Metric and English Units and Unit Analysis

Metric and English Units and Unit Analysis

C H A P T E R 16 Metric and English Units and Unit Analysis 16.1 METRIC UNITS The metric system (called SI from the French for systeme internationale...

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C H A P T E R

16 Metric and English Units and Unit Analysis 16.1 METRIC UNITS The metric system (called SI from the French for systeme internationale) is the common system used in the scientific literature to describe measurements. All measurements can be derived from the seven base units and two supplementary units shown in Table 16.1. As the US pulp and paper industry (unfortunately!) uses English measurements extensively, some of the base SI units are given in terms of their approximate English system equivalents. Because only seven fundamental units are used in the metric system, it is extremely easy to use in problem-solving. Even when going from English to English units, it is sometimes helpful to use metric units as intermediates. The multipliers that are used as prefixes before the units are given in Table 16.2. Here the English equivalents of the multipliers greater than one are given. Complex measurements are combinations of the base units. For example, area is derived from length and is actually length2 such as m2; volume is also derived from length and is length3 such as m3; density is derived from mass and volume with units such as kg/ m3 or g/cm3. Table 16.3 gives the list of derived SI units that have special names. Table 16.4 gives some values of the universal constants that are used in various aspects of

Biermann's Handbook of Pulp and Paper: Paper and Board Making https://doi.org/10.1016/B978-0-12-814238-7.00016-7

engineering and science. Table 16.5 gives some additional metric-based units with special names that have traditional use. In the following section, the numerous English units will be presented with conversion factors to metric units. Also, the relationships between many of the English units are presented.

16.2 ENGLISH AND METRIC UNITS Tables 16.6 and 16.7 are designed to define most commonly encountered English units in pulp and paper without having unnecessary conversion factors for all of the possible derived units. For example, if one knows the conversion factor for cm to in. then cm2 can be converted to in.2 and cm3 to in3. Similarly, gal/min can easily be converted to mL/s if one has a conversion factor for gallons to milliliters (or liters) and knows there are 60 s in a minute. The technique for this is shown in Section 16.3. Table 16.8 gives units for paper analysis. Table 16.9 gives DIN format sizes of paper. Tables in this chapter include as follows: 16.1. Base units of the metric system. 16.2. Prefix units with corresponding multipliers for SI units. 16.3. Derived SI units with special symbols and names.

349

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350 TABLE 16.1

16. METRIC AND ENGLISH UNITS AND UNIT ANALYSIS

Base Units of the Metric System

Base Quantity

SI Unit

Symbol

Equivalent English Units

Length

Meter

m

39.3701 in.

Mass

Kilogram

kg

2.2046 lb (g ¼ 1.00)

Time

Second

s

s

Temperature

Kelvin

K

K ¼ (5/9)$( F32) þ 273.15

Amount by number

Mole

mol

6.0220  1023

Electric current

Ampere

A

6.2422  1018 electrons/s

Luminous intensity

Candela

cd

Plane angle

Radian

rad

360 degrees/2p ¼ 57.296 degrees of a circle

Solid angle

Steradian

sr

360 degrees/2p ¼ 57.296 degrees of a sphere

SUPPLEMENTARY UNITS

16.4. Table of universal constants. 16.5. Other metric units with special names. 16.6. Fundamental and derived English units with special names and their conversion factors. 16.7. Common compound units with conversion factors. 16.8. Paper analysis conversion factors. 16.9. DIN format sizes of paper. Japan, China, and many European countries use the DIN standards for paper size. DIN is an acronym for Deutsche Industrie Normen, which might be thought of as the German Industry Standard. The standard-sized sheet for a particular DIN series is indicated by a capital letter such as A, B, C, or D. The A series is usually used for printing and writing papers. Envelopes, file folders, and so on use the B and C series. The standard sheet size of a series is indicated by 0 such as A0. Subsequent designations within a series are indicated by the number of folds needed to make the sheet. For example, Al is defined as a sheet of A0 folded in half. The base sheet of paper has a length to width ratio of (2)1/2:1, or approximately 1.414:1. As

TABLE 16.2

Prefix Units With Corresponding Multipliers for SI Units

Name

Symbol

Multiplier

deca

da

10

hecto

h

100

kilo

k

1000

M

6

Million

9

mega

10

English Equivalent

Thousand

giga

G

10

Billiona

tera

T

1012

Trillionb

peta

P

1015

Quadrillion

exa

E

18

10

deci

d

0.1

centi

c

0.01

milli

m

0.001

micro

m

10e6

nano

n

10e9

pico

P

10e12

femto

f

10e15

atto

a

10e18

a b

Quintillion

British define a billion as a million millions or 1012. British define a trillion as a million billions or 1018.

