Preface to the Festschrift in Honor of Professor Kingo Itaya

Preface to the Festschrift in Honor of Professor Kingo Itaya

Journal of Electroanalytical Chemistry 716 (2014) 1–7 Contents lists available at ScienceDirect Journal of Electroanalytical Chemistry journal homep...

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Journal of Electroanalytical Chemistry 716 (2014) 1–7

Contents lists available at ScienceDirect

Journal of Electroanalytical Chemistry journal homepage: www.elsevier.com/locate/jelechem

Preface

Preface to the Festschrift in Honor of Professor Kingo Itaya

It is with immense pleasure that we dedicate this issue of the Journal of Electroanalytical Chemistry to Professor Kingo Itaya in honor and in celebration of his 65th birthday. As a dauntless pioneer, tenacious innovator and prolific contributor in several sub-fields of electrochemistry, applied physics and engineering, Professor Itaya has achieved global renown. The influences that he has imparted to his students, postdoctoral research associates, collaborators and peers are evident in the collection of articles archived in this issue. Kingo Itaya was born in Hokkaido, a city in northern Japan, on April 5, 1948. He received his M.S. (1974) and Ph.D. (1977) degrees in Engineering from Tohoku University under the supervision of Professor Shinobu Toshima. After his graduation, he spent two years as a postdoctoral research fellow in the laboratory of Professor Allen J. Bard, a preeminent electrochemist at the University of Texas at Austin; at that time, Kingo focused primarily on the electrochemical and photo-electrochemical studies of modified surfaces and electrodes in liquid ammonia. He then returned to Tohoku University to embark on his own academic career at the Institute of Electric Communication. In 1982, Kingo moved to the department of Chemical Engineering as an assistant professor. Two years later, he was promoted to associate professor; full professorship was conferred in 1991. The tireless pursuit of Kingo for a comprehensive representation of the electrode–electrolyte interface in a wide range of electron-transfer processes is best showcased by the evolutionary advances in his laboratories over the past quarter-century. He initiated his work with electron spectroscopy that, although extremely surface sensitive, required ultrahigh-vacuum environments. His seminal contribution to the area of electrochemical surface science was the implementation of scanning tunneling microscopy (STM) under electrochemical (EC) conditions. He elevated EC-STM as the premier operando technique to monitor, http://dx.doi.org/10.1016/j.jelechem.2014.01.024 1572-6657/Ó 2014 Published by Elsevier B.V.

at the atomic scale, a wide variety of surface phenomena. But non-optical scanned-probe techniques are not without handicaps, the most critical of which is the fact that the probes may interfere with the interfacial processes. Such hindrances led Kingo to his most recent innovation, an optical microscope that combines a laser confocal microscope with a differential interference contrast microscope (LCM-DIM). A successful application has been in the study of the atom-resolved layer-by-layer electrochemical dissolution of well-defined metal electrodes; the converse process, electrodeposition, has likewise been investigated at the atomic scale. Fundamentally, the research of Kingo Itaya, as documented in over 270 papers, has helped establish interfacial structure–composition–function correlations, identify the critical parameters that enable nanometer-level interrogation of surface-immobilized species, and draw up detailed procedures in the preparation of novel materials. Technologically, his work finds relevance in commercial fields as diverse as fuel cells, sensors, green chemistry, consumer electronics and nanodevices. From his laboratories, a new generation of talented and able researchers, all 250-odd of them, has been spawned globally. The numerous national and international accolades that Kingo has garnered, such as the Japanese Emperor Award, the Chemical Society of Japan Award, and the Tacussel Prize of the International Society of Electrochemistry, attest to the esteem that his peers, worldwide, has bestowed on him. It is a tremendous distinction for us to be regarded by Professor Kingo Itaya amidst his friends and collaborators; even, occasionally, among his amicable competitors. In return, with unrestrained delight, we dedicate this singular issue of the Journal of Electroanalytical Chemistry to him on the occasion of his 65th birthday. List of Publications Kingo Itaya

‘‘Direct Evidence of Homoepitaxial Growth in the Electrodeposition of Au Observed by Ultra-High Resolution Differential Optical Microscopy’’ M. Azhagurajan, R. Wen, A. Lahiri, Y. G. Kim, T. Itoh, and K. Itaya. J. Electrochem. Soc. 169 (2013) D361–D365. ‘‘Potential-induced phase transition of low-index Au single crystal surfaces in propylene carbonate solution’’ S. Yoshimoto, Y. G. Kim, K. Sato, J. Inukai, and K. Itaya. Phys. Chem. Chem. Phys. 14(7) (2012) 2286–2291. ‘‘Visualization of Single Atomic Steps on An Ultra-Flat Si(1 0 0) Surface by Advanced Differential Interference Contrast Microscopy’’ S. I. Kobayashi, Y. G. Kim, R. Wen, K, Yasuda, H. Fukidome,

