference between the "natural abundance" of 13 C in atmospheric C0 2 and that in commercially supplied C0 2 . In our conversion of reported intensities to a consistent set of units, we have attempted to rescale each intensity value to represent the band intensity for a 100% pure sample of a single isotope. Where no specific isotopic abundance information has been given in the original reference, we have used the 1986 HITRAN abundances [9].
HI.
COLLISION BROADENING
For most of the range of pressures typically encountered in the terrestrial and planetary atmospheres, infrared vibration-rotation lines have predominantly the
156
τ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
Lorentz, or collision-broadened line shape, in which the width of the line is linearly dependent on the gas pressure (for a fixed temperature). At very low gas pressures, the line shapes follow the Doppler profile, where the line width depends only on the temperature, mass of the molecule, and wavenumber of the transition. In the intermediate range where the Doppler and Lorentz profiles both contribute significantly, the line shape is most often modeled by the Voigt profile, which is the convolution of these two profiles. Detailed expressions for these three line profiles have been given in [2] and will not be repeated here. The dependence of the collision-broadened halfwidth on pressure and temperature is usually expressed as bdp, T) = b°L(T0)p(To/Ty
(4)
where bL(p, T) is the collision-broadened halfwidth of the line at measured pressure p and temperature T, b*l(T0) is the collision-broadened halfwidth of the line at the reference pressure (usually 1 atm) and temperature T0 (usually 296 K). According to the classical theory, the exponent n should have the value 0.5; however, many of the experimental results cited in Table IV of the present compilation and in [2], show quite different values for n. The experimentally determined values of this exponent appear to vary according to the absorbing and perturbing gases and the vibrational and rotational quantum numbers. In recent years measurements of Lorentz broadening coefficients and their temperature dependence have become more numerous. There have been more measurements of individual line widths within a band, and very few studies reporting simply an average broadening coefficient (or n value) for an entire band. Recognizing that temperatures in the terrestrial upper atmosphere and in planetary atmospheres are quite different from ambient values in the laboratory, several investigators have pursued measurements of collision-broadened gasphase spectra at low temperatures down to about 150K. Other investigators, driven by requirements to measure the spectra of combustion exhaust gases in situ, have recorded laboratory collision-broadened spectra at high temperatures. Another area of increased interest has been the examination of line shapes that depart from the usual three forms (Lorentz, Doppler, Voigt) most commonly used to model laboratory, atmospheric, planetary, or astronomical spectra. Collisional narrowing is observed for spectral lines whose Lorentz halfwidth bL is very small. The Galatry line shape [10] is usually used to model the profiles of absorption lines affected by collisional narrowing in addition to Doppler and Lorentz broadening. Other phenomena that have been examined extensively include non-Lorentzian profiles in the far wings of very strong absorption lines (particularly for H 2 0 and C0 2 ) and line mixing (also called line coupling) in regions of very closely spaced lines such as ß-branches. References for laboratory studies of collisional narrowing, far-wing line shapes, and line mixing have also been included in Table IV.
INTENSITIES AND COLLISION-BROADENING PARAMETERS ψ
IV.
157
PRESSURE-INDUCED LINE SHIFTS
Shifts in the positions of vibration-rotation lines due to collisions with other gases have become a concern for certain types of infrared measurements. Since ambient pressures in the terrestrial and planetary atmospheres range from several Torr to several atmospheres, pressure-induced line shifts must be considered in spectroscopic studies of these atmospheres. Knowledge of line shifts is also important for certain transitions of C0 2 , CH4, and other gases that are used for stabilization of laser frequencies. Prior to the mid-1980s, very few measurements of pressure-induced line shifts appeared in the literature; most of these were for diatomic molecules such as CO, HBr, HC1, HF, H2, and HD. More recent studies have provided extensive information on shifts in transitions of larger molecules, including C0 2 , H 2 0, N 2 0, 0 3 , NH3, and CH4. However, some of these studies report measurements of shifts for only a small number of lines within a band. Theoretical prediction of pressure-induced line shifts has been successful only for selected types of molecules such as polar diatomic molecules [11,12]. Adequate models for pressure-induced shifts in bands of other molecules of interest for atmospheric studies, such as 0 3 or CH4, have not yet appeared. Only a very few measurements of pressure-induced line shifts at temperatures far above or below room temperature have been reported, and the form of the temperature dependence of the shifts is not certain. A number of investigators, including Grossmann and Browell [13,14], have modeled pressure-induced line shifts at low temperatures using a relation similar to that used for the Lorentz half widths: δ(Γ) = δ(Γ0)(Γ/Γ0Γ'
(5)
where δ(Γ) is the shift coefficient (in cnrVatm) at the measured temperature T, δ(Γ0) is the shift coefficient at the reference temperature T0, and the exponent ri is empirically determined. However, the above expression is not valid in cases where the line shift changes sign with temperature. Other investigators, such as Houdeau and Boulet [15], have developed more rigorous theoretical models to account for the temperature dependence of both halfwidths and shifts. V. EXPLANATION OF TABLES AND TABLE REFERENCES The tables continue in the format of Refs. [1-2] with one exception. For carbon dioxide and its isotopic variants, we have adopted the vibrational band notation of Rothman and Young [16], which is also used in the HITRAN and GEIS A spectroscopic line parameters compilations [9,17]. This notation is widely used by numerous investigators. Briefly, each vibrational level of C0 2 is designated by an integer whose five digits correspond to the sequence ViV2lv3r, where vi9
158 v
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
v2, and υ3 are the vibrational quantum numbers, / is the degeneracy index of the v2 vibrational mode, and r indicates the level's ranking in a Fermi resonance poly ad. Thus, the ground state is designated by 00001, the v\ level by 01101, the V! level by 10001, and the 2v\ level by 10002. For each transition the level designations are given with the upper level first. For example, the 12 C 16 0 2 laser transition at 961 cm -1 , designated v3-vx in the previous compilations, is indicated as 00011-10001 in the present work, and the v3-2v2 laser transition at 1064 cm-1 is indicated as 00011-10002. The literature values and references for intensities of vibration-rotation transitions are given in Tables II and III. All of these values are for electric dipole allowed transitions measured in the gas phase with a few exceptions. These include the "forbidden" 03301-00001 band of 12 C 16 0 2 at 2003 cm"1, liquid-phase measurements of several N 2 0 bands that were published along with gas-phase measurements, and quadrupole and electrically-induced dipole vibration-rotation transitions of H2 and N2. Purely rotational and electronic transitions are not included in the compilation. As in the previous compilations, Table II contains the data for molecules with 2, 3, 4, and 5 atoms. The molecular data are sorted first by number of atoms, then by molecular formula in alphabetical order, then by isotopic form in order of increasing molecular weight. If the isotopic forms are not individually specified, the reader should assume that the data refer to the most abundant isotope of the molecule. The first page of Table II serves as an index to the succeeding pages of the table. The bands for each molecule are presented in order of increasing wave number, with the assignments and band centers (in cm-1) given in the first column of the table. In the second column, headed Reference Value, are listed the integrated band intensity values as reported in the original references. Any unusual features of the reported measurements are indicated by footnotes in the relevant sections of the table. The third column of Table II contains the reported intensity values converted to units of cm -2 atm-1 at 300K using the factors given in Table I. References for the band intensity values are given in the fourth column of the table. Additional references that do not report band intensity values, but contain measurements of individual line intensities or transition dipole moments, are listed following the words See or See also in the second column. Table III lists references for gas-phase intensity measurements in vibrationrotation bands of molecules having six or more atoms. The entries are arranged in alphabetical order according to the name of the molecule. We have not distinguished among references for band intensities, individual line intensities, or dipole moment matrix elements. References for collision broadening are given in Table IV and those for pressure-induced line shifts are listed in Table V. Both tables have the same format. The arrangement of the data according to the number of atoms, molecular formula, and isotopic species of the absorbing molecule is the same as in Table II, and for each molecule the bands are listed in ascending wavenumber order. For
INTENSITIES A N D COLLISION-BROADENING PARAMETERS T
159
each band, whose identification and wavenumber are given in the first column, the references are listed according to the perturbing gases given in the second column, sortedfirstby number of atoms per molecule, then in alphabetical order by molecular formula or name as appropriate. Mixtures of broadening gases are listed according to their predominant component. As in the previous compilation of broadening references [2], the listings in the table do not indicate the precise nature of the broadening or shift measurements reported. The references cited include measurements for individual lines as well as average values reported for an entire band, and some of these measurements also address the temperature dependence of the line widths and shifts. For both Table IV and Table V, as in Table II, the first page of each table serves as an index to the remainder of the table. The reference lists are divided into two sections. The part labeled References contains only the references cited in the text, while that labeled Table References lists only the numbered references given in Tables II-V. ACKNOWLEDGEMENTS Our thanks are due to J. Miller of Hampton University for his assistance in collecting the references and Dr. W. B. Grant of NASA Langley Research Center for providing a number of references from Russian-language journals. TABLE I.
COMMONLY USED BAND INTENSITY UNITS AND CONVERSION FACTORS
Units cm^atm"1 at 300K cm^atm"1 at T cm^atm"1 at STP
For conversion to cm"2atm"1 at 300K, multiply by 1.0 3.3333T x 10"3 0.91053
(also called cm"2 amagat"1) cm-1 m"1 amagat"1
91.053
cm"V(g cm"2)
4.0623M x 10"5
cm mole'1
4.0623 x 10"5
km mole"1
4.0623
cm-Vimolecule cm"2) (also called cm molecule"1) cm"1 m"1 Pa"1 at 300K Notes: T is temperature in K. M is molecular weight in g/mole.
2.4464 x 10 19 1.01325 x 103
160
τ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO TABLE II
BIBLIOGRAPHY FOR BAND INTENSITIES OF MOLECULES WITH TWO TO FIVE ATOMS
Molecule
Page
Diatomic BrO CO ClO FO H79Br H81Br H35C1 H37C1 HF H2 N2 NH NO OH
161 161 161 161 161 162 162 162 162 162 162 163 163 163
Molecule
Page
Molecule
Page
H02 HOC1 H 2 32 S H 2 33 S H 2 34 S N20 N02
188 189 189 189 189 190 192 192 194 194 195 195 195 195 196 196 196 196
Five atomic CBrF3 CC14 CF4 CFC13 CF2C12 CF3C1 12 CH 4 13 CH 4 12 CH 3 D 12 CD 4 CHC13 CDC13 CH335C1 CH337C1 CHC12F CHC1F2 CHD2F CHF3 CDF 3 CH3I CH3N C1N0 3 GeH4 70 GeH 3 D HN0 3 SiF 4 SiH3D
201 201 201 201 201 202 202 204 204 204 205 205 206 206 206 206 207 207 208 208 209 209 210 210 210 211 211
16
o3 16 16 18
o o o o o o
16 18 16
16Q18Q18Q 18016Q180 18
03
16 0 12 C 32 S 16 0 13 C 32 S 16012C33S
Triatomic CF 2 12 16
c o2 13 16 c o2
12C160170 12 16 18
c o o
13C160180 12 18
c o2 c o2
13 18
cs2
C102 H 12 C 14 N H 13 C 14 N H 12 C 15 N DCN H2160 HDO D20 HTO H2180
16 0 12 C 34 S
164 164 171 173 174 176 177 177 177 177 177 180 180 180 181 186 187 187 187
so2 Four atomic CF3 CH3 C2H2 C2N2 COF2 H2CO H202 trans-HONO 14 NH 3 15 NH 3 14 ND 2 H 14 ND 3 15 ND 3 N03 PH3
196 196 196 198 198 198 199 199 199 200 200 200 200 200 200
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
161
TABLE II (2) BAND
REFERENCE VALUE
cm"2atm_1 at300K
REFERENCE
BrO 1-0 a
(723 cm"1)
*5.04 ± 0.80 cm^atm"1 at 298K
5.0
5 B a n d obtained by summing individual line intensities for both the 79BrO and
325(1991) 81
BrO isotopes.
CO 1-0
(2143 cm"1)
See Refs. 260(1985) and 196(1986)
2-0
(4260 cm"1)
2.07 ± 0.02 cm_1/(atm cm) STP See also Ref. 96(1985)
1.88
174(1986)
4.8 9.6
238(1986) 89(1987) 245(1988) 88(1989)
0.93
89(1987)
CIO 1-0
2-0
(844 cm"1)
(1670 cm"1)
4.9 cm^atm"1 at 296K 11.3 ± 2.0 cm^atm"1 at 296K 13.1 ± 1.1 cm^atm"1 at 296K 9.68 ± 1.45 cm^atm"1 at 296K See also Ref. 447(1988) ~ 0.94 cm^atm"1 at 296K
FO 8-7 7-6 6-5 5-4 4-3 3-2 2-1 1-0
(878 cm"1) ' (902 cm"1) (925 cm"1) (948 cm"1) (970 cm"1) (992 cm"1) (1013 cm'1) (1032 cm"1),
See Ref. 194(1988)
H79Br 1-0
(2559 cm'1)
See Ref. 382(1985)
6-0
(13989 cm"1)
See Ref. 109(1988)
7-0
(15998 cm"1)
See Ref. 109(1988)
8-0
(17909 cm"1)
See Ref. 109(1988)
11.1 12.9
162
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (3) BAND
REFERENCE VALUE
cm^atm'1 at 300K
REFERENCE
H81Br 1-0
(2559 cm"1)
See Ref. 382(1985)
6-0
(13987 cm"1)
See Ref. 109(1988)
7-0
(15996 cm"1)
See Ref. 109(1988)
8-0
(17907 cm"1)
See Ref. 109(1988) H35C1
1-0
(2886 cm"1)
118.39 c n r W 1 at 295K
116.42
344(1985)
37.22
344(1985)
383.45
344(1985)
See also Ref. 111(1985) 3-0
(8347 cm"1)
See Refs. 398(1988) and 322(1989) H37C1
1-0
(2884 cm'1)
37.85 cm^atm"1 at 295K See also Ref. 111(1985)
3-0
(8341 cm"1)
See Ref. 322(1989) HF
1
1
1-0
(3962 cm" )
389.95 cm^atm" at 295K H2
1-0
(4161 cm"1)
See Ref. 60(1990)
2-0
(8087 cm"1)
See Ref. 307(1987) N2
1-0
(2325 cm'1)
See Refs. 356(1986) and 412(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
T
163
TABLE II (4) BAND
REFERENCE VALUE
at300K
REFERENCE
NH 5-4
(2494 cm"1)
See Ref. 113(1989)
4-3
(2656 cm"1)
See Ref. 113(1989)
3-2
(2813 cm'1)
See Ref. 113(1989)
2-1
(2969 cm'1)
See Ref. 113(1989)
1-0
(3126 cm"1)
See Ref. 113(1989)
NO 117 + 3 cm^atm"1 at 273K 4.45 ± 0.04 x lO"17 cm molecule 1 See also Ref. 339(1986)
1-0
(1876 cm"1)
7-6
(1876 cm"1)
See Ref. 141(1985)
8-7
(1876 cm"1)
See Ref. 141(1985)
9-8
(1876 cm"1)
See Ref. 141(1985)
2-0
(3724 cm"1)
1.878 +90 -40 cm^atm"1 at 296K
5-0
(9100 cm-1)
b
a
(2.18 ± 0.11) x 10"26 m at 296.8K
106. 109.
316(1987) 33(1988)
1.853
346(1985)
5.3 x 10'5
251(1988)
a Value reported in text is apparently a typographical error and is inconsistent with individual intensities reported in Table I of Ref. 33. The correct value should be 4.45 + 0.04 x 10 -18 cm molecule-1. b
Units are actually m molecule·1.
OH 1-0
(3570 cm'1)
See Refs. 447(1988) and 318(1989)
164
v
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O T A B L E Π (5)
BAND
REFERENCE VALUE
at300K
REFERENCE
CF9 u3
(1114 cm·1)
νλ
(1225 cm"1)
2.8 x 10 -17 cm molecule-1 See also Ref. 445(1989)
690.
405(1990)
(3.4 ± 0.8) x 10 -18 cm molecule-1 (1.5 ± 0.4) x 10 -17 cm molecule-1 (1.1 ± 0.4) X 10 -17 cm -1 (molecule/cm2)-1
83. 367. 270.
326(1987) 327(1988) 445(1989)
8.9 x 10-3
222(1990)
a
Corrected value based on data in Ref. 326. 12 16
c o,
11102-10001 (544 cm-1)
f
0.00875 ± 0.00012 cm-2atm-1 at300K
11102-02201 (597 cm-1)
f
0.14929 ± 0.00056 cm-2atm-1 at300K
0.1517
222(1990)
10002-01101 (618 cm-1)
f
3.9904 ± 0.0068 cm^atm-1 at300K
4.05
222(1990)
11102-10002 (647 cm-1)
f
0.6903 ± 0.0018 cm-2atm-1 at300K
0.701
222(1990)
01101-00001 (667 cm-1)
f
02201-01101 (668 cm-1)
f
16.042 ± 0.028 cm-2atm-1 at 300K
03301-02201 (668 cm-1)
f
0.9751 ± 0.0028 cm-2atm-1 at300K
11101-10001 (689 cm-1)
f
20001-11101 (720 cm-1)
f
202.45 ± 0.29 cm-2atm-1 at 300K See also Ref. 429(1989)
205.7 16.30
222(1990) 222(1990)
0.991
222(1990)
0.3837 ± 0.0012 cm^atm'1 at300K
0.390
222(1990)
4.15 X 10 -22 cm-1/(molecule cm-2) at 296K
0.0103
129(1990)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
165
TABLE II (6) BAND
at 300K
REFERENCE VALUE
REFERENCE
12rl6, C 1 6 0 2 (continued) 10001-01101 (721 cm"1)
c f
3.78 ± 0.13 cm^atm"1 at 296K 4.0685 ± 0.0097 cm^atm"1 at300K See also Ref. 426(1989)
3.7 4.134
214(1988) 222(1990)
20002-11102 (739 cm"1)
f
6.89 X 10"3
222(1990)
11101-02201 (742 cm-1)
f
0.1736
222(1990)
0.158
129(1990) 222(1990)
0.006782 ± 0.000041 embalm"1 at300K See also Ref. 193(1990) 0.17085 ± 0.00037 cm^atm"1 at300K f 63.4 x 10"22 cm'1/(molecule cm'2) at 296K
12201-03301 (757 cm"1)
f
0.006763 ± 0.000049 cm^atm"1 at300K See also Ref. 193(1990)
6.87 x lO'3
11101-10002 (791 cm'1)
e
0.017
2(1986)
0.0187
131(1989)
0.02048
222(1990)
6.93 ± 0.42 x 10"22 cm_1/mol cm"2 at 294K c 7.65 x 10"22 cm/molecule f 0.020156 ± 0.000040 cm^atm"1 at300K
12201-11102 (828 cm'1)
e
20001-11102 (865 cm"1)
e
0.151 ± 0 . 0 1 1 x 10"22 cm'Vmol cm"2 at 294K
2(1986)
1.0 X 10"4
2(1986)
2.7 x 10"5
2(1986)
2.1 x 10"5
2(1986)
9.5 x lO"4
2(1986)
3.06 x 10"5
2(1986)
22
0.042 ± 0.002 x 10" cm_1/mol cm"2 at 294K
22
02211-12201 (899 cm"1)
«Ό.ΟΠ ± 0.001 x 10" cm'Vmol cm"2 at 294K
10011-20001 (918 cm"1)
e
01111-11101 (927 cm"1)
e
10012-20002 (942 cm"1)
3.8 x 10"4
0.0086 ± 0.0007 x 10cnrVmol cm -2 at 294K
22
22
0.382 ± 0.019 x 10" cm'Vmol cm"2 at 294K
22
^.0123 ± 0.0006 x lO" cm'Vmol cm'2 at 294K
166
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (7) BAND
REFERENCE VALUE 12
at300K
REFERENCE
C 1 6 0 2 (continued)
00011-10001 (961 cm"1)
e
6.000 ± 0.300 x 10"22 cm'Vmol cm -2 at 294K See also Refs. 399(1987), 182(1988), and 400(1989)
10011-20002 (1044 cm"1)
*0.015 ± 0.002 x 10"22 cm'Vmol cm -2 at 294K
00011-10002 (1064 cm"1)
*9.83 ± 0.49 X 10-22 cm'Vmol cm -2 at 294K See also Refs. 399(1987), 182(1988), and 400(1989)
10012-20003 (1064 cm"1)
0.015
2(1986)
3.7 x 10'5
2(1986)
0.024
2(1986)
^.029 ± 0.003 x 10"22 cm_1/mol cm -2 at 294K
7.2 x 10"5
2(1986)
01111-11102 (1072 cm"1)
*0.78 ± 0.04 x lO'22 cm'Vmol cm -2 at 294K
1.9 x 10"3
2(1986)
02211-12202 (1074 cm"1)
*0.026 ± 0.003 x 10"22 cnrVmol cm -2 at 294K
6.5 x 10"5
2(1986)
20003-01101 (1881 cm"1)
b
12.9 x 10"24 cnrVmolecule cm -2 at 296K
3.21 x 10"4
359(1985)
21103-10002 (1896 cm'1)
b
2.11 x lO'24 cm'1/molecule cm'2 at 296K
5.25 x 10"5
359(1985)
13302-02201 (1905 cm"1)
b
1.62 x 10' 24 cm"1/molecule cm"2 at 296K
4.03 x 10"5
359(1985)
12202-01101 (1918 cm"1)
b
39.12 x 10' 24 cnrVmolecule cm"2 at 296K
9.725 X 10"4 359(1985)
11102-00001 (1932 cm'1) Band System
5.55 ± 0.26 x 102 cm/mol
21102-10001 (1951 cm"1)
b
03301-00001 (2003 cm"1)
^.194 x 10"30 cm"1/molecule cm"2 at 296K
1.14 x 10"24 cm"1/molecule cm"2 at 296K
0.023
412(1989)
2.83 x 10"5
359(1985)
4.82 x 10"12 42(1985)
INTENSITIES AND COLLISION-BROADENING PARAMETERS ψ
167
TABLE II (8) BAND
REFERENCE VALUE 12
cm'^atm"1 at 300K
REFERENCE
6.62 X 10'5
358(1984)
5.5 x lO"6
359(1985)
2.84 X lO"4
358(1984)
3.11 X 10'5
358(1984)
C 16 0 2 (continued)
20002-01101 (2004 cm"1)
b
21102-02201 (2004 cm"1]
b
21102-10002 (2054 cm"1;)
b
22202-11102 (2075 cm"1,)
b
11101-00001 (2077 cm"1 i
b
5397.0 x 10"24 cm'Vmolecule cm"2 at 296K See also Ref. 177(1987)
0.13416
360(1986)
12201-01101 (2093 cm"1 )
b
0.01253
360(1986)
13301-02201 (2107 cm'1,)
b
34.4 x 10"24 cm'Vmolecule cm"2 at 296K
8.55 x 10"4
360(1986)
21101-10001 (2112 cm-1 )
b
23.3 x 10"24 cm'Vmolecule cm"2 at 296K
5.79 X 10"4
360(1986)
14401-03301 (2119 cm"1 )
b
2.09 x 10"24 cm'Vmolecule cm"2 at 296K
5.19 X lO'5
360(1986)
22201-11101 (2121 cm"1 )
b
4.10 X 10'5
360(1986)
20001-01101 (2130 cm"1 )
b
30002-11102 (2132 cm"1 l
b
0.73 x 10"24 cm'Vmolecule cm"2 at 296K
1.8 X 10'5
360(1986)
30001-11101 (2148 cm"1 i
b
1.23 x 10"24 cm'Vmolecule cm'2 at 296K
3.06 X 10'5
360(1986)
21101-02201 (2166 cm"1 I
b
16.5 x 10' 24 cm'Vmolecule cm"2 at 296K
4.10 X 10"4
360(1986)
2.661 x lO"24 cm'Vmolecule cm"2 at 296K 0.22 x 10"24 cm'Vmolecule cm -2 at 296K
11.44 X 10"24 cm'Vmolecule cm"2 at 296K 1.25 x 10"24 cm'Vmolecule cm"2 at 296K
504.0 x 10' 24 cm'Vmolecule cm"2 at 296K
1.65 x 10"24 cm'Vmolecule cm"2 at 296K 309.0 x 10"24 cm'Vmolecule cm"2 at 296K
7.681 X 10'3 360(1986)
168
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (9) BAND
REFERENCE VALUE
at300K
REFERENCE
1.06 x 10"4
360(1986)
3.0 x 10"6
360(1986)
7.0 X 10"6
360(1986)
2.3 x 10"5
360(1986)
3.6 x 103 cm/mol
0.15
412(1989)
02211-02201 (2324 cm"1)
a
7.097 ± 0.032 cm-2/atm at 300K 7.115 ± 0.033 cm"2/atm at 300K
7.21 7.23
220(1987) 221(1989)
10011-10001 (2327 cm'1)
a
2.765 ± 0.011 cm"2/atm at 300K 2.772 ± 0.012 cnrVatm at 300K
2.81 2.82
220(1987) 221(1989)
10012-10002 (2327 cm'1)
a
4.609 ± 0.016 cm"2/atm at 300K 4.625 ± 0.016 cm-2/atm at 300K
4.68 4.70
220(1987) 221(1989)
01111-01101 (2337 cm'1)
a
00011-00001 (2349 cm'1)
a
20011-20002 (2429 cm"1)
b
10011-10002 (2429 cm"1)
b
12
11112-11101 (2171 cm"1)
b
20012-20001 (2181 cm'1)
b
20013-20002 (2182 cm"1)
b
22201-03301 (2194 cm'1)
b
11101-00001 12201-01101 20001-01101 Band System
C 1 6 0 2 (continued)
4.26 x 10"24 cm'1/molecule cm'2 at 296K 0.12 x 10"24 cm'Vmolecule cm -2 at 296K 0.28 x 10"24 cm-1/molecule cm -2 at 296K 0.92 x 10"24 cm-1/molecule cm -2 at 296K
d
d
d
180.21 ± 0.30 cm-2/atm at 300K 180.69 ± 0.30 cm"2/atm at 300K
d
2218.6 ± 2.7 cm"2/atm at 300K 2232.7 ± 1.7 cm"2/atm at 300K See also Refs. 128(1986), 255(1986), 374(1988), and 375(1988)
d
0.085 x 10"24 cm-1/molecule cm -2 at 296K
65.26 x 10"24 cm_1/molecule cm -2 at 296K See also Refs. 200(1986) and 130(1988)
183.1 183.5
220(1987) 221(1989)
2254. 2268.
220(1987) 221(1989)
2.1 X 10"6
274(1984)
1.62 x lO'3
274(1984)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
169
TABLE II (10) BAND
REFERENCE VALUE 12
at 300K
REFERENCE
3.41 X 10-6
274(1984)
3.95 X 10-5
274(1984)
C 1 6 0 2 (continued)
20012-20003 (2429 cm"
b
0.137 x 10"24 cm-1/molecule cm -2 at 296K
11111-11102 (2458 cm"
b
20001-00001
See Ref. 412(1989)
1.59 x 10 -24 cm-1/molecule cm"2 at 296K
(2671 cm01111-00001 (3004 cm" 30004-01101 (3125 cm"
See Ref. 412(1989) b
7.11 x 10 -25 cm molecule"1
1.77 X 10-5
41(1988)
22203-01101 (3155 cm"
b
7.04 x 10"25 cm molecule-1
1.75 X 10-5
41(1988)
21103-00001 (3182 cm'
b
1.20 X 10 -23 cm molecule-1
2.98 x 10 -4
41(1988)
30003-01101 (3275 cm"
b
1.99 x 10 - 2 4 cm molecule-1
4.95 x 10-5
41(1988)
31103-10002 (3306 cm"
b
5.53 x 10 -25 cm molecule-1
1.38 x 10-5
41(1988)
21102-00001 (3339 cm
b
1.025 x 10 -22 cm molecule-1
2.55 x 10-3
41(1988)
22202-01101 (3341 cm
b
8.348 x 10 -24 cm molecule-1
2.08 x 10 -4
41(1988)
23302-02201 (3342 cm
b
5.63 x 10 -25 cm molecule-1
1.40 x 10-5
41(1988)
21102-00001 22202-01101 ! 23302-02201 ] Band System
6.6 X 101 cm/mol
2.7 X 10-3
412(1989)
170
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (11) BAND
REFERENCE VALUE 12
cm^atm"1 at300K
REFERENCE
9.57 X 10"6
41(1988)
1.918 1.902
140(1988) 221(1989)
C 1 6 0 2 (continued)
31102-10001 (3365 cm'1)
b
3.85 x 10 -25 cm molecule"1
11112-01101 (3580 cm'1)
a
1.8877 ± 0.0075 cm^atm'1 at 300K 1.8723 ± 0.0060 cm"2/atm at 300K
10012-00001 (3612 cm"1)
a
10011-00001 (3715 cm"1)
a
11111-01101 (3723 cm"1)
a
10012-00001 i 10011-00001 / Band system
76.0 ± 0.6 cm^atm"1 at STP See also Ref. 255(1986)
31103-00001 (4591 cm"1)
b
0.019 ± 0.001 x 10"22 cm_1/mol cm -2
4.7 x 10"5
20013-00001 (4854 cm"1)
4.85 ± 0.1 X 103 cm/mol
0.20
412(1990)
20012-00001 (4978 cm'1)
0.9699 cm_1/cm atm at STP 2.02 X 104 cm/mol
0.8826 0.821
403(1990) 412(1990)
1.46 ± 0.1 cm^atm"1 at STP
1.33
173(1986)
20013-00001 ^ (4854 cm'1) 20012-00001 ' (4978 cm"1) 1 20011-00001 (5100 cm' 1 )) a
d
23.878 ± 0.035 cm^atm'1 at 300K 24.015 ± 0.035 cm"2/atm at 300K
24.26 24.39
140(1988) 221(1989)
36.863 ± 0.073 cm^atm"1 at 300K 37.071 ± 0.074 cm-2/atm at 300K
37.45 37.65
140(1988) 221(1989)
d
d
3.0378 ± 0.0098 cm^atm"1 at 300K 3.076 ± 0.010 cm"2/atm at 300K
d
3.087 3.12 69.2
140(1988) 221(1989) 173(1986)
1(1984)
5 v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of C 1 6 0 2 in the sample, which was assumed to be 0.98421.
12
b
^band ( ^ t e x t *° r definition). Reported intensity is uncorrected for the isotopic abundance of C"O 2 ; HITRAN value 0.98414 was used.
12
C
5V (see text for definition).
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
171
TABLE II (12) BAND
REFERENCE VALUE 12
at300K
REFERENCE
C 1 6 0 2 (continued)
d
5 v (see text for definition) from measurements of Refs. 220 and 140 corrected for errors in temperature and isotope composition, and some new measurements in the 00011-00001 band. Reported intensity is uncorrected for the isotopic abundance of 1 2 C 1 6 0 2 , which was 0.98462.
e
S v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of C 1 6 0 2 ; HITRAN value 0.98414 was used.
12
Sw (see text for definition). Reported intensity is scaled using the isotopic abundance of 1 2 C 1 6 0 2 appropriate to the atmosphere (see Refs. 220 and 221), which was assumed to be 0.98421. f
10002-01101 (617 cm"1)
«Ό.ΟΟΚΕ ± 0.00036 c n r W 1 at300K
01101-00001 (648 cm"1)
^.HOO ± 0.0085 cm^atm'1 at300K
10001-01101 (722 cm"1)
<Ό.023773 ± 0.000094 cm^atm'1 at300K
2.149
222(1990)
00011-10001 (913 cm"1)
c
0.077 ± 0.004 x 10"22 cm'Vmol cm"2 at 294K See also Refs. 399(1987), 182(1988), and 400(1989)
0.017
2(1986)
00011-10002 (1018 cm"1)
c
0.012
2(1986)
12202-01101 (1883 cm"1)
b
9.1 x 10"4
359(1985)
11102-00001 (1897 cm'1)
b
9.10 X 10'3
359(1985)
20002-01101 (1997 cm"1)
b
1.0 x 10'3
359(1985)
21102-10002 (2024 cm'1)
b
3.41 x 10·4
358(1984)
0.054 ± 0.005 x 10-22 cm'Vmol cm -2 at 294K See also Refs. 399(1987) and 400(1989) 0.41 x 10' 24 cm'Vmolecule cm -2 at 296K
4.11 X 10' 24 cm'Vmolecule cm'2 at 296K 0.46 x 10' 24 cm"1/molecule cm'2 at 296K 0.154 x 10' 24 cm'Vmolecule cm"2 at 296K
5.5235 193.5
222(1990) 222(1990)
172
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (13) BAND
REFERENCE VALUE 13
cm^atm-1 at300K
REFERENCE
C 1 6 0 2 (continued)
11101-00001 (2037 cm"1)
b
63.04 X 10-24 cm"1/molecule cm"2 at 296K
0.140
358(1984)
12201-01101 (2052 cm"1)
b
6.38 x 10"24 cm'Vmolecule cm"2 at 296K
0.0141
358(1984)
21101-10001 (2064 cm"1)
b
0.338 x 10' 24 cm'1/molecule cm"2 at 296K
7.5 x 10"4
358(1984)
13301-02201 (2064 cm"1)
b
0.657 X 10"24 cm'Vmolecule cm"2 at 296K
1.5 X 10'3
358(1984)
20001-01101 (2102 cm'1)
b
7.68 X 10"3
360(1986)
21101-02201 (2136 cm"1)
b
6.2 x 10-4
360(1986)
10012-10001 (2158 cm'1)
b
1.7 x 10'3
360(1986)
21101-10002 (2168 cm'1)
b
0.13 x 10-24 cm"1/molecule cm"2 at 296K
2.9 X 10"4
360(1986)
01111-01101 (2272 cm"1)
a
1.969 ± 0.008 cm"2/atm at 300K 1.9763 ± 0.0085 cm"2/atm at 300K
00011-00001 (2283 cm"1)
a
21102-00001 (3290 cm'1)
b
8.98 x 10"25 cm molecule'1
20012-00001 (4887 cm"1)
c
6.2 ± 0.3 x 10'3 cm'2/atm STP
a
3.47 X 10"24 cm"1/molecule cm"2 at 296K 0.28 x 10"24 cm"1/molecule cm"2 at 296K 0.79 x 10-24 cm"1/molecule cm"2 at 296K
d
22.537 ± 0.038 cm"2/atm at 300K 22.633 ± 0.036 cnr2/atm at 300K
d
178.0 185.6 2038. 2125. 1.99 x 10"5 0.51
220(1987) 221(1989) 220(1987) 221(1989) 41(1988) 53(1985)
5 v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of C 1 6 0 2 in the sample, which was assumed to be 0.01106.
13
b
^bßnd ( ^ text f° r definition). Reported intensity is uncorrected for the isotopic abundance of Ä 2 ; HITRAN value 0.01105 was used.
1 3
INTENSITIES A N D COLLISION-BROADENING PARAMETERS T
173
TABLE II (14) BAND
REFERENCE VALUE 13
cm"zatm" at300K
REFERENCE
C 1 6 0 2 (continued)
C
5V (see text for definition). Reported intensity is uncorrected for the isotopic abundance of C 1 6 0 2 ; HITRAN value 0.01105 was used.
