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Physical Properties
Appendix D. Physical Properties Physical property data may be found directly in the literature or in standard data compilations, or they may be estimated from correlations or molecular structure. The last method is described for example in the books of Bretsznajder (1962), Lyman et al. (1982), Reid et al. (1977), and Sterbacek et al. (1979). According to one estimate, about 2 million data are published annually in some 35,000-50,000 articles, so keeping up with the literature requires computer retrieval, which is implemented in several systems. Several helpful lists of compilations of data are available—for example: 1. Fratzcher, W., H.P. Picht, & H.J. Bittrich. The acquisi tion, collection and tabulation of substance data on fluid systems for calculations in chemical engineering. Int. Chem. Eng. 20(1), 19-28(1980). 2. Maizeil, R.E. How to Find Chemical Information. Wiley (1978). 3. Mellon, M.G., Chemical Publications: Their Nature and Use, McGraw-Hill, (1982). 4. Rasmussen, P., & A. Fredenslund. Data Banks for Chemical Engineers. Kemiingeniorgruppen (Lyngby, Den mark) (1980). 5. Torres-Mar chai, C. Getting chemical engineering infor mation from non-English-speaking countries. Chem. Eng. 88 (14), 117-125 (July 13, 1981). 6. Physico-Chem ical Properties for Chem ical Engineering. Prepared by the Society of Chemical Engineers of Japan. Approximately annual volumes since 1977. Literature refer ences with abstracts of theoretical articles and indications as to the nature of the data in the source. Categories are PVT and liquid density, vapor pressure and enthalpy of vaporization, heat capacity and enthalpy, vapor-liquid equilibria, solubility and heat of solution, viscosity, thermal conductivity, and molecular diffusivity. Maruzen, Tokyo (1977-date). Several proprietary data banks provide information on demand for a fee. Some of these sources are identified in the book of Rasmussen (loc. cit.) and also in these references: 7. Peterson, J.N., C.-C. Chen, & L. B. Evans, Computer programs for chemical engineers. Chem. Eng. 145-154 (June 5, 1978); 69-82 (July 3, 1978); 79-86 (July 31, 1978); 107115 (August 28, 1978); 167-173 (May 21, 1979). Prepared in connection with the ASPEN project. 8. Hilsenrath, J. Summary of on-line or interactive physicochemical numerical data systems. National Bureau of Stan dards Technical Note 1122 (1980). 9. Leesley, M.E., Computer-Aided Process Plant Design. Gulf Publishing Company (1982). A service of this kind is being provided now to subscribers by the American Institute of Chemical Engineers and will be made accessible to the public eventually. The data on 72 substances in this appendix are excerpted largely from a list of 468 substances, identified following. Another useful compilation on 176 substances is taken from the FLOWTRAN simulation program and is reproduced in: 10. Henley, E.J., & J.D. Seader. Equilibrium-Stage Separation Processes in Chemical Engineering. Wiley (1981). Phase .equilibrium data have been collected recently in a comprehensive manner in the books of Gmehling & Onken (1977 ff)., Kogan et al. (1966), Landolt-Börnstein (1966date), Maczynski et al. (1976ff.), Hirata et al. (1976), and
Sorensen & Arlt (1979-1980). A bibliography of equilibrium properties of fluids has been prepared by Hiza, Kidnay, & Miller (1975, 1982). In Table D. 1, the constants of the equation of the equili brium constants of formation, \ogl0Kp =
A+B/T,
were obtained by regression of the tabulated data of Stull et al. (1969) over the temperature range 298-1,000 K. The general data of Table D.2 are excerpted from a revision of a table that appears in Reid et al. (1977), except for the solubility parameters, which are gathered from other sources. Table D.I. Equilibrium Constants of Formation, \ogl0Kp =A+ 1,000 BIT over the temperature range 2 9 8 1,000 K Formula HC1 H20 H2S H3N H4N2
so2 so3 COCl
2
CC1 4 CO
co2 cs2 CHC13 CH202 CH 4 CH4O C2H2 C2H3N C2H4 C2H40 C2H402 C2H6 C2H60 C3H6 C3H60 C
3H8
C3H80 C3H80 C4H6 C4H6 C4H8 C4H8 C4H8 C4H80 C4H802 C4H802 C4H10 C4H10 C4HJOO C4HJOO C4HJOO
C4H10O
Name hydrogen chloride water hydrogen sulfide ammonia hydrazine sulfur dioxide sulfur trioxide phosgene carbon tetrachloride carbon monoxide carbon dioxide carbon disulfide chloroform formic acid methane methanol acetylene acetonitrile ethylene acetaldehyde acetic acid ethane ethanol propylene acetone propane 1-propanol isopropanol 1,2-butadiene 1,3-butadiene 1-butène cis-2-butene trans-2-butene methyl ethyl ketone 1,4-dioxane ethyl acetate «-butane isobutane /i-butanol isobutanol tert-butyl alcohol ethyl ether
A
B
0.4285 4.852 -2.6322 12.7401 1.1627 1.4390 -5.7596 2.5853 -11.8129 -4.7331 -0.2973 15.8165 -5.1933 20.9378 -2.4317 11.5237 -7.0782 5.1369 4.7272 5.7622 0.1165 20.5658 7.3293 - 5 . 5 9 3 9 5.8676 5.3323 -7.0563 20.5541 -5.1030 4.2138 -7.7901 10.8527 2.9533 -11.8005 -3.7480 -4.3729 -3.6279 -2.4422 -6.7327 9.0089 -11.1003 23.0204 -10.4383 4.8874 -13.0030 12.7215 -8.7127 -0.6258 -12.6811 11.8304 -15.8040 6.0076 -18.8086 14.5270 -18.9711 14.7867 -7.4546 -8.0979 -8.1031 -5.4136 -14.1659 0.5660 -14.6256 0.9963 -14.6446 1.1448 -17.7890 12.9993 -25.4654 17.1068 -21.8841 23.6913 -21.1552 7.2844 -21.9428 7.7140 -23.7886 15.0466 -23.8537 15.9293 -25.5398 17.6692 -24.8400 13.8636 577
578
Appendix D. Physical Properties
Table D.l C5H5N C
5H8
C5H12 C
5H12 C H 5 12
C5H120 C
6H6
C6H60 C6H7N C6H12 QH14 C7H602 C7H8 C
7H16
CgHg C
8H10
C8H18
Table D.2 (continued)
(continued) pyridine isoprene /i-pentane 2-methyl butane 2,2-dimethyl propane 1-pentanol benzene phenol aniline cyclohexane «-hexane benzoic acid toluene «-heptane styrene ethyl benzene «-octane
-9.9614 -13.5832 -26.5977 -26.8757 -28.6731 -29.2003 -9.5963 -12.2574 -15.3245 -29.8950 -32.0048 -15.8402 -14.3874 -37.4102 -13.1807 -19.7509 -42.0549
-6.9212 -3.5175 8.4631 8.8811 9.4316 16.6242 -3.8557 5.4163 -4.0887 7.3581 9.6646 15.7865 -2.0150 10.8575 -7.1768 -0.8499 12.0549
ANT 1 TO ANT7
TMIN TMAX DHVB
δ *i
Table D.2\. Property Data Bank Selected from Appendix A of The Properties of Gases and Liquids, by Reid, Prausnitz, & Sherwood, published by McGraw-Hill Book Company (1977), in the version prepared for CAST, Massachusetts Institute of Technology, by J.F. Boston. Conversion factors to other common units are shown in parentheses following. Codes and Units of the Properties MW TFP TB TC PC VC ZC OMEGA VL TREF MUP CPIG1 TO CPIG4
VISC 1 VISC 2
DHFORM
DGFORM
MOLECULAR WEIGHT NORMAL FREEZING POINT, K NORMAL BOILING POINT, K CRITICAL TEMPERATURE, K CRITICAL PRESSURE, N/M**2 (X 1/101,325 = atm) CRITICAL VOLUME, M**3/KG-MOLE (= liters/gmol) CRITICAL COMPRESSIBILITY PITZER ACENTRIC FACTOR LIQUID DENSITY AT TREF, KG/M**3 (= grams/liter) REFERENCE TEMPERATURE FOR VL. K DIPOLE MOMENT, (N M**4)**.5 (X0.3162D25 = Debye) CONSTANTS FOR IDEAL GAS HEAT CAPACITY EQUATION. CP = CPIG1 + (CPIG2*T) + (CPIG3*T**2) + (CPIG4*T**3) IN (N M/KG-MOLE K) AND T IN K [x2.388D-4=cal/(gmol)(K)l LIQUID VISCOSITY EQUATION CONSTANT, Ns/m 2 (X 1,000 = centipoise) LIQUID VISCOSITY EQUATION CONSTANT, K LOG(VISC) = (VISC1)* ((1/T)*(1/VISC2)) STANDARD ENTHALPY OF FORMATION AT 298 K, N M/KG-MOLE (X 2.388D-4=cal/gmol) STANDARD GIBBS ENERGY OF FORMATION AT 298 K. IDEAL GAS, 1
ATM, N M/KG-MOLE (X 2.388D-4 = cal/gmol) ANTOINE VAPOUR PRESSURE EQUATION COEFFICIENTS, LN(VP) = ANT1 + ANT2/(T + ANT3) + (ANT4*T) + (ANT5*LN(T)) + (ANT6*T** ANT7) WITH VAPOUR PRESSURE IN PA, AND TEMPERATURE IN K (X 1/101325 = atm) MINIMUM TEMPERATURE FOR ANTOINE EQUATION, K MAXIMUM TEMPERATURE FOR ANTOINE EQUATION, K HEAT OF VAPOURIZATION AT NORMAL BOILING POINT, N M/KG-MOLE (X 2.388D-4 = cal/gmol) SOLUBILITY PARAMETER AT 25 C, (CAL/ML) 0 · 5 SOLUBILITY PARAMETER AT 25 C, (MPa) 0 · 5
4
0.65314080D+07 5.33 10.91
DHVB 6
0.0 0.0
DHFORM DGFORM
-0.73078490D+04 0.17633770D+06 0.39 162290D+02 -0.638494 1ODSO 1 O.l4404790D+04 0.5 824 1780D-02 0.2OOOOOOOD+O 1 0.83800000Df02 O.l5080000D+03
O.l075700OD+03 0.22268146D+02
VISCl VISC2
ANT1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
0.1 9196OOOD+O3 0.46662679D+02
0.0
0.2043 1584D+08 8.708 17.818
-0.361433 10D-I-04 0.19292300D+06 0.10600010D+03 -0.10226 150D+01 0.60082960D+03 0.36163370D-03 0.20000000D+01 O.l7220000D+03 0.41700000D+03
0.0 0.0
0.26929498D+05 0.338377 18Df02 -0.38690219D-01 0.15470226D-04
0.20804209Df05 -0.321 12756D-01 0.51665112D-04
CPIG 1 CPIG2 CPIG3 CPIG4
0.1616 1048D-I-08 7.01 10 14.346
-0.64603 120D+04 0.28430820D+06 0.82323240D+02 -0.2361 2360D+01 0.1 1128860D+04 0.10312470D-02 0.20000000D+01 0.1590OOOODf03 0.32460000Df03
0.30291498D+05 -0.7201 2960D+01 0.12459917D-01 -0.38979 108D-05
0.34785054D-24
0.63245552D-25
MUP
0.0
0.1 1930000Df04 0.188 1OO00Df03
0.1 2000000D+00
0.15630000D+04 0.239 10000D+03
0.73000OOOD-0 1
0.3246OOOOD+03 0.83086500Df07 0.8 1OOOOOOD-0 1 0.24900000DfOO
HCL 0.36461000D+02 0.15900000D+03 0.18810OOODS03
HYDROGEN CHLORIDE
VL TREF
OMEGA
-0.40000000D -02
0.41700000D+03 0.77007000D+07 0.12400000D+00 0.275OOOOOD+OO
0.15080000D+03 0.48737325Df07 0.7490OOOOD -0 1 0.29 100000D+00
TC PC
vc zc
CL2 0.70906000D+02 0.1 7220000D+03 0.23870000D+03
AR 0.39948000D+02 0.83800000D+02 0.87300000D+02
CHLORINE
FORMULA MW TFP TB
ARGON
-0.5 1752 110D-I-04 0.38036580D+05 0.82040620D+O 1 -0.30307020D+02 O.l4664860D+O4 O.l2734970D+OO 0.20000000DfO 1 0.15660000D+02 0.3 320WOD+02
0.0 0.0
O.I382OOOOD+02 0.2483821 3D+01
0.27 143024D+05 0.92737620D+01 -0.1 3808066D-01 0.76450968D-05
0.0
0.7 1000000Di-02 0.20000000D+02
-22000000D+OO
0.33200000D+02 0.12969600D+07 0.65000000D-0 1 0.30500000D+OO
H2 0.20160000D+01 O.l4000000D+02 0.20400000D+02
HYDROGEN (NORMAL)
0.40683 136D+08 23.53 48.15
-0.3 1397400D+02 -0.20463660D+04 -0.75402240D+02 -0.12054280D-01 0.916575 10D+01 0.48791950D-17 0.60000000D+01 0.27 32WOD+03 0.64730000D-I-03
-0.24199704D-I-09 -0.22876675D-I-09
0.65 825000D+03 0.12362298D+03
0.32242547D+05 0.19238346D-I-01 0.105 54923D-0 1 -0.359646 12D-05
0.569209972)-24
0.64730000D-I-03 0.22048320D+08 0.5 6OOOOOOD-0 1 0.22900000D+00
H20 0,18015OOOD+02 0.27320000D+03 0.37320000D+03
WATER
0.18673128D+08 8.8 18.0
-0.82474460D+OO -0.1 8128770D+03 -0.5550484OD-01 0.2 1720190D+02 0.668 17760D- 10 0.40000000D+01 0.18760000D+03 0.37320000D-I-03
-0.9320 1210D+02
-0.20180376D+08 -0.33075720D+08
0.34279000D+03 0.67601597D-I-02
0.3 1941097D-I-05 0.143649 11D+01 0.24321121D-01 -0.1 1764908D-04
0.28460498D-24
0.99300000D+03 0.2 1360000D-tO3
O.l0000000D+OO
0.37320000D+03 0.89368650D+07 0.98500000D-01 0.28400000D+OO
H2S 0.34080000D+02 0.18760000D+03 0.2 128OOOOD+03
HYDROGEN SULFIDE
>
W
u
01
E
2 =.
