Journal Pre-proof New constraints on the tectono-magmatic evolution of the central Gangdese belt from Late Cretaceous magmatic suite in southern Tibet
Yuanku Meng, M. Santosh, Guangzhou Mao, Peijun Lin, Jinqing Liu, Peng Ren PII:
S1342-937X(19)30304-1
DOI:
https://doi.org/10.1016/j.gr.2019.10.014
Reference:
GR 2246
To appear in:
Gondwana Research
Received date:
27 June 2019
Revised date:
14 October 2019
Accepted date:
27 October 2019
Please cite this article as: Y. Meng, M. Santosh, G. Mao, et al., New constraints on the tectono-magmatic evolution of the central Gangdese belt from Late Cretaceous magmatic suite in southern Tibet, Gondwana Research(2019), https://doi.org/10.1016/ j.gr.2019.10.014
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© 2019 Published by Elsevier.
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New constraints on the tectono-magmatic evolution of the central Gangdese belt from Late Cretaceous magmatic suite in southern Tibet Yuanku Menga,b*, M. Santoshc,d,e, Guangzhou Maoa*, Peijun Linf, Jinqing Liua,b, Peng Reng a
College of Earth Science and Engineering, Shandong University of Science and
of
Technology, Qingdao 266590, China b
ro
Laboratory for Marine Mineral Resources, Qingdao National Laboratory for Marine Science and Technology, Qingdao 266061, China
c
-p
School of Earth Sciences and Resources, China University of Geosciences (Beijing),
re
Beijing 100083, China d
Department of Earth Sciences, University of Adelaide, Adelaide SA 5005, Australia
e
lP
Yonsei Frontier Lab, Yonsei University, Seoul 03722, Republic of Korea
f
China g
na
Testing center of Shandong Bureau of China Metallurgical Geology Bureau, Jinan 250014,
Abstract
Jo ur
Chang’An University, Xi’an 710064, China
In the Gangdese magmatic belt of southern Tibet, widespread Late Mesozoic
magmatism
has
been
reported,
although
their
petrogenesis and tectonic evolution remain ambiguous. Here we present new zircon U-Pb and geochemical data on a gabbro-diorite suite near the Namling County in the central Gangdese belt, that provide insights into the geodynamic processes in this region. Zircon U-Pb data from LA-ICP-MS and SHRIMP II analyses
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indicate that the granite crystallized at ca. 87 Ma, and the gabbro-diorite suite was emplaced at ca. 91-95 Ma, both suggesting an early Late Cretaceous magmatism in the central Gangdese belt. The gabbro-diorite suite displays wide ranges of SiO2 (57.21-44.25 wt. %) and MgO contents (9.04-3.18 wt. %), with
of
high Al2O3 (21.47-16.14 wt. %) and Na2O/K2O (1.10-5.84) values. Compared to these, the granite rocks show limited variations of
ro
SiO2 (76.97-76.40 wt. %), high Na2O+K2O (8.84-8.04 wt. %),
values
and
significant
re
(30.77-20.39)
-p
K2O/Na2O (2.33-1.30) and Sr/Y (48.99-80.36), with low Mg# Eu
anomalies
lP
(Eu/Eu*=1.20-0.24). The gabbro-diorite rocks are characterized by
na
typical arc-type features including enrichment of light rare earth elements (LREE) (LaN/YbN=11.52-5.06>1) and large ion lithophile
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elements (LILE) (e.g. Cs, K and Rb), but are depleted in high strength field elements (HSFE) (e.g. Nb, Ta, Ti and P). The granitic rocks are also enriched in LREE (LaN/YbN=55.42-26.55>1) and LILE (e.g. Cs, Rb, K and Pb), but depleted in HSFE (e.g. Nb, Ta, Ti and P). The gabbro-diorite rocks show distinctly positive εNd(t) (+3.5 to +4.2)
and εHf(t) values (+8.5 to +15.6) values with a restricted
range, with relatively homogeneous and low (87Sr/86Sr)I ratios (0.704213-0.703820). The granitic rocks also show positive εNd(t) values
(+4.1
to
+4.4)
and
consistent
(87Sr/86Sr)I
ratios
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(0.703977-0.703180). Our data suggest that the gabbro-diorite rocks were mostly sourced from partial melting of the depleted mantle that was metasomatized by fluids released from the subducted Neo-Tethys oceanic slab. The granite was probably produced by partial melting of the juvenile crust with no
of
participation of mantle material. We correlate the magmatism with tectonics associated with the roll-back of the Neo-Tethys oceanic
Gabbro-diorite
suite;
Granite
dike;
Zircon
re
Keywords:
-p
ro
slab during the early Late Cretaceous.
na
1. Introduction
lP
geochronology; Geochemistry; Gangdese magmatic belt.
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The Cretaceous tectono-magmatic events in southern Tibet have been correlated to northward subduction of the Neo-Tethys oceanic slab beneath the Lhasa terrane (e.g. Yin and Harrison, 2000; Zhu et al., 2011; Zhang et al., 2014a; Meng et al., 2019). However, the petrogenesis and geodynamic setting of the early Late Cretaceous (100~80 Ma) magmatic suites in this region remain debated. Some studies suggest that the early Late Cretaceous magmatism was associated with the mid-oceanic ridge subduction of the Neo-Tethys Ocean (e.g. Guan et al., 2010; Meng et al., 2010; Zhang et al., 2010; Guo et al., 2013; Zhu et al., 2013;
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Wu et al., 2018), whereas other workers invoke the rollback of the Neo-Tethys oceanic slab to explain the magmatic activities in the Gangdese belt (e.g. Ma et al., 2013a, b, 2015, 2017a; Xu et al., 2015; Meng et al., 2019). Alternate models include flat slab subduction (e.g. Wen et al., 2008a, b), normal-angle northward
of
subduction (Ji et al., 2009) and high-angle oblique subduction (Wang et al., 2013). Previous models on the petrogenesis of early
ro
Late Cretaceous adakite-like rocks in this region include: (1) partial
-p
melting of thickened juvenile crust (e.g. Wen et al., 2008b; Guan et
re
al., 2010; Ma et al., 2013b; Ji et al., 2014); (2) partial melting of
lP
subducted oceanic slab (Zhang et al., 2010; Jiang et al., 2014); and
na
(3) differentiation of mafic magmas (Wang et al., 2013; Xu et al., 2015; Meng et al., 2019).
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Compared to the eastern Gangdese belt, the early Late Cretaceous gabbroic rocks in the central belt are poorly studied. Therefore, with a view to delineate the geodynamic setting of the mantle magmatism in the central Gangdese region, we investigate a suite of magmatic rocks in the Shanba area of the Namling County (study area), including gabbro, diorite and granite. We present petrologic, geochronological, whole-rock geochemical and Sr-Nd-Hf isotope dataset for the diorite-gabbro suite and the accompanying granitic rocks with a view to evaluate the magma
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petrogenesis and tectonic setting. Our results provide new constraints on the early Late Cretaceous tectono-magmatic evolution in southern Tibet.
