3.2.3 Polymers and waxes A-C325 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
A-C325
CAS #
-
Common name
Oxidized polyethylene homopolymer
Chemical class
-
polymer
68441-17-8
PHYSICAL PROPERTIES State
-
solid, granules
Odor
-
waxy odor
Color
-
white
Freezing point
o
C
88-140
Dropping point
o
C
136
Particle hardness
dmm
0.5 max ASTM D-5 0.85-1.00
Specific gravity at 20 C
-
Density at 20oC
kg/m3
990 approx.
Bulk density
kg/m
625
Acid number
mg KOH/g
24-27
Viscosity at 140oC
mPas
4500
g/l
insoluble
o
Solubility in water at 25 C o
3
HEALTH & SAFETY HMIS personal protection
goggles, apron, gloves
DOT class
-
not regulated
ADR/RIC class
-
not regulated
TDG class
-
not regulated
Flash point
o
Flash point method
-
OC
TLV – TWA 8h, ACGIH
mg/m3
10 total particulates
Animal testing, acute toxicity, Rat oral LD50
mg/kg
2,500
Skin irritation
considered non-irritant
Eye irritation (human)
considered non-irritant
C
255.0 min
USE & PERFORMANCE Manufacturer
-
Honeywell
Additive type
-
antiblocking agent
Recommended for polymers
PVC
Recommended for products
packaging products
Outstanding properties
effective lubricant for PVC
Processing methods
coating
Additive application method
process aid additive
Databook of Antiblocking, Release, and Slip Additives
103
A-C629 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
A-C629
CAS #
-
Common name
Oxidized polyethylene homopolymer
Chemical class
-
polymer
68441-17-8
PHYSICAL PROPERTIES State
-
solid, prill
Odor
-
waxy odor
Color
-
white
Freezing point
o
C
88-140
Dropping point
o
C
101
Particle size
m
2000-3000
Particle hardness
dmm
5.5 ASTM D-5
Specific gravity at 20oC
-
0.85-1.00
Density at 20 C
kg/m
3
Bulk density
kg/m
3
Acid number
mg KOH/g
o
930 485 14-17
Viscosity at 140oC
mPas
200
Solubility in water at 25oC
g/l
insoluble
HEALTH & SAFETY HMIS personal protection
goggles, apron, gloves
Food approval(s)
FDA approved 21 CFR 175.105, 125, 300, 310; 176.170, 180, 200, 210; 177.1200, 1210; 177.2600; 178.3570
DOT class
-
not regulated
ADR/RIC class
-
not regulated
TDG class
-
not regulated
Flash point
o
Flash point method
-
C
255.0 min OC
TLV – TWA 8h, ACGIH
mg/m
10 total particulates
Animal testing, acute toxicity, Rat oral LD50
mg/kg
2,500
Skin irritation
considered non-irritant
Eye irritation (human)
considered non-irritant
3
USE & PERFORMANCE Manufacturer
-
Honeywell
Additive type
-
antiblocking agent
Recommended for polymers
PVC
Databook of Antiblocking, Release, and Slip Additives
104
A-C629 PARAMETER
UNIT
Recommended for products
windows & doors, packaging products
Outstanding properties
effective lubricant for PVC
Features and benefits
increases gloss
Processing methods
injection & blow molding, extrusion, calendering, coating
Additive application method
process aid additive
Databook of Antiblocking, Release, and Slip Additives
VALUE
105
Addid 130 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Addid 130
Common name
Polyether-modified polydimethylsiloxane
Chemical class
-
siloxane
-
liquid
PHYSICAL PROPERTIES State Odor
-
slight
Color
-
yellowish
Refractive index at 25oC
-
Density at 25 C
kg/m
Viscosity at 25oC
mPas
800
cSt
600-1200
o
Kinematic viscosity at 25oC
1.425 3
1030
Surface tension at 25 C
mN/m
22
Solubility in water at 25oC
g/l
miscible
Solubility in solvents
IBA, xylene, isobutanol, butanol, 2-propanol
o
HEALTH & SAFETY HMIS classification
Health
1
Flammability
1
Reactivity
0
HMIS personal protection
goggles, apron, gloves
Hazardous components
octamethyl cyclotetrasiloxane CAS# 556-67-2 (0.1-1%)
Food approval(s)
FDA approved 21 CFR 176.200
OSHA hazard class
-
combustible IIIB
DOT class
-
not regulated
ADR/RIC class
-
not regulated
TDG class
-
not regulated
Canadian WHMIS classification
-
D2A
Autoignition temperature
o
C
320
Flash point
o
C
140
TLV – TWA 8h, ACGIH
ppm
10 octamethyl cyclotetrasiloxane
Animal testing, acute toxicity, Rat oral LD50
mg/kg
>2000
Skin irritation
considered non-irritant
Eye irritation (human)
may cause slight irritation
Carcinogenicity
contains 1% max listed as possible carcinogen
Databook of Antiblocking, Release, and Slip Additives
106
Addid 130 PARAMETER
UNIT
VALUE
Manufacturer
-
Wacker Silicones
Additive type
-
antiblocking agent
Recommended for polymers
solvent-borne alkyd-, melamine- & polyester resin-based binder system, water-borne alkyd resins
Outstanding properties
improves surface smoothness, scratch resistance, reduces surface tension of coatings
USE & PERFORMANCE
Features and benefits
improves flow & leveling
Processing methods
coatings systems
Additive application method
process aid additive
Recommended dosage
wt%
Databook of Antiblocking, Release, and Slip Additives
0.01-0.6 (total solids) 0.05-1 (total formulation)
107
Algoflon L206 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Algoflon L206
CAS #
-
Common name
Tetrafluoroethylene homopolymer
Common synonym
Polytetrafluoroethylene
Acronym
-
PTFE
Empirical formula
-
(CF2CF2)n
9002-84-0
Formula
F(CF2)nF
Chemical class
-
fluoropolymer
EC number
-
204-126-9
Solids content
wt%
100
PHYSICAL PROPERTIES State
solid, micronized powder
Odor
-
odorless
Color
-
off-white
Melting point
o
Particle size
m
0.25
Surface area (BET)
m2/g
7.5
C
Specific gravity at 20 C
-
Bulk density
kg/m
o
329-332
2.2 3
330
HEALTH & SAFETY NFPA classification
HMIS classification
Health
1
Flammability
0
Reactivity
0
Health
1
Flammability
0
Reactivity
0
HMIS personal protection
goggles, apron, gloves
Hazardous components
heating above 400oC can evolve degradation to: hydrogen fluoride (HF); carbonyl fluoride (CF2)
Food approval(s)
FDA approved 21 CFR 177.1550
UN risk phrases, R
-
US safety phrases, S
26,39,24/25,45,22,23,53
DOT class
-
Databook of Antiblocking, Release, and Slip Additives
41,36/38,45 not regulated 108
Algoflon L206 PARAMETER
UNIT
VALUE not regulated
TDG class
-
Autoignition temperature
o
TLV – TWA 8h, ACGIH
mg/m
5.0 HF, CF2O; 10 total dust, 5 respiratory PTFE
TLV – TWA 8h, OSHA
mg/m3
5.0 HF, CF2O; 15.0 total, 5.0 respiratory dust PTFE
TLV – TWA 8h, OSHA
ppm
2.0 HF
Skin irritation
may cause irritation
Eye irritation (human)
may cause irritation
Carcinogenicity
no carcinogenic ingredients present at over 0.1%
C
530-570 3
USE & PERFORMANCE Manufacturer
-
Solvay Solexis, Inc.
