Polymers and waxes

Polymers and waxes

3.2.3 Polymers and waxes A-C325 PARAMETER UNIT VALUE GENERAL INFORMATION Name A-C325 CAS # - Common name Oxidized polyethylene homopolymer Ch...

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3.2.3 Polymers and waxes A-C325 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

A-C325

CAS #

-

Common name

Oxidized polyethylene homopolymer

Chemical class

-

polymer

68441-17-8

PHYSICAL PROPERTIES State

-

solid, granules

Odor

-

waxy odor

Color

-

white

Freezing point

o

C

88-140

Dropping point

o

C

136

Particle hardness

dmm

0.5 max ASTM D-5 0.85-1.00

Specific gravity at 20 C

-

Density at 20oC

kg/m3

990 approx.

Bulk density

kg/m

625

Acid number

mg KOH/g

24-27

Viscosity at 140oC

mPas

4500

g/l

insoluble

o

Solubility in water at 25 C o

3

HEALTH & SAFETY HMIS personal protection

goggles, apron, gloves

DOT class

-

not regulated

ADR/RIC class

-

not regulated

TDG class

-

not regulated

Flash point

o

Flash point method

-

OC

TLV – TWA 8h, ACGIH

mg/m3

10 total particulates

Animal testing, acute toxicity, Rat oral LD50

mg/kg

2,500

Skin irritation

considered non-irritant

Eye irritation (human)

considered non-irritant

C

255.0 min

USE & PERFORMANCE Manufacturer

-

Honeywell

Additive type

-

antiblocking agent

Recommended for polymers

PVC

Recommended for products

packaging products

Outstanding properties

effective lubricant for PVC

Processing methods

coating

Additive application method

process aid additive

Databook of Antiblocking, Release, and Slip Additives

103

A-C629 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

A-C629

CAS #

-

Common name

Oxidized polyethylene homopolymer

Chemical class

-

polymer

68441-17-8

PHYSICAL PROPERTIES State

-

solid, prill

Odor

-

waxy odor

Color

-

white

Freezing point

o

C

88-140

Dropping point

o

C

101

Particle size

m

2000-3000

Particle hardness

dmm

5.5 ASTM D-5

Specific gravity at 20oC

-

0.85-1.00

Density at 20 C

kg/m

3

Bulk density

kg/m

3

Acid number

mg KOH/g

o

930 485 14-17

Viscosity at 140oC

mPas

200

Solubility in water at 25oC

g/l

insoluble

HEALTH & SAFETY HMIS personal protection

goggles, apron, gloves

Food approval(s)

FDA approved 21 CFR 175.105, 125, 300, 310; 176.170, 180, 200, 210; 177.1200, 1210; 177.2600; 178.3570

DOT class

-

not regulated

ADR/RIC class

-

not regulated

TDG class

-

not regulated

Flash point

o

Flash point method

-

C

255.0 min OC

TLV – TWA 8h, ACGIH

mg/m

10 total particulates

Animal testing, acute toxicity, Rat oral LD50

mg/kg

2,500

Skin irritation

considered non-irritant

Eye irritation (human)

considered non-irritant

3

USE & PERFORMANCE Manufacturer

-

Honeywell

Additive type

-

antiblocking agent

Recommended for polymers

PVC

Databook of Antiblocking, Release, and Slip Additives

104

A-C629 PARAMETER

UNIT

Recommended for products

windows & doors, packaging products

Outstanding properties

effective lubricant for PVC

Features and benefits

increases gloss

Processing methods

injection & blow molding, extrusion, calendering, coating

Additive application method

process aid additive

Databook of Antiblocking, Release, and Slip Additives

VALUE

105

Addid 130 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Addid 130

Common name

Polyether-modified polydimethylsiloxane

Chemical class

-

siloxane

-

liquid

PHYSICAL PROPERTIES State Odor

-

slight

Color

-

yellowish

Refractive index at 25oC

-

Density at 25 C

kg/m

Viscosity at 25oC

mPas

800

cSt

600-1200

o

Kinematic viscosity at 25oC

1.425 3

1030

Surface tension at 25 C

mN/m

22

Solubility in water at 25oC

g/l

miscible

Solubility in solvents

IBA, xylene, isobutanol, butanol, 2-propanol

o

HEALTH & SAFETY HMIS classification

Health

1

Flammability

1

Reactivity

0

HMIS personal protection

goggles, apron, gloves

Hazardous components

octamethyl cyclotetrasiloxane CAS# 556-67-2 (0.1-1%)

Food approval(s)

FDA approved 21 CFR 176.200

OSHA hazard class

-

combustible IIIB

DOT class

-

not regulated

ADR/RIC class

-

not regulated

TDG class

-

not regulated

Canadian WHMIS classification

-

D2A

Autoignition temperature

o

C

320

Flash point

o

C

140

TLV – TWA 8h, ACGIH

ppm

10 octamethyl cyclotetrasiloxane

Animal testing, acute toxicity, Rat oral LD50

mg/kg

>2000

Skin irritation

considered non-irritant

Eye irritation (human)

may cause slight irritation

Carcinogenicity

contains 1% max listed as possible carcinogen

Databook of Antiblocking, Release, and Slip Additives

106

Addid 130 PARAMETER

UNIT

VALUE

Manufacturer

-

Wacker Silicones

Additive type

-

antiblocking agent

Recommended for polymers

solvent-borne alkyd-, melamine- & polyester resin-based binder system, water-borne alkyd resins

Outstanding properties

improves surface smoothness, scratch resistance, reduces surface tension of coatings

USE & PERFORMANCE

Features and benefits

improves flow & leveling

Processing methods

coatings systems

Additive application method

process aid additive

Recommended dosage

wt%

Databook of Antiblocking, Release, and Slip Additives

0.01-0.6 (total solids) 0.05-1 (total formulation)