U
9
Lu
n
5_.
=r 71
p
a
U ID 2
U
0.40560000D+03 0.1 1277473Di-08 0.72500000D+01 0.24200000D+00
TC PC
0.97678044D-l-04 0.18945270D+03 -0.1 657 1354D+00 0.60248052D-04 0.52498000D+03 0.10926159Df03
0.47434 164D-24
0.273 14683Df05 0.2383 1266D+02 0.17073770D-0 1 -0.1 1848644D-04
0.34904000Df03 0.6901 2222Df02
MUP
CPIG 1 CPIG2 CPIG3 CPIG4
VISC 1 VIsc2
0.44798760D-kO8 18.11 37.06
-0.36891000Df02 -0.80343580Df03 -0.66161870Df02 -0.2078526OD-01 0.10587760D+02 0.77121770D- 16 0.60000000D+0 1 O.l954OOOOD+03 0.40560000D+03
0.23362344D+08 12.408 25.389
ANT 1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
DHVB
s
-0.8 1937220Df04 0.67364210D+06 0.1 7465370D+03 -0.12760300D+Ol O.l251860OD+O4 0.2709293OD-03 0.20000000D+01 0.3591 5000D+03 0.65300000D+03
-0.4571 9856D+08 -0.16 161048D+08
DHFORM DGFORM
0.94868328D-24
0.63900000D+03 0.27320000Df03
0.92 109600D+05
0.0 0.0 0.0 0.30000000D+01 0.50000000Df0 1
0.0
0.17144170Df02 -0.33732900Df02 0.1 7900000Df 0 1
0.0 0.0
0.0 0.0
0.0 0.0 0.0 0.0
0.0
0.1 2300000Df03 0.43000000D+01
0.5 1900000Df01 0.22696800Df06 0.57300WOD-0 1 0.30 1OOOOODf 00
0.65300000D+03 0.14692125D+08 0.96 100000D-01 0.26000COOD+00
0.10080000DS04 0.29300000D+03
HE(4) 0.40030000D+01 0.0 0.42 100000Df01
H4N2 0.32045000D+02 0.27470000D+03 0.38670000D+03
~
HELI UM-4
~~
HYDRAZINE
VL TREF
OMEGA
vc zc
H3N 0.1 703 1000D+02 O.l954000OD+03 0.23970000D+03
FORMULA MW TFP TB
AMMONIA
0.25 100000D+00 O.l455OoOOD+04 0.26 30OOOOD+03 0.50596442D-24
0.2 1000000D-01
0.1 1490000Df04 0.90000000D+02 0.0
0.40000OOOD-0 1 0.80400000D+03 0.78 100000D+02
0.558 10044Df07 4.40 9.00
-O.l949643OD+04 0.47772050Df05 0.39737620D+02 -0.1349910OD+Ol 0.38108330Di-03 0.1386607OD-07 0.40000000D+0 1 0.63300000D+02 O.l262000OD+03
0.68244840D+07 4.0 8.18
-0.14079980Df04 0.39737770D+05 0.48151280D+02 -0.798951 IODfOO 0.26744380Df03 0.4929324OD-08 0.40000000D+ 0 1 0.61 840000D+02 O.l5460000D+03
0.0 0.0
0.85680000D+02 0.1837 1721 D f 0 2
0.90300000Di-02 0.1 8216343D+02 0.0 0.0
0.28105988D+05 -0.3680 1972D-02 0.17458956D-01 -0.10651219D-04
0.3 1149792D+05 -0.1 3565232D+02 0.26795520D-01 -0.1 1681172D-04
0.24932394D4-08 6.0 12.28
-0.1 8537 110D-I-02 -0.15622620D+04 -0.45780700D+02 -0.1772248OD-01 0.75 143910D+Ol 0.3573 1280D- 13 0.50000000D+ 0 1 O.l977000OD+03 0.43080000Df03
-0.29705346Df09 -0.30036103D+09
0.23852200Df05 0.66988800D+02 -0.49613580D-01 0.13280530D-04
0.43080000D+03 0.78830850D+07 0.12200000Di-00 0.26800000Df00
0.1546WOD+03 0.50459850D+07 0.73400WOD-0 1 0.28800000D+00
O.l262000OD+03 0.33943875D+07 0.89500000D-01 0.2900OOOODf 00
0.0
02s 0.64063000D+02 0.19770000D+03 0.26300000D+03
02 0.3 1999000D+02 0.54400000D+02 0.90200000Df02
N2 0.28013000D+02 0.63300000D+02 0.77400000Df02
SULFUR DIOXIDE
OXYGEN
NITROGEN
a
2 e.
U
9
P
to 0
01
0.17800000D+04 0.3 180OOOOD+03
0.0
OMEGA
VL TREF
MUP
0.24409044D+08 7.1200 14.5691
0.40678949D+08 15.329 31.366
DHVB
81
s
0.0 0.0 0.0 0.2 1300000D+03 0.34100000D+03
0.0
0.20649270D+02 -0.21673 100D+04 -0.43150000D+02
0.79498460D+05 -0.5 1465900D+07 0.1272191OD+03 0.16615650Di-02 -0.1 2628050D+05 -0.4425 5 980D-02 0.20000000D+O 1 0.29000000D+03 0.49 100000D+03
ANT1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN Th4AX
-0.22106304D+09 -0.20691 166D+09
0.0 0.0
-0.39552700D+09 -0.3 706 1554D+09
0.1 37 2 8000D+04 0.1869 1687D+03
0.28089241D+05 O.l360710OD+O3 -0.1 3736891D+00 0.50702148D-04
0.34785054D-24
0.13810000D+04 0.2 9300000D+03
0.2040OOOOD+00
CCL20 0.9891 6000D+02 0.14500000Dt03 0.28080000D+03
PHOSGENE
DHFORM DGFORM
VISC 1 vIsc2
CPIGl CPIG2 CPIG3 CPIG4
0.45904D+5 0.5240Di-2 -0.2731D-1 0.5560D-5
0.4 1000000DHO
vc zc
TC PC
0.49 100000D+03 0.82073250D+07 O.l3000000D+00 0.26000000D+00
FORMULA MW TFP TB
SULFUR TRIOXIDE
0.1 1714666Di-09 0.66946932D+08
-0.181021 1OD+04 0.14750340D+06 O.l7363370D+03 -0.23 123160D+OO 0.27678890D4-03 0.3 164495OD-10 0.4oOOCmOOD+O 1 0.22080000D-l-03 0.55200000D+03 0.2675 3652D+08 9.8640 20.1839
-0.39376854D+09 -0.39464777D4-09 -0.52840260D+04 0.309 15310D+06 0.1 1114140D+03 -0.10099290D+01 0.85020940D+03 0.1 8866410D-14 0.6oooOOOOD+O 1 0.1673 1000D+03 0.30420000D+03 0.17 165880D+08 7.1200 14.5691
-0.30121 770D+04 0.62507530D+05 0.33 139810D+02 -0.3334509OD+Ol 0.6 1935790D+03 0.37 10065OD-02 0.20000000D+01 0.68 100000D+02 0.13290000D+03 0.60457392D+07 3.1300 6.4047
-0.34210080D+02 -0.1 1587170D+04 -0.87403690D+02 -0.1 3500030D-01 0.93655890D+01 0.10799190D-16 0.60000000D+01 0.25000000D+03 0.55640000D+03 0.300 19356D+08 9.338 19.108
0.30869276D+05 -0.12853476D+02 0.27892462D-0 1 -0.1271 53 12D-04
-0.1 1061526D+09 -0.1 3736891D+09
0.54015000D+03 0.1 1120589D-i-03
0.407 16630D+05 0.2048601 2D+03 -0.22696643D+00 0.8842521 6D-04
0.27408000D-l-03 0.627344 1OD+O2
0.0
0.57808000D+03 0.94446586DI-02
0.0
0.27444474D+05 0.8 1265788D+02 -0.76660308D-01 0.2672853 1D-04
0.3 1622776D-25
0.19795 190D+05 0.73436472D+02 -0.5 60 19384D-0 1 0.17 153320D-04
0.0
0.1 5840000D+04 0.2 980OOOOD +03
0.1 1500000D+00
0.552oooOOD+O3 0.79033500D+07 0.17oOOoOOD+00 0.29300000D-l-00
0.30420000D+03 0.73764600D+07 0.94000000D-01 0.27400000D+00
0.13290000D+03 0.34957 125D+07 0.93 100000D-0 1 0.29500000Di-00
0.55640000D+03 0.45596250D+07 0.27600000D+00 0.2 720WOD +00 0.49OOOOOOD-0 1
cs2 0.7613 1000D+02 0.16 13oOOOD+03 0.3 1940000D+03
CARBON DISULFIDE
c02 0.44010000D+02 0.21660000D+03 0.19470000D+03
CARBON DIOXIDE
0.28010000D+02 0.68 ~~~~~~02 0.8 1700000Dt02
co
CARBON MONOXIDE
CCIA 0.15382300D+03 0.25000000D+03 0.34970000D+03
CARBON TETRACHLORIDE
a
3 rn
> U
U
582
A p p e n d i x D. Physical Properties
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0.1 1504590D+03 -0.7769 1770D+04 0.1 052 17 1OD +02 0.1 1846230D-01 -0.14594400D+02 0.13296100D-16 0.6000OOOOD+O 1 0.20272000D+03 0.5 0680000D+ 03
0.16550420D+05 0.22453808D+03 -0.434171 16D-01 0.29144315D-04
0.56689272Di-04 0.36889895D+03 -0.28646086D+00 0.987666 12D-04
0.6301 1340D+04 0.26058643D+03 -O.l2526906D+OO 0.20377 156D-04 0.36725000D+03 0.77291 732D+02
0.53758719D-24
0.47434164D-24
0.9 1706050D-24
0.18786172D+08 6.400 13.096
-0.2 1284520D+04 0.1 1710080D+06 0.10987330D+03 -0.4947 1660D+00 0.35067670D+03 0.1 7788010D-06 0.3~OoOOD+O1 0.14792000D+03 0.36980000D+03
0.10391 638D+09 -0.23487948D+08