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T. Suwa, R. Kuroda, X. Li, A. Teramoto, T. Ohmi, and K. Itaya. Electrochem. Solid State Lett. 14(9) (2011) H351–H353. ‘‘A New in situ Optical Microscope with Single Atomic Layer Resolution for observation of Electrochemical Dissolution of Au(1 1 1)’’ R. Wen, A. Lahiri, M. Azhagurajan, S. Kobayashi, and K. Itaya. J. Am. Chem. Soc. 132 (2010) 13657–13659. ‘‘Preparation and characterization of ultra-flat single crystal surfaces of Pd(1 1 1) and Au(1 1 1) by an in situ interference optical microscopy’’ R. Wen, A. Lahiri, M. Alagurajan, A. Kuzume, S. Kobayashi, and K. Itaya. J. Electroanal. Chem. 649 (2010) 257– 260. ‘‘Substrate-Induced Varied Conformation and Molecular Assemblies: In Situ STM Observation of beta-Substituted Oligothiophene Adlayers on Au(1 1 1)’’ L. Wang, B. J. V. Tongol, S. L. Yau, T. Otsubo, and K. Itaya. Langmuir 26(10) (2010) 7148–7152. ‘‘Direct Observation of Conformational Changes of beta-Substituted Duodecithiophene on a Au(1 1 1)-(root 3 x22) Substrate Using in Situ Electrochemical STM in 0.1 M HClO4’’ B. J. V. Tongol, L. Wang, S. L. Yau, T. Otsubo, and K. Itaya. Langmuir 26(2) (2010) 982–989. ‘‘Conformations of polyaniline molecules adsorbed on Au(1 1 1) probed by in situ STM and ex situ XPS and NEXAFS’’ Y. H. Lee, C. Z. Chang, S. L. Yau, L. J. Fan, Y. W. Yang, L. Y. O. Yang, and K. Itaya. J. Am. Chem. Soc. 131 (2009) 6468–6474. ‘‘Organic field effect transistor using pentacene single crystals grown by liquid-phase crystallization process’’ Y. Kimura, M. Niwano, N. Ikuma, K. Goushi, and K. Itaya. Langmuir 25 (2009) 4861–4863. ‘‘Recent progress in electrochemical surface science with atomic and molecular levels’’ S. Ye, T. Kondo, N. Hoshi, J. Inukai, S. Yoshimoto, M. Osawa, and K. Itaya. Electrochemistry 4 (2009) 2–20. ‘‘In situ scanning tunneling microscopy imaging of mercury film electrodeposited on Ir(1 1 1)’’ H. L. Wu, S. L. Yau, W. Vogel, M. C. Zei, L. Y. O. Yang, and K. Itaya. Electrochem, Commun. 11 (2009) 454–456. ‘‘Bimolecular two-dimensional organization of porphyrins on Au(1 1 1): Site selective, metal Ion-dependent adsorption of tetraphenylporphyrin’’ K. Suto, S. Yoshimoto, and K. Itaya. J. Nanosci. Nanotechnol. 9 (2009) 288–294. ‘‘High-resolution molecular images of rubrene single crystals obtained by frequency modulation atomic force microscopy’’ T. Minato, H. Aoki, H. Fukidome, T. Wagner, and K. Itaya. J. Appl. Phys. 95 (2009) 093302. ‘‘Nanostructures and molecular assembly of b-blocked long oligothiophenes up to the 96-mer on Au(1 1 1) as probed by in situ electrochemical scanning tunneling microscopy’’ B. J. V. Tongol, L. Wang, S. L. Yau, T. Otsubo, and K. Itaya. J. Phys. Chem. C 113 (2009) 13819–13824. ‘‘Supramolecular pattern of fullerene on 2D bimolecular ‘Chessboard’ consisting of bottom-up assembly of porphyrin and phthalocyanine molecules’’ S. Yoshimoto, Y. Honda, O. Ito, and K. Itaya. J. Am. Chem. Soc. 130 (2008) 1085–1092. ‘‘Non-Contact Atomic Force Microscopy of Perfect Single Crystals of Pentacene Prepared by Crystallization from Solution’’ K. Sato, T. Sawaguchi, M. Sakata, and K. Itaya. Langmuir 23 (2007) 12788–12790. ‘‘Advances in Supramolecularly Assembled Nanostructures of Fullerenes and Porphyrins at Surfaces’’ S. Yoshimoto, and K. Itaya. J. Porphyrins Phthalocyanines 11 (2007) 313–333. ‘‘Epitaxial Supramolecular Assembly of Fullerenes Formed by Using a Coronene Template on a Au(1 1 1) Surface in Solution’’ S. Yoshimoto, E. Tsutsumi, R. Narita, K. Fujiwara, M. Murata, Y. Murata, K. Komatsu, O. Ito, and K. Itaya. J. Am. Chem. Soc. 129 (2007) 4366–4376.