107

Algoflon L206 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Algoflon L206

CAS #

-

Common name

Tetrafluoroethylene homopolymer

Common synonym

Polytetrafluoroethylene

Acronym

-

PTFE

Empirical formula

-

(CF2CF2)n

9002-84-0

Formula

F(CF2)nF

Chemical class

-

fluoropolymer

EC number

-

204-126-9

Solids content

wt%

100

PHYSICAL PROPERTIES State

solid, micronized powder

Odor

-

odorless

Color

-

off-white

Melting point

o

Particle size

m

0.25

Surface area (BET)

m2/g

7.5

C

Specific gravity at 20 C

-

Bulk density

kg/m

o

329-332

2.2 3

330

HEALTH & SAFETY NFPA classification

HMIS classification

Health

1

Flammability

0

Reactivity

0

Health

1

Flammability

0

Reactivity

0

HMIS personal protection

goggles, apron, gloves

Hazardous components

heating above 400oC can evolve degradation to: hydrogen fluoride (HF); carbonyl fluoride (CF2)

Food approval(s)

FDA approved 21 CFR 177.1550

UN risk phrases, R

-

US safety phrases, S

26,39,24/25,45,22,23,53

DOT class

-

Databook of Antiblocking, Release, and Slip Additives

41,36/38,45 not regulated 108

Algoflon L206 PARAMETER

UNIT

VALUE not regulated

TDG class

-

Autoignition temperature

o

TLV – TWA 8h, ACGIH

mg/m

5.0 HF, CF2O; 10 total dust, 5 respiratory PTFE

TLV – TWA 8h, OSHA

mg/m3

5.0 HF, CF2O; 15.0 total, 5.0 respiratory dust PTFE

TLV – TWA 8h, OSHA

ppm

2.0 HF

Skin irritation

may cause irritation

Eye irritation (human)

may cause irritation

Carcinogenicity

no carcinogenic ingredients present at over 0.1%

C

530-570 3

USE & PERFORMANCE Manufacturer

-

Solvay Solexis, Inc.

Additive type

-

antiblocking agent

Recommended for polymers

printing inks, thermoplastics & thermosetting resins, rubber, perfluoroelastomers

Recommended for products

packaging articles, protective coatings, bakeware, coated rollers, etc.

Outstanding properties

improves abrasion, scratch, scuff resistance; increases slip and block resistance, surface smoothness & gloss

Features and benefits

improves chemical & stain resistance; in thermoplastics improves lubricity & reduces friction, enhances tear resistance at elevated temperatures

Processing methods

variety of coating systems, offset, gravure, & flexographic printing inks

Additive application method

process aid additive

Databook of Antiblocking, Release, and Slip Additives

109

Aquacer 593 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Aquacer 593

Common name

PP wax

Chemical class

-

PP wax, modified

Mixture

-

yes

Solids content

wt%

30

PHYSICAL PROPERTIES State

liquid - non-ionic aq emulsion

Odor

-

mild

Color

-

yellow

Boiling point

o

C

Melting point

o

C

100 160

Density at 25 C

kg/m

pH

-

9

mPas

15 approx.

g/l

miscible

o

Viscosity at 25 C o

Solubility in water at 25 C o

3

900

HEALTH & SAFETY HMIS personal protection

goggles, apron, gloves

Hazardous components

wt%

Food approval(s)

FDA approved CFR21 175.105

UN risk phrases, R

22,41 ethoxylated alcohol; 22,35 NaOH

DOT class

-

not regulated

ADR/RIC class

-

not regulated

ICAO/IATA class

-

not regulated

IMDG class

-

not regulated

61827-42-7 (6.5%); 1310-58-3 (3.4%)

TDG class

-

not regulated

Canadian WHMIS classification

-

not controlled

Animal testing, acute toxicity, Rat oral LD50

mg/kg

3000

USE & PERFORMANCE Manufacturer

BYK-Cera bv, BYK-Chemie GmbH

Additive type

-

Recommended for products

printing inks: flexo-, gravure, overprint varnishes, offset & screen inks

Outstanding properties

reduces friction & adhesion forces

antiblocking agent

Features and benefits

improves scratch & rub resistance

Processing methods

printing inks

Databook of Antiblocking, Release, and Slip Additives

110

Aquacer 593 PARAMETER

UNIT

Additive application method

process aid additive

Recommended dosage

wt%

Databook of Antiblocking, Release, and Slip Additives

VALUE 3-4

111

Aquamat 263 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Aquamat 263

Common name

HD polyethylene wax

Chemical class

oxidized HD PE wax

Mixture

-

yes

Solids content

wt%

35

PHYSICAL PROPERTIES State

liquid - aqueous dispersion

Odor

-

mild

Color

-

white

Boiling point

o

C

100

Melting point

o

C

120

Particle size

m

25 max, dispersed

Density at 25oC

kg/m3

1000

pH

-

8.5

Viscosity at 25 C

mPas

75-275

Solubility in water at 25oC

g/l

miscible

o

HEALTH & SAFETY HMIS personal protection

goggles, apron, gloves

Hazardous components

wt%

Food approval(s)

FDA approved CFR21 175.105

UN risk phrases, R

36/38 3-butoxypropanol; 22,41,50 ethoxylated fatty acid

5131-66-8 (5%); 68439-50-9 (1.1%)

DOT class

-

not regulated

ADR/RIC class

-

not regulated

ICAO/IATA class

-

not regulated

IMDG class

-

not regulated

TDG class

-

not regulated

Canadian WHMIS classification

-

not controlled

Animal testing, acute toxicity, Rat oral LD50

mg/kg

9000

USE & PERFORMANCE Manufacturer

BYK-Cera bv, BYK-Chemie GmbH

Additive type

-

Recommended for products

paints, lacquers, inks

antiblocking agent

Features and benefits

improves scratch & rub resistance

Processing methods

industrial & decorative coatings, furniture & floor lacquers, inks

Databook of Antiblocking, Release, and Slip Additives

112

Aquamat 263 PARAMETER

UNIT

Additive application method

process aid additive

Recommended dosage

wt%

Databook of Antiblocking, Release, and Slip Additives

VALUE 3-6 (water-based); 3-14 (inks)