2. Geological background and sample description 2.1 Geological background
of
The Himalayan-Tibetan plateau is mainly composed of Himalaya, Lhasa, Qiangtang, Songpan-Ganzi and Qaidam-Kunlun
ro
terranes, which are separated by well-defined sutures (e.g. Yin and
-p
Harrison, 2000) (Fig.1a). The Lhasa terrane, located between the
re
Indus-Yarlung Tsangpo suture zone (IYSZ) and Bangong-Nujiang
lP
suture zone (BNSZ), was considered as a remnant drifted from
na
Gondwana continent during the Permian (e.g. Zhu et al., 2011; Pan et al., 2012). Based on the distribution of regional faults and
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ultra-high pressure (UHP) rocks, as well as Hf isotope features, Zhu et al. (2011) and Hou et al. (2015) suggested that the Lhasa terrane can be divided into three segments, namely the northern Lhasa, the central and the southern Lhasa sub-terranes. However, Yang et al. (2009) and Zhang et al. (2014b) suggested that the Lhasa terrane can be divided into two segments rather than three, the southern and northern sub-terranes. In this study, we adopt the three-fold sub-division of the Lhasa terrane as suggested by Zhu et al. (2011). The southern Lhasa sub-terrane, which is located
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between the IYSZ and Luobadui-Milashan fault (LMF) over 2000 km in length (Fig.1a), is known as the Gangdese magmatic belt that is mainly comprised of granitoids and intermediate-acidic volcanic sequences. Available geochronological data identify four distinct stages in the Gangdese belt during the periods of 230~152 Ma,
of
109~80 Ma, 65~40 Ma and 33-13 Ma, respectively (e.g. Ji et al., 2009; Meng et al., 2016a, b, 2018a, b; Wang et al., 2016). The
ro
230~152 Ma magmatic activities belong to the early evolutionary
-p
history of the Neo-Tethys oceanic northward subduction beneath
re
the Lhasa terrane (e.g. Meng et al., 2016a, b, 2018a; Wang et al.,
lP
2016; Ma et al., 2017b). However, some researchers argued that
na
the Neo-Tethys oceanic northward subduction began not earlier than the early stage of Early Cretaceous (~145 Ma), and suggested
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that the 230~152 Ma magmatism is associated with the southward subduction of the Bangong-Nujiang oceanic crust (e.g. Zhu et al., 2011; Wang et al., 2014; Zhang et al., 2019). In an alternate model, Dong and Zhang (2013) suggested that the Late Triassic-Early Jurassic magmatism was induced by the breakoff or rollback of the Sumdo oceanic crust (Paleo-Tethys Ocean). The 109~80 Ma magmatism in the Gangdese belt is correlated to the northward subduction of the Neo-Tethys oceanic crust (e.g. Yin and Harrison, 2000; Chung et al., 2005, 2009; Ji et al., 2009; Zhu et al., 2011, and
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references therein). However, the petrogenesis and tectonic history of the Early Late Cretaceous (100~80 Ma) magmatic event remains ambiguous (e.g. Wen et al., 2008a, b; Ji et al., 2009; Zhang et al., 2010; Ma et al., 2013a, b, 2015, 2017a; Gao et al., 2017). The 100~80 Ma magmatic suites mainly comprise granitoid rocks that
of
can be divided into two groups: normal arc-type and adakite-like rocks (Xu et al., 2015; Ma et al., 2017c; Meng et al., 2019). In
ro
addition, a few field outcrops of mafic rocks also were identified in
-p
the Gangdese belt. Integrated with published data, the Late
re
Mesozoic igneous rocks are characterized by high
176
Hf/177Hf ratios
lP
and significantly positive εHf(t) values as well as young model ages
na
reflecting depleted mantle compositions (Ji et al., 2009; Zhu et al., 2011; Hou et al., 2015). The 65~40 Ma magmatism in the
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Gangdese belt is the most dominant, constituting the main body of the Gangdese composite batholiths (e.g. Ji et al., 2009; Mo et al., 2007, 2008, 2009; Zhu et al., 2011; Meng et al., 2018b). These rocks are mainly represented by granitoids and intermediate-acidic volcanic rocks. The granitoid rocks show wide ranges of geochemical and Hf isotope compositions (Ji et al., 2009; Xu et al., 2015; Zhou et al., 2018). Coeval with the granitoid rocks in the Gangdese belt, the Linzizong volcanic rocks define three different Formations, and also have wide variations of geochemical and Hf
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isotope compositions. According to geochemical and isotopic signatures, Mo et al. (2007, 2009) proposed that the 65~40 Ma magmatism was related to syn-collisional and major-collisional processes. Ji et al. (2009) and Zhu et al. (2015) argued that the 65~40 Ma magmatism represents the complex geodynamic
of
processes, including continuous subduction, rollback and breakoff of the Neo-Tethys oceanic crust. The 33~13 Ma magmatism is the
ro
youngest in the Gangdese belt. This stage belongs to the typical
-p
post-collisional setting (Hou et al., 2004; Mo et al., 2007, 2008;
re
Meng et al., 2018c). The rock types mainly consist of granite
lP
porphyry and diorite porphyry as well as few mafic stocks. The
thickened
na
Miocene granitoid porphyries are products of partial melting of lithosphere,
and
were
emplaced
into
the
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Paleocene-Eocene batholiths as small stocks, dike swarms and rock knobs. Geochemically, the 33-13 Ma granitoid porphyries show adakite-like features, and most of the porphyries have relatively enriched Hf isotopes representing incorporation of ancient crustal material (Hou et al., 2004; Ji et al., 2009; Chen et al., 2014). The nature of magmatism associated with the Oligocene-Miocene granitoid porphyries is still ambiguous, with some workers suggesting these to be products of partial melting of thickened Lhasa lower crust (Chung et al., 2003; Hou et al., 2004; Chen et al.,
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2014), whereas others considering these to be derived from partial melting of mafic lower crust that was metasomatized by subducted fluids (Guo et al., 2007; Xu, 2010). 2.2 Summary of the gabbroic rocks in the central Gangdese In the central Gangdese belt, gabbroic rocks are exposed
of
sporadically, as small stocks and dikes (Fig.1b). Hou et al. (2001), Xiong et al. (2001) and Gao et al. (2003) regarded these stocks as
ro
the vestiges of the Yarlung Tsangpo ophiolites. However, others
-p
refuted this idea and argued that the gabbroic plutons are
re
components of the Gangdese composite batholiths, related to the
lP
northward subduction of the Neo-Tethys Ocean (e.g. Dong et al.,
na
2006, 2008; Qiu et al., 2015; Meng et al., 2016a). According to previous studies, the gabbroic rocks can be classified into three
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stages: (i) Late Triassic to Early Jurassic; (ii) early Late Cretaceous; (iii) Late Paleocene to Early Eocene. These rocks comprise hornblende gabbro, gabbroic diorite, gabbro norite and gabbro diabase, as well as minor ultramafic rocks (e.g. hornblendite). Mo et al. (2005) and Dong et al. (2006, 2008) investigated the gabbroic rocks in the central Gangdese belt, and proposed that they were formed during the Early Eocene (53-40 Ma), as products of India-Asia collision. Subsequently, Qiu et al. (2015), Meng et al. (2016a) and Wang et al. (2017) identified the Late Triassic to Early
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Jurassic gabbroic intrusions in the central belt, and argued that they were derived by partial melting of hydrous mantle related to northward subduction of the Neo-Tethys oceanic slab. Furthermore, Qiu et al. (2015) concluded that the central Gangdese belt preserves evidence for multiple underplating of mafic magmas
of
which induced magma mixing during >205 to 40 Ma. Therefore, the central Gangdese belt might contain multiple mafic magma events.
ro
Although some studies related to the gabbroic rocks were carried
-p
out in the central Gangdese belt, these mainly focused on the Late
re
Triassic to Early Jurassic intrusions (e.g. Qiu et al., 2015; Meng et
lP
al., 2016a; Wang et al., 2017). Figure 1b shows the few Late
na
Cretaceous mafic plutons reported in the central Gangdese belt (Schärer et al., 1984; Ye et al., 2015; Xu et al., 2015), although
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systematic and integrated studies on these rocks are lacking. 2.3 Sample descriptions 2.3.1 Field observations
The study area is located in the southern part of the Namling County (Xigaze region), in a region with good infrastructure for geological survey and sampling (Fig.1c), and the gabbro-diorite suite is well-exposed (Fig.2a-d). Field studies show that this suite is dominantly composed of foliated gabbro, coarse-grained gabbro, gabbroic diorite and diorite. In addition to the gabbroic rocks, a
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granitic dike, emplaced as a thick sheet-like intrusion trending NE within the gabbro-diorite suite, and was also identified (Fig.1c, Fig.2e). The granitic dike is approximately 5-15 m wide and over 1-km long (Fig.2e). The presence of verdigris on the surface of the granitic dike (Fig.2f) indicates that the dike is associated with
of
Cu-related mineralization. The samples from the gabbro-diorite composite suite can be
ro
divided into three groups. Groups I and II are normal diorite and
-p
gabbro whereas group III is represented by granitic rocks. Based
re
on field, petrological and mineralogical data, the group I and group
lP
II rocks can be divided into different sub-groups, such as
na
hornblende gabbro (lacking pyroxene), coarse-grained gabbro (containing pyroxene), fine-grained gabbro and diorite. The
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petrology and microstructures of the representative gabbro-diorite sub-groups are described below. 2.3.2 Petrography and EPMA analyses Group I: the fine-grain diorite samples are characterized by amphibole (~45%) and plagioclase (~50%), as well as minor amounts of biotite and quartz (Supplementary Figure 1a). Electron probe microanalysis (EPMA) reveals that the plagioclase mainly belongs to andesine and labradorite, and the amphibole belongs to hornblende, but few are actinolite. In addition, another diorite
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subgroup belongs to medium-coarse grain diorite (Supplementary Figure 1b) that comprises euhedral plagioclases (~55%) marked by typical polysynthetic twinning and biotite (~10%) and epidote (~30%). The epidote formed from the alteration of amphibole. Group
II:
gabbro
samples
include
three
subgroups
of
(Supplementary Figure 1c-e). Subgroup I: hornblende gabbro is composed of typical subhedral to euhedral amphibole crystals and
ro
euhedral plagioclase grains. The EPMA results reveal that the
-p
amphibole is hornblende (few crystals belonging to actinolite), and
re
the plagioclase ranges in composition from anorthite to bytownite.