351

16.2 ENGLISH AND METRIC UNITS

TABLE 16.3

Derived SI Units With Special Symbols and Names

Quantity

Name

Symbol

Base Units

Other Units

Frequency

Hertz

Hz

(cycle) s1

Force

Newton

N

m kg s2

Pressure; stress

Pascal

Pa

m1 kg s2

N/m2

Energy; work; heat

Joule

J

m2 kg s2

Nm

SI UNITS WITH SPECIAL SYMBOLS

3

Power, radiant flux

Watt

W

m kg s

Electric charge

Coulomb

C

As

Electric potential

Volt

V

m2 kg s3 A1

Electric capacitance Electric resistance Electric conductance Magnetic flux

Farad

F

Ohm

U

Siemens Weber

S Wb

2

J/s

2

1 4

2

2

3

2

2

1 3

m kg

s A

m kg s m

kg

C/V

A

V/A 2

s A

2

2

m kg s 2

W/A

1

A

1

A/V Vs

Magnetic flux density

Tesla

T

kgs

A

Wb/m2

Inductance

Henry

H

m2 kg s2 A2

Wb/A

Luminous flux

Lumen

lm

cd sr

Luminous flux density

Lux

lx

m2 cd sr

Radionuclide activity

Becquerel

Bq

s1

Absorbed dose of ionizing radiation

Gray

Gy

m2 s2

lm/m2

J/kg

OTHER DERIVED SI UNITS Area

Square meter

m2

Volume

Cubic meter

m3

Speed, velocity

Meter per second

m/s

Acceleration

Meter per second squared

m/s2

Wave number

Per meter

m1

Concentration

Molarity

mol/m3 3

Density of mass

Kilogram per cubic meter

kg/m

Moment of force

Newton meter

Nm

Surface tension

Newton per meter

N/m

Specific heat capacity

Joule per kilogram kelvin

J/(kg  K)

mol/L g/L

352

16. METRIC AND ENGLISH UNITS AND UNIT ANALYSIS

TABLE 16.4

Table of Universal Constants

Constant

Symbol

Value

Avogadro constant

No

6.0220  1023 mol1

Gas constant

R

8.314 J mol1 K1 0.08206 L atm K1 mol1 62.37 L  Torr  K1 mol1

Faraday constant

F

96485 C mol1

Planck constant

h

6.6262  1034 Js

Speed of light (vacuum)

c

2.99792  108 m s1

Acceleration, gravity

g

9.80665 m s2 (by definition)

Pi

p

3.141592654

e

e

2.718281828

by keeping track of the units (mass, length, area or length2, density or mass/length3, time, etc.) of numbers to solve problems. By using this method, one can solve a wide variety of problems by memorizing very few things. All solutions to problems should show units throughout the solution to prevent “silly” oversights and to be considered correct; a number without the proper units is meaningless. In many of the examples throughout this book, conversion factors are listed for convenience. In other examples, it will be necessary to find conversion factors from the tables presented in this chapter. One important tip for solving word problems is that “of” usually implies multiplication, whereas “per” usually implies division. One straightforward application of unit analysis lies in multiplying a starting figure by conversion factors that are equal to unity (one) to convert the original number to new units. These conversion factors merely substitute one set of units for another set of units without making any changes in the quantity considered.

EXAMPLE 1 smaller sheets are defined by folding the larger sheet in half successively, the length to width of any sheet of paper will maintain the 1.414:1 ratio. The most common series is the A series where the base sheet is exactly 1 m2. Because the area and the ratio of the length to width are both stipulated, the base sheet is “forced” to have the dimensions of 0.841 m by 1.189 m. The A series in millimeters and inches is given in Table 16.8. If one knows the weight of a single sheet of A4, the basis weight in g/m2 can be determined by multiplying by 42 (or 16).