‘‘Picket-Fence Porphyrin on Au Surfaces’’ S. Yoshimoto, K. Sato, S. Sugawara, Y. Chen, O. Ito, T. Sawaguchi, O. Niwa, and K. Itaya. Langmuir 23 (2007) 809–816. ‘‘Pioneer works in development of in situ scanning tunneling microscopy for electrochemical surface science’’ K. Itaya. Electrochemistry 74(1) (2006) 19–27. ‘‘In situ STM Study of Underpotential Deposition of Bismuth on Au(1 1 0) in Perchloric Acid Solution’’ M. Hara, Y. Nagahara, J. Inukai, S. Yoshimoto, and K. Itaya. Electrochim. Acta 51(11) (2006) 2327–2332. ‘‘Formation of highly ordered porphyrin adlayers induced by electrochemical potential modulation’’ S. Yoshimoto, N. Yokoo, T. Fukuda, N. Kobayashi, and K. Itaya. Chem. Commun. (5) (2006) 500–502. ‘‘Effect of Underlying Ni(II) Porphyrin Adlayer on the Formation of Supramolecular Assembly of Fullerenes on Au(1 1 1) in Solution’’ S. Yoshimoto, S. Sugawara, and K. Itaya. Electrochemistry 74(2) (2006) 75–178. ‘‘Adsorbed Structures of 4,40 -Bipyridine on Cu(1 1 1) in Acid Studied by STM and IR’’ Y. X. Diao, M. J. Han, L. J. Wan, K. Itaya, T. Uchida, H. Miyake, A. Yamakata, and M. Osawa. Langmuir 22(8) (2006) 3640–3646. ‘‘Effect of sulfuric acid concentration on the structure of sulfate adlayer on Au(1 1 1) electrode’’ K.Sato, S. Yoshimoto, J. Inukai, and K. Itaya. Electrochem. Commun. 8(5) (2006) 725–730. ‘‘Electrochemical Control of the Structure of two-dimensional Supramolecular Organization Consisting of Phthalocyanine and Porphyrin on a Gold Single-Crystal Surface’’ K. Suto, S. Yoshimoto, and K. Itaya. Langmuir 22(25) (2006) 10766–10776. ‘‘Effect of underlying coronene & perylene adlayers for [60]fullerene molecular assembly’’ S. Yoshimoto, E. Tsutsumi, O. Fujii, R. Narita, and K. Itaya. Chem. Commun. (2005) 1188–1190. ‘‘In-Situ Scanning Tunneling Microscopy of Carbon Monoxide Adsorbed on Au(1 1 1) Electrode’’ C. H. Shue, L. Y. O. Yang, S. L. Yau, and K. Itaya. Langmuir 21(5) (2005) 1942–1948. ‘‘Adlayer of Hydroquinone on Rh(1 1 1) in Solution and in Vacuum Studied by STM and LEED’’ J. Inukai, M. Wakisaka, M.Yamagishi, and K. Itaya. J. Electrochem. Soc. 152(2) (2005) E35–E39. ‘‘Dependence of Molecular Recognition of Fullerene Derivative on the Adlayer Structure of Zinc Octaethylporphyrin Formed on Au(1 0 0) Surface’’ S. Yoshimoto, Y. Honda, Y. Murata, M. Murata, K. Komatsu, O. Ito, and K. Itaya. J. Phys. Chem. B 109(18) (2005) 8547–8550. ‘‘Adsorption of Formaldehyde on Pt(1 1 1) and Pt(1 0 0) Electrodes: Cyclic Voltammetry and Scanning Tunneling Microscopy’’ C. F. Mai, C. H. Shue, Y. C. Yang, L. Y. O. Yang, S. L. Yau, and K. Itaya. Langmuir 21(11) (2005) 4964–4970. ‘‘Role of the Anion in the Underpotential Deposition of Cadmium on a Rh(1 1 1) Electrode: Probed by Voltammetry and in situ Scanning Tunneling Microscopy’’ L. Y. O. Yang, F. Bensliman, C. H. Shue, Y. C. Yang, Z. H. Zang, L. Wang, S. L. Yau, S. Yoshimoto, and K. Itaya. J. Phys. Chem. B 109(31) (2005) 14917–14924. ‘‘Molecular assemblies and redox reactions of zinc(II) tetraphenylporphyrin and zinc(II) phthalocyanine on Au(1 1 1) single crystal surface at electrochemical interface’’ S. Yoshimoto, E. Tsutsumi, K. Suto, Y. Honda, and K. Itaya. Chem. Phys. 319(1– 3) (2005) 147–158. ‘‘Two-dimensional Supramolecular Arrangements of Enantiomers and Racemic Modification of 1,10 -Binaphthyl-2,20 -Dicarboxylic Acid’’ M. Kunitake, T. Hattori, S. Miyano, and K. Itaya. Langmuir 21(20) (2005) 9206–9210. ‘‘Adlayer Structure of and Electrochemical Reduction of O2 on Cobalt Porphine-Modified and Cobalt Octaethylporphyrin-