lP
Although this group lacks pyroxene, the calcic plagioclase and Subgroup II:
na
hornblende indicate a gabbroic composition.
medium-coarse grained gabbro is comprised of pyroxene,
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plagioclase and biotite. The EPMA data show that the pyroxene is diopside, and the plagioclase is andesine and labradorite. Subgroup III: medium-coarse gabbro is composed of plagioclase, hornblende, diopside and biotite. The hornblende crystals surrounding diopside indicate a reaction rim texture. Group III: the coarse-grained granitic dike mainly comprises K-feldspar, quartz and plagioclase, with only minor mafic minerals (Supplementary Figure 1f), corresponding to granite. The representative BSE images of thin sections of the
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gabbro-diorite suite are shown in Supplementary Figure 2. The chemical compositions are given in Supplementary Table 1.
3. Results 3.1 Zircon U-Pb geochronology The
representative
zircon
CL
images
are
given
in
of
Supplementary Figure 3. The white and red circles represent zircon LA-ICP-MS U-Pb and SHRIMP II dating sites, respectively, and the
ro
yellow dotted circle represents sites where in situ Lu-Hf isotope
-p
analyses were performed. Zircon grains from the gabbro-diorite
re
suite are characterized by prismatic morphologies and high Th/U
lP
ratios (mean value=1.04) (>0.4), suggesting an igneous origin
several
grains
na
(Corfu et al., 2003; Hoskin and Schaltegger, 2003). In addition, show
tabular
zoning
indicative
of
an
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intermediate-mafic magma origin (Hoskin and Schaltegger, 2003). The zircon from the granite shows prismatic shapes and clear oscillatory zoning as well as high Th/U ratios (mean value=0.80) (>0.4) that together indicate a felsic magmatic origin (Hoskin and Schaltegger, 2003). The zircon U-Pb data and Th/U ratio calculations are listed in Supplementary Table 2. Three samples from the gabbro-diorite suite yielded weighted mean
206
Pb/238U ages of 94.63 ± 0.72 Ma (sample NM112; N=19,
MSWD=1.8), 90.66 ± 0.88 Ma (sample NM113; N=18, MSWD=1.3)
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and 91. 08 ± 0.65 Ma (sample NM114; N=18, MSWD=0.85), which are interpreted as the emplacement and crystallization ages of the gabbro-diorite suite. Another two samples collected from the granite rocks yielded weighted average
206
Pb/238U ages of 87.69 ±
0.58 Ma (sample MG111-1; N=33, MSWD=2.3) and 86.5 ± 1.6 Ma
of
(sample MG111-2; N=9, MSW=1.9) that constrain the crystallization ages of the granite belonging to Coniacian stage of Late
ro
Cretaceous. The 206Pb/238U versus 207Pb/235U plots shown in Figure
-p
3 demonstrate that the analytical spots fall along the Concordia,
re
with no indication of apparent common Pb loss. The analytical
lP
results are consistent with the field observations (Fig.2e) that the
na
granite is younger than the gabbro-diorite suite. 3.2 Zircon Lu-Hf isotope compositions
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A total of 43 in situ zircon Lu-Hf isotope analyses were carried out on the gabbro-diorite suite. The Hf isotopic results are given in Supplementary Table 3. The results reveal that the 176Lu/177Hf ratios vary from 0.000193 to 0.001617 (mean value=0.000587), suggesting low
176
Lu/177Hf accumulations. The
176
Hf/177Hf values of
the analytical zircons from the gabbro-diorite suite range between 0.282970 and 0.283168, and the zircon εHf(t) values range from +8.5 to +15.6, suggesting a depleted mantle feature. The TDM1 ages range from 117 Ma to 393 Ma, with a mean value of 241 Ma.
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The younger model ages suggest juvenile mantle compositions rather than ancient or enriched mantle. The Lu-Hf isotopic data are plotted in Supplementary Figure 4. 3.3 Whole-rock major and trace-elemental composition 3.3.1 Major-element compositions
of
The whole-rock major element compositions are given in Supplementary Table 4. The gabbro-diorite suite shows variable
ro
SiO2 contents ranging from 44.3 wt. % to 57.2 wt. %
-p
(Supplementary Table 4). On the TAS diagram, all the samples fall
re
into the gabbro-diorite and granite fields (Fig.4a), which are
lP
consistent with the field observations and petrologic data (Figure 2
na
and Supplementary Figure 1). All the samples plot in the sub-alkaline field (Fig.4a). Figure 4b defines calc-alkali features for
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the gabbro-diorite samples, but the granite samples show a transitional affinity. According to the SiO2 versus K2O diagram (Fig.4c), the gabbro-diorite suite can be separated into two groups, high-K calc-alkaline for diorite samples (SiO2>50 wt. %) and medium-low K calc-alkaline fields (SiO2<50 wt. %). The granite samples show a high-K calc-alkaline feature. In the triangular plot (Fig.4d), the gabbro-diorite rocks display tholeiitic and calc-alkaline features, respectively, and the granite rocks show calc-alkaline nature. The rocks from the gabbro-diorite suite have different
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geochemical affinities that might be related to later magma evolution and differentiation (Fig.5c, e, g). Furthermore, the granite rocks show weakly peraluminous nature in the molecular Al2O3/Na2O+K2O versus molecular Al2O3/CaO+Na2O+K2O diagram, suggesting a transitional affinity between S- and I-type granite
of
(Fig.4e). Additionally, they have low Mg# (Mg#=Mg/Mg+FeT) values consistent with typical crustal melts (Fig.4f).
ro
In the Harker diagrams (Fig.5), the gabbro-diorite samples
-p
have no obvious relations between SiO2 and other oxides (e.g.
re
Al2O3, BaO, TiO2, P2O5 and MnO). However, SiO2 shows better
lP
relations with CaO, Fe2O3T and MgO, indicating that fractionation of
na
pyroxene, amphibole and plagioclase played a key role in the evolution of the gabbro-diorite suite (Fig.5c, e, g). Fig.5i-j plots
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suggest no significant magma mixing during the evolution of the gabbro-diorite suite as suggested by magma mixing models that were proposed by Langmuir et al. (1978). Moreover, the samples from the diorite-gabbro suite have low TiO2 (0.50-1.40 wt. %) and high Al2O3 (16.14-21.47 wt. %) contents, similar to high-alumina basalts (Fig.5a). 3.3.2 Trace-element compositions The ∑REE contents range from 37.4 to 161.76 ppm for the gabbro-diorite suite (mean value=89.18 ppm), whereas the granite
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rocks have low REE contents varying from 26.13 to 47.90 ppm (mean value=35.25 ppm). In addition, the lower REE contents of the granite as compared to the mafic suite exclude the possibility that the granite was derived from partial melting of the gabbro-diorite suite. The chondrite-normalized REE patterns
of
presented in Figure 6 show that the gabbro-diorite samples are enriched in light REE (LREE) with LaN/YbN ratios varying from 5.06
ro
to 11.52, and diorite rocks show higher REE contents than the
-p
gabbroic rocks that indicate a fractionation process. No prominent
re
Eu anomalies (Eu/Eu*=0.75-1.33) are seen for the gabbro-diorite
lP
suite (Fig.6a), whereas the granite shows a significant Eu negative
na
anomaly (Fig.6c), which is associated with feldspar fractional crystallization or cumulates in the magma source. Additionally, the
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gabbro-diorite suite shows different REE features, which are inconsistent with those of OIB, E-MORB and N-MORB as shown in Figure 6a. Therefore, we exclude the possibility that the mafic suite belongs to the nappe complex derived from the southern Yarlung Tsangpo ophiolites as suggested by Hou et al. (2001) and Gao et al. (2003). In the primitive-mantle normalized trace element variation spider diagrams, the gabbro-diorite suite and granite are both enriched in large ion lithophile elements (LILE) (e.g. Cs, Rb, K, U
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and Pb), but depleted in high field strength elements (e.g. Nb, Ta, P and Ti) (Fig.6b and 6d). These geochemical features indicate a crustal characteristic or arc-related magma affinity (e.g. Kelemen, 1990). In addition, the gabbro-diorite and granite rocks show enrichment
in
Zr-Hf,
which
are
probably
related
to
of
subduction-released fluids or melts leading to incompatible element (e.g. Zr, Hf) concentration.