113

Ceretan ME 0420 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ceretan ME 0420

CAS #

-

Common name

Spherical, micronized, non-polar polyethylene wax

Formula

9002-88-4

CH2(CH2)nCH3

Mixture

-

no

Product contents

wt%

100

State

-

solid

Color

-

white

Dropping point

o

Particle size

m

20

Density at 25oC

kg/m3

930-960

PHYSICAL PROPERTIES

C

108-116

HEALTH & SAFETY Flash point

o

C

>170

Animal testing, acute toxicity, Rat oral LD50

mg/kg

Skin irritation

no significant effects or critical hazards known

Eye irritation (human)

no significant effects or critical hazards known

>2000

USE & PERFORMANCE Manufacturer

Muenzing, Micro Technologies GmbH

Additive type

-

Recommended for products

paints and coatings (powder, car, industrial, building, furniture, floor) and printing inks (water- and solvent-based)

Outstanding properties

abrasion resistance, good adhesion, improved dispersion

Databook of Antiblocking, Release, and Slip Additives

antiblocking agent

114

Ceretan MP 2150 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ceretan MP 2150

CAS #

-

Common name

Micronized polypropylene wax

Formula

9003-07-0

CH3 CH2CH

Mixture

-

yes

Product contents

wt%

100

n

PHYSICAL PROPERTIES State

-

solid

Color

-

white

Dropping point

o

C

156-164

Particle size

m

50

Density at 25oC

kg/m3

870-890

HEALTH & SAFETY Flash point

o

Animal testing, acute toxicity, Rat oral LD50

mg/kg

C

280

Skin irritation

no significant effects or critical hazards known

Eye irritation (human)

no significant effects or critical hazards known

Carcinogenicity

no significant effects or critical hazards known

>2000

USE & PERFORMANCE Manufacturer

Muenzing, Micro Technologies GmbH

Additive type

-

Recommended for products

paints and coatings (powder, industrial, construction, furniture, parquet), masterbatch

Outstanding properties

scratch resistance, matting, texturing, temperature resistance

Databook of Antiblocking, Release, and Slip Additives

antiblocking agent

115

Ceretan MX 9718 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ceretan MX 9718

Common name

Micronized functional blend

Mixture

-

yes

Product contents

wt%

100

PHYSICAL PROPERTIES State

-

solid

Color

-

white

Dropping point

o

C

134-142

Particle size

m

18

Density at 25oC

kg/m3

960-980

HEALTH & SAFETY Flash point

o

Animal testing, acute toxicity, Rat oral LD50

mg/kg

C

>200

Skin irritation

no significant effects or critical hazards known

Eye irritation (human)

no significant effects or critical hazards known

Carcinogenicity

no significant effects or critical hazards known

>15000

USE & PERFORMANCE Manufacturer

Muenzing, Micro Technologies GmbH

Additive type

-

Recommended for products

paints and coatings (powder, can, furniture, parquet, industrial)

Outstanding properties

matting, improved sandability, improved scratch resistance, `soft feel` in wood coatings

Databook of Antiblocking, Release, and Slip Additives

antiblocking agent

116

Ceretan WE 0601 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ceretan WE 0601

Common name

Water emulsion of paraffin wax

Mixture

-

yes

Product contents

wt%

50

PHYSICAL PROPERTIES State

-

liquid

Color

-

white

Boiling point

o

C

Melting point

o

C

Particle size

m

1

Density at 25oC

kg/m3

1000

Vapor pressure at 20 C

kPa

2.3

pH

-

8.5-10.5

mPas

400

g/l

fully miscible

mg/kg

>2000

o

Viscosity at 20 C o

Solubility in water at 25 C o

100 52-60

HEALTH & SAFETY Animal testing, acute toxicity, Rat oral LD50

USE & PERFORMANCE Manufacturer

Muenzing, Micro Technologies GmbH

Additive type

slip and antiblocking agent

Recommended for products

water-based paints and coatings (wood, industrial)

Outstanding properties

hydrophobic character

Databook of Antiblocking, Release, and Slip Additives

117

Ceretan WE 3501 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ceretan WE 3501

Common name

Water emulsion of polyethylene

Mixture

-

yes

Product contents

wt%

35

PHYSICAL PROPERTIES State

-

liquid

Color

-

white

Boiling point

o

C

Melting point

o

C

Particle size

m

1

Density at 25oC

kg/m3

1000

Vapor pressure at 20 C

kPa

2.3

pH

-

8.5-9.5

mPas

400

g/l

fully miscible

o

Viscosity at 20 C o

Solubility in water at 25 C o

100 129-137

HEALTH & SAFETY Skin irritation

not irritating

Eye irritation (human)

not irritating

USE & PERFORMANCE Manufacturer

Muenzing, Micro Technologies GmbH

Additive type

slip and antiblocking agent

Recommended for products

water-based paints and coatings (wood, automotive, industrial, can, metal), water-based printing inks (flexo, gravure)

Outstanding properties

abrasion resistance, hydrophobic character, increased gloss

Databook of Antiblocking, Release, and Slip Additives

118

Ceretan WM 8701 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ceretan WM 8701