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Modified Au(1 1 1) in HClO4’’ S. Yoshimoto, J. Inukai, A. Tada, T. Abe, T. Morimoto, A. Osuka, H.Furuta, and K. Itaya. J. Phys. Chem. B 108(6) (2004) 1948–1954. ‘‘Adlayers of C60–C60 and C60–C70 Fullerene Dimers Formed on Au(1 1 1) in Benzene Solutions Studied by STM and LEED’’ M. Matsumoto, J. Inukai, E. Tsutsumi, S. Yoshimoto, K. Itaya, O. Ito, K.Fujiwara, M. Murata, Y. Murata, and K. Komatsu. Langmuir 20(4) (2004) 1245–1250. ‘‘Underpotentially Deposited Layers of Bi on Au(1 0 0) in HClO4 Investigated by In Situ STM’’ M. Hara, Y. Nagahara, S. Yoshimoto, J. Inukai, and K. Itaya. J. Electrochem. Soc. 151(3) (2004) E92– E96. ‘‘In Situ Scanning Tunneling Microscopy Examination of Molecular Adlayers of Haloplatinate Complexes and Electrochemically Produced Platinum Nanoparticles on Au(1 1 1)’’ Y. Nagahara, M. Hara, S. Yoshimoto, J. Inukai, S. L. Yau, and K. Itaya. J. Phys. Chem. B 108(10) (2004) 3224–3230. ‘‘In Situ Scanning Tunneling Microscopy of Molecular Assemblies of Cobalt(II) and Copper(II) Coordinated Tetraphenyl Porphine and Phthalocyanine on Au(1 0 0)’’ S. Yoshimoto, A. Tada, K. Suto, S. L. Yau, and K. Itaya. Langmuir 20(8) (2004) 3159– 3164. ‘‘In Situ Scanning Tunneling Microscopy Study of the Effect of Iron Octaethylporphyrin Adlayer on the Electrocatalytic Reduction of O2 on Au(1 1 1)’’ S. Yoshimoto, A. Tada, and K. Itaya. J. Phys. Chem. B 108(17) (2004) 5171–5174. ‘‘Scanning Tunneling Microscopy of Sulfur and Benzenethiol Chemisorbed on Ru(0 0 0 1) in 0.1 M HClO4’’ L. Y. O. Yang, S. L. Yau, and K. Itaya. Langmuir 20(11) (2004) 4596–4603. ‘‘Controlled Molecular Orientation in an Adlayer on Au(1 1 1) of a Supramolecular Assembly Consisting of an Open-Cage C60 Derivative and Zn(II) Octaethylporphyrin’’ S. Yoshimoto, E. Tsutsumi, Y. Honda, Y. Murata, M. Murata, K. Komatsu, O. Ito, and K. Itaya. Angew. Chem., Int. Ed. 43(23) (2004) 3044–3047. ‘‘Adsorption of Sulfur and Growth of Copper Sulfide on Cu(1 0 0) and Cu(1 1 0) in Alkaline Solution’’ J. Inukai, M. Sugimasa, S. L. Yau, and K. Itaya. Electrochemistry 72(6) (2004) 458–461. ‘‘Effect of Adlayer Structure on the Host–Guest Recognition between Calcium and Crown-ether-Substituted Phthalocyanine Arrays on Au Single Crystal Surfaces’’ S. Yoshimoto, K. Suto, A. Tada, N. Kobayashi, and K. Itaya. J. Am. Chem. Soc. 126(25) (2004) 8020–8027. ‘‘Supramolecular Assembly of [60] Fullerene and Highly Ordered Zinc Octaethylporphyrin Adlayer Formed on Au(1 1 1) Surface’’ S. Yoshimoto, E. Tsutsumi, Y. Honda, O. Ito, K. Itaya. Chem. Lett. 33(7) (2004) 914–915. ‘‘Two-dimensional Supramolecular Organization Consisting of Copper Octaethylporphyrin and Cobalt Phthalocyanine on Au(1 1 1): Molecular Assembly Control at an Electrochemical Interface’’ S. Yoshimoto, N. Higa, and K. Itaya. J. Am. Chem. Soc. 126(27) (2004) 8540–8545. ‘‘p-Xylene Adlayers Formed on Rh(1 1 1) and Pt(1 1 1) Surfaces in Vacuum’’ J. Inukai, M. Wakisaka, and K. Itaya. Jpn. J. Appl. Phys. 43(7B) (2004) 4549–4553. ‘‘Adlayer of Naphthalene on Rh(1 1 1) Studied by Scanning Tunneling Microscopy’’ J. Inukai, M. Wakisaka, and K. Itaya. Jpn. J. Appl. Phys. 43(7B) (2004) 4554–4556. ‘‘Adlayer of Hydroquinone on Pt(1 1 1) in Solution and in a Vacuum Studied by STM and LEED’’ J. Inukai, M. Wakisaka, M. Yamagishi, and K. Itaya. Langmuir 20(18) (2004) 7507–7511. ‘‘A Highly Selective and Simple Synthesis of C2n-X-C2m Fullerene Dimers’’ Y. Zhao, Z. Chen, H. Yuan, X. Gao, L. Qu, Z. Chai, G. Xing, S. Yoshimoto, E. Tsutsumi, and K. Itaya. J. Am. Chem. Soc. 126(36) (2004) 11134–11135. ‘‘Electroreduction of Peroxide on Au(1 0 0) surface Modified with Underpotentially-deposited Bismuth’’ M. Hara, Y. Nagaha-