ro
3.4 Whole-rock Sr-Nd isotope compositions
-p
Seventeen representative samples from the diorite-gabbro and
re
granite were analyzed for whole-rock Sr-Nd isotopes. The
lP
analytical data are given in Supplementary Table 5. The results 87
Sr/86Sr
na
show slightly variable Sr-Nd compositions, with initial
varying from 0.703820 to 0.704213, with εNd(t) values from +4.2 to
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+3.5. The second stage model ages (TDM2) (based on the depleted mantle) of the diorite-gabbro is in the range of 606-550 Ma (mean value= 575 Ma). The granite rocks also display initial 87
Sr/86Sr ratios of 0.703977 to 0.703180, and homogeneous Nd
isotope compositions, with εNd(t) values ranging from +4.1 to +4.4. Similar to the gabbro-diorite suite, the granite rocks yield young model ages ranging from 534 Ma to 556 Ma. The whole-rock Sr-Nd analytical results suggest that the gabbro-diorite suite and granite both have depleted mantle compositions. In the (87Sr/86Sr)I versus
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εNd(t) diagram (Fig.7), all the samples fall in the mantle evolution array and correspond with the Mesozoic magmatic rocks of the Gangdese belt. Furthermore, the gabbro-diorite rocks show similar Sr-Nd isotope compositions with the Yeba and Zhengga mafic rocks.
of
4. Discussion 4.1 The emplacement timing and significance of the granite
ro
The field relationship suggests that the granite was emplaced
-p
later than the gabbro-diorite complex (Fig.2e). The U-Pb data on
re
zircon grains from the granite dike indicate emplacement at
lP
87.69±0.5 Ma (MSWD=2.3), belonging to Late Cretaceous
na
(Coniacian stage) rather than Miocene as previously considered (Fig.3g-j). However, SHRIMP II dating results reveal a complex
Jo ur
geochronological feature, indicating a continuous crystallization process (Fig.3i-j). The zircon SHRIMP II results can be divided into two stages. Stage two is represented by three zircon grains, yielding a weighted mean age of 78.0±1.5 Ma (MSWD=0.061). Stage one comprises nine zircon crystals, giving a mean weighted age of 86.5±1.6 Ma. In addition, one zircon shows a weighted age of 80.0±1.3 Ma between stage one and stage two. All the grains analyzed using SHRIMP II fall along a Concordia diagram (Fig.3i). Combined with results of SHRIMP II, we argue that the granite
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experienced a continuous crystallization process, with stage one representing an early crystallization process, and stage two suggesting a late crystallization phase. Most zircon grains from the granite dikes were formed during stage one, suggesting that stage one represents the main crystallization and emplacement time. The
of
ages reported in this study suggest that the granite dike crystallized at ca. 87 Ma, belonging to Late Cretaceous (Coniacian stage)
ro
rather than Miocene as previously considered.
-p
4.2 Crustal contamination and fractional crystallization of the
re
gabbro-diorite suite
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Figure 6 shows that the gabbro-diorite rocks are characterized
na
by enrichment of LREE and LILE (e.g. Cs, Ba, Th and U), but are depleted in HREE and HFSE (e.g. Nb, Ta, Ti and P). These
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features suggest crustal magma affinity or arc-type magma source. Mafic magmas derived depleted mantle source usually undergo crustal contamination, and display typical arc-type or crustal magma geochemical features. Generally, crustal contamination is inevitable for mantle-derived melts during their ascent through a crustal magma chamber or crust (e.g. Castillo et al., 1999). It is recognized that crustal melts generally have significantly low MgO contents, low Mg# and εNd(t) values, as well as low Nb/La ratios, but have high (87Sr/86Sr)i and La/Nb ratios (Rudnick, 1992;
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Rudnick and Fountain, 1995; Rudnick and Gao, 2003). Thus, any crustal melt participation and input will cause an increase of (87Sr/86Sr)I and decrease in εNd(t) values significantly for the mantle-derived melts (Rogers et al., 2000). In this study, the analyzed
samples
have
significant
positive
εNd(t)
values
of
(+4.16~+3.48) and low (87Sr/86Sr)I ratios (0.704213~0.703820) excluding the possibility of crustal material. In the discrimination
ro
diagrams (Fig.8a-f), all the gabbro-diorite samples demonstrate
-p
homogeneous Sr-Nd isotope compositions indicating that crustal
re
contamination played only a negligible or minor role in the magma
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evolution. In addition, if the mantle-derived melts undergo
na
significant crustal contamination, they will show negative or positive trends along the Nb/La versus MgO and La/Nb versus SiO2 plots.
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The discrimination diagrams reveal that all the samples have relatively homogeneous ratios of Nb/La and La/Nb when the MgO and SiO2 contents decrease or increase, indicating that magma did not witness significant crustal contamination (Fig.8g-h). Coeval mafic rocks and felsic rocks are interpreted by magma mixing or assimilation fractional crystallization (AFC) in the Gangdese belt (e.g. Dong et al., 2006, 2008; Mo et al., 2005; 2009; Qiu et al., 2015; Meng et al., 2016b, 2019). As shown in Figures 6-7 and Supplementary Figure 4, the diorites (SiO2=54.3 to 57.21 wt. %)
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have similar Sr-Nd-Hf isotope compositions and REE and trace elements patterns with the gabbros, suggesting a genetic link. Plots in Figure 8a-h indicates that the fractional crystallization played an important role in the formation of the diorite rocks rather than magma mixing
and AFC processes. Thus, the fractional
of
crystallization process can better explain the wide ranges of SiO2 and MgO contents. Furthermore, the diorites show higher REE
ro
contents than the gabbros, which also suggest a fractional
-p
crystallization process because incompatible REE are preferentially
re
concentrated in the magma. Fig.5i-j shows non-mixing modeling
lP
curves, suggesting a fractional crystallization process rather than
na
magma mixing (Langmuir et al., 1978). In addition to geochemical and isotope evidence, the field relations also agree with the
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fractional crystallization (Fig.2b-d). 4.3 Petrogenesis
4.3.1 Granite rocks
In the Gangdese belt, the majority of granitoid rocks show I-type features with low A/CNK ratios (<1.1) and lack typical Al-rich minerals (e.g. muscovite, garnet and cordierite) (e.g. Tafti, 2011; Hou et al., 2015; Meng et al., 2018b, c). In addition, the granitoid rocks from this belt are characterized by depleted Sr-Nd-Hf isotopic compositions, and reflect juvenile crustal components (e.g. Ji et al.,
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2009; Tafti, 2011; Zhu et al. 2011; Hou et al., 2015). In this study, the
granite
peraluminous
rocks
demonstrate
feature
metaluminous
(Fig.4e),
with
to
A/CNK
weakly [molar
Al2O3/(CaO+Na2O+K2O)] ratios varying from 1.01 to 1.10, suggesting an I-type granitic feature. The decrease in P2O5 with
of
increasing SiO2 (Fig.9g) indicates that the granite belongs to I-type granite because P2O5 decreases with fractional crystallization
ro
process in I-type granite and increases in S-type granite as
-p
suggested by Chappell and White (1992). In addition, the granite
re
rocks have significantly positive εNd(t) values (mantle array) that are
lP
inconsistent with S-type granite (Fig.7b) (e.g. Ma et al., 2017a).
na
Recently, Ma et al. (2017a) and Zhang et al. (2019) reported some granite rocks characterized by the absence of mafic minerals
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in southern Tibet (Gangdese region and central-Lhasa), and pointed out that these rocks are highly evolved, and show A-type granite features. In general, A-type granites have a close affinity with extensional settings (e.g. Eby, 1992; Hao et al., 2019; Meng et al., 2018d). The Gangdese region experienced tectonic extension during the early Late Cretaceous (100~80 Ma) (Ma et al., 2015; Xu et al., 2015; Ye et al., 2015; Meng et al., 2019) and asthenosphere upwelling (mid-oceanic ridge subduction or rollback) (e.g. Zhang et al., 2010). Moreover, several studies on the more evolved S- and
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I-type granites also suggest A-type granitic features (e.g. Meng et al., 2018d; Zhang et al., 2019), especially high-silica A-type granites (King et al., 1997; Wu et al., 2007). Although the granite rocks in this study show I-type granitic feature, the possibility of A-type affinity cannot be excluded. The
of
geochemical features suggest that the granites have relatively high alkaline contents (Na2O+K2O>8.0 wt. %) and alkali index
ro
(0.69-0.61), but low contents of P2O5 (<0.02 wt. %) and CaO (<1.1
-p
wt. %) (Fig.9d, 9g) that correspond with A-type granites as
re
proposed by Eby (1990).