-0.422448 12D4-04 0.30626442D+03 -0.15863785D+00 0.32 146250D-04
0.1 5200000D+OO
0.32400000D+ 00
0.5 3600000D+00 0.7 9000000D+ 03 0.29300000D+03
0.36980000D+03 0.42455 175D+07 0.20300000D+00 0.28100000D+00
0.506 80000D+ 03 0.46913475D+07 0.2 2800000D+00 0.254000OOD+OO
0.61200000D+03 0.537022501)+07 0.2 3OOOOOOD+00 0.24200000D+00
0.41784264D+08 12.050 24.657
0.39826350D+03 -0.22098850D+05 0.281 34120D+02 0.5 5 27422OD-0 1 -0.59550090D+02 0.33038320D-05 0.20000000D4-0 1 0.21468000D+03 0.53670000D+03
-0.25656710Di-09 -0.16 190356D+09
0.95 104000D+03 0.16 116547Di-03
0.24702120DI-04 0.3325 I566Dt03 -0.1 855 1711D+00 0.42956568D-04
0.53758719D-24
0.62400000Dt00
0.5 367OOOOD+03 0.5 1675750Dt07 0.2185000OD+OO 0.25300000D+00
C3H80 0.60096000D+02 0.14690000Dt03 0.37040000D+03
C3H8 0.440970001)+02 0.85500000D+02 0.231 10000Di-03
0.508 10000D+03 0.47014800D+07 0.20900000D+00 0.2 3200000D+ 00
I-PROPANOL
PROPANE
C3H602 0.7 408oOOOD+02 0.25250000D+03 0.41400000D+03
METHYL ACETATE
C3H60 0.58080000D+02 0.17820000D+03 0.32940000D+03
ACETONE
PROPIONIC ACID
a
UI 0
4
0.61 127280D+08 17.69 36.20
0.39858336D+08 11.572 23.679
s
DHVB
-0.5 853 1464D+09
0.3337 1000D+04 0.2974386 1D4-03
0.221 3 1970D+02 -0.44870400D+04 -O.l402000OD+O3 0.0 0.0 0.0 0.0 0.44000000D+03 0.60000000D+03
0.1 1397000D+04 0.1 7470193D+03
vISCl vIsc2
0.84238416D+04 0.44421948D+03 -0.3 1589406Di-00 0.93784320D-04
0.23585670D+02 -0.3 6402000D+04 -0.5 354WODi-02 0.0 0.0 0.0 0.0 0.27300000D+03 0.3 7400000D+03
0.32426766D+05 0.18848974D+03 0.6405 804OD-0 1 -0.9261201 6D-04
CPIGl CPIG2 CPIG3 CPIG4
0.94868328D-24
ANT 1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
0.53758719D-24
MUP
0.0
0.7 8600WOD+03 0.29300000D+03
VL TREF
0.0
0.72600000D+03 0.66874500D+07 0.2 5 5 00000D+ 00 0.28000000D+00
C3H803 0.92095000D4-02 0.29 100000D+03 0.56300000D+03
GL YCER OL
DHFORh4 DGFORM
0.7 2400000D+ 00
C3H80 0.60096000D+02 0.18470000D+03 0.35540000D-tO3
OMEGA
ZC
vc
Pc
TC
FORMULA MW TFP TB
ISOPROPYL ALCOHOL
0.24283440D+08 7.950 16.267
0.20996670D+02 -0.23972600D+04 -0.30880000D+02 0.0 0.0 0.0 0.0 0.24500000D+03 0.30500000D+03
0.0 0.0
0.1 1199690Di-05 0.27235134D+03 -0.14683108D+00 0.308902 1OD-04
0.126491 10D-24
C4H6 0.54092000D+02 0.13700000D+03 0.28400000D+03
1.2-B UTADIENE
0.22483 1 16D-I-08 6.940 14.201
0.20665470D+02 -0.21 426600D+04 -0.34300000D+02 0.0 0.0 0.0 0.0 0.21500000D+03 0.29000000D+03
0.1 1023844D+09 0.1 5076667D+09
0.30059000D+03 0.62070056D+02
-O.l6872804D+04 0.341 85222D+03 -0.23400025D+00 0.63346284D-04
0.0
0.62 100000D+03 0.29300000D+03
0.1 9500000D+OO
C4H6 0.54092000D+02 0.16430000D+03 0.26870000Di-03
I , 3-B UTADIENE
0.21930458D+08 6.766 13.845
-0.26389800D+04 0.14105410D+06 0.10929260D+03 -0.76149810D+00 0.44014500D+03 0.27743420D-03 0.20000000D-l-0 1 0.16784000D+03 0.4 1960000D+03
-0.12560400D+06 0.7 1343072D+08
-0.29935620D+04 0.35319845D+03 -0.19904047D+00 0.44631288D-04
0.94868328D-25
0.5 9500000D+03 0.29300000D+03
0.1 8700000D+00
C4H8 0.56 108WODi-02 0.87800OOOD+ 02 0.26690000D+03
I-BUTENE
0.23362344D+08 6.760 13.832
-0.235 13930D+04 O.l2905430D+O6 0.1 1409570D+03 -0.65874770D+00 0.3907 1810D+03 0.23470370D-03 0.20000000D+O 1 0.1 7424000D+03 0.43560000D+03
0.26894000Di-03 0.56842739D+02
0.4396 1400D+03 0.29533687D+03 -0.10178111D+00 -0.6 154596OD-06
0.94868328D-25
0.62 IOOOOOD+03 0.2930oooOD+03
0.43560000D+03 0.42049875D+07 0.2 340WOD+ 00 0.27200000D+00
C4H8 0.56 108000D+02 O.l343OOOOD+O3 0.27690000D+03
CIS-2-BUTENE
>
n
z_.
U
0
c.l
n
5 _.
5 7)
0
a
3 rn
U
-0
0.5 356WOD+03 0.41543250D+07 0.26700000D+00 0.24900000D+00
TC PC
0.10944295D+05 0.3559 1987D+03 -O.l8999698D+00 0.39196822D-04
CPIG 1 CPIG2 CPIG3 CPIG4
0.20999670D+02 -0.27683800Di-04 -0.46900000D+02 0.0 0.0 0.0 0.0 0.27000000D+03 0.37000000Di-03 0.29600676D+08 9.10 18.62
-0.78357580D+04 0.53 123170D+06 0.1 3869530D+03 -0.15758780Di-01 0.12395040D+04 0.41455620D-03 0.200oooO0D+01 ~~~~~~~~~~03 0.5356WOD+03
0.3 1233528D-i-08 9.199 18.823
ANT1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
DHVB 6 61
-0.18434480D+09 0.0
-0.23852200D+09 -0.1461 61 19D+09
DHFORM DGFORM
0.41 979000D+03 0.88991097D+02
-0.1 9104368D+05 0.5 1623244D+03 -0.41315342D+00 0,145407562)-03
0.104355 16D-23
MUP
VISC 1 vIsc2
0.53758719D-24
0.805 00000D+ 03 0.29300000D+03
0.0
0.54020000D+03 0.5 1878400D+07 0.22400000D+00 0.2590000OD+OO
C4H80 0.72 107000D+02 0.16470000D+03 0.33910000D+03
TETRAHYDROFURAN
VL TREF
OMEGA
vc zc
TB
C4H80 0.72 107000D+02 0.18650000D+03 0.35280000D+03
FORMULA MW TFP
METHYL ETHYL KETONE
0.36383292D4-08 10.13 20.73
0.21025470D+02 -0.29668800D+04 -0.62 150000D+02 0.0 0.0 0.0 0.0 0.27500000D+03 0.41000000D+03
-0.3 1526604D+09 -0.18091 163Di-09
0.66036000D+03 0.12850773Di-03
-0.5 3574293D+05 0.59871240D+03 -0.40850608D+00 0.10621912D-03
0.126491 10D-24
0.5 8700000D+03 0.5208 1050D+07 0.23800000D+00 0.25400000D+00
C4H802 0.88 107000D+02 0.28500000D+03 0.37450000D+03
I . CDIOXANE
0.3223836ODl-08 8.974 18.363
0.20928000D+03 0.52320000D+03
~~~~~~~~01
0.486 10870Di-02 -0.82999240D+04 0.28708980D+02 -0.47696360D-01 -0.46 184520D+00 0.34456160D-04
-0.4432 1465D+09 -0.32761710D+09
0.42738000D+03 0.8882667 1D+02
0.72347904Di-04 0.407 16630D+03 -0.2091 7253D+00 0.28545602D-04
0.60083274D-24
C4H802 0.88 107000D+02 0.18960000D+03 0.35030000D4-03
ETHYL ACETATE
0.22407754Di-08 6.634 13.575
-0.20775660D+04 0.1 3037520D+06 0.12967170D+03 -0.40673270D+00 0.33409570D+03 0.1 11357801)-06 0.30000000D+01 0.1 7008000D+03 0.42520000D+03
-0.1 2623202D+09 -0.17 165880D+08
0.26584000D+03 0.5705424 1D+02
0.94872888D+04 0.33 130148D+03 -0.1 1082460D+00 -0.2821 9032D-05
0.0
0.5 7900000D+03 0.29300000D+03
0.1 9300000D+00
C4H 1 0 0.58 124000D+02 0.1 3480000D+03 0.27270000D+03
N-B UTANE
0.2 1310812D+08 6.730 13.771
-0.22805 130D+04 0.13705 180D-t-06 0.12196710D+03 -0.46894860D+00 0.369145 10D4-03 0.1 3719500D-06 0.3000000OD+Ol O.l6324OOOD+03 0.408 1WOD+03
-0.1 3460562D+09 -0.208921 32Di-08
0.3025 1000D+03 0.63321324Di-02
-0.1 3900176Di-04 0.38472505Di-03 -0.1 845960 1D +00 0.2895 1722D-04
0.3 1622776D-25
0.55 700000D+03 0.29300000D+03
O.l7600000D+00
0.40810000D+03 0.36477000Di-07 0.26 30OOOODt00 0.28300000Dt00
0.58124000D+02 0.1 1360000Dt03 0.261 30000Dt03
C4H10
ISOB UTANE
E
: 5.
7J
7
'y
2n -.