16.3 UNIT ANALYSIS Unit analysis (sometimes called dimensional analysis) is a powerful way of solving problems

You are a Canadian buying a car in the United States and the salesman tells you it gets 30 mi per gallon, but you are not really sure this is good gas mileage, as your point of reference is kilometers per L. Convert 30 mi/gal (mpg) to km/L.

Solution One realizes that both mi and km are units of distance and comparable, and that gallons and L are units of volume and comparable. We can look up conversion factors and find out that 1 mi ¼ 1.609 km and 1 gallon ¼ 3.637 L. Thus, we can take 30 mpg and multiply by appropriate conversion factors that cancel out the units we have and leave us with the units desired: 30

mi 1:609 km 1 gal km   ¼ 12:75 gal 1 mi 3:785 l l

353

16.3 UNIT ANALYSIS

TABLE 16.5

Other Metric Units With Special Names (Not SI)

Quantity

Name

Symbol

Base Units

Other Units

CGS SYSTEM OF DERIVED UNITS (USING BASE UNITS OF CM, G, AND S) Force

Dyne

dyn

cm g s2

105 N

Energy

Erg

erg

cm2 g s2

107 J

Viscosity

Poise

P

cm1 g s1

Kinematic viscosity

Stokes

St

cm s2

Acceleration, gravity

Gal

Gal

cm s2

Distance (obsolete)

Micron

m

mm

Distance (obsolete)

Millimicron

mm

Nm

Distance (obsolete)

Angstrom

A or Å

1010 m

MISCELLANEOUS

0.1 nm 2

0.01 km2

Area

Hectare

ha

10,000 m

Volume

Litera

1, L

0.001 m3

1000 cm3

Mass, metric ton

Tonne

t or MT

106 g

1000 kg 10

Radionuclide decay

Curie

Ci

3.7 10 Bq

Absorbed dose

Rad

rd

0.01 Gy

Exposure

Roentgen

R

2.58  104 C/kg

a

1 L of water weighs exactly 1 kg at 25 C; 1 mL is then 1 g.

One can use any conversion factor (with the correct units) that is equal to unity. For example, we could just as easily use 1 km ¼ 0.6215 mi and 1 L ¼ 0.2642 gal. 30

mi 1 km 0:2642 gal km   ¼ 12:75 gal 0:6125 mi 1l l

Of course, there are an infinite number of equally valid ways to achieve the same result. In the above case, one might remember the following: 1 mi ¼ 5280 ft 1 ft ¼ 12 in: 1 in. ¼ 2:54 cm 1 cm ¼ 0:00001 km 1 gal ¼ 3:785 L

Thus, within rounding error, the same result is achieved as follows: 30

mi 5280 ft 12 in: 2:54 cm 105 km     gal 1 mi 1 ft 1 in: 1 cm 1 gal km  ¼ 12:76 3:785 l l

To find a general conversion factor to convert mpg to km/L, start with 1 mpg as follows: 1

mi 1:609 km 1 gal km   ¼ 0:4521 gal 1 mi 3:785 l l

This is often abbreviated by saying “multiply mpg by 0.4251 to give km/L”; it is preferable,

354 TABLE 16.6

16. METRIC AND ENGLISH UNITS AND UNIT ANALYSIS

Fundamental and Derived English Units With Special Names and Their Conversion Factors to Other Units; the Reciprocal Is Listed for Reverse Conversions

Unit

Abbreviation

Multiplier

Other Unit

Reciprocal

doz

12

0.083333

Score

20

0.05

Gross

144

0.0069444

M

1000

0.001

mil

0.001

in.

1000

0.01

in.

100

DIMENSIONLESS VALUES Dozen

Thousand UNITS OF LENGTH Mil Caliber Inch

in.,00

2.54

cm

0.39370

Foot

ft,0

30.48

cm

0.032808

0.3048

m

3.2808

12

in.

0.083333

0.91440

m.