lP
In the normalized REE patterns (Fig.6c), the granites have
with
na
high light REE contents and low heavy REE contents inconsistent highly-fractionated
granites
(HFG),
but
exclude
the
are
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classification as A-type granites (Fig.10a-e). A-type granites usually formed
at
high-temperatures
(>800
℃,
mean
temperature=891 ℃, up to 944 ℃) (e.g. Hao et al., 2019), whereas I- or S-type granites are from at relatively low temperature (mean temperatures at 800 ℃ and 770 ℃). Whole-rock zircon saturation and zircon Ti thermometers suggest that the granite rocks were crystallized at a low temperature (<800℃) (Fig.10f) excluding their correlation as A-type. Although Fig.10d suggests fractionated granite nature, the REE patterns and other features do not support
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of high degree of fractionation. Combined with petrologic, mineral chemical and geochemical features, we argue that the granite from the study area belongs to typical I-type granite (unfractionated granite). 4.3.2 Evaluation on the adakite rocks Geochemically, normal adakites have SiO2 content ≥ 56 wt. %, 15 wt. %, and Na2O/K2O>1 (Defant and
of
Al2O3 content ≥
ro
Drummond, 1990). Compared to normal arc-type rocks, they
-p
possess high Sr contents (>400 ppm), and enriched in Eu (Eu
re
positive anomaly), but are strongly depleted in Yb (≤1.9 ppm) and Y
lP
(≤18 ppm) (Defant and Drmmond, 1990; Richards and Kerrich,
na
2007). Plots in Figure 9 (c, e, and f) indicate that the granite rocks have geochemical features that are inconsistent with typical
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adakites, following the definition by Defant and Drmmond (1990) and Richards and Kerrich (2007). The Y versus Sr/Y and YbN versus (La/Yb)N diagrams are regarded as effective tools in discriminating adakite and classic arc magma, where the granite shows adakite features. In the Gangdese belt, the early Late Cretaceous granitoid rocks can be divided into adakitic rocks and normal arc-type rocks (e.g. Xu et al., 2015; Meng et al., 2019). It is notable that adakitic rocks overlap with normal arc-type rocks in space and time, suggesting a complex setting in the Gangdese belt.
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Competing models are also proposed related to the petrogenesis of adakitic rocks in the Gangdese belt (e.g. Ji et al., 2012; Xu et al., 2015; Ma et al., 2017c; Meng et al., 2019). Among these, Xu et al. (2015) and Meng et al. (2019) argued that the early Late Cretaceous adakitic rocks are marked by high Sr/Y and (La/Yb)N ratios which are related to amphibole fractionation rather than
in the Gangdese belt (Defant et al., 1992). He et al. (2011)
ro
slab
of
typical adakites that formed by partial melting of subducted oceanic
-p
argued that the high Sr/Y and (La/Yb)N ratios can result in multiple
re
settings. Combined with previous studies, we also propose that the
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high Sr/Y and (La/Yb)N ratios of intermediate-felsic rocks from the
na
Gangdese do not represent adakitic features that were produced due to subducted young oceanic crust or thickened crust. Adakites
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or adakitic rocks can be formed in the following settings: (I) partial melting of subducted oceanic slab (Defant and Drummond, 1990); (II) partial melting of thickened or foundering crust (Atherton and Petford, 1993; Xu et al., 2002, 2007); (III) crystallization and differentiation (Macpherson et al., 2006; Richards and Kerrich, 2007; Xu et al., 2015; Meng et al., 2019); (IV) magma mixing (e.g. Chen et al., 2004; Guo et al., 2007); (V) partial melting of granulite rocks (Jiang et al., 2007) and (VI) high Sr/Y magma source (Kamei et al., 2009; Zhang et al. 2009; Moyen, 2009). However, adakitic
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rocks, formed in the III to VI settings above belong to pseudo-adakites (e.g. He et al., 2011; Wang et al., 2013; Meng et al., 2019). He et al. (2011) proposed that Sr versus SiO2 and Sr versus CaO diagrams can better discriminate pseudo adakites. If adakitic rocks are products of partial melting of subducted oceanic slab or partial melting of thickened crust and foundering, they will
of
show high Sr and steep slope, which can exclude the possibilities
ro
of fractional crystallization and magma mixing. The granites have
-p
similar trends with normal granitoid rocks, suggesting a pseudo
re
adakitic feature (Fig.11a-b). Moreover, Figure 11c-d also suggests
lP
that the granite rocks belong to normal granitoids rather than typical
na
adakites. The diorites from the gabbro-diorite complex also suggest a pseudo adakitic feature. High Sr diorite rocks are products of
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differentiation crystallization that has been proved in Figure 8. Therefore, the Y versus Sr/Y and YbN versus (La/Yb)N diagrams are not effective in discriminating pseudo adakites (Fig.9a-b). In conclusion, we argue that the granite and diorites of the complex cannot be ascribed to adakite rocks. Combined with published data and "adakitic rocks" distribution features, we conclude that the early Late Cretaceous granitoid rocks belong to typical arc-type rocks. 4.3.3 Magma source of the granite The Mesozoic granitoid rocks show positive Sr-Nd-Hf isotope
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features, corresponding to deplete mantle feature (e.g. Ji et al., 2009; Zhu et al., 2011; Hou et al., 2015) (Fig. 7 and Supplementary Figure 4a). Their young Nd-Hf model ages and isotope features indicate that the majority of granitoid rocks were derived from partial melting (recycling) of juvenile crust (Ji et al., 2009; Ma et al.,
of
2019). In our study area, the granites have low Mg# (<40) values indicating a partial melting of pure crustal material (Fig.4f). However,
ro
it has been shown that mantle material injection played a key role in
-p
the formation of the Gangdese composite batholiths, indicating
re
multiple mafic magma underplating and magma mixing during the
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Mesozoic and Early Cenozoic (>40 Ma) (e.g. Dong et al., 2005; Qiu
na
et al., 2015; Ma et al., 2017d; Meng et al., 2019). The Mesozoic granitoid rocks from the Gangdese batholith demonstrate high Mg#
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values (>40), indicating magma mixing (e.g. Meng et al., 2019). Coeval mafic enclaves and mafic rocks occur with the granitoid rocks in space and time (e.g. Qiu et al., 2015; Meng et al., 2019). However, the partial melting of pure crustal material forming granitic plutons is rare in the Gangdese belt. Although the granite sheet intruded into the gabbro-diorite suite (Fig.2e-f), the mafic magma contamination
played
a
negligible
role
as
suggested
by
homogeneous Sr-Nd isotope composition (Supplementary Table 5) and related plots (Fig.9h) (Langmuir et al., 1978). The granite rocks
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have significantly positive εNd(t) values plotting into the mantle evolution array, and possess similar Sr-Nd isotope compositions with the Mesozoic magmatic rocks. Combined with petrological features and geochemical indicators, as well as Sr-Nd isotopes, we suggest that the granite rocks are products of partial melting
of
(recycling) of the juvenile crust, and mantle material played a negligible role in the formation of the granite.
ro
4.3.4 The gabbro-diorite suite
-p
Cumulate gabbroic rocks can be divided into two types,
Compared
the
sheeted
cumulate
rocks
cumulate
display
rocks,
the
coarse-medium-fine
na
annular-texture
to
lP
2015).
re
sheeted- and annular-texture cumulate rocks (e.g. Shao et al.,
grained texture from the core to the margin of the intrusion. Field
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observations exclude the possibility that the gabbro-diorite complex belongs to group with annular texture (Fig.2a-d). It is known that the sheeted-texture
gabbro
rocks
with
cumulate
texture
are
characterized by the following characteristics: (i) horizontal rhythmic layering or "graded layer
";
(ii) oriented minerals; (iii)
mega-crystal texture; and (iv) poikilitic texture. Field evidence reveals that the gabbro-diorite complex lacks typical sheetedtexture, and mainly display massive texture (Fig.2a-d). Additionally, the rocks collected from the suite have no Eu positive anomaly that
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is inconsistent with the effect of crystal cumulation.