0 5
P
a
3
> -0 7J
cn m m
C4H100 0.74123000D+02 0.29880000D+03 0.35560000D+03
C4H100 0.74123000D+02 0.16520000D+03 0.38 100000D+03 0.54770000D+03 0.4296 1800D+07 0.27300000D+00 0.25700000D+00
C4H100 0.74123000D+02 0.1 585OoOOD-tO3 0.37270000D+03
-0.77078988D+04 0.46892160D+03 -0.28838678D+00 0.72306036D-04 0.1 1991000D+04 0.18483874D+03
0.57600000D+00 0.80700000D+03 0.29300000D+03 0.537587 19D-24 0.57526632D+04 0.42454152D+03 -0.23282795D+00 0.47729520D-04 0.144 I 7000D+04 0.19617583D+03
0.56290000D+03 0.44177700D+07 0.27400000D-tOO 0.25900000D+00
0.59OOOOOOD+00 0.81000000D+03 0.29300000D+03
0.56920997D-24
0.32657040D+04 0.4180101 1D+03 -0.22416127D+00 0.46850292D-04
TC
zc
OMEGA VL TREF
MUP
CPIG 1 CPIG2 CPIG3 CPIG4
0.40821300D+08 1 1.08 22.67
0.43 124040D+08 1 1.440 23.409
81
8
DHVB
0.22108770D+02 -0.3 1370200D+04 -0.94430000D+02
ANT1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
0.0 0.0 0.0 0.28800000D+03 0.40400000D+03
0.0
0.22102970D+02 -0.30260300D+04 -0.86650000D+02 0.0 0.0 0.0 0.0 0.29800000D+03 0.39300000D+03
-0.27486342D-I-09 -O.l5089227D+09
DHFORM DGFORM
VISCl VISC2
vc
Pc
TB
TFP
0.42077340D+08 10.949 22.404
0.2 1763970D+02 -0.28747344D+04 -0.10030000D+03 0.0 0.0 0.0 0.0 0.29300000D-kO3 0.3 8800000D+03
-0.28340449D+09 -0.1674301 3D+09
0.53758719D-24
0.5 8800000D+00 0.80200000D+03 0.29300000D+03
0.5 3600000D+03 0.41948550D+07 0.26800000D+00 0.25200000D+00
C4H100 0.74123000D+02 O.l8390000D+03 0.39090000D+03
MW
0.39062844D+08 10.316 21.109
0.2 1747570D+02 -0.26582900D+04 -0.95500000D+02 0.0 0.0 0.0 0.0 0.29300000D+03 0.37600000D+03
-0.3 1262836D+09 -0.1 7777153D+09
0.97210000D+03 0.1 7129030D+03
-0.48612935D+05 0.7 1719884D+03 -0.70840656D+00 0.291987431)-03
0.53758719D-24
TERT-BUTYL ALCOHOL
ISOB UTANOL
2-BUTANOL
FORMULA
N-B UTANOL
0.2671 I784D+08 7.544 15.437
0.98234300D-kOI -0.25462230D+04 -0.3544279OD-kO2 -0.68873780D-02 0.22952660D-kOl 0.28640650D- 16 0.60000000D+01 0.18668000D+03 0.46670000D+03
-0.25238030D+09 -0.1 2242203D+09
0.353 14OOOD+O3 0.7276 7733DS-02
0.2 1423856D+05 0.335865 10D+03 -0.1035 3956D+W -0.9357498OD-05
0.41 109609D-24
0.28100000D+00 0.7 130oooOD+03 0.29300000D+03
0.46670000D+03 0.36375675D+07 0.28000000D+00 0.26200000D+00
C4H100 0.74123000D+02 0.15690000D+03 0.30770000D+03
ETHYL ETHER
0.57233556D+08 13.551 27.728
0.2 1925370Dt02 -0.4 1225200Dt04 -0.12250000D+03 0.0 0.0 0.0 0.0 0.40200000D+03 0.5 600OOOOD+03
-0.57149820D+09 0.0
0.1943cKlOOD+04 0.241 55823D+03
0.73059660Dt05 0.34608089Di-03 -0.1 4678921D+00 0.18463788D-04
0.0
0.0 0.1 1160000Dt04 0.29300000D+03
0.68 1OOOOOD+03 0.46609500D+07 0.3 16ooOOOD+OO 0.26000000D+00
C4H1003 0.106 122WDi-03 0.26500000D+03 0.5 19ooOoOD+03
DIE THYL.ENE GLYCOL
m v
0.3 1366000D+03 0.66469257D-I-02
0.3979 1347Df05 0.49278636Df03 -0.35579426Df00 0.100441 33D-03
0.6 1850000D+03 0.12077243D+03
CPIGl CPIG2 CPIG3 CPIG4
VISC 1 VIsc2
0.25790688D+08 7.020 14.364
0.35 169120D+08 10.62 21.73
DHVB
s
-0.31 144360Di-02 -0.12065390D-l-04 -0.64139850Df02 -0.16082770D-01 0.9 1627870Df01 0.31313440D-16 0.60000000Df01 0.18784000Df03 0.46960000Df03
0.20983770D+02 -0.3095 1300Df04 -0.61 150000Df02 0.0 0.0 0.0 0.0 0.28500000D+03 0.42500000D+03
ANT 1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
DHFORM DGFORM
-0.36257688D-I-04 0.48734352D-l-03 -0.25803248D-kOO 0.53046756D-04
0.72732385D-24
MUP 0.0
0.9 8300000D 0 3 0.29300000Df03
0.24702120D+08 7.020 14.364
-0.2 59659 1OD +04 0.1 5024030D+06 0.12090470Df03 -0.67404480Df00 0.42657630Df03 0.2250 1220D-03 0.20000000Df01 0.1 8416000D+03 0.46040000D+03
0.30781354D-kO8 9.158 18.739
0.0 0.0 0.0 0.3 1000000Di-03 0.41 100000Df03 0.44380080D+08 11.12 22.75 0.2276781 8Di-08 7.020 14.364
0.0
-0.37675460D4-02 -O.l0975230D+04 -0.93532510D+02 -0.14047730D-01 0.9948222OD+Ol 0.10416500D- 16 0.60000000D+01 0.27870000D+03 0.562 1WOD+03
0.82982376D-I-08 0.12974893Di-09
-0.339 17267D+05 0.47436444D-kO3 -0.3017008 1D+00 0.7 1301204D-04
0.0
-0.53893750D-i-04 0.3 1478200D+06 0.1 1741390D+03 -0.1 3554940D+01 0.879 16190D+03 0.43847210D-03 0.20000000D-kOl 0.25660000D+03 0.43380000D+03
0.21419770Df02 -0.30268900Di-04 -0.10500000D+03
-0.29893752Di-09 -0.1461 1932D+09
-O.l6609036D+09 -0.1 5239952D+08
-0.1 5457666D+09 -0.1 4821272D+08
0.3 8686032D+04 0.50450940D-l-03 -0.26393587D+00 0.51204564D-04
0.537587 19D-24
0.1151 1000D+04 O.l8293405D+03
-0.16592288Di-05 0.555 16968D+03 -0.33063 160D+W 0.76325364D-04
0.0
0.8 1500000DS03 0.29300000D+03
0.36732000D-I-03 0.74699240Df02
-0.95249700D+04 0.50660280D-kO3 -0.27293749Dl-00 0.57233556D-04
0.3 1622776D-25
0.59 100000D+03 0.29300000D+03
0.562 10000D+03 0.48939975D-I-07 0.25900000D+00 0.27 100000D+00
0.5 8600000D+03 0.38503500Df07 0.326OOOOOD+OO 0.26000000D+00
0.43380000D+03 0.3201 8700Di-07 0.30300000D+00 0.26900000D+00
0.46040000D+03 0.33842550D+07 0.30600000D+00 0.27 100000D+00
0.46960000D+03 0.33741225D+07 0.3 0400000D+00 0.2 6200000D+00
0.2 1200000D+00
C6H6 0.781 14000Di-02 0.27870000D+03 0.35 330000D+03
C5H120 0.88 150000D+02 O.l950000OD+03 0.41 100000Df03
C5H12 0.72151000D+02 0.25660000D+03 0.28260000D+03
BENZENE
C5H12 0.7215 1000D+02 0.1 1330000D+03 0.30100000D+03
I-PENTANOL
C5H12 0.7215 1000Df02 0.14340000D+03 0.3 0920000D+03
N-PENTANE
VL TREF
OMEGA
vc zc
+
0.62000000Df03 0.56336700D+07 0.25400000Df00 0.2 7700000D+00
TC PC
TFP TB
Mw
C5H5N 0.79 102000D+02 0.23 150000D-l-03 0.38850000D-kO3
FORMULA
PYRIDINE
2,I-DIMETHYL PROPANE
2-METHYL BUTANE
b
m
03
VI
589
Appendix D. Physical Properties
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s
DHVB
ANT1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
0.36006480D-I-08 8.769 17.943
0.35587800D-I-08 8.783 17.972
0.34436430Di-08 7.551 15.451
0.36843840Dl-08 8.987 18.389
0.36843840Di-08 9.21 1 18.848
0.0 0.0 0.0 0.30500000D+03 0.4600000OD-I-03
0.36383292DI-08 8.818 18.044
-0.1 1737850D-I-03 -0.15641240D+04 -0.60739230D-I-02 -0.8668081OD-01 0.2697 1140D+02 0.41 398210D-04 0.20000000D-I-01 0.2275200OD-I-03 0.56880000D-I-03
-0.1 293 1300D+02 -0.33902620D-I-04 -0.36508840D+02 -0.155391 80D-01 0.66026580D-I-01 0.7144069OD-11 0.40000000D+01 0.24684000D-I-03 0.6 1710000D-I-03 -0.43637890D-I-04 0.33397640D-I-06 0.16450780D-I-03 -0.76 178230D-I-00 0.6775002OD-I-03 0.1 804438OD-03 0.20000000D+01 0.28640000D+03 0.61620000D+03
-0.32447 180D-I-04 0.24302390D-I-06 0.16336200D-I-03 -0.58847630D-I-00 0.50685500D-I-03 0.14444320D-03 0.20000000D-I-01 0.24680000D+03 0.6 1700000D+03
0.8081 1040D-I-01 -0.34240540D-I-04 -0.508 15350D+02 -0.52463410D-02 0.24766890D+01 0.48 165370D-17 0.60000COOD-I-01 0.25208000D+03 0.63020000D+03
0.20912070D-I-02 -0.33285700D+04 -0.63720000D-I-02
0.0
-0.20858638D+09 0.16412256D-I-08
0.2981oO16D+08 0.1 3067003D+09
0.17961372D-I-08 0.12120786D-I-09
0.1 7249616Di-08 0.1 1894699Di-09
0.19008072D-I-08 0.12217082D-I-09
0.14745910D+09 0.21 394548Di-09
DHFORM DGFORM
0.47370000D-I-03 0.97031344D-I-02 0.47282000D-I-03 0.98720249D-I-02
0.47516000D-I-03 0.98626941D-I-02
0.5 1354000D-I-03 0.10594135D-I-03
-0.60959808D-I-04 0.77 120856D-I-03 -0.41951736D-I-00 0.88550820D-04
0.45342000D+03 0.95 195399D-I-02
0.52864000D-I-03 0.1076561 7D-I-03
VISCl VISC2
-0.29165249D-I-05 0.62969472D-I-03 -0.37471860D-I-00 0.84782700D-04
-0.1585 1225D-I-05 0.59620032D+03 -0.34432243D-kOO 0.75278664D-04
0.0
0.70300000D-I-03 0.29300000D-I-03
0.568800OOD-I-03 0.24824625D-I-07 0.49200000D+00 0.25 900000D-I-00
C8H18 0.11423200D-I-03 0.21640000D-I-03 0.39880000D-I-03
N- OCTANE
-0.4309891 9D-I-05 0.7071 5052D+03 -0.48106332D+00 0.1 3OO8388D-03
-0.28248340D-I-05 0.61587828D-I-03 -0.4023096 1D-I-00 0.99352764D-04
CPIGl CPIG2 CPIG3 CPIG4
0.126491 10D-24
0.86700000D-I-03 0.29300000D-I-03
0.30 100000D-I-00
0.6 171OOOOD-I-03 0.3607 1700D-I-07 0.3 7400000D+00 0.26300000D-I-00
C8H10 0.10616800D+03 O.l7820000D+03 0.40930000D+03
ETHYLBENZENE
-0.2509 1492D+05 0.6041 5524D-I-03 -0.33737234D-I-00 0.68202972D-04
0.31622776D-25
MUP
0.3 1622776D-25
0.86 100000D+03 0.29300000D+03
0.86400000D-I-03 0.29300000D+03
OMEGA
0.94868328D-25
0.32400000D-I-00
0.33 100000D+00
0.3 1400000D+00
0.25700000D-I-00
vc zc
0.1581 13882)-24
0.6 1620000D+03 0.35 159775D+07 0.37900000Df00 0.26000000D+00
0.6 1700000D-I-03 0.35463750D-kO7 0.37600000D-I-00 0.26000000Dl-00
0.63020000D-I-03 0.37287600D+07 0.36900000Df00 0.26300000D-I-00
0.64700000D+03 0.39922050Dl-07 0.0 0.0
TC PC
VL TREF
C8H10 0.10616800D-I-03 0.28640000D+03 0.41 150000D+03
C8H10 0.10616800D+03 0.22530000D-I-03 0.41230000D+03
C8H10 0.10616800D+03 0.24800000D+03 0.4 176oOOOD+03
P-XYLENE
C8H8 0.10415200D+03 0.24250000D-I-03 0.4183000OD-I-03
M-XYLENE
0-XYLENE
FORMULA MW TFP TB
STYRENE
1.