1.0936

3

ft

0.33333

36

in.

0.027778

Yard

yd

Fathom

fath

6

ft

0.16667

Rod

rod

16.5

ft

0.060606

Chain

ch

Gunter’s

66

ft

0.015152

Ramsden’s

100

ft

0.01

660

ft

0.0015152

1.6093

km

0.62137

5280

ft

0.00018939

1.852

km

0.53996

6076.1

ft

0.00016458

3

mi

0.33333

Kip

4448.2

N

0.00022481

Poundals

0.13826

N

7.2327

Furlong

fur.

Mile

mile, mi

Statute

Nautical

League Statute or nautical FORCE

355

16.3 UNIT ANALYSIS

TABLE 16.6

Fundamental and Derived English Units With Special Names and Their Conversion Factors to Other Units; the Reciprocal Is Listed for Reverse Conversionsdcont'd

Unit

Abbreviation

Multiplier

Other Unit

Reciprocal

acre

0.0015625

mi2

640

0.40469

ha

2.4711

UNITS OF AREA Acre

UNITS OF VOLUME Teaspoon, US

tsp

4.93

mL

0.20284

Tablespoon

Tbs

14.79

mL

0.067613

Ounce

oz 0.029574

L

33.814

0.5

qt

2

US liquid

0.94635

L

1.0567

US dry

1.1012

L

0.98794

British

1.1365

L

0.87988

gal

4

qt

0.25

pk

8

qt

0.125

Bushel

bu

32

qt

0.03125

Barrel

bbl

42 (petroleum)

gal (US liquid)

0.023810

fbm

0.083333

ft3

12

US fluid

oz

a

Pint

Quart

qt

a

Gallon a

Peck

a

WOOD, VOLUMETRIC Board foot Cord, stacked wood

cd

Unit, usually chips Cunit, solid wood

128

ft

2400

lb, dry

100

Stere

3

ft

3 3

0.0078125 0.00041667 0.01 1

1

m

64.799

mg

0.015432

0.2

g

5

Avoirdupois

28.350

g

0.035274

Troy (for gold)

31.103

g

0.032151

453.59

g

0.0022046

2000

lb

0.0005

b

UNITS OF MASS Grain Carat, metric

c

Ounce

oz

Pound Avoirdupois Ton (short ton)

lb, #

(Continued)

356 TABLE 16.6

16. METRIC AND ENGLISH UNITS AND UNIT ANALYSIS

Fundamental and Derived English Units With Special Names and Their Conversion Factors to Other Units; the Reciprocal Is Listed for Reverse Conversionsdcont'd

Unit

Abbreviation

Multiplier

Other Unit

Reciprocal

2240

lb

0.00044643

2204.6

lb

0.00045359

1000

kg

0.001

1.0133$105

Pa

9.8692$106

760

mm of Hg

0.0013157

14.696

psi

0.068046

33.899

ft water

0.029450

29.921

in. Hg

0.033421

1.0332

Technical atm

0.96787

psi

6894.8

pascal

0.0001450

Minute

min

60

s

0.016667

Hour

hr, h

60

min

0.016667

3600

s

0.00027778

24

h

0.041667

7

d

0.14286

168

h

0.59524

d

0.0027379

3.1558$10

s

3.1688$108

kn

1.852

km/h

0.53996

cal

4.1868

J

0.23885

4.184

J

0.23901

1055.1

J

0.00094782

252.00

cal

0.0039683

0.00029307

kWh

3412.1

kWh

3.6

MJ

0.27778

hp

746

J/s

0.0013405

550

ft-lb/s

0.0018182

Ton (long ton) Metric ton, tonne

t, MT

UNITS OF PRESSURE Atmosphere

psi (lb/sq in)

atm

UNITS OF TIME

Day Week

Year (solar)

wk

yr

365.25 7

UNITS OF VELOCITY Knot Units of energy Calorie, International (Thermochemical) British thermal unit

Btu

(International)

Kilowatt-hour UNITS OF POWER Horsepower

357

16.3 UNIT ANALYSIS

TABLE 16.6

Fundamental and Derived English Units With Special Names and Their Conversion Factors to Other Units; the Reciprocal Is Listed for Reverse Conversionsdcont'd