Generally,
cumulate gabbro shows positive Eu anomalies due to plagioclase crystal accumulation in the magma chamber (e.g. Piccardo and Guarnieri, 2011; Parlak et al., 2019). Furthermore, mineral microstructures are inconsistent with typical cumulate gabbro, in
of
the absence of meta-crystals (e.g. hornblende) and mineral orientation. In this study, the rocks show high REE contents (Fig.6a)
ro
are also inconsistent with mafic cumulate rocks that are
-p
characterized by low REE contents (e.g. Zhou et al., 2005; Caroff et
re
al., 2011; Kristoffer et al., 2015). Based on the above features, we
lP
infer that the gabbro-diorite suite in our study does not belong to
na
the class.
The REE, trace element spider diagrams and homogeneous
gabbroic
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Sr-Nd-Hf isotope reveal that the diorites are products of the magma
crystallization
differentiation.
Zircon
geochronology of these rocks reveals crystallization during 94.63 to 90.66 Ma. Gabbroic magmas are generally associated with the partial melting of mantle material. In our study area, the gabbro-diorite rocks show depleted Sr-Nd-Hf isotopes and young Hf-Nd model ages, suggesting that the gabbro-diorite rocks were sourced from partial melting of the depleted mantle (Fig.7 and Supplementary
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Figure 4a-b). The La/Yb versus Sm/Yb diagram suggests that the gabbro-diorite suite was sourced from ca. 15-17% melting of garnet peridotite (Supplementary Figure 5). In the zircon U-Pb age versus εHf(t) diagram, the gabbro-diorite rocks fall in the same region with the Mesozoic granitoids from the Gangdese composite batholiths
of
(Supplementary Figure 4a). Previous studies suggest that the Mesozoic Gangdese batholiths formed through the northward
ro
subduction of the Neo-Tethys oceanic slab beneath the Lhasa
-p
terrane (e.g. Yin and Harrison, 2000; Ji et al., 2009; Tafti, 2011; Zhu
re
et al., 2011; Hou et al., 2015; Meng et al., 2016a, b, 2019). In the
lP
Sr-Nd diagram (Fig.7), the gabbro-diorite rocks plot into the mantle
na
array and demonstrate similar Sr-Nd isotopes with the Early Jurassic Yeba basalts and early Late Cretaceous Zhengga
Jo ur
gabbro-diorite suite (Fig.7). The Yeba basalts were derived from a common and heterogeneous mantle that was metasomatized by sediments/fluids released from the subducted Neo-Tethys oceanic crust (e.g. Zhu et al., 2008; Ma et al., 2017c; Wei et al., 2017; Ma et al., 2018). However, crustal contamination (enriched compositions) played a key role in the petrogenetic process of the Yeba Formation basalts (e.g. Zhu et al., 2008; Wei et al., 2017). In contrast, the enriched components (e.g. crustal material and sediments) had only a minor or negligible role during the evolution of the
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gabbro-diorite suite in study area (Fig.5i-j and Fig.8). Therefore, the early Late Cretaceous gabbro-diorite rocks show more depleted Sr-Nd-Hf isotopes than the Early Jurassic Yeba Formation basalts. Furthermore,
the
coeval
Zhengga
gabbro-diorite
complex
(crystallization ca. 94 Ma) shows a complex magma source, with
of
group I formed by the fractional crystallization of clinopyroxene and accumulation of plagioclase without significant contamination,
ro
whereas group II was sourced from the fractional crystallization of
-p
plagioclase and clinopyroxene with the same magma source but
re
showing significant crustal contamination in the eastern Gangdese
lP
belt (Ma et al., 2013a). We thus infer a heterogeneous magma
na
source in the Gangdese belt. Recently, Wang et al. (2019) also reported that the Paleogene gabbroic rocks show geochemical and
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isotope variations along the Gangdese arc. The mafic rocks from the west-east segments of the Gangdese belt have distinct geochemical and isotope compositions suggesting hybrid magma sources during the Neo-Tethys oceanic subduction. Fluids/sediments and melts from the down-going oceanic slab induce partial melting of the lithosphere mantle in such setting. In the (Ta/La)PM versus (Hf/Sm)PM diagram (Supplementary Figure 6a), the majority of samples plot into the hydrated mantle source. Supplementary Figure 6b-c further suggests that fluids derived from
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slab dehydration are the dominant factor that induced partial melting of the depleted mantle. In combination with the Sr-Nd-Hf isotope features, we argue that the dehydration of the Neo-Tethys oceanic slab induced the partial melting of the depleted mantle forming the gabbro-diorite rocks (Fig.12). Petrographic studies
of
reveal that the gabbro-diorite rocks contain abundant hornblende and calcic plagioclase (Supplementary Figures 1a-e and 2), the
ro
latter (An>50) characterized by labradorite and bytownite crystals
-p
(Supplementary Table 1), suggesting high-pressure H2O-rich
re
setting (e.g. Sisson et al., 1993; Qiu et al., 2015; Meng et al.,
lP
2016a). During the later evolution and ascent, the gabbro-diorite
na
suite did not witness any significant crustal contamination. 4.4 Magma processes and fractional crystallization
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In Figure 5, the linear relations with decreasing of Cao, Fe2O3T and MgO contents with increasing of SiO2, suggest crystallization of mafic minerals and plagioclase during magma evolution. This is also indicated by the plots in Cr versus V, Sr versus Rb/Sr and Ba versus Rb/Sr diagrams (Supplementary Figure 7a-c). The geochemical
discrimination
diagrams
further
demonstrate
pyroxene-, hornblende- and plagioclase-dominated evolution fractionation. The Cpx- and Opx-dominated fractionation probably suggests the presence of minor olivine during the early-stage
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evolution. The granite rocks display fractionation of K-feldspar (Supplementary Figure 7a-c). Additionally, negative anomalies of Eu
and
significant
Ba
depletions
indicate
that
alkali
feldspar-dominated fractionation (K-plagioclase) (Fig.6c-d). 4.5 Genetic affiliation
of
Yin et al. (1994) identified two regional faults which are the Gangdese thrust (GT) and Great converse thrust (GCT). Due to
ro
strong tectonic activities of two faults during the Oligocene-Miocene,
-p
it is possible that the mafic rock assemblages from the ophiolites
re
were transported to the Gangdese belt forming new tectonic
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mélanges. Our study area is adjacent to the ophiolites of the IYSZ
na
(Fig.1b-c). According to the data from geophysical studies and regional faults as well as rock assemblages, the early workers
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considered that the gabbro-diorite complexes of the middle segment of the Gangdese batholith (Fig.1b) belong to the ophiolites of the IYSZ rather than the Gangdese batholiths (Hou et al., 2001; Xiong et al., 2001; Gao et al., 2003). Later, some workers attributed the gabbro-diorite complexes to the Gangdese batholith, and proposed that these complexes are products of the northward subduction of the Neo-Tethys oceanic lithosphere and Indian-Asian collision (e.g. Dong et al., 2006, 2008; Qiu et al., 2015; Meng et al., 2016a; Wang et al., 2017). The data from field observations,
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petrology, geochemistry, and isotopes in this study indicate arc-type features for the gabbro-diorite complex in the Shanba region (Fig.1c). Based on regional geology and published data, we conclude that the Shanba gabbro-diorite suite belongs to the Gangdese batholiths rather than being remnants of the ophiolites
of
from the IYSZ. 4.6 Tectonic implications
ro
Previous studies suggested that a juvenile island-arc terrane
-p
accreted to the southernmost Lhasa terrane during the Cretaceous
re
(e.g. Ji et al., 2009; Zhu et al., 2011; Ma et al., 2013a; Hou et al.,
lP
2015; Meng et al., 2019). However, the subduction style of the
na
Neo-Tethys oceanic crust has been debated, including mid-oceanic ridge subduction (e.g. Zhang et al., 2010; Guo et al., 2013; Wu et
Jo ur
al., 2018), rollback of the Neo-Tethys oceanic slab (e.g. Ma et al., 2013a; Xu et al., 2015; Meng et al., 2019) and high-angle oblique subduction (Wang et al., 2013). The REE, trace elements patterns and Sr-Nd-Hf features suggest an arc-related setting (Fig.6a-b). In the Nb/Yb versus Th/Yb diagram, the gabbro-diorite rocks plot into the continental arc (Supplementary Figure 8e). Other geochemical data also suggest that the gabbro-diorite complex was formed in an active continental margin setting (Supplementary Figure 8a-d). We therefore correlate
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the early Late Cretaceous magmatism with the Neo-Tethys oceanic subduction beneath the Lhasa terrane (Fig.12). There is a striking flare-up of Early Late Cretaceous magmatic events in the Gangdese belt. Based on the discovery of charnockites in the eastern Gangdese, Zhang et al. (2010)
of
proposed a mid-oceanic subduction model to decipher the high-temperature garnet-bearing granulite. Moreover, Guo et al. also
attested
to
this
model
ro
(2013)
and
argued
that
-p
high-temperature metamorphism in the southeastern Lhasa terrane
re
was associated with the Neo-Tethys oceanic ridge subduction. The
lP
mid-oceanic ridge subduction setting is generally characterized by
na
H2O-poor, CO2-rich environment and high oxygen fugacity (fO2). The high-temperature metamorphism granulite and presence of
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charnockite are restricted to the eastern Gangdese (Nyingchi region). If the Early Late Cretaceous magmatic rocks were products of the high-heat flux mid-oceanic ridge subduction in the whole Gangdese belt, the Gangdese arc should be in a dry and H2O-poor setting. However, the recent discoveries of H2O-rich hornblende gabbro-diorite
rocks
are
contradictory
with
the
model
of
mid-oceanic subduction (e.g. Meng et al., 2019). In addition, Dong and Xu (2016) concluded that the eastern Gangdese region (Nyingchi region) experienced rapid exhumation during the
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Miocene leading to the lower crust of the Nyingchi region being exhumed and exposed on the surface. It is therefore possible that the high-temperature granulite and charnockite represent the lower crustal compositions (Rudnick and Presper, 1990; Rudnick, 1992; Gao et al., 2004) rather than the products of the Neo-Tethys
of
oceanic-ridge subduction. Additionally, several studies have established that the Gangdese belt is mainly composed of I-type Mid-oceanic ridge subduction will usually generate a
ro
granites.