Additive type
-
antiblocking agent
Recommended for polymers
printing inks, thermoplastics & thermosetting resins, rubber, perfluoroelastomers
Recommended for products
packaging articles, protective coatings, bakeware, coated rollers, etc.
Outstanding properties
improves abrasion, scratch, scuff resistance; increases slip and block resistance, surface smoothness & gloss
Features and benefits
improves chemical & stain resistance; in thermoplastics improves lubricity & reduces friction, enhances tear resistance at elevated temperatures
Processing methods
variety of coating systems, offset, gravure, & flexographic printing inks
Additive application method
process aid additive
Databook of Antiblocking, Release, and Slip Additives
109
Aquacer 593 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Aquacer 593
Common name
PP wax
Chemical class
-
PP wax, modified
Mixture
-
yes
Solids content
wt%
30
PHYSICAL PROPERTIES State
liquid - non-ionic aq emulsion
Odor
-
mild
Color
-
yellow
Boiling point
o
C
Melting point
o
C
100 160
Density at 25 C
kg/m
pH
-
9
mPas
15 approx.
g/l
miscible
o
Viscosity at 25 C o
Solubility in water at 25 C o
3
900
HEALTH & SAFETY HMIS personal protection
goggles, apron, gloves
Hazardous components
wt%
Food approval(s)
FDA approved CFR21 175.105
UN risk phrases, R
22,41 ethoxylated alcohol; 22,35 NaOH
DOT class
-
not regulated
ADR/RIC class
-
not regulated
ICAO/IATA class
-
not regulated
IMDG class
-
not regulated
61827-42-7 (6.5%); 1310-58-3 (3.4%)
TDG class
-
not regulated
Canadian WHMIS classification
-
not controlled
Animal testing, acute toxicity, Rat oral LD50
mg/kg
3000
USE & PERFORMANCE Manufacturer
BYK-Cera bv, BYK-Chemie GmbH
Additive type
-
Recommended for products
printing inks: flexo-, gravure, overprint varnishes, offset & screen inks
Outstanding properties
reduces friction & adhesion forces
antiblocking agent
Features and benefits
improves scratch & rub resistance
Processing methods
printing inks
Databook of Antiblocking, Release, and Slip Additives
110
Aquacer 593 PARAMETER
UNIT
Additive application method
process aid additive
Recommended dosage
wt%
Databook of Antiblocking, Release, and Slip Additives
VALUE 3-4
111
Aquamat 263 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Aquamat 263
Common name
HD polyethylene wax
Chemical class
oxidized HD PE wax
Mixture
-
yes
Solids content
wt%
35
PHYSICAL PROPERTIES State
liquid - aqueous dispersion
Odor
-
mild
Color
-
white
Boiling point
o
C
100
Melting point
o
C
120
Particle size
m
25 max, dispersed
Density at 25oC
kg/m3
1000
pH
-
8.5
Viscosity at 25 C
mPas
75-275
Solubility in water at 25oC
g/l
miscible
o
HEALTH & SAFETY HMIS personal protection
goggles, apron, gloves
Hazardous components
wt%
Food approval(s)
FDA approved CFR21 175.105
UN risk phrases, R
36/38 3-butoxypropanol; 22,41,50 ethoxylated fatty acid
5131-66-8 (5%); 68439-50-9 (1.1%)
DOT class
-
not regulated
ADR/RIC class
-
not regulated
ICAO/IATA class
-
not regulated
IMDG class
-
not regulated
TDG class
-
not regulated
Canadian WHMIS classification
-
not controlled
Animal testing, acute toxicity, Rat oral LD50
mg/kg
9000
USE & PERFORMANCE Manufacturer
BYK-Cera bv, BYK-Chemie GmbH
Additive type
-
Recommended for products
paints, lacquers, inks
antiblocking agent
Features and benefits
improves scratch & rub resistance
Processing methods
industrial & decorative coatings, furniture & floor lacquers, inks
Databook of Antiblocking, Release, and Slip Additives
112
Aquamat 263 PARAMETER
UNIT
Additive application method
process aid additive
Recommended dosage
wt%
Databook of Antiblocking, Release, and Slip Additives
VALUE 3-6 (water-based); 3-14 (inks)
113
Ceretan ME 0420 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Ceretan ME 0420
CAS #
-
Common name
Spherical, micronized, non-polar polyethylene wax
Formula
9002-88-4
CH2(CH2)nCH3
Mixture
-
no
Product contents
wt%
100
State
-
solid
Color
-
white
Dropping point
o
Particle size
m
20
Density at 25oC
kg/m3
930-960
PHYSICAL PROPERTIES
C
108-116
HEALTH & SAFETY Flash point
o
C
>170
Animal testing, acute toxicity, Rat oral LD50
mg/kg
Skin irritation
no significant effects or critical hazards known
Eye irritation (human)
no significant effects or critical hazards known
>2000
USE & PERFORMANCE Manufacturer
Muenzing, Micro Technologies GmbH
Additive type
-
Recommended for products
paints and coatings (powder, car, industrial, building, furniture, floor) and printing inks (water- and solvent-based)
Outstanding properties
abrasion resistance, good adhesion, improved dispersion
Databook of Antiblocking, Release, and Slip Additives
antiblocking agent
114
Ceretan MP 2150 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Ceretan MP 2150
CAS #
-
Common name
Micronized polypropylene wax
Formula
9003-07-0
CH3 CH2CH
Mixture
-
yes
Product contents
wt%
100
n
PHYSICAL PROPERTIES State
-
solid
Color
-
white
Dropping point
o
C
156-164
Particle size
