- Email: [email protected]
LASER DYES
Appendix LASER DYES
433
436
•S
437
Name
W e i g h t (au)
Molecular
Maximum X(nm)
Absorption X(nm)
Fluorescence
Maximum ( P u m p Laser)
L a n s i n g λ (nm)
Maximum Solvents
A p p e n d i x of L a s e r Dyes
Molecular Structure
F l u o r e s c e i n 27)
(Fluorescein 548;
Fluorescein
( C o u m a r i n 540)
Coumarin 6
coumarin)
7-N,N-diethylamino
(2'-Benzimidazolyl)-
(Coumarin 535; 3 -
Coumarin 7
( C o u m a r i n 519)
Coumarin 343
( C o u m a r i n 521)
Coumarin 334
332.31
350.44
333.39
285.30
283.33
498
458
437
440
452
518
497
488
482
491
(continues)
Tetrafluoroborate)
(Rhodamine 590
Tetrafluoroborate
Rhodamine 6G
2',7'-Dichlorofluorescein
512
528
401.20
530.37
498
366.80
R h o d a m i n e 110
( R h o d a m i n e 560)
X(nm)
W e i g h t (au)
Name
Maximum Absorption
Molecular
547
526 + 2 % base
methanol
557 (Nd:YAG)1
methanol, ethanol
( N 2)
Solvents
554
( P u m p Laser)
\(nm)
520
Maximum L a n s i n g λ (nm)
Maximum Fluorescence
A p p e n d i x of L a s e r Dyes
Molecular Structure
(continues)
c a r b o c y a n i n e Iodide)
3,3'-Diethyloxadi
(DODCI;
D O D C Iodide
Name
486.35
W e i g h t (au)
Molecular
Maximum
Maximum X(nm)
605
578
Fluorescence
X(nm)
Absorption
(Nd:YAG)2
647
( P u m p Laser)
L a n s i n g λ (nm)
Maximum
methanol
Solvents
A p p e n d i x of L a s e r Dyes
Q
C 2H 5
f
-
ιθ
-CH=CH-CH=CH-CH=i^
Molecular Structure
C 2H 5
4^
(Oxazine 725 Perchlorate)
Oxazine 1 Perchlorate
(Nile B l u e 6 9 0 Perchlorate)
Nile Blue A Perchlorate
(Oxazine 720 Perchlorate)
O x a z i n e 170 Perchlorate
aminostyryl)-4H-pyran)
methyl-6-(p-dimethyl-
(4-(Dicyanomethylene)-2-
DCM
(LD690 Perchlorate)
Oxazine 4 Perchlorate
423.90
417.85
431.88
303.37
395.84
643
627
620
480
610
658
660
637
627
625
(continues)
679
662
methanol
^ \ {^y^ N
^
f
if
^
Perchlorate)
indotricarbocyanine
1,1 \ 3 , 3 , 3 \ 3 ' - H e x a m e t h y l -
(HITCP;
HITC Perchlorate
c a r b o c y a n i n e Iodide)
3,3'-Diethyloxatri-
(DOTCI;
D O T C Iodide
509.05
5
S
s-
°PTS
p.
5
( C H 3)
C 2H
( Ο Η = α Η ) ^ ^ > - Ν
I©
CH=CH-CH=CH-C
C 2H
512.39
715 ( N 2)
-
] ^
704
S
Molecular Structure
p-Toluenesulfonate)
phenyl)-1,3-butadienyl]-3-
^
560
DMSO
Solvents
ethylbenzothiazolium
(2-[4-(4-Dimethylamino-
4^
Styryl 7
Iodide)
506.6
698 (Nd:YAG)2
3,3'-Diethylthiadi
carbocyanine
( N 2)
518.48
743
( P u m p Laser)
X(nm)
X(nm)
W e i g h t (au)
(DTDCI;
D T D C Iodide
Name
Maximum Lansing λ (nm)
Maximum
Absorption
Molecular
Maximum Fluorescence
A p p e n d i x of L a s e r Dyes
2
(DTTCI;
IR-144
Iodide)
carbocyanine
3,3'-Diethylthiatri
D T T C Iodide
4^
^
Perchlorate)
carbocyanine
3,3'-Diethylthiatri
(DTTCP;
D T T C Perchlorate
cyanine Iodide)
methylindotricarbo-
1,1\3,3,3\3'-Hexa-
(HITCI;
HITC Iodide
1008.00
544.00
517.06
536.00
745
772
772
750
825
820
818
790
C 2H 5
C 2H 5
(continues)
A p p e n d i x of L a s e r Dyes
A b s o r p t i o n a n d e m i s s i o n d a t a o b t a i n e d w i t h s o l v e n t l i s t e d i n first p l a c e .
1
T h i r d H a r m o n i c f r o m N d : Y A G at 3 5 5 n m .
S e c o n d H a r m o n i c f r o m N d : Y A G at 5 3 2 n m .
2
(CH 2) 4S(V
For further a l t e r n a t i v e s o l v e n t s , s e e D r e x h a g e (1977) a n d M a e d a (1984).