-p
wide variety of magmas, with chemical compositions ranging from
re
adakites-high-Mg andesites to alkaline and tholeiitic mafic volcanic
lP
rocks (e.g. Abratis and Worner, 2001; Tang et al., 2012). Therefore,
na
the lithology in our study area is inconsistent with the rocks that are produced by mid-oceanic subduction.
Gangdese
Jo ur
Compared to the Nyingchi region, the central-western region
experienced
low-rate
exhumation
and
denudation, so the middle-upper crustal components are preserved in the absence of exposed lower crust. It has been suggested that the northward subduction of the Neo-Tethys oceanic slab had an important effect on the southernmost part of the Eurasian continent for a distance of over >2000 km prior to India-Asia collision (Xiong et al., 2019). The mid-oceanic ridge subduction of the Neo-Tethys is likely to influence the whole of Gangdese belt, and multiple
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high-temperature, Nb-rich and high-Mg mafic rocks might have been produced during the early Late Cretaceous. Furthermore, the duration of mid-oceanic ridge subduction can extend over 40 Ma from initiation to termination. Similar examples were reported in the Andes orogen (Kula-Farallon ridge subduction) and the western
of
Junggar area (e.g. Tang et al., 2012). In contrast, the flare-up of the Early Late Cretaceous magmatism had a short duration. In addition
ro
to these, the Early Late Cretaceous magmatic rock types and
-p
geochemical features are inconsistent with the typical rocks
re
generated by ridge subduction which are characterized by
lP
high-temperature and MORB-, OIB-like features. Also, the
na
high-angle oblique subduction model cannot explain the Early Late Cretaceous magmatic flare-up and mantle underplating (e.g. Ma et
Jo ur
al., 2015; Meng et al., 2019).
In combination with regional setting and published data, as well the results reported in this study, we propose that the gabbro-diorite suite formed in an active continental margin setting, and the rollback of the Neo-Tethys oceanic slab might be the major factor that contributed to the flare-up of the Early Late Cretaceous magmatism in the Gangdese belt.
5. Conclusions (1) The gabbro-diorite suite was emplaced at ca. 91-95 Ma,
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and the granite crystallized at ca. 87 Ma. These rocks thus belong to the Early Late Cretaceous magmatic event. (2) The gabbro-diorite rocks are products of partial melting of the depleted mantle, and slab dehydration played a key role in causing the partial melting of the lithosphere mantle. However, the
of
granite rocks were derived from partial melting (recycling) of the juvenile crust.
ro
(3) There is no major crustal or sediment contamination in the
-p
formation of the gabbro-diorite suite during the magma evolution.
re
The diorite rocks of the suite are related to fractionation
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crystallization of the gabbroic magma.
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(4) The granite belongs to typical I-type granite, and mantle material was not involved in the formation of the magma.
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(5) The rollback of the Neo-Tethys oceanic slab might be responsible for the Early Late magmatism in southern Tibet.
Acknowledgements We thank Editor Prof. Zeming Zhang and three anonymous reviewers for their valuable comments that improved the manuscript greatly. We also thank Prof. Zhiqin Xu for her academic guidance and warm-hearted help in the geological survey of the southern Tibet. This study was co-supported by the Key Laboratory
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of Deep-Earth Dynamics of Ministry of Natural Resources (Open foundation) (J1901-16), the Natural Foundation of Shandong province (No.ZR2019QD002, ZR2017BD033), National Natural Science Foundation of China (41902230) and special foundation of the central subordinate University (No. 300102278105). In addition,
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first author Dr. Yuanku Meng thanks Boxian Meng for his guidance
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and help.
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Appendix A. Descriptions of analytical methods
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A.1. Electron probe microanalyses
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The representative thin sections from the gabbro-diorite suite
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were selected for electron probe microanalysis (EPMA). The EPMA analysis was carried out at the testing center of Shandong Bureau
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of China Metallurgical Geology Bureau (Jinan). Mineral chemical compositions were determined using a JEOL JXA-8230 microprobe with a 15.0 kv excitation voltage, 20 nA beam current and 5 µm beam spot in diameter. A.2. Zircon U-Pb dating analyses Zircon grains were separated using magnetic and heavy liquid methods at the Institution of Geological Survey and Mapping of Hebei Province (Langfang), China. The selected zircons were mounted in epoxy and polished down to half-section for
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Cathodo-luminescence (CL) images, to reveal the internal textures of studied zircons. Zircon LA-ICP-MS U-Pb dating was conducted at the Wuhan Sample Solution Analytical Technology Co., Ltd (China) using a Neptune ICP-MS attached to a New Wave 213 nm laser ablation system (Thermo Finnigan Element 2) with an
of
in-house sample cell. Fixed 35 µm diameter laser beam was adopted with a laser pulse frequency of 8~10 Hz. The ablated
ro
material was transported into the plasma torch by He-Ar mixed
Pb/206Pb age of 608.5±0.4 Ma, 206Pb/238U age of 600.3±0.3 Ma)
re
207
-p
gases. The standard zircon samples GJ-1 (internal standard,
206
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and 91500 (external standard,
Pb/238U age of 1064.4±4.8 Ma)
na
were used to correct the zircon U-Th-Pb isotopic fractionation. The analytical results were processed using ICPMSDataCal10.9
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software (Liu et al., 2010). The Concordia plots and weighted average U-Pb ages were obtained by Isoplot 4.11 program (Ludwig, 2003). The common lead (Pb) correction was performed using Com Pb Corr# 3_15G program, following Andersen (2002). Detailed principles and procedures of zircon LA-ICP-MS dating technique followed those described by Chang et al. (2006). Zircon grains from the granite samples were analyzed using SHRIMP II technique at the Beijing SHRIMP Centre, Chinese Academy of Geological Sciences, Beijing. A primary O2- ion beam
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of 6 nA was used to bombard the zircon surface with a 20 µm diameter spot size. Standard zircons 91500 (U=91 mm), SL 13 (U=238 ppm) and M257 (U=840 ppm) were used for elemental abundance calibration (Williams, 1998). TEMORA is 206Pb/238U age of 417 Ma analyzed for calibration of
206
Pb/238U ratios after three
described by Williams (1998).