m
50
Density at 25oC
kg/m3
870-890
HEALTH & SAFETY Flash point
o
Animal testing, acute toxicity, Rat oral LD50
mg/kg
C
280
Skin irritation
no significant effects or critical hazards known
Eye irritation (human)
no significant effects or critical hazards known
Carcinogenicity
no significant effects or critical hazards known
>2000
USE & PERFORMANCE Manufacturer
Muenzing, Micro Technologies GmbH
Additive type
-
Recommended for products
paints and coatings (powder, industrial, construction, furniture, parquet), masterbatch
Outstanding properties
scratch resistance, matting, texturing, temperature resistance
Databook of Antiblocking, Release, and Slip Additives
antiblocking agent
115
Ceretan MX 9718 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Ceretan MX 9718
Common name
Micronized functional blend
Mixture
-
yes
Product contents
wt%
100
PHYSICAL PROPERTIES State
-
solid
Color
-
white
Dropping point
o
C
134-142
Particle size
m
18
Density at 25oC
kg/m3
960-980
HEALTH & SAFETY Flash point
o
Animal testing, acute toxicity, Rat oral LD50
mg/kg
C
>200
Skin irritation
no significant effects or critical hazards known
Eye irritation (human)
no significant effects or critical hazards known
Carcinogenicity
no significant effects or critical hazards known
>15000
USE & PERFORMANCE Manufacturer
Muenzing, Micro Technologies GmbH
Additive type
-
Recommended for products
paints and coatings (powder, can, furniture, parquet, industrial)
Outstanding properties
matting, improved sandability, improved scratch resistance, `soft feel` in wood coatings
Databook of Antiblocking, Release, and Slip Additives
antiblocking agent
116
Ceretan WE 0601 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Ceretan WE 0601
Common name
Water emulsion of paraffin wax
Mixture
-
yes
Product contents
wt%
50
PHYSICAL PROPERTIES State
-
liquid
Color
-
white
Boiling point
o
C
Melting point
o
C
Particle size
m
1
Density at 25oC
kg/m3
1000
Vapor pressure at 20 C
kPa
2.3
pH
-
8.5-10.5
mPas
400
g/l
fully miscible
mg/kg
>2000
o
Viscosity at 20 C o
Solubility in water at 25 C o
100 52-60
HEALTH & SAFETY Animal testing, acute toxicity, Rat oral LD50
USE & PERFORMANCE Manufacturer
Muenzing, Micro Technologies GmbH
Additive type
slip and antiblocking agent
Recommended for products
water-based paints and coatings (wood, industrial)
Outstanding properties
hydrophobic character
Databook of Antiblocking, Release, and Slip Additives
117
Ceretan WE 3501 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Ceretan WE 3501
Common name
Water emulsion of polyethylene
Mixture
-
yes
Product contents
wt%
35
PHYSICAL PROPERTIES State
-
liquid
Color
-
white
Boiling point
o
C
Melting point
o
C
Particle size
m
1
Density at 25oC
kg/m3
1000
Vapor pressure at 20 C
kPa
2.3
pH
-
8.5-9.5
mPas
400
g/l
fully miscible
o
Viscosity at 20 C o
Solubility in water at 25 C o
100 129-137
HEALTH & SAFETY Skin irritation
not irritating
Eye irritation (human)
not irritating
USE & PERFORMANCE Manufacturer
Muenzing, Micro Technologies GmbH
Additive type
slip and antiblocking agent
Recommended for products
water-based paints and coatings (wood, automotive, industrial, can, metal), water-based printing inks (flexo, gravure)
Outstanding properties
abrasion resistance, hydrophobic character, increased gloss
Databook of Antiblocking, Release, and Slip Additives
118
Ceretan WM 8701 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Ceretan WM 8701
Common name
Water emulsion of montan wax
Mixture
-
yes
Product contents
wt%
30
PHYSICAL PROPERTIES State
-
liquid
Color
-
white
Boiling point
o
C
Melting point
o
C
Particle size
m
1
Density at 25oC
kg/m3
1000
Vapor pressure at 20 C
kPa
2.3
pH
-
6-8
mPas
400
g/l
fully miscible
Animal testing, acute toxicity, Rat oral LD50
mg/kg
>2000
Skin irritation
not irritating
Eye irritation (human)
not irritating
o
Viscosity at 20 C o
Solubility in water at 25 C o
100 78-80
HEALTH & SAFETY
USE & PERFORMANCE Manufacturer
Muenzing, Micro Technologies GmbH
Additive type
-
Recommended for products
water-based paints and coatings (wood), water-based leather coatings
Outstanding properties
adhesion, hydrophobic character, scratch resistance, soft feel effect
Databook of Antiblocking, Release, and Slip Additives
antiblocking agent
119
Ceridust 3731 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Ceridust 3731
CAS #
-
Common name
High density polyethylene wax
Common synonym
Polyethylene wax, high density
Chemical class
-
68441-17-8; 68476-03-9
polyethylene wax
PHYSICAL PROPERTIES State
solid, powder micronized
Odor
-
odorless
Color
-
white
Dropping point
o
C
114-117
Particle size
m
12-18
Density at 25oC
kg/m3
980 average
mg KOH/g
26.0-32.0
g/l
insoluble
Acid number Solubility in water at 25 C o
HEALTH & SAFETY HMIS personal protection
goggles, apron, gloves
Animal testing, acute toxicity, Rat oral LD50
mg/kg
2000 min
ECOLOGICAL PROPERTIES Aquatic toxicity Fathead minnow, 96-h LC50