13 d
S v (see text for definition) from measurements of Ref. 220 corrected for errors in temperature and isotope composition, and some new measurements in the 00011-00001 band. Reported intensity is uncorrected for the isotopic abundance of 1 3 C 1 6 0 2 , which was 0.01065. e
5 v (see text for definition). Reported intensity is scaled using the isotopic abundance of C 1 6 0 2 appropriate to the atmosphere (see Refs. 220 and 221), which was assumed to be 0.01106. 13
12C160170
01101-00001 (665 cm'1)
«Ό. 14988 ± 0.00075 cm^atm"1 at300K
01111-11102 (1068 cm'1)
c
10002-00001 (1272 cm'1)
a
0.0075 ± 0.0015 x 10"22 cm-1/mol cm -2 at 294K
205.3
222(1990)
0.03
2(1986)
3.77 ± 0.08 x 10-5 cm"2/atm at 296K c 0.018 ± 0.003 x 10"22 cm'Vmol cm -2 at 294K
0.0510
413(1985)
0.060
2(1986)
10001-00001 (1376 cm"1)
*5.49 ± 0.09 x 10-5 cm-2/atm at 296K
0.0742
413(1985)
11102-00001 (1918 cm"1)
b
0.020
359(1985)
11101-00001 (2062 cm"1)
b
0.115
358(1984)
20001-01101 (2111 cm"1)
b
8.7 x 10"3
360(1986)
00011-00001 (2340 cm'1)
a
2256.
220(1987)
2234.
221(1989)
20003-00001 (2524 cm"1)
0.60 x 10"24 cm'Vmolecule cm -2 at 296K 3.43 x 10"24 cm'Vmolecule cm"2 at 296K 0.26 x 10"24 cm"1/molecule cm"2 at 296K
1.647 ± 0.016 cm"2/atm at300K d 1.653 ± 0.017 cm"2/atm at300K b
0.507 x 10"24 cm'Vmolecule cm"2 at 296K
0.017
274(1984)
174
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (15) BAND
REFERENCE VALUE
cm"zatm"J at300K
REFERENCE
I 2 c i 6 0 n 0 (continued) 20002-00001 (2641 cm"1)
b
1.14 x 10' 24 cm'Vmolecule cm"2 at 296K
0.0382
274(1984)
a
5 v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of I 2 c i 6 0 n 0 i n the sample, which was assumed to be 0.00073.
b
^Band ( ^ t e x t *°Γ definition). Reported intensity is uncorrected for the isotopic abundance of i 2 c T r 0 i 7 0 . H I T R A N value 0.000730 was used.
c
Sy (see text for definition). Reported intensity is uncorrected for the isotopic abundance of 12 C 16 0 17 0 . H I T R A N v a l u e 0.000730 was used.
d
5 v (see text for definition) from measurements of Ref. 220 corrected for errors in temperature and isotope composition, and some new measurements in the 00011-00001 band. Reported intensity is uncorrected for the isotopic abundance of 1 2 C 1 6 0 1 7 0 , which was 0.00074. e
5 v (see text for definition). Reported intensity is scaled using the isotopic abundance of C 1 6 0 1 7 0 appropriate to the atmosphere (see Refs. 220 and 221), which was assumed to be 0.00073. 12
12C160180
01101-00001 (662 cm"1)
f
00011-10001 (966 cm'1)
c
0.018 + 0.001 x 10"22 cnfVmol cm -2 at 294K
0.011
2(1986)
00011-10002 (1073 cm'1)
c
0.036 ± 0.004 x 10"22 cnvVmol cm"2 at 294K
0.022
2(1986)
11102-01101 (1239 cm'1)
d
5.53 ± 0.15 x 10-5cm-2/atm at 296K c 0.021 ± 0.002 x 10-22 cm-Vmol cm -2 at 294K
0.014
413(1985)
0.013
2(1986)
d
7.93 ± 0.07 x 10"4 cm"2/atm at 296K c 0.31 ± 0.016 x 10"22 cm-Vmol cm'2 at 294K
0.195
413(1985)
0.19
2(1986)
d
0.220
413(1985)
10002-00001 (1259 cm"1)
10001-00001 (1365 cm"1)
0.8081 ± 0.0039 cm^atm"1 at300K
8.91 ± 0.06 x 10-4 cm"2/atm at 296K
220.
222(1990)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
175
TABLE II (16) BAND
REFERENCE VALUE
cm^atm"1 at300K
REFERENCE
12 C 16 0 18 0 (continued) 11101-01101 (1387 cm"1)
d
8.49 ± 0.17 x 10-5cm"2/atm at 296K
11102-00001 (1902 cm"1)
b
11101-00001 (2049 cm'1)
b
12201-01101 (2066 cm"1)
b
20001-01101 (2095 cm"1)
b
00011-00001 (2332 cm'1)
a
10011-10002 (2416 cm"1)
b
21103-01101 (2465 cm-1)
b
20003-00001 (2501 cm"1)
b
20002-00001 (2614 cm"1)
b
21102-01101 (2619 cm"1)
b
21102-00001 (3281 cm"1)
b
01121-01101 (4615 cm"1)
b
00021-00001 (4640 cm'1)
b
e
0.021
413(1985)
0.0195
359(1985)
17.51 x 10-24 cm'Vmolecule cm"2 at 296K
0.107
358(1984)
1.94 X 10"24 cm'Vmolecule cm"2 at 296K
0.012
358(1984)
1.16 x 10"24 cm'Vmolecule cm"2 at 296K
7.06 x 10"3
360(1986)
8.952 ± 0.034 cm'2/atm at 300K 8.975 ± 0.041 cm'2/atm at 300K
2439. 2249.
220(1987) 221(1989)
3.20 x 10"24 cm'Vmolecule cm"2 at 296K
0.325 x lO'24 cm"1/molecule cm'2 at 296K 1.15 x 10"24 cm'Vmolecule cm"2 at 296K 11.49 x 10"24 cm'Vmolecule cm"2 at 296K
1.98 x lO"3
274(1984)
7.00 x lO'3
274(1984)
0.06992
274(1984)
0.1529
274(1984)
9.86 x 10"3
274(1984)
4.49 x 10"25 cm molecule"1
2.73 x lO'3
41(1988)
0.0104 + 0.0009 x 10"22 cm'Vmol cm"2
6.33 x lO"3
1(1984)
0.0755
1(1984)
25.13 x 10' 24 cm'Vmolecule cm'2 at 296K 1.62 x 10' 24 cm'Vmolecule cm'2 at 296K
0.124 ± 0.002 x 10"22 cm"Vmol cm"2
176
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (17) BAND
REFERENCE VALUE
cm"2atm_1 at 300K
REFERENCE
12 C 16 0 18 0 (continued) 20012-00001 (4905 cm"1)
See Ref. 53(1985)
a
5 v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of 12 C 16 0 18 0 in the sample, which was assumed to be 0.00367.
b
^Band ( ^ text f° r definition). Reported intensity is uncorrected for the isotopic abundance of 12 C TCQ18 0 . H I T R A N v a l u e 0.00402 was used.
C
5V (see text for definition). Reported intensity is uncorrected for the isotopic abundance of 12 C 16 0 18 0; HITRAN value 0.00402 was used.
d
5 v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of 12 C 16 0 18 0) w h i c h w a s o 00402.
β
5 ν (see text for definition) from measurements of Ref. 220 corrected for errors in temperature and isotope composition, and some new measurements in the 00011-00001 band. Reported intensity is uncorrected for the isotopic abundance of 1 2 C 1 6 0 1 8 0 , which was 0.00399. f
5v 12
(see text for definition). Reported intensity is scaled using the isotopic abundance of C 1 6 0 1 8 0 appropriate to the atmosphere (see Refs. 220 and 221), which was assumed to be 0.00367. 13C160180
10002-00001 (1244 cm"1)
*6.63 ± 0.52 x 10"6 cm"2/atm at 296K
0.14
413(1985)
10001-00001 (1342 cm'1)
a
0.343
413(1985)
11101-00001 (2005 cm"1)
b
0.20 x 10"24 cm-1/molecule cm -2 at 296K
0.11
359(1985)
20002-00001 (2614 cm"1)
b
0.242 X 10-24 cnfVmolecule cm -2 at 296K
0.13
274(1984)
1.55 ± 0.07 x 10"5 cm-2/atm at 296K
a
5 v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of 13 C 16 0 18 0) w h i c h w a s 0.0000452.
b
^Band ( ^ t e x t f° r definition). Reported intensity is uncorrected for the isotopic abundance of C**0 18 0; HITRAN value 0.0000452 was used.
13
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
177
TABLE II (18) BAND
REFERENCE VALUE 12
at 300K
REFERENCE
C 1 8 0,
00011-10001 (967 cm"1)
See Refs. 182(1988) and 400(1989)
00011-10002 (1084 cm'1)
See Refs. 399(1987) and 400(1989) 13 r 18, 18
c o2
00011-10001 (944 cm-1)
See Ref. 400(1989)
00011-10002 (1069 cm'1)
See Ref. 400(1989) CS9
vyvx νλ+ρ3
(877 cm"1) 1
1.064 + 0.020 cm^atm"1 at 297K *64.2 ± 1.2 cm^atm'1 at 297K
1.05 64.
132(1986) 132(1986)
(2185 cm" )
Predicted using vibrational transition moment determined from measurements in the v3-v1 band.
cio 7 vvll p3
1 (946 ^40 cm' cm x;) ΛΛ (1110 cm- 1 )/
See Ref. 7(1984) H 12 C 14 N
vx
(2097 cm"1)
See Ref. 21(1988)
i/3
(3311 cm"1)
267 + 8 cm^atm'1 at 273.2K See also Refs. 142(1984), 150(1984), and 21(1988)
2vx
(4173 cm'1)
See Ref. 21(1988)
vx+v3
(5394 cm"1)
See Ref. 21(1988)
243.
434(1984)
178
ψ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE II (19) BAND
REFERENCE VALUE
at 300K
REFERENCE
H12C14N (continued) 2vyv2l
(5806 cm1) (6085 cm"1)
3^ i>2
2v3
(6229 cm"1) -rlvyv^
1
1369.0 ± 23.0 cm/mol
0.0556
387(1989)
104.0 ± 2.0 cm/mol
4.23 x 10"3 387(1989)
23.21 ± 0.79 cm/mol See also Ref. 21(1988)
9.43 x 10-4
387(1989)
8.20 ±0.11 x 104 cm/mol
3.3
387(1989)
8.499 ± 0.054 X 104 cm/mol See also Refs. 21(1988) and 376(1988)
3.45
387(1989)
(6480 cm' )
(6520 cm"1)
2ίΊ + ί/3
(7455 cm"1)
20.92 ± 0.86 cm/mol See also Ref. 21(1988)
8.50 x 10"4 387(1989)
1094.0 ± 17.0 cm/mol
0.0444
387(1989)
^j+2^3
1010.0 ± 3.0 cm/mol See also Ref. 21(1988)
0.04103
387(1989)
ίΊ+ί>2 +2ι/3 (9257 cm"1)
3.825 ± 0.045 cm/mol
1.55 x 10"4 387(1989)
3^1 + ^3
10.53 ± 0.20 cm/mol
4.28 x 10"4 387(1989)
(8544 cm"1) (8586 cm"1)
1
(9496 cm" )
V'Ll+?>VyV2L
2492.0 ± 38.0 cm/mol
0.101
387(1989)
2547.0 ± 12.0 cm/mol See also Ref. 21(1988)
0.104
387(1989)
1
(9568 cm' ) 3P3
(9627 cm'1)
vl+2v1°+2v3 (9914 cm"1)
7.72 ± 0.08 cm/mol
3.14 X 10-4
387(1989)
v2l+?>v3 (10282 cm"1)
0.702 ± 0.021 cm/mol
2.9 x 10"5
387(1989)
INTENSITIES AND COLLISION-BROADENING PARAMETERS v 179 TABLE I1 (20) BAND
REFERENCE VALUE
cmZatm-l at 300K
REFERENCE
387(1989)
H12C14N (continued)
2v1+2v3 (10631 cm-')
6.79 f 0.10 cmlmol
2.8
V1+3V3 (1 1674 cm-')
100.0 f 0.5 cm/mol
4.062
v21+4v3-v2' (12557 cm-')
176.0 k 7.0 cm/mol
7.15
4v3 (12636 cm-')
154 f 3 cmlmol 157.0 f 1.0 cm/mol
6.26 X l o 3 388(1987) 6.38 x l o 3 387(1989)
3V1+2V3 (12658 cm-')
9.7 f 0.3 cmlmol 9.11 f 0.25 cm/mol
3.9 3.7
X X
lo4 lo4
388(1987) 387(1989)
0.171 k 0.025 cm/mol
6.9
X
10"
387(1989)
2V1+3V3 (13702 cm-')
3.1 f 0.2 cm/mol 2.89 f 0.04 cm/mol
1.3 X lo4 1.17 X lo4
4V1+2V3 (14654 cm-')
8.0 f 0.4 cm/mol 8.33 f 0.10 cm/mol
3.3 3.4
v1+4v3 (14670 cm-')
7.2 0.4 cm/mol 9.42 f 0.09 cm/mol
2.9 x lo4 3.83 x lo4
388(1987) 387(1989)
v2+5v3-v2 (15452 cm-')
16.8 cmlmol
6.82
X
lo4
390(1986)
5v3 (15552 cm-')
17.5 f 0.4 cm/mol 17.5 f 0.4 cm/mol
7.11 7.11
X
lo4 lo4
390(1986) 388(1987)
3v, +3v3 (15711 cm-')
0.05 f 0.01 cm/mol
2
10"
V2'+5V3 (16164 cm-')
0.047 f 0.008 cm/mol
1.9
5Vl+2V3 (16640 cm-')
0.40 f 0.04 cm/mol
1.6 x
V2'
+4V3 (13271 cm-')
X
lo4
X
l o 3 387(1989)
X
X
X X
X
X
lo3 387(1989)
lo4 lo4
10"
388(1987) 387(1989) 388(1987) 387(1989)
388(1987) 388(1987) 388(1987)
180
v
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE II (21) BAND
REFERENCE VALUE
cm^atm"1 at300K
REFERENCE
H 12 C 14 N (continued) 2ί>1+4ϊ'3 (16674 cm"1)
1.7 + 0.1 cm/mol
6.9 x 10"5
388(1987)
ΐΊ+5ι>3 (17550 cm"1)
13.9 ± 0.4 cm/mol 16.7 ± 0.4 cm/mol
5.65 x 10"4 6.78 X 10"4
388(1987) 389(1989)
2.4 ± 0.2 cm/mol
9.8 x IQ'5
388(1987)
6v3
(18377 cm"1)
H 13 C 14 N 2i>3
(6483 cm"1)
l>l+2l>3 (8519 cm'1) 3v3
(9572 cm"1)
8.68 ± 0.21 x 104 cm/mol
3.5
387(1989)
902.0 ± 29.0 cm/mol
0.037
387(1989)
0.103
387(1989)
2537.0 ± 64.0 cm/mol 12
15
H C N 2i/3
(6516 cm"1)
8.78 ± 0.27 x 104 cm/mol
3.6
387(1989)
3i>3
(9621 cm"1)
2900.0 ± 125.0 cm/mol
0.12
387(1989)
DCN νγ
(1925 cm'1)
See Ref. 21(1988)
v3
(2630 cm"1)
See Ref. 21(1988)
2vx
(3836 cm'1)
See Ref. 21(1988)
"l + "3
See Ref. 21(1988) (4523 cm"1)
2v3
(5220 cm"1)
See Ref. 21(1988)
3vx
(5734 cm"1)
See Ref. 21(1988)
2νγ+ν3 (6402 cm"1)
See Ref. 21(1988)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
181
TABLE II (22) BAND
REFERENCE VALUE
cm"zatm"J at300K
REFERENCE
DCN (continued) See Ref. 21(1988)
ί'1+2ϊ>3 1
(7080 cm" ) 3^3
(7771 cm"1)
See Ref. 21(1988) See also Ref. 142(1984) H2160
v2
(1595 cm'1)
3v2
(4667 cm"1)
1 T "2
v2 + v 3
(5235 cm'1)
See Refs. 271(1985), 4(1986), 198(1987), and 6(1988) 28400 ( ± 57c) cm1 Ig cm7
20.8
446(1985)
(5331 cm"1)
Ργ+2ν2 (6775 cm'1) (6872 cm"1) 2νγ
(7202 cm"1)
Vi + V2 + VyV2
(7212 cm'1) (7250 cm"1)
See Ref. 281(1986) See Ref. 281(1986) See Ref. 281(1986) See Ref. 281(1986) See Ref. 281(1986)
2„ 3
(7445 cm"1)
See Ref. 281(1986)
5*2
(7552 cm"1)
0.028 ( ± 20%) x 10"22 cm'Vimolecule cm"2) at 296K See also Ref. 92(1987)
6.8 x 10"5
285(1988)
Ργ+2ν2 2P2+V2
2vx "i + "3
2i>2
24700 ( ± 5%)cm" 1 /gcm- 2 See also Ref. 67(1987)
18.1
446(1985)
182
τ
SMITH, R I N S L A N D , D E V I , R O T H M A N , R A O
TABLE II (23) BAND
REFERENCE VALUE
at 300K
REFERENCE
2.9 X 10"3
285(1988)
1.2
446(1985)
H 2 1 6 0 (continued) (8274 cm"1) 3^2+^3 (8374 cm"1) (8734 cm"1) 2i> 1 + »>2
(8762 cm"1) (8807 cm"1)
6v2
(8890 cm"1)
^2+2^3 (9000 cm 1 )
See Refs. 92(1987) and 285(1988) See Refs. 92(1987) and 285(1988) See Ref. 285(1988) See Refs. 115(1985), 92(1987), and 285(1988) See Refs. 115(1985), 436(1985), 92(1987), and 285(1988) 1.2 ( ± 20%) x 10' 22 cm-Vimolecule cm-2) at 296K See Refs. 115(1985), 436(1985), 92(1987), and 285(1988)
Vi+3i>2 3^2 + ^3 1^2+2^3 4^2 + ^3 (9834 cm"1)
1610 ( ± 10%) cm'Vg cm'2
See Ref. 121(1989)
2^+21/2 (10284 cm'1)
See Ref. 121(1989)
Ργ +2^2 + ^3 (10329 cm"1)
See Ref. 121(1989)
2^2+2^3 (10537 cm"1)
See Ref. 121(1989)
(10600 cm-1)
See Ref. 121(1989)
2νγ +Ρ3 (10613 cm'1)
See Ref. 121(1989)
3^
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
183
TABLE II (24) BAND
REFERENCE VALUE
cm^atm"1 at300K
REFERENCE
H 2 1 6 0 (continued) See Ref. 121(1989)
ί>1+2ί'3
(10869 cm"1)
3P3
(11032 cm·1)
See Ref. 121(1989)
2Ργ+2Ρ2 \ Ργ+2Ρ2 + Ρ-$ 3PX 1 2Ργ + Ρ<$ 1
»Ί+2ι>3 3^
1110 ( ± 10%) cm-Vg cm'2
0.81
446(1985)
51 ( ± 10%) cm-Vg cm"2
0.037
446(1985)
/
V\+3P2+V3
\
(11813 cm·1) 3Ργ+Ρ2 J (12140 cm"1) ( 2ργ + Ρ2+Ρι I (12151 cm"1) \ Ργ + Ρ2 + 2Ρ<±
(12408 cm- 1 )/
2Ργ + Ρ2 + Ρ3
See Ref. 314(1988)
P\+^P2 + V3
See Refs. 283(1986) and 187(1989)
4i/ 2 +2i>3
See Refs. 283(1986) and 187(1989)
3^+2^2 (13642 cm"1)
See Refs. 283(1986) and 187(1989)
2i' 1 +2j>2+J'3
See Refs. 94(1986), 283(1986), and 187(1989)
2ργ+2ρ$
See Refs. 283(1986) and 187(1989)
3Ργ + Ρ<$
See Refs. 94(1986), 283(1986), and 187(1989)
(12151 cm"1) (13200 cm"1) (13500 cm'1)
(13653 cm"1) (13828 cm'1) (13831 Dm'1)
184
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N ,
RAO
TABLE II (25) BAND
REFERENCE VALUE
at 300K
REFERENCE
H 2 1 6 0 (continued) 2l>!+ 2 »>2 + ^3 2ί>1+2ί>3
56 ( ± 10%) cm'Vg cm'2
v^-\-2vj+2v>$ (13911cm· 1 )
See Ref. 187(1989)
2ϊ>2 + 3ϊ>3
See Ref. 283(1986)
(14066 cm-1) 4vx
(14221 cm"1) (14319 cm'1)
See Ref. 283(1986) See Ref. 283(1986)
2νγ +3^2"·" ^3 (15119 cm"1)
See Ref. 283(1986)
2i>1 + »'2+ 2^3 (15345 cm'1)
See Ref. 283(1986)
3l^ + J>2 + ^3 (15348 cm"1)
See Ref. 283(1986)
4^1 + ^2 (15743 cm"1)
See Ref. 283(1986)
Vi +^2 + 3^3 (15833 cm'1)
See Ref. 283(1986)
21/^2^2+2^3 (16819 cm"1)
See Ref. 99(1985)
3»^+21/2+^3 (16822 cm'1)
See Ref. 99(1985)
3v\+2v^ (16898 cm 1 )
See Ref. 99(1985)
2v\+3v-$ (16899 cm 1 )
See Ref. 99(1985)
0.041
446(1985)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
185
T A B L E II (26)
BAND
REFERENCE VALUE H 2 1 6 0 (continued) See Ref. 99(1985)
ρχ +2P2+3P3 1
(17313 cm" ) (17458 cm"1)
See Ref. 99(1985)
4 ^ + 1/3 (17496 cm"1)
See Ref. 99(1985)
3PX+3P2+P2
See Ref. 99(1985)
2PX + P2+3P3 (18393 cm"1)
S e e Ref
3PX+P2+2P2
See Ref. 99(1985)
4ι>1 + ι>2+μ3 (18990 cm"1)
See Ref. 99(1985)
4PX+2P2+P3
See Ref. 99(1985)
3*!+3*3 (19781 cm'1)
See Ref. 99(1985)
4PX+2P3
See Ref. 99(1985)
5PX + P3 (20543 cm"1)
See Ref. 99(1985)
3PX+P2+3P3
See Ref. 99(1985)
4PX+P2+2P3
See Ref. 99(1985)
4ΡΧ+3Ρ3
See Ref. 99(1985)
5vx
(18266 cm'1)
(18393 cm"1)
(19740 cm"1)
(19782 cm'1)
(21222 cm"1) (21222 cm"1) (22529 cm"1)
· 99(1985)
cm"2atm-1 at 300K
REFERENCE
186
v
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (27) BAND
REFERENCE VALUE
cm"zatm"J at300K
REFERENCE
HDO v2
ρχ
2v2
\+v2
(1403 cm"1)
(2724 cm"1)
(2782 cm"1)
v
3P2
(4100 cm"1)
(4145 cm"1)
*0.353 X 10"17 cm_1/(molecule cm"2) at 296K b 0.595 x 10-17 cm_1/(molecule cm"2) at 296K See also Ref. 411(1986) c
0.206 X 10"17 cm"V(molecule cm"2) at 296K d 0.438 x 10"19 cm"V(molecule cm"2) at 296K ^.211 x 10"17 cm'Vimolecule cm"2) at 296K
c
86.4 146.
50.4 1.07 51.6
156(1986) 156(1986)
334(1985) 334(1985) 334(1985)
0.174 X 10"18 cm"1/(molecule cm"2) at 296K «kUOö x 10"18 cm'Vimolecule cm'2) at 296K *0.280 x 10"18 cm'Vimolecule cm"2) at 296K
4.26
334(1985)
2.59
334(1985)
6.85
334(1985)
f
0.201 X 10"18 cm'Vimolecule cm"2) at 296K 80.115 x 10"19 cm'Vimolecule cm"2) at 296K
4.92
332(1986)
0.281
332(1986)
f
2.59
332(1986)
0.201
332(1986)
0.106 x 10"18 cm"V(molecule cm"2) at 296K «0.821 x 10"20 cm'Vimolecule cm"2) at 296K
a
5 B a n d value for /4-type transitions.
b
5 B a n d value for B-type transitions.
c
5 B a n d value derived from a re-analysis of/1-type transitions whose measurements were reported in Ref. 494 of Smith et al. [2].
d
5 B a n d value derived from a re-analysis of 5-type transitions whose measurements were reported in Ref. 494 of Smith et al. [2].
e
5 B a n d value derived from a re-analysis of Λ-type and Ä-type transitions whose measurements were reported in Ref. 494 of Smith et al. [2].
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
187
TABLE II (28) BAND
REFERENCE VALUE
at300K
REFERENCE
HDO (continued) f 5 B a n d value derived from a re-analysis of Λ-type transitions whose measurements were reported in Ref. 488 of Smith et al. [2]. 8
^Band value derived from a re-analysis of B-type transitions whose measurements were reported in Ref. 488 of Smith et al [2].
D2O "2
(1178 cm"1)
See Ref. 411(1986)
HTO "2
(1324 cm"1)
See Ref. 116(1987) H2180
3P2
(4658 cm'1) (5212 cm"1)
2l>2 + *'3-i,2
(5256 cm"1)
i>2+p3
1
4.88 x 10"22 cm molecule-1
0.0119
118(1985)
3.09 x 10"20 cm molecule'1
0.756
118(1985)
See Refs. 119(1986) and 417(1989) 7.62 x 10' 19 cm molecule"1
18.6
118(1985)
(5310 cm' ) 4J/ 2
(6134 cm"1)
1>γ+2ν2
1
(6756 cm" )
2^2 + v3
(6845 cm"1)
2vx
(7186 cm"1)
a
7 x 10"23 cm^molecule^cm"2 at300K See also Ref. 117(1986)
0.002
416(1989)
a
0.033 x 10"19 cm^molecule^cnT2 at 300K See also Ref. 117(1986)
0.081
416(1989)
a
0.403 x 10"19 cm'Molecule -1 cm -2 at 300K See also Ref. 117(1986)
0.986
416(1989)
*0.780 x 10"19 cm"1 molecule" ^m"2 at 300K See also Ref. 117(1986)
1.91
416(1989)
188
τ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE II (29) BAND
at300K
REFERENCE VALUE
REFERENCE
H 2 18 0 (continued) vx + v3 (7229 cm"1) 2P3
(7419 cm'1)
a
4.852 X lO'19 cm^molecule^cm"2 at 300K See also Ref. 117(1986)
11.87
416(1989)
*0.056 x 10"19 cm^molecule^cm'2 at 300K See also Ref. 117(1986)
0.14
416(1989)
4^2 + ^3
See Ref. 120(1987)
2^+2^ (10257 cm"1)
See Ref. 120(1987)
1^+2^2 + ^3
See Ref. 120(1987)
(9795 cm"1)
(10296 cm'1) 3vx (10574 cm'1)
See Ref. 120(1987) See Ref. 120(1987)
2i'1H-i»3
(10585 cm'1) v{+2i>2
See Ref. 120(1987)
(10840 cm"1) 3*>3 (10994 cm-1) a
From a re-analysis
See Ref. 120(1987) of the data from Ref. 117. HO.
v3
(1080 cm'1)
1.1 x 10'18 cm molecule"1
27.
79(1983)
v2
(1390 cm*1)
58 ± 16 cm-2(STP atm)"1
53.
448(1989)
2
18.
448(1989)
vx
1
(3436 cm" )
1
20 ± 6 cm" (STP atm)"
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
189
TABLE II (30) BAND
REFERENCE VALUE
at 300K
REFERENCE
HOC1 i>3
(720 cm"1)
45 ( ± 5%) cm^atm'1 at 295K See also Ref. 242(1986)
44.
321(1979)
v2
(1238 cm'1)
265 ( ± 5%) cm^atm'1 at 295K See also Ref. 242(1986)
261.
321(1979)
H 2 32 S 2v2
(2354 cm"1)
0.1390 x 10'19 cm-Vmolecule cm'2
0.3401
250(1984)
νγ
(2614 cm'1)
0.1776 x 10'19 cm-Vmolecule cm"2
0.4345
250(1984)
0.4520 x 10"20 cm-Vmolecule cm"2
0.1106
250(1984)
0.2373 x 10' 20 cm'Vmolecule cm*2 at 296K
0.06696
249(1987)
0.8641 x 10"20 cm'Vmolecule cm"2 at 296K
0.2114
249(1987)
0.4521 X lO"22 cm'Vmolecule cm"2 at 296K
0.001106
249(1987)
v3
1
(2628 cm" ) 1
(6288 cm" ) 1
(6289 cm" ) j/2+2i>3
(6389 cm'1)
H 2 33 S 2i>2 v
(2353 cm'1) 1
See Ref. 250(1984)
\
(2613 cm' )
See Ref. 250(1984)
"3
(2627 cm'1)
See Ref. 250(1984) H 2 34 S
2v2
(2352 cm'1)
See Ref. 250(1984)
vx
(2612 cm'1)
See Ref. 250(1984)
v3
(2626 cm'1)
See Ref. 250(1984)
2^1 + ^2 (6283 cm'1)
See Ref. 249(1987)
190
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (31) BAND
REFERENCE VALUE
cm^atm'1 at300K
REFERENCE
H 2 34 S (continued) (6284 cm"1) ί>2+2ι>3
(6384 cm'1)
See Ref. 249(1987) See Ref. 249(1987)
N20 2i>2° (1168 cm"1)
6.98 ± 0.26 cm^atm'1 at 296K
6.9
407(1989)
2v2° Band System
8.46 ± 0.09 cm^atnf1 at 297K
8.38
419(1988)
1
vx
(1285 cm" )
vi
Band System
v
2 ~^~vyv2
See Ref. 432(1989) 225 ± 2 cm^atm-1 at 297K
223.
419(1988)
1191.
259(1986)
See Ref. 259(1986)
(2224 cm"1)
i>3
(2224 cm"1)
(3364 cm"1) I "ι + ^ , ' (3481 cm"1) Band System 2i/ 1 +2i/ 2 ° (3749 cm"1) 3^ (3836 cm"1) Band System
1203 ± 22 cm^atm'1 at 297K a
49.9 ± 0.3 cm'Viatm cm) STP
b
45.4
174(1986)
3.25 ± 0.02 cm-V(atm cm) STP
2.96
174(1986)
0.035 ± 0.002 cm-V(atm cm) STP 288 x IO-4 cm^amagaf1
0.032 0.0262
174(1986) 8(1989)
e
1.67 ± 0.01 cm-V(atm cm) STP 1850 x 10"4 cm^amagaf1
1.52 0.168
174(1986) 8(1989)
ί/ 1 +2ί/ 2 °+ι/ 3 (4630 cm'1)
1780 x 10"4 cm^amagaf1
0.162
8(1989)
2^2 + ^3
1080 x 10"4 cm^amagaf1
0.0983
8(1989)
l* 1 + 1*2 +"3 (4062 cm"1) 2v3
(4417 cm'1)
(4731 cm"1)
c
d
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
191
TABLE II (32) BAND
REFERENCE VALUE
at 300K
REFERENCE
N 2 0 (continued) 21Ί+Ϊ/3 J Band System
f
1.14 ± 0.01 cm_1/(atm cm) STP
1.04
174(1986)
2i/1+4i>2° (4911 cm"1)
120 x 10"4 cm^amagaf1
0.0109
8(1989)
670 x 10"4 cm"zamagaf
0.0610
8(1989)
720 x 10"4 cm^amagat"1
0.0656
8(1989)
«0.153 ± 0.002 cm_1/(atm cm) STP
0.139
174(1986)
112 x 10"4 cm^amagaf1
0.0102
8(1989)
72.7 x 10"4 cm^amagaf1
6.62 x 10-3
8(1989)
184 x 10"4 cm_2amagat"1
0.0168
8(1989)
*21+2"3
(4978 cm"1) 3i/ 1 +2// 2 ° (5026 cm"1) 4Ϊ/Χ
(5107 cm-1)
2I/,+4I/2° "2 +2J> 3 3^+2P20 4I/J
Band System 6i> 2 +»>3
(5647 cm"1) (5888 cm"1) (5975 cm"1)
d
14.4 x 10"4 cm^amagat'1
1.31 X 10"3
8(1989)
d
45 x 10"4 cm^amagaf1
4.1 x 10"3
8(1989)
21 x 10"4 cm^amagaf1
1.9 x lO"3
8(1989)
3ί/1+4ι/2° (6192 cm"1) 4I/ 1 +2J/2°
1
(6295 cm' )
5vx 3i>3
(6373 cm"1) 1
(6581 cm" )
d
4
330 x 10" cm^amagaf
integrated intensity from 3200 to 3670 cm-1. integrated intensity from 3670 to 4000 cm'1.
1
0.0301
8(1989)
192
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (33) BAND
REFERENCE VALUE
cm"zatm_1 at 300K
REFERENCE
1015.
104(1986)
N 2 0 (continued) c
Integrated intensity from 4000 to 4100 cm"1.
d
Liquid-phase measurement.
integrated intensity from 4100 to 4530 cm"1. integrated intensity from 4530 to 4900 cm"1. «Integrated intensity from 4900 to 5300 cm"1.