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A.3. Zircon Lu-Hf isotopic analyses
of
analyses. SHRIMP II analytical methods and conditions are
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In situ Zircon Hf isotopic analyses were carried out using a
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New Wave U-Pb 213 laser ablation microprobe attached to a
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Neptune MC-ICP-MS technique at the State Key Laboratory for
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Mineral Deposits Research, Nanjing University. Laser beam of analytical spot was 40 µm diameter and the pulse frequency of
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laser beam was 8~10 Hz. Standard zircon 91500 was used for evaluating the accuracy of the analytical spots that yielded a weighted mean
176
Hf/177Hf ratio of 0.282296±8 (2σ, MSWD=0.58)
(Goolaerts et al., 2004). The measured
176
Lu/177Hf ratios and
176
Lu
decay constant of 1.867×10−11/annual were used for calculating the (176Hf/177Hf)initial values (Söderlund et al., 2004). The chondritic values of 176Hf/177Hf (0.282785 ± 11; 2σ) and 176Lu/177Hf (0.03361 ± 1; 2σ) were used for calculating epsilon Hf (εHf(t)) values (Bouvier et al., 2008). The model ages (TDM) ages were calculated by using a
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Lu/177Hf value of 0.015 of the average continental crust (Vervoort
and Blichert-Toft, 1999; Griffin et al., 2000, 2002). A.4. Whole-rock major-trace analyses Whole-rock major and trace element analyses were performed at the Wuhan Sample Solution Analytical Technology Co., Ltd
of
(China). Major elements were analyzed using a XRF spectrometer, with an analytical precision of ± 5%. Trace and rare earth elements
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(REE) concentrations were analyzed using an Agilent 7500a
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better ± 10% (some are ± 5%).
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ICP-MS technique, with the precision of the ICP-MS analyses being
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A.5. Whole-rock Sr-Nd isotopic analyses
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Seventeen representative samples from the gabbro-diorite suite and the granite were selected for whole-rock Sr-Nd isotope
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analyses. The samples were assayed on a VG 354 mass spectrometer with five collectors at the Center of Modern Analysis, Nanjing University, China. The whole procedural blanks are <300 pg for Sr, <30 pg for Sm, <100 pg for Rb and <100 pg for Nd. The Sr-Nd isotope ratios were normalized relative to =8.375209 and
86
Sr/88Sr
146
NBS-987 yielded
Nd/144Nd = 0.7219, respectively. Sr standard
87
Sr/86Sr = 0.710233 ± 0.000006 (2σ) and Nd
standard La Jolla gave
143
Nd/144Nd = 0.511863 ± 0.000006 (2σ).
The details on Sr and Nd isotope measurements are as those
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described in Li et al (2011a, b).
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cumulate gabbro in Tahe, northern Da Hinggan Mountain. Acta Petrologica Sinica 21(3), 763-775 (in Chinese with English abstract). Zhu, D.C., Pan, G.T., Chung, S.L., Liao, Z.L., Wang, L.Q., Li, G.M., 2008. SHRIMP zircon age and geochemical constraints on the origin of lower Jurassic volcanic rocks from the Yeba formation, southern Gangdese, South Tibet. International Geology Review 50(5), 442-471. Zhu, D.C., Wang, Q., Zhao, Z.D., Chung, S.L., Cawood, P.A., Niu, Y.L., Liu, S.A., Wu, F.Y., Mo, X.X., 2015. Magmatic record of India-Asia collision. Sci. Rep. 5, 14289. https:// doi.org/10.1038/srep14289. Zhu, D.C., Zhao, Z.D., Niu, Y.L., Mo, X.X., Chung, S.L., Hou, Z.Q., Wang, L.Q., Wu, F.Y., 2011. The Lhasa terrane: record of a microcontinent and its histories of drift and growth. Earth Planet. Sci. Lett. 301 (1-2), 241-255. Zhu, D.C., Zhao, Z.D., Niu, Y., Dilek, Y., Hou, Z.Q., Mo, X.X., 2013. The origin
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Figure Captions Figure 1 (a) Simplified tectonic framework of the Himalaya-Tibetan plateau (after Yin and Harrison, 2000; Zhu et al., 2011); (b) Geological simplified map
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of the study and adjacent regions and previous studies related to gabbroic
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rocks (base maps are after 1:25, 0000 Lhasa and Xigaze regional geological maps (No. H46C003001 and H45C003004), PRC); (c) Geological sampling
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locations (after 1:25, 0000 geological map (map No. H46C003001) and
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geological survey)
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Figure 2 (a-d) Field outcrops of the gabbro-diorite suite; (e-f) field pictures and
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distributions of the granite rocks
granite (g-j)
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Figure 3 Zircon U-Pb age Concordia plots for the gabbro-diorite suite (a-f) and
Figure 4 (a) TAS diagram (after Middlemost, 1994), dotted line for Irvine line (after Irvine and Baragar, 1971); (b) Alkalinity ratio (A.R.) versus SiO2 plot (after Wright, 1969); (c) SiO2 versus K2O plot (after Peccerillo and Taylor, 1976); (d) Fe2O3T-Na2O+K2O-MgO diagram (after Irvine and Baragar, 1971); (e)
A/CNK
(molar
Al2O3/(CaO+Na2O+K2O))
versus
A/NK
(molar
Al2O3/(Na2O+K2O)) plot (after Maniar and Piccoli, 1989); (f) SiO2 versus Mg# plot (Mg#=100×molar Mg/(Mg+Total Fe)) (after Rapp and Watson, 1995)
Figure 5 (a-h) Harker diagrams of the gabbro-diorite suite (SiO2 versus major oxides); (i-j) SiO2/Al2O3 versus Fe2O3/Al2O3 and SiO2/Al2O3 versus
Journal Pre-proof Al2O3/MgO (mixing curve after Langmuir et al., 1978)
Figure 6 Chondrite-normalized REE patterns (a for the gabbro-diorite suite, c for the granite); primitive mantle normalized multiple trace element diagram (b for the gabbro-diorite suite, d for the granite). The chondrite normalization values are from Boynton (1984), and primitive mantle normalization values are adopted from Sun and McDonough (1989); OIB, E-MORB and N-MORB patterns are after Sun and McDonough (1989); tetrad effect line is after Sun et
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al. (2003); OIB=oceanic island basalt; E-MORB=enriched mid-oceanic ridge
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basalt; N-MORB=normal mid-oceanic ridge basalt
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Figure 7 (87Sr/86Sr)I versus εNd(t) diagram for the gabbro-diorite suite (the
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Mesozoic magmatic rocks field is after Ji et al., 2009; Linzizong volcanic field is
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after Mo et al., 2007, 2008, 2009; Zhengga and Milin mafic rocks fields are after Ma et al., 2013a, b, 2015; the Neo-Tethys ophiolites field is after Mahoney
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et al. (1998) and Zhang et al., 2005; the Yeba basaltic rocks field is after Zhu et
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al., 2008; the Langxian adakites filed is after Wen et al., 2008a)
Figure 8 (a-h) Fractional crystallization (FC) and crustal contamination (or magma
mixing)
discrimination
diagrams
of
whole-rock
Sr-Nd
and
geochemistry for the gabbro-diorite suite
Figure 9 (a-b) Y versus Sr/Y and YbN versus (La/Yb)N diagrams (base maps are after Defant et al., 2002; Petford and Atherton, 1996); (c-h) Harker diagrams of SiO2 versus oxides (Al2O3, CaO, P2O5 and Na2O/K2O) and Sr of the granite rocks; (h) Na2O/Fe2O3T versus Al2O3/Fe2O3T (mixing curve is after Langmuir et al., 1978)
Figure 10 (a-e) Discrimination diagrams for A-type granitic rocks (a-d base
Journal Pre-proof maps are after Whalen et al., 1987; e base map is after Eby, 1990); (f) zircon Ti (Watson et al., 2006) and whole-rock zircon saturation geothermometers
Figure 11 Discrimination diagrams for normal adakites and pseudo-adakites (base maps are after He et al., 2011)
Figure 12 Geodynamic model for the southern Tibet during Early Late Cretaceous (ca. 100-85 Ma); LMF=Luobadui-Milashan Fault (after Zhu et al.,
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2011)
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Highlights The gabbro-diorite and granite crystallized at the Early Late Cretaceous. The gabbro-diorite suite was products of partial melting of the depleted mantle, and slab dehydration played a key role.
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The granite was partial melting of pure crust with no injection of mantle material.
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The rollback of the Neo-Tethys accounts for the magmatic
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flare-up in the southern Tibet during the Early Late Cretaceous.
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Figure 12