Mechanical properties of nano SiO2 filled gypsum particleboard

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Trans. Nonferrous Met. SOC.China 16(2006)~361-s364

Mechanical properties of nano S i 0 2 filled gypsum particleboard LEI Wen(@ *)I, DENG Yu-he(%3$l)2, ZHOU Mei(M XUAN Ling@ @)', FENG Qian(P3 %)3

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1.College of Information Science and Technology, Nanjing Forestry University, Jiangsu 2 10037, China; 2.College of Wood Science and Technology, Nanjing Forestry University, Jiangsu 2 10037, China; 3.College of Mechanic Engineering, Nanjing Forestry University, Jiangsu 2 10037, China Received 10 April 2006; accepted 25 April 2006 Abstract: Nano SiOz was filled into gypsum particleboard. Effect of the amount of nano SiO2particles filled, ultrasonic dissipating duration and treating the nano particles with different coupling agents on the mechanical properties of the board were studied respectively. The results show that nano SiOz is helpful for the improvement of the properties. Adding 3%(mass fraction) nano SiOz is the best for the improvement of both modulus of rupture(M0R) and modulus of elasticity(M0E) of the boards formed at 30 "C or 40 "C. For the boards formed at 30 "C, their MOR and MOE can be improved by 8.77% and 12.24%, and MOR and MOE of the boards formed at 40 "C can be improved by 44.44% and 108.38%.3% is also the best addition proportion to improve internal bond(1B) of the boards formed at 30 C , while 5% is the best for that of the boards formed at 40 "C. At room temperature, dissipating nano SiOz into flake by ultrasonic has better effect on the properties of the final products. Through ultrasonic treating for 1 h and the best treating duration, the MOR and MOE can be increased by 41.99% and 47.80%. In addition, different coupling agents have different effects on the final properties too, and silane coupling agent KH570 is better for the improvement of properties of the boards formed at room temperature.

Key words: nano SiOz:gypsum particleboard; rupture modulus; elastic modulus; internal bond

1 Introduction Gypsum particleboard, as a new kind of green building material, has many advantages such as no formaldehyde emission, fire retardancy, heat-resistance, light mass, high efficiency to produce[l], it is used widely and has attracted much attention since it appeared[2]. But the lower strength than that of the boards bonded by synthetic polymer limits its applications. Nan0 particle is a kind of particle which is at least smaller than 100 nm in one dimension, it has also attracted much attentions of material researchers and manufacturers because of its many advantages over conventional large sized particles[3-51. Nano-Si02 has been added to polymer to increase its strength, flexibility and aging resistance[6, 71. In consideration of nanoparticles with many novel properties and significant improvement on some properties of materials mixed with

nanoparticles[8, 91, the effect of nano-Si02 in improving the mechanical properties of gypsum particleboards was studied. The effects of treating duration by ultrasonic, kinds and amount of coupling agents used to enhance the bonding between nano particles and flake and the proportion of nano particles to flake on the properties of the boards were investigated.

2 Experimental Tap water was poured into an ultrasonic cleansing device to a referred level, then nano SiO2 was put into the water and the nano particles were stirred together with water by hand homogeneously, the ultrasonic device was turned on and kept at work for 15 min, some weighed flake was added into the device after the water solution hade been cooled down for 30 min. After stirred homogeneously by hand, the equipment was turned on again to treat the mixture of nano particles and flake in the water for 30 min, another 30 min was necessary for

Foundation item: Project (3037 1130) supported by the National Natural Science Foundation of China Corresponding author: LEI Wen; Tel: +86-25-81777389; E-mail: [email protected]

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LEI Wen, et al/Trans. Nonferrous Met. SOC.China 16(2006)

cooling the water solution once more, then the solution should be ultrasonic treated continuously or cooled for 30 min alternatively. The total treating time was decided by requirement. In order to enhance the bonding between nano Si02 particles and flake, two kinds of coupling agents, i.e, titanated NDZ401 and silane KH570 were selected to treat the surface of the nano particles by mixing each one with the particles in a proper proportion very quickly and then sealed for 24 h before ultrasonic treatment. Gypsum particleboards are formed by weighing proper amount of flake with or without nano particles, gypsum and other additives, mixing them homogeneously and then compressing under a pressure of 3 MPa at a designed temperature for a definite time. The amount of raw materials used for each board is decided by the apparent density of the board. All the mechanical properties including MOR,MOE and IB are measured according to Chinese national standards.

where R is the relative property; PI is the property including MOR,MOE and IB of any particleboard; Po is the property of pure gypsum particleboard which is formed from original flake and gypsum, neither any nano SiOz particles is filled nor the flake is ultrasonic treated.