N0 9 1
v2
(750 cm" )
See Ref. 333(1988)
P3
(1621 cm"1)
See Ref. 301(1990)
v3
Band System
4.15 x 10"17 cm molecule"1 16
0,
See Ref. 340(1988)
2v 2 - p 2
(698 cm"1) v2
(701 cm"1)
See Ref. 101(1990)
2vyvx v3
(955 cm"1) (1042 cm"1)
vx
(1103 cm"1)
10-^m Band System 2v2
See Ref. 340(1988)
(1399 cm"1)
Vi + VyV2
(1410 cm"1)
0.1413 x 10"16 cm'Vmolecule cm"2 at 296K See also Ref. 341(1985) 0.5403 x 10"18 cm'Vmolecule cm"2 at 296K See also Ref. 341(1985)
345.7
13.22
159(1987)
159(1987)
See Ref. 161(1990) 5.43 x 10"22 cm'Vmolecule cm"2 at 296K
0.0133
162(1989)
1.01 x 10"21 cm'Vmolecule cm"2 at 296K
0.0247
162(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
193
TABLE II (34) BAND
REFERENCE VALUE 16
cm"2atm-1 at 300K
REFERENCE
0 3 (continued)
2v2 + VyV2
(1707 cm'1)
3.45 x 10'21 cm-1/molecule cm"2 at 296K
0.0844
368(1990)
v2+v3
(1727 cm"1)
0.536 X 10"19 cm'Vmolecule cm -2 at 296K
1.31
270(1987)
ίΊ+2ϊ>2-ί>2 (1786 cm"1)
1.40 x 10"21 cm-1/molecule cm -2 at 296K
0.0343
368(1990)
(1796 cm"1)
0.237 x 10"19 cm-1/molecule cm'2 at 296K
0.580
270(1987)
0.1120 x 10'18 cm'Vmolecule cm'2 at 296K
2.740
367(1988)
2v3
l + v3
(2058 cm"1)
v
2vx
1
(2111cm" ) (2201 cm -1 )
0.1236 x 10"17 cm'Vmolecule cm"2 at 296K 0.3371 x 10"19 cm"1/molecule cm"2 at 296K
30.24
367(1988)
0.8247
367(1988)
4.8-^m Band System See Ref. 101(1990) 2^2 + ^3
(2408 cm'1)
4.35 x 10"22 cm'Vmolecule cm"2 at 296K
0.0106
368(1990)
ί>1+2ι>2 (2487 cm'1)
4.08 x 10' 22 cm'Vmolecule cm"2 at 296K
9.98 X 10'3
368(1990)
ϊ>2+2ϊ/3
0.336 x 10' 20 cm'Vmolecule cm"2 at 296K
0.0822
393(1990)
0.243 x 10"19 cm'Vmolecule cm"2 at 296K
0.594
393(1990)
0.115 x 10"20 cm'Vmolecule cm"2 at 296K
0.0281
393(1990)
0.131 X 10"18 cm'Vmolecule cm'2 at 296K
3.20
102(1990)
0.311
102(1990)
(2726 cm'1) V\ + Vj + V3
(2785 cm"1)
2i/j4-i^2
1
(2886 cm" )
3v3
VX+2P3
(3046 cm'1)
(3084 cm"1)
0.127
X 1019
cnrVmolecule cm"2 at 296K
194
ψ
SMITH, R I N S L A N D , D E V I , R O T H M A N , R A O
TABLE II (35) BAND
REFERENCE VALUE 16
cm"2atm-1 at300K
REFERENCE
0 3 (continued)
0.934 X 10' 20 cm"1/molecule cm"2 at 296K
0.228
102(1990)
ι>2+3ϊ>3
0.615 x 10"20 cm'1/molecule cm"2 at 296K
0.150
273(1990)
I>1 + J>2+2»'3
0.138 x 10"21 cm"1/molecule cm"2 at 296K
3.38 x 10"3
273(1990)
(3186 cm"1) (3698 cm"1) (3738 cm"1)
See also Ref. 163(1990) 16Q16Q180
p2
(685 cm"1)
0.649 x 1 0 1 8 cm'Vmolecule cm"2 at 296K
15.9
160(1989)
v3
(1028 cm"1)
0.128 x 10"16 cm'Vmolecule cm"2 at 296K See also Ref. 364(1985)
313.1
100(1986)
νλ
(1090 cm"1)
*0.612 x 10"18 cm'Vmolecule cm"2 at 296K b 0.512 x 10"18 cm"1/molecule cm'2 at 296K
15.0
100(1986)
12.5
100(1986)
15.8
160(1989)
See also Ref. 163(1990) a
^Band ( ^
b
text
f° r definition) for Λ-type transitions only.
5 B a n d (see text for definition) for B-type transitions only. 16 0 18 0 16 0 (693 cm 1 )
0.645 x 10"18 cm"1/molecule cm'2 at 296K
(1008 cm"1)
0.133 x 10"16 cm'Vmolecule cm"2 at 296K See also Ref. 364(1985)
325.
157(1986)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
T
195
TABLE II (36) BAND
REFERENCE VALUE
at300K
REFERENCE
I 6 0 i 8 0 i 6 0 (continued) νγ
(1074 cm"1)
0.241 X 10"18 cm'Vmolecule cm"2 at 296K
5.90
157(1986)
See also Ref. 163(1990) 16Q18Q18Q
v2 a
(678 cm"1)
°0.600 x 10"18 cm"1/molecule cm"2 at 296K
14.7
336(1990)
14.7
336(1990)
14.5
336(1990)
29. 29.5
57(1986) 50(1990)
5 B a n d (see text for definition) for B-type transitions only. 18 16 18
o o o
v2
(668 cm"1)
0.602 x 10"18 2
cm'Vmolecule cm' at 296K v3
(1019 cm"1) 1
vx
(1072 cm" )
v2
(661 cm"1)
See Ref. 158(1987) See Ref. 158(1987)
0.593 x 10"18 1
2
cm" /molecule cm' at 296K v2
(985 cm"1)
See Ref. 158(1987)
vx
(1042 cm"1)
See Ref. 158(1987) 16012C32S
vx 2v2° 3v2l-v2
(859 cm"1) (1047 cm"1)
(1053 cm"1)
29.63 ± 1.48 cm^atm"1 at 298K 29.69 ± 0.15 cm^atm"1 at 298K See Ref. 143(1988) See Ref. 143(1988)
196
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (37) BAND
cm^atm"1 at 300K
REFERENCE VALUE
REFERENCE
16012C32S ( c o n t i n u e d )
P3 P2+P3
(2062 cm"1) 1
See Ref. 295(1987) 0.1474 + 0.0090 cm^atm"1 at 295K
0.1449
137(1986)
(2575 cm' ) 16 0 13 C 32 S
vx
(859 cm'1)
29.21 ± 0.16 cm^atm"1 at 298K
29.0
50(1990)
28.8
50(1990)
29.5
50(1990)
102.9
230(1984)
16012C33S
px
(859 cm"1)
28.98 ± 0.37 cm^alm'1 at 298K 16 0 12 C 34 S
px
(859 cm'1)
29.68 ± 0.16 cm^atm"1 at 298K S0 2
P2
(518 cm'1)
25.33 ± 0.04 km/mol
vx
(1151 cm"1)
20.60 ± 0.07 km/mol See also Ref. 13(1989)
v3
(1362 cm"1)
192.13 ± 0.14 km/mol
83.68
230(1984)
780.5
230(1984)
611.
444(1989)
CF3 P3
(1264 cm'1)
See Refs. 75(1987) and 76(1988) CH3
p2
(606 cm"1)
2.5 ± 0.8 X 10"17 cm"1 (molecule/cm2)"1 C
(P4+P5)°-P41 (729 cm'1) P5
(729 cm'1)
2H2
13.7 ± 0.3 cm^atm"1 at 296K 581 ± 10 cm^atm"1 at 296K
13.5 573.
439(1989) 439(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
197
TABLE II (38) BAND
REFERENCE VALUE
cm^atm"1 at 300K
REFERENCE
C 2 H 2 (continued) ("4+"5)° (1328 cm"1) (3282 cm"1) i>3
(3295 cm"1)
(2v2+vA+v5f
See Ref. 391(1988) See Ref. 391(1988) See Ref. 391(1988)
(5230 cm"1)
See Ref. 391(1988)
(5260 cm'1)
See Ref. 391(1988)
1 2vyv5l (5772 cm' ) (5783 cm"1)
2vr"5
64.4 + 2.0 cm^atm"1 at 296K
See Ref. 391(1988)
. (5979 cm"1)
See Ref. 391(1988)
vx + v3+2v£ (7733 cm"1)
See Ref. 309(1989)
{Vl+v3+2vA\ (1131 cm"1)
See Ref. 309(1989)
3P3
(9640 cm'1)
See Ref. 391(1988)
v\ +
v2+v3+2v® (9668 cm"1)
See Ref. 391(1988)
2ΪΊ+Ϊ>3
(9835 cm'1)
See Ref. 391(1988)
V\+2v2+v3+2v£ (11571cm- 1 )
See Ref. 323(1988)
vx+3v2+?>vAx + vcl (11586 cm'1)
See Ref. 323(1988)
64.
347(1984)
198
v
SMITH, R I N S L A N D , D E V I , R O T H M A N , R A O
TABLE II (39) cm-2atm_1 at300K
REFERENCE
3.7 ( ± 20%) cm/mol 7.2 cm/mol
1.5 x 10"4 2.9 x 10"4
252(1989) 252(1989)
38 ± 1 cm/mol
1.5 x 10"3
252(1989)
0.95 cm/mol
3.9 x 10"5
252(1989)
0.52 cm/mol
2.1 x 10"5
252(1989)
(17519 cm"1)
3.0 cm/mol See also Ref. 406(1988)
1.2 x 10"4
252(1989)
(18430 cm-1)
4.8 + 0.4 cm/mol
2.0 X 10"4
252(1989)
REFERENCE VALUE
BAND
C 2 H 2 (continued) J>2+3i>3
See Ref. 323(1988)
2ρ 1 + ί>2+ί'3
See Ref. 323(1988)
(11600 cm-1) (11783 cm-1)
!/ 2 +4i> 3 u
(14597 cm"1) (14617 cm'1)
5v3u (15600 cm-1) (15948 cm"1) 5P3U+V41
1
(16137 cm" ) i/ 2 +5i>3 U
6P3U
C2N2 vs
(226 cm-1)
36.28 ± 0.32 km/mol
v3
(2149 cm"1)
4.55 ± 0.04 km/mol
147.
229(1983)
18.5
229(1983)
36.
369(1986)
21. 20.
135(1988) 357(1989)
COF2 v6
(774 cm'1)
vx
(1942 cm"1)
a
1.47 ± 0.22 x 10"18 cm molecule"1 See also Ref. 183(1990) See Ref. 369(1986)
integrated intensity of the Q branch. H2CO vA
(1167 cm-1)
20.9 ± 1.3 cm^atm"1 at 297K 4.82 ± 0.10 km/mol See also Ref. 312(1987)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS T
199
T A B L E II (40)
BAND
REFERENCE VALUE
at 300K
REFERENCE
H2CO (continued) (1249 cm"1)
P6
'4 1 (1500 cm"1)
P3
38.0 ± 1.9 cm^atm·1 at 297K 8.20 ± 0.24 km/mol See also Ref. 312(1987)
38. 33.
135(1988) 357(1989)
13.02 ± 0.26 km/mol
52.9
357(1989)
11.59 ± 0.31 km/mol
47.1
357(1989)
H202 APX (13366 cm"1) * 4P5 (13366 cm" 1 )/
See Ref. 147(1989) trans-HONO
(1263 cm"1)
P3
See Ref. 264(1988) 14
NH 3
s
2,2 -,2< 2P2*-P2S
P2S A
P2
P4
(629 cm"1) (950 cm"1) (932 cm'1)> l (968 cm'1) /
(1627 cm"1)
See Refs. 85(1983), 203(1986), 39(1987), and 386(1988) 567.6 ± 9.4 a t m - W 2 STP See also Refs. 239(1981), 313(1985), 44(1986), 95(1986), 203(1986), and 39(1987)
517.
227(1985)
110.5 ± 2.0 a t n r W 2 STP
101.
227(1985)
See also Ref. 253(1987) 2v2* (1882 cm"1) ργ P3
(3337 cm"1) * (3444 cm"1) /
5P{ 6PX
See Ref. 253(1987) 43.9 ± 0.6 a t n r W 2 STP
39.9
227(1985)
(15504 cm"1)
0.66 cm^nWamagar1 See also Ref. 178(1969)
60.
180(1975)
(18116 cm'1)
See Ref. 178(1969)
200
v
SMITH, R I N S L A N D , D E V I , R O T H M A N , R A O
TABLE II (41) BAND
REFERENCE VALUE 15
2P2S-P2& a
(629 cm"1) (
NH 3
See Refs. 203(1986) and 377(1986)
(950 cm"1) )
P2S p2a
(928 cm'1) \ (963 cm'1) /
See Ref. 203(1986)
P4
(1622 cm"1)
145.8 ± 7.6 cm^atm"1 at 300K 14
P2*
p2a p2s
pf p2s
REFERENCE
S
2"2 -"2
P2S
cm^atm"1 at 300K
(928 cm"1) i (963 cm"1) /
(746 cm"1) \ (749 cm"1) i
(740 cm"1) i (743 cm"1) /
146.
272(1990)
ND 2 H
See Ref. 223(1988) 14
ND 3
15
ND 3
See Ref. 239(1981)
See Ref. 239(1981) N03
p2
(762 cm"1)
1.1 ± 0.8 x 10"18 cm molecule-1
27.
172(1987)
p3
(1492 cm'1)
6.0 ± 4.0 x 10' 18 cm molecule"1
147.
172(1987)
PH3 2P2*
(1984
P2+P4
I (2110 cm"1) ( (2236 cm"1) ( (2323 cm"1) ) (2328 cm' 1 )/
2ΡΛ px p3
cmM
See Refs. 30(1980) and 260(1985)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
201
TABLE II (42) BAND
cm^atm'1 at300K
REFERENCE
1974.
422(1988)
1936.
422(1988)
867. 900.
294(1985) 449(1987)
3418.
422(1988)
1470. 1505. 1718. 1718.
294(1985) 449(1987) 423(1988) 422(1988)
590. 671. 671.
294(1985) 423(1988) 422(1988)
300 ± 50 cm^atm'1 at STP
273.
319(1986)
1278 ± 63 cm^atm'1 at STP 292 cm^atm"1 at 296K b 292 cm^atm"1 at 296K c 8.70 x 10' 18 cm molecule'1 1421 ± 12 cm^atm'1 at 300K 1421 ± 12 cm^atm'1 at 300K
1164. 288. 288. 213. 1421. 1421.
319(1986) 437(1986) 438(1987) 449(1987) 423(1988) 422(1988)
REFERENCE VALUE CBrF3
7 ?
(1085 cm"1) 1
(1209 cm" )
1974 ± 10 cm^atm'1 at 300K 1
1936 ± 18 cnAtm' at 300K CC14
v3
(794 cm'1)
879 cm^atm'1 at 296K 3.68 x 10"17 cm molecule"1 See also Ref. 155(1990)
CF4 2vA v3
(1261 cm'1) χ (1283 cm"1) /
3418 ± 179 cm^atm'1 at 300K See also Ref. 294(1985) CFCU
vA
(846 cm"1)
vx
(1085 cm"1)
1490 6.15 1718 1718
cm^atm'1 at 296K x 10~17 cm molecule'1 ± 17 cm^atm'1 at 300K ± 17 cm^atm'1 at 300K
598 cm^atm'1 at 296K 671 ± 8 cm^atm'1 at 300K 671 ± 8 cm^atm'1 at 300K See also Ref. 155(1990) CF2C12 a
ί>3 + ϊ>9 1
(889 cm' ) a
ve
(923 cm'1)
b
202
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (43) BAND
cm"zatm"J at300K
REFERENCE
1520 cm^atnT1 at 296K 1646 ± 80 cm^atm"1 at STP a 1602 ± 108 cm^atnr1 at STP
1500. 1499. 1459.
294(1985) 319(1986) 319(1986)
REFERENCE VALUE CF2C12 (continued) d
vx
(1102 cm"1)
1129 ± llcm^atm^atSOOK 1129 ± 1 1 cm^atnT1 at 300K
1129. 1129.
423(1988) 422(1988)
v%
(1161cm"1)
5.85 x 10 -18 cm molecule-1 717 ± 14 cm^atm"1 at 300K 717 ± 14 cm^atm'1 at 300K
143. 717.
111.
449(1987) 423(1988) 422(1988)
1747. 1973. 1920.
294(1985) 319(1986) 319(1986)
1770 cm-2atm_1 at 296K 2167 ± 103 cm^atnr1 at STP a 2109 ± 84 cm^atm"1 at STP d
See also Ref. 155(1990) a
Derived from measurements at 200K.
b
CF 2 35 Cl 2 isotope only.
integrated intensity of the Q branches. d
Derived from measurements at 296K. CF3C1
vx
(1109 cm"1)
1820 ± 7 c n r W 1 at 300K
1820.
422(1988)
vA
(1212 cm'1)
2162 ± 9 cm^atm"1 at 300K
2162.
422(1988)
vA
(1306 cm"1)
133. 127.
228(1987) 78(1989)
v2
(1534 cm"1)
'41 p2f
146.0 ± 2.4 cm^atm'1 STP 129.05 ± 3.87 cm^atm"1 at 296K See also Refs. 74(1985), 31(1986), and 297(1988)
a
a
1.36 ± 0.04 cm^atm"1 at 296K
a
130.41 ± 3.91 cm^atm"1 at 296K
1.34 129.
78(1989) 78(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
203
TABLE II (44) BAND
REFERENCE VALUE 12
REFERENCE
CH 4 (continued)
0.050 ± 0.002 cm^atm"1 at 296K
"3-"4
at300K
0.049
204(1985)
(1720 cm"1)
p3
(3019 cm"1)
298.1 ± 1.0cm_2atm_1 STP See also Refs. 74(1985), 19(1985), and 10(1989)
3v4
(3868 cm"1)
b
0.85 ± 0.02 cm^atm"1 STP
0.77
175(1986)
3v4
(3868 cm"1) c
1.42cm- 2 atm- 1 at 297K
1.41
77(1988)
ϊ>2+2ί/4
(4125 cm'1)
V\+V4
"l+"4
271.
228(1987)
(4220 cm'1) See Ref. 74(1985) (4220 cm-1)
1*2+2^4
\
(4125 cm"1) *
v
\ + v4
"3+"4
v2+v2
(4220 cm"1)
22.5 ± 0.2 cm^atm"1 STP
175(1986)
(4544 cm· 1 )/ ( - 5 5 9 0 cm-1) (6005 cm"1)
Unassigned lines (5500-6200 cm"1)
See Ref. 289(1990) 1.641 cm^atm"1 at 296K See Refs. 288(1988) and 289(1990)
a
Sum of line intensities measured from 1080 to 1752 cm-1
integrated intensity measured from 3700 to 3970 cm -1 . c
20.5
(4321 cm"1)
J>3+2I>4
2u3
d
Sum of line intensities measured from 3700 to 4136 cm-1
integrated intensity measured from 3970 to 4900 cm -1 .
1.619
288(1988)
204
v
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (45) BAND
REFERENCE VALUE 13
1/4
(1299 cm"1)
a
v2
(1529 cm'1)
a
a
REFERENCE
CH 4
124.04 ± 4.96 cm^atm"1 at 296K See also Ref. 425(1989) 1.18 ± 0.05 cm^atm"1 at 296K
a
"4 1 v2\
at300K
125.22 ± 5.01 embalm'1 at 296K
122. 1.16 124.
78(1989) 78(1989) 78(1989)
Sum of line intensities measured from 1080 to 1752 cm"1. 12
CH3D
"6
(1156 cm"1)
61.7 ± 1.8cm- 2 atm- 1 at295K 53.2 ± 0.6 cm^atm'1 at 296K See also Refs. 268(1987), 409(1987), and 428(1989)
60.7 52.5
65(1985) 410(1988)
"3
(1307 cm"1)
49.3 + 1.4 cm^atm"1 at 295K 40.1 ± 0.9 cm^atnr1 at 296K See also Refs. 276(1986), 409(1987), and 424(1989)
48.5 39.6
65(1985) 410(1988)
"5
(1471 cm"1)
13.4 ± 0.6 cm^atm"1 at 296K See also Ref. 409(1987)
13.2
410(1988)
"2
(2200 cm'1)
See Ref. 122(1987)
77.3
228(1987)
12
"4
2„4 i>2 +
"4
CD 4
(998 cm"1)
84.9 ± 2.8 cm^atm'1 STP
(1996 cm"1)
31.48 x 10"21 cm/molecule
0.7701
329(1987)
57.33 x 10"21 cm/molecule
1.403
329(1987)
(2089 cm'1)
"l
(2061 cm"1)
0.50 x 10*21 cm/molecule
0.012
329(1987)
2v2
(2181 cm"1)
42.68 x 10 -21 cm/molecule
1.044
329(1987)
"3
(2249 cm'1)
133.1 ± S.Scm^atm-1 STP 4891.18 x 10"21 cm/molecule
121. 119.658
228(1987) 329(1987)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
205
TABLE II (46) REFERENCE VALUE
BAND
12
2vA v2+vA , "1
Pentad
cm'^atnv at300K
REFERENCE
CD 4 (continued)
5023.17 x 10' 2 1 cm/molecule
122.887
329(1987)
17.9
231(1984)
"3
CHCl·, v2
(678 cm"1)
4 . 4 0 ± 0.03 km mol"1
v5
(773 cm"1)
218.7 ± 2.5 km mol"1
1
-1
888.
231(1984)
123.
231(1984)
vA
(1219 cm' )
30.2 ± 1.0 km mol
vx
(3034 cm' 1 )
a
2160 fm 2
1.60
258(1986)
2νγ
(5941 cm' 1 )
^ 3 1 0 fm 2
7.72
258(1986)
3^
(8727 cm' 1 )
a
145 fm 2
0.310
258(1986)
4*!
(11385 cm- 1 )
a
4 . 6 fm 2
0.013
258(1986)
a
Value given is for G (see text or Ref. 258 for definition). Units are actually fm 2 molecule" 1 . CDC1 3
v2
(659 cm"1)
4.90 + 0.03 km mol"1
19.9
231(1984)
ps
(745 cm' 1 )
145.9 ± 0.7 km mol"1
592.7
231(1984)
v4
(913 cm' 1 )
100.0 ± 1.4 km mol"1
406.
231(1984)
px
(2266 cm"1)
2vx
(~ 4400 cm"1)
a
2260 fm2
-2.4
258(1986)
3^
( - 6 5 0 0 cm-1)
^ 0 fm2
-0.08
258(1986)
a
-0.003
258(1986)
Avx ( - 8 6 0 0 cm"1) a
a
335 fm 2
1 . 2 fm 2
0.186
258(1986)
Value given is for G (see text or Ref. 258 for definition). Units are actually fm 2 molecule" 1 .
206
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (47) BAND
REFERENCE VALUE
cm^atm"1 at300K
REFERENCE
CH335C1 (732 cm"1)
"3
90.7 ± 1.3 cm^atnT1 at 296K
89.
133(1988)
88.
49(1989)
CH337C1 (727 cm"1)
"3
89.16 ± 1.43 cm^atm-1 at 296K CHC12F
v%
(807 cm'1)
679 cm^atm"1 at 296K
670.
294(1985)
v3
(1079 cm"1)
625 cm^atm"1 at 296K
617.
294(1985)
1
2PX
(5927 cm" ) Band system
a
3νγ
( - 8 7 0 0 cm-1) Band system
a
2
2.8 x 10° pm
1.5 x 10"4 pm2
4.1
9(1984)
0.32
9(1984)
0.016
9(1984)
(9791 cm"1) , (9904 cm'1) I
See Ref. 148(1984)
3V1-\-P2
(9975 cm"1) y Band System
4vx a
( - 1 1 4 0 0 cm-1) *5.6 x KT6 pm2 Band system
Value given is for G (see text or Ref. 9 for definition). Units are actually pm2 molecule"1. CHC1F2
2v2
(829 cm'1)
a
3.60 x 10"19 cm molecule"1 3.33 x 10"19 cm molecule'1
νΊ 2v2
(809 cm"1) χ (829 cm"1) /
550 ± 2 cm^atm'1 at 300K
a
v3
(1116 cm'1)
1768 ± 23 cm^atm'1 at 300K See also Ref. 262(1989)
v%
(1128 cm"1)
See Ref. 262(1989)
8.81 8.15
449(1987) 363(1989)
550.
422(1988)
1768.
422(1988)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
207
TABLE II (48) BAND
REFERENCE VALUE
at300K
REFERENCE
CHC1F2 (continued) vx
(3023 cm"1) Band system
b
5.6 x 10"2 pm2
2vx
(5927 cm"1) Band system
b
1.3 X 10"3 pm2
1.9
9(1984)
3vx
( - 8 7 0 0 cm"1) Band system
M.lxlO^pm2
0.23
9(1984)
4vx
(~ 11400 cm'1) Band system
0.016
9(1984)
b
41.
5.6 x 10"6 pm2
9(1984)
See also Ref. 155(1990) integrated intensity of the Q branch. b
Value given is for G (see text or Ref. 9 for definition). Units are actually pm2 molecule'1. CHD2F
vx
(2976 cm"1)
«0.193 pm2
2vx
(5835 cm"1)
«0.57 x 10"3 pm2
0.81
236(1988)
3vx
(8582 cm"1)
«0.11 x 10"3 pm2
0.23
236(1988)
4vx
(11240 cm"1)
^ . 8 0 x 10"5 pm2
0.022
236(1988)
a
141.
236(1988)
Value given is for G (see text or Ref. 236 for definition). Units are actually pm2 molecule-1. CHF.
2i/4
(2710 cm"1)
a
(0.0063 ± 0.002) pm2
vx
(3036 cm'1)
a
(0.132 ± 0.02) pm2
2vA\ vx )
b
1.33 x 10"1 pm2
a
(1.3 ± 0.3) X Hrv4 T pnm m2z
Band system
vx+2v4 (5710 cm"1)
4.
149(1984)
98.0
149(1984)
98.8
9(1984)
0.18
149(1984)
208
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (49) BAND
REFERENCE VALUE
cm"^atm"J at300K
REFERENCE
CHF3 (continued) 2vx
(5959 cm"1)
a
(2 ± 0.4) x 10"4 pm2
0.29
149(1984)
1
4vA
(5337 cm" )
2vx
(5710 cm"1) | (5959 cm"1) Band system
3^
b
2.4 x 10"4 pm2
0.35
9(1984)
(8793 cm'1)
a
(3 ± 1) x 10"5 pm2
0.06
149(1984)
3J>! Band system
b
4.4 X 10 -5 pm2
0.095
9(1984)
3ίΊ+2ϊ>4 (11347 cm"1)
a
(2.4 ± 1) x 10-6 pm2
0.007
149(1984)
(11563 cm-1) Band system
b
0.010
9(1984)
4^ a
3.6 x IQ"6 pm2
Value given is for G (see text or Ref. 149 for definition). Units are actually pm2 molecule-1.
b
Value given is for G derived from data of Ref. 149. Units are actually pm2 molecule"1. These values are also quoted in Ref. 258. CDF3 vx
(2268 cm" )
a
2vx
( - 4 4 0 0 cm"1)
a
3^
( - 6 5 0 0 cm"1)
4i/x
( - 8 6 0 0 cm"1)
a
1
2
86.6
258(1986)
l l l fm2
-0.12
258(1986)
a
13 fm2
-0.021
258(1986)
a
< 2 fm2
<0.004
258(1986)
156000 fm
Value given is for G (see text or Ref. 258 for definition). Units are actually fm2 molecule-1
2*2
(2486 cm"1)
See Ref. 246(1989)
3P6
(2644 cm"1)
See Ref. 246(1989)
r2+v3+v6 (2655 cm"1)
See Ref. 246(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
T
209
TABLE II (50) BAND
REFERENCE VALUE
cm_2atm_1 at300K
REFERENCE
CH3I (continued) "2 +"5
See Ref. 246(1989) (2682 cm"1) CH3N
p7
(1058 cm"1)
See Ref. 191(1986)
v9
(1061 cm"1)
See Ref. 191(1986)
1
i/8
(1127 cm" )
See Ref. 191(1986) C1NO.
"5
H
"3 VA
(560 cm"1)
a
1.16 ± 1.1 x 10"17 cm molecule 1
(780 cm"1)
b
3.93 ± 0.20 x 10"19 cm molecule 1 See also Refs. 32(1988) and 361(1985)
9.6
139(1987)
(809 cm"1)
b
5.1
139(1987)
2.09 ± 0.10 x 10"19 cm molecule'1
v2
(1292 cm"1)
vx
(1735 cm"1)
139(1987)
368 cm^atm"1 at 296K 2.85 ± 0.15 x 10"17 cm molecule"1 c 3.04 -0.21 +0.30 X 10"17 cm molecule"1
363. 697. 744.
294(1985) 139(1987) 32(1988)
699 cm^atm"1 at 296K 1.56 ± 0.078 x 10"18 cm molecule"1 a 3.47 ± 0.55 x 10"17 cm molecule"1 c 3.59 -0.25 +0.36 x 10"17 cm molecule"1 See also Refs. 17(1986) and 16(1987)
690. 38.2 849. 878.
294(1985) 139(1987) 139(1987) 32(1988)
a
)
284.
b
*5.09 + 0.55 x 10"17 cm molecule"1 c 5.68 -0.4 +0.6 x 10"17
1245. 1390.
139(1987) 32(1988)
integrated band intensity at 296K. Values at 223K are also reported. integrated intensity of the Q branch at 296K. Integrated Q branch values at 213K are also reported. integrated band intensity at 296K. Values at 213K are also reported.
210
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (51) BAND
REFERENCE VALUE
at300K
REFERENCE
595. 1116. 1252. 1148.
93(1985) 380(1985) 420(1987) 420(1987)
GeR. v3
(2114 cm"1)
*654 ± 100 cm^atm"1 b 1226 ± 172 cm^amagaf1 c 1278 ± 38 cm^atm"1 at 294K d 1171 cm^atm"1 at 294K
Combined intensity for all five Ge isotopes in natural telluric abundance (0.208 70 Ge + 0.277 72 Ge + 0.077 73 Ge + 0.346 74 Ge + 0.077 75 Ge). Temperature of the measurement is not explicitly stated, but quotations of values from previous studies indicate that the reference temperature assumed is 273K. b
From measurements of 74 GeH 4 lines only.
c
Combined intensity for all five Ge isotopes in natural telluric abundance.
d
From measurements of 72 GeH 4 lines only. 70
"6 "3 "5
(710 cm"1) (822 cm"1) (899 cm"1)
GeH 3 D
See Ref. 87(1986) HN0 3
"7
(580 cm"1)
39 ± 8 cm^amagaf1
35.
265(1989)
"6
(647 cm"1)
50 ± 5 cm^amagat"1 See also Ref. 265(1989)
46.
181(1984)
"8
(763 cm'1)
45 ± 4 cm^amagat"1 See also Ref. 265(1989)
41.
181(1984)
"5
(879 cm"1) \ (897 cm'1) l
692 ± 35 cm-2amagaf1 490 cm-2atm-1 at 296K 1.36 x 10' 17 cm molecule"1 2.21 ± 0.2 x 10"17 cm molecule-1 a 202 ± 40 cm^atm"1 at 296K
630. 483. 333. 541. 200.
181(1984) 294(1985) 104(1986) 206(1987) 35(1988)
40.
181(1984)
7v9
"8 + "9 (1204 cm"1)
44 ± 4 cm^amagat"1
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
211
TABLE II (52) BAND
REFERENCE VALUE
cm"zatm"J at300K
REFERENCE
HN0 3 (continued) P4
(1303 cm"1)
b
305.6 cm^atm"1 at 296K
301.5
335(1989)
P3
(1326 cm"1)
b
605.0 cm^atm-1 at 296K
596.9
335(1989)
P3!
P2
(1710 cm"1)
1383 ± 70 cm^amagaf1 924 cm^atm"1 at 296K 2.81 x 10"17 cm molecule-1 4.29 ± 0.6 x 10"17 cm molecule"1 c 1187 cm^atnT1 at 296K (±20%) See also Refs. 299(1987) and 300(1989)
1259. 912. 687. 1050. 1171.
181(1984) 294(1985) 104(1986) 206(1987) 335(1989)
1530 ± 100 cm^amagaf1 See also Refs. 235(1987), 302(1987), and 264(1988)
1392.
181(1984)
"Intensity of v5 band only. b
5 v (see text for definition).
c
5 B a n d (see text for definition) including contribution from hot bands. SiF 4
P3
(1031 cm"1)
See Ref. 330(1982) SiH3D
P6 P3
p5
(784 cm"1) (913 cm"1) (951 cm"1)
See Ref. 87(1986)
212
ψ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE III.
BIBLIOGRAPHY FOR BAND INTENSITIES OF MOLECULES WITH SIX OR MORE ATOMS
MOLECULE
REFERENCE
Acetaldehyde (CH3CHO)
372(1985), 104(1986)
Allene (C3H^
138(1986)
Benzene (C6H6)
355(1982), 134(1989)
Benzene-d5 (C6H5D)
355(1982)
Benzene-d6 (C 6 D 6 )
355(1982)
Chlorofluorocarbon 113 (C2C13F3)
294(1985), 373(1988), 422(1988), 155(1990)
Chlorofluorocarbon 114 (C2C12F4)
294(1985), 373(1988), 422(1988), 155(1990)
Chlorofluorocarbon 115 (C2C1F5)
155(1990)
Dinitrogen Pentoxide (N 2 0 5 )
108(1985), 294(1985), 331(1985), 104(1986), 97(1987), 206(1987), 98(1988), 105(1988), 106(1988), 107(1988)
Ethane (C2H6)
125(1985), 362(1986), 136(1987)
Fluorobenzene (C6H5F)
355(1982)
Heptafluoropropane (C3F7H)
9(1984), 148(1984)
Hexafluoroethane (C2F6)
422(1988)
Hydrochlorofluorocarbon 123 (C2HC12F3)
155(1990)
Hydrochlorofluorocarbon 124 (C2HC1F4)
155(1990)
Hydrochlorofluorocarbon 141b (C2H3C12F)
155(1990)
Hydrochlorofluorocarbon 142b (C2H3C1F2)
155(1990)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
213
TABLE III (continued) MOLECULE
REFERENCE
Hydrofluorocarbon 125 (C2HF5)
9(1984), 155(1990)
Hydrofluorocarbon 134a (C 2 H 2 F 4 )
155(1990)
Hydrofluorocarbon 143a (C2H3F3)
155(1990)
Hydrofluorocarbon 152a (C2H4F2)
155(1990)
Methylhydroperoxide (CH 4 0 2 )
38(1989)
Methyl chloroform (C2H3C13)
155(1990)
Neptunium Hexafluoride (NpF6)
338(1986)
Pentafluorobenzene (C6HF5)
355(1982)
Peroxynitric acid (HN0 4 )
294(1985), 298(1988)
Plutonium Hexafluoride (PuF6)
232(1984), 338(1986)
Propyne (C3H4)
43(1990)
Sulfur Hexafluoride (SF6)
166(1976), 3(1978), 412(1989)
Tellurium Hexafluoride (TeF6)
303(1986)
Toluene (C7H8)
355(1982)
Tristrifluoromethylmethane (C4HF9)
9(1984), 22(1985)
Uranium Hexafluoride (UF6)
243(1980), 233(1981), 232(1984)
214
ψ
SMITH, R I N S L A N D , D E V I , R O T H M A N , R A O TABLE IV.