5 71
P
3
U U
>
0
Gl a
Sorensen & Arlt (1979-1980). A bibliography of equilibrium properties of fluids has been prepared by Hiza, Kidnay, & Miller (1975, 1982). In Table D. 1, the constants of the equation of the equili brium constants of formation, \ogl0Kp =
A+B/T,
were obtained by regression of the tabulated data of Stull et al. (1969) over the temperature range 298-1,000 K. The general data of Table D.2 are excerpted from a revision of a table that appears in Reid et al. (1977), except for the solubility parameters, which are gathered from other sources. Table D.I. Equilibrium Constants of Formation, \ogl0Kp =A+ 1,000 BIT over the temperature range 2 9 8 1,000 K Formula HC1 H20 H2S H3N H4N2
so2 so3 COCl
2
CC1 4 CO
co2 cs2 CHC13 CH202 CH 4 CH4O C2H2 C2H3N C2H4 C2H40 C2H402 C2H6 C2H60 C3H6 C3H60 C
3H8
C3H80 C3H80 C4H6 C4H6 C4H8 C4H8 C4H8 C4H80 C4H802 C4H802 C4H10 C4H10 C4HJOO C4HJOO C4HJOO
C4H10O
Name hydrogen chloride water hydrogen sulfide ammonia hydrazine sulfur dioxide sulfur trioxide phosgene carbon tetrachloride carbon monoxide carbon dioxide carbon disulfide chloroform formic acid methane methanol acetylene acetonitrile ethylene acetaldehyde acetic acid ethane ethanol propylene acetone propane 1-propanol isopropanol 1,2-butadiene 1,3-butadiene 1-butène cis-2-butene trans-2-butene methyl ethyl ketone 1,4-dioxane ethyl acetate «-butane isobutane /i-butanol isobutanol tert-butyl alcohol ethyl ether
A
B
0.4285 4.852 -2.6322 12.7401 1.1627 1.4390 -5.7596 2.5853 -11.8129 -4.7331 -0.2973 15.8165 -5.1933 20.9378 -2.4317 11.5237 -7.0782 5.1369 4.7272 5.7622 0.1165 20.5658 7.3293 - 5 . 5 9 3 9 5.8676 5.3323 -7.0563 20.5541 -5.1030 4.2138 -7.7901 10.8527 2.9533 -11.8005 -3.7480 -4.3729 -3.6279 -2.4422 -6.7327 9.0089 -11.1003 23.0204 -10.4383 4.8874 -13.0030 12.7215 -8.7127 -0.6258 -12.6811 11.8304 -15.8040 6.0076 -18.8086 14.5270 -18.9711 14.7867 -7.4546 -8.0979 -8.1031 -5.4136 -14.1659 0.5660 -14.6256 0.9963 -14.6446 1.1448 -17.7890 12.9993 -25.4654 17.1068 -21.8841 23.6913 -21.1552 7.2844 -21.9428 7.7140 -23.7886 15.0466 -23.8537 15.9293 -25.5398 17.6692 -24.8400 13.8636 577
578
Appendix D. Physical Properties
Table D.l C5H5N C
5H8
C5H12 C
5H12 C H 5 12
C5H120 C
6H6
C6H60 C6H7N C6H12 QH14 C7H602 C7H8 C
7H16
CgHg C
8H10
C8H18
Table D.2 (continued)
(continued) pyridine isoprene /i-pentane 2-methyl butane 2,2-dimethyl propane 1-pentanol benzene phenol aniline cyclohexane «-hexane benzoic acid toluene «-heptane styrene ethyl benzene «-octane
-9.9614 -13.5832 -26.5977 -26.8757 -28.6731 -29.2003 -9.5963 -12.2574 -15.3245 -29.8950 -32.0048 -15.8402 -14.3874 -37.4102 -13.1807 -19.7509 -42.0549
-6.9212 -3.5175 8.4631 8.8811 9.4316 16.6242 -3.8557 5.4163 -4.0887 7.3581 9.6646 15.7865 -2.0150 10.8575 -7.1768 -0.8499 12.0549
ANT 1 TO ANT7
TMIN TMAX DHVB
δ *i
Table D.2\. Property Data Bank Selected from Appendix A of The Properties of Gases and Liquids, by Reid, Prausnitz, & Sherwood, published by McGraw-Hill Book Company (1977), in the version prepared for CAST, Massachusetts Institute of Technology, by J.F. Boston. Conversion factors to other common units are shown in parentheses following. Codes and Units of the Properties MW TFP TB TC PC VC ZC OMEGA VL TREF MUP CPIG1 TO CPIG4
VISC 1 VISC 2
DHFORM
DGFORM
MOLECULAR WEIGHT NORMAL FREEZING POINT, K NORMAL BOILING POINT, K CRITICAL TEMPERATURE, K CRITICAL PRESSURE, N/M**2 (X 1/101,325 = atm) CRITICAL VOLUME, M**3/KG-MOLE (= liters/gmol) CRITICAL COMPRESSIBILITY PITZER ACENTRIC FACTOR LIQUID DENSITY AT TREF, KG/M**3 (= grams/liter) REFERENCE TEMPERATURE FOR VL. K DIPOLE MOMENT, (N M**4)**.5 (X0.3162D25 = Debye) CONSTANTS FOR IDEAL GAS HEAT CAPACITY EQUATION. CP = CPIG1 + (CPIG2*T) + (CPIG3*T**2) + (CPIG4*T**3) IN (N M/KG-MOLE K) AND T IN K [x2.388D-4=cal/(gmol)(K)l LIQUID VISCOSITY EQUATION CONSTANT, Ns/m 2 (X 1,000 = centipoise) LIQUID VISCOSITY EQUATION CONSTANT, K LOG(VISC) = (VISC1)* ((1/T)*(1/VISC2)) STANDARD ENTHALPY OF FORMATION AT 298 K, N M/KG-MOLE (X 2.388D-4=cal/gmol) STANDARD GIBBS ENERGY OF FORMATION AT 298 K. IDEAL GAS, 1
ATM, N M/KG-MOLE (X 2.388D-4 = cal/gmol) ANTOINE VAPOUR PRESSURE EQUATION COEFFICIENTS, LN(VP) = ANT1 + ANT2/(T + ANT3) + (ANT4*T) + (ANT5*LN(T)) + (ANT6*T** ANT7) WITH VAPOUR PRESSURE IN PA, AND TEMPERATURE IN K (X 1/101325 = atm) MINIMUM TEMPERATURE FOR ANTOINE EQUATION, K MAXIMUM TEMPERATURE FOR ANTOINE EQUATION, K HEAT OF VAPOURIZATION AT NORMAL BOILING POINT, N M/KG-MOLE (X 2.388D-4 = cal/gmol) SOLUBILITY PARAMETER AT 25 C, (CAL/ML) 0 · 5 SOLUBILITY PARAMETER AT 25 C, (MPa) 0 · 5
4
0.65314080D+07 5.33 10.91
DHVB 6
0.0 0.0
DHFORM DGFORM
-0.73078490D+04 0.17633770D+06 0.39 162290D+02 -0.638494 1ODSO 1 O.l4404790D+04 0.5 824 1780D-02 0.2OOOOOOOD+O 1 0.83800000Df02 O.l5080000D+03
O.l075700OD+03 0.22268146D+02
VISCl VISC2
ANT1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
0.1 9196OOOD+O3 0.46662679D+02
0.0
0.2043 1584D+08 8.708 17.818
-0.361433 10D-I-04 0.19292300D+06 0.10600010D+03 -0.10226 150D+01 0.60082960D+03 0.36163370D-03 0.20000000D+01 O.l7220000D+03 0.41700000D+03
0.0 0.0
0.26929498D+05 0.338377 18Df02 -0.38690219D-01 0.15470226D-04
0.20804209Df05 -0.321 12756D-01 0.51665112D-04
CPIG 1 CPIG2 CPIG3 CPIG4
0.1616 1048D-I-08 7.01 10 14.346
-0.64603 120D+04 0.28430820D+06 0.82323240D+02 -0.2361 2360D+01 0.1 1128860D+04 0.10312470D-02 0.20000000D+01 0.1590OOOODf03 0.32460000Df03
0.30291498D+05 -0.7201 2960D+01 0.12459917D-01 -0.38979 108D-05
0.34785054D-24
0.63245552D-25
MUP
0.0
0.1 1930000Df04 0.188 1OO00Df03
0.1 2000000D+00
0.15630000D+04 0.239 10000D+03
0.73000OOOD-0 1
0.3246OOOOD+03 0.83086500Df07 0.8 1OOOOOOD-0 1 0.24900000DfOO
HCL 0.36461000D+02 0.15900000D+03 0.18810OOODS03
HYDROGEN CHLORIDE
VL TREF
OMEGA
-0.40000000D -02
0.41700000D+03 0.77007000D+07 0.12400000D+00 0.275OOOOOD+OO
0.15080000D+03 0.48737325Df07 0.7490OOOOD -0 1 0.29 100000D+00
TC PC
vc zc
CL2 0.70906000D+02 0.1 7220000D+03 0.23870000D+03
AR 0.39948000D+02 0.83800000D+02 0.87300000D+02
CHLORINE
FORMULA MW TFP TB
ARGON
-0.5 1752 110D-I-04 0.38036580D+05 0.82040620D+O 1 -0.30307020D+02 O.l4664860D+O4 O.l2734970D+OO 0.20000000DfO 1 0.15660000D+02 0.3 320WOD+02
0.0 0.0
O.I382OOOOD+02 0.2483821 3D+01
0.27 143024D+05 0.92737620D+01 -0.1 3808066D-01 0.76450968D-05
0.0
0.7 1000000Di-02 0.20000000D+02
-22000000D+OO
0.33200000D+02 0.12969600D+07 0.65000000D-0 1 0.30500000D+OO
H2 0.20160000D+01 O.l4000000D+02 0.20400000D+02
HYDROGEN (NORMAL)
0.40683 136D+08 23.53 48.15
-0.3 1397400D+02 -0.20463660D+04 -0.75402240D+02 -0.12054280D-01 0.916575 10D+01 0.48791950D-17 0.60000000D+01 0.27 32WOD+03 0.64730000D-I-03
-0.24199704D-I-09 -0.22876675D-I-09
0.65 825000D+03 0.12362298D+03
0.32242547D+05 0.19238346D-I-01 0.105 54923D-0 1 -0.359646 12D-05
0.569209972)-24
0.64730000D-I-03 0.22048320D+08 0.5 6OOOOOOD-0 1 0.22900000D+00
H20 0,18015OOOD+02 0.27320000D+03 0.37320000D+03
WATER
0.18673128D+08 8.8 18.0
-0.82474460D+OO -0.1 8128770D+03 -0.5550484OD-01 0.2 1720190D+02 0.668 17760D- 10 0.40000000D+01 0.18760000D+03 0.37320000D-I-03
-0.9320 1210D+02
-0.20180376D+08 -0.33075720D+08
0.34279000D+03 0.67601597D-I-02
0.3 1941097D-I-05 0.143649 11D+01 0.24321121D-01 -0.1 1764908D-04
0.28460498D-24
0.99300000D+03 0.2 1360000D-tO3
O.l0000000D+OO
0.37320000D+03 0.89368650D+07 0.98500000D-01 0.28400000D+OO
H2S 0.34080000D+02 0.18760000D+03 0.2 128OOOOD+03
HYDROGEN SULFIDE
>
W
u
01
E
2 =.