no harmful effect to fish
Aquatic toxicity, Rainbow trout, 96-h LC50
no harmful effect to fish
USE & PERFORMANCE Manufacturer
Clariant Corporation
Additive type
-
Recommended for products
liquid lacquers, printing inks water or water/alcohol-borne
Outstanding properties
improves abrasion resistance & antiblocking properties
Features and benefits
enhanced pigment dispersion
Processing methods
printing
Additive application method
process aid additive
Databook of Antiblocking, Release, and Slip Additives
antiblocking agent
120
Ceridust 9615 A PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Ceridust 9615 A
CAS #
-
Common name
Polyethylene wax
Molecular weight
daltons
yes
Chemical class
-
polyethylene wax
Product contents
polyethylene wax, modified with PTFE
9002-88-4; 110-30-5
PHYSICAL PROPERTIES State
solid, powder micronized
Odor
-
odorless
Color
-
white
Dropping point
o
Particle size
m
C
137-143 5.5-7.5 D50
Density at 25 C
kg/m
Acid number
mg KOH/g
2.0-5.0
Solubility in water at 25oC
g/l
insoluble
o
3
985 average
HEALTH & SAFETY HMIS personal protection
goggles, apron, gloves
Food approval(s)
FDA approved 21 CFR 175.105; 175.300
Animal testing, acute toxicity, Rat oral LD50
mg/kg
2000 min
ECOLOGICAL PROPERTIES Aquatic toxicity, Bluegill sunfish, 96-h LC50
no harmful effect to fish
Aquatic toxicity Fathead minnow, 96-h LC50
no harmful effect to fish
Aquatic toxicity, Rainbow trout, 96-h LC50
no harmful effect to fish
USE & PERFORMANCE Manufacturer
Clariant Corporation
Additive type
-
Recommended for products
packaging films
Outstanding properties
decreases coefficient of friction, improves scratch resistance & slip properties
Features and benefits
enhanced pigment dispersion, rub resistance after short drying time
Processing methods
printing: flexo, gravure
Additive application method
process aid additive
Databook of Antiblocking, Release, and Slip Additives
antiblocking agent
121
Ceridust 9630 F PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Ceridust 9630 F
CAS #
-
Common name
Polyethylene wax modified with polytetrafluoroethylene
Molecular weight
daltons
yes
Chemical class
-
polyethylene wax
Product contents
polyethylene wax, modified with PTFE
9002-88-4; 9002-84-0
PHYSICAL PROPERTIES State
solid, powder micronized
Odor
-
odorless
Color
-
white
Melting point
o
C
126.5 average
m
Particle size
7.0-9.5 D50
Density at 25 C
kg/m
Acid number
mg KOH/g
1.0-3.0
Solubility in water at 25oC
g/l
insoluble
o
3
1135 average
HEALTH & SAFETY HMIS personal protection
goggles, apron, gloves
Food approval(s)
FDA approved 21 CFR 175.300
Animal testing, acute toxicity, Rat oral LD50
mg/kg
2000 min
ECOLOGICAL PROPERTIES Aquatic toxicity, Bluegill sunfish, 96-h LC50
no harmful effect to fish
Aquatic toxicity Fathead minnow, 96-h LC50
no harmful effect to fish
Aquatic toxicity, Rainbow trout, 96-h LC50
no harmful effect to fish
USE & PERFORMANCE Manufacturer
Clariant Corporation
Additive type
antiblocking & slip agent
Recommended for products
various coatings, printing inks
Outstanding properties
decreases coefficient of friction, improves slip properties
Features and benefits
enhanced pigment dispersion
Processing methods
printing: gravure, screen, powder coating
Additive application method
process aid additive
Databook of Antiblocking, Release, and Slip Additives
122
Dynamar FX 5920A PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Dynamar FX 5920A
Chemical class
-
fluoropolymer
Solids content
wt%
100
-
solid, granular
PHYSICAL PROPERTIES State Odor
-
odorless
Color
-
off-white
Particle size
m
Bulk density
kg/m
Solubility in water at 25oC
g/l
10 max mesh 3
700 insoluble
HEALTH & SAFETY HMIS personal protection
goggles, apron, gloves
Hazardous components
heating above 400C can evolve degradation to: hydrogen fluoride (HF); carbonyl fluoride (CF2)
Food approval(s)
FDA approved 21 CFR 176.170; 177.1520; 177.1350
Skin irritation
may cause irritation
Eye irritation (human)
may cause irritation
Carcinogenicity
no carcinogenic ingredients present at over 0.1%
USE & PERFORMANCE Manufacturer
-
3M Company
Additive type
antiblocking & slip agent
Recommended for polymers
polyolefin resins, LDPE, LLDPE; HDPE
Recommended for products
film, pipe & tubing, wire & cable
Outstanding properties
reduces melt fracture & die build-up, effective in resins containing silica/talc based antiblocking agent
Features and benefits
improves surface & gloss, reduces cycle time, minimized equipment maintenance
Processing methods
blow molding, extrusion
Additive application method
process aid additive
Recommended dosage
50 - 1000 ppm; for products indirect food contact less than 0.22%
Recommended mold material
metal-on-metal; metal-on-plastic; plastic-on-plastic
Databook of Antiblocking, Release, and Slip Additives
123
Dyneon PA 5952 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Dyneon PA 5952
Chemical class
-
fluoropolymer
PHYSICAL PROPERTIES State