BIBLIOGRAPHY FOR COLLISION-BROADENING MEASUREMENTS
Molecule
Page
CO ClO HBr
215 215 215 215 215 216 216 216 216 216 216 218 218 218 219 219 221 221 221 222 222 222 222 223 223 223 224 224 224 225 225 225 226 227 227 227 227 228 228 228 228
H35C1 H37C1
HF H2 D2 N2 NO
12 16
c o2 c o2
13 16
12C160180
12 18
c o2
HCN
H2160
HDO D20 HTO H2180
N20 N0 2 03
ocs so2 2
2
H2CO H202 14 NH 3 15 NH 3
PH3 CF2C12 12 CH 4 13 CH 4 12 CH 3 D GeH4 HN0 3 SiF 4 Ethane (C2H6) Sulfur Hexafluoride ( 32 SF 6 ) Uranium Hexafluoride (UF6)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
215
TABLE IV (2) BAND
BROADENING GAS
REFERENCE
CO 1-0
1
(2143 cm· )
Ar He Ne CO H2 N2
196(1986) 83(1984), 36(1984) 83(1984) 36(1984), 83(1984) 83(1984), 248(1986), 433(1987) 83(1984), 196(1986), 248(1986), 433(1987) 261(1984), 397(1988) 261(1984), 442(1984), 196(1986), 396(1987)
C02 H20 2-0
(4260 cm·1)
He CO
36(1984) 55(1984), 36(1984)
3-0
(6350 cm"1)
CO
36(1984)
ClO 1-0
1
(844 cm' )
N2
88(1989)
HBr 1-0
(2559 cm"1)
HBr C02
382(1985) 382(1985) H35C1
1-0
(2886 cm'1)
Ar He Kr Ne Xe HC1 N2 Air (N 2 + 0 2 )
440(1984), 350(1987) 440(1984) 440(1984) 440(1984) 440(1984) 111(1985), 343(1985) 34(1985), 345(1987), 112(1990) 345(1987)
3-0
(8347 cm"1)
Air (N 2 + 0 2 )
398(1988) H37C1
1-0
(2884 cm"1)
HC1
111(1985), 343(1985)
216
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE IV (3) BAND
BROADENING GAS
REFERENCE
HF 1-0
(3962 cm"1)
HF N2 Air (N 2 + 0 2 )
343(1985) 345(1987) 345(1987) H2
1-0
(4161 cm"1)
He
60(1990) 165(1966), 68(1968), 80(1971), 60(1990)
2-0
(8087 cm'1)
H2
307(1987) D2
1-0
(2994 cm'1)
D2
68(1968) N2
1-0
(2325 cm"1)
N2
356(1986) NO
1-0
(1876 cm"1)
N2 NO
339(1986), 316(1987), 33(1988) 33(1988)
2-0
(3724 cm'1)
N2 NO
346(1985) 346(1985)
5-0
(9100 cm"1)
NO
251(1988) 12 r 16 1 0(
c o2
01101-00001 (667 cm"1) Band system
co9
222(1990)
10001-01101 (721 cm"1)
co9
214(1988), 215(1989)
11101-10002 (791 cm"1)
N2
131(1989) 131(1989) 2(1986), 131(1989)
o2 co 2
INTENSITIES AND COLLISION-BROADENING PARAMETERS ψ
217
TABLE IV (4) BAND
BROADENING GAS 12
00011-10001 (961 cm"1)
REFERENCE
16
C 0 2 (continued)
He He + C0 2 + N2 + Xe N2
o2
311(1974) 182(1988) 311(1974) 14(1986), 15(1987) 311(1974), 2(1986), 371(1986), 15(1987), 186(1987), 328(1987), 370(1989)
00011-10002 (1064 cm"1)
co9
311(1974), 2(1986), 186(1987)
11102-00001 (1932 cm"1)
Ar He Ne Xe C0 2
145(1986) 145(1986) 145(1986) 145(1986) 401(1986)
11101-00001 (2077 cm"1)
Ar Xe N2 C0 2
145(1986) 145(1986) 177(1987) 177(1987)
00011-00001 (2349 cm"1)
Ar He Ne Xe H2 D2 N9
ΗΛΟ
83(1984), 146(1985) 83(1984), 146(1985) 83(1984), 146(1985) 146(1985) 83(1984), 146(1985) 146(1985) 83(1984), 103(1985), 126(1985), 146(1985) , 127(1986), 128(1986), 255(1986) , 197(1988), 291(1988), 374(1988) 375(1988), 337(1989), 381(1989) 103(1985) , 126(1985), 128(1986), 291(1988) 36(1984), 103(1985), 247(1985), 127(1986) , 128(1986), 255(1986), 291(1988) , 195(1989), 381(1989) 255(1986) , 374(1988)
N2 CO.
23(1987) 308(1987)
CO?
O,
co?
00011-00001 Band System
218
ψ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE IV (5) BAND
BROADENING GAS
REFERENCE
12
c1 6 0 2 (continued)
10011-10002 (2429 cm"1)
C0 2
200(1986) 177(1988)
10011-00001 (3715 cm"1)
N2 02
co 2
255(1986), 291(1988) 291(1988) 255(1986), 291(1988)
31103-00001 (4591 cm"1)
co2
1(1984)
20012-00001 (4978 cm"1)
co2
404(1990)
01121-00001 (5315 cm'1)
He N2
408(1987) 408(1987)
00031-00001 (6973 cm"1)
He N2 C0 2
185(1985), 81(1989) 185(1985), 81(1989) 81(1989) 13 16
c o2
00011-10001 (913 cm"1)
He + C0 2 + N2 + Xe
182(1988)
20012-00001 (4887 cm'1)
C0 2
53(1985) 12C160180
10002-00001 (1259 cm"1)
C0 2
2(1986)
01121-01101 (4614 cm"1)
co2
1(1984)
00021-00001 (4640 cm1)
co2
1(1984) 12
00011-10001 (967 cm"1)
C 18 0 2
He + C0 2 + N2 + Xe
182(1988)
INTENSITIES AND COLLISION-BROADENING PARAMETERS T
TABLE IV (6) BAND
BROADENING GAS
REFERENCE
HCN 1
(3311cm· )
v3
(15452 cm"1) 5i/3
(15552 cm"1)
Ar N2
434(1984) 434(1984)
HCN
390(1986)
HCN
390(1986) H 2 16 0
8-14 /xm Region
N2 H20
421(1987), 418(1988) 421(1987), 418(1988)
N2 Air(N2 + 0 2 ) H20
so2
271(1985), 267(1986), 198(1987) 267(1986), 4(1986) 271(1985), 267(1986), 198(1987) 320(1987)
v2
(1595 cm"1)
vx p3
1
(3657 cm" ) \ (3756 cm"1) / Band System
H20
256(1986)
2vx
(7201 cm'1)
H20
67(1987)
vx+v2 (7250 cm-1)
Air (N2 + O2) H20
67(1987) 67(1987)
(7445 cm'1)
Air (N2 + o2) H20
67(1987) 67(1987)
N,
284(1988)
2v3 ΪΊ+3Ϊ>2
3ί/2+^3
2^1+^2
(8274 cm"1)
(8762 cm'1) (8807 cm"1)
^2+2^3
284(1988)
(8374 cm"1)
(9000 cm"1)
N,
284(1988)
N,
284(1988)
N,
284(1988)
219
220
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE IV (7) BAND
BROADENING GAS
REFERENCE
H 2 1 6 0 (continued) N,
282(1989), 286(1989)
(10600 cm'1)
N,
282(1989), 286(1989)
2Ργ+Ϋ2 (10613 cm'1)
N,
282(1989), 286(1989)
P1+2i'3
N,
286(1989)
N^
282(1989), 286(1989)
Ar
188(1989) 286(1989) 188(1989) 187(1989)
(10537 cm'1) 3^
(10869 cm 1 ) 3i>3
(11032 cm"1)
4ί>2+2ι>3 (13500 cm"1)
Air (N 2 + O2)
3ί^+2ί/2 (13642 cm"1)
O,
188(1989)
2j/1+2i'2+i'3 (13653 cm'1)
Ar N2
188(1989) 188(1989), 286(1989) 188(1989) 94(1986), 188(1989) 187(1989)
o2
Air (N 2 + O2) H20 2i/ 1 +2i/ 3 (13828 cm"1)
Ar N2
o2
Air (N 2 + 0 2 ) H20
3*Ί+Ι/ 3
Avx
(13831 cm'1)
(14221 cm"1)
Vj+3^3
(14319 cm"1)
Ar N2
188(1989) 188(1989), 286(1989) 188(1989) 188(1989) 187(1989)
o2
Air (N 2 + Ο2) H20
188(1989) 188(1989), 286(1989) 188(1989) 94(1986), 188(1989) 187(1989)
N2
286(1989)
N2
286(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS T
TABLE IV (8) BAND
BROADENING GAS
REFERENCE
1
H2 O (continued) N,
286(1989)
N,
286(1989)
V1 + l'2+3i'3
N,
286(1989)
2νγ
No
286(1989)
3J>J+ 2ι>2+^3
N.
286(1989)
3»Ί+2Ι>3
No
286(1989)
2I>1+3J>3
N,
286(1989)
4^+1/3
No
286(1989)
No
286(1989)
No
286(1989)
2ΙΊ+Ι>2+2Ι>3
(15345 cm"1) (15348 cm"1) (15833 cm"1)
+2P2+2I>2
(16819 cm 1 ) (16822 cm"1) (16898 cm"1) (16899 cm"1)
3VI+3PJ
(17496 cm 4 ) (19781 cm"1)
4ι/ 1 +2ί/ 3 (19782 cm"1)
HDO "2
(1403 cm"1)
267(1986) 267(1986)
N2 Air (N 2 + O2)
D20 "2
1
(1178 cm" )
275(1986) 275(1986)
N2 Air (N 2 + 0 2 )
ΗΤΟ v2
1
(~ 1300 cm" )
Air (N 2 + 0 2 ) H20
116(1987) 116(1987)
221
222 ψ SMITH, RINSLAND, DEVI, ROTHMAN, RAO TABLE IV (9) BAND
BROADENING GAS
REFERENCE
Έ[ 2 18 o u2
(1588 cm"1)
N2 Air(N 2 + 0 2 ) H20
267(1986) 267(1986) 267(1986)
N20 (1283 cm"1)
N2 02
431(1989) 431(1989)
2
~^vyvi (2210 cm"1)
N2
259(1986)
v3
(2224 cm"1)
He N2 02 N20
83(1984) 83(1984), 201(1985), 259(1986) 201(1985) 290(1985)
p2+v3
(2798 cm-1)
N2 N20
292(1989) 402(1988), 292(1989)
vx
v
N0 2 v3
(1621 cm'1)
Air (N 2 + 0 2 )
301(1990)
03 v3
(1042 cm"1)
N2 Air (N 2 + 0 2 )
392(1988) 392(1988)
vx
(1103 cm"1)
N2 02 Air (N 2 + 0 2 )
392(1988) 392(1988) 392(1988)
INTENsmES A N D COLLISION-BROADENING PARAMETERS ψ
TABLE IV (10) BAND
BROADENING GAS
REFERENCE
ocs (850 cm"1) (859 cm-1)
νγ
2v2°
(1047 cm'1) (1053 cm"1)
u3
(2062 cm-1)
Ar
48(1990)
Ar He Kr N2
61(1988) 56(1989) 47(1990) 310(1985) 63(1987) 61(1988) 57(1986)
o2 co2 ocs
ocs ocs
143(1988) 143(1988)
Ar He H2
73(1986) 73(1986) 73(1986)
S0 2 vx
(1152 cm·1)
13(1989) 13(1989)
Air(N 2 + 0 2 ) S02 C2H2
(729 cm"1)
v5l
("4+"5) 0
(1328 cm'1)
(P2+3P3)
(11600 cm-1)
(2vl + v2+v3) (11783 cm"1)
H2 N2 02
51(1987) 51(1987), 244(1989), 62(1990) 244(1990)
He N2 Air (N 2
347(1984) 347(1984), 266(1985) 266(1985)
+ OJ
2
323(1988)
C2H2
323(1988)
2
223
224
ψ SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE IV (11)
BROADENING GAS
BAND
REFERENCE
H2CO
H2 N2
(1167 cm"1)
"4
+ 02)
312(1987) 312(1987) 312(1987) 312(1987)
Air (N 2 + 0 2 )
312(1987) 312(1987)
o 2 (N Air
H2
(1249 cm'1)
"6
2
H202 (1266 cm 1 )
"6
Air (N 2 + 02) H202 + H20
280(1986) 280(1986) 14
H&-^
(716 cm"1)
H2 N2
Air (N 2 + 0 2 )
co NH2
3
2v{
-*"
2v2*-"2 s
(629 cm'1) (950 cm"1)
1
He H2 N2
Air (N 2 + 0 2 )
C0 2 NH3
*ί "2*
(932 cm"1) \ (968 cm"1),
Ar He H2 N2
Air (N 2 + 0 2 )
C0 2 NH3
NH 3 He26(1990) 26(1990) 26(1990) 26(1990) 26(1990) 25(1989) 26(1990) 26(1990) 39(1987), 386(1988), 26(1990) 26(1990) 26(1990) 85(1983), 86(1985), 203(1986), 39(1987), 25(1989) 39(1987) 44(1986), 26(1990) 26(1990) 44(1986), 39(1987), 26(1990) 26(1990) 26(1990) 82(1978), 28(1985), 86(1985), 44(1986), 203(1986), 39(1987), 124(1988), 25(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
225
TABLE IV (12) BAND
BROADENING GAS 14
p4
1
(1627 cm" )
REFERENCE
NH 3 (continued)
NH3
72(1987), 71(1988) 70(1985), 72(1987), 71(1988), 114(1990) 253(1987), 114(1990)
He H2
2*2
(1882 cm"1)
H2 NH3
114(1990) 253(1987), 114(1990)
i>3
(3444 cm"1)
He H2 NH3
72(1987) 72(1987) 199(1988)
5*!
(15504 cm"1)
He H2 NH3
225(1986) 224(1985), 225(1986) 178(1969), 180(1975), 225(1986), 296(1987) 293(1970)
NH3 + Air 15
i>2* *> 2 a P4
(928 cm"1) Ϊ (963 cm"1) / (1622 cm"1)
NH 3
NH 3
86(1985), 383(1985)
N2
272(1990) PH3
vx v3
(2323 cm"1) \ (2328 cm"1) i
H2
260(1985) CF2C12
(923 cm"1)
Air (N 2 + O^ CF2C12
237(1990) 237(1990)
226
ψ SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE IV (13) BAND
BROADENING GAS
REFERENCE
^CH4 j>4
(1306 cm -1 )
Ar He H2 N2
oAir2 (N
+
o2)
Air (N 2 +
o2)
2
CH4 P2
P3
(1534 cm"1) (3019 cm"1)
N2
Ar He Kr Ne Xe N2
Air (N 2 +
co CH2
4
o2)
366(1989), 430(1989) 430(1989) 430(1989) 74(1985), 277(1985), 365(1988), 427(1989), 430(1989) 427(1989) 277(1985), 365(1988), 427(1989) 31(1986) 365(1988) 365(1988) 184(1968), 10(1989) 184(1968), 11(1976), 10(1989) 184(1968), 10(1989) 184(1968) 184(1968), 11(1976), 10(1989) 74(1985) 11(1976), 10(1989) 11(1976), 10(1989) 263(1969), 11(1976), 19(1985), 10(1989)
N2
74(1985)
Ar He H2 N2
169(1988) 167(1985), 169(1988) 167(1985) 167(1985), 169(1988) 167(1985), 169(1988)
2^+3*3 (14640 cm"1)
He H2 N2 CH4
226(1986) 226(1986) 226(1986) 226(1986)
5Ρ^Ρ3
He H2 N2 CH4
226(1986) 226(1986) 226(1986) 176(1979), 226(1986)
"l + "4 3P3
(4224 cm"1) (9047 cm"1)
He + H 2
(16160 cm'1)
INTENsmES A N D COLLISION-BROADENING PARAMETERS ψ
227
TABLE IV (14)
BROADENING GAS
BAND
13
1
REFERENCE
CH 4
"4
(1299 cm" )
Ar He H2 N2 02 Air (N 2 + Oj)
425(1989) 425(1989) 425(1989) 278(1985), 425(1989) 425(1989) 278(1985), 279(1988), 425(1989)
"3
(3010 cm"1)
N2 Air (N 2 + Ο2)
269(1991) 269(1991) 269(1991)
H2
167(1985)
3, 3
(9045 cm-1)
o2
12
v
6
v
3
v
2
CH 3 D
(1161cm- 1 )
He H2 N2 Air (N 2 + 0 2 ) CH3D
424(1989) 241(1987), 424(1989) 241(1987), 268(1987), 424(1989) 268(1987) 241(1987), 424(1989)
(1307 cm"1)
H2 N2 Air (N 2 + Ο2) CH3D
424(1989) 276(1986), 424(1989) 276(1986) 276(1986)
(2200 cm'1)
H2 N2
122(1987) 122(1987) GeH4
"3
1
(2114 cm" )
H2
93(1985), 420(1987) HN0 3
(1307 cm"1) χ (1326 cm"1) /
Air (N 2 + 0 2 )
300(1989)
228
v
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE IV (15) BAND
BROADENING GAS
REFERENCE
SiF 4 "3
1
(1032 cm" )
He Xe
217(1985) 216(1985) 317(1973), 46(1974), 24(1982)
SiF 4 Ethane (C2H6)
v
9
(822 cm"1)
Ar He H2 N2 CH4 C
2H6
52(1987) 52(1987) 52(1987), 192(1988) 52(1987), 123(1985) 52(1987) 52(1987)
Sulfur Hexafluoride ( 32 SF 6 ) "3
(950 cm'1)
Ar He Kr Ne Xe CO H2
8*SF« 34
SF 6
237(1990) 237(1990) 237(1990) 237(1990) 237(1990) 237(1990) 237(1990) 237(1990) 237(1990) 237(1990)
Uranium Hexafluoride (UF6) v3
(628 cm"1)
Ar
304(1985)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS TABLE V.
BIBLIOGRAPHY FOR PRESSURE-INDUCED LINE-SHIFT MEASUREMENTS
Molecule
Page
CO HBr
230 230 230 231 232 232 232 232 233 233 233 234 234 234 235 235 236 236 236 237 237 237
H35C1 H37C1 D35C1
HF DF H2 HD D2
12 16 c o2 13 16 c o2 12 18 c o2 13 18 c o2
HCN H20 N20 O3 14
NH 3 NH 3 12 CH 4 13 CH 4 15
ψ
229
230
ψ
SMITH, R I N S L A N D , D E V I , R O T H M A N , R A O
TABLE V (2) BAND
BROADENING GAS
REFERENCE
CO 1
1-0
(2143 cm" )
Ar
352(1963)
2-0
(4260 cm-1)
Ar Xe CO HC1 H2 N2 NO 02 C02
352(1963) 352(1963) 58(1973), 59(1974), 348(1983) 58(1973) 58(1973) 58(1973) 58(1973) 58(1973) 58(1973)
3-0
(6350 cm"1)
CO
59(1974) HBr
1-0
(2559 cm"1)
Ar Xe H2 N2
352(1963) 352(1963) 352(1963) 352(1963) H35C1
1-0
(2886 cm'1)
Ar He Kr Ne Xe HC1 HF H2 D2 N2 Air (N 2 + 0 2 ) 02 CF 4
40(1961), 352(1963), 257(1973), 209(1975), 210(1976), 440(1984) 40(1961), 352(1963) 40(1961), 352(1963) 40(1961) 40(1961), 352(1963), 257(1973), 210(1976) 343(1985) 64(1981) 211(1977), 213(1980) 211(1977), 213(1980) 212(1977), 213(1980), 345(1987) 345(1987) 213(1980) 352(1963)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
T
TABLE V (3) BAND
BROADENING GAS
REFERENCE
H35C1 (continued)
Ar
351(1960), 205(1960), 40(1961), 353(1964), 189(1978), 208(1981) 351(1960), 40(1961), 353(1964) 40(1961), 353(1964) 351(1960), 40(1961), 189(1978) 40(1961), 352(1963), 353(1964), 257(1973), 208(1981) 351(1960), 205(1960) 234(1959), 189(1978) 205(1960) 189(1978), 64(1981) 351(1960) 351(1960), 189(1978) 234(1959) 351(1960) 351(1960), 189(1978) 351(1960) 205(1960) 205(1960)
He Kr Ne Xe CO HC1 DC1 HF H2 N2
Air (N 2 + O2)
02
co2
N20 S0 2
CH3CI H37C1
1-0
(2884 cm"1)
HC1 HF
343(1985) 64(1981)
2-0
(5664 cm"1)
Ar Ne CO HC1 HF N2
205(1960), 40(1961), 189(1978) 189(1978) 205(1960) 234(1959), 189(1978) 189(1978), 64(1981) 189(1978) 234(1959) 189(1978) 205(1960)
Air (N 2 + 0 2 )
co 2 CH3CI
231
232
τ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE V (4) BAND
BROADENING GAS
REFERENCE
D35C1 1-0
(2091 cm"1)
Ar Xe
352(1963) 352(1963)
2-0
(4127 cm"1)
HC1
218(1964) HF
1-0
(3961 cm"1)
Ar Kr Ne Xe HF N2 Air (N 2
co2
2-0
(7751 cm"1)
+ o2)
Ar Kr Ne Xe HC1 HF N2
co 2
324(1963), 219(1965) 189(1978) 219(1965) 240(1958), 189(1978), 345(1987) 384(1969),
219(1965), 189(1978)
219(1965), 219(1965), 189(1978) 219(1965), 189(1978), 189(1978) 189(1978) 189(1978)
441(1970), 189(1978) 441(1970)
202(1962), 343(1985) 345(1987) 189(1978)
441(1970) 64(1981)
DF 2-0
(5810 cm 4 )
144(1971)
HF TJ Ά
1
2
1-0
(4161 cm' )
H2
354(1963), 154(1965), 165(1966), 68(1968), 80(1971), 66(1982)
2-0
(8087 cm"1)
H2
110(1975), 66(1982)
4-0
(15625 cm'1)
H2
45(1978), 69(1980)
INTENSITIES AND COLLISION-BROADENING PARAMETERS ψ
233
TABLE V (5) BROADENING GAS
BAND
REFERENCE
HD 1
1-0
(3677 cm- )
Ar Kr Xe HD
315(1983) 315(1983) 315(1983) 305(1973), 315(1983)
2-0
(7087 cm"1)
HD
305(1973)
3-0
(10368 cm"1)
H2
306(1974)
4-0
(13477 cm"1)
H2 HD
306(1974) 415(1983)
5-0
(16416 cm-1)
HD
415(1983) D2
1-0
1
(2994 cm" )
D2
68(1968) 12 16
c o2
00011-10001 (961 cm'1)
Ar He He + N2 + C0 2 He + CO l + N2 + H2 Xe H2 N2 C0 2 CH3F
394(1984), 395(1985) 394(1984), 5(1985), 395(1985) 170(1970) 207(1982) 394(1984), 395(1985) 394(1984), 395(1985) 394(1984), 395(1985) 443(1976), 171(1977), 394(1984), 395(1985) 394(1984), 395(1985)
00011-10002 (1064 cm"1)
He N2
435(1972) 435(1972) 435(1972), 394(1984), 395(1985)
11102-00001 (1932 cm"1)
Ar He Ne Xe
145(1986) 145(1986) 145(1986) 145(1986)
co2
234
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O TABLE v
BAND
(6)
BROADENING GAS 12
REFERENCE
C 1 6 0 2 (continued)
00011-00001 (2349 cm"1) Band System
N2
23(1987)
00031-00001 (6973 cm"1)
co 2
12(1980), 81(1989) 13 16
c o2
00011-10001 (913 cm·1)
co 2
394(1984), 395(1985)
00011-10002 (1018 cm"1)
co 2
394(1984), 395(1985) 12 18
c o2
00011-10001 (967 cm"1)
Ar He Xe H2 N2 C0 2 CH3F
394(1984), 394(1984), 394(1984), 394(1984), 394(1984), 394(1984), 394(1984),
00011-10002 (1084 cm"1)
co 2
394(1984), 395(1985) 13
00011-10001 (929 cm"1)
He Xe H2 N2
C1802
CH3F
395(1985) 395(1985) 395(1985) 395(1985) 394(1984), 395(1985) 395(1985)
CO,
394(1984), 395(1985)
co 2
00011-10002 (1027 cm"1)
395(1985) 395(1985) 395(1985) 395(1985) 395(1985) 395(1985) 395(1985)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS T
TABLE V (7) BAND
BROADENING GAS
REFERENCE
HCN 1
(712 cm" )
v2
1^2 +2i'3~i'2
(6480 cm 1 ) (6520 cm"1)
2i/3
V2+$vyV2
HCN
164(1946)
HCN
379(1990)
HCN
390(1986)
HCN
390(1986)
(15452 cm"1)
5*>3
(15552 cm"1)
H20 (1595 cm'1)
Xe N2 Air (N 2 + 0 2 ) H20 S02
151(1972) 153(1973) 153(1973), 152(1974) 151(1972) 320(1987)
Air (N 2 + 0 2 )
451(1985), 450(1986), 90(1988), 91(1988)
Air (N 2 + 0 2 )
179(1982)
2J/ 1 +2J/ 2 +»>3
Ar No 02 Air (N 2 + 0 2 )
188(1989) 188(1989) 188(1989) 188(1989) 187(1989)
2J>1+2I>3
Ar N2
o2
Air (N 2 + 0 2 ) H20
188(1989) 188(1989) 188(1989) 54(1985), 188(1989) 187(1989)
Ar N2 02 Air (N 2 + 0 2 ) H20
188(1989) 188(1989) 188(1989) 54(1985), 188(1989) 187(1989)
v2
J>2+2l>3 2ίΊ+ϊ>3
(9000 cm 1 )
(10613 cm'1) (13653 cm"1)
(13828 cm'1)
3*1+?3 (13831 cm"1)
235
236
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE V (8) BAND
BROADENING GAS
REFERENCE
H 2 0 (continued) 3y 1 +2j'2
(13850 cm"1) (13850 cm"1)
1^+3^3
(14400 cm'1)
o2
188(1989)
Air (N 2 + 0 2 )
188(1989)
Air (N 2 + O2)
349(1985), 451(1985), 450(1986), 90(1988)
N20 vy vx
I/J
1
(939 cm' ) (1285 cm"1)
N2
190(1986)
o2
429(1989) 429(1989) 429(1989) 414(1986)
N2 Air (N 2 + O2) N20
o3 v3
(1042 cm"1)
N2 Air (N 2 + 0 2 )
392(1988) 392(1988)
vx
(1103 cm"1)
N2 Air (N 2 + Ο2)
392(1988) 392(1988) 14
" 4 ^
(716 cm"1)
co 2
NH 3
V^-vf 2"2a-"2S p2s p2*
(629 cm'1) (950 cm"1) (932 cm"1) \ (968 cm'1) i
NH 3 N226(1990) 26(1990) 25(1989)
N2 C02 NH.
26(1990) 26(1990) 85(1983), 29(1983), 28(1985), 86(1985), 378(1986), 25(1989)
N2 C02 Ntt,
26(1990) 26(1990) 254(1974), 27(1982), 124(1988), 25(1989)
INTENsmES A N D COLLISION-BROADENING PARAMETERS
ψ
TABLE V (9) BAND
BROADENING GAS 15
2, 2 a - - 2 S "?S "2*
(943 cm'1) (928 cm"1) \ (963 cm"1) /
NH 3
NH3
378(1986)
NH3
84(1982), 86(1985), 383(1985) 12
"4
(1306 cm"1)
2
(1534 cm' )
"3
(3019 cm"1)
v
CH 4
Ar N2 Air (N 2
1
366(1989) 429(1989) 365(1988), 429(1989) 365(1988), 429(1989)
+ o2)
N2
365(1988) 365(1988)
Ar He
184(1968), 10(1989) 184(1968), 18(1972), 10(1989) 184(1968), 10(1989) 184(1968), 20(1983) 184(1968), 18(1972), 10(1989) 342(1976), 11(1976), 11(1976), 10(1989) 385(1968), 37(1969), 11(1976), 10(1989)
Air(N 2 + 0 2 )
Kr Ne Xe Air(N 2 + 0 2 )
co CH2
4
3, 3
(9047 cm 1 )
Ar He H2 N2 CH4
168(1989) 168(1989) 168(1989) 168(1989) 287(1971) 13
"4
(1299 cm"1)
"3
(3010 cm"1)
REFERENCE
CH 4
H2
Air (N 2 + 0 2 )
429(1989) 279(1988)
N2 02 Air (N 2 + 0 2 )
269(1991) 269(1991) 269(1991)
11(1976),
11(1976), 10(1989) 18(1972),
237
238
ψ SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE REFERENCES 1. Abubakar, M., and Shaw, J. H. (1984). "Analysis of Carbon Dioxide Bands near 2.2 μπι," Appl. Opt. 23, 3310. 2. Abubakar, M., and Shaw, J. H. (1986). "Carbon Dioxide Band Intensities and Linewidths in the 8-12 μπι Region," Appl. Opt. 25, 1196. 3. Ackerhalt, J. R., Flicker, H., Galbraith, H. W., King, J., and Person, W. B. (1978). "Analysis of 3v3 in SF6," J. Chem. Phys. 69, 1461. 4. Adiks, T. G., Vinogradova, A. A., and Malkov, I. P. (1986). "Measurement of the Absorption Line Parameters of Water Vapor in the 5.8-μπι Region Using a Tunable diode laser Spectrometer." Zh. Prikl. Spektrosk. 45, 194; English trans. J. Appl. Spectrosc. 45, 778 (1987). 5. Agalakov, Yu. G., Bulanin, M. O., Bertsev, V. V., Burtsev, A. P., and Rubinov, Yu. A. (1985). "Observation of a Frequency Shift of Vibrational-Rotational Transitions of the CO2 Molecule Caused by a Buffer Gas," Opt. Spektrosk. 58, 493; English trans. Opt. Spectrosc. 58, 298 (1985). 6. Aganbekyan, K. A., Voitsekhovskaya, O. K., Gulyaev, G. A., Kulikov, V. V., and Trifonova, N. N. (1988). "The Water-Vapor Weak Line Intensities in the Range 8 to 10 μπι," J. Mol. Spectrosc. 130, 258. 7. Ahlberg, H., Lundqvist, S., and Eng, S. T. (1984). "Absorption Coefficients of Chlorine Dioxide at 12 C 16 0 2 and , 2 C 1 8 0 2 Laser Wavelengths: Applications to Remote Monitoring in the Working Environment," Appl. Opt. 23, 2902. 8. Akhmedzhanov, R., and Kurbaniyazov, S. Kh. (1989). "Absorption Band Strengths in the 1.5-2.5-μπι Region in Liquid and Gaseous Nitrous Oxide," Opt. Spektrosk. 66, 283; English trans. Opt. Spectrosc. 66, 163 (1989). 9. Amrein, A., Dubai, H.-R., Lewerenz, M., and Quack, M. (1984). "Group Additivity and Overtone Intensities for the Isolated CH Chromophore," Chem. Phys. Lett. 112, 387. 10. Antipov, A. B., Kochanov, V. P., Sapozhnikova, V. A., and Tinchurina, E. G. (1989). "Collisional Broadening and Shift of the 3.39-μπι Line of the v3 Band of Methane," Opt. Spektrosk. 66, 64; English trans. Opt. Spectrosc. 66, 36 (1989). 11. Antipov, A. B., Pyrsikova, P. D., and Sapozhnikova, V. A. (1976). "Effect of Temperature and Pressure on the Profile of the Methane Absorption Line with Its Center at v0 = 2947.9 cm"1," Opt. Spektrosk. 40, 795; English trans. Opt. Spectrosc. 40, 455 (1976). 12. Areas, P., Arie, E., Boulet, C , and Maillard, J. P. (1980). "Self-Shifting of C0 2 Lines in the 3v3 Band at 1.43 μπι," J. Chem. Phys. 73, 5383. 13. Arefev, V. N., and Visheratin, K. N. (1989). "Investigation of Spectral Parameters in the Vibration-Rotation Lines of SO2 Band vi," Optika Atmosfery 2(11), 1160. 14. Arie, E., Lacome, N., Areas, P., and Levy, A. (1986). "Oxygen- and Air-Broadened Linewidths of C0 2 ," Appl. Opt. 25, 2584. 15. Ari6, E., Lacome, N., and Levy, A. (1987). "Measurement of C0 2 Line Broadening in the 10.4-μπι Laser Transition at Low Temperatures," Appl. Opt. 26, 1636. 16. Atkinson, R., Aschmann, S. M., Tuazon, E. C , Goodman, M. A., and Winer, A. M. (1987). "The Gas-Phase Reaction of C10N0 2 with Hydrogen Chloride," J. Atmos. Chem. 5, 83. 17. Atkinson, R., Tuazon, E. C , MacLeod, H., Aschmann, S. M., and Winer, A. M. (1986). "The Gas-Phase Reaction of Chlorine Nitrate with Water Vapor," Geophys. Res. Lett. 13, 117. 18. Bagaev, S. N., Baklanov, E. V., and Chebotaev, V. P. (1972). "Anomalous Decrease of the Shift of the Center of the Lamb Dip in Low-Pressure Molecular Gases," Pis'ma Zh. Eksp. Teor. Fiz. 16, 344; English trans. JETP Lett. 16, 243 (1972). 19. Bagaev, S. N., Dychkov, A. S., Semibalamut, V. M., Titov, E. A., and Chebotaev, V. P. (1985). "Intensity of Narrow Resonances in a Low Pressure Gas," Opt. Spektrosk. 59, 481; English trans. Opt. Spectrosc. 59, 291 (1985).
INTENSITIES AND COLLISION-BROADENING PARAMETERS ψ
239
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TAT Mary Ann H. Smith and Curtis P. Rinsland NASA Langley Research Center Hampton, Virginia
V. Malathy Devi The College of William and Mary Williamsburg, Virginia
Laurence S. Rothman Geophysics Laboratory Hanscom AFB, Massachusetts and
K. Narahari Rao The Ohio State University Columbus, Ohio I. II. III. IV. V.
Introduction Intensities Collision Broadening Pressure-Induced Line Shifts Explanation of Tables and Table References Acknowledgments References
153 154 155 157 157 159 260
I. INTRODUCTION This chapter is the third in a series of periodic compilations of experimentally determined infrared vibration-rotation band intensity values for molecules in the gas phase. The first two works in this series were by Pugh and Rao [1] and Smith et al. [2]. The second of these works also included, for the first time, a bibliography for measurements of collision broadening in infrared vibrationrotation spectra. In the present chapter we continue the bibliographies for band 153
Copyright © 1992 by Academic Press Inc. All rights of reproduction in any form reserved. ISBN 0-12-580645-0
154 ψ SMITH, RINSLAND, DEVI, ROTHMAN, RAO
intensities and collision broadening, and we include a new bibliography for measurements of pressure-induced line shifts in infrared spectra. We have attempted to make these bibliographies as complete and comprehensive as possible. The intensity and broadening compilations cover the published literature from November 1983 through June 1990, and they include several earlier references overlooked in the previous compilations. The pressure-induced line shift compilation includes all references published through June 1990 that were available to us. We have also added a number of more recent references as they came to our attention in the course of preparing the present bibliography.