U
9
Lu
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0.40560000D+03 0.1 1277473Di-08 0.72500000D+01 0.24200000D+00
TC PC
0.97678044D-l-04 0.18945270D+03 -0.1 657 1354D+00 0.60248052D-04 0.52498000D+03 0.10926159Df03
0.47434 164D-24
0.273 14683Df05 0.2383 1266D+02 0.17073770D-0 1 -0.1 1848644D-04
0.34904000Df03 0.6901 2222Df02
MUP
CPIG 1 CPIG2 CPIG3 CPIG4
VISC 1 VIsc2
0.44798760D-kO8 18.11 37.06
-0.36891000Df02 -0.80343580Df03 -0.66161870Df02 -0.2078526OD-01 0.10587760D+02 0.77121770D- 16 0.60000000D+0 1 O.l954OOOOD+03 0.40560000D+03
0.23362344D+08 12.408 25.389
ANT 1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
DHVB
s
-0.8 1937220Df04 0.67364210D+06 0.1 7465370D+03 -0.12760300D+Ol O.l251860OD+O4 0.2709293OD-03 0.20000000D+01 0.3591 5000D+03 0.65300000D+03
-0.4571 9856D+08 -0.16 161048D+08
DHFORM DGFORM
0.94868328D-24
0.63900000D+03 0.27320000Df03
0.92 109600D+05
0.0 0.0 0.0 0.30000000D+01 0.50000000Df0 1
0.0
0.17144170Df02 -0.33732900Df02 0.1 7900000Df 0 1
0.0 0.0
0.0 0.0
0.0 0.0 0.0 0.0
0.0
0.1 2300000Df03 0.43000000D+01
0.5 1900000Df01 0.22696800Df06 0.57300WOD-0 1 0.30 1OOOOODf 00
0.65300000D+03 0.14692125D+08 0.96 100000D-01 0.26000COOD+00
0.10080000DS04 0.29300000D+03
HE(4) 0.40030000D+01 0.0 0.42 100000Df01
H4N2 0.32045000D+02 0.27470000D+03 0.38670000D+03
~
HELI UM-4
~~
HYDRAZINE
VL TREF
OMEGA
vc zc
H3N 0.1 703 1000D+02 O.l954000OD+03 0.23970000D+03
FORMULA MW TFP TB
AMMONIA
0.25 100000D+00 O.l455OoOOD+04 0.26 30OOOOD+03 0.50596442D-24
0.2 1000000D-01
0.1 1490000Df04 0.90000000D+02 0.0
0.40000OOOD-0 1 0.80400000D+03 0.78 100000D+02
0.558 10044Df07 4.40 9.00
-O.l949643OD+04 0.47772050Df05 0.39737620D+02 -0.1349910OD+Ol 0.38108330Di-03 0.1386607OD-07 0.40000000D+0 1 0.63300000D+02 O.l262000OD+03
0.68244840D+07 4.0 8.18
-0.14079980Df04 0.39737770D+05 0.48151280D+02 -0.798951 IODfOO 0.26744380Df03 0.4929324OD-08 0.40000000D+ 0 1 0.61 840000D+02 O.l5460000D+03
0.0 0.0
0.85680000D+02 0.1837 1721 D f 0 2
0.90300000Di-02 0.1 8216343D+02 0.0 0.0
0.28105988D+05 -0.3680 1972D-02 0.17458956D-01 -0.10651219D-04
0.3 1149792D+05 -0.1 3565232D+02 0.26795520D-01 -0.1 1681172D-04
0.24932394D4-08 6.0 12.28
-0.1 8537 110D-I-02 -0.15622620D+04 -0.45780700D+02 -0.1772248OD-01 0.75 143910D+Ol 0.3573 1280D- 13 0.50000000D+ 0 1 O.l977000OD+03 0.43080000Df03
-0.29705346Df09 -0.30036103D+09
0.23852200Df05 0.66988800D+02 -0.49613580D-01 0.13280530D-04
0.43080000D+03 0.78830850D+07 0.12200000Di-00 0.26800000Df00
0.1546WOD+03 0.50459850D+07 0.73400WOD-0 1 0.28800000D+00
O.l262000OD+03 0.33943875D+07 0.89500000D-01 0.2900OOOODf 00
0.0
02s 0.64063000D+02 0.19770000D+03 0.26300000D+03
02 0.3 1999000D+02 0.54400000D+02 0.90200000Df02
N2 0.28013000D+02 0.63300000D+02 0.77400000Df02
SULFUR DIOXIDE
OXYGEN
NITROGEN
a
2 e.
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9
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to 0
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0.17800000D+04 0.3 180OOOOD+03
0.0
OMEGA
VL TREF
MUP
0.24409044D+08 7.1200 14.5691
0.40678949D+08 15.329 31.366
DHVB
81
s
0.0 0.0 0.0 0.2 1300000D+03 0.34100000D+03
0.0
0.20649270D+02 -0.21673 100D+04 -0.43150000D+02
0.79498460D+05 -0.5 1465900D+07 0.1272191OD+03 0.16615650Di-02 -0.1 2628050D+05 -0.4425 5 980D-02 0.20000000D+O 1 0.29000000D+03 0.49 100000D+03
ANT1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN Th4AX
-0.22106304D+09 -0.20691 166D+09
0.0 0.0
-0.39552700D+09 -0.3 706 1554D+09
0.1 37 2 8000D+04 0.1869 1687D+03
0.28089241D+05 O.l360710OD+O3 -0.1 3736891D+00 0.50702148D-04
0.34785054D-24
0.13810000D+04 0.2 9300000D+03
0.2040OOOOD+00
CCL20 0.9891 6000D+02 0.14500000Dt03 0.28080000D+03
PHOSGENE
DHFORM DGFORM
VISC 1 vIsc2
CPIGl CPIG2 CPIG3 CPIG4
0.45904D+5 0.5240Di-2 -0.2731D-1 0.5560D-5
0.4 1000000DHO
vc zc
TC PC
0.49 100000D+03 0.82073250D+07 O.l3000000D+00 0.26000000D+00
FORMULA MW TFP TB
SULFUR TRIOXIDE
0.1 1714666Di-09 0.66946932D+08
-0.181021 1OD+04 0.14750340D+06 O.l7363370D+03 -0.23 123160D+OO 0.27678890D4-03 0.3 164495OD-10 0.4oOOCmOOD+O 1 0.22080000D-l-03 0.55200000D+03 0.2675 3652D+08 9.8640 20.1839
-0.39376854D+09 -0.39464777D4-09 -0.52840260D+04 0.309 15310D+06 0.1 1114140D+03 -0.10099290D+01 0.85020940D+03 0.1 8866410D-14 0.6oooOOOOD+O 1 0.1673 1000D+03 0.30420000D+03 0.17 165880D+08 7.1200 14.5691
-0.30121 770D+04 0.62507530D+05 0.33 139810D+02 -0.3334509OD+Ol 0.6 1935790D+03 0.37 10065OD-02 0.20000000D+01 0.68 100000D+02 0.13290000D+03 0.60457392D+07 3.1300 6.4047
-0.34210080D+02 -0.1 1587170D+04 -0.87403690D+02 -0.1 3500030D-01 0.93655890D+01 0.10799190D-16 0.60000000D+01 0.25000000D+03 0.55640000D+03 0.300 19356D+08 9.338 19.108
0.30869276D+05 -0.12853476D+02 0.27892462D-0 1 -0.1271 53 12D-04
-0.1 1061526D+09 -0.1 3736891D+09
0.54015000D+03 0.1 1120589D-i-03
0.407 16630D+05 0.2048601 2D+03 -0.22696643D+00 0.8842521 6D-04
0.27408000D-l-03 0.627344 1OD+O2
0.0
0.57808000D+03 0.94446586DI-02
0.0
0.27444474D+05 0.8 1265788D+02 -0.76660308D-01 0.2672853 1D-04
0.3 1622776D-25
0.19795 190D+05 0.73436472D+02 -0.5 60 19384D-0 1 0.17 153320D-04
0.0
0.1 5840000D+04 0.2 980OOOOD +03
0.1 1500000D+00
0.552oooOOD+O3 0.79033500D+07 0.17oOOoOOD+00 0.29300000D-l-00
0.30420000D+03 0.73764600D+07 0.94000000D-01 0.27400000D+00
0.13290000D+03 0.34957 125D+07 0.93 100000D-0 1 0.29500000Di-00
0.55640000D+03 0.45596250D+07 0.27600000D+00 0.2 720WOD +00 0.49OOOOOOD-0 1
cs2 0.7613 1000D+02 0.16 13oOOOD+03 0.3 1940000D+03
CARBON DISULFIDE
c02 0.44010000D+02 0.21660000D+03 0.19470000D+03
CARBON DIOXIDE
0.28010000D+02 0.68 ~~~~~~02 0.8 1700000Dt02
co
CARBON MONOXIDE
CCIA 0.15382300D+03 0.25000000D+03 0.34970000D+03
CARBON TETRACHLORIDE
a
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A p p e n d i x D. Physical Properties
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Appendix D. Physical Properties
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0.36500000D+03 0.46204200Dt-07 0.18 100000D+00 0.27500000D+00
0.1 4800000D+00
0.6 120oOOOD+03 0.22300000D+03
0.126491 1OD-24
0.37095048D+04 0.23454454D+03 -0.1 1601623D+00 0.22047689D-04
0.27384000D+03 0.53901 5 l4D+02
0.2043 1584D+08 0.62760132D+08
TC
vc zc
OMEGA
VL TREF
MUP
CPIGl CPIG2 CPIG3 CPIG4
VISC 1 VIsc2
DHFORM DGFORM
-0.24957960D+04 0.1 1799810D+06 0.94078850D+02 -0.85284220D+00 0.42674050D+03 0.3578286OD-03 0.20000000D+01 0.14600000D+03 0.36500000D4-03
0.1 842 1920D+08 6.208 12.703
ANT1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
DHVB 6 61
Pc
C3H6 0.4208 1000D+02 0.8 790WOD+ 02 0.2 2540000D+ 03
FORMULA MW TFP TE3
PR OPYLENE
0.5 8200oOOD+03 0.23100000D+03
0.0
0.9 3400000D+ 03 0.29300000D+03
0.29140128D+08 9.566 19.574
0.2 1544070D+02 -0.29404600D+04 -0.35930000D+02 0.0 0.0 0.0 0.0 0.24100000D+03 0.3 5000000D+03
-0.21771360D+09 -0.153 15314D+09
0.32238360D+08 12.385 25.342
0.15382540D+04 -0.12824810D+06 O.l4256410D+03 0.16885370D+00 -0.2266232OD-tO3 -0.8520342OD-08 0.3OOOOOO0D+0 1 0.33660000D+03 0.61200000D+03
0.5 3504000D+03 0.1 1175727D+03
0.30144960D+08 9.0 14 18.445