Unit

Abbreviation

Multiplier

Other Unit

Reciprocal

2p

rad

0.15915

ANGULAR VALUES Circumference Degree

deg

0.017453

rad

57.296

Minute

min’

0.016667

deg

60

sec00

0.016667

min

60

Fahrenheit

F

0.55556

C

1.8

1

Rankine

1

Celsius

C

1

K

1

Second C

TEMPERATURE INTERVALS

or K

Less than five significant figures indicate exact to at least six significant figures. a The British pint, gallon, peck, and bushel are made up of 0.5, 4, 8, and 32 British quarts, respectively, whereas the US pint, gallon, peck, and bushel have the same number of US dry quarts. 1 US liquid gallon of water has a weight of 8.349 lb. There are 7.4805 gallons per ft3, and 1 ft3 of water weighs 62.45 lb. b Most English units of “mass” such as the pound (except the slug that really is mass) are really measures of weight at the earth’s surface. The mass of an object is constant; the weight depends on the acceleration of gravity. The English units are commonly set equal to SI mass units, although this is not strictly correct. c Temperature scale conversions are as follows: F ¼ 9/5 C þ 32 degrees;  C ¼ K  273.15 degrees; Rankine ¼ 9/5 K ¼  F þ 491.67.

TABLE 16.7

Common Compound Units With Conversion Factorsa

Compound Unit

Abbreviation

Multiplier

Other Unit

Reciprocal

in.2

6.4516

cm2

0.15500

UNITS OF AREA inch2 2

foot

2

mile

2

ft

0.0929

2

m

10.764

2

2

mi

2.5898

km

0.38613

in.3

16.387

cm3

0.061024

UNITS OF VOLUME inch3 3

foot

3

ft

3

0.028317

m

35.314

0.016018

g/cm3

62.428

3

UNITS OF DENSITY OR CONCENTRATION lb/ft3 lb/US liquid gallon

0.11983

g/cm

8.3454

119.83

g/1

0.0083454

ENERGY Horsepower-hour

hp-hr

0.746

kWh

1.3405

Horsepower-day

hp-day

17.904

kWh

0.055853

Kilowatt-hour

kWh

3.6

MJ

0.27778 (Continued)

358

16. METRIC AND ENGLISH UNITS AND UNIT ANALYSIS

TABLE 16.7

Common Compound Units With Conversion Factorsadcont'd

Compound Unit

Abbreviation

Multiplier

Other Unit

Reciprocal

Btu/lb

2.3260

kJ/kg

0.42991

psi

6894.8

pascal

0.00014504

mph

0.44704

m/s

2.2369

SPECIFIC ENERGY Btu per pound PRESSURE lb/sq in VELOCITY, SPEED Miles per hour a

All of these conversion factors could be derived from information in the previous tables; they are presented here as a reference tool.

but alas not common, to indicate “multiply mpg by 0.4251 gal km mi1 L1 to give km/L.” The difference is that 0.4251 is not equal to 1.000 (unity); however, the term 0.4251 gal km mi1 L1 is equal to unity.

Unit analysis is very important when using equations. The units of the answer must be appropriate for those used in the equation; in short, they must match. There are often difficulties in unit analysis in pulp and paper because units may be mixed between English and metric, or even unmatched within either system.

EXAMPLE 2 The basis weight of one type of linerboard is 79 lb/1000 ft2. Convert this to g/m2.

Solution This involves two conversion factors to get appropriate units. Notice how the conversion factor for area is derived by squaring the linear conversion factor. Instead of squaring the numerator and denominator separately, the entire fraction could be squared; the result, of course, is the same as (a/b)2 ¼ a2/b2. 79

lb ft

 2

453:6 g ð1 ftÞ2 g ¼ 38:6 2  2 1 lb m ð0:3048 mÞ

Exercise In Table 16.8, the conversion factor for basis weight in terms of lb per 17 in. by 22 in. printing ream (500 sheets) to g/m2 of individual paper sheets is given as 3.7597; show how this factor is derived.