Common name

Water emulsion of montan wax

Mixture

-

yes

Product contents

wt%

30

PHYSICAL PROPERTIES State

-

liquid

Color

-

white

Boiling point

o

C

Melting point

o

C

Particle size

m

1

Density at 25oC

kg/m3

1000

Vapor pressure at 20 C

kPa

2.3

pH

-

6-8

mPas

400

g/l

fully miscible

Animal testing, acute toxicity, Rat oral LD50

mg/kg

>2000

Skin irritation

not irritating

Eye irritation (human)

not irritating

o

Viscosity at 20 C o

Solubility in water at 25 C o

100 78-80

HEALTH & SAFETY

USE & PERFORMANCE Manufacturer

Muenzing, Micro Technologies GmbH

Additive type

-

Recommended for products

water-based paints and coatings (wood), water-based leather coatings

Outstanding properties

adhesion, hydrophobic character, scratch resistance, soft feel effect

Databook of Antiblocking, Release, and Slip Additives

antiblocking agent

119

Ceridust 3731 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ceridust 3731

CAS #

-

Common name

High density polyethylene wax

Common synonym

Polyethylene wax, high density

Chemical class

-

68441-17-8; 68476-03-9

polyethylene wax

PHYSICAL PROPERTIES State

solid, powder micronized

Odor

-

odorless

Color

-

white

Dropping point

o

C

114-117

Particle size

m

12-18

Density at 25oC

kg/m3

980 average

mg KOH/g

26.0-32.0

g/l

insoluble

Acid number Solubility in water at 25 C o

HEALTH & SAFETY HMIS personal protection

goggles, apron, gloves

Animal testing, acute toxicity, Rat oral LD50

mg/kg

2000 min

ECOLOGICAL PROPERTIES Aquatic toxicity Fathead minnow, 96-h LC50

no harmful effect to fish

Aquatic toxicity, Rainbow trout, 96-h LC50

no harmful effect to fish

USE & PERFORMANCE Manufacturer

Clariant Corporation

Additive type

-

Recommended for products

liquid lacquers, printing inks water or water/alcohol-borne

Outstanding properties

improves abrasion resistance & antiblocking properties

Features and benefits

enhanced pigment dispersion

Processing methods

printing

Additive application method

process aid additive

Databook of Antiblocking, Release, and Slip Additives

antiblocking agent

120

Ceridust 9615 A PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ceridust 9615 A

CAS #

-

Common name

Polyethylene wax

Molecular weight

daltons

yes

Chemical class

-

polyethylene wax

Product contents

polyethylene wax, modified with PTFE

9002-88-4; 110-30-5

PHYSICAL PROPERTIES State

solid, powder micronized

Odor

-

odorless

Color

-

white

Dropping point

o

Particle size

m

C

137-143 5.5-7.5 D50

Density at 25 C

kg/m

Acid number

mg KOH/g

2.0-5.0

Solubility in water at 25oC

g/l

insoluble

o

3

985 average

HEALTH & SAFETY HMIS personal protection

goggles, apron, gloves

Food approval(s)

FDA approved 21 CFR 175.105; 175.300

Animal testing, acute toxicity, Rat oral LD50

mg/kg

2000 min

ECOLOGICAL PROPERTIES Aquatic toxicity, Bluegill sunfish, 96-h LC50

no harmful effect to fish

Aquatic toxicity Fathead minnow, 96-h LC50

no harmful effect to fish

Aquatic toxicity, Rainbow trout, 96-h LC50

no harmful effect to fish

USE & PERFORMANCE Manufacturer

Clariant Corporation

Additive type

-

Recommended for products

packaging films

Outstanding properties

decreases coefficient of friction, improves scratch resistance & slip properties

Features and benefits

enhanced pigment dispersion, rub resistance after short drying time

Processing methods

printing: flexo, gravure

Additive application method

process aid additive

Databook of Antiblocking, Release, and Slip Additives

antiblocking agent

121

Ceridust 9630 F PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ceridust 9630 F

CAS #

-

Common name

Polyethylene wax modified with polytetrafluoroethylene

Molecular weight

daltons

yes

Chemical class

-

polyethylene wax

Product contents

polyethylene wax, modified with PTFE

9002-88-4; 9002-84-0

PHYSICAL PROPERTIES State

solid, powder micronized

Odor

-

odorless

Color

-

white

Melting point

o

C

126.5 average

m

Particle size

7.0-9.5 D50

Density at 25 C

kg/m

Acid number

mg KOH/g

1.0-3.0

Solubility in water at 25oC

g/l

insoluble

o

3

1135 average

HEALTH & SAFETY HMIS personal protection

goggles, apron, gloves

Food approval(s)

FDA approved 21 CFR 175.300

Animal testing, acute toxicity, Rat oral LD50

mg/kg

2000 min

ECOLOGICAL PROPERTIES Aquatic toxicity, Bluegill sunfish, 96-h LC50

no harmful effect to fish

Aquatic toxicity Fathead minnow, 96-h LC50

no harmful effect to fish

Aquatic toxicity, Rainbow trout, 96-h LC50

no harmful effect to fish

USE & PERFORMANCE Manufacturer

Clariant Corporation

Additive type

antiblocking & slip agent

Recommended for products

various coatings, printing inks

Outstanding properties

decreases coefficient of friction, improves slip properties

Features and benefits

enhanced pigment dispersion

Processing methods

printing: gravure, screen, powder coating

Additive application method

process aid additive

Databook of Antiblocking, Release, and Slip Additives

122

Dynamar FX 5920A PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Dynamar FX 5920A

Chemical class

-

fluoropolymer

Solids content

wt%

100

-

solid, granular

PHYSICAL PROPERTIES State Odor

-

odorless

Color

-

off-white

Particle size

m

Bulk density

kg/m

Solubility in water at 25oC

g/l

10 max mesh 3

700 insoluble

HEALTH & SAFETY HMIS personal protection

goggles, apron, gloves

Hazardous components

heating above 400C can evolve degradation to: hydrogen fluoride (HF); carbonyl fluoride (CF2)

Food approval(s)

FDA approved 21 CFR 176.170; 177.1520; 177.1350

Skin irritation

may cause irritation

Eye irritation (human)

may cause irritation

Carcinogenicity

no carcinogenic ingredients present at over 0.1%

USE & PERFORMANCE Manufacturer

-

3M Company

Additive type

antiblocking & slip agent

Recommended for polymers

polyolefin resins, LDPE, LLDPE; HDPE

Recommended for products

film, pipe & tubing, wire & cable

Outstanding properties

reduces melt fracture & die build-up, effective in resins containing silica/talc based antiblocking agent