II. INTENSITIES Detailed discussions of intensity parameters, units, and measurement techniques have been given in Refs. [1-2] and will not be repeated here. However, in order to properly interpret the values given in Tables II and III and in the individual references, we must discuss the difference between the vibrational band intensity, Sv, and the integrated band intensity SBand. Sv is related to the squared vibrational transition moment by
s
»=(f£) v °§ iwr
(i)
where h is Planck's constant, c is the speed of light, v0 is the wavenumber of the band center, N is the total number of molecules of the absorbing gas per cubic centimeter per atmosphere, Qv is the vibrational partition function, and Κμ^)! is the vibrational transition moment. SBand is defined as the summation of individual line intensities S% for all possible rotational transitions within the vibrational band; that is, Sßand = Σ $A = Σ SvR*kF = Sv 2 RAF
(2)
where RA is the rotational factor, given by RBA = SXB exp {-hcEJkT)
(Wv 0 Q r ) [1 - exp (-hcv^/kT)]
(3)
where S'AB is the dimensionless quantity called the line strength by Herzberg [3], EA is the energy of the lower state A, k is Boltzmann's constant, T is the gas temperature in degrees Kelvin, v^ is the wavenumber of the transition from lower state A to upper state B, and Qr is the rotational partition function. In Eqs. (1-3) we are using the approximation Qv · Qr = Q, where Q is the total internal partition sum; this approximation is valid except at very high temperatures. The F-factor in Eq. (2) accounts for the effects of centrifugal distortion, Fermiand Coriolis-type interactions, and other perturbations. For a rigid rotor, the F-factor would be 1, and Sv and 5Band would be equal (assuming all possible rotational transitions are included in the summation). However, if the F-factor
INTENSITIES AND COLLISION-BROADENING PARAMETERS T
155
is significantly different from 1 for most of the rotational transitions, as the case for many C0 2 bands, SBand is usually larger than Sv. SBand values determined from the summation of individual line-intensity measurements using high-resolution techniques are more appropriate for comparison to low-resolution band intensity measurements (e.g., [4]). Therefore, where a given reference reports both Sv and SBand values, (e.g., [5]) we have chosen to include only the SBand values in Table 2. Unless the reported intensity is designated as Sv or SBand in the footnotes to the table, the reader should obtain more detailed information from the original reference. Table I gives the various units in which band intensities have been reported in our literature survey, along with the multiplicative factors used to convert these units to our standard units (cm-2 aim"1 at 300K) for comparison purposes. However, because these multiplicative factors do not account for the temperature dependence of the partition functions or the exponential factors shown in Eq. (3), the converted values may not represent the true band intensity at 300K, particularly for transitions whose lower state is not the ground state. Goldman, Dang-Nhu and Bouanich [6] give an excellent brief discussion of the temperature dependence of line intensities. Several of the references reporting intensity measurements of bands of CHC13, CDC13, CHC12F, CHC1F2, CHD2F, CHF3, and CDF3 give the results not as Sv or SBand as defined in Eqs. (1-3), but as a quantity denoted as G. This G is identical to the Γ originally defined by Golike et al. [7] and is usually reported in units of (length)2 mole-1 or (length)2 molecule-1. As previously stated in [2], G (or Γ) may be related to 5Band approximately by SBand = Gv0, where v0 is the wavenumber of the observed band center. To compare measurements by investigators in different laboratories and apply their results to atmospheric or astrophysical measurements, we must also understand the corrections applied for the isotopic composition of the measured gas samples. Unfortunately, in many papers, the isotopic composition is not specified, and the interpretation of "natural abundance" is left to the reader. Johns [8] discussed in detail the difference between the "natural abundance" of 13 C in atmospheric C0 2 and that in commercially supplied C0 2 . In our conversion of reported intensities to a consistent set of units, we have attempted to rescale each intensity value to represent the band intensity for a 100% pure sample of a single isotope. Where no specific isotopic abundance information has been given in the original reference, we have used the 1986 HITRAN abundances [9].
HI.
COLLISION BROADENING
For most of the range of pressures typically encountered in the terrestrial and planetary atmospheres, infrared vibration-rotation lines have predominantly the
156
τ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
Lorentz, or collision-broadened line shape, in which the width of the line is linearly dependent on the gas pressure (for a fixed temperature). At very low gas pressures, the line shapes follow the Doppler profile, where the line width depends only on the temperature, mass of the molecule, and wavenumber of the transition. In the intermediate range where the Doppler and Lorentz profiles both contribute significantly, the line shape is most often modeled by the Voigt profile, which is the convolution of these two profiles. Detailed expressions for these three line profiles have been given in [2] and will not be repeated here. The dependence of the collision-broadened halfwidth on pressure and temperature is usually expressed as bdp, T) = b°L(T0)p(To/Ty
(4)
where bL(p, T) is the collision-broadened halfwidth of the line at measured pressure p and temperature T, b*l(T0) is the collision-broadened halfwidth of the line at the reference pressure (usually 1 atm) and temperature T0 (usually 296 K). According to the classical theory, the exponent n should have the value 0.5; however, many of the experimental results cited in Table IV of the present compilation and in [2], show quite different values for n. The experimentally determined values of this exponent appear to vary according to the absorbing and perturbing gases and the vibrational and rotational quantum numbers. In recent years measurements of Lorentz broadening coefficients and their temperature dependence have become more numerous. There have been more measurements of individual line widths within a band, and very few studies reporting simply an average broadening coefficient (or n value) for an entire band. Recognizing that temperatures in the terrestrial upper atmosphere and in planetary atmospheres are quite different from ambient values in the laboratory, several investigators have pursued measurements of collision-broadened gasphase spectra at low temperatures down to about 150K. Other investigators, driven by requirements to measure the spectra of combustion exhaust gases in situ, have recorded laboratory collision-broadened spectra at high temperatures. Another area of increased interest has been the examination of line shapes that depart from the usual three forms (Lorentz, Doppler, Voigt) most commonly used to model laboratory, atmospheric, planetary, or astronomical spectra. Collisional narrowing is observed for spectral lines whose Lorentz halfwidth bL is very small. The Galatry line shape [10] is usually used to model the profiles of absorption lines affected by collisional narrowing in addition to Doppler and Lorentz broadening. Other phenomena that have been examined extensively include non-Lorentzian profiles in the far wings of very strong absorption lines (particularly for H 2 0 and C0 2 ) and line mixing (also called line coupling) in regions of very closely spaced lines such as ß-branches. References for laboratory studies of collisional narrowing, far-wing line shapes, and line mixing have also been included in Table IV.
INTENSITIES AND COLLISION-BROADENING PARAMETERS ψ
IV.
157
PRESSURE-INDUCED LINE SHIFTS
Shifts in the positions of vibration-rotation lines due to collisions with other gases have become a concern for certain types of infrared measurements. Since ambient pressures in the terrestrial and planetary atmospheres range from several Torr to several atmospheres, pressure-induced line shifts must be considered in spectroscopic studies of these atmospheres. Knowledge of line shifts is also important for certain transitions of C0 2 , CH4, and other gases that are used for stabilization of laser frequencies. Prior to the mid-1980s, very few measurements of pressure-induced line shifts appeared in the literature; most of these were for diatomic molecules such as CO, HBr, HC1, HF, H2, and HD. More recent studies have provided extensive information on shifts in transitions of larger molecules, including C0 2 , H 2 0, N 2 0, 0 3 , NH3, and CH4. However, some of these studies report measurements of shifts for only a small number of lines within a band. Theoretical prediction of pressure-induced line shifts has been successful only for selected types of molecules such as polar diatomic molecules [11,12]. Adequate models for pressure-induced shifts in bands of other molecules of interest for atmospheric studies, such as 0 3 or CH4, have not yet appeared. Only a very few measurements of pressure-induced line shifts at temperatures far above or below room temperature have been reported, and the form of the temperature dependence of the shifts is not certain. A number of investigators, including Grossmann and Browell [13,14], have modeled pressure-induced line shifts at low temperatures using a relation similar to that used for the Lorentz half widths: δ(Γ) = δ(Γ0)(Γ/Γ0Γ'
(5)
where δ(Γ) is the shift coefficient (in cnrVatm) at the measured temperature T, δ(Γ0) is the shift coefficient at the reference temperature T0, and the exponent ri is empirically determined. However, the above expression is not valid in cases where the line shift changes sign with temperature. Other investigators, such as Houdeau and Boulet [15], have developed more rigorous theoretical models to account for the temperature dependence of both halfwidths and shifts. V. EXPLANATION OF TABLES AND TABLE REFERENCES The tables continue in the format of Refs. [1-2] with one exception. For carbon dioxide and its isotopic variants, we have adopted the vibrational band notation of Rothman and Young [16], which is also used in the HITRAN and GEIS A spectroscopic line parameters compilations [9,17]. This notation is widely used by numerous investigators. Briefly, each vibrational level of C0 2 is designated by an integer whose five digits correspond to the sequence ViV2lv3r, where vi9
158 v
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
v2, and υ3 are the vibrational quantum numbers, / is the degeneracy index of the v2 vibrational mode, and r indicates the level's ranking in a Fermi resonance poly ad. Thus, the ground state is designated by 00001, the v\ level by 01101, the V! level by 10001, and the 2v\ level by 10002. For each transition the level designations are given with the upper level first. For example, the 12 C 16 0 2 laser transition at 961 cm -1 , designated v3-vx in the previous compilations, is indicated as 00011-10001 in the present work, and the v3-2v2 laser transition at 1064 cm-1 is indicated as 00011-10002. The literature values and references for intensities of vibration-rotation transitions are given in Tables II and III. All of these values are for electric dipole allowed transitions measured in the gas phase with a few exceptions. These include the "forbidden" 03301-00001 band of 12 C 16 0 2 at 2003 cm"1, liquid-phase measurements of several N 2 0 bands that were published along with gas-phase measurements, and quadrupole and electrically-induced dipole vibration-rotation transitions of H2 and N2. Purely rotational and electronic transitions are not included in the compilation. As in the previous compilations, Table II contains the data for molecules with 2, 3, 4, and 5 atoms. The molecular data are sorted first by number of atoms, then by molecular formula in alphabetical order, then by isotopic form in order of increasing molecular weight. If the isotopic forms are not individually specified, the reader should assume that the data refer to the most abundant isotope of the molecule. The first page of Table II serves as an index to the succeeding pages of the table. The bands for each molecule are presented in order of increasing wave number, with the assignments and band centers (in cm-1) given in the first column of the table. In the second column, headed Reference Value, are listed the integrated band intensity values as reported in the original references. Any unusual features of the reported measurements are indicated by footnotes in the relevant sections of the table. The third column of Table II contains the reported intensity values converted to units of cm -2 atm-1 at 300K using the factors given in Table I. References for the band intensity values are given in the fourth column of the table. Additional references that do not report band intensity values, but contain measurements of individual line intensities or transition dipole moments, are listed following the words See or See also in the second column. Table III lists references for gas-phase intensity measurements in vibrationrotation bands of molecules having six or more atoms. The entries are arranged in alphabetical order according to the name of the molecule. We have not distinguished among references for band intensities, individual line intensities, or dipole moment matrix elements. References for collision broadening are given in Table IV and those for pressure-induced line shifts are listed in Table V. Both tables have the same format. The arrangement of the data according to the number of atoms, molecular formula, and isotopic species of the absorbing molecule is the same as in Table II, and for each molecule the bands are listed in ascending wavenumber order. For
INTENSITIES A N D COLLISION-BROADENING PARAMETERS T
159
each band, whose identification and wavenumber are given in the first column, the references are listed according to the perturbing gases given in the second column, sortedfirstby number of atoms per molecule, then in alphabetical order by molecular formula or name as appropriate. Mixtures of broadening gases are listed according to their predominant component. As in the previous compilation of broadening references [2], the listings in the table do not indicate the precise nature of the broadening or shift measurements reported. The references cited include measurements for individual lines as well as average values reported for an entire band, and some of these measurements also address the temperature dependence of the line widths and shifts. For both Table IV and Table V, as in Table II, the first page of each table serves as an index to the remainder of the table. The reference lists are divided into two sections. The part labeled References contains only the references cited in the text, while that labeled Table References lists only the numbered references given in Tables II-V. ACKNOWLEDGEMENTS Our thanks are due to J. Miller of Hampton University for his assistance in collecting the references and Dr. W. B. Grant of NASA Langley Research Center for providing a number of references from Russian-language journals. TABLE I.
COMMONLY USED BAND INTENSITY UNITS AND CONVERSION FACTORS
Units cm^atm"1 at 300K cm^atm"1 at T cm^atm"1 at STP
For conversion to cm"2atm"1 at 300K, multiply by 1.0 3.3333T x 10"3 0.91053
(also called cm"2 amagat"1) cm-1 m"1 amagat"1
91.053
cm"V(g cm"2)
4.0623M x 10"5
cm mole'1
4.0623 x 10"5
km mole"1
4.0623
cm-Vimolecule cm"2) (also called cm molecule"1) cm"1 m"1 Pa"1 at 300K Notes: T is temperature in K. M is molecular weight in g/mole.
2.4464 x 10 19 1.01325 x 103
160
τ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO TABLE II
BIBLIOGRAPHY FOR BAND INTENSITIES OF MOLECULES WITH TWO TO FIVE ATOMS
Molecule
Page
Diatomic BrO CO ClO FO H79Br H81Br H35C1 H37C1 HF H2 N2 NH NO OH
161 161 161 161 161 162 162 162 162 162 162 163 163 163
Molecule
Page
Molecule
Page
H02 HOC1 H 2 32 S H 2 33 S H 2 34 S N20 N02
188 189 189 189 189 190 192 192 194 194 195 195 195 195 196 196 196 196
Five atomic CBrF3 CC14 CF4 CFC13 CF2C12 CF3C1 12 CH 4 13 CH 4 12 CH 3 D 12 CD 4 CHC13 CDC13 CH335C1 CH337C1 CHC12F CHC1F2 CHD2F CHF3 CDF 3 CH3I CH3N C1N0 3 GeH4 70 GeH 3 D HN0 3 SiF 4 SiH3D
201 201 201 201 201 202 202 204 204 204 205 205 206 206 206 206 207 207 208 208 209 209 210 210 210 211 211
16
o3 16 16 18
o o o o o o
16 18 16
16Q18Q18Q 18016Q180 18
03
16 0 12 C 32 S 16 0 13 C 32 S 16012C33S
Triatomic CF 2 12 16
c o2 13 16 c o2
12C160170 12 16 18
c o o
13C160180 12 18
c o2 c o2
13 18
cs2
C102 H 12 C 14 N H 13 C 14 N H 12 C 15 N DCN H2160 HDO D20 HTO H2180
16 0 12 C 34 S
164 164 171 173 174 176 177 177 177 177 177 180 180 180 181 186 187 187 187
so2 Four atomic CF3 CH3 C2H2 C2N2 COF2 H2CO H202 trans-HONO 14 NH 3 15 NH 3 14 ND 2 H 14 ND 3 15 ND 3 N03 PH3
196 196 196 198 198 198 199 199 199 200 200 200 200 200 200
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
161
TABLE II (2) BAND
REFERENCE VALUE
cm"2atm_1 at300K
REFERENCE
BrO 1-0 a
(723 cm"1)
*5.04 ± 0.80 cm^atm"1 at 298K
5.0
5 B a n d obtained by summing individual line intensities for both the 79BrO and
325(1991) 81
BrO isotopes.
CO 1-0
(2143 cm"1)
See Refs. 260(1985) and 196(1986)
2-0
(4260 cm"1)
2.07 ± 0.02 cm_1/(atm cm) STP See also Ref. 96(1985)
1.88
174(1986)
4.8 9.6
238(1986) 89(1987) 245(1988) 88(1989)
0.93
89(1987)
CIO 1-0
2-0
(844 cm"1)
(1670 cm"1)
4.9 cm^atm"1 at 296K 11.3 ± 2.0 cm^atm"1 at 296K 13.1 ± 1.1 cm^atm"1 at 296K 9.68 ± 1.45 cm^atm"1 at 296K See also Ref. 447(1988) ~ 0.94 cm^atm"1 at 296K
FO 8-7 7-6 6-5 5-4 4-3 3-2 2-1 1-0
(878 cm"1) ' (902 cm"1) (925 cm"1) (948 cm"1) (970 cm"1) (992 cm"1) (1013 cm'1) (1032 cm"1),
See Ref. 194(1988)
H79Br 1-0
(2559 cm'1)
See Ref. 382(1985)
6-0
(13989 cm"1)
See Ref. 109(1988)
7-0
(15998 cm"1)
See Ref. 109(1988)
8-0
(17909 cm"1)
See Ref. 109(1988)
11.1 12.9
162
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (3) BAND
REFERENCE VALUE
cm^atm'1 at 300K
REFERENCE
H81Br 1-0
(2559 cm"1)
See Ref. 382(1985)
6-0
(13987 cm"1)
See Ref. 109(1988)
7-0
(15996 cm"1)
See Ref. 109(1988)
8-0
(17907 cm"1)
See Ref. 109(1988) H35C1
1-0
(2886 cm"1)
118.39 c n r W 1 at 295K
116.42
344(1985)
37.22
344(1985)
383.45
344(1985)
See also Ref. 111(1985) 3-0
(8347 cm"1)
See Refs. 398(1988) and 322(1989) H37C1
1-0
(2884 cm'1)
37.85 cm^atm"1 at 295K See also Ref. 111(1985)
3-0
(8341 cm"1)
See Ref. 322(1989) HF
1
1
1-0
(3962 cm" )
389.95 cm^atm" at 295K H2
1-0
(4161 cm"1)
See Ref. 60(1990)
2-0
(8087 cm"1)
See Ref. 307(1987) N2
1-0
(2325 cm'1)
See Refs. 356(1986) and 412(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
T
163
TABLE II (4) BAND
REFERENCE VALUE
at300K
REFERENCE
NH 5-4
(2494 cm"1)
See Ref. 113(1989)
4-3
(2656 cm"1)
See Ref. 113(1989)
3-2
(2813 cm'1)
See Ref. 113(1989)
2-1
(2969 cm'1)
See Ref. 113(1989)
1-0
(3126 cm"1)
See Ref. 113(1989)
NO 117 + 3 cm^atm"1 at 273K 4.45 ± 0.04 x lO"17 cm molecule 1 See also Ref. 339(1986)
1-0
(1876 cm"1)
7-6
(1876 cm"1)
See Ref. 141(1985)
8-7
(1876 cm"1)
See Ref. 141(1985)
9-8
(1876 cm"1)
See Ref. 141(1985)
2-0
(3724 cm"1)
1.878 +90 -40 cm^atm"1 at 296K
5-0
(9100 cm-1)
b
a
(2.18 ± 0.11) x 10"26 m at 296.8K
106. 109.
316(1987) 33(1988)
1.853
346(1985)
5.3 x 10'5
251(1988)
a Value reported in text is apparently a typographical error and is inconsistent with individual intensities reported in Table I of Ref. 33. The correct value should be 4.45 + 0.04 x 10 -18 cm molecule-1. b
Units are actually m molecule·1.
OH 1-0
(3570 cm'1)
See Refs. 447(1988) and 318(1989)
164
v
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O T A B L E Π (5)
BAND
REFERENCE VALUE
at300K
REFERENCE
CF9 u3
(1114 cm·1)
νλ
(1225 cm"1)
2.8 x 10 -17 cm molecule-1 See also Ref. 445(1989)
690.
405(1990)
(3.4 ± 0.8) x 10 -18 cm molecule-1 (1.5 ± 0.4) x 10 -17 cm molecule-1 (1.1 ± 0.4) X 10 -17 cm -1 (molecule/cm2)-1
83. 367. 270.
326(1987) 327(1988) 445(1989)
8.9 x 10-3
222(1990)
a
Corrected value based on data in Ref. 326. 12 16
c o,
11102-10001 (544 cm-1)
f
0.00875 ± 0.00012 cm-2atm-1 at300K
11102-02201 (597 cm-1)
f
0.14929 ± 0.00056 cm-2atm-1 at300K
0.1517
222(1990)
10002-01101 (618 cm-1)
f
3.9904 ± 0.0068 cm^atm-1 at300K
4.05
222(1990)
11102-10002 (647 cm-1)
f
0.6903 ± 0.0018 cm-2atm-1 at300K
0.701
222(1990)
01101-00001 (667 cm-1)
f
02201-01101 (668 cm-1)
f
16.042 ± 0.028 cm-2atm-1 at 300K
03301-02201 (668 cm-1)
f
0.9751 ± 0.0028 cm-2atm-1 at300K
11101-10001 (689 cm-1)
f
20001-11101 (720 cm-1)
f
202.45 ± 0.29 cm-2atm-1 at 300K See also Ref. 429(1989)
205.7 16.30
222(1990) 222(1990)
0.991
222(1990)
0.3837 ± 0.0012 cm^atm'1 at300K
0.390
222(1990)
4.15 X 10 -22 cm-1/(molecule cm-2) at 296K
0.0103
129(1990)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
165
TABLE II (6) BAND
at 300K
REFERENCE VALUE
REFERENCE
12rl6, C 1 6 0 2 (continued) 10001-01101 (721 cm"1)
c f
3.78 ± 0.13 cm^atm"1 at 296K 4.0685 ± 0.0097 cm^atm"1 at300K See also Ref. 426(1989)
3.7 4.134
214(1988) 222(1990)
20002-11102 (739 cm"1)
f
6.89 X 10"3
222(1990)
11101-02201 (742 cm-1)
f
0.1736
222(1990)
0.158
129(1990) 222(1990)
0.006782 ± 0.000041 embalm"1 at300K See also Ref. 193(1990) 0.17085 ± 0.00037 cm^atm"1 at300K f 63.4 x 10"22 cm'1/(molecule cm'2) at 296K
12201-03301 (757 cm"1)
f
0.006763 ± 0.000049 cm^atm"1 at300K See also Ref. 193(1990)
6.87 x lO'3
11101-10002 (791 cm'1)
e
0.017
2(1986)
0.0187
131(1989)
0.02048
222(1990)
6.93 ± 0.42 x 10"22 cm_1/mol cm"2 at 294K c 7.65 x 10"22 cm/molecule f 0.020156 ± 0.000040 cm^atm"1 at300K
12201-11102 (828 cm'1)
e
20001-11102 (865 cm"1)
e
0.151 ± 0 . 0 1 1 x 10"22 cm'Vmol cm"2 at 294K
2(1986)
1.0 X 10"4
2(1986)
2.7 x 10"5
2(1986)
2.1 x 10"5
2(1986)
9.5 x lO"4
2(1986)
3.06 x 10"5
2(1986)
22
0.042 ± 0.002 x 10" cm_1/mol cm"2 at 294K
22
02211-12201 (899 cm"1)
«Ό.ΟΠ ± 0.001 x 10" cm'Vmol cm"2 at 294K
10011-20001 (918 cm"1)
e
01111-11101 (927 cm"1)
e
10012-20002 (942 cm"1)
3.8 x 10"4
0.0086 ± 0.0007 x 10cnrVmol cm -2 at 294K
22
22
0.382 ± 0.019 x 10" cm'Vmol cm"2 at 294K
22
^.0123 ± 0.0006 x lO" cm'Vmol cm'2 at 294K
166
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (7) BAND
REFERENCE VALUE 12
at300K
REFERENCE
C 1 6 0 2 (continued)
00011-10001 (961 cm"1)
e
6.000 ± 0.300 x 10"22 cm'Vmol cm -2 at 294K See also Refs. 399(1987), 182(1988), and 400(1989)
10011-20002 (1044 cm"1)
*0.015 ± 0.002 x 10"22 cm'Vmol cm -2 at 294K
00011-10002 (1064 cm"1)
*9.83 ± 0.49 X 10-22 cm'Vmol cm -2 at 294K See also Refs. 399(1987), 182(1988), and 400(1989)
10012-20003 (1064 cm"1)
0.015
2(1986)
3.7 x 10'5
2(1986)
0.024
2(1986)
^.029 ± 0.003 x 10"22 cm_1/mol cm -2 at 294K
7.2 x 10"5
2(1986)
01111-11102 (1072 cm"1)
*0.78 ± 0.04 x lO'22 cm'Vmol cm -2 at 294K
1.9 x 10"3
2(1986)
02211-12202 (1074 cm"1)
*0.026 ± 0.003 x 10"22 cnrVmol cm -2 at 294K
6.5 x 10"5
2(1986)
20003-01101 (1881 cm"1)
b
12.9 x 10"24 cnrVmolecule cm -2 at 296K
3.21 x 10"4
359(1985)
21103-10002 (1896 cm'1)
b
2.11 x lO'24 cm'1/molecule cm'2 at 296K
5.25 x 10"5
359(1985)
13302-02201 (1905 cm"1)
b
1.62 x 10' 24 cm"1/molecule cm"2 at 296K
4.03 x 10"5
359(1985)
12202-01101 (1918 cm"1)
b
39.12 x 10' 24 cnrVmolecule cm"2 at 296K
9.725 X 10"4 359(1985)
11102-00001 (1932 cm'1) Band System
5.55 ± 0.26 x 102 cm/mol
21102-10001 (1951 cm"1)
b
03301-00001 (2003 cm"1)
^.194 x 10"30 cm"1/molecule cm"2 at 296K
1.14 x 10"24 cm"1/molecule cm"2 at 296K
0.023
412(1989)
2.83 x 10"5
359(1985)
4.82 x 10"12 42(1985)
INTENSITIES AND COLLISION-BROADENING PARAMETERS ψ
167
TABLE II (8) BAND
REFERENCE VALUE 12
cm'^atm"1 at 300K
REFERENCE
6.62 X 10'5
358(1984)
5.5 x lO"6
359(1985)
2.84 X lO"4
358(1984)
3.11 X 10'5
358(1984)
C 16 0 2 (continued)
20002-01101 (2004 cm"1)
b
21102-02201 (2004 cm"1]
b
21102-10002 (2054 cm"1;)
b
22202-11102 (2075 cm"1,)
b
11101-00001 (2077 cm"1 i
b
5397.0 x 10"24 cm'Vmolecule cm"2 at 296K See also Ref. 177(1987)
0.13416
360(1986)
12201-01101 (2093 cm"1 )
b
0.01253
360(1986)
13301-02201 (2107 cm'1,)
b
34.4 x 10"24 cm'Vmolecule cm"2 at 296K
8.55 x 10"4
360(1986)
21101-10001 (2112 cm-1 )
b
23.3 x 10"24 cm'Vmolecule cm"2 at 296K
5.79 X 10"4
360(1986)
14401-03301 (2119 cm"1 )
b
2.09 x 10"24 cm'Vmolecule cm"2 at 296K
5.19 X lO'5
360(1986)
22201-11101 (2121 cm"1 )
b
4.10 X 10'5
360(1986)
20001-01101 (2130 cm"1 )
b
30002-11102 (2132 cm"1 l
b
0.73 x 10"24 cm'Vmolecule cm"2 at 296K
1.8 X 10'5
360(1986)
30001-11101 (2148 cm"1 i
b
1.23 x 10"24 cm'Vmolecule cm'2 at 296K
3.06 X 10'5
360(1986)
21101-02201 (2166 cm"1 I
b
16.5 x 10' 24 cm'Vmolecule cm"2 at 296K
4.10 X 10"4
360(1986)
2.661 x lO"24 cm'Vmolecule cm"2 at 296K 0.22 x 10"24 cm'Vmolecule cm -2 at 296K
11.44 X 10"24 cm'Vmolecule cm"2 at 296K 1.25 x 10"24 cm'Vmolecule cm"2 at 296K
504.0 x 10' 24 cm'Vmolecule cm"2 at 296K
1.65 x 10"24 cm'Vmolecule cm"2 at 296K 309.0 x 10"24 cm'Vmolecule cm"2 at 296K
7.681 X 10'3 360(1986)
168
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (9) BAND
REFERENCE VALUE
at300K
REFERENCE
1.06 x 10"4
360(1986)
3.0 x 10"6
360(1986)
7.0 X 10"6
360(1986)
2.3 x 10"5
360(1986)
3.6 x 103 cm/mol
0.15
412(1989)
02211-02201 (2324 cm"1)
a
7.097 ± 0.032 cm-2/atm at 300K 7.115 ± 0.033 cm"2/atm at 300K
7.21 7.23
220(1987) 221(1989)
10011-10001 (2327 cm'1)
a
2.765 ± 0.011 cm"2/atm at 300K 2.772 ± 0.012 cnrVatm at 300K
2.81 2.82
220(1987) 221(1989)
10012-10002 (2327 cm'1)
a
4.609 ± 0.016 cm"2/atm at 300K 4.625 ± 0.016 cm-2/atm at 300K
4.68 4.70
220(1987) 221(1989)
01111-01101 (2337 cm'1)
a
00011-00001 (2349 cm'1)
a
20011-20002 (2429 cm"1)
b
10011-10002 (2429 cm"1)
b
12
11112-11101 (2171 cm"1)
b
20012-20001 (2181 cm'1)
b
20013-20002 (2182 cm"1)
b
22201-03301 (2194 cm'1)
b
11101-00001 12201-01101 20001-01101 Band System
C 1 6 0 2 (continued)
4.26 x 10"24 cm'1/molecule cm'2 at 296K 0.12 x 10"24 cm'Vmolecule cm -2 at 296K 0.28 x 10"24 cm-1/molecule cm -2 at 296K 0.92 x 10"24 cm-1/molecule cm -2 at 296K
d
d
d
180.21 ± 0.30 cm-2/atm at 300K 180.69 ± 0.30 cm"2/atm at 300K
d
2218.6 ± 2.7 cm"2/atm at 300K 2232.7 ± 1.7 cm"2/atm at 300K See also Refs. 128(1986), 255(1986), 374(1988), and 375(1988)
d
0.085 x 10"24 cm-1/molecule cm -2 at 296K
65.26 x 10"24 cm_1/molecule cm -2 at 296K See also Refs. 200(1986) and 130(1988)
183.1 183.5
220(1987) 221(1989)
2254. 2268.
220(1987) 221(1989)
2.1 X 10"6
274(1984)
1.62 x lO'3
274(1984)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
169
TABLE II (10) BAND
REFERENCE VALUE 12
at 300K
REFERENCE
3.41 X 10-6
274(1984)
3.95 X 10-5
274(1984)
C 1 6 0 2 (continued)
20012-20003 (2429 cm"
b
0.137 x 10"24 cm-1/molecule cm -2 at 296K
11111-11102 (2458 cm"
b
20001-00001
See Ref. 412(1989)
1.59 x 10 -24 cm-1/molecule cm"2 at 296K
(2671 cm01111-00001 (3004 cm" 30004-01101 (3125 cm"
See Ref. 412(1989) b
7.11 x 10 -25 cm molecule"1
1.77 X 10-5
41(1988)
22203-01101 (3155 cm"
b
7.04 x 10"25 cm molecule-1
1.75 X 10-5
41(1988)
21103-00001 (3182 cm'
b
1.20 X 10 -23 cm molecule-1
2.98 x 10 -4
41(1988)
30003-01101 (3275 cm"
b
1.99 x 10 - 2 4 cm molecule-1
4.95 x 10-5
41(1988)
31103-10002 (3306 cm"
b
5.53 x 10 -25 cm molecule-1
1.38 x 10-5
41(1988)
21102-00001 (3339 cm
b
1.025 x 10 -22 cm molecule-1
2.55 x 10-3
41(1988)
22202-01101 (3341 cm
b
8.348 x 10 -24 cm molecule-1
2.08 x 10 -4
41(1988)
23302-02201 (3342 cm
b
5.63 x 10 -25 cm molecule-1
1.40 x 10-5
41(1988)
21102-00001 22202-01101 ! 23302-02201 ] Band System
6.6 X 101 cm/mol
2.7 X 10-3
412(1989)
170
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (11) BAND
REFERENCE VALUE 12
cm^atm"1 at300K
REFERENCE
9.57 X 10"6
41(1988)
1.918 1.902
140(1988) 221(1989)
C 1 6 0 2 (continued)
31102-10001 (3365 cm'1)
b
3.85 x 10 -25 cm molecule"1
11112-01101 (3580 cm'1)
a
1.8877 ± 0.0075 cm^atm'1 at 300K 1.8723 ± 0.0060 cm"2/atm at 300K
10012-00001 (3612 cm"1)
a
10011-00001 (3715 cm"1)
a
11111-01101 (3723 cm"1)
a
10012-00001 i 10011-00001 / Band system
76.0 ± 0.6 cm^atm"1 at STP See also Ref. 255(1986)
31103-00001 (4591 cm"1)
b
0.019 ± 0.001 x 10"22 cm_1/mol cm -2
4.7 x 10"5
20013-00001 (4854 cm"1)
4.85 ± 0.1 X 103 cm/mol
0.20
412(1990)
20012-00001 (4978 cm'1)
0.9699 cm_1/cm atm at STP 2.02 X 104 cm/mol
0.8826 0.821
403(1990) 412(1990)
1.46 ± 0.1 cm^atm"1 at STP
1.33
173(1986)
20013-00001 ^ (4854 cm'1) 20012-00001 ' (4978 cm"1) 1 20011-00001 (5100 cm' 1 )) a
d
23.878 ± 0.035 cm^atm'1 at 300K 24.015 ± 0.035 cm"2/atm at 300K
24.26 24.39
140(1988) 221(1989)
36.863 ± 0.073 cm^atm"1 at 300K 37.071 ± 0.074 cm-2/atm at 300K
37.45 37.65
140(1988) 221(1989)
d
d
3.0378 ± 0.0098 cm^atm"1 at 300K 3.076 ± 0.010 cm"2/atm at 300K
d
3.087 3.12 69.2
140(1988) 221(1989) 173(1986)
1(1984)
5 v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of C 1 6 0 2 in the sample, which was assumed to be 0.98421.
12
b
^band ( ^ t e x t *° r definition). Reported intensity is uncorrected for the isotopic abundance of C"O 2 ; HITRAN value 0.98414 was used.
12
C
5V (see text for definition).
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
171
TABLE II (12) BAND
REFERENCE VALUE 12
at300K
REFERENCE
C 1 6 0 2 (continued)
d
5 v (see text for definition) from measurements of Refs. 220 and 140 corrected for errors in temperature and isotope composition, and some new measurements in the 00011-00001 band. Reported intensity is uncorrected for the isotopic abundance of 1 2 C 1 6 0 2 , which was 0.98462.
e
S v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of C 1 6 0 2 ; HITRAN value 0.98414 was used.
12
Sw (see text for definition). Reported intensity is scaled using the isotopic abundance of 1 2 C 1 6 0 2 appropriate to the atmosphere (see Refs. 220 and 221), which was assumed to be 0.98421. f
10002-01101 (617 cm"1)
«Ό.ΟΟΚΕ ± 0.00036 c n r W 1 at300K
01101-00001 (648 cm"1)
^.HOO ± 0.0085 cm^atm'1 at300K
10001-01101 (722 cm"1)
<Ό.023773 ± 0.000094 cm^atm'1 at300K
2.149
222(1990)
00011-10001 (913 cm"1)
c
0.077 ± 0.004 x 10"22 cm'Vmol cm"2 at 294K See also Refs. 399(1987), 182(1988), and 400(1989)
0.017
2(1986)
00011-10002 (1018 cm"1)
c
0.012
2(1986)
12202-01101 (1883 cm"1)
b
9.1 x 10"4
359(1985)
11102-00001 (1897 cm'1)
b
9.10 X 10'3
359(1985)
20002-01101 (1997 cm"1)
b
1.0 x 10'3
359(1985)
21102-10002 (2024 cm'1)
b
3.41 x 10·4
358(1984)
0.054 ± 0.005 x 10-22 cm'Vmol cm -2 at 294K See also Refs. 399(1987) and 400(1989) 0.41 x 10' 24 cm'Vmolecule cm -2 at 296K
4.11 X 10' 24 cm'Vmolecule cm'2 at 296K 0.46 x 10' 24 cm"1/molecule cm'2 at 296K 0.154 x 10' 24 cm'Vmolecule cm"2 at 296K
5.5235 193.5
222(1990) 222(1990)
172
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (13) BAND
REFERENCE VALUE 13
cm^atm-1 at300K
REFERENCE
C 1 6 0 2 (continued)
11101-00001 (2037 cm"1)
b
63.04 X 10-24 cm"1/molecule cm"2 at 296K
0.140
358(1984)
12201-01101 (2052 cm"1)
b
6.38 x 10"24 cm'Vmolecule cm"2 at 296K
0.0141
358(1984)
21101-10001 (2064 cm"1)
b
0.338 x 10' 24 cm'1/molecule cm"2 at 296K
7.5 x 10"4
358(1984)
13301-02201 (2064 cm"1)
b
0.657 X 10"24 cm'Vmolecule cm"2 at 296K
1.5 X 10'3
358(1984)
20001-01101 (2102 cm'1)
b
7.68 X 10"3
360(1986)
21101-02201 (2136 cm"1)
b
6.2 x 10-4
360(1986)
10012-10001 (2158 cm'1)
b
1.7 x 10'3
360(1986)
21101-10002 (2168 cm'1)
b
0.13 x 10-24 cm"1/molecule cm"2 at 296K
2.9 X 10"4
360(1986)
01111-01101 (2272 cm"1)
a
1.969 ± 0.008 cm"2/atm at 300K 1.9763 ± 0.0085 cm"2/atm at 300K
00011-00001 (2283 cm"1)
a
21102-00001 (3290 cm'1)
b
8.98 x 10"25 cm molecule'1
20012-00001 (4887 cm"1)
c
6.2 ± 0.3 x 10'3 cm'2/atm STP
a
3.47 X 10"24 cm"1/molecule cm"2 at 296K 0.28 x 10"24 cm"1/molecule cm"2 at 296K 0.79 x 10-24 cm"1/molecule cm"2 at 296K
d
22.537 ± 0.038 cm"2/atm at 300K 22.633 ± 0.036 cnr2/atm at 300K
d
178.0 185.6 2038. 2125. 1.99 x 10"5 0.51
220(1987) 221(1989) 220(1987) 221(1989) 41(1988) 53(1985)
5 v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of C 1 6 0 2 in the sample, which was assumed to be 0.01106.