T h e i n f o r m a t i o n g i v e n in t h i s t a b l e h a s b e e n r e p r o d u c e d f r o m K O D A K L a s e r D y e s ( B i r g e , 1 9 8 7 ) c o u r t e s y o f E a s t m a n K o d a k C o m p a n y .
iodide
1,3'-diethyl-4,2'-quinolyoxacarbocyanine
1,1'3,3,3',3'-hexamethylindocarbocyanine
1,1',3,3,3',3'-hexamethylindotricarbocyanine
2-methyl-4-nitroaniline
DQOCI
HICI
HITCI
MNA
1,3'-Diethyl-4,2'-quinolthiacarbocyanine
DTDCI
DQTCI
iodide
1,1 ' - D i e t h y l - 4 , 4 ' - c a r b o c y a n i n e
3,3'-Diethyl thiadicarbocyanine
*Cryptocyanine
iodide
iodide
iodide
iodide
iodide
3,3'-diethyl oxatricarbocyanine
DOTCI iodide
3,3'-diethyl oxadicarbocyanine
iodide
3,3'-diethyl oxacarbocyanine
iodide
1,1'-diethyl-2,2'-dicarbocyanine
DODCI
DDI
DOCI
=
DDCI*
iodide
1,1'-diethyl-2,4'-carbocyanine
DCI
DCCI
=
4-dicyanomethylene-2-methyl-6-p-dimethylaminostyryl-4H-pyran
DCM
iodide
1,1 ' - d i e t h y l - 1 3 - a c e t o x y - 2 , 2 ' - q u i n o t e t r a c a r b o c y a n i n e
DaQTeC
iodide
2-(p-dimethylaminostyryl)-benzothiazolylethyl
DASBTI
A b b r e v i a t i o n s u s e d i n C h a p t e r 3:
M a e d a , M. (1984). Laser Dyes. A c a d e m i c Press, N e w York.
D r e x h a g e , K . H . ( 1 9 7 7 ) . S t r u c t u r e a n d P r o p e r t i e s o f L a s e r D y e s . In D y e L a s e r s ( S c h ä f e r , F.P., e d . ) . S p r i n g e r - V e r l a g , N e w Y o r k , p p . 1 4 4 - 1 9 3 .
B i r g e , R.R. ( 1 9 8 7 ) . K O D A K L a s e r D y e s . K O D A K P u b l i c a t i o n J J - 1 6 9 . E a s t m a n K o d a k C o m p a n y , R o c h e s t e r , N.Y.
References:
Notes:
(CH 2) 4S0 3Na
433
436
•S
437
Name
W e i g h t (au)
Molecular
Maximum X(nm)
Absorption X(nm)
Fluorescence
Maximum ( P u m p Laser)
L a n s i n g λ (nm)
Maximum Solvents
A p p e n d i x of L a s e r Dyes
Molecular Structure
F l u o r e s c e i n 27)
(Fluorescein 548;
Fluorescein
( C o u m a r i n 540)
Coumarin 6
coumarin)
7-N,N-diethylamino
(2'-Benzimidazolyl)-
(Coumarin 535; 3 -
Coumarin 7
( C o u m a r i n 519)
Coumarin 343
( C o u m a r i n 521)
Coumarin 334
332.31
350.44
333.39
285.30
283.33
498
458
437
440
452
518
497
488
482
491
(continues)
Tetrafluoroborate)
(Rhodamine 590
Tetrafluoroborate
Rhodamine 6G
2',7'-Dichlorofluorescein
512
528
401.20
530.37
498
366.80
R h o d a m i n e 110
( R h o d a m i n e 560)
X(nm)
W e i g h t (au)
Name
Maximum Absorption
Molecular
547
526 + 2 % base
methanol
557 (Nd:YAG)1
methanol, ethanol
( N 2)
Solvents
554
( P u m p Laser)
\(nm)
520
Maximum L a n s i n g λ (nm)
Maximum Fluorescence
A p p e n d i x of L a s e r Dyes
Molecular Structure
(continues)
c a r b o c y a n i n e Iodide)
3,3'-Diethyloxadi
(DODCI;
D O D C Iodide
Name
486.35
W e i g h t (au)
Molecular
Maximum
Maximum X(nm)
605
578
Fluorescence
X(nm)
Absorption
(Nd:YAG)2
647
( P u m p Laser)
L a n s i n g λ (nm)
Maximum
methanol
Solvents
A p p e n d i x of L a s e r Dyes
Q
C 2H 5
f
-
ιθ
-CH=CH-CH=CH-CH=i^
Molecular Structure
C 2H 5
4^
(Oxazine 725 Perchlorate)
Oxazine 1 Perchlorate
(Nile B l u e 6 9 0 Perchlorate)
Nile Blue A Perchlorate
(Oxazine 720 Perchlorate)
O x a z i n e 170 Perchlorate
aminostyryl)-4H-pyran)
methyl-6-(p-dimethyl-
(4-(Dicyanomethylene)-2-
DCM
(LD690 Perchlorate)
Oxazine 4 Perchlorate
423.90
417.85
431.88
303.37
395.84
643
627
620
480
610
658
660
637
627
625
(continues)
679
662
methanol
^ \ {^y^ N
^
f
if
^
Perchlorate)
indotricarbocyanine
1,1 \ 3 , 3 , 3 \ 3 ' - H e x a m e t h y l -
(HITCP;
HITC Perchlorate
c a r b o c y a n i n e Iodide)
3,3'-Diethyloxatri-
(DOTCI;
D O T C Iodide
509.05
5
S
s-
°PTS
p.