EXAMPLE 3 Velocity (v) is equal to distance (s) traveled divided by the time (f) it took to travel that distance ðv ¼ s=t ¼ s  t1 Þ Suppose we know that 60 mi per hour is equal to 26.82 m per s. Does a paper machine that travels 140 ft in 2 s travel faster or slower than this? s ¼ v=t ¼ 140 ft=ð2 sÞ ¼ 70 ft=s The units of the answer are not directly comparable, but we can compare the results after the use of conversion factors. ft 1m m  ¼ 21:3 or s 3:281 ft s ft 3600 s 1 mi mi  ¼ 47:7 70  s 1h 5280 ft h

70

In either case, whether we convert ft/s to m/s or mi/hr, one obtains values that are comparable with (and less than) the original speeds given.

359

16.3 UNIT ANALYSIS

TABLE 16.8

Paper Analysis Conversion Factors

Compound Unit

Type

Multiplier

Other Unit

Reciprocal

3.7597

g/m2

0.26598

3.0836

2

0.32429

2

0.36981

2

0.43808

2

0.53196

2

0.45604

2

0.61445

2

0.67561

1.4061

2

g/m

0.71117

4.8824

g/m2

0.20482

1.6275

2

0.61445

BASIS WEIGHT IN LB PER REAM OF 500 SHEETS 17 in. by 22 in.

Printing

19 in. by 24 in.

Blotting

20 in. by 26 in.

Cover

22 in. by 28 in.

Cardboard

22 in. by 34 in.

2.7041 2.2827 1.8799

22.5 in. by 28.5 in. 24 in. by 36 in.

Bristol News

25 in. by 38 in.

Book

25 in. by 40 in.

Old standard

2.1928 1.6275 1.4801

g/m g/m g/m

g/m g/m

g/m g/m

BASIS WEIGHT BY SHEET AREA lb/1000 ft2

Paperboard

2

ISO

lb/3000 ft

g/m

SELECTED PAPER TESTS (TO FOUR SIGNIFICANT FIGURES) lb/in2

Burst 2

2

(gf/cm )/(g/m )

Burst index

in

Caliper

lb 2

lb/in.

6.895

kPa

0.09807

kPa.m  g

25.40

0.1450 2

1

10.20

mm

0.03937 0.2248

Concora crush

4.448

N

Flat crush

6.895

kPa

0.1450 2

ft-lb/in.

Internal bond

2.102

kJ  m

0.4758

lb

Ring crush

4.448

N

0.2248

mg/

Stiffness, Gurley

0.009807

mN

102.0

Stiffness, Taber

2.03

mN

2

Taber units

0.493 1

100gf  m /g

Tear index

0.09807

mN$m  g

10.20

gf

Tear strength

9.807

mN

0.1020

2

kgf/(15 mm)

Tensile strength

6.538

1

kN  m

1

0.1530

lb/in.

Tensile strength

0.1751

kN-m

5.710

gf  cm

Toughness index

0.09807

mJ

10.20

360

16. METRIC AND ENGLISH UNITS AND UNIT ANALYSIS

TABLE 16.9

DIN Format Sizes of Paper Length, Metric Dimensions

Width, Millimeters

Length, English Dimensions

Width, Inches

A0

1189

841

46.82

33.11

Al

841

595

33.11

23.41

A2

595

420

23.41

16.55

A3

420

297

16.55

11.70

A4

297

210

11.70

8.28

A5

210

149

8.28

5.85

A6

149

105

5.85

4.14

A7

105

74

4.14

2.93

A8

74

53

2.93

2.07

1414

1000

55.68

39.37

1297

917

51.06

36.10

Designation A SERIES

a

B SERIES B0 C SERIES C0 a

This is the standard letter size that corresponds to the English system 8.5 in. by 11 in. sheet.

EXAMPLE 4

EXAMPLE 5

Use Table 2.2, Volume 1 to determine an approximate conversion factor of cords to units.

The relationship for converting mass into energy is the famous equation of Albert Einstein, E ¼ mc2. Although this is applicable to any change of energy, it is usually applied to nuclear reactions where very large amounts of energy are released. In normal chemical reactions, the changes in mass are minuscule. For the sake of argument, assume one could completely convert coal into energy via a nuclear reaction. How many horsepower-days of energy would be produced from 1 g of coal?