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ra, S. Yoshimoto, J. Inukai, and K. Itaya. Jpn. J. Appl. Phys. 43(10) (2004) 7232–7233. ‘‘Elucidation of the Deposition Processes and Spatial Structures of Alkanethiol and Arylthiol Molecules Adsorbed on Pt(1 1 1) Electrodes with in Situ Scanning Tunneling Microscopy’’ Y. C. Yang, Y. P. Yen, L. Y. O. Yang, S. L. Yau, and K. Itaya. Langmuir 20(23) (2004)10030–10037. ‘‘In Situ Scanning Tunneling Microscopy of Au(1 1 1) in Acidic and Alkaline Potassium Cyanide’’ C. H. Shue, S. L. Yau, and K. Itaya. J. Phys. Chem. B 108(45) (2004) 17433–17440. ‘‘Electrochemical and In situ Scanning Tunneling Microscopy Studies of Submonolayer Deposition of Antimony on Au(1 0 0) in Perchloric Acid Solution’’ M. Hara, J. Inukai, S. Yoshimoto, and K. Itaya. J. Phys. Chem. B 108(45) (2004) 17441–17447. ‘‘An STM study on growth process of vapor-deposited hydroquinone adlayers on Rh(1 1 1) and Pt(1 1 1)’’ J. Inukai, M. Wakisaka, and K. Itaya. Chem. Phys. Lett. 399(4–6) (2004) 373–377. ‘‘Electrochemical Redox Control of Ferrocene using a Supramolecular Assembly of Ferrocene-Linked C60 Derivative and Metallooctaethylporphyrin Array on a Au(1 1 1) Electrode’’ S. Yoshimoto, A. Saito, E. Tsutsumi, F. D’Souza, O. Ito, and K. Itaya. Langmuir 20(25) (2004) 11046–11052. ‘‘Structural Change and Electrochemical Behavior of Pt(1 0 0)hex-R0.7 degrees Surfaces in Gases and in Solution’’ M. Wakisaka, M. Sugimasa, J. Inukai, and K. Itaya, J. Electrochem. Soc. 150(2) E81–E88. ‘‘Structure of Sulfur Adlayer on Cu(1 1 1) Electrode in Alkaline Solution’’ M. Sugimasa, J. Inukai, and K. Itaya. J. Electrochem. Soc. 150(2) (2003) E110–E116. ‘‘Adlayer Structure and Electrochemical Reduction of O2 on Self-Organized Arrays of Cobalt and Copper Tetraphenyl Porphines on a Au(1 1 1) Surface’’ S. Yoshimoto, A. Tada, K. Suto, R. Narita, and K. Itaya. Langmuir 19(3) (2003) 672–677. ‘‘Adlayer of 1,10-Phenanthroline on Cu(1 1 1) in Acidic Solution An In Situ STM Study’’ M. Sugimasa, J. Inukai, and K. Itaya. J. Electrochem. Soc. 150(5) (2003) E266–E270. ‘‘Host–guest recognition of calcium by crown-ether substituted phthalocyanine array on Au(1 1 1): relationship between crown moieties and gold lattice’’ S. Yoshimoto, K. Suto, K. Itaya, and N. Kobayashi. Chem. Commun. (2003) 2174–2175. ‘‘Adlayers of methyl-substituted benzene derivatives formed on Rh(1 1 1) in HF solution’’ K. Suto, J. Inukai, and K. Itaya. J. Electroanal. Chem. 550–551(2003) 105–112. ‘‘In situ STM studies of sulfur and thiocyanate adlayers on Cu(1 1 1) in alkaline solution’’ M. Sugimasa, J. Inukai, and K. Itaya. J. Electroanal. Chem. 554–555 (2003) 285–291. ‘‘Adlayer Structures and Electrocatalytic Activity for O2 of Metallophthalocyanines on Au(1 1 1): In Situ Scanning Tunneling Microscopy Study’’ S. Yoshimoto, A. Tada, K. Suto, and K. Itaya. J. Phys. Chem. B. 107(24) (2003) 5836–5843. ‘‘Formation of Well-Defined p-tert-Butylcalix[4]arenedithiolate Monolayers on a Au(1 0 0)-(1  1) Surface Studied by In Situ Scanning Tunneling Microscopy’’ S. Yoshimoto, M. Abe, K. Itaya, F. Narumi, K. Sashikata, K. Nishiyama, and I. Taniguchi. Langmuir 19(20) (2003) 8130–8133. ‘‘Two-Dimensional Self-Organization of Phthalocyanine and Porphyrin: Dependence on the Crystallographic Orientation of Au’’ K. Suto, S. Yoshimoto, and K. Itaya. J. Am. Chem. Soc. 125(49) (2003) 14976–14977. ‘‘Highly Ordered Coronene Adlayer on Au(1 1 1) Surface Formed in Benzene Solution: In situ Scanning Tunneling Microscopy Study’’ S. Yoshimoto, R. Narita, and K. Itaya. Chem. Lett. (2003) 356–357. ‘‘Adlayer Structures of Cl and Br and Growth Bulk AgBr Layers on Ag(1 0 0) Electrodes’’ T. Shimooka, J. Inukai, and K. Itaya. J. Electrochem. Soc. 149(2) (2002) E19–E25.