5
( C H 3)
C 2H
( Ο Η = α Η ) ^ ^ > - Ν
I©
CH=CH-CH=CH-C
C 2H
512.39
715 ( N 2)
-
] ^
704
S
Molecular Structure
p-Toluenesulfonate)
phenyl)-1,3-butadienyl]-3-
^
560
DMSO
Solvents
ethylbenzothiazolium
(2-[4-(4-Dimethylamino-
4^
Styryl 7
Iodide)
506.6
698 (Nd:YAG)2
3,3'-Diethylthiadi
carbocyanine
( N 2)
518.48
743
( P u m p Laser)
X(nm)
X(nm)
W e i g h t (au)
(DTDCI;
D T D C Iodide
Name
Maximum Lansing λ (nm)
Maximum
Absorption
Molecular
Maximum Fluorescence
A p p e n d i x of L a s e r Dyes
2
(DTTCI;
IR-144
Iodide)
carbocyanine
3,3'-Diethylthiatri
D T T C Iodide
4^
^
Perchlorate)
carbocyanine
3,3'-Diethylthiatri
(DTTCP;
D T T C Perchlorate
cyanine Iodide)
methylindotricarbo-
1,1\3,3,3\3'-Hexa-
(HITCI;
HITC Iodide
1008.00
544.00
517.06
536.00
745
772
772
750
825
820
818
790
C 2H 5
C 2H 5
(continues)
A p p e n d i x of L a s e r Dyes
A b s o r p t i o n a n d e m i s s i o n d a t a o b t a i n e d w i t h s o l v e n t l i s t e d i n first p l a c e .
1
T h i r d H a r m o n i c f r o m N d : Y A G at 3 5 5 n m .
S e c o n d H a r m o n i c f r o m N d : Y A G at 5 3 2 n m .
2
(CH 2) 4S(V
For further a l t e r n a t i v e s o l v e n t s , s e e D r e x h a g e (1977) a n d M a e d a (1984).
T h e i n f o r m a t i o n g i v e n in t h i s t a b l e h a s b e e n r e p r o d u c e d f r o m K O D A K L a s e r D y e s ( B i r g e , 1 9 8 7 ) c o u r t e s y o f E a s t m a n K o d a k C o m p a n y .
iodide
1,3'-diethyl-4,2'-quinolyoxacarbocyanine
1,1'3,3,3',3'-hexamethylindocarbocyanine
1,1',3,3,3',3'-hexamethylindotricarbocyanine
2-methyl-4-nitroaniline
DQOCI
HICI
HITCI
MNA
1,3'-Diethyl-4,2'-quinolthiacarbocyanine
DTDCI
DQTCI
iodide
1,1 ' - D i e t h y l - 4 , 4 ' - c a r b o c y a n i n e
3,3'-Diethyl thiadicarbocyanine
*Cryptocyanine
iodide
iodide
iodide
iodide
iodide
3,3'-diethyl oxatricarbocyanine
DOTCI iodide
3,3'-diethyl oxadicarbocyanine
iodide
3,3'-diethyl oxacarbocyanine
iodide
1,1'-diethyl-2,2'-dicarbocyanine
DODCI
DDI
DOCI
=
DDCI*
iodide
1,1'-diethyl-2,4'-carbocyanine
DCI
DCCI
=
4-dicyanomethylene-2-methyl-6-p-dimethylaminostyryl-4H-pyran
DCM
iodide
1,1 ' - d i e t h y l - 1 3 - a c e t o x y - 2 , 2 ' - q u i n o t e t r a c a r b o c y a n i n e
DaQTeC
iodide
2-(p-dimethylaminostyryl)-benzothiazolylethyl
DASBTI
A b b r e v i a t i o n s u s e d i n C h a p t e r 3:
M a e d a , M. (1984). Laser Dyes. A c a d e m i c Press, N e w York.
D r e x h a g e , K . H . ( 1 9 7 7 ) . S t r u c t u r e a n d P r o p e r t i e s o f L a s e r D y e s . In D y e L a s e r s ( S c h ä f e r , F.P., e d . ) . S p r i n g e r - V e r l a g , N e w Y o r k , p p . 1 4 4 - 1 9 3 .
B i r g e , R.R. ( 1 9 8 7 ) . K O D A K L a s e r D y e s . K O D A K P u b l i c a t i o n J J - 1 6 9 . E a s t m a n K o d a k C o m p a n y , R o c h e s t e r , N.Y.
References:
Notes:
(CH 2) 4S0 3Na