13
b
^bßnd ( ^ text f° r definition). Reported intensity is uncorrected for the isotopic abundance of Ä 2 ; HITRAN value 0.01105 was used.
1 3
INTENSITIES A N D COLLISION-BROADENING PARAMETERS T
173
TABLE II (14) BAND
REFERENCE VALUE 13
cm"zatm" at300K
REFERENCE
C 1 6 0 2 (continued)
C
5V (see text for definition). Reported intensity is uncorrected for the isotopic abundance of C 1 6 0 2 ; HITRAN value 0.01105 was used.
13 d
S v (see text for definition) from measurements of Ref. 220 corrected for errors in temperature and isotope composition, and some new measurements in the 00011-00001 band. Reported intensity is uncorrected for the isotopic abundance of 1 3 C 1 6 0 2 , which was 0.01065. e
5 v (see text for definition). Reported intensity is scaled using the isotopic abundance of C 1 6 0 2 appropriate to the atmosphere (see Refs. 220 and 221), which was assumed to be 0.01106. 13
12C160170
01101-00001 (665 cm'1)
«Ό. 14988 ± 0.00075 cm^atm"1 at300K
01111-11102 (1068 cm'1)
c
10002-00001 (1272 cm'1)
a
0.0075 ± 0.0015 x 10"22 cm-1/mol cm -2 at 294K
205.3
222(1990)
0.03
2(1986)
3.77 ± 0.08 x 10-5 cm"2/atm at 296K c 0.018 ± 0.003 x 10"22 cm'Vmol cm -2 at 294K
0.0510
413(1985)
0.060
2(1986)
10001-00001 (1376 cm"1)
*5.49 ± 0.09 x 10-5 cm-2/atm at 296K
0.0742
413(1985)
11102-00001 (1918 cm"1)
b
0.020
359(1985)
11101-00001 (2062 cm"1)
b
0.115
358(1984)
20001-01101 (2111 cm"1)
b
8.7 x 10"3
360(1986)
00011-00001 (2340 cm'1)
a
2256.
220(1987)
2234.
221(1989)
20003-00001 (2524 cm"1)
0.60 x 10"24 cm'Vmolecule cm -2 at 296K 3.43 x 10"24 cm'Vmolecule cm"2 at 296K 0.26 x 10"24 cm"1/molecule cm"2 at 296K
1.647 ± 0.016 cm"2/atm at300K d 1.653 ± 0.017 cm"2/atm at300K b
0.507 x 10"24 cm'Vmolecule cm"2 at 296K
0.017
274(1984)
174
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (15) BAND
REFERENCE VALUE
cm"zatm"J at300K
REFERENCE
I 2 c i 6 0 n 0 (continued) 20002-00001 (2641 cm"1)
b
1.14 x 10' 24 cm'Vmolecule cm"2 at 296K
0.0382
274(1984)
a
5 v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of I 2 c i 6 0 n 0 i n the sample, which was assumed to be 0.00073.
b
^Band ( ^ t e x t *°Γ definition). Reported intensity is uncorrected for the isotopic abundance of i 2 c T r 0 i 7 0 . H I T R A N value 0.000730 was used.
c
Sy (see text for definition). Reported intensity is uncorrected for the isotopic abundance of 12 C 16 0 17 0 . H I T R A N v a l u e 0.000730 was used.
d
5 v (see text for definition) from measurements of Ref. 220 corrected for errors in temperature and isotope composition, and some new measurements in the 00011-00001 band. Reported intensity is uncorrected for the isotopic abundance of 1 2 C 1 6 0 1 7 0 , which was 0.00074. e
5 v (see text for definition). Reported intensity is scaled using the isotopic abundance of C 1 6 0 1 7 0 appropriate to the atmosphere (see Refs. 220 and 221), which was assumed to be 0.00073. 12
12C160180
01101-00001 (662 cm"1)
f
00011-10001 (966 cm'1)
c
0.018 + 0.001 x 10"22 cnfVmol cm -2 at 294K
0.011
2(1986)
00011-10002 (1073 cm'1)
c
0.036 ± 0.004 x 10"22 cnvVmol cm"2 at 294K
0.022
2(1986)
11102-01101 (1239 cm'1)
d
5.53 ± 0.15 x 10-5cm-2/atm at 296K c 0.021 ± 0.002 x 10-22 cm-Vmol cm -2 at 294K
0.014
413(1985)
0.013
2(1986)
d
7.93 ± 0.07 x 10"4 cm"2/atm at 296K c 0.31 ± 0.016 x 10"22 cm-Vmol cm'2 at 294K
0.195
413(1985)
0.19
2(1986)
d
0.220
413(1985)
10002-00001 (1259 cm"1)
10001-00001 (1365 cm"1)
0.8081 ± 0.0039 cm^atm"1 at300K
8.91 ± 0.06 x 10-4 cm"2/atm at 296K
220.
222(1990)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
175
TABLE II (16) BAND
REFERENCE VALUE
cm^atm"1 at300K
REFERENCE
12 C 16 0 18 0 (continued) 11101-01101 (1387 cm"1)
d
8.49 ± 0.17 x 10-5cm"2/atm at 296K
11102-00001 (1902 cm"1)
b
11101-00001 (2049 cm'1)
b
12201-01101 (2066 cm"1)
b
20001-01101 (2095 cm"1)
b
00011-00001 (2332 cm'1)
a
10011-10002 (2416 cm"1)
b
21103-01101 (2465 cm-1)
b
20003-00001 (2501 cm"1)
b
20002-00001 (2614 cm"1)
b
21102-01101 (2619 cm"1)
b
21102-00001 (3281 cm"1)
b
01121-01101 (4615 cm"1)
b
00021-00001 (4640 cm'1)
b
e
0.021
413(1985)
0.0195
359(1985)
17.51 x 10-24 cm'Vmolecule cm"2 at 296K
0.107
358(1984)
1.94 X 10"24 cm'Vmolecule cm"2 at 296K
0.012
358(1984)
1.16 x 10"24 cm'Vmolecule cm"2 at 296K
7.06 x 10"3
360(1986)
8.952 ± 0.034 cm'2/atm at 300K 8.975 ± 0.041 cm'2/atm at 300K
2439. 2249.
220(1987) 221(1989)
3.20 x 10"24 cm'Vmolecule cm"2 at 296K
0.325 x lO'24 cm"1/molecule cm'2 at 296K 1.15 x 10"24 cm'Vmolecule cm"2 at 296K 11.49 x 10"24 cm'Vmolecule cm"2 at 296K
1.98 x lO"3
274(1984)
7.00 x lO'3
274(1984)
0.06992
274(1984)
0.1529
274(1984)
9.86 x 10"3
274(1984)
4.49 x 10"25 cm molecule"1
2.73 x lO'3
41(1988)
0.0104 + 0.0009 x 10"22 cm'Vmol cm"2
6.33 x lO"3
1(1984)
0.0755
1(1984)
25.13 x 10' 24 cm'Vmolecule cm'2 at 296K 1.62 x 10' 24 cm'Vmolecule cm'2 at 296K
0.124 ± 0.002 x 10"22 cm"Vmol cm"2
176
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (17) BAND
REFERENCE VALUE
cm"2atm_1 at 300K
REFERENCE
12 C 16 0 18 0 (continued) 20012-00001 (4905 cm"1)
See Ref. 53(1985)
a
5 v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of 12 C 16 0 18 0 in the sample, which was assumed to be 0.00367.
b
^Band ( ^ text f° r definition). Reported intensity is uncorrected for the isotopic abundance of 12 C TCQ18 0 . H I T R A N v a l u e 0.00402 was used.
C
5V (see text for definition). Reported intensity is uncorrected for the isotopic abundance of 12 C 16 0 18 0; HITRAN value 0.00402 was used.
d
5 v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of 12 C 16 0 18 0) w h i c h w a s o 00402.
β
5 ν (see text for definition) from measurements of Ref. 220 corrected for errors in temperature and isotope composition, and some new measurements in the 00011-00001 band. Reported intensity is uncorrected for the isotopic abundance of 1 2 C 1 6 0 1 8 0 , which was 0.00399. f
5v 12
(see text for definition). Reported intensity is scaled using the isotopic abundance of C 1 6 0 1 8 0 appropriate to the atmosphere (see Refs. 220 and 221), which was assumed to be 0.00367. 13C160180
10002-00001 (1244 cm"1)
*6.63 ± 0.52 x 10"6 cm"2/atm at 296K
0.14
413(1985)
10001-00001 (1342 cm'1)
a
0.343
413(1985)
11101-00001 (2005 cm"1)
b
0.20 x 10"24 cm-1/molecule cm -2 at 296K
0.11
359(1985)
20002-00001 (2614 cm"1)
b
0.242 X 10-24 cnfVmolecule cm -2 at 296K
0.13
274(1984)
1.55 ± 0.07 x 10"5 cm-2/atm at 296K
a
5 v (see text for definition). Reported intensity is uncorrected for the isotopic abundance of 13 C 16 0 18 0) w h i c h w a s 0.0000452.
b
^Band ( ^ t e x t f° r definition). Reported intensity is uncorrected for the isotopic abundance of C**0 18 0; HITRAN value 0.0000452 was used.
13
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
177
TABLE II (18) BAND
REFERENCE VALUE 12
at 300K
REFERENCE
C 1 8 0,
00011-10001 (967 cm"1)
See Refs. 182(1988) and 400(1989)
00011-10002 (1084 cm'1)
See Refs. 399(1987) and 400(1989) 13 r 18, 18
c o2
00011-10001 (944 cm-1)
See Ref. 400(1989)
00011-10002 (1069 cm'1)
See Ref. 400(1989) CS9
vyvx νλ+ρ3
(877 cm"1) 1
1.064 + 0.020 cm^atm"1 at 297K *64.2 ± 1.2 cm^atm'1 at 297K
1.05 64.
132(1986) 132(1986)
(2185 cm" )
Predicted using vibrational transition moment determined from measurements in the v3-v1 band.
cio 7 vvll p3
1 (946 ^40 cm' cm x;) ΛΛ (1110 cm- 1 )/
See Ref. 7(1984) H 12 C 14 N
vx
(2097 cm"1)
See Ref. 21(1988)
i/3
(3311 cm"1)
267 + 8 cm^atm'1 at 273.2K See also Refs. 142(1984), 150(1984), and 21(1988)
2vx
(4173 cm'1)
See Ref. 21(1988)
vx+v3
(5394 cm"1)
See Ref. 21(1988)
243.
434(1984)
178
ψ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE II (19) BAND
REFERENCE VALUE
at 300K
REFERENCE
H12C14N (continued) 2vyv2l
(5806 cm1) (6085 cm"1)
3^ i>2
2v3
(6229 cm"1) -rlvyv^
1
1369.0 ± 23.0 cm/mol
0.0556
387(1989)
104.0 ± 2.0 cm/mol
4.23 x 10"3 387(1989)
23.21 ± 0.79 cm/mol See also Ref. 21(1988)
9.43 x 10-4
387(1989)
8.20 ±0.11 x 104 cm/mol
3.3
387(1989)
8.499 ± 0.054 X 104 cm/mol See also Refs. 21(1988) and 376(1988)
3.45
387(1989)
(6480 cm' )
(6520 cm"1)
2ίΊ + ί/3
(7455 cm"1)
20.92 ± 0.86 cm/mol See also Ref. 21(1988)
8.50 x 10"4 387(1989)
1094.0 ± 17.0 cm/mol
0.0444
387(1989)
^j+2^3
1010.0 ± 3.0 cm/mol See also Ref. 21(1988)
0.04103
387(1989)
ίΊ+ί>2 +2ι/3 (9257 cm"1)
3.825 ± 0.045 cm/mol
1.55 x 10"4 387(1989)
3^1 + ^3
10.53 ± 0.20 cm/mol
4.28 x 10"4 387(1989)
(8544 cm"1) (8586 cm"1)
1
(9496 cm" )
V'Ll+?>VyV2L
2492.0 ± 38.0 cm/mol
0.101
387(1989)
2547.0 ± 12.0 cm/mol See also Ref. 21(1988)
0.104
387(1989)
1
(9568 cm' ) 3P3
(9627 cm'1)
vl+2v1°+2v3 (9914 cm"1)
7.72 ± 0.08 cm/mol
3.14 X 10-4
387(1989)
v2l+?>v3 (10282 cm"1)
0.702 ± 0.021 cm/mol
2.9 x 10"5
387(1989)
INTENSITIES AND COLLISION-BROADENING PARAMETERS v 179 TABLE I1 (20) BAND
REFERENCE VALUE
cmZatm-l at 300K
REFERENCE
387(1989)
H12C14N (continued)
2v1+2v3 (10631 cm-')
6.79 f 0.10 cmlmol
2.8
V1+3V3 (1 1674 cm-')
100.0 f 0.5 cm/mol
4.062
v21+4v3-v2' (12557 cm-')
176.0 k 7.0 cm/mol
7.15
4v3 (12636 cm-')
154 f 3 cmlmol 157.0 f 1.0 cm/mol
6.26 X l o 3 388(1987) 6.38 x l o 3 387(1989)
3V1+2V3 (12658 cm-')
9.7 f 0.3 cmlmol 9.11 f 0.25 cm/mol
3.9 3.7
X X
lo4 lo4
388(1987) 387(1989)
0.171 k 0.025 cm/mol
6.9
X
10"
387(1989)
2V1+3V3 (13702 cm-')
3.1 f 0.2 cm/mol 2.89 f 0.04 cm/mol
1.3 X lo4 1.17 X lo4
4V1+2V3 (14654 cm-')
8.0 f 0.4 cm/mol 8.33 f 0.10 cm/mol
3.3 3.4
v1+4v3 (14670 cm-')
7.2 0.4 cm/mol 9.42 f 0.09 cm/mol
2.9 x lo4 3.83 x lo4
388(1987) 387(1989)
v2+5v3-v2 (15452 cm-')
16.8 cmlmol
6.82
X
lo4
390(1986)
5v3 (15552 cm-')
17.5 f 0.4 cm/mol 17.5 f 0.4 cm/mol
7.11 7.11
X
lo4 lo4
390(1986) 388(1987)
3v, +3v3 (15711 cm-')
0.05 f 0.01 cm/mol
2
10"
V2'+5V3 (16164 cm-')
0.047 f 0.008 cm/mol
1.9
5Vl+2V3 (16640 cm-')
0.40 f 0.04 cm/mol
1.6 x
V2'
+4V3 (13271 cm-')
X
lo4
X
l o 3 387(1989)
X
X
X X
X
X
lo3 387(1989)
lo4 lo4
10"
388(1987) 387(1989) 388(1987) 387(1989)
388(1987) 388(1987) 388(1987)
180
v
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE II (21) BAND
REFERENCE VALUE
cm^atm"1 at300K
REFERENCE
H 12 C 14 N (continued) 2ί>1+4ϊ'3 (16674 cm"1)
1.7 + 0.1 cm/mol
6.9 x 10"5
388(1987)
ΐΊ+5ι>3 (17550 cm"1)
13.9 ± 0.4 cm/mol 16.7 ± 0.4 cm/mol
5.65 x 10"4 6.78 X 10"4
388(1987) 389(1989)
2.4 ± 0.2 cm/mol
9.8 x IQ'5
388(1987)
6v3
(18377 cm"1)
H 13 C 14 N 2i>3
(6483 cm"1)
l>l+2l>3 (8519 cm'1) 3v3
(9572 cm"1)
8.68 ± 0.21 x 104 cm/mol
3.5
387(1989)
902.0 ± 29.0 cm/mol
0.037
387(1989)
0.103
387(1989)
2537.0 ± 64.0 cm/mol 12
15
H C N 2i/3
(6516 cm"1)
8.78 ± 0.27 x 104 cm/mol
3.6
387(1989)
3i>3
(9621 cm"1)
2900.0 ± 125.0 cm/mol
0.12
387(1989)
DCN νγ
(1925 cm'1)
See Ref. 21(1988)
v3
(2630 cm"1)
See Ref. 21(1988)
2vx
(3836 cm'1)
See Ref. 21(1988)
"l + "3
See Ref. 21(1988) (4523 cm"1)
2v3
(5220 cm"1)
See Ref. 21(1988)
3vx
(5734 cm"1)
See Ref. 21(1988)
2νγ+ν3 (6402 cm"1)
See Ref. 21(1988)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
181
TABLE II (22) BAND
REFERENCE VALUE
cm"zatm"J at300K
REFERENCE
DCN (continued) See Ref. 21(1988)
ί'1+2ϊ>3 1
(7080 cm" ) 3^3
(7771 cm"1)
See Ref. 21(1988) See also Ref. 142(1984) H2160
v2
(1595 cm'1)
3v2
(4667 cm"1)
1 T "2
v2 + v 3
(5235 cm'1)
See Refs. 271(1985), 4(1986), 198(1987), and 6(1988) 28400 ( ± 57c) cm1 Ig cm7
20.8
446(1985)
(5331 cm"1)
Ργ+2ν2 (6775 cm'1) (6872 cm"1) 2νγ
(7202 cm"1)
Vi + V2 + VyV2
(7212 cm'1) (7250 cm"1)
See Ref. 281(1986) See Ref. 281(1986) See Ref. 281(1986) See Ref. 281(1986) See Ref. 281(1986)
2„ 3
(7445 cm"1)
See Ref. 281(1986)
5*2
(7552 cm"1)
0.028 ( ± 20%) x 10"22 cm'Vimolecule cm"2) at 296K See also Ref. 92(1987)
6.8 x 10"5
285(1988)
Ργ+2ν2 2P2+V2
2vx "i + "3
2i>2
24700 ( ± 5%)cm" 1 /gcm- 2 See also Ref. 67(1987)
18.1
446(1985)
182
τ
SMITH, R I N S L A N D , D E V I , R O T H M A N , R A O
TABLE II (23) BAND
REFERENCE VALUE
at 300K
REFERENCE
2.9 X 10"3
285(1988)
1.2
446(1985)
H 2 1 6 0 (continued) (8274 cm"1) 3^2+^3 (8374 cm"1) (8734 cm"1) 2i> 1 + »>2
(8762 cm"1) (8807 cm"1)
6v2
(8890 cm"1)
^2+2^3 (9000 cm 1 )
See Refs. 92(1987) and 285(1988) See Refs. 92(1987) and 285(1988) See Ref. 285(1988) See Refs. 115(1985), 92(1987), and 285(1988) See Refs. 115(1985), 436(1985), 92(1987), and 285(1988) 1.2 ( ± 20%) x 10' 22 cm-Vimolecule cm-2) at 296K See Refs. 115(1985), 436(1985), 92(1987), and 285(1988)
Vi+3i>2 3^2 + ^3 1^2+2^3 4^2 + ^3 (9834 cm"1)
1610 ( ± 10%) cm'Vg cm'2
See Ref. 121(1989)
2^+21/2 (10284 cm'1)
See Ref. 121(1989)
Ργ +2^2 + ^3 (10329 cm"1)
See Ref. 121(1989)
2^2+2^3 (10537 cm"1)
See Ref. 121(1989)
(10600 cm-1)
See Ref. 121(1989)
2νγ +Ρ3 (10613 cm'1)
See Ref. 121(1989)
3^
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
183
TABLE II (24) BAND
REFERENCE VALUE
cm^atm"1 at300K
REFERENCE
H 2 1 6 0 (continued) See Ref. 121(1989)
ί>1+2ί'3
(10869 cm"1)
3P3
(11032 cm·1)
See Ref. 121(1989)
2Ργ+2Ρ2 \ Ργ+2Ρ2 + Ρ-$ 3PX 1 2Ργ + Ρ<$ 1
»Ί+2ι>3 3^
1110 ( ± 10%) cm-Vg cm'2
0.81
446(1985)
51 ( ± 10%) cm-Vg cm"2
0.037
446(1985)
/
V\+3P2+V3
\
(11813 cm·1) 3Ργ+Ρ2 J (12140 cm"1) ( 2ργ + Ρ2+Ρι I (12151 cm"1) \ Ργ + Ρ2 + 2Ρ<±
(12408 cm- 1 )/
2Ργ + Ρ2 + Ρ3
See Ref. 314(1988)
P\+^P2 + V3
See Refs. 283(1986) and 187(1989)
4i/ 2 +2i>3
See Refs. 283(1986) and 187(1989)
3^+2^2 (13642 cm"1)
See Refs. 283(1986) and 187(1989)
2i' 1 +2j>2+J'3
See Refs. 94(1986), 283(1986), and 187(1989)
2ργ+2ρ$
See Refs. 283(1986) and 187(1989)
3Ργ + Ρ<$
See Refs. 94(1986), 283(1986), and 187(1989)
(12151 cm"1) (13200 cm"1) (13500 cm'1)
(13653 cm"1) (13828 cm'1) (13831 Dm'1)
184
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N ,
RAO
TABLE II (25) BAND
REFERENCE VALUE
at 300K
REFERENCE
H 2 1 6 0 (continued) 2l>!+ 2 »>2 + ^3 2ί>1+2ί>3
56 ( ± 10%) cm'Vg cm'2
v^-\-2vj+2v>$ (13911cm· 1 )
See Ref. 187(1989)
2ϊ>2 + 3ϊ>3
See Ref. 283(1986)
(14066 cm-1) 4vx
(14221 cm"1) (14319 cm'1)
See Ref. 283(1986) See Ref. 283(1986)
2νγ +3^2"·" ^3 (15119 cm"1)
See Ref. 283(1986)
2i>1 + »'2+ 2^3 (15345 cm'1)
See Ref. 283(1986)
3l^ + J>2 + ^3 (15348 cm"1)
See Ref. 283(1986)
4^1 + ^2 (15743 cm"1)
See Ref. 283(1986)
Vi +^2 + 3^3 (15833 cm'1)
See Ref. 283(1986)
21/^2^2+2^3 (16819 cm"1)
See Ref. 99(1985)
3»^+21/2+^3 (16822 cm'1)
See Ref. 99(1985)
3v\+2v^ (16898 cm 1 )
See Ref. 99(1985)
2v\+3v-$ (16899 cm 1 )
See Ref. 99(1985)
0.041
446(1985)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
185
T A B L E II (26)
BAND
REFERENCE VALUE H 2 1 6 0 (continued) See Ref. 99(1985)
ρχ +2P2+3P3 1
(17313 cm" ) (17458 cm"1)
See Ref. 99(1985)
4 ^ + 1/3 (17496 cm"1)
See Ref. 99(1985)
3PX+3P2+P2
See Ref. 99(1985)
2PX + P2+3P3 (18393 cm"1)
S e e Ref
3PX+P2+2P2
See Ref. 99(1985)
4ι>1 + ι>2+μ3 (18990 cm"1)
See Ref. 99(1985)
4PX+2P2+P3
See Ref. 99(1985)
3*!+3*3 (19781 cm'1)
See Ref. 99(1985)
4PX+2P3
See Ref. 99(1985)
5PX + P3 (20543 cm"1)
See Ref. 99(1985)
3PX+P2+3P3
See Ref. 99(1985)
4PX+P2+2P3
See Ref. 99(1985)
4ΡΧ+3Ρ3
See Ref. 99(1985)
5vx
(18266 cm'1)
(18393 cm"1)
(19740 cm"1)
(19782 cm'1)
(21222 cm"1) (21222 cm"1) (22529 cm"1)
· 99(1985)
cm"2atm-1 at 300K
REFERENCE
186
v
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (27) BAND
REFERENCE VALUE
cm"zatm"J at300K
REFERENCE
HDO v2
ρχ
2v2
\+v2
(1403 cm"1)
(2724 cm"1)
(2782 cm"1)
v
3P2
(4100 cm"1)
(4145 cm"1)
*0.353 X 10"17 cm_1/(molecule cm"2) at 296K b 0.595 x 10-17 cm_1/(molecule cm"2) at 296K See also Ref. 411(1986) c
0.206 X 10"17 cm"V(molecule cm"2) at 296K d 0.438 x 10"19 cm"V(molecule cm"2) at 296K ^.211 x 10"17 cm'Vimolecule cm"2) at 296K
c
86.4 146.
50.4 1.07 51.6
156(1986) 156(1986)
334(1985) 334(1985) 334(1985)
0.174 X 10"18 cm"1/(molecule cm"2) at 296K «kUOö x 10"18 cm'Vimolecule cm'2) at 296K *0.280 x 10"18 cm'Vimolecule cm"2) at 296K
4.26
334(1985)
2.59
334(1985)
6.85
334(1985)
f
0.201 X 10"18 cm'Vimolecule cm"2) at 296K 80.115 x 10"19 cm'Vimolecule cm"2) at 296K
4.92
332(1986)
0.281
332(1986)
f
2.59
332(1986)
0.201
332(1986)
0.106 x 10"18 cm"V(molecule cm"2) at 296K «0.821 x 10"20 cm'Vimolecule cm"2) at 296K
a
5 B a n d value for /4-type transitions.
b
5 B a n d value for B-type transitions.
c
5 B a n d value derived from a re-analysis of/1-type transitions whose measurements were reported in Ref. 494 of Smith et al. [2].
d
5 B a n d value derived from a re-analysis of 5-type transitions whose measurements were reported in Ref. 494 of Smith et al. [2].
e
5 B a n d value derived from a re-analysis of Λ-type and Ä-type transitions whose measurements were reported in Ref. 494 of Smith et al. [2].
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
187
TABLE II (28) BAND
REFERENCE VALUE
at300K
REFERENCE
HDO (continued) f 5 B a n d value derived from a re-analysis of Λ-type transitions whose measurements were reported in Ref. 488 of Smith et al. [2]. 8
^Band value derived from a re-analysis of B-type transitions whose measurements were reported in Ref. 488 of Smith et al [2].
D2O "2
(1178 cm"1)
See Ref. 411(1986)
HTO "2
(1324 cm"1)
See Ref. 116(1987) H2180
3P2
(4658 cm'1) (5212 cm"1)
2l>2 + *'3-i,2
(5256 cm"1)
i>2+p3
1
4.88 x 10"22 cm molecule-1
0.0119
118(1985)
3.09 x 10"20 cm molecule'1
0.756
118(1985)
See Refs. 119(1986) and 417(1989) 7.62 x 10' 19 cm molecule"1
18.6
118(1985)
(5310 cm' ) 4J/ 2
(6134 cm"1)
1>γ+2ν2
1
(6756 cm" )
2^2 + v3
(6845 cm"1)
2vx
(7186 cm"1)
a
7 x 10"23 cm^molecule^cm"2 at300K See also Ref. 117(1986)
0.002
416(1989)
a
0.033 x 10"19 cm^molecule^cnT2 at 300K See also Ref. 117(1986)
0.081
416(1989)
a
0.403 x 10"19 cm'Molecule -1 cm -2 at 300K See also Ref. 117(1986)
0.986
416(1989)
*0.780 x 10"19 cm"1 molecule" ^m"2 at 300K See also Ref. 117(1986)
1.91
416(1989)
188
τ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE II (29) BAND
at300K
REFERENCE VALUE
REFERENCE
H 2 18 0 (continued) vx + v3 (7229 cm"1) 2P3
(7419 cm'1)
a
4.852 X lO'19 cm^molecule^cm"2 at 300K See also Ref. 117(1986)
11.87
416(1989)
*0.056 x 10"19 cm^molecule^cm'2 at 300K See also Ref. 117(1986)
0.14
416(1989)
4^2 + ^3
See Ref. 120(1987)
2^+2^ (10257 cm"1)
See Ref. 120(1987)
1^+2^2 + ^3
See Ref. 120(1987)
(9795 cm"1)
(10296 cm'1) 3vx (10574 cm'1)
See Ref. 120(1987) See Ref. 120(1987)
2i'1H-i»3
(10585 cm'1) v{+2i>2
See Ref. 120(1987)
(10840 cm"1) 3*>3 (10994 cm-1) a
From a re-analysis
See Ref. 120(1987) of the data from Ref. 117. HO.
v3
(1080 cm'1)
1.1 x 10'18 cm molecule"1
27.
79(1983)
v2
(1390 cm*1)
58 ± 16 cm-2(STP atm)"1
53.
448(1989)
2
18.
448(1989)
vx
1
(3436 cm" )
1
20 ± 6 cm" (STP atm)"
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
189
TABLE II (30) BAND
REFERENCE VALUE
at 300K
REFERENCE
HOC1 i>3
(720 cm"1)
45 ( ± 5%) cm^atm'1 at 295K See also Ref. 242(1986)
44.
321(1979)
v2
(1238 cm'1)
265 ( ± 5%) cm^atm'1 at 295K See also Ref. 242(1986)
261.
321(1979)
H 2 32 S 2v2
(2354 cm"1)
0.1390 x 10'19 cm-Vmolecule cm'2
0.3401
250(1984)
νγ
(2614 cm'1)
0.1776 x 10'19 cm-Vmolecule cm"2
0.4345
250(1984)
0.4520 x 10"20 cm-Vmolecule cm"2
0.1106
250(1984)
0.2373 x 10' 20 cm'Vmolecule cm*2 at 296K
0.06696
249(1987)
0.8641 x 10"20 cm'Vmolecule cm"2 at 296K
0.2114
249(1987)
0.4521 X lO"22 cm'Vmolecule cm"2 at 296K
0.001106
249(1987)
v3
1
(2628 cm" ) 1
(6288 cm" ) 1
(6289 cm" ) j/2+2i>3
(6389 cm'1)
H 2 33 S 2i>2 v
(2353 cm'1) 1
See Ref. 250(1984)
\
(2613 cm' )
See Ref. 250(1984)
"3
(2627 cm'1)
See Ref. 250(1984) H 2 34 S
2v2
(2352 cm'1)
See Ref. 250(1984)
vx
(2612 cm'1)
See Ref. 250(1984)
v3
(2626 cm'1)
See Ref. 250(1984)
2^1 + ^2 (6283 cm'1)
See Ref. 249(1987)
190
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (31) BAND
REFERENCE VALUE
cm^atm'1 at300K
REFERENCE
H 2 34 S (continued) (6284 cm"1) ί>2+2ι>3
(6384 cm'1)
See Ref. 249(1987) See Ref. 249(1987)
N20 2i>2° (1168 cm"1)
6.98 ± 0.26 cm^atm'1 at 296K
6.9
407(1989)
2v2° Band System
8.46 ± 0.09 cm^atnf1 at 297K
8.38
419(1988)
1
vx
(1285 cm" )
vi
Band System
v
2 ~^~vyv2
See Ref. 432(1989) 225 ± 2 cm^atm-1 at 297K
223.
419(1988)
1191.
259(1986)
See Ref. 259(1986)
(2224 cm"1)
i>3
(2224 cm"1)
(3364 cm"1) I "ι + ^ , ' (3481 cm"1) Band System 2i/ 1 +2i/ 2 ° (3749 cm"1) 3^ (3836 cm"1) Band System
1203 ± 22 cm^atm'1 at 297K a
49.9 ± 0.3 cm'Viatm cm) STP
b
45.4
174(1986)
3.25 ± 0.02 cm-V(atm cm) STP
2.96
174(1986)
0.035 ± 0.002 cm-V(atm cm) STP 288 x IO-4 cm^amagaf1
0.032 0.0262
174(1986) 8(1989)
e
1.67 ± 0.01 cm-V(atm cm) STP 1850 x 10"4 cm^amagaf1
1.52 0.168
174(1986) 8(1989)
ί/ 1 +2ί/ 2 °+ι/ 3 (4630 cm'1)
1780 x 10"4 cm^amagaf1
0.162
8(1989)
2^2 + ^3
1080 x 10"4 cm^amagaf1
0.0983
8(1989)
l* 1 + 1*2 +"3 (4062 cm"1) 2v3
(4417 cm'1)
(4731 cm"1)
c
d
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
191
TABLE II (32) BAND
REFERENCE VALUE
at 300K
REFERENCE
N 2 0 (continued) 21Ί+Ϊ/3 J Band System
f
1.14 ± 0.01 cm_1/(atm cm) STP
1.04
174(1986)
2i/1+4i>2° (4911 cm"1)
120 x 10"4 cm^amagaf1
0.0109
8(1989)
670 x 10"4 cm"zamagaf
0.0610
8(1989)
720 x 10"4 cm^amagat"1
0.0656
8(1989)
«0.153 ± 0.002 cm_1/(atm cm) STP
0.139
174(1986)
112 x 10"4 cm^amagaf1
0.0102
8(1989)
72.7 x 10"4 cm^amagaf1
6.62 x 10-3
8(1989)
184 x 10"4 cm_2amagat"1
0.0168
8(1989)
*21+2"3
(4978 cm"1) 3i/ 1 +2// 2 ° (5026 cm"1) 4Ϊ/Χ
(5107 cm-1)
2I/,+4I/2° "2 +2J> 3 3^+2P20 4I/J
Band System 6i> 2 +»>3
(5647 cm"1) (5888 cm"1) (5975 cm"1)
d
14.4 x 10"4 cm^amagat'1
1.31 X 10"3
8(1989)
d
45 x 10"4 cm^amagaf1
4.1 x 10"3
8(1989)
21 x 10"4 cm^amagaf1
1.9 x lO"3
8(1989)
3ί/1+4ι/2° (6192 cm"1) 4I/ 1 +2J/2°
1
(6295 cm' )
5vx 3i>3
(6373 cm"1) 1
(6581 cm" )
d
4
330 x 10" cm^amagaf
integrated intensity from 3200 to 3670 cm-1. integrated intensity from 3670 to 4000 cm'1.