-
solid
Odor
-
odorless
Color
-
white
Particle size
m
Surface area (BET)
m /g
Bulk density
kg/m
Solubility in water at 25oC
g/l
15.0 avg 2
2
3
450 insoluble
HEALTH & SAFETY HMIS personal protection
goggles, apron, gloves
Eye irritation (human)
may cause irritation
USE & PERFORMANCE Manufacturer
-
3M Company
Additive type
antiblocking & slip agent
Recommended for polymers
thermoplastics & engineering resins
Recommended for products
automotive parts, building industries, wire & cable
Outstanding properties
improves wear resistance, nonstick properties, lubricity & frictional characteristics
Features and benefits
improves chemical & stain resistance
Processing methods
extrusion, injection molding
Additive application method
process aid additive
Recommended mold material
metal-on-metal; metal-on-plastic; plastic-on-plastic
Databook of Antiblocking, Release, and Slip Additives
124
Hordamer PE 35 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Hordamer PE 35
Common name
Polyethylene wax dispersion
Product contents
primary polyethylene & wax polyethylene dispersion
Solids content
wt%
37.5 average
PHYSICAL PROPERTIES State
liquid, emulsion-anionic/nonionic emulsifiers
Odor
-
odorless
Color
-
milky white
Melting point
o
C
125 (wax)
Density at 20 C
kg/m
Vapor pressure at 25oC
kPa
<250
pH
-
9.0-10.0
Viscosity at 20 C
mPas
250 max
Solubility in water at 25oC
g/l
miscible in all ratios
o
o
3
980 average
HEALTH & SAFETY HMIS personal protection
goggles, apron, gloves
Animal testing, acute toxicity, Rat oral LD50
mg/kg
>2000 (polyoxyethylene isodecyl ether)
USE & PERFORMANCE Manufacturer
BYK Additives & Instruments
Additive type
-
Recommended for products
lacquers, inks
Outstanding properties
primarily used as antiblocking agent in printing inks
antiblocking agent
Processing methods
coatings, printing
Additive application method
external application-overprint varnish for paper
Recommended dosage
wt%
Databook of Antiblocking, Release, and Slip Additives
4-13 (total formulation)
125
Masil SF 100 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Masil SF 100
CAS #
-
Common name
Polydimethylsiloxane
Acronym
-
63148-62-9 PDMS
Formula
CH3 H3C Si CH3
Chemical class
CH3
CH3 O Si
O Si CH3
CH3 n CH3
-
silicone polymer
State
-
liquid
Odor
-
odorless
Color
-
colorless
Pour point
o
PHYSICAL PROPERTIES
Refractive index at 25 C o
C
-
-55 1.403
Specific gravity at 25 C
-
0.968
Solubility in water at 25oC
g/l
insoluble
Solubility in solvents
miscible with aliphatic & aromatic solvents
Volatility
wt%
o
0.5 24 h @ 150C
HEALTH & SAFETY DOT class
-
not regulated
ADR/RIC class
-
not regulated
TDG class
-
not regulated
Flash point
o
Flash point method
-
Eye irritation (human)
may cause slight irritation
C
461 PMCC
USE & PERFORMANCE Manufacturer
Emerald Performance Materials
Additive type
mold release & antiblocking agent
Recommended for polymers
plastics, rubber
Recommended for products
rubber & plastics parts, paper, textile, fiber & thread
Outstanding properties
high thermal & oxidation stability, chemically inert/non-reactive with variety of materials, non-corrosive & non-toxic
Databook of Antiblocking, Release, and Slip Additives
126
Masil SF 100 PARAMETER
UNIT
Features and benefits
low viscosity/temperature coefficient ratios, stability to mechanical shear stress
Processing methods
calendering, extrusion
Databook of Antiblocking, Release, and Slip Additives
VALUE
127
Masil SF 1000 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Masil SF 1000
CAS #
-
Common name
Polydimethylsiloxane
Acronym
-
63148-62-9 PDMS
Formula
CH3 H3C Si CH3
Chemical class
CH3
CH3 O Si
O Si CH3
CH3 n CH3
-
silicone polymer
PHYSICAL PROPERTIES State
-
liquid
Odor
-
odorless
Color
-
colorless
Boiling point
o
C
>65
Pour point
o
C
-50
Refractive index at 25 C o
-
1.4035
Specific gravity at 25 C
-
0.974
Solubility in water at 25oC
g/l
insoluble
Solubility in solvents
miscible with aliphatic & aromatic solvents
Volatility
wt%
0.5 24 h @ 150oC
Health
1
Flammability
1
Reactivity
0
Health
1
Flammability
1
Reactivity
0
o
HEALTH & SAFETY NFPA classification
HMIS classification
DOT class
-
not regulated
ADR/RIC class
-
not regulated
TDG class
-
not regulated
Flash point
o
Flash point method
-
Eye irritation (human)
may cause slight irritation
C
Databook of Antiblocking, Release, and Slip Additives
>120 PMCC
128
Masil SF 1000 PARAMETER
UNIT
VALUE
USE & PERFORMANCE Manufacturer
Emerald Performance Materials
Additive type
mold release & antiblocking agent
Recommended for polymers
plastics, rubber
Recommended for products
rubber & plastics parts, paper, textile, fiber & thread
Outstanding properties
high thermal & oxidation stability, chemically inert/non-reactive with variety of materials, non-corrosive & non-toxic
Features and benefits
low viscosity/temperature coefficient ratios, stability to mechanical shear stress
Processing methods
molding, calendering, extrusion
