- Email: [email protected]
Intercalation of sodium into graphite-like layered material BC2N
CARBON
5 0 ( 2 0 1 2 ) 7 3 7 –7 3 9
Available at www.sciencedirect.com
journal homepage: www.elsevier.com/locate/carbon
Tanso 249 Abstracts Intercalation of sodium into graphite-like layered material BC2N
TANSO 2011 (No. 249), 168–173
Kaoru Yamadaa, Akihiro Kurasakia, Masayuki Kawaguchia,b a
Graduate School of Engineering, Osaka Electro-Communication
doi:10.1016/j.carbon.2011.08.062
University b
Fundamental
Electronics
Research
Institute,
Osaka
Electro-
Communication University
Carbon fiber & composite material – Landscape Germany Wilhelm Frohs, Hubert Jaeger
Graphite-like layered material of composition BC2N was prepared by the CVD reaction of acetonitrile with boron trichloride at 2070 K. Sodium was intercalated into the BC2N film and powder by two methods: a vapor phase reaction and an electrochemical method. The first stage compounds were prepared by the vapor phase reaction using the BC2N film and powder. A mixture of the first and the second stage compounds was prepared from the BC2N powder, while the first stage compound was prepared from the BC2N film by the electrochemical method. The d-spacing of the intercalated layers was 0.43 nm, calculated from the sharp (0 0 1) and (0 0 2) diffraction lines observed on the X-ray diffraction patterns of the first stage compounds prepared from the BC2N films by the two methods. TANSO 2011 (No. 249), 161–167 doi:10.1016/j.carbon.2011.08.061
SGL CARBON GmbH The commercialization of carbon fibers and their composites initially served the defence and aerospace industry. Sporting goods followed and allowed carbon fiber companies to survive the years after the cold war. High prices and manual production technologies hindered entrance into big consumer markets. This situation is going to change with the implementation of highly automated textile processes for the production of carbon fiber reinforced polymers (CFRP). The biggest impetus is coming from the energy and CO2 debate. Thus CFRP components will further grow in the aviation industry but also spread into automobiles, windmills, civil engineering and other industrial applications. The carbon fiber market is dominated by producers based in Japan and in the USA, with precursor production in the hands of Japanese companies. Europe has failed to build home-based precursor and carbon fiber production technologies. SGL Group – The Carbon Company as a leader in the carbon and graphite
Measurement of the dimension changes of carbon artifacts
industry recognized this situation and started to expand its com-
during graphitization in a pilot LWG furnace
petence in carbon fiber and related technology. This includes its
Raymond Perruchouda, Werner Fischera, Italo Letiziab
own precursor production as well as downstream processes like
a
R&D Carbon Ltd.
textile techniques and CFRP components. These activities are
b
Letizia Associates A pilot lengthwise graphitization (LWG) furnace designed and
operated by R&D Carbon Ltd. is a high temperature/pressure dilatometer. The equipment is suitable either for research purposes or for checking industrial baked carbon artifacts (electrodes/cath-
embedded in an industrial and scientific network which has its centre in the south of Germany. SGL’s strategy is to become a European/German home-based key player in carbon fiber and composite technology. TANSO 2011 (No. 249), 174–178 doi:10.1016/j.carbon.2011.08.063
odes) which have to resist the thermal stress created in the full size LWG process. Unlike conventional high temperature dilatometers, this equipment offers the possibility to test cylindrical specimens of large size (Ø50 500 mm) and under pressure.
Pore structures and ethylene adsorption behavior of polysac-
This pilot testing provides useful information for the optimiza-
charide-derived carbons
tion of the power profile in industrial furnaces aiming to maxi-
Naoya Miyajimaa, Koji Hirookaa, Hideto Sakanea,
mize the productivity and minimizing the scrap rate of the end
Masako Furuyab, Kaoru Tamurab, Yorioki Matsumotob
products.
doi:10.1016/S0008-6223(11)00707-X
5 0 ( 2 0 1 2 ) 7 3 7 –7 3 9
Available at www.sciencedirect.com
journal homepage: www.elsevier.com/locate/carbon
Tanso 249 Abstracts Intercalation of sodium into graphite-like layered material BC2N
TANSO 2011 (No. 249), 168–173
Kaoru Yamadaa, Akihiro Kurasakia, Masayuki Kawaguchia,b a
Graduate School of Engineering, Osaka Electro-Communication
doi:10.1016/j.carbon.2011.08.062
University b
Fundamental
Electronics
Research
Institute,
Osaka
Electro-
Communication University
Carbon fiber & composite material – Landscape Germany Wilhelm Frohs, Hubert Jaeger
Graphite-like layered material of composition BC2N was prepared by the CVD reaction of acetonitrile with boron trichloride at 2070 K. Sodium was intercalated into the BC2N film and powder by two methods: a vapor phase reaction and an electrochemical method. The first stage compounds were prepared by the vapor phase reaction using the BC2N film and powder. A mixture of the first and the second stage compounds was prepared from the BC2N powder, while the first stage compound was prepared from the BC2N film by the electrochemical method. The d-spacing of the intercalated layers was 0.43 nm, calculated from the sharp (0 0 1) and (0 0 2) diffraction lines observed on the X-ray diffraction patterns of the first stage compounds prepared from the BC2N films by the two methods. TANSO 2011 (No. 249), 161–167 doi:10.1016/j.carbon.2011.08.061
SGL CARBON GmbH The commercialization of carbon fibers and their composites initially served the defence and aerospace industry. Sporting goods followed and allowed carbon fiber companies to survive the years after the cold war. High prices and manual production technologies hindered entrance into big consumer markets. This situation is going to change with the implementation of highly automated textile processes for the production of carbon fiber reinforced polymers (CFRP). The biggest impetus is coming from the energy and CO2 debate. Thus CFRP components will further grow in the aviation industry but also spread into automobiles, windmills, civil engineering and other industrial applications. The carbon fiber market is dominated by producers based in Japan and in the USA, with precursor production in the hands of Japanese companies. Europe has failed to build home-based precursor and carbon fiber production technologies. SGL Group – The Carbon Company as a leader in the carbon and graphite
Measurement of the dimension changes of carbon artifacts
industry recognized this situation and started to expand its com-
during graphitization in a pilot LWG furnace
petence in carbon fiber and related technology. This includes its
Raymond Perruchouda, Werner Fischera, Italo Letiziab
own precursor production as well as downstream processes like
a
R&D Carbon Ltd.
textile techniques and CFRP components. These activities are
b
Letizia Associates A pilot lengthwise graphitization (LWG) furnace designed and
operated by R&D Carbon Ltd. is a high temperature/pressure dilatometer. The equipment is suitable either for research purposes or for checking industrial baked carbon artifacts (electrodes/cath-
embedded in an industrial and scientific network which has its centre in the south of Germany. SGL’s strategy is to become a European/German home-based key player in carbon fiber and composite technology. TANSO 2011 (No. 249), 174–178 doi:10.1016/j.carbon.2011.08.063
odes) which have to resist the thermal stress created in the full size LWG process. Unlike conventional high temperature dilatometers, this equipment offers the possibility to test cylindrical specimens of large size (Ø50 500 mm) and under pressure.
Pore structures and ethylene adsorption behavior of polysac-
This pilot testing provides useful information for the optimiza-
charide-derived carbons
tion of the power profile in industrial furnaces aiming to maxi-
Naoya Miyajimaa, Koji Hirookaa, Hideto Sakanea,
mize the productivity and minimizing the scrap rate of the end
Masako Furuyab, Kaoru Tamurab, Yorioki Matsumotob
products.
doi:10.1016/S0008-6223(11)00707-X