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‘‘Structure of p-Xylene Adlayer Formed on Rh(1 1 1) Surface in Vacuum Studied by STM and LEED’’ M. Wakisaka, K. Suto, J. Inukai, and K. Itaya. Langmuir 18 (2002) 729–735. ‘‘The structure of a coronene adlayer formed in a benzene solution: studies by in situ STM and ex situ LEED’’ S. Yoshimoto, R. Narita, M. Wakisaka, and K. Itaya. J. Electroanal. Chem. 532 (2002) 331–335. ‘‘Adlayer Structures of Benzotriazole on Cu(1 1 0), (1 0 0), and (1 1 1) in HClO4 Solution: In situ Scanning Tunneling Microscopy’’ M. Sugimasa, L. J. Wan, J. Inukai, and K. Itaya. J. Electrochem. Soc. 149 (2002) E367–E373. ‘‘Adlayers of Fullerene Monomer and [2+2]-Type Dimer on Au(1 1 1) in Aqueous Solution Studied by in Situ Scanning Tunneling Microscopy’’ S. Yoshimoto, R. Narita, E. Tsutsumi, M. Matsumoto, K. Itaya, O. Ito, K.Fujiwara, Y. Murata, and K. Komatsu. Langmuir 18(22) (2002) 8518–8522. ‘‘In situ scanning tunneling microscopy of maleic acid and fumaric acid adsorbed on Pt(1 1 1)’’ J. Zhang, L.-J. Wan, and K. Itaya. J. Electroanal. Chem. 500 (2001) 156–162. ‘‘In Situ Electrochemical Scanning Tunneling Microscopy: Adlayers of Organic Molecules’’ K. Itaya. Electrochemistry 69(5) (2001) 69–76. ‘‘Underpotential and bulk deposition of copper on Pd(1 1 1) in sulfuric acid solution studied by in situ scanning tunneling microscopy’’ J. Okada, J. Inukai, and K. Itaya. Phys. Chem. Chem. Phys. 3 (2001) 3297–3302. ‘‘Highly Ordered Anthracene Adlayers on Ag Single-Crystal Surfaces in Perchloric Acid Solution: In Situ STM Study’’ T. Shimooka, S. Yoshimoto, M. Wakisaka, J. Inukai, and K. Itaya. Langmuir 17(20) (2001) 6380–6385. ‘‘In situ STM study of CN Adlayer on Ir(1 1 1) Electrode in Solution’’ M. Hara, S. Yoshimoto, J. Inukai, and K. Itaya. Electrochemistry 69(12) (2001) 934–936. ‘‘Orderd Adlayers of Organic Molecules on Sulfur-Modified Au(1 1 1): In Situ Scanning Tunneling Microscopy Study’’ L. J. Wan, S. Shundo, J. Inukai, and K. Itaya. Langmuir 16 (2000) 2164–2168. ‘‘In situ scanning tunneling microscopy of adsorbed sulfate on well-defined Pd(1 1 1) in sulfuric acid solution’’ L. J. Wan, T. Suzuki, K. Sashikata, J. Okada, J. Inukai, and K. Itaya. J. Electroanal. Chem. 484 (2000) 189–193. ‘‘Highly Ordered p-Xylene Adlayer Formed on Rh(1 1 1) in HF Solution: In Situ STM and Ex Situ LEED’’ K. Suto, M. Wakisaka, M. Yamagishi, L. J. Wan, J. Inukai, and K. Itaya. Langmuir 16 (2000) 9368–9373. ‘‘Formation of an ordered structure of iodine adsorbed on Ni(1 1 1) and the anodic dissolution processes: in situ STM study’’ P. Muller, S. Ando, T. Yamada, and K. Itaya. J. Electroanal. Chem. 467 (1999) 282–290. ‘‘In Situ Scanning Tunneling Microscopy of Well-Defined Ir(1 1 1) Surface: High-Resolution Imaging of Adsorbed Sulfate’’ L. J. Wan, M. Hara, J. Inukai, and K. Itaya. J. Phys. Chem. B. 103 (1999) 6978–6983. ‘‘In Situ Scanning Tunneling Microscopy of Highly Ordered Adlayers of Aromatic Molecules on Well-Defined Pt(1 1 1) Electrodes in Solution: Benzoic Acid, Terephthalic Acid, and Pyrazine’’ Y. G. Kim, S. L. Yau, and K. Itaya. Langmuir 15 (1999) 7810–7815. ‘‘In situ scanning tunneling microscopy of Cu(1 1 0): atomic structures of halide adlayers and anodic dissolution’’ L. J. Wan, and K. Itaya. J. Electroanal. Chem. 473 (1999) 10–18. ‘‘In situ Electrochemical Scanning Tunneling Microscopy of Zinc-terminated ZnO(0 0 0 1) Single Crystal Electrode in Solution’’ J. Inukai, K. Ito, and K. Itaya. Electrochemistry 67(12) (1999) 1126–1128.