0.1 1504590D+03 -0.7769 1770D+04 0.1 052 17 1OD +02 0.1 1846230D-01 -0.14594400D+02 0.13296100D-16 0.6000OOOOD+O 1 0.20272000D+03 0.5 0680000D+ 03
0.16550420D+05 0.22453808D+03 -0.434171 16D-01 0.29144315D-04
0.56689272Di-04 0.36889895D+03 -0.28646086D+00 0.987666 12D-04
0.6301 1340D+04 0.26058643D+03 -O.l2526906D+OO 0.20377 156D-04 0.36725000D+03 0.77291 732D+02
0.53758719D-24
0.47434164D-24
0.9 1706050D-24
0.18786172D+08 6.400 13.096
-0.2 1284520D+04 0.1 1710080D+06 0.10987330D+03 -0.4947 1660D+00 0.35067670D+03 0.1 7788010D-06 0.3~OoOOD+O1 0.14792000D+03 0.36980000D+03
0.10391 638D+09 -0.23487948D+08
-0.422448 12D4-04 0.30626442D+03 -0.15863785D+00 0.32 146250D-04
0.1 5200000D+OO
0.32400000D+ 00
0.5 3600000D+00 0.7 9000000D+ 03 0.29300000D+03
0.36980000D+03 0.42455 175D+07 0.20300000D+00 0.28100000D+00
0.506 80000D+ 03 0.46913475D+07 0.2 2800000D+00 0.254000OOD+OO
0.61200000D+03 0.537022501)+07 0.2 3OOOOOOD+00 0.24200000D+00
0.41784264D+08 12.050 24.657
0.39826350D+03 -0.22098850D+05 0.281 34120D+02 0.5 5 27422OD-0 1 -0.59550090D+02 0.33038320D-05 0.20000000D4-0 1 0.21468000D+03 0.53670000D+03
-0.25656710Di-09 -0.16 190356D+09
0.95 104000D+03 0.16 116547Di-03
0.24702120DI-04 0.3325 I566Dt03 -0.1 855 1711D+00 0.42956568D-04
0.53758719D-24
0.62400000Dt00
0.5 367OOOOD+03 0.5 1675750Dt07 0.2185000OD+OO 0.25300000D+00
C3H80 0.60096000D+02 0.14690000Dt03 0.37040000D+03
C3H8 0.440970001)+02 0.85500000D+02 0.231 10000Di-03
0.508 10000D+03 0.47014800D+07 0.20900000D+00 0.2 3200000D+ 00
I-PROPANOL
PROPANE
C3H602 0.7 408oOOOD+02 0.25250000D+03 0.41400000D+03
METHYL ACETATE
C3H60 0.58080000D+02 0.17820000D+03 0.32940000D+03
ACETONE
PROPIONIC ACID
a
UI 0
4
0.61 127280D+08 17.69 36.20
0.39858336D+08 11.572 23.679
s
DHVB
-0.5 853 1464D+09
0.3337 1000D+04 0.2974386 1D4-03
0.221 3 1970D+02 -0.44870400D+04 -O.l402000OD+O3 0.0 0.0 0.0 0.0 0.44000000D+03 0.60000000D+03
0.1 1397000D+04 0.1 7470193D+03
vISCl vIsc2
0.84238416D+04 0.44421948D+03 -0.3 1589406Di-00 0.93784320D-04
0.23585670D+02 -0.3 6402000D+04 -0.5 354WODi-02 0.0 0.0 0.0 0.0 0.27300000D+03 0.3 7400000D+03
0.32426766D+05 0.18848974D+03 0.6405 804OD-0 1 -0.9261201 6D-04
CPIGl CPIG2 CPIG3 CPIG4
0.94868328D-24
ANT 1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
0.53758719D-24
MUP
0.0
0.7 8600WOD+03 0.29300000D+03
VL TREF
0.0
0.72600000D+03 0.66874500D+07 0.2 5 5 00000D+ 00 0.28000000D+00
C3H803 0.92095000D4-02 0.29 100000D+03 0.56300000D+03
GL YCER OL
DHFORh4 DGFORM
0.7 2400000D+ 00
C3H80 0.60096000D+02 0.18470000D+03 0.35540000D-tO3
OMEGA
ZC
vc
Pc
TC
FORMULA MW TFP TB
ISOPROPYL ALCOHOL
0.24283440D+08 7.950 16.267
0.20996670D+02 -0.23972600D+04 -0.30880000D+02 0.0 0.0 0.0 0.0 0.24500000D+03 0.30500000D+03
0.0 0.0
0.1 1199690Di-05 0.27235134D+03 -0.14683108D+00 0.308902 1OD-04
0.126491 10D-24
C4H6 0.54092000D+02 0.13700000D+03 0.28400000D+03
1.2-B UTADIENE
0.22483 1 16D-I-08 6.940 14.201
0.20665470D+02 -0.21 426600D+04 -0.34300000D+02 0.0 0.0 0.0 0.0 0.21500000D+03 0.29000000D+03
0.1 1023844D+09 0.1 5076667D+09
0.30059000D+03 0.62070056D+02
-O.l6872804D+04 0.341 85222D+03 -0.23400025D+00 0.63346284D-04
0.0
0.62 100000D+03 0.29300000D+03
0.1 9500000D+OO
C4H6 0.54092000D+02 0.16430000D+03 0.26870000Di-03
I , 3-B UTADIENE
0.21930458D+08 6.766 13.845
-0.26389800D+04 0.14105410D+06 0.10929260D+03 -0.76149810D+00 0.44014500D+03 0.27743420D-03 0.20000000D-l-0 1 0.16784000D+03 0.4 1960000D+03
-0.12560400D+06 0.7 1343072D+08
-0.29935620D+04 0.35319845D+03 -0.19904047D+00 0.44631288D-04
0.94868328D-25
0.5 9500000D+03 0.29300000D+03
0.1 8700000D+00
C4H8 0.56 108WODi-02 0.87800OOOD+ 02 0.26690000D+03
I-BUTENE
0.23362344D+08 6.760 13.832
-0.235 13930D+04 O.l2905430D+O6 0.1 1409570D+03 -0.65874770D+00 0.3907 1810D+03 0.23470370D-03 0.20000000D+O 1 0.1 7424000D+03 0.43560000D+03
0.26894000Di-03 0.56842739D+02
0.4396 1400D+03 0.29533687D+03 -0.10178111D+00 -0.6 154596OD-06
0.94868328D-25
0.62 IOOOOOD+03 0.2930oooOD+03
0.43560000D+03 0.42049875D+07 0.2 340WOD+ 00 0.27200000D+00
C4H8 0.56 108000D+02 O.l343OOOOD+O3 0.27690000D+03
CIS-2-BUTENE
>
n
z_.
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c.l
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5 7)
0
a
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0.5 356WOD+03 0.41543250D+07 0.26700000D+00 0.24900000D+00
TC PC
0.10944295D+05 0.3559 1987D+03 -O.l8999698D+00 0.39196822D-04
CPIG 1 CPIG2 CPIG3 CPIG4
0.20999670D+02 -0.27683800Di-04 -0.46900000D+02 0.0 0.0 0.0 0.0 0.27000000D+03 0.37000000Di-03 0.29600676D+08 9.10 18.62
-0.78357580D+04 0.53 123170D+06 0.1 3869530D+03 -0.15758780Di-01 0.12395040D+04 0.41455620D-03 0.200oooO0D+01 ~~~~~~~~~~03 0.5356WOD+03
0.3 1233528D-i-08 9.199 18.823
ANT1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
DHVB 6 61
-0.18434480D+09 0.0
-0.23852200D+09 -0.1461 61 19D+09
DHFORM DGFORM
0.41 979000D+03 0.88991097D+02
-0.1 9104368D+05 0.5 1623244D+03 -0.41315342D+00 0,145407562)-03
0.104355 16D-23
MUP
VISC 1 vIsc2
0.53758719D-24
0.805 00000D+ 03 0.29300000D+03
0.0
0.54020000D+03 0.5 1878400D+07 0.22400000D+00 0.2590000OD+OO
C4H80 0.72 107000D+02 0.16470000D+03 0.33910000D+03
TETRAHYDROFURAN
VL TREF
OMEGA
vc zc
TB
C4H80 0.72 107000D+02 0.18650000D+03 0.35280000D+03
FORMULA MW TFP
METHYL ETHYL KETONE
0.36383292D4-08 10.13 20.73
0.21025470D+02 -0.29668800D+04 -0.62 150000D+02 0.0 0.0 0.0 0.0 0.27500000D+03 0.41000000D+03
-0.3 1526604D+09 -0.18091 163Di-09
0.66036000D+03 0.12850773Di-03
-0.5 3574293D+05 0.59871240D+03 -0.40850608D+00 0.10621912D-03
0.126491 10D-24
0.5 8700000D+03 0.5208 1050D+07 0.23800000D+00 0.25400000D+00
C4H802 0.88 107000D+02 0.28500000D+03 0.37450000D+03
I . CDIOXANE
0.3223836ODl-08 8.974 18.363
0.20928000D+03 0.52320000D+03
~~~~~~~~01
0.486 10870Di-02 -0.82999240D+04 0.28708980D+02 -0.47696360D-01 -0.46 184520D+00 0.34456160D-04
-0.4432 1465D+09 -0.32761710D+09
0.42738000D+03 0.8882667 1D+02
0.72347904Di-04 0.407 16630D+03 -0.2091 7253D+00 0.28545602D-04
0.60083274D-24
C4H802 0.88 107000D+02 0.18960000D+03 0.35030000D4-03
ETHYL ACETATE
0.22407754Di-08 6.634 13.575
-0.20775660D+04 0.1 3037520D+06 0.12967170D+03 -0.40673270D+00 0.33409570D+03 0.1 11357801)-06 0.30000000D+01 0.1 7008000D+03 0.42520000D+03
-0.1 2623202D+09 -0.17 165880D+08
0.26584000D+03 0.5705424 1D+02
0.94872888D+04 0.33 130148D+03 -0.1 1082460D+00 -0.2821 9032D-05
0.0
0.5 7900000D+03 0.29300000D+03
0.1 9300000D+00
C4H 1 0 0.58 124000D+02 0.1 3480000D+03 0.27270000D+03
N-B UTANE
0.2 1310812D+08 6.730 13.771
-0.22805 130D+04 0.13705 180D-t-06 0.12196710D+03 -0.46894860D+00 0.369145 10D4-03 0.1 3719500D-06 0.3000000OD+Ol O.l6324OOOD+03 0.408 1WOD+03
-0.1 3460562D+09 -0.208921 32Di-08
0.3025 1000D+03 0.63321324Di-02
-0.1 3900176Di-04 0.38472505Di-03 -0.1 845960 1D +00 0.2895 1722D-04
0.3 1622776D-25
0.55 700000D+03 0.29300000D+03
O.l7600000D+00
0.40810000D+03 0.36477000Di-07 0.26 30OOOODt00 0.28300000Dt00
0.58124000D+02 0.1 1360000Dt03 0.261 30000Dt03
C4H10
ISOB UTANE
E
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7
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2n -.