Features and benefits

improves surface & gloss, reduces cycle time, minimized equipment maintenance

Processing methods

blow molding, extrusion

Additive application method

process aid additive

Recommended dosage

50 - 1000 ppm; for products indirect food contact less than 0.22%

Recommended mold material

metal-on-metal; metal-on-plastic; plastic-on-plastic

Databook of Antiblocking, Release, and Slip Additives

123

Dyneon PA 5952 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Dyneon PA 5952

Chemical class

-

fluoropolymer

PHYSICAL PROPERTIES State

-

solid

Odor

-

odorless

Color

-

white

Particle size

m

Surface area (BET)

m /g

Bulk density

kg/m

Solubility in water at 25oC

g/l

15.0 avg 2

2

3

450 insoluble

HEALTH & SAFETY HMIS personal protection

goggles, apron, gloves

Eye irritation (human)

may cause irritation

USE & PERFORMANCE Manufacturer

-

3M Company

Additive type

antiblocking & slip agent

Recommended for polymers

thermoplastics & engineering resins

Recommended for products

automotive parts, building industries, wire & cable

Outstanding properties

improves wear resistance, nonstick properties, lubricity & frictional characteristics

Features and benefits

improves chemical & stain resistance

Processing methods

extrusion, injection molding

Additive application method

process aid additive

Recommended mold material

metal-on-metal; metal-on-plastic; plastic-on-plastic

Databook of Antiblocking, Release, and Slip Additives

124

Hordamer PE 35 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Hordamer PE 35

Common name

Polyethylene wax dispersion

Product contents

primary polyethylene & wax polyethylene dispersion

Solids content

wt%

37.5 average

PHYSICAL PROPERTIES State

liquid, emulsion-anionic/nonionic emulsifiers

Odor

-

odorless

Color

-

milky white

Melting point

o

C

125 (wax)

Density at 20 C

kg/m

Vapor pressure at 25oC

kPa

<250

pH

-

9.0-10.0

Viscosity at 20 C

mPas

250 max

Solubility in water at 25oC

g/l

miscible in all ratios

o

o

3

980 average

HEALTH & SAFETY HMIS personal protection

goggles, apron, gloves

Animal testing, acute toxicity, Rat oral LD50

mg/kg

>2000 (polyoxyethylene isodecyl ether)

USE & PERFORMANCE Manufacturer

BYK Additives & Instruments

Additive type

-

Recommended for products

lacquers, inks

Outstanding properties

primarily used as antiblocking agent in printing inks

antiblocking agent

Processing methods

coatings, printing

Additive application method

external application-overprint varnish for paper

Recommended dosage

wt%

Databook of Antiblocking, Release, and Slip Additives

4-13 (total formulation)

125

Masil SF 100 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Masil SF 100

CAS #

-

Common name

Polydimethylsiloxane

Acronym

-

63148-62-9 PDMS

Formula

CH3 H3C Si CH3

Chemical class

CH3

CH3 O Si

O Si CH3

CH3 n CH3

-

silicone polymer

State

-

liquid

Odor

-

odorless

Color

-

colorless

Pour point

o

PHYSICAL PROPERTIES

Refractive index at 25 C o

C

-

-55 1.403

Specific gravity at 25 C

-

0.968

Solubility in water at 25oC

g/l

insoluble

Solubility in solvents

miscible with aliphatic & aromatic solvents

Volatility

wt%

o

0.5 24 h @ 150C

HEALTH & SAFETY DOT class

-

not regulated

ADR/RIC class

-

not regulated

TDG class

-

not regulated

Flash point

o

Flash point method

-

Eye irritation (human)

may cause slight irritation

C

461 PMCC

USE & PERFORMANCE Manufacturer

Emerald Performance Materials

Additive type

mold release & antiblocking agent

Recommended for polymers

plastics, rubber

Recommended for products

rubber & plastics parts, paper, textile, fiber & thread

Outstanding properties

high thermal & oxidation stability, chemically inert/non-reactive with variety of materials, non-corrosive & non-toxic

Databook of Antiblocking, Release, and Slip Additives

126

Masil SF 100 PARAMETER

UNIT

Features and benefits

low viscosity/temperature coefficient ratios, stability to mechanical shear stress

Processing methods

calendering, extrusion

Databook of Antiblocking, Release, and Slip Additives

VALUE

127

Masil SF 1000 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Masil SF 1000

CAS #

-

Common name

Polydimethylsiloxane

Acronym

-

63148-62-9 PDMS

Formula

CH3 H3C Si CH3

Chemical class

CH3

CH3 O Si

O Si CH3

CH3 n CH3

-

silicone polymer

PHYSICAL PROPERTIES State

-

liquid

Odor

-

odorless

Color

-

colorless

Boiling point

o

C

>65

Pour point

o

C

-50

Refractive index at 25 C o

-

1.4035

Specific gravity at 25 C

-

0.974

Solubility in water at 25oC

g/l

insoluble

Solubility in solvents

miscible with aliphatic & aromatic solvents

Volatility

wt%

0.5 24 h @ 150oC

Health

1

Flammability

1

Reactivity

0

Health

1

Flammability

1

Reactivity

0

o

HEALTH & SAFETY NFPA classification

HMIS classification

DOT class

-

not regulated

ADR/RIC class

-

not regulated

TDG class

-

not regulated

Flash point

o

Flash point method

-

Eye irritation (human)

may cause slight irritation

C

Databook of Antiblocking, Release, and Slip Additives

>120 PMCC

128

Masil SF 1000 PARAMETER

UNIT

VALUE

USE & PERFORMANCE Manufacturer

Emerald Performance Materials

Additive type

mold release & antiblocking agent

Recommended for polymers

plastics, rubber

Recommended for products

rubber & plastics parts, paper, textile, fiber & thread

Outstanding properties

high thermal & oxidation stability, chemically inert/non-reactive with variety of materials, non-corrosive & non-toxic