Databook of Antiblocking, Release, and Slip Additives
129
Masil SF 10000 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Masil SF 10000
CAS #
-
Common name
Polydimethylsiloxane
Acronym
-
63148-62-9 PDMS
Formula
CH3 H3C Si CH3
CH3
CH3 O Si
O Si CH3
CH3 n CH3
Molecular weight
daltons
Chemical class
-
silicone polymer
State
-
liquid
Odor
-
odorless
Color
-
colorless
Pour point
o
PHYSICAL PROPERTIES
Refractive index at 25 C o
C
-
-47 1.4035
Specific gravity at 25 C
-
0.975
Solubility in water at 25oC
g/l
insoluble
Solubility in solvents
miscible with aliphatic & aromatic solvents
Volatility
wt%
o
2.0 24 h @ 150oC
HEALTH & SAFETY DOT class
-
not regulated
ADR/RIC class
-
not regulated
TDG class
-
not regulated
Flash point
o
Flash point method
-
Eye irritation (human)
may cause slight irritation
C
500 PMCC
USE & PERFORMANCE Manufacturer
Emerald Performance Materials
Additive type
mold release & antiblocking agent
Recommended for polymers
plastics, rubber
Recommended for products
rubber & plastics parts, paper, textile, fiber & thread
Outstanding properties
high thermal & oxidation stability, chemically inert/non-reactive with variety of materials, non-corrosive & non-toxic
Databook of Antiblocking, Release, and Slip Additives
130
Masil SF 10000 PARAMETER
UNIT
Features and benefits
low viscosity/temperature coefficient ratios, stability to mechanical shear stress
Processing methods
molding, calendering, extrusion
Databook of Antiblocking, Release, and Slip Additives
VALUE
131
Masil SF 1000000 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Masil SF 1000000
CAS #
-
Common name
Polydimethylsiloxane
Acronym
-
63148-62-9 PDMS
Formula
CH3 H3C Si CH3
Chemical class
CH3
CH3 O Si
O Si CH3
CH3 n CH3
-
silicone polymer
PHYSICAL PROPERTIES State
-
liquid
Odor
-
odorless
Color
-
colorless
Pour point
o
Refractive index at 25oC
-
1.4035
Specific gravity at 25oC
-
0.979 insoluble
C
-25
Solubility in water at 25 C
g/l
Solubility in solvents
miscible with aliphatic & aromatic solvents
Volatility
wt%
2.0 24 h @ 150C
DOT class
-
not regulated
ADR/RIC class
-
not regulated
TDG class
-
not regulated
Flash point
o
Flash point method
-
Eye irritation (human)
may cause slight irritation
o
HEALTH & SAFETY
C
500 PMCC
USE & PERFORMANCE Manufacturer
Emerald Performance Materials
Additive type
mold release & antiblocking agent
Recommended for polymers
plastics, rubber
Recommended for products
rubber & plastics parts, paper, textile, fiber & thread
Outstanding properties
high thermal & oxidation stability, chemically inert/non-reactive with variety of materials, non-corrosive & non-toxic
Databook of Antiblocking, Release, and Slip Additives
132
Masil SF 1000000 PARAMETER
UNIT
Features and benefits
low viscosity/temperature coefficient ratios, stability to mechanical shear stress
Processing methods
molding, calendering, extrusion
Databook of Antiblocking, Release, and Slip Additives
VALUE
133
Michem Emulsion 1270 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Michem Emulsion 1270
Common name
Carnauba wax emulsion
Mixture
-
Product contents
24.5-25.5%
yes
PHYSICAL PROPERTIES State
-
liquid
Color
-
tan
-
8-11
mPas
40
pH Viscosity at 25 C o
HEALTH & SAFETY Food approval(s)
Approved for food contact
USE & PERFORMANCE Manufacturer
-
Additive type
antiblocking and slip agent
Recommended for products
coatings
Recommended dosage
wt%
Databook of Antiblocking, Release, and Slip Additives
Michelman
2-4
134
Michem Emulsion 29730 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Michem Emulsion 29730
Common name
Polyethylene wax aqueous emulsion
Chemical class
wax aqueous emulsion
Mixture
-
Product contents
24.5-25.5%
Solids content
wt%
yes 30
PHYSICAL PROPERTIES State
liquid, aq-based anionic emulsion
Odor
-
slight
Color
-
off-white
Melting point
o
C
101.0 wax
Particle size
m
0.045
Specific gravity at 20oC
-
0.97-0.99
pH
-
9
Manufacturer
-
Michelman
Additive type
-
antiblocking agent
Recommended for products
packaging paper, skin & medical packaging
Processing methods
laminating adhesives for paper, foil & film, heat-seal adhesives
Recommended dosage
wt%
USE & PERFORMANCE
Databook of Antiblocking, Release, and Slip Additives
2-4
135
Michem Emulsion 59740 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Michem Emulsion 59740
Common name
Polypropylene wax aqueous emulsion
Chemical class
wax aqueous emulsion
Mixture
-
Product contents
24.5-25.5%
Solids content
wt%
yes 40
PHYSICAL PROPERTIES State
liquid, aq-based anionic emulsion
Odor
-
slight
Color
-
tan
Melting point
o
C
142.0-148.0 wax
Particle size
m
0.024
Specific gravity at 20oC
-
1.00-1.02
pH
-
10
Manufacturer
-
Michelman
Additive type
-
antiblocking agent
USE & PERFORMANCE
Recommended for polymers
fiberglass, filaments
Outstanding properties
prevents fiberglass and other filaments from contacting machinery and one another
Processing methods
laminating adhesives for paper, foil & film, heat-seal adhesives