Solution As a direct relationship is not available, two relationships are used in series. 3:62 m3 stacked wood 1 cord 1 unit ¼ 1:10 units  3:28 m3 stacked wood

1 cord 

c ¼ speed of light in a vaccum ¼ 3  108 m=s: hp ¼ 746 J=s;

thus 1:00 hp  s ¼ 746 J

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EXERCISES

Solution (Note that if one were to try to solve this problem in English units one might be tempted to use the units of lb; however, lb are a unit of weight, not mass, and this would lead to incorrect results. This is just one of many advantages to the metric system.) Because energy is in units of joules, which in turn is units of m, kg, and s, it is convenient to solve as follows:  m2 kg$m2 E ¼ 0:001 kg  3$108 ¼ 9$1013 2 ¼ 9$1013 J s s 9$1013 J 

1 hp$s 1h 1d   ¼ 1; 396; 000 hpd 746 J 3600 s 24 h

The amount of energy generated is enough to keep a 4000 hp motor operating for almost 1 year. This calculation indicates the tremendous amounts of energy released in nuclear reactions. Although coal is not converted to pure energy on the face of the earth, nuclear reactions can occur. For example, 1 mol (235.0439 g) of uranium-235 decomposes (fission) to form 234.8286 g of products, while 0.2153 g of mass is converted to energy. Analogously, 140.4634 g of hydrogen can be fused (fusion) to form 139.4635 g of helium, while 1.000 g of mass is converted to energy. The larger amount of energy given off, and the high availability of hydrogen and deuterium makes fusion a very good potential source of energy, although the conditions required for fusion reactions are extremely difficult to obtain under controllable conditions. For this reason, fusion has not been used as an energy source to generate electricity. Energy of nuclear reactions is given off as heat. About 30% of the heat energy is converted to electricity.

EXAMPLE 6 How much work in horsepower is accomplished by pumping 3000 gallons (22,500 lb) of water per minute up to 70 vertical ft (equal to a pressure of 30 psi)?

Solution The horsepower is a rate of energy. One horsepower is the work accomplished by lifting 550 lb one-ft high (perpendicular to gravity) per s. This is equal to 33,000 ft-lb per minute. The work required to lift 3000 gallons of water every minute a height of 70 ft is easily converted to ft-lb of work. This is about the amount of work the primary fan pump must accomplish for a paper machine that produces 80 tons/day with a speed of 4000 ft/ min. 22400 lb  71 ft 

1 hp ¼ 47:4 hp 33000 ft$lb

EXERCISES 1. Calculate the number of gallons of paint required to paint the walls of a room 6 m by 8 m by 3.25 m high with a dry paint thickness of 0.1 mm. Use these conversion factors: 1 gal paint ¼ 0.30 gallons solids when dry 1 gal ¼ 3.785 L 1 L ¼ 0.001 m3 1 m ¼ 100 cm One approach is to calculate the wall area to be painted. Convert this to the volume of dry paint (surface area times thickness) in a separate calculation, then convert to wet paint gallons. The details remain.

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2. Refining energy is often reported in units of horsepower-days/ton; however, one buys electricity by kW hours. Convert hp-days/ton to kWh/ton. 3. Derive a conversion factor to convert Btu/hr to watts. 4. Derive a conversion factor to convert lb/(24 in. by 36 in. ream) to g/m2 of a single sheet of paper. Remember one ream has 500 sheets, 1 lb is 453.59 g, and 1 cm is 2.54 in. 5. Derive a conversion factor for kg-s-m2 to A/mol.

6. A certain type of paper is 78 lb/3000 ft2 with a thickness of 0.009 in. What is its density? 7. How many s would a 1 A flow of current take to move 1 mol (6.0220  1023 of electrons? 8. Keeping in mind that 1 W is 1 J/s, if electricity is $0.10 per kW h, how much is the energy generated by 1 g of mass (Example 5) worth? 9. If a mill makes 1000 tons/day of paper and a certain additive worth $1.15/lb is used at 0.03% on paper, how much will this mill spend on this additive in 1 year?