1
0.0301
8(1989)
192
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (33) BAND
REFERENCE VALUE
cm"zatm_1 at 300K
REFERENCE
1015.
104(1986)
N 2 0 (continued) c
Integrated intensity from 4000 to 4100 cm"1.
d
Liquid-phase measurement.
integrated intensity from 4100 to 4530 cm"1. integrated intensity from 4530 to 4900 cm"1. «Integrated intensity from 4900 to 5300 cm"1.
N0 9 1
v2
(750 cm" )
See Ref. 333(1988)
P3
(1621 cm"1)
See Ref. 301(1990)
v3
Band System
4.15 x 10"17 cm molecule"1 16
0,
See Ref. 340(1988)
2v 2 - p 2
(698 cm"1) v2
(701 cm"1)
See Ref. 101(1990)
2vyvx v3
(955 cm"1) (1042 cm"1)
vx
(1103 cm"1)
10-^m Band System 2v2
See Ref. 340(1988)
(1399 cm"1)
Vi + VyV2
(1410 cm"1)
0.1413 x 10"16 cm'Vmolecule cm"2 at 296K See also Ref. 341(1985) 0.5403 x 10"18 cm'Vmolecule cm"2 at 296K See also Ref. 341(1985)
345.7
13.22
159(1987)
159(1987)
See Ref. 161(1990) 5.43 x 10"22 cm'Vmolecule cm"2 at 296K
0.0133
162(1989)
1.01 x 10"21 cm'Vmolecule cm"2 at 296K
0.0247
162(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
193
TABLE II (34) BAND
REFERENCE VALUE 16
cm"2atm-1 at 300K
REFERENCE
0 3 (continued)
2v2 + VyV2
(1707 cm'1)
3.45 x 10'21 cm-1/molecule cm"2 at 296K
0.0844
368(1990)
v2+v3
(1727 cm"1)
0.536 X 10"19 cm'Vmolecule cm -2 at 296K
1.31
270(1987)
ίΊ+2ϊ>2-ί>2 (1786 cm"1)
1.40 x 10"21 cm-1/molecule cm -2 at 296K
0.0343
368(1990)
(1796 cm"1)
0.237 x 10"19 cm-1/molecule cm'2 at 296K
0.580
270(1987)
0.1120 x 10'18 cm'Vmolecule cm'2 at 296K
2.740
367(1988)
2v3
l + v3
(2058 cm"1)
v
2vx
1
(2111cm" ) (2201 cm -1 )
0.1236 x 10"17 cm'Vmolecule cm"2 at 296K 0.3371 x 10"19 cm"1/molecule cm"2 at 296K
30.24
367(1988)
0.8247
367(1988)
4.8-^m Band System See Ref. 101(1990) 2^2 + ^3
(2408 cm'1)
4.35 x 10"22 cm'Vmolecule cm"2 at 296K
0.0106
368(1990)
ί>1+2ι>2 (2487 cm'1)
4.08 x 10' 22 cm'Vmolecule cm"2 at 296K
9.98 X 10'3
368(1990)
ϊ>2+2ϊ/3
0.336 x 10' 20 cm'Vmolecule cm"2 at 296K
0.0822
393(1990)
0.243 x 10"19 cm'Vmolecule cm"2 at 296K
0.594
393(1990)
0.115 x 10"20 cm'Vmolecule cm"2 at 296K
0.0281
393(1990)
0.131 X 10"18 cm'Vmolecule cm'2 at 296K
3.20
102(1990)
0.311
102(1990)
(2726 cm'1) V\ + Vj + V3
(2785 cm"1)
2i/j4-i^2
1
(2886 cm" )
3v3
VX+2P3
(3046 cm'1)
(3084 cm"1)
0.127
X 1019
cnrVmolecule cm"2 at 296K
194
ψ
SMITH, R I N S L A N D , D E V I , R O T H M A N , R A O
TABLE II (35) BAND
REFERENCE VALUE 16
cm"2atm-1 at300K
REFERENCE
0 3 (continued)
0.934 X 10' 20 cm"1/molecule cm"2 at 296K
0.228
102(1990)
ι>2+3ϊ>3
0.615 x 10"20 cm'1/molecule cm"2 at 296K
0.150
273(1990)
I>1 + J>2+2»'3
0.138 x 10"21 cm"1/molecule cm"2 at 296K
3.38 x 10"3
273(1990)
(3186 cm"1) (3698 cm"1) (3738 cm"1)
See also Ref. 163(1990) 16Q16Q180
p2
(685 cm"1)
0.649 x 1 0 1 8 cm'Vmolecule cm"2 at 296K
15.9
160(1989)
v3
(1028 cm"1)
0.128 x 10"16 cm'Vmolecule cm"2 at 296K See also Ref. 364(1985)
313.1
100(1986)
νλ
(1090 cm"1)
*0.612 x 10"18 cm'Vmolecule cm"2 at 296K b 0.512 x 10"18 cm"1/molecule cm'2 at 296K
15.0
100(1986)
12.5
100(1986)
15.8
160(1989)
See also Ref. 163(1990) a
^Band ( ^
b
text
f° r definition) for Λ-type transitions only.
5 B a n d (see text for definition) for B-type transitions only. 16 0 18 0 16 0 (693 cm 1 )
0.645 x 10"18 cm"1/molecule cm'2 at 296K
(1008 cm"1)
0.133 x 10"16 cm'Vmolecule cm"2 at 296K See also Ref. 364(1985)
325.
157(1986)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
T
195
TABLE II (36) BAND
REFERENCE VALUE
at300K
REFERENCE
I 6 0 i 8 0 i 6 0 (continued) νγ
(1074 cm"1)
0.241 X 10"18 cm'Vmolecule cm"2 at 296K
5.90
157(1986)
See also Ref. 163(1990) 16Q18Q18Q
v2 a
(678 cm"1)
°0.600 x 10"18 cm"1/molecule cm"2 at 296K
14.7
336(1990)
14.7
336(1990)
14.5
336(1990)
29. 29.5
57(1986) 50(1990)
5 B a n d (see text for definition) for B-type transitions only. 18 16 18
o o o
v2
(668 cm"1)
0.602 x 10"18 2
cm'Vmolecule cm' at 296K v3
(1019 cm"1) 1
vx
(1072 cm" )
v2
(661 cm"1)
See Ref. 158(1987) See Ref. 158(1987)
0.593 x 10"18 1
2
cm" /molecule cm' at 296K v2
(985 cm"1)
See Ref. 158(1987)
vx
(1042 cm"1)
See Ref. 158(1987) 16012C32S
vx 2v2° 3v2l-v2
(859 cm"1) (1047 cm"1)
(1053 cm"1)
29.63 ± 1.48 cm^atm"1 at 298K 29.69 ± 0.15 cm^atm"1 at 298K See Ref. 143(1988) See Ref. 143(1988)
196
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (37) BAND
cm^atm"1 at 300K
REFERENCE VALUE
REFERENCE
16012C32S ( c o n t i n u e d )
P3 P2+P3
(2062 cm"1) 1
See Ref. 295(1987) 0.1474 + 0.0090 cm^atm"1 at 295K
0.1449
137(1986)
(2575 cm' ) 16 0 13 C 32 S
vx
(859 cm'1)
29.21 ± 0.16 cm^atm"1 at 298K
29.0
50(1990)
28.8
50(1990)
29.5
50(1990)
102.9
230(1984)
16012C33S
px
(859 cm"1)
28.98 ± 0.37 cm^alm'1 at 298K 16 0 12 C 34 S
px
(859 cm'1)
29.68 ± 0.16 cm^atm"1 at 298K S0 2
P2
(518 cm'1)
25.33 ± 0.04 km/mol
vx
(1151 cm"1)
20.60 ± 0.07 km/mol See also Ref. 13(1989)
v3
(1362 cm"1)
192.13 ± 0.14 km/mol
83.68
230(1984)
780.5
230(1984)
611.
444(1989)
CF3 P3
(1264 cm'1)
See Refs. 75(1987) and 76(1988) CH3
p2
(606 cm"1)
2.5 ± 0.8 X 10"17 cm"1 (molecule/cm2)"1 C
(P4+P5)°-P41 (729 cm'1) P5
(729 cm'1)
2H2
13.7 ± 0.3 cm^atm"1 at 296K 581 ± 10 cm^atm"1 at 296K
13.5 573.
439(1989) 439(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
197
TABLE II (38) BAND
REFERENCE VALUE
cm^atm"1 at 300K
REFERENCE
C 2 H 2 (continued) ("4+"5)° (1328 cm"1) (3282 cm"1) i>3
(3295 cm"1)
(2v2+vA+v5f
See Ref. 391(1988) See Ref. 391(1988) See Ref. 391(1988)
(5230 cm"1)
See Ref. 391(1988)
(5260 cm'1)
See Ref. 391(1988)
1 2vyv5l (5772 cm' ) (5783 cm"1)
2vr"5
64.4 + 2.0 cm^atm"1 at 296K
See Ref. 391(1988)
. (5979 cm"1)
See Ref. 391(1988)
vx + v3+2v£ (7733 cm"1)
See Ref. 309(1989)
{Vl+v3+2vA\ (1131 cm"1)
See Ref. 309(1989)
3P3
(9640 cm'1)
See Ref. 391(1988)
v\ +
v2+v3+2v® (9668 cm"1)
See Ref. 391(1988)
2ΪΊ+Ϊ>3
(9835 cm'1)
See Ref. 391(1988)
V\+2v2+v3+2v£ (11571cm- 1 )
See Ref. 323(1988)
vx+3v2+?>vAx + vcl (11586 cm'1)
See Ref. 323(1988)
64.
347(1984)
198
v
SMITH, R I N S L A N D , D E V I , R O T H M A N , R A O
TABLE II (39) cm-2atm_1 at300K
REFERENCE
3.7 ( ± 20%) cm/mol 7.2 cm/mol
1.5 x 10"4 2.9 x 10"4
252(1989) 252(1989)
38 ± 1 cm/mol
1.5 x 10"3
252(1989)
0.95 cm/mol
3.9 x 10"5
252(1989)
0.52 cm/mol
2.1 x 10"5
252(1989)
(17519 cm"1)
3.0 cm/mol See also Ref. 406(1988)
1.2 x 10"4
252(1989)
(18430 cm-1)
4.8 + 0.4 cm/mol
2.0 X 10"4
252(1989)
REFERENCE VALUE
BAND
C 2 H 2 (continued) J>2+3i>3
See Ref. 323(1988)
2ρ 1 + ί>2+ί'3
See Ref. 323(1988)
(11600 cm-1) (11783 cm-1)
!/ 2 +4i> 3 u
(14597 cm"1) (14617 cm'1)
5v3u (15600 cm-1) (15948 cm"1) 5P3U+V41
1
(16137 cm" ) i/ 2 +5i>3 U
6P3U
C2N2 vs
(226 cm-1)
36.28 ± 0.32 km/mol
v3
(2149 cm"1)
4.55 ± 0.04 km/mol
147.
229(1983)
18.5
229(1983)
36.
369(1986)
21. 20.
135(1988) 357(1989)
COF2 v6
(774 cm'1)
vx
(1942 cm"1)
a
1.47 ± 0.22 x 10"18 cm molecule"1 See also Ref. 183(1990) See Ref. 369(1986)
integrated intensity of the Q branch. H2CO vA
(1167 cm-1)
20.9 ± 1.3 cm^atm"1 at 297K 4.82 ± 0.10 km/mol See also Ref. 312(1987)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS T
199
T A B L E II (40)
BAND
REFERENCE VALUE
at 300K
REFERENCE
H2CO (continued) (1249 cm"1)
P6
'4 1 (1500 cm"1)
P3
38.0 ± 1.9 cm^atm·1 at 297K 8.20 ± 0.24 km/mol See also Ref. 312(1987)
38. 33.
135(1988) 357(1989)
13.02 ± 0.26 km/mol
52.9
357(1989)
11.59 ± 0.31 km/mol
47.1
357(1989)
H202 APX (13366 cm"1) * 4P5 (13366 cm" 1 )/
See Ref. 147(1989) trans-HONO
(1263 cm"1)
P3
See Ref. 264(1988) 14
NH 3
s
2,2 -,2< 2P2*-P2S
P2S A
P2
P4
(629 cm"1) (950 cm"1) (932 cm'1)> l (968 cm'1) /
(1627 cm"1)
See Refs. 85(1983), 203(1986), 39(1987), and 386(1988) 567.6 ± 9.4 a t m - W 2 STP See also Refs. 239(1981), 313(1985), 44(1986), 95(1986), 203(1986), and 39(1987)
517.
227(1985)
110.5 ± 2.0 a t n r W 2 STP
101.
227(1985)
See also Ref. 253(1987) 2v2* (1882 cm"1) ργ P3
(3337 cm"1) * (3444 cm"1) /
5P{ 6PX
See Ref. 253(1987) 43.9 ± 0.6 a t n r W 2 STP
39.9
227(1985)
(15504 cm"1)
0.66 cm^nWamagar1 See also Ref. 178(1969)
60.
180(1975)
(18116 cm'1)
See Ref. 178(1969)
200
v
SMITH, R I N S L A N D , D E V I , R O T H M A N , R A O
TABLE II (41) BAND
REFERENCE VALUE 15
2P2S-P2& a
(629 cm"1) (
NH 3
See Refs. 203(1986) and 377(1986)
(950 cm"1) )
P2S p2a
(928 cm'1) \ (963 cm'1) /
See Ref. 203(1986)
P4
(1622 cm"1)
145.8 ± 7.6 cm^atm"1 at 300K 14
P2*
p2a p2s
pf p2s
REFERENCE
S
2"2 -"2
P2S
cm^atm"1 at 300K
(928 cm"1) i (963 cm"1) /
(746 cm"1) \ (749 cm"1) i
(740 cm"1) i (743 cm"1) /
146.
272(1990)
ND 2 H
See Ref. 223(1988) 14
ND 3
15
ND 3
See Ref. 239(1981)
See Ref. 239(1981) N03
p2
(762 cm"1)
1.1 ± 0.8 x 10"18 cm molecule-1
27.
172(1987)
p3
(1492 cm'1)
6.0 ± 4.0 x 10' 18 cm molecule"1
147.
172(1987)
PH3 2P2*
(1984
P2+P4
I (2110 cm"1) ( (2236 cm"1) ( (2323 cm"1) ) (2328 cm' 1 )/
2ΡΛ px p3
cmM
See Refs. 30(1980) and 260(1985)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
201
TABLE II (42) BAND
cm^atm'1 at300K
REFERENCE
1974.
422(1988)
1936.
422(1988)
867. 900.
294(1985) 449(1987)
3418.
422(1988)
1470. 1505. 1718. 1718.
294(1985) 449(1987) 423(1988) 422(1988)
590. 671. 671.
294(1985) 423(1988) 422(1988)
300 ± 50 cm^atm'1 at STP
273.
319(1986)
1278 ± 63 cm^atm'1 at STP 292 cm^atm"1 at 296K b 292 cm^atm"1 at 296K c 8.70 x 10' 18 cm molecule'1 1421 ± 12 cm^atm'1 at 300K 1421 ± 12 cm^atm'1 at 300K
1164. 288. 288. 213. 1421. 1421.
319(1986) 437(1986) 438(1987) 449(1987) 423(1988) 422(1988)
REFERENCE VALUE CBrF3
7 ?
(1085 cm"1) 1
(1209 cm" )
1974 ± 10 cm^atm'1 at 300K 1
1936 ± 18 cnAtm' at 300K CC14
v3
(794 cm'1)
879 cm^atm'1 at 296K 3.68 x 10"17 cm molecule"1 See also Ref. 155(1990)
CF4 2vA v3
(1261 cm'1) χ (1283 cm"1) /
3418 ± 179 cm^atm'1 at 300K See also Ref. 294(1985) CFCU
vA
(846 cm"1)
vx
(1085 cm"1)
1490 6.15 1718 1718
cm^atm'1 at 296K x 10~17 cm molecule'1 ± 17 cm^atm'1 at 300K ± 17 cm^atm'1 at 300K
598 cm^atm'1 at 296K 671 ± 8 cm^atm'1 at 300K 671 ± 8 cm^atm'1 at 300K See also Ref. 155(1990) CF2C12 a
ί>3 + ϊ>9 1
(889 cm' ) a
ve
(923 cm'1)
b
202
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (43) BAND
cm"zatm"J at300K
REFERENCE
1520 cm^atnT1 at 296K 1646 ± 80 cm^atm"1 at STP a 1602 ± 108 cm^atnr1 at STP
1500. 1499. 1459.
294(1985) 319(1986) 319(1986)
REFERENCE VALUE CF2C12 (continued) d
vx
(1102 cm"1)
1129 ± llcm^atm^atSOOK 1129 ± 1 1 cm^atnT1 at 300K
1129. 1129.
423(1988) 422(1988)
v%
(1161cm"1)
5.85 x 10 -18 cm molecule-1 717 ± 14 cm^atm"1 at 300K 717 ± 14 cm^atm'1 at 300K
143. 717.
111.
449(1987) 423(1988) 422(1988)
1747. 1973. 1920.
294(1985) 319(1986) 319(1986)
1770 cm-2atm_1 at 296K 2167 ± 103 cm^atnr1 at STP a 2109 ± 84 cm^atm"1 at STP d
See also Ref. 155(1990) a
Derived from measurements at 200K.
b
CF 2 35 Cl 2 isotope only.
integrated intensity of the Q branches. d
Derived from measurements at 296K. CF3C1
vx
(1109 cm"1)
1820 ± 7 c n r W 1 at 300K
1820.
422(1988)
vA
(1212 cm'1)
2162 ± 9 cm^atm"1 at 300K
2162.
422(1988)
vA
(1306 cm"1)
133. 127.
228(1987) 78(1989)
v2
(1534 cm"1)
'41 p2f
146.0 ± 2.4 cm^atm'1 STP 129.05 ± 3.87 cm^atm"1 at 296K See also Refs. 74(1985), 31(1986), and 297(1988)
a
a
1.36 ± 0.04 cm^atm"1 at 296K
a
130.41 ± 3.91 cm^atm"1 at 296K
1.34 129.
78(1989) 78(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS ψ
203
TABLE II (44) BAND
REFERENCE VALUE 12
REFERENCE
CH 4 (continued)
0.050 ± 0.002 cm^atm"1 at 296K
"3-"4
at300K
0.049
204(1985)
(1720 cm"1)
p3
(3019 cm"1)
298.1 ± 1.0cm_2atm_1 STP See also Refs. 74(1985), 19(1985), and 10(1989)
3v4
(3868 cm"1)
b
0.85 ± 0.02 cm^atm"1 STP
0.77
175(1986)
3v4
(3868 cm"1) c
1.42cm- 2 atm- 1 at 297K
1.41
77(1988)
ϊ>2+2ί/4
(4125 cm'1)
V\+V4
"l+"4
271.
228(1987)
(4220 cm'1) See Ref. 74(1985) (4220 cm-1)
1*2+2^4
\
(4125 cm"1) *
v
\ + v4
"3+"4
v2+v2
(4220 cm"1)
22.5 ± 0.2 cm^atm"1 STP
175(1986)
(4544 cm· 1 )/ ( - 5 5 9 0 cm-1) (6005 cm"1)
Unassigned lines (5500-6200 cm"1)
See Ref. 289(1990) 1.641 cm^atm"1 at 296K See Refs. 288(1988) and 289(1990)
a
Sum of line intensities measured from 1080 to 1752 cm-1
integrated intensity measured from 3700 to 3970 cm -1 . c
20.5
(4321 cm"1)
J>3+2I>4
2u3
d
Sum of line intensities measured from 3700 to 4136 cm-1
integrated intensity measured from 3970 to 4900 cm -1 .
1.619
288(1988)
204
v
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (45) BAND
REFERENCE VALUE 13
1/4
(1299 cm"1)
a
v2
(1529 cm'1)
a
a
REFERENCE
CH 4
124.04 ± 4.96 cm^atm"1 at 296K See also Ref. 425(1989) 1.18 ± 0.05 cm^atm"1 at 296K
a
"4 1 v2\
at300K
125.22 ± 5.01 embalm'1 at 296K
122. 1.16 124.
78(1989) 78(1989) 78(1989)
Sum of line intensities measured from 1080 to 1752 cm"1. 12
CH3D
"6
(1156 cm"1)
61.7 ± 1.8cm- 2 atm- 1 at295K 53.2 ± 0.6 cm^atm'1 at 296K See also Refs. 268(1987), 409(1987), and 428(1989)
60.7 52.5
65(1985) 410(1988)
"3
(1307 cm"1)
49.3 + 1.4 cm^atm"1 at 295K 40.1 ± 0.9 cm^atnr1 at 296K See also Refs. 276(1986), 409(1987), and 424(1989)
48.5 39.6
65(1985) 410(1988)
"5
(1471 cm"1)
13.4 ± 0.6 cm^atm"1 at 296K See also Ref. 409(1987)
13.2
410(1988)
"2
(2200 cm'1)
See Ref. 122(1987)
77.3
228(1987)
12
"4
2„4 i>2 +
"4
CD 4
(998 cm"1)
84.9 ± 2.8 cm^atm'1 STP
(1996 cm"1)
31.48 x 10"21 cm/molecule
0.7701
329(1987)
57.33 x 10"21 cm/molecule
1.403
329(1987)
(2089 cm'1)
"l
(2061 cm"1)
0.50 x 10*21 cm/molecule
0.012
329(1987)
2v2
(2181 cm"1)
42.68 x 10 -21 cm/molecule
1.044
329(1987)
"3
(2249 cm'1)
133.1 ± S.Scm^atm-1 STP 4891.18 x 10"21 cm/molecule
121. 119.658
228(1987) 329(1987)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
205
TABLE II (46) REFERENCE VALUE
BAND
12
2vA v2+vA , "1
Pentad
cm'^atnv at300K
REFERENCE
CD 4 (continued)
5023.17 x 10' 2 1 cm/molecule
122.887
329(1987)
17.9
231(1984)
"3
CHCl·, v2
(678 cm"1)
4 . 4 0 ± 0.03 km mol"1
v5
(773 cm"1)
218.7 ± 2.5 km mol"1
1
-1
888.
231(1984)
123.
231(1984)
vA
(1219 cm' )
30.2 ± 1.0 km mol
vx
(3034 cm' 1 )
a
2160 fm 2
1.60
258(1986)
2νγ
(5941 cm' 1 )
^ 3 1 0 fm 2
7.72
258(1986)
3^
(8727 cm' 1 )
a
145 fm 2
0.310
258(1986)
4*!
(11385 cm- 1 )
a
4 . 6 fm 2
0.013
258(1986)
a
Value given is for G (see text or Ref. 258 for definition). Units are actually fm 2 molecule" 1 . CDC1 3
v2
(659 cm"1)
4.90 + 0.03 km mol"1
19.9
231(1984)
ps
(745 cm' 1 )
145.9 ± 0.7 km mol"1
592.7
231(1984)
v4
(913 cm' 1 )
100.0 ± 1.4 km mol"1
406.
231(1984)
px
(2266 cm"1)
2vx
(~ 4400 cm"1)
a
2260 fm2
-2.4
258(1986)
3^
( - 6 5 0 0 cm-1)
^ 0 fm2
-0.08
258(1986)
a
-0.003
258(1986)
Avx ( - 8 6 0 0 cm"1) a
a
335 fm 2
1 . 2 fm 2
0.186
258(1986)
Value given is for G (see text or Ref. 258 for definition). Units are actually fm 2 molecule" 1 .
206
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (47) BAND
REFERENCE VALUE
cm^atm"1 at300K
REFERENCE
CH335C1 (732 cm"1)
"3
90.7 ± 1.3 cm^atnT1 at 296K
89.
133(1988)
88.
49(1989)
CH337C1 (727 cm"1)
"3
89.16 ± 1.43 cm^atm-1 at 296K CHC12F
v%
(807 cm'1)
679 cm^atm"1 at 296K
670.
294(1985)
v3
(1079 cm"1)
625 cm^atm"1 at 296K
617.
294(1985)
1
2PX
(5927 cm" ) Band system
a
3νγ
( - 8 7 0 0 cm-1) Band system
a
2
2.8 x 10° pm
1.5 x 10"4 pm2
4.1
9(1984)
0.32
9(1984)
0.016
9(1984)
(9791 cm"1) , (9904 cm'1) I
See Ref. 148(1984)
3V1-\-P2
(9975 cm"1) y Band System
4vx a
( - 1 1 4 0 0 cm-1) *5.6 x KT6 pm2 Band system
Value given is for G (see text or Ref. 9 for definition). Units are actually pm2 molecule"1. CHC1F2
2v2
(829 cm'1)
a
3.60 x 10"19 cm molecule"1 3.33 x 10"19 cm molecule'1
νΊ 2v2
(809 cm"1) χ (829 cm"1) /
550 ± 2 cm^atm'1 at 300K
a
v3
(1116 cm'1)
1768 ± 23 cm^atm'1 at 300K See also Ref. 262(1989)
v%
(1128 cm"1)
See Ref. 262(1989)
8.81 8.15
449(1987) 363(1989)
550.
422(1988)
1768.
422(1988)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
207
TABLE II (48) BAND
REFERENCE VALUE
at300K
REFERENCE
CHC1F2 (continued) vx
(3023 cm"1) Band system
b
5.6 x 10"2 pm2
2vx
(5927 cm"1) Band system
b
1.3 X 10"3 pm2
1.9
9(1984)
3vx
( - 8 7 0 0 cm"1) Band system
M.lxlO^pm2
0.23
9(1984)
4vx
(~ 11400 cm'1) Band system
0.016
9(1984)
b
41.
5.6 x 10"6 pm2
9(1984)
See also Ref. 155(1990) integrated intensity of the Q branch. b
Value given is for G (see text or Ref. 9 for definition). Units are actually pm2 molecule'1. CHD2F
vx
(2976 cm"1)
«0.193 pm2
2vx
(5835 cm"1)
«0.57 x 10"3 pm2
0.81
236(1988)
3vx
(8582 cm"1)
«0.11 x 10"3 pm2
0.23
236(1988)
4vx
(11240 cm"1)
^ . 8 0 x 10"5 pm2
0.022
236(1988)
a
141.
236(1988)
Value given is for G (see text or Ref. 236 for definition). Units are actually pm2 molecule-1. CHF.
2i/4
(2710 cm"1)
a
(0.0063 ± 0.002) pm2
vx
(3036 cm'1)
a
(0.132 ± 0.02) pm2
2vA\ vx )
b
1.33 x 10"1 pm2
a
(1.3 ± 0.3) X Hrv4 T pnm m2z
Band system
vx+2v4 (5710 cm"1)
4.
149(1984)
98.0
149(1984)
98.8
9(1984)
0.18
149(1984)
208
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (49) BAND
REFERENCE VALUE
cm"^atm"J at300K
REFERENCE
CHF3 (continued) 2vx
(5959 cm"1)
a
(2 ± 0.4) x 10"4 pm2
0.29
149(1984)
1
4vA
(5337 cm" )
2vx
(5710 cm"1) | (5959 cm"1) Band system
3^
b
2.4 x 10"4 pm2
0.35
9(1984)
(8793 cm'1)
a
(3 ± 1) x 10"5 pm2
0.06
149(1984)
3J>! Band system
b
4.4 X 10 -5 pm2
0.095
9(1984)
3ίΊ+2ϊ>4 (11347 cm"1)
a
(2.4 ± 1) x 10-6 pm2
0.007
149(1984)
(11563 cm-1) Band system
b
0.010
9(1984)
4^ a
3.6 x IQ"6 pm2
Value given is for G (see text or Ref. 149 for definition). Units are actually pm2 molecule-1.
b
Value given is for G derived from data of Ref. 149. Units are actually pm2 molecule"1. These values are also quoted in Ref. 258. CDF3 vx
(2268 cm" )
a
2vx
( - 4 4 0 0 cm"1)
a
3^
( - 6 5 0 0 cm"1)
4i/x
( - 8 6 0 0 cm"1)
a
1
2
86.6
258(1986)
l l l fm2
-0.12
258(1986)
a
13 fm2
-0.021
258(1986)
a
< 2 fm2
<0.004
258(1986)
156000 fm
Value given is for G (see text or Ref. 258 for definition). Units are actually fm2 molecule-1
2*2
(2486 cm"1)
See Ref. 246(1989)
3P6
(2644 cm"1)
See Ref. 246(1989)
r2+v3+v6 (2655 cm"1)
See Ref. 246(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
T
209
TABLE II (50) BAND
REFERENCE VALUE
cm_2atm_1 at300K
REFERENCE
CH3I (continued) "2 +"5
See Ref. 246(1989) (2682 cm"1) CH3N
p7
(1058 cm"1)
See Ref. 191(1986)
v9
(1061 cm"1)
See Ref. 191(1986)
1
i/8
(1127 cm" )
See Ref. 191(1986) C1NO.
"5
H
"3 VA
(560 cm"1)
a
1.16 ± 1.1 x 10"17 cm molecule 1
(780 cm"1)
b
3.93 ± 0.20 x 10"19 cm molecule 1 See also Refs. 32(1988) and 361(1985)
9.6
139(1987)
(809 cm"1)
b
5.1
139(1987)
2.09 ± 0.10 x 10"19 cm molecule'1
v2
(1292 cm"1)
vx
(1735 cm"1)
139(1987)
368 cm^atm"1 at 296K 2.85 ± 0.15 x 10"17 cm molecule"1 c 3.04 -0.21 +0.30 X 10"17 cm molecule"1
363. 697. 744.
294(1985) 139(1987) 32(1988)
699 cm^atm"1 at 296K 1.56 ± 0.078 x 10"18 cm molecule"1 a 3.47 ± 0.55 x 10"17 cm molecule"1 c 3.59 -0.25 +0.36 x 10"17 cm molecule"1 See also Refs. 17(1986) and 16(1987)
690. 38.2 849. 878.
294(1985) 139(1987) 139(1987) 32(1988)
a
)
284.
b
*5.09 + 0.55 x 10"17 cm molecule"1 c 5.68 -0.4 +0.6 x 10"17
1245. 1390.
139(1987) 32(1988)
integrated band intensity at 296K. Values at 223K are also reported. integrated intensity of the Q branch at 296K. Integrated Q branch values at 213K are also reported. integrated band intensity at 296K. Values at 213K are also reported.
210
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE II (51) BAND
REFERENCE VALUE
at300K
REFERENCE
595. 1116. 1252. 1148.
93(1985) 380(1985) 420(1987) 420(1987)
GeR. v3
(2114 cm"1)
*654 ± 100 cm^atm"1 b 1226 ± 172 cm^amagaf1 c 1278 ± 38 cm^atm"1 at 294K d 1171 cm^atm"1 at 294K
Combined intensity for all five Ge isotopes in natural telluric abundance (0.208 70 Ge + 0.277 72 Ge + 0.077 73 Ge + 0.346 74 Ge + 0.077 75 Ge). Temperature of the measurement is not explicitly stated, but quotations of values from previous studies indicate that the reference temperature assumed is 273K. b
From measurements of 74 GeH 4 lines only.
c
Combined intensity for all five Ge isotopes in natural telluric abundance.
d
From measurements of 72 GeH 4 lines only. 70
"6 "3 "5
(710 cm"1) (822 cm"1) (899 cm"1)
GeH 3 D
See Ref. 87(1986) HN0 3
"7
(580 cm"1)
39 ± 8 cm^amagaf1
35.
265(1989)
"6
(647 cm"1)
50 ± 5 cm^amagat"1 See also Ref. 265(1989)
46.
181(1984)
"8
(763 cm'1)
45 ± 4 cm^amagat"1 See also Ref. 265(1989)
41.
181(1984)
"5
(879 cm"1) \ (897 cm'1) l
692 ± 35 cm-2amagaf1 490 cm-2atm-1 at 296K 1.36 x 10' 17 cm molecule"1 2.21 ± 0.2 x 10"17 cm molecule-1 a 202 ± 40 cm^atm"1 at 296K
630. 483. 333. 541. 200.
181(1984) 294(1985) 104(1986) 206(1987) 35(1988)
40.
181(1984)
7v9
"8 + "9 (1204 cm"1)
44 ± 4 cm^amagat"1
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
211
TABLE II (52) BAND
REFERENCE VALUE
cm"zatm"J at300K
REFERENCE
HN0 3 (continued) P4
(1303 cm"1)
b
305.6 cm^atm"1 at 296K
301.5
335(1989)
P3
(1326 cm"1)
b
605.0 cm^atm-1 at 296K
596.9
335(1989)
P3!
P2
(1710 cm"1)
1383 ± 70 cm^amagaf1 924 cm^atm"1 at 296K 2.81 x 10"17 cm molecule-1 4.29 ± 0.6 x 10"17 cm molecule"1 c 1187 cm^atnT1 at 296K (±20%) See also Refs. 299(1987) and 300(1989)
1259. 912. 687. 1050. 1171.
181(1984) 294(1985) 104(1986) 206(1987) 335(1989)
1530 ± 100 cm^amagaf1 See also Refs. 235(1987), 302(1987), and 264(1988)
1392.
181(1984)
"Intensity of v5 band only. b
5 v (see text for definition).
c
5 B a n d (see text for definition) including contribution from hot bands. SiF 4
P3
(1031 cm"1)
See Ref. 330(1982) SiH3D
P6 P3
p5
(784 cm"1) (913 cm"1) (951 cm"1)
See Ref. 87(1986)
212
ψ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE III.
BIBLIOGRAPHY FOR BAND INTENSITIES OF MOLECULES WITH SIX OR MORE ATOMS
MOLECULE
REFERENCE
Acetaldehyde (CH3CHO)
372(1985), 104(1986)
Allene (C3H^
138(1986)
Benzene (C6H6)
355(1982), 134(1989)
Benzene-d5 (C6H5D)
355(1982)
Benzene-d6 (C 6 D 6 )
355(1982)
Chlorofluorocarbon 113 (C2C13F3)
294(1985), 373(1988), 422(1988), 155(1990)
Chlorofluorocarbon 114 (C2C12F4)
294(1985), 373(1988), 422(1988), 155(1990)
Chlorofluorocarbon 115 (C2C1F5)
155(1990)
Dinitrogen Pentoxide (N 2 0 5 )
108(1985), 294(1985), 331(1985), 104(1986), 97(1987), 206(1987), 98(1988), 105(1988), 106(1988), 107(1988)
Ethane (C2H6)
125(1985), 362(1986), 136(1987)
Fluorobenzene (C6H5F)
355(1982)
Heptafluoropropane (C3F7H)
9(1984), 148(1984)
Hexafluoroethane (C2F6)
422(1988)
Hydrochlorofluorocarbon 123 (C2HC12F3)
155(1990)
Hydrochlorofluorocarbon 124 (C2HC1F4)
155(1990)
Hydrochlorofluorocarbon 141b (C2H3C12F)
155(1990)
Hydrochlorofluorocarbon 142b (C2H3C1F2)
155(1990)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
213
TABLE III (continued) MOLECULE
REFERENCE
Hydrofluorocarbon 125 (C2HF5)
9(1984), 155(1990)
Hydrofluorocarbon 134a (C 2 H 2 F 4 )
155(1990)
Hydrofluorocarbon 143a (C2H3F3)
155(1990)
Hydrofluorocarbon 152a (C2H4F2)
155(1990)
Methylhydroperoxide (CH 4 0 2 )
38(1989)
Methyl chloroform (C2H3C13)
155(1990)
Neptunium Hexafluoride (NpF6)
338(1986)
Pentafluorobenzene (C6HF5)
355(1982)
Peroxynitric acid (HN0 4 )
294(1985), 298(1988)
Plutonium Hexafluoride (PuF6)
232(1984), 338(1986)
Propyne (C3H4)
43(1990)
Sulfur Hexafluoride (SF6)
166(1976), 3(1978), 412(1989)
Tellurium Hexafluoride (TeF6)
303(1986)
Toluene (C7H8)
355(1982)
Tristrifluoromethylmethane (C4HF9)
9(1984), 22(1985)
Uranium Hexafluoride (UF6)
243(1980), 233(1981), 232(1984)
214
ψ
SMITH, R I N S L A N D , D E V I , R O T H M A N , R A O TABLE IV.