Recommended dosage
wt%
Databook of Antiblocking, Release, and Slip Additives
2-4
136
Michem Emulsion 98040M1 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Michem Emulsion 98040M1
Common name
Fischer-Tropsch wax aqueous emulsion
Chemical class
wax aqueous emulsion
Mixture
-
Product contents
24.5-25.5%
Solids content
wt%
yes 40
PHYSICAL PROPERTIES State
liquid, aq-based nonionic emulsion
Odor
-
slight
Color
-
off-white
Melting point
o
C
98.0 wax
Particle size
m
0.7
Specific gravity at 20oC
-
0.98-1.00
pH
-
3.0-10.0
Manufacturer
-
Michelman
Additive type
-
antiblocking agent
Recommended for products
paints, coatings, varnishes
Outstanding properties
improves scratch & mar resistance
USE & PERFORMANCE
Databook of Antiblocking, Release, and Slip Additives
137
Michem Lube 162 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Michem Lube 162
Common name
Carnauba wax aqueous emulsion
Chemical class
wax aqueous emulsion
Mixture
-
Product contents
24.5-25.5%
Solids content
wt%
yes 25
PHYSICAL PROPERTIES State
liquid, aq-based nonionic emulsion
Odor
-
slight
Color
-
off-white
Melting point
o
C
85.0-93.0 wax
Particle size
m
0.13
Specific gravity at 20oC
-
0.99-1.01
pH
-
6
Manufacturer
-
Michelman
Additive type
-
antiblocking agent
Recommended for products
inks, varnishes, paints
Outstanding properties
recommended as antislip additives
Processing methods
printing, coating
USE & PERFORMANCE
Databook of Antiblocking, Release, and Slip Additives
138
Michem Lube 368 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Michem Lube 368
Common name
Anionic paraffin/polyethylene wax aqueous emulsion
Chemical class
wax aqueous emulsion
Mixture
-
Product contents
24.5-25.5%
Solids content
wt%
yes 35
PHYSICAL PROPERTIES State
liquid, aq-based anionic emulsion
Odor
-
slight
Color
-
off-white
Melting point
o
Particle size
m
0.18
-
0.95-0.99
Manufacturer
-
Michelman
Additive type
-
antiblocking agent
Recommended for products
inks, varnishes, paints
Outstanding properties
recommended as strong antiblocking additive, average lubricity & mar resistance
Processing methods
printing, coating
Specific gravity at 20 C o
C
60.0-101.0 wax
USE & PERFORMANCE
Databook of Antiblocking, Release, and Slip Additives
139
Tego Glide 482 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Tego Glide 482
Common name
Polyether siloxane copolymer
Chemical class
-
siloxane copolymer
Product contents
wt%
65
PHYSICAL PROPERTIES State
-
liquid
Color
-
hazy
Viscosity at 25oC
mPas
100
HEALTH & SAFETY Skin irritation
no harmful effect
Eye irritation (human)
no harmful effect
Carcinogenicity
not listed by NTP, IARC, or OSHA
USE & PERFORMANCE Manufacturer
Evonic Industries AG
Additive type
antiblocking & slip agent
Recommended for products
waterborne systems
Recommended dosage
wt%
Databook of Antiblocking, Release, and Slip Additives
0.1-1.0
140
Zonyl MP 1100 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Zonyl MP 1100
CAS #
-
Common name
Tetrafluoroethylene homopolymer
Common synonym
Polytetrafluoroethylene
Acronym
-
9002-84-0
PTFE
Formula
F(CF2)nF
Chemical class
-
fluoropolymer
Solids content
wt%
99.0-100.0
PHYSICAL PROPERTIES State
-
solid, powder
Odor
-
odorless
Color
-
white
Melting point
o
C
325 average
Particle size
m
1.8-4.0 avg
Surface area (BET)
m /g
5.0-10.0
Specific gravity at 20oC
-
2.2
Bulk density
kg/m3
300 average
Dielectric constant at 1 MHz
-
2.1
Solubility in water at 25oC
g/l
insoluble
Coefficient of friction
0.1 dynamic (max 3m/min); 0.05 static (3.4 MPa)
2
HEALTH & SAFETY NFPA classification
HMIS classification
Health
2
Flammability
1
Reactivity
0
Health
2
Flammability
1
Reactivity
0
HMIS personal protection
goggles, apron, gloves
Hazardous components
heating above 400C can evolve degradation to: hydrogen fluoride (HF); carbonyl fluoride (CF2)
DOT class
-
not regulated
TDG class
-
not regulated
Databook of Antiblocking, Release, and Slip Additives
141
Zonyl MP 1100 PARAMETER
UNIT
Proper shipping name
plastic, synthetic, O.T.L., NOIBN by rail; plastics, materials, granules by truck
Autoignition temperature
o
TLV – TWA 8h, ACGIH
mg/m
10.0 total, 5.0 respiratory dust PTFE-Dupont Acceptable Limit
TLV – TWA 8h, OSHA
mg/m3
15.0 total, 5.0 respiratory dust PTFE
TLV – TWA 8h, ACGIH
ppm
0.5 HF; 2.0 CF2O
TLV – TWA 8h, OSHA
ppm
2.0 HF
Skin irritation
may cause irritation
Eye irritation (human)
may cause irritation
Carcinogenicity
no carcinogenic ingredients present at over 0.1%
C
VALUE
520-560 3
USE & PERFORMANCE Manufacturer
-
DuPont
Additive type
-
antiblocking agent
Recommended for polymers
printing inks, thermoplastics & thermosetting resins, rubber
Recommended for products
printing; protective coatings, bakeware, coated rollers
Outstanding properties
improves abrasion, scratch, scuff resistance; increases slip, surface smoothness & gloss
Features and benefits
improves chemical & stain resistance
Processing methods