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‘‘An Electrochemical Fabrication Method for Gold and Carbon Ultramicroelectrode’’ T. Abe, K. Itaya, and I. Uchida. Chem. Lett. (1988) 399–402. ‘‘Evaluation of Kinetic Parameters from Steady-State Voltammograms at Ultramicrodisk Electrodes’’ T. Abe, K. Itaya, I. Uchida, K. Aoki, and K. Tokuda. Bull. Chem. Soc. Jpn. 61 (1988) 3417–3420. ‘‘In-Situ Scanning Tunneling Microscopy of Platinum Electrode in Sulfuric Acid’’ K. Itaya, K. Higaki, and S. Sugawara. Chem. Lett. (1988) 421–424. ‘‘In Situ Scanning Tunneling Microscopy for Platinum Surfaces in Aqueous Solutions’’ K. Itaya, S. Sugawara, and K. Higaki. J. Phys. Chem. 92 (1988) 6714–6718. ‘‘Scanning Tunneling Microscope for Electrochemistry – A New Concept for the In situ Scanning Tunneling Microscope in Electrolyte Solutions’’ K. Itaya and E. Tomita. Surf. Sci. 201 (1988) L507-L512. ‘‘Vibrational spectra and normal coordinate calculations for trimethylselenonium-d0 and -d9 ions and dimethyl selenide-d0, d6’’ Y. Imai, K. Aida, and K. Itaya. Spectrochim. Acta 44A (1988) 179–183. ‘‘Anion-Exchanged Hydrotalcite-like-Clay-Modified Electrodes’’ K. Itaya, H.-C. Chang, and I. Uchida. Inorg. Chem. 26 (1987) 624–626. ‘‘Scanning Tunneling Microscopy with Atomic Resolution in Aqueous Solutions’’ K. Itaya, and S. Sugawara. Chem. Lett. (1987) 1927–1930. ‘‘An Electrochemical Fabrication Method for Platinum Ultramicro Disk Electrodes’’ K. Itaya, T. Abe, and I. Uchida. J. Electrochem. Soc. 134 (1987) 1191–1193. ‘‘Electrochemical Growth of Pt Ultra-microparticles in Nafion Films on Glassy Carbon Electrodes’’ K. Itaya, Y. Matsushima, and I. Uchida. Chem. Lett. (1986) 571–572. ‘‘Electrodeposition of Pt Ultramicroparticles in Nafion Films on Glassy Carbon Electrodes’’ K. Itaya, H. Takahashi, and I. Uchida. J. Electroanal. Chem. 208 (1986) 373–382. ‘‘Gas Electrode Reactions in Molten Carbonate Media Part I. Exchange Current Density of Oxygen Reduction in (Li+K) CO3 Eutectic at 650 °C’’ I. Uchida, T. Nishina, Y. Mugikura, and K. Itaya. J. Electroanal. Chem. 206 (1986) 229–239. ‘‘Gas Electrodes Reactions in Molten Carbonate Media Part II. Oxygen Reduction Kinetics on Conductive Oxide Electrodes in (Li+K) CO3 Eutectic at 650 °C’’ I. Uchida, Y. Mugikura, T. Nishina, and K. Itaya. J. Electroanal. Chem. 206 (1986) 241–252. ‘‘Gas Electrode Reactions in Molten Carbonate Media Part III. Temperature Dependence of Oxygen Reduction Kinetics in (Li+K)CO3 Eutectic’’ I. Uchida, T. Nishina, Y. Mugikura, and K. Itaya. J. Electroanal. Chem. 209 (1986) 125–133. ‘‘Nature of Intervalence Charge-Transfer Bands in Prussian Blues’’ K. Itaya and I. Uchida. Inorganic Chem. 25 (1986) 389– 392. ‘‘Electrochemistry of Polynuclear Transition Metal Cyanides: Prussian Blue and Its Analogues’’ K. Itaya, I. Uchida, and V. D. Neff. Acc. Chem. Res. 19 (1986) 162–168. ‘‘Images of Barrier Layer of Anodic Aluminum Oxide in Air Obtained with Scanning Tunneling Microscope’’ S. Morita, K. Itaya, and N. Mikoshiba. J. J. Appl. Phys. 25 (1986) L743-L745. ‘‘Clay-Modified Electrodes. 5. Preparation and Electrochemical Characterization of Pillared Clay-Modified Electrodes and Membranes’’ K. Itaya, and A. J. Bard. J. Phys. Chem. 89 (1985) 5565– 5568. ‘‘Photoelectrochemical Studies of Prussian Blue on n-Type Semiconductor (n-TiO2)’’ K. Itaya, I. Uchida, S. Toshima, and R. M. De La Rue. J. Electrochem. Soc. 131 (1984) 2086–2091.