0 5
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a
3
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cn m m
C4H100 0.74123000D+02 0.29880000D+03 0.35560000D+03
C4H100 0.74123000D+02 0.16520000D+03 0.38 100000D+03 0.54770000D+03 0.4296 1800D+07 0.27300000D+00 0.25700000D+00
C4H100 0.74123000D+02 0.1 585OoOOD-tO3 0.37270000D+03
-0.77078988D+04 0.46892160D+03 -0.28838678D+00 0.72306036D-04 0.1 1991000D+04 0.18483874D+03
0.57600000D+00 0.80700000D+03 0.29300000D+03 0.537587 19D-24 0.57526632D+04 0.42454152D+03 -0.23282795D+00 0.47729520D-04 0.144 I 7000D+04 0.19617583D+03
0.56290000D+03 0.44177700D+07 0.27400000D-tOO 0.25900000D+00
0.59OOOOOOD+00 0.81000000D+03 0.29300000D+03
0.56920997D-24
0.32657040D+04 0.4180101 1D+03 -0.22416127D+00 0.46850292D-04
TC
zc
OMEGA VL TREF
MUP
CPIG 1 CPIG2 CPIG3 CPIG4
0.40821300D+08 1 1.08 22.67
0.43 124040D+08 1 1.440 23.409
81
8
DHVB
0.22108770D+02 -0.3 1370200D+04 -0.94430000D+02
ANT1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
0.0 0.0 0.0 0.28800000D+03 0.40400000D+03
0.0
0.22102970D+02 -0.30260300D+04 -0.86650000D+02 0.0 0.0 0.0 0.0 0.29800000D+03 0.39300000D+03
-0.27486342D-I-09 -O.l5089227D+09
DHFORM DGFORM
VISCl VISC2
vc
Pc
TB
TFP
0.42077340D+08 10.949 22.404
0.2 1763970D+02 -0.28747344D+04 -0.10030000D+03 0.0 0.0 0.0 0.0 0.29300000D-kO3 0.3 8800000D+03
-0.28340449D+09 -0.1674301 3D+09
0.53758719D-24
0.5 8800000D+00 0.80200000D+03 0.29300000D+03
0.5 3600000D+03 0.41948550D+07 0.26800000D+00 0.25200000D+00
C4H100 0.74123000D+02 O.l8390000D+03 0.39090000D+03
MW
0.39062844D+08 10.316 21.109
0.2 1747570D+02 -0.26582900D+04 -0.95500000D+02 0.0 0.0 0.0 0.0 0.29300000D+03 0.37600000D+03
-0.3 1262836D+09 -0.1 7777153D+09
0.97210000D+03 0.1 7129030D+03
-0.48612935D+05 0.7 1719884D+03 -0.70840656D+00 0.291987431)-03
0.53758719D-24
TERT-BUTYL ALCOHOL
ISOB UTANOL
2-BUTANOL
FORMULA
N-B UTANOL
0.2671 I784D+08 7.544 15.437
0.98234300D-kOI -0.25462230D+04 -0.3544279OD-kO2 -0.68873780D-02 0.22952660D-kOl 0.28640650D- 16 0.60000000D+01 0.18668000D+03 0.46670000D+03
-0.25238030D+09 -0.1 2242203D+09
0.353 14OOOD+O3 0.7276 7733DS-02
0.2 1423856D+05 0.335865 10D+03 -0.1035 3956D+W -0.9357498OD-05
0.41 109609D-24
0.28100000D+00 0.7 130oooOD+03 0.29300000D+03
0.46670000D+03 0.36375675D+07 0.28000000D+00 0.26200000D+00
C4H100 0.74123000D+02 0.15690000D+03 0.30770000D+03
ETHYL ETHER
0.57233556D+08 13.551 27.728
0.2 1925370Dt02 -0.4 1225200Dt04 -0.12250000D+03 0.0 0.0 0.0 0.0 0.40200000D+03 0.5 600OOOOD+03
-0.57149820D+09 0.0
0.1943cKlOOD+04 0.241 55823D+03
0.73059660Dt05 0.34608089Di-03 -0.1 4678921D+00 0.18463788D-04
0.0
0.0 0.1 1160000Dt04 0.29300000D+03
0.68 1OOOOOD+03 0.46609500D+07 0.3 16ooOOOD+OO 0.26000000D+00
C4H1003 0.106 122WDi-03 0.26500000D+03 0.5 19ooOoOD+03
DIE THYL.ENE GLYCOL
m v
0.3 1366000D+03 0.66469257D-I-02
0.3979 1347Df05 0.49278636Df03 -0.35579426Df00 0.100441 33D-03
0.6 1850000D+03 0.12077243D+03
CPIGl CPIG2 CPIG3 CPIG4
VISC 1 VIsc2
0.25790688D+08 7.020 14.364
0.35 169120D+08 10.62 21.73
DHVB
s
-0.31 144360Di-02 -0.12065390D-l-04 -0.64139850Df02 -0.16082770D-01 0.9 1627870Df01 0.31313440D-16 0.60000000Df01 0.18784000Df03 0.46960000Df03
0.20983770D+02 -0.3095 1300Df04 -0.61 150000Df02 0.0 0.0 0.0 0.0 0.28500000D+03 0.42500000D+03
ANT 1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
DHFORM DGFORM
-0.36257688D-I-04 0.48734352D-l-03 -0.25803248D-kOO 0.53046756D-04
0.72732385D-24
MUP 0.0
0.9 8300000D 0 3 0.29300000Df03
0.24702120D+08 7.020 14.364
-0.2 59659 1OD +04 0.1 5024030D+06 0.12090470Df03 -0.67404480Df00 0.42657630Df03 0.2250 1220D-03 0.20000000Df01 0.1 8416000D+03 0.46040000D+03
0.30781354D-kO8 9.158 18.739
0.0 0.0 0.0 0.3 1000000Di-03 0.41 100000Df03 0.44380080D+08 11.12 22.75 0.2276781 8Di-08 7.020 14.364
0.0
-0.37675460D4-02 -O.l0975230D+04 -0.93532510D+02 -0.14047730D-01 0.9948222OD+Ol 0.10416500D- 16 0.60000000D+01 0.27870000D+03 0.562 1WOD+03
0.82982376D-I-08 0.12974893Di-09
-0.339 17267D+05 0.47436444D-kO3 -0.3017008 1D+00 0.7 1301204D-04
0.0
-0.53893750D-i-04 0.3 1478200D+06 0.1 1741390D+03 -0.1 3554940D+01 0.879 16190D+03 0.43847210D-03 0.20000000D-kOl 0.25660000D+03 0.43380000D+03
0.21419770Df02 -0.30268900Di-04 -0.10500000D+03
-0.29893752Di-09 -0.1461 1932D+09
-O.l6609036D+09 -0.1 5239952D+08
-0.1 5457666D+09 -0.1 4821272D+08
0.3 8686032D+04 0.50450940D-l-03 -0.26393587D+00 0.51204564D-04
0.537587 19D-24
0.1151 1000D+04 O.l8293405D+03
-0.16592288Di-05 0.555 16968D+03 -0.33063 160D+W 0.76325364D-04
0.0
0.8 1500000DS03 0.29300000D+03
0.36732000D-I-03 0.74699240Df02
-0.95249700D+04 0.50660280D-kO3 -0.27293749Dl-00 0.57233556D-04
0.3 1622776D-25
0.59 100000D+03 0.29300000D+03
0.562 10000D+03 0.48939975D-I-07 0.25900000D+00 0.27 100000D+00
0.5 8600000D+03 0.38503500Df07 0.326OOOOOD+OO 0.26000000D+00
0.43380000D+03 0.3201 8700Di-07 0.30300000D+00 0.26900000D+00
0.46040000D+03 0.33842550D+07 0.30600000D+00 0.27 100000D+00
0.46960000D+03 0.33741225D+07 0.3 0400000D+00 0.2 6200000D+00
0.2 1200000D+00
C6H6 0.781 14000Di-02 0.27870000D+03 0.35 330000D+03
C5H120 0.88 150000D+02 O.l950000OD+03 0.41 100000Df03
C5H12 0.72151000D+02 0.25660000D+03 0.28260000D+03
BENZENE
C5H12 0.7215 1000D+02 0.1 1330000D+03 0.30100000D+03
I-PENTANOL
C5H12 0.7215 1000Df02 0.14340000D+03 0.3 0920000D+03
N-PENTANE
VL TREF
OMEGA
vc zc
+
0.62000000Df03 0.56336700D+07 0.25400000Df00 0.2 7700000D+00
TC PC
TFP TB
Mw
C5H5N 0.79 102000D+02 0.23 150000D-l-03 0.38850000D-kO3
FORMULA
PYRIDINE
2,I-DIMETHYL PROPANE
2-METHYL BUTANE
b
m
03
VI
589
Appendix D. Physical Properties
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81
s
DHVB
ANT1 ANT2 ANT3 ANT4 ANT5 ANT6 ANT7 TMIN TMAX
0.36006480D-I-08 8.769 17.943
0.35587800D-I-08 8.783 17.972
0.34436430Di-08 7.551 15.451
0.36843840Dl-08 8.987 18.389
0.36843840Di-08 9.21 1 18.848
0.0 0.0 0.0 0.30500000D+03 0.4600000OD-I-03
0.36383292DI-08 8.818 18.044
-0.1 1737850D-I-03 -0.15641240D+04 -0.60739230D-I-02 -0.8668081OD-01 0.2697 1140D+02 0.41 398210D-04 0.20000000D-I-01 0.2275200OD-I-03 0.56880000D-I-03
-0.1 293 1300D+02 -0.33902620D-I-04 -0.36508840D+02 -0.155391 80D-01 0.66026580D-I-01 0.7144069OD-11 0.40000000D+01 0.24684000D-I-03 0.6 1710000D-I-03 -0.43637890D-I-04 0.33397640D-I-06 0.16450780D-I-03 -0.76 178230D-I-00 0.6775002OD-I-03 0.1 804438OD-03 0.20000000D+01 0.28640000D+03 0.61620000D+03
-0.32447 180D-I-04 0.24302390D-I-06 0.16336200D-I-03 -0.58847630D-I-00 0.50685500D-I-03 0.14444320D-03 0.20000000D-I-01 0.24680000D+03 0.6 1700000D+03
0.8081 1040D-I-01 -0.34240540D-I-04 -0.508 15350D+02 -0.52463410D-02 0.24766890D+01 0.48 165370D-17 0.60000COOD-I-01 0.25208000D+03 0.63020000D+03
0.20912070D-I-02 -0.33285700D+04 -0.63720000D-I-02
0.0
-0.20858638D+09 0.16412256D-I-08
0.2981oO16D+08 0.1 3067003D+09
0.17961372D-I-08 0.12120786D-I-09
0.1 7249616Di-08 0.1 1894699Di-09
0.19008072D-I-08 0.12217082D-I-09
0.14745910D+09 0.21 394548Di-09
DHFORM DGFORM
0.47370000D-I-03 0.97031344D-I-02 0.47282000D-I-03 0.98720249D-I-02
0.47516000D-I-03 0.98626941D-I-02
0.5 1354000D-I-03 0.10594135D-I-03
-0.60959808D-I-04 0.77 120856D-I-03 -0.41951736D-I-00 0.88550820D-04
0.45342000D+03 0.95 195399D-I-02
0.52864000D-I-03 0.1076561 7D-I-03
VISCl VISC2
-0.29165249D-I-05 0.62969472D-I-03 -0.37471860D-I-00 0.84782700D-04
-0.1585 1225D-I-05 0.59620032D+03 -0.34432243D-kOO 0.75278664D-04
0.0
0.70300000D-I-03 0.29300000D-I-03
0.568800OOD-I-03 0.24824625D-I-07 0.49200000D+00 0.25 900000D-I-00
C8H18 0.11423200D-I-03 0.21640000D-I-03 0.39880000D-I-03
N- OCTANE
-0.4309891 9D-I-05 0.7071 5052D+03 -0.48106332D+00 0.1 3OO8388D-03
-0.28248340D-I-05 0.61587828D-I-03 -0.4023096 1D-I-00 0.99352764D-04
CPIGl CPIG2 CPIG3 CPIG4
0.126491 10D-24
0.86700000D-I-03 0.29300000D-I-03
0.30 100000D-I-00
0.6 171OOOOD-I-03 0.3607 1700D-I-07 0.3 7400000D+00 0.26300000D-I-00
C8H10 0.10616800D+03 O.l7820000D+03 0.40930000D+03
ETHYLBENZENE
-0.2509 1492D+05 0.6041 5524D-I-03 -0.33737234D-I-00 0.68202972D-04
0.31622776D-25
MUP
0.3 1622776D-25
0.86 100000D+03 0.29300000D+03
0.86400000D-I-03 0.29300000D+03
OMEGA
0.94868328D-25
0.32400000D-I-00
0.33 100000D+00
0.3 1400000D+00
0.25700000D-I-00
vc zc
0.1581 13882)-24
0.6 1620000D+03 0.35 159775D+07 0.37900000Df00 0.26000000D+00
0.6 1700000D-I-03 0.35463750D-kO7 0.37600000D-I-00 0.26000000Dl-00
0.63020000D-I-03 0.37287600D+07 0.36900000Df00 0.26300000D-I-00
0.64700000D+03 0.39922050Dl-07 0.0 0.0
TC PC
VL TREF
C8H10 0.10616800D-I-03 0.28640000D+03 0.41 150000D+03
C8H10 0.10616800D+03 0.22530000D-I-03 0.41230000D+03
C8H10 0.10616800D+03 0.24800000D+03 0.4 176oOOOD+03
P-XYLENE
C8H8 0.10415200D+03 0.24250000D-I-03 0.4183000OD-I-03
M-XYLENE
0-XYLENE
FORMULA MW TFP TB
STYRENE
1.
5 71
P
3
U U
>
0
Gl a