variety of coating systems, offset, gravure, & flexographic printing inks
Additive application method
process aid additive
Recommended dosage
1.00 - 3.00% weight inks; elastomers 5.00 - 20.00% weight; can be used at temperature 190 to 250C
Databook of Antiblocking, Release, and Slip Additives
142
Zonyl MP 1200 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Zonyl MP 1200
CAS #
-
Common name
Tetrafluoroethylene homopolymer
Common synonym
Polytetrafluoroethylene
Acronym
-
9002-84-0
PTFE
Formula
F(CF2)nF
Chemical class
-
fluoropolymer
Solids content
wt%
99.0-100.0
PHYSICAL PROPERTIES State
solid, non-agglomerated powder
Odor
-
odorless
Color
-
white
Melting point
o
C
325 average
Particle size
m
2.5-4.5 avg
Surface area (BET)
m /g
1.5-3.0
Specific gravity at 20oC
-
2.2
Bulk density
kg/m3
450 average
Dielectric constant at 1 MHz
-
2.1
Solubility in water at 25oC
g/l
insoluble
Coefficient of friction
0.1 dynamic (max 3m/min); 0.05 static (3.4 MPa)
2
HEALTH & SAFETY NFPA classification
HMIS classification
Health
2
Flammability
1
Reactivity
0
Health
2
Flammability
1
Reactivity
0
HMIS personal protection
goggles, apron, gloves
Hazardous components
heating above 400oC can evolve degradation to: hydrogen fluoride (HF); carbonyl fluoride (CF2)
DOT class
-
not regulated
TDG class
-
not regulated
Databook of Antiblocking, Release, and Slip Additives
143
Zonyl MP 1200 PARAMETER
UNIT
Proper shipping name
plastic, synthetic, O.T.L., NOIBN by rail; plastics, materials, granules by truck
Autoignition temperature
o
TLV – TWA 8h, ACGIH
mg/m
TLV – TWA 8h, NIOSH
mg/m3
TLV – TWA 8h, OSHA
mg/m3
15.0 total, 5.0 respiratory dust PTFE
TLV – TWA 8h, ACGIH
ppm
0.5 HF; 2.0 CF2O
TLV – TWA 8h, OSHA
ppm
2.0 HF
Skin irritation
may cause irritation
Eye irritation (human)
may cause irritation
Carcinogenicity
no carcinogenic ingredients present at over 0.1%
C
VALUE
520-560 3
10.0 total, 5.0 respiratory dust PTFE-Dupont Acceptable Limit
USE & PERFORMANCE Manufacturer
-
DuPont
Additive type
-
antiblocking agent
Recommended for polymers
printing inks, thermoplastics & thermosetting resins, rubber
Recommended for products
printing; protective coatings, bakeware, coated rollers
Outstanding properties
improves abrasion, scratch, scuff resistance; increases slip, surface smoothness & gloss
Features and benefits
improves chemical & stain resistance
Processing methods
variety of coating systems, offset, gravure, & flexographic printing inks
Additive application method
process aid additive
Recommended dosage
1.00 - 3.00% weight inks; elastomers 5.00 - 20.00% weight; can be used at temperature 190 to 250oC
Databook of Antiblocking, Release, and Slip Additives
144
Zonyl MP 1500 PARAMETER
UNIT
VALUE
GENERAL INFORMATION Name
Zonyl MP 1500
CAS #
-
Common name
Tetrafluoroethylene homopolymer
Common synonym
Polytetrafluoroethylene
Acronym
-
Formula
9002-84-0
PTFE
F(CF2)nF
Chemical class
-
fluoropolymer
Solids content
wt%
99.0-100.0
PHYSICAL PROPERTIES State
-
solid, powder
Odor
-
odorless
Color
-
white
Melting point
o
Particle size
m
C
325 average 20.0 avg agglomerate size
m2/g
8.0-12.0
Specific gravity at 20 C
-
2.2
Bulk density
kg/m3
375 average
Dielectric constant at 1 MHz
-
2.1
Solubility in water at 25oC
g/l
insoluble
Coefficient of friction
0.1 dynamic (max 3m/min); 0.05 static (3.4 MPa)
Surface area (BET) o
HEALTH & SAFETY NFPA classification
HMIS classification
Health
2
Flammability
1
Reactivity
0
Health
2
Flammability
1
Reactivity
0
HMIS personal protection
goggles, apron, gloves
Hazardous components
heating above 400oC can evolve degradation to: hydrogen fluoride (HF); carbonyl fluoride (CF2)
Databook of Antiblocking, Release, and Slip Additives
145
Zonyl MP 1500 PARAMETER
UNIT
Food approval(s)
FDA approved 21 CFR 175.105; 175. 300; 176.170; 176.180; 177.1550, 1520 & 2600; 177.1520
DOT class
-
not regulated
TDG class
-
not regulated
Proper shipping name
plastic, synthetic, O.T.L., NOIBN by rail; plastics, materials, granules by truck
Autoignition temperature
o
TLV – TWA 8h, ACGIH
mg/m
10.0 total, 5.0 respiratory dust PTFE-Dupont Acceptable Limit
TLV – TWA 8h, OSHA
mg/m3
15.0 total, 5.0 respiratory dust PTFE
TLV – TWA 8h, ACGIH
ppm
0.5 HF; 2.0 CF2O
TLV – TWA 8h, OSHA
ppm
2.0 HF
Skin irritation
may cause irritation
Eye irritation (human)
may cause irritation
Carcinogenicity
no carcinogenic ingredients present at over 0.1%
C
VALUE
520-560 3
USE & PERFORMANCE Manufacturer
-
DuPont
Additive type
-
antiblocking agent
Recommended for polymers
fluoroelastomers, EPDM elastomers, Neoprene elastomers, SBR elastomers
Recommended for products
various articles
Outstanding properties
improves wear resistance, nonstick properties, lubricity & frictional characteristics
Processing methods
variety of coating systems
Additive application method
process aid additive
Recommended dosage
50/50 masterbatch with elastomer; 10 phr or more
Databook of Antiblocking, Release, and Slip Additives
146