Fig.1 TEM micrograph of nano SiOz (Presented by Nanjing Haitai Nano-particle Co Ltd)

Fig.2 SEM micrograph of original flake

3 Results and discussion 3.1 Effect of duration of ultrasonic treatment on mechanical properties of gypsum particleboards The nano SiOzused in this study is spherical (Fig. 1) whose diameter is 10-20 nm. The flake has much damage in processing, as shown in Fig.2. When the nano particles are treated together with flake by ultrasonic, the particles can be dissipated into the damaged part and even the inside of the flake(Fig.3). In order to study the effect of the duration of ultrasonic treatment on the mechanical properties of gypsum particleboards, three different durations, i.e, 30 min, 60 min and 90 min are selected. Actually, the duration of treatment by ultrasonic has effect on both the MOR and MOE of the nano Si02 filled gypsum particleboards, as shown in Fig.4. From Fig.4, it can be concluded that treating the mixture of nano Si02 and flake by ultrasonic can get higher relative values of MOR and MOE, and when the duration of ultrasonic treatment is 1 h, MOR and MOE can be improved to a maximum extent by 41.99% and 47.80% respectively compared with the properties of those boards without being ultrasonic treated. The main reason may lie in the adequate structural alternation of the flake because of the high frequency from ultrasonic,

Fig3 SEM micrograph of nano filled flake

. *-Relative MOR =-Relative MOE *

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Duration of ultrasonic treatmendmin Fig.4 Effect of duration of ultrasonic treatment on properties of nano SOz filled gypsum particleboards

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the change allows the fine nano particles to enter the inside of the flake, as a result, the flake is reinforced, and the mechanical properties of the board are improved accordingly. The duration of ultrasonic treatment is 60 min may be the best duration for the structural change, 30 min is too short for the structure to change enough, while 90 min is too long and may destroy the-structure more heavily.

3.2 Effect of amount of nano-Si02 filled on mechanical properties of gypsum particleboards Figs.5-7 show the changes of relative MOR,MOE and IB with the proportion of nano Si02 added into the gypsum particleboards formed at 30 "C and 40 "C. All the relative mechanical properties including relative MOR,MOE and IB can be improved when nano Si02 is used in compressing the boards. As for the relative MOR and MOE, 3% of nano SiOz may be the best addition for their improvement. MOR for the boards pressed at 30 'C and 40 "C can be increased by 8.77% and 44.44% from those boards without nano SiOz,and MOE increases by 12.24% and 108.38% compared with those of boards without any nano particles.

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0 a 1 2 3 4 5 Proportion of nano particles to flake/% Fig.6 Variation of relative MOE of board with proportion of nano particles to flake

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Fig.5 Variation of relative R,, nano particles to flake

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Fig.7 Variation of relative IB of board with proportion of nano particles to flake

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However, the best proportion for the improvement of IB differs from each other for those boards formed at 30 'C and 40 C , 3% is the best for the board formed at 30 C ,IB will be increased by 16.67%, while 5% is the best for the board formed at 40 C ,in this situation, IB can be increased by 50%.

3.3 Effect of treating nano SiOz by coupling agents on mechanical properties of gypsum particleboards Coupling agent is a kind of compound which has two parts. One is hydrophilic, and the other is hydrophobic. It is often used to improve the adhesion between inorganic particles and organic matrix[ 101. Nan0 SiOz is a typical kind of inorganic particles, while flake should be organic because there are much

cellulose, semi-cellulose and lignin-cellulose, coupling agent may be good for the adhesion between nano SiOz and flake. In this study, titanated coupling agent NDZ 401 and silane coupling agent KH570 are selected to treat nano-Si02 by quick mixing in related solvents. Then the treated nano particles are dissipated into flake by 5% in mass fraction. Figs.8 and 9 show the effects of the mass fraction of coupling agent to nano Si02 on the relative MOR and MOE of gypsum particleboads. From these two figures, it can be seen that whether it is KH570 or NDZ401 treating nano S i 0 2 with coupling agent, it 1201

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I I I I 2 3 Proportion of NDZ401 to nano particles/%

Fig.8 Variation of relative properties of board with proportion

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is of NDZ401 to nano SiOzgood for the improvement of MOR and MOE, though no definite tendency appears. And generally, KH570 has better effect on the mechanical properties than NDZ401. Yet this effect is not so great as that of the duration of ultrasonic treatment and the addition proportion of nano-SiOzdo.

the improvement of the mechanical properties of gypsum particleboard by adding nano SiOz may be described as follows: high frequency of ultra-sonic makes it possible for the fine nano particles to enter the inside of flake , the flake is reinforced accordingly. And the bonding between nano SiOz and flake may also have effect on the strength of the final board. In other words, the reason for the improvement of the mechanical properties of gypsum particleboard with the addition of nano SiOzmainly lies in the increase of strength of flake, not in the improvement of bonding between flake and gypsum. Certainly, the details of the mechanism are not available yet, more studies should be camed out in the future.

References

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Proportion of KH570 to nano particles/% Fig.9 Variation of relative properties of board with proportion of KH570 to nano SiOz

4 Conclusions 1) Treating the mixture of flake and nano SiOz by ultrasonic has a positive effect on the mechanical properties of the gypsum particleboards. And 1 h is the best duration for the treatment. When the mass fraction of nano-Si02 to flake is 5%, MOR and MOE of the board can be improved by 41.99% and 47.80% respectively after 1 h treating. 2) Addition of nano Si02 can increase the values of MOR, MOE and IB of gypsum particleboards formed at 30 'C or40 'C. 3) Treating nano Si02 with coupling agents is also helpful for the improvement of the mechanical properties of the gypsum particleboards, but the effect not only does not have a definite tendency but also may differ from the kind and amount of the coupling agent. Generally, KH570, a silane coupling agent, is better for the improvement. 4) Based on the testing results, the mechanism for

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