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Preparation of an alcohol-free beer by adsorption of alcohol
Patent report The title method involves contacting C2-7 aliphatic and/or alicyclic hydrocarbon(s) with an acid-type crystalline galiosilicate that contains PT and is prepared from a mixture of Ga, Pt, and Si compounds. The above catalyst is also described.
SEPARATION PROCESSES Zeolite adsorbent for vapors from fuels containing alcohols
The title compositions showing optimum bleach activator performance contain nonionic surfactant 8-35, zeolite 4A 20-60, a peroxide generating H202 in water 5-20, an organic peracid precursor that generates quaternary ammonium group-containing organic peracid upon reaction with H202 1-10, and a copolymer having -CH(COOM)CH(COOM)- unit (M = H, alkali metal, alkaline earth metal, ammonium) 1-5%, with phosphate salt content being < 0.1%.
T. Sugimoto; T. Kato; M. Harada et al.
Tosoh Corp. Ger. Often. 4,110,646, Oct. 24, 1991; Jpn. Appl. Apr. 4, 1990 Vapors from fuels such as gasoline containing MeOH or EtOH are adsorbed on a zeolite having a Si/AI ratio of ~> 10:1 in the crystal lattice, e.g., faujasite, mordenite, or zeolite ZSM-5.
Gas adsorbent element for air purification T. Kuma
Seibu Giken K.K. PCT Int. Appl. 91,16,971, Nov. 14, 1991; Jpn. Appl. May 2, 1990 The adsorbent element for removing noxious gases, organic solvent vapors, and malodors from polluted air comprises dealuminated high-silica zeolite NaY powder loaded in the pore surface of a refractory honeycomb core block that is preferably prepared from corrugated inorganic fibre sheets having thickness 0.10-0.30, pitch width 2.5-4.5, pitch height 1.0-3.0, and pore size 100-150 ram.
Removal of nitrogenous components of a hydrocarbon feedstream D.D. Rosenfeld; J.Y. Ou
Exxon Chemical Patents Inc. PCT Int. Appl. 91,15,449, Oct. 17, 1991