BIBLIOGRAPHY FOR COLLISION-BROADENING MEASUREMENTS
Molecule
Page
CO ClO HBr
215 215 215 215 215 216 216 216 216 216 216 218 218 218 219 219 221 221 221 222 222 222 222 223 223 223 224 224 224 225 225 225 226 227 227 227 227 228 228 228 228
H35C1 H37C1
HF H2 D2 N2 NO
12 16
c o2 c o2
13 16
12C160180
12 18
c o2
HCN
H2160
HDO D20 HTO H2180
N20 N0 2 03
ocs so2 2
2
H2CO H202 14 NH 3 15 NH 3
PH3 CF2C12 12 CH 4 13 CH 4 12 CH 3 D GeH4 HN0 3 SiF 4 Ethane (C2H6) Sulfur Hexafluoride ( 32 SF 6 ) Uranium Hexafluoride (UF6)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
215
TABLE IV (2) BAND
BROADENING GAS
REFERENCE
CO 1-0
1
(2143 cm· )
Ar He Ne CO H2 N2
196(1986) 83(1984), 36(1984) 83(1984) 36(1984), 83(1984) 83(1984), 248(1986), 433(1987) 83(1984), 196(1986), 248(1986), 433(1987) 261(1984), 397(1988) 261(1984), 442(1984), 196(1986), 396(1987)
C02 H20 2-0
(4260 cm·1)
He CO
36(1984) 55(1984), 36(1984)
3-0
(6350 cm"1)
CO
36(1984)
ClO 1-0
1
(844 cm' )
N2
88(1989)
HBr 1-0
(2559 cm"1)
HBr C02
382(1985) 382(1985) H35C1
1-0
(2886 cm'1)
Ar He Kr Ne Xe HC1 N2 Air (N 2 + 0 2 )
440(1984), 350(1987) 440(1984) 440(1984) 440(1984) 440(1984) 111(1985), 343(1985) 34(1985), 345(1987), 112(1990) 345(1987)
3-0
(8347 cm"1)
Air (N 2 + 0 2 )
398(1988) H37C1
1-0
(2884 cm"1)
HC1
111(1985), 343(1985)
216
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE IV (3) BAND
BROADENING GAS
REFERENCE
HF 1-0
(3962 cm"1)
HF N2 Air (N 2 + 0 2 )
343(1985) 345(1987) 345(1987) H2
1-0
(4161 cm"1)
He
60(1990) 165(1966), 68(1968), 80(1971), 60(1990)
2-0
(8087 cm'1)
H2
307(1987) D2
1-0
(2994 cm'1)
D2
68(1968) N2
1-0
(2325 cm"1)
N2
356(1986) NO
1-0
(1876 cm"1)
N2 NO
339(1986), 316(1987), 33(1988) 33(1988)
2-0
(3724 cm'1)
N2 NO
346(1985) 346(1985)
5-0
(9100 cm"1)
NO
251(1988) 12 r 16 1 0(
c o2
01101-00001 (667 cm"1) Band system
co9
222(1990)
10001-01101 (721 cm"1)
co9
214(1988), 215(1989)
11101-10002 (791 cm"1)
N2
131(1989) 131(1989) 2(1986), 131(1989)
o2 co 2
INTENSITIES AND COLLISION-BROADENING PARAMETERS ψ
217
TABLE IV (4) BAND
BROADENING GAS 12
00011-10001 (961 cm"1)
REFERENCE
16
C 0 2 (continued)
He He + C0 2 + N2 + Xe N2
o2
311(1974) 182(1988) 311(1974) 14(1986), 15(1987) 311(1974), 2(1986), 371(1986), 15(1987), 186(1987), 328(1987), 370(1989)
00011-10002 (1064 cm"1)
co9
311(1974), 2(1986), 186(1987)
11102-00001 (1932 cm"1)
Ar He Ne Xe C0 2
145(1986) 145(1986) 145(1986) 145(1986) 401(1986)
11101-00001 (2077 cm"1)
Ar Xe N2 C0 2
145(1986) 145(1986) 177(1987) 177(1987)
00011-00001 (2349 cm"1)
Ar He Ne Xe H2 D2 N9
ΗΛΟ
83(1984), 146(1985) 83(1984), 146(1985) 83(1984), 146(1985) 146(1985) 83(1984), 146(1985) 146(1985) 83(1984), 103(1985), 126(1985), 146(1985) , 127(1986), 128(1986), 255(1986) , 197(1988), 291(1988), 374(1988) 375(1988), 337(1989), 381(1989) 103(1985) , 126(1985), 128(1986), 291(1988) 36(1984), 103(1985), 247(1985), 127(1986) , 128(1986), 255(1986), 291(1988) , 195(1989), 381(1989) 255(1986) , 374(1988)
N2 CO.
23(1987) 308(1987)
CO?
O,
co?
00011-00001 Band System
218
ψ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE IV (5) BAND
BROADENING GAS
REFERENCE
12
c1 6 0 2 (continued)
10011-10002 (2429 cm"1)
C0 2
200(1986) 177(1988)
10011-00001 (3715 cm"1)
N2 02
co 2
255(1986), 291(1988) 291(1988) 255(1986), 291(1988)
31103-00001 (4591 cm"1)
co2
1(1984)
20012-00001 (4978 cm"1)
co2
404(1990)
01121-00001 (5315 cm'1)
He N2
408(1987) 408(1987)
00031-00001 (6973 cm"1)
He N2 C0 2
185(1985), 81(1989) 185(1985), 81(1989) 81(1989) 13 16
c o2
00011-10001 (913 cm"1)
He + C0 2 + N2 + Xe
182(1988)
20012-00001 (4887 cm'1)
C0 2
53(1985) 12C160180
10002-00001 (1259 cm"1)
C0 2
2(1986)
01121-01101 (4614 cm"1)
co2
1(1984)
00021-00001 (4640 cm1)
co2
1(1984) 12
00011-10001 (967 cm"1)
C 18 0 2
He + C0 2 + N2 + Xe
182(1988)
INTENSITIES AND COLLISION-BROADENING PARAMETERS T
TABLE IV (6) BAND
BROADENING GAS
REFERENCE
HCN 1
(3311cm· )
v3
(15452 cm"1) 5i/3
(15552 cm"1)
Ar N2
434(1984) 434(1984)
HCN
390(1986)
HCN
390(1986) H 2 16 0
8-14 /xm Region
N2 H20
421(1987), 418(1988) 421(1987), 418(1988)
N2 Air(N2 + 0 2 ) H20
so2
271(1985), 267(1986), 198(1987) 267(1986), 4(1986) 271(1985), 267(1986), 198(1987) 320(1987)
v2
(1595 cm"1)
vx p3
1
(3657 cm" ) \ (3756 cm"1) / Band System
H20
256(1986)
2vx
(7201 cm'1)
H20
67(1987)
vx+v2 (7250 cm-1)
Air (N2 + O2) H20
67(1987) 67(1987)
(7445 cm'1)
Air (N2 + o2) H20
67(1987) 67(1987)
N,
284(1988)
2v3 ΪΊ+3Ϊ>2
3ί/2+^3
2^1+^2
(8274 cm"1)
(8762 cm'1) (8807 cm"1)
^2+2^3
284(1988)
(8374 cm"1)
(9000 cm"1)
N,
284(1988)
N,
284(1988)
N,
284(1988)
219
220
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE IV (7) BAND
BROADENING GAS
REFERENCE
H 2 1 6 0 (continued) N,
282(1989), 286(1989)
(10600 cm'1)
N,
282(1989), 286(1989)
2Ργ+Ϋ2 (10613 cm'1)
N,
282(1989), 286(1989)
P1+2i'3
N,
286(1989)
N^
282(1989), 286(1989)
Ar
188(1989) 286(1989) 188(1989) 187(1989)
(10537 cm'1) 3^
(10869 cm 1 ) 3i>3
(11032 cm"1)
4ί>2+2ι>3 (13500 cm"1)
Air (N 2 + O2)
3ί^+2ί/2 (13642 cm"1)
O,
188(1989)
2j/1+2i'2+i'3 (13653 cm'1)
Ar N2
188(1989) 188(1989), 286(1989) 188(1989) 94(1986), 188(1989) 187(1989)
o2
Air (N 2 + O2) H20 2i/ 1 +2i/ 3 (13828 cm"1)
Ar N2
o2
Air (N 2 + 0 2 ) H20
3*Ί+Ι/ 3
Avx
(13831 cm'1)
(14221 cm"1)
Vj+3^3
(14319 cm"1)
Ar N2
188(1989) 188(1989), 286(1989) 188(1989) 188(1989) 187(1989)
o2
Air (N 2 + Ο2) H20
188(1989) 188(1989), 286(1989) 188(1989) 94(1986), 188(1989) 187(1989)
N2
286(1989)
N2
286(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS T
TABLE IV (8) BAND
BROADENING GAS
REFERENCE
1
H2 O (continued) N,
286(1989)
N,
286(1989)
V1 + l'2+3i'3
N,
286(1989)
2νγ
No
286(1989)
3J>J+ 2ι>2+^3
N.
286(1989)
3»Ί+2Ι>3
No
286(1989)
2I>1+3J>3
N,
286(1989)
4^+1/3
No
286(1989)
No
286(1989)
No
286(1989)
2ΙΊ+Ι>2+2Ι>3
(15345 cm"1) (15348 cm"1) (15833 cm"1)
+2P2+2I>2
(16819 cm 1 ) (16822 cm"1) (16898 cm"1) (16899 cm"1)
3VI+3PJ
(17496 cm 4 ) (19781 cm"1)
4ι/ 1 +2ί/ 3 (19782 cm"1)
HDO "2
(1403 cm"1)
267(1986) 267(1986)
N2 Air (N 2 + O2)
D20 "2
1
(1178 cm" )
275(1986) 275(1986)
N2 Air (N 2 + 0 2 )
ΗΤΟ v2
1
(~ 1300 cm" )
Air (N 2 + 0 2 ) H20
116(1987) 116(1987)
221
222 ψ SMITH, RINSLAND, DEVI, ROTHMAN, RAO TABLE IV (9) BAND
BROADENING GAS
REFERENCE
Έ[ 2 18 o u2
(1588 cm"1)
N2 Air(N 2 + 0 2 ) H20
267(1986) 267(1986) 267(1986)
N20 (1283 cm"1)
N2 02
431(1989) 431(1989)
2
~^vyvi (2210 cm"1)
N2
259(1986)
v3
(2224 cm"1)
He N2 02 N20
83(1984) 83(1984), 201(1985), 259(1986) 201(1985) 290(1985)
p2+v3
(2798 cm-1)
N2 N20
292(1989) 402(1988), 292(1989)
vx
v
N0 2 v3
(1621 cm'1)
Air (N 2 + 0 2 )
301(1990)
03 v3
(1042 cm"1)
N2 Air (N 2 + 0 2 )
392(1988) 392(1988)
vx
(1103 cm"1)
N2 02 Air (N 2 + 0 2 )
392(1988) 392(1988) 392(1988)
INTENsmES A N D COLLISION-BROADENING PARAMETERS ψ
TABLE IV (10) BAND
BROADENING GAS
REFERENCE
ocs (850 cm"1) (859 cm-1)
νγ
2v2°
(1047 cm'1) (1053 cm"1)
u3
(2062 cm-1)
Ar
48(1990)
Ar He Kr N2
61(1988) 56(1989) 47(1990) 310(1985) 63(1987) 61(1988) 57(1986)
o2 co2 ocs
ocs ocs
143(1988) 143(1988)
Ar He H2
73(1986) 73(1986) 73(1986)
S0 2 vx
(1152 cm·1)
13(1989) 13(1989)
Air(N 2 + 0 2 ) S02 C2H2
(729 cm"1)
v5l
("4+"5) 0
(1328 cm'1)
(P2+3P3)
(11600 cm-1)
(2vl + v2+v3) (11783 cm"1)
H2 N2 02
51(1987) 51(1987), 244(1989), 62(1990) 244(1990)
He N2 Air (N 2
347(1984) 347(1984), 266(1985) 266(1985)
+ OJ
2
323(1988)
C2H2
323(1988)
2
223
224
ψ SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE IV (11)
BROADENING GAS
BAND
REFERENCE
H2CO
H2 N2
(1167 cm"1)
"4
+ 02)
312(1987) 312(1987) 312(1987) 312(1987)
Air (N 2 + 0 2 )
312(1987) 312(1987)
o 2 (N Air
H2
(1249 cm'1)
"6
2
H202 (1266 cm 1 )
"6
Air (N 2 + 02) H202 + H20
280(1986) 280(1986) 14
H&-^
(716 cm"1)
H2 N2
Air (N 2 + 0 2 )
co NH2
3
2v{
-*"
2v2*-"2 s
(629 cm'1) (950 cm"1)
1
He H2 N2
Air (N 2 + 0 2 )
C0 2 NH3
*ί "2*
(932 cm"1) \ (968 cm"1),
Ar He H2 N2
Air (N 2 + 0 2 )
C0 2 NH3
NH 3 He26(1990) 26(1990) 26(1990) 26(1990) 26(1990) 25(1989) 26(1990) 26(1990) 39(1987), 386(1988), 26(1990) 26(1990) 26(1990) 85(1983), 86(1985), 203(1986), 39(1987), 25(1989) 39(1987) 44(1986), 26(1990) 26(1990) 44(1986), 39(1987), 26(1990) 26(1990) 26(1990) 82(1978), 28(1985), 86(1985), 44(1986), 203(1986), 39(1987), 124(1988), 25(1989)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
ψ
225
TABLE IV (12) BAND
BROADENING GAS 14
p4
1
(1627 cm" )
REFERENCE
NH 3 (continued)
NH3
72(1987), 71(1988) 70(1985), 72(1987), 71(1988), 114(1990) 253(1987), 114(1990)
He H2
2*2
(1882 cm"1)
H2 NH3
114(1990) 253(1987), 114(1990)
i>3
(3444 cm"1)
He H2 NH3
72(1987) 72(1987) 199(1988)
5*!
(15504 cm"1)
He H2 NH3
225(1986) 224(1985), 225(1986) 178(1969), 180(1975), 225(1986), 296(1987) 293(1970)
NH3 + Air 15
i>2* *> 2 a P4
(928 cm"1) Ϊ (963 cm"1) / (1622 cm"1)
NH 3
NH 3
86(1985), 383(1985)
N2
272(1990) PH3
vx v3
(2323 cm"1) \ (2328 cm"1) i
H2
260(1985) CF2C12
(923 cm"1)
Air (N 2 + O^ CF2C12
237(1990) 237(1990)
226
ψ SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE IV (13) BAND
BROADENING GAS
REFERENCE
^CH4 j>4
(1306 cm -1 )
Ar He H2 N2
oAir2 (N
+
o2)
Air (N 2 +
o2)
2
CH4 P2
P3
(1534 cm"1) (3019 cm"1)
N2
Ar He Kr Ne Xe N2
Air (N 2 +
co CH2
4
o2)
366(1989), 430(1989) 430(1989) 430(1989) 74(1985), 277(1985), 365(1988), 427(1989), 430(1989) 427(1989) 277(1985), 365(1988), 427(1989) 31(1986) 365(1988) 365(1988) 184(1968), 10(1989) 184(1968), 11(1976), 10(1989) 184(1968), 10(1989) 184(1968) 184(1968), 11(1976), 10(1989) 74(1985) 11(1976), 10(1989) 11(1976), 10(1989) 263(1969), 11(1976), 19(1985), 10(1989)
N2
74(1985)
Ar He H2 N2
169(1988) 167(1985), 169(1988) 167(1985) 167(1985), 169(1988) 167(1985), 169(1988)
2^+3*3 (14640 cm"1)
He H2 N2 CH4
226(1986) 226(1986) 226(1986) 226(1986)
5Ρ^Ρ3
He H2 N2 CH4
226(1986) 226(1986) 226(1986) 176(1979), 226(1986)
"l + "4 3P3
(4224 cm"1) (9047 cm"1)
He + H 2
(16160 cm'1)
INTENsmES A N D COLLISION-BROADENING PARAMETERS ψ
227
TABLE IV (14)
BROADENING GAS
BAND
13
1
REFERENCE
CH 4
"4
(1299 cm" )
Ar He H2 N2 02 Air (N 2 + Oj)
425(1989) 425(1989) 425(1989) 278(1985), 425(1989) 425(1989) 278(1985), 279(1988), 425(1989)
"3
(3010 cm"1)
N2 Air (N 2 + Ο2)
269(1991) 269(1991) 269(1991)
H2
167(1985)
3, 3
(9045 cm-1)
o2
12
v
6
v
3
v
2
CH 3 D
(1161cm- 1 )
He H2 N2 Air (N 2 + 0 2 ) CH3D
424(1989) 241(1987), 424(1989) 241(1987), 268(1987), 424(1989) 268(1987) 241(1987), 424(1989)
(1307 cm"1)
H2 N2 Air (N 2 + Ο2) CH3D
424(1989) 276(1986), 424(1989) 276(1986) 276(1986)
(2200 cm'1)
H2 N2
122(1987) 122(1987) GeH4
"3
1
(2114 cm" )
H2
93(1985), 420(1987) HN0 3
(1307 cm"1) χ (1326 cm"1) /
Air (N 2 + 0 2 )
300(1989)
228
v
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE IV (15) BAND
BROADENING GAS
REFERENCE
SiF 4 "3
1
(1032 cm" )
He Xe
217(1985) 216(1985) 317(1973), 46(1974), 24(1982)
SiF 4 Ethane (C2H6)
v
9
(822 cm"1)
Ar He H2 N2 CH4 C
2H6
52(1987) 52(1987) 52(1987), 192(1988) 52(1987), 123(1985) 52(1987) 52(1987)
Sulfur Hexafluoride ( 32 SF 6 ) "3
(950 cm'1)
Ar He Kr Ne Xe CO H2
8*SF« 34
SF 6
237(1990) 237(1990) 237(1990) 237(1990) 237(1990) 237(1990) 237(1990) 237(1990) 237(1990) 237(1990)
Uranium Hexafluoride (UF6) v3
(628 cm"1)
Ar
304(1985)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS TABLE V.
BIBLIOGRAPHY FOR PRESSURE-INDUCED LINE-SHIFT MEASUREMENTS
Molecule
Page
CO HBr
230 230 230 231 232 232 232 232 233 233 233 234 234 234 235 235 236 236 236 237 237 237
H35C1 H37C1 D35C1
HF DF H2 HD D2
12 16 c o2 13 16 c o2 12 18 c o2 13 18 c o2
HCN H20 N20 O3 14
NH 3 NH 3 12 CH 4 13 CH 4 15
ψ
229
230
ψ
SMITH, R I N S L A N D , D E V I , R O T H M A N , R A O
TABLE V (2) BAND
BROADENING GAS
REFERENCE
CO 1
1-0
(2143 cm" )
Ar
352(1963)
2-0
(4260 cm-1)
Ar Xe CO HC1 H2 N2 NO 02 C02
352(1963) 352(1963) 58(1973), 59(1974), 348(1983) 58(1973) 58(1973) 58(1973) 58(1973) 58(1973) 58(1973)
3-0
(6350 cm"1)
CO
59(1974) HBr
1-0
(2559 cm"1)
Ar Xe H2 N2
352(1963) 352(1963) 352(1963) 352(1963) H35C1
1-0
(2886 cm'1)
Ar He Kr Ne Xe HC1 HF H2 D2 N2 Air (N 2 + 0 2 ) 02 CF 4
40(1961), 352(1963), 257(1973), 209(1975), 210(1976), 440(1984) 40(1961), 352(1963) 40(1961), 352(1963) 40(1961) 40(1961), 352(1963), 257(1973), 210(1976) 343(1985) 64(1981) 211(1977), 213(1980) 211(1977), 213(1980) 212(1977), 213(1980), 345(1987) 345(1987) 213(1980) 352(1963)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS
T
TABLE V (3) BAND
BROADENING GAS
REFERENCE
H35C1 (continued)
Ar
351(1960), 205(1960), 40(1961), 353(1964), 189(1978), 208(1981) 351(1960), 40(1961), 353(1964) 40(1961), 353(1964) 351(1960), 40(1961), 189(1978) 40(1961), 352(1963), 353(1964), 257(1973), 208(1981) 351(1960), 205(1960) 234(1959), 189(1978) 205(1960) 189(1978), 64(1981) 351(1960) 351(1960), 189(1978) 234(1959) 351(1960) 351(1960), 189(1978) 351(1960) 205(1960) 205(1960)
He Kr Ne Xe CO HC1 DC1 HF H2 N2
Air (N 2 + O2)
02
co2
N20 S0 2
CH3CI H37C1
1-0
(2884 cm"1)
HC1 HF
343(1985) 64(1981)
2-0
(5664 cm"1)
Ar Ne CO HC1 HF N2
205(1960), 40(1961), 189(1978) 189(1978) 205(1960) 234(1959), 189(1978) 189(1978), 64(1981) 189(1978) 234(1959) 189(1978) 205(1960)
Air (N 2 + 0 2 )
co 2 CH3CI
231
232
τ
SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE V (4) BAND
BROADENING GAS
REFERENCE
D35C1 1-0
(2091 cm"1)
Ar Xe
352(1963) 352(1963)
2-0
(4127 cm"1)
HC1
218(1964) HF
1-0
(3961 cm"1)
Ar Kr Ne Xe HF N2 Air (N 2
co2
2-0
(7751 cm"1)
+ o2)
Ar Kr Ne Xe HC1 HF N2
co 2
324(1963), 219(1965) 189(1978) 219(1965) 240(1958), 189(1978), 345(1987) 384(1969),
219(1965), 189(1978)
219(1965), 219(1965), 189(1978) 219(1965), 189(1978), 189(1978) 189(1978) 189(1978)
441(1970), 189(1978) 441(1970)
202(1962), 343(1985) 345(1987) 189(1978)
441(1970) 64(1981)
DF 2-0
(5810 cm 4 )
144(1971)
HF TJ Ά
1
2
1-0
(4161 cm' )
H2
354(1963), 154(1965), 165(1966), 68(1968), 80(1971), 66(1982)
2-0
(8087 cm"1)
H2
110(1975), 66(1982)
4-0
(15625 cm'1)
H2
45(1978), 69(1980)
INTENSITIES AND COLLISION-BROADENING PARAMETERS ψ
233
TABLE V (5) BROADENING GAS
BAND
REFERENCE
HD 1
1-0
(3677 cm- )
Ar Kr Xe HD
315(1983) 315(1983) 315(1983) 305(1973), 315(1983)
2-0
(7087 cm"1)
HD
305(1973)
3-0
(10368 cm"1)
H2
306(1974)
4-0
(13477 cm"1)
H2 HD
306(1974) 415(1983)
5-0
(16416 cm-1)
HD
415(1983) D2
1-0
1
(2994 cm" )
D2
68(1968) 12 16
c o2
00011-10001 (961 cm'1)
Ar He He + N2 + C0 2 He + CO l + N2 + H2 Xe H2 N2 C0 2 CH3F
394(1984), 395(1985) 394(1984), 5(1985), 395(1985) 170(1970) 207(1982) 394(1984), 395(1985) 394(1984), 395(1985) 394(1984), 395(1985) 443(1976), 171(1977), 394(1984), 395(1985) 394(1984), 395(1985)
00011-10002 (1064 cm"1)
He N2
435(1972) 435(1972) 435(1972), 394(1984), 395(1985)
11102-00001 (1932 cm"1)
Ar He Ne Xe
145(1986) 145(1986) 145(1986) 145(1986)
co2
234
τ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O TABLE v
BAND
(6)
BROADENING GAS 12
REFERENCE
C 1 6 0 2 (continued)
00011-00001 (2349 cm"1) Band System
N2
23(1987)
00031-00001 (6973 cm"1)
co 2
12(1980), 81(1989) 13 16
c o2
00011-10001 (913 cm·1)
co 2
394(1984), 395(1985)
00011-10002 (1018 cm"1)
co 2
394(1984), 395(1985) 12 18
c o2
00011-10001 (967 cm"1)
Ar He Xe H2 N2 C0 2 CH3F
394(1984), 394(1984), 394(1984), 394(1984), 394(1984), 394(1984), 394(1984),
00011-10002 (1084 cm"1)
co 2
394(1984), 395(1985) 13
00011-10001 (929 cm"1)
He Xe H2 N2
C1802
CH3F
395(1985) 395(1985) 395(1985) 395(1985) 394(1984), 395(1985) 395(1985)
CO,
394(1984), 395(1985)
co 2
00011-10002 (1027 cm"1)
395(1985) 395(1985) 395(1985) 395(1985) 395(1985) 395(1985) 395(1985)
INTENSITIES A N D COLLISION-BROADENING PARAMETERS T
TABLE V (7) BAND
BROADENING GAS
REFERENCE
HCN 1
(712 cm" )
v2
1^2 +2i'3~i'2
(6480 cm 1 ) (6520 cm"1)
2i/3
V2+$vyV2
HCN
164(1946)
HCN
379(1990)
HCN
390(1986)
HCN
390(1986)
(15452 cm"1)
5*>3
(15552 cm"1)
H20 (1595 cm'1)
Xe N2 Air (N 2 + 0 2 ) H20 S02
151(1972) 153(1973) 153(1973), 152(1974) 151(1972) 320(1987)
Air (N 2 + 0 2 )
451(1985), 450(1986), 90(1988), 91(1988)
Air (N 2 + 0 2 )
179(1982)
2J/ 1 +2J/ 2 +»>3
Ar No 02 Air (N 2 + 0 2 )
188(1989) 188(1989) 188(1989) 188(1989) 187(1989)
2J>1+2I>3
Ar N2
o2
Air (N 2 + 0 2 ) H20
188(1989) 188(1989) 188(1989) 54(1985), 188(1989) 187(1989)
Ar N2 02 Air (N 2 + 0 2 ) H20
188(1989) 188(1989) 188(1989) 54(1985), 188(1989) 187(1989)
v2
J>2+2l>3 2ίΊ+ϊ>3
(9000 cm 1 )
(10613 cm'1) (13653 cm"1)
(13828 cm'1)
3*1+?3 (13831 cm"1)
235
236
ψ
SMITH, R I N S L A N D , DEVI, R O T H M A N , R A O
TABLE V (8) BAND
BROADENING GAS
REFERENCE
H 2 0 (continued) 3y 1 +2j'2
(13850 cm"1) (13850 cm"1)
1^+3^3
(14400 cm'1)
o2
188(1989)
Air (N 2 + 0 2 )
188(1989)
Air (N 2 + O2)
349(1985), 451(1985), 450(1986), 90(1988)
N20 vy vx
I/J
1
(939 cm' ) (1285 cm"1)
N2
190(1986)
o2
429(1989) 429(1989) 429(1989) 414(1986)
N2 Air (N 2 + O2) N20
o3 v3
(1042 cm"1)
N2 Air (N 2 + 0 2 )
392(1988) 392(1988)
vx
(1103 cm"1)
N2 Air (N 2 + Ο2)
392(1988) 392(1988) 14
" 4 ^
(716 cm"1)
co 2
NH 3
V^-vf 2"2a-"2S p2s p2*
(629 cm'1) (950 cm"1) (932 cm"1) \ (968 cm'1) i
NH 3 N226(1990) 26(1990) 25(1989)
N2 C02 NH.
26(1990) 26(1990) 85(1983), 29(1983), 28(1985), 86(1985), 378(1986), 25(1989)
N2 C02 Ntt,
26(1990) 26(1990) 254(1974), 27(1982), 124(1988), 25(1989)
INTENsmES A N D COLLISION-BROADENING PARAMETERS
ψ
TABLE V (9) BAND
BROADENING GAS 15
2, 2 a - - 2 S "?S "2*
(943 cm'1) (928 cm"1) \ (963 cm"1) /
NH 3
NH3
378(1986)
NH3
84(1982), 86(1985), 383(1985) 12
"4
(1306 cm"1)
2
(1534 cm' )
"3
(3019 cm"1)
v
CH 4
Ar N2 Air (N 2
1
366(1989) 429(1989) 365(1988), 429(1989) 365(1988), 429(1989)
+ o2)
N2
365(1988) 365(1988)
Ar He
184(1968), 10(1989) 184(1968), 18(1972), 10(1989) 184(1968), 10(1989) 184(1968), 20(1983) 184(1968), 18(1972), 10(1989) 342(1976), 11(1976), 11(1976), 10(1989) 385(1968), 37(1969), 11(1976), 10(1989)
Air(N 2 + 0 2 )
Kr Ne Xe Air(N 2 + 0 2 )
co CH2
4
3, 3
(9047 cm 1 )
Ar He H2 N2 CH4
168(1989) 168(1989) 168(1989) 168(1989) 287(1971) 13
"4
(1299 cm"1)
"3
(3010 cm"1)
REFERENCE
CH 4
H2
Air (N 2 + 0 2 )
429(1989) 279(1988)
N2 02 Air (N 2 + 0 2 )
269(1991) 269(1991) 269(1991)
11(1976),
11(1976), 10(1989) 18(1972),
237
238
ψ SMITH, RINSLAND, DEVI, ROTHMAN, RAO
TABLE REFERENCES 1. Abubakar, M., and Shaw, J. H. (1984). "Analysis of Carbon Dioxide Bands near 2.2 μπι," Appl. Opt. 23, 3310. 2. Abubakar, M., and Shaw, J. H. (1986). "Carbon Dioxide Band Intensities and Linewidths in the 8-12 μπι Region," Appl. Opt. 25, 1196. 3. Ackerhalt, J. R., Flicker, H., Galbraith, H. W., King, J., and Person, W. B. (1978). "Analysis of 3v3 in SF6," J. Chem. Phys. 69, 1461. 4. Adiks, T. G., Vinogradova, A. A., and Malkov, I. P. (1986). "Measurement of the Absorption Line Parameters of Water Vapor in the 5.8-μπι Region Using a Tunable diode laser Spectrometer." Zh. Prikl. Spektrosk. 45, 194; English trans. J. Appl. Spectrosc. 45, 778 (1987). 5. Agalakov, Yu. G., Bulanin, M. O., Bertsev, V. V., Burtsev, A. P., and Rubinov, Yu. A. (1985). "Observation of a Frequency Shift of Vibrational-Rotational Transitions of the CO2 Molecule Caused by a Buffer Gas," Opt. Spektrosk. 58, 493; English trans. Opt. Spectrosc. 58, 298 (1985). 6. Aganbekyan, K. A., Voitsekhovskaya, O. K., Gulyaev, G. A., Kulikov, V. V., and Trifonova, N. N. (1988). "The Water-Vapor Weak Line Intensities in the Range 8 to 10 μπι," J. Mol. Spectrosc. 130, 258. 7. Ahlberg, H., Lundqvist, S., and Eng, S. T. (1984). "Absorption Coefficients of Chlorine Dioxide at 12 C 16 0 2 and , 2 C 1 8 0 2 Laser Wavelengths: Applications to Remote Monitoring in the Working Environment," Appl. Opt. 23, 2902. 8. Akhmedzhanov, R., and Kurbaniyazov, S. Kh. (1989). "Absorption Band Strengths in the 1.5-2.5-μπι Region in Liquid and Gaseous Nitrous Oxide," Opt. Spektrosk. 66, 283; English trans. Opt. Spectrosc. 66, 163 (1989). 9. Amrein, A., Dubai, H.-R., Lewerenz, M., and Quack, M. (1984). "Group Additivity and Overtone Intensities for the Isolated CH Chromophore," Chem. Phys. Lett. 112, 387. 10. Antipov, A. B., Kochanov, V. P., Sapozhnikova, V. A., and Tinchurina, E. G. (1989). "Collisional Broadening and Shift of the 3.39-μπι Line of the v3 Band of Methane," Opt. Spektrosk. 66, 64; English trans. Opt. Spectrosc. 66, 36 (1989). 11. Antipov, A. B., Pyrsikova, P. D., and Sapozhnikova, V. A. (1976). "Effect of Temperature and Pressure on the Profile of the Methane Absorption Line with Its Center at v0 = 2947.9 cm"1," Opt. Spektrosk. 40, 795; English trans. Opt. Spectrosc. 40, 455 (1976). 12. Areas, P., Arie, E., Boulet, C , and Maillard, J. P. (1980). "Self-Shifting of C0 2 Lines in the 3v3 Band at 1.43 μπι," J. Chem. Phys. 73, 5383. 13. Arefev, V. N., and Visheratin, K. N. (1989). "Investigation of Spectral Parameters in the Vibration-Rotation Lines of SO2 Band vi," Optika Atmosfery 2(11), 1160. 14. Arie, E., Lacome, N., Areas, P., and Levy, A. (1986). "Oxygen- and Air-Broadened Linewidths of C0 2 ," Appl. Opt. 25, 2584. 15. Ari6, E., Lacome, N., and Levy, A. (1987). "Measurement of C0 2 Line Broadening in the 10.4-μπι Laser Transition at Low Temperatures," Appl. Opt. 26, 1636. 16. Atkinson, R., Aschmann, S. M., Tuazon, E. C , Goodman, M. A., and Winer, A. M. (1987). "The Gas-Phase Reaction of C10N0 2 with Hydrogen Chloride," J. Atmos. Chem. 5, 83. 17. Atkinson, R., Tuazon, E. C , MacLeod, H., Aschmann, S. M., and Winer, A. M. (1986). "The Gas-Phase Reaction of Chlorine Nitrate with Water Vapor," Geophys. Res. Lett. 13, 117. 18. Bagaev, S. N., Baklanov, E. V., and Chebotaev, V. P. (1972). "Anomalous Decrease of the Shift of the Center of the Lamb Dip in Low-Pressure Molecular Gases," Pis'ma Zh. Eksp. Teor. Fiz. 16, 344; English trans. JETP Lett. 16, 243 (1972). 19. Bagaev, S. N., Dychkov, A. S., Semibalamut, V. M., Titov, E. A., and Chebotaev, V. P. (1985). "Intensity of Narrow Resonances in a Low Pressure Gas," Opt. Spektrosk. 59, 481; English trans. Opt. Spectrosc. 59, 291 (1985).
INTENSITIES AND COLLISION-BROADENING PARAMETERS ψ
239
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