Features and benefits

low viscosity/temperature coefficient ratios, stability to mechanical shear stress

Processing methods

molding, calendering, extrusion

Databook of Antiblocking, Release, and Slip Additives

129

Masil SF 10000 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Masil SF 10000

CAS #

-

Common name

Polydimethylsiloxane

Acronym

-

63148-62-9 PDMS

Formula

CH3 H3C Si CH3

CH3

CH3 O Si

O Si CH3

CH3 n CH3

Molecular weight

daltons

Chemical class

-

silicone polymer

State

-

liquid

Odor

-

odorless

Color

-

colorless

Pour point

o

PHYSICAL PROPERTIES

Refractive index at 25 C o

C

-

-47 1.4035

Specific gravity at 25 C

-

0.975

Solubility in water at 25oC

g/l

insoluble

Solubility in solvents

miscible with aliphatic & aromatic solvents

Volatility

wt%

o

2.0 24 h @ 150oC

HEALTH & SAFETY DOT class

-

not regulated

ADR/RIC class

-

not regulated

TDG class

-

not regulated

Flash point

o

Flash point method

-

Eye irritation (human)

may cause slight irritation

C

500 PMCC

USE & PERFORMANCE Manufacturer

Emerald Performance Materials

Additive type

mold release & antiblocking agent

Recommended for polymers

plastics, rubber

Recommended for products

rubber & plastics parts, paper, textile, fiber & thread

Outstanding properties

high thermal & oxidation stability, chemically inert/non-reactive with variety of materials, non-corrosive & non-toxic

Databook of Antiblocking, Release, and Slip Additives

130

Masil SF 10000 PARAMETER

UNIT

Features and benefits

low viscosity/temperature coefficient ratios, stability to mechanical shear stress

Processing methods

molding, calendering, extrusion

Databook of Antiblocking, Release, and Slip Additives

VALUE

131

Masil SF 1000000 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Masil SF 1000000

CAS #

-

Common name

Polydimethylsiloxane

Acronym

-

63148-62-9 PDMS

Formula

CH3 H3C Si CH3

Chemical class

CH3

CH3 O Si

O Si CH3

CH3 n CH3

-

silicone polymer

PHYSICAL PROPERTIES State

-

liquid

Odor

-

odorless

Color

-

colorless

Pour point

o

Refractive index at 25oC

-

1.4035

Specific gravity at 25oC

-

0.979 insoluble

C

-25

Solubility in water at 25 C

g/l

Solubility in solvents

miscible with aliphatic & aromatic solvents

Volatility

wt%

2.0 24 h @ 150C

DOT class

-

not regulated

ADR/RIC class

-

not regulated

TDG class

-

not regulated

Flash point

o

Flash point method

-

Eye irritation (human)

may cause slight irritation

o

HEALTH & SAFETY

C

500 PMCC

USE & PERFORMANCE Manufacturer

Emerald Performance Materials

Additive type

mold release & antiblocking agent

Recommended for polymers

plastics, rubber

Recommended for products

rubber & plastics parts, paper, textile, fiber & thread

Outstanding properties

high thermal & oxidation stability, chemically inert/non-reactive with variety of materials, non-corrosive & non-toxic

Databook of Antiblocking, Release, and Slip Additives

132

Masil SF 1000000 PARAMETER

UNIT

Features and benefits

low viscosity/temperature coefficient ratios, stability to mechanical shear stress

Processing methods

molding, calendering, extrusion

Databook of Antiblocking, Release, and Slip Additives

VALUE

133

Michem Emulsion 1270 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Michem Emulsion 1270

Common name

Carnauba wax emulsion

Mixture

-

Product contents

24.5-25.5%

yes

PHYSICAL PROPERTIES State

-

liquid

Color

-

tan

-

8-11

mPas

40

pH Viscosity at 25 C o

HEALTH & SAFETY Food approval(s)

Approved for food contact

USE & PERFORMANCE Manufacturer

-

Additive type

antiblocking and slip agent

Recommended for products

coatings

Recommended dosage

wt%

Databook of Antiblocking, Release, and Slip Additives

Michelman

2-4

134

Michem Emulsion 29730 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Michem Emulsion 29730

Common name

Polyethylene wax aqueous emulsion

Chemical class

wax aqueous emulsion

Mixture

-

Product contents

24.5-25.5%

Solids content

wt%

yes 30

PHYSICAL PROPERTIES State

liquid, aq-based anionic emulsion

Odor

-

slight

Color

-

off-white

Melting point

o

C

101.0 wax

Particle size

m

0.045

Specific gravity at 20oC

-

0.97-0.99

pH

-

9

Manufacturer

-

Michelman

Additive type

-

antiblocking agent

Recommended for products

packaging paper, skin & medical packaging

Processing methods

laminating adhesives for paper, foil & film, heat-seal adhesives

Recommended dosage

wt%

USE & PERFORMANCE

Databook of Antiblocking, Release, and Slip Additives

2-4

135

Michem Emulsion 59740 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Michem Emulsion 59740

Common name

Polypropylene wax aqueous emulsion

Chemical class

wax aqueous emulsion

Mixture

-

Product contents

24.5-25.5%

Solids content

wt%

yes 40

PHYSICAL PROPERTIES State

liquid, aq-based anionic emulsion

Odor

-

slight

Color

-

tan

Melting point

o

C

142.0-148.0 wax

Particle size

m

0.024

Specific gravity at 20oC

-

1.00-1.02

pH

-

10

Manufacturer

-

Michelman

Additive type

-

antiblocking agent

USE & PERFORMANCE

Recommended for polymers

fiberglass, filaments

Outstanding properties

prevents fiberglass and other filaments from contacting machinery and one another