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‘‘Catalysis of the Reduction of Molecular Oxygen to Water at Prussian Blue Modified Electrodes’’ K. Itaya, N. Shoji, and I. Uchida. J. Am. Chem. Soc. 106 (1984) 3423–3429. ‘‘Analog and mixed-valence complex Prussian Blue as a new oxygen reduction catalyst’’ K. Itaya, I. Uchida, and S. Toshima. J. Chem. Soc. Jpn. (1984) 1849–1853. ‘‘Properties of Porous Anodic Aluminum Oxide Films as Membranes’’ K. Itaya, S. Sugawara, K. Arai, and S. Saito. J. Chem. Eng. Jpn. 17 (1984) 514–520. ‘‘Prussian Blue modified electrode similar’’ K. Itaya, I.Uchida, S. Toshima. DENKIKAGAKU. 51 89–90. ‘‘Polymerization of styrene monodisperse polybutadiene presence’’ K. Itaya, S. Sugawara, K. Arai, S. Saito. Polymer Proceedings 40 (1983) 629–635. ‘‘Mediated Electron Transfer Reactions between Redox Centers in Prussian Blue and Reactants in the Solution’’ K. Itaya, I. Uchida, and S. Toshima. J. Phys. Chem. 87 (1983) 105–112. ‘‘Polymer-Modified Electrode. Spectroelectrochemical Properties of a Ligand (Bathophenanthroline Disulfonic Acid) Bound to Polyelectrolytes on Electrodes and the Use of the Modified Electrodes for an Electrochromic Display Device’’ K. Itaya, H. Akahoshi, and S. Toshima. J. Electrochem. Soc. 129 (1982) 762–767. ‘‘Electrochemistry of Prussian Blue Modified Electrodes: An Electrochemical Preparation Method’’ K. Itaya, H. Akahoshi, and S. Toshima. J. Electrochem. Soc. 129 (1982) 1498–1500. ‘‘Prussian-blue-modified electrodes: An application for a stable electrochromic display device’’ K. Itaya, K. Shibayama, H. Akahoshi, and S. Toshima. J. Appl. Phys. 53 (1982) 804–805. ‘‘Spectroelectrochemistry and Electrochemical Preparation Method of Prussian Blue Modified Electrodes’’ K. Itaya, T. Ataka, and S. Toshima. J. Am. Chem. Soc. 104 (1982) 4767–4772. ‘‘Electrochemistry of Prussian Blue. An in Situ Mossbauer Effect Measurement’’ K. Itaya, T. Ataka, S. Toshima, and T. Shinobara. J. Phys. Chem. 86 (1982) 2415–2418. ‘‘High Resolution Electron Beam Negative Resist with Very Narrow Molecular Weight Distributions’’ K. Itaya, K. Shibayama, and T. Fujimoto. J. Electrochem. Soc. 129 (1982) 663–665. ‘‘Electrochemical Preparation of a Prussian Blue Analogue: IronRuthenium Cyanide’’ K. Itaya, T. Ataka, and S. Toshima. J. Am. Chem. Soc. 104 (1982) 3751–3752. ‘‘Prussian Blue modified electrode similar - its stability’’ K. Itaya, I. Uchida, T. Ataka, S. Toshmia. DENKIKAKU. 50 (1982) 436–437. ‘‘Electrogenerated Chemiluminescence. 39. Reactions of Solvated Electrons in Liquid Ammonia’’ K. Itaya, and A. J. Bard. J. Phys. Chem. 85 (1981) 1358–1365. ‘‘Semiconductor Electrodes. 32. n- and p-GaAs, n- and p-Si, and n-TiO2 in Liquid Ammonia’’ R. E. Malpas, K. Itaya, and A. J. Bard. J. Am. Chem. Soc. 103 (1981) 1622–1627. ‘‘Electrochemical and Spectroelectrochemical Properties of Polyviologen Complex Modified Electrodes’’ H. Akahoshi, S. Toshima, and K. Itaya. J. Phys. Chem. 85 (1981) 818–822.

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‘‘Electron Transfer Induced Isomerization of cis-4,40 -Diphenylstilbene into Its Trans Form’’ C. K. Chien, H. C. Wang, M. Szwarc, A. J. Bard, and K. Itaya. J. Am. Chem. Soc. 102 (1980) 3100–3104. ‘‘Photoelectron Emission from a Metal Electrode in Liquid Ammonia’’ K. Itaya, R. E. Malpas, and A. J. Bard. Chem. Phys. Lett. 63 (1979) 411–415. ‘‘Semiconductor Electrodes. 20. Photogeneration of Solvated Electrons on p-Type GaAs Electrodes in Liquid Ammonia’’ R. E. Malpas, K. Itaya, and A. J. Bard. J. Am. Chem. Soc. 101 (1979) 2535–2537. ‘‘Electrochemical and Photoelectrochemical Studies of Excess Electrons in Liquid Ammonia’’ A. J. Bard, K. Itaya, R. E. Malpas, and T. Teherani. J. Phys. Chem. 84 (1979) 1262–1266. ‘‘Formation of Intramolecular Exciplexes in Electrogenerated Chemiluminescence. 2’’ M. Kawai, K. Itaya, and S. Toshima. J. Phys. Chem. 84 (1979) 2368–2374. ‘‘Electrogenerated Chemiluminescence with Solvated Electrons in Hexamethyl-phosphoroamide. 2’’ K. Itaya, M. Kawai, and S. Toshima. J. Am. Chem. Soc. 100 (1978) 5996–6002. ‘‘Successive Electron Transfers to Molecules with Identical Interacting Centers-The Electroreduction of a, w-9,90 -Dianthryalkanes’’ K. Itaya, A. J. Bard, and M. Szwarc. J. Phys. Chem., New Series. 112 (1978) 1–9. ‘‘An Electrochemical Study of Solvated Electrons in Liquid Ammonia’’ T. Teherani, K. Itaya, and A. J. Bard. New J. Chem. 2 (1978) 481–487. ‘‘Chemically Modified Polymer Electrodes: Synthetic Approach Employing Poly (methacryl chloride) Anchors’’ K. Itaya, and A. J. Bard. Anal. Chem. 50 (1978) 1487–1489. ‘‘Formation of Intramolecular Exciplexes in Electrogenerated Chemiluminescence’’ K. Itaya, and S. Toshima. Chem. Phys. Lett. 51 (1977) 447–452. ‘‘ESR Studies of Nitrobenzene Ion-Pair Equilibria in N,NDimethylformamide’’ S. Toshima, and K. Itaya. Bull. Chem. Soc. Jpn. 49 (1976) 957–964. ‘‘Electrogenerated Chemiluminescence with Solvated Electrons in Hexamethyl-phosphoroamide (HMPA)’’ K. Itaya, M. Kawai, and S. Toshima. Chem. Phys. Lett. 42 (1976) 179–183. ‘‘Catalytic reactivity of silver oxide anode’’ S. Toshima, T. Sasaki, and K. Itaya. DENKIKAGAKU 40 (1972) 234–238.

Manuel P. Soriaga Department of Chemistry, Texas A&M University, College Station, TX 77843, USA E-mail address: [email protected] Li-Jun Wan Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China E-mail addresses: [email protected] Available online 27 January 2014