Processing methods

laminating adhesives for paper, foil & film, heat-seal adhesives

Recommended dosage

wt%

Databook of Antiblocking, Release, and Slip Additives

2-4

136

Michem Emulsion 98040M1 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Michem Emulsion 98040M1

Common name

Fischer-Tropsch wax aqueous emulsion

Chemical class

wax aqueous emulsion

Mixture

-

Product contents

24.5-25.5%

Solids content

wt%

yes 40

PHYSICAL PROPERTIES State

liquid, aq-based nonionic emulsion

Odor

-

slight

Color

-

off-white

Melting point

o

C

98.0 wax

Particle size

m

0.7

Specific gravity at 20oC

-

0.98-1.00

pH

-

3.0-10.0

Manufacturer

-

Michelman

Additive type

-

antiblocking agent

Recommended for products

paints, coatings, varnishes

Outstanding properties

improves scratch & mar resistance

USE & PERFORMANCE

Databook of Antiblocking, Release, and Slip Additives

137

Michem Lube 162 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Michem Lube 162

Common name

Carnauba wax aqueous emulsion

Chemical class

wax aqueous emulsion

Mixture

-

Product contents

24.5-25.5%

Solids content

wt%

yes 25

PHYSICAL PROPERTIES State

liquid, aq-based nonionic emulsion

Odor

-

slight

Color

-

off-white

Melting point

o

C

85.0-93.0 wax

Particle size

m

0.13

Specific gravity at 20oC

-

0.99-1.01

pH

-

6

Manufacturer

-

Michelman

Additive type

-

antiblocking agent

Recommended for products

inks, varnishes, paints

Outstanding properties

recommended as antislip additives

Processing methods

printing, coating

USE & PERFORMANCE

Databook of Antiblocking, Release, and Slip Additives

138

Michem Lube 368 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Michem Lube 368

Common name

Anionic paraffin/polyethylene wax aqueous emulsion

Chemical class

wax aqueous emulsion

Mixture

-

Product contents

24.5-25.5%

Solids content

wt%

yes 35

PHYSICAL PROPERTIES State

liquid, aq-based anionic emulsion

Odor

-

slight

Color

-

off-white

Melting point

o

Particle size

m

0.18

-

0.95-0.99

Manufacturer

-

Michelman

Additive type

-

antiblocking agent

Recommended for products

inks, varnishes, paints

Outstanding properties

recommended as strong antiblocking additive, average lubricity & mar resistance

Processing methods

printing, coating

Specific gravity at 20 C o

C

60.0-101.0 wax

USE & PERFORMANCE

Databook of Antiblocking, Release, and Slip Additives

139

Tego Glide 482 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Tego Glide 482

Common name

Polyether siloxane copolymer

Chemical class

-

siloxane copolymer

Product contents

wt%

65

PHYSICAL PROPERTIES State

-

liquid

Color

-

hazy

Viscosity at 25oC

mPas

100

HEALTH & SAFETY Skin irritation

no harmful effect

Eye irritation (human)

no harmful effect

Carcinogenicity

not listed by NTP, IARC, or OSHA

USE & PERFORMANCE Manufacturer

Evonic Industries AG

Additive type

antiblocking & slip agent

Recommended for products

waterborne systems

Recommended dosage

wt%

Databook of Antiblocking, Release, and Slip Additives

0.1-1.0

140

Zonyl MP 1100 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Zonyl MP 1100

CAS #

-

Common name

Tetrafluoroethylene homopolymer

Common synonym

Polytetrafluoroethylene

Acronym

-

9002-84-0

PTFE

Formula

F(CF2)nF

Chemical class

-

fluoropolymer

Solids content

wt%

99.0-100.0

PHYSICAL PROPERTIES State

-

solid, powder

Odor

-

odorless

Color

-

white

Melting point

o

C

325 average

Particle size

m

1.8-4.0 avg

Surface area (BET)

m /g

5.0-10.0

Specific gravity at 20oC

-

2.2

Bulk density

kg/m3

300 average

Dielectric constant at 1 MHz

-

2.1

Solubility in water at 25oC

g/l

insoluble

Coefficient of friction

0.1 dynamic (max 3m/min); 0.05 static (3.4 MPa)

2

HEALTH & SAFETY NFPA classification

HMIS classification

Health

2

Flammability

1

Reactivity

0

Health

2

Flammability

1

Reactivity

0

HMIS personal protection

goggles, apron, gloves

Hazardous components

heating above 400C can evolve degradation to: hydrogen fluoride (HF); carbonyl fluoride (CF2)

DOT class

-

not regulated

TDG class

-

not regulated

Databook of Antiblocking, Release, and Slip Additives

141

Zonyl MP 1100 PARAMETER

UNIT

Proper shipping name

plastic, synthetic, O.T.L., NOIBN by rail; plastics, materials, granules by truck

Autoignition temperature

o

TLV – TWA 8h, ACGIH

mg/m

10.0 total, 5.0 respiratory dust PTFE-Dupont Acceptable Limit

TLV – TWA 8h, OSHA

mg/m3

15.0 total, 5.0 respiratory dust PTFE

TLV – TWA 8h, ACGIH

ppm

0.5 HF; 2.0 CF2O

TLV – TWA 8h, OSHA

ppm

2.0 HF

Skin irritation

may cause irritation

Eye irritation (human)

may cause irritation

Carcinogenicity

no carcinogenic ingredients present at over 0.1%

C

VALUE

520-560 3

USE & PERFORMANCE Manufacturer

-

DuPont

Additive type

-

antiblocking agent

Recommended for polymers

printing inks, thermoplastics & thermosetting resins, rubber

Recommended for products

printing; protective coatings, bakeware, coated rollers

Outstanding properties

improves abrasion, scratch, scuff resistance; increases slip, surface smoothness & gloss

Features and benefits

improves chemical & stain resistance

Processing methods

variety of coating systems, offset, gravure, & flexographic printing inks

Additive application method

process aid additive

Recommended dosage

1.00 - 3.00% weight inks; elastomers 5.00 - 20.00% weight; can be used at temperature 190 to 250C

Databook of Antiblocking, Release, and Slip Additives

142

Zonyl MP 1200 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Zonyl MP 1200

CAS #

-

Common name

Tetrafluoroethylene homopolymer

Common synonym

Polytetrafluoroethylene

Acronym

-

9002-84-0

PTFE

Formula

F(CF2)nF

Chemical class

-

fluoropolymer

Solids content

wt%

99.0-100.0

PHYSICAL PROPERTIES State

solid, non-agglomerated powder

Odor

-

odorless

Color

-

white

Melting point

o

C

325 average

Particle size

m

2.5-4.5 avg

Surface area (BET)

m /g

1.5-3.0

Specific gravity at 20oC

-

2.2

Bulk density

kg/m3

450 average

Dielectric constant at 1 MHz

-

2.1

Solubility in water at 25oC

g/l

insoluble

Coefficient of friction

0.1 dynamic (max 3m/min); 0.05 static (3.4 MPa)

2

HEALTH & SAFETY NFPA classification

HMIS classification

Health

2

Flammability

1

Reactivity

0

Health

2

Flammability

1

Reactivity

0

HMIS personal protection

goggles, apron, gloves

Hazardous components

heating above 400oC can evolve degradation to: hydrogen fluoride (HF); carbonyl fluoride (CF2)

DOT class

-

not regulated

TDG class

-

not regulated

Databook of Antiblocking, Release, and Slip Additives

143

Zonyl MP 1200 PARAMETER

UNIT

Proper shipping name

plastic, synthetic, O.T.L., NOIBN by rail; plastics, materials, granules by truck

Autoignition temperature

o

TLV – TWA 8h, ACGIH

mg/m

TLV – TWA 8h, NIOSH

mg/m3

TLV – TWA 8h, OSHA

mg/m3

15.0 total, 5.0 respiratory dust PTFE

TLV – TWA 8h, ACGIH

ppm

0.5 HF; 2.0 CF2O

TLV – TWA 8h, OSHA

ppm

2.0 HF

Skin irritation

may cause irritation

Eye irritation (human)

may cause irritation

Carcinogenicity

no carcinogenic ingredients present at over 0.1%

C

VALUE

520-560 3

10.0 total, 5.0 respiratory dust PTFE-Dupont Acceptable Limit

USE & PERFORMANCE Manufacturer

-

DuPont

Additive type

-

antiblocking agent

Recommended for polymers

printing inks, thermoplastics & thermosetting resins, rubber

Recommended for products

printing; protective coatings, bakeware, coated rollers

Outstanding properties

improves abrasion, scratch, scuff resistance; increases slip, surface smoothness & gloss

Features and benefits

improves chemical & stain resistance

Processing methods

variety of coating systems, offset, gravure, & flexographic printing inks

Additive application method

process aid additive

Recommended dosage

1.00 - 3.00% weight inks; elastomers 5.00 - 20.00% weight; can be used at temperature 190 to 250oC

Databook of Antiblocking, Release, and Slip Additives

144

Zonyl MP 1500 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Zonyl MP 1500

CAS #

-

Common name

Tetrafluoroethylene homopolymer

Common synonym

Polytetrafluoroethylene

Acronym

-

Formula

9002-84-0

PTFE

F(CF2)nF

Chemical class

-

fluoropolymer

Solids content

wt%

99.0-100.0

PHYSICAL PROPERTIES State

-

solid, powder

Odor

-

odorless

Color

-

white

Melting point

o

Particle size

m

C

325 average 20.0 avg agglomerate size

m2/g

8.0-12.0

Specific gravity at 20 C

-

2.2

Bulk density

kg/m3

375 average

Dielectric constant at 1 MHz

-

2.1

Solubility in water at 25oC

g/l

insoluble

Coefficient of friction

0.1 dynamic (max 3m/min); 0.05 static (3.4 MPa)

Surface area (BET) o

HEALTH & SAFETY NFPA classification

HMIS classification

Health

2

Flammability

1

Reactivity

0

Health

2

Flammability

1

Reactivity

0

HMIS personal protection

goggles, apron, gloves

Hazardous components

heating above 400oC can evolve degradation to: hydrogen fluoride (HF); carbonyl fluoride (CF2)

Databook of Antiblocking, Release, and Slip Additives

145

Zonyl MP 1500 PARAMETER

UNIT

Food approval(s)

FDA approved 21 CFR 175.105; 175. 300; 176.170; 176.180; 177.1550, 1520 & 2600; 177.1520

DOT class

-

not regulated

TDG class

-

not regulated

Proper shipping name

plastic, synthetic, O.T.L., NOIBN by rail; plastics, materials, granules by truck

Autoignition temperature

o

TLV – TWA 8h, ACGIH

mg/m

10.0 total, 5.0 respiratory dust PTFE-Dupont Acceptable Limit

TLV – TWA 8h, OSHA

mg/m3

15.0 total, 5.0 respiratory dust PTFE

TLV – TWA 8h, ACGIH

ppm

0.5 HF; 2.0 CF2O

TLV – TWA 8h, OSHA

ppm

2.0 HF

Skin irritation

may cause irritation

Eye irritation (human)

may cause irritation

Carcinogenicity

no carcinogenic ingredients present at over 0.1%

C

VALUE

520-560 3

USE & PERFORMANCE Manufacturer

-

DuPont

Additive type

-

antiblocking agent

Recommended for polymers

fluoroelastomers, EPDM elastomers, Neoprene elastomers, SBR elastomers

Recommended for products

various articles

Outstanding properties

improves wear resistance, nonstick properties, lubricity & frictional characteristics

Processing methods

variety of coating systems

Additive application method

process aid additive

Recommended dosage

50/50 masterbatch with elastomer; 10 phr or more

Databook of Antiblocking, Release, and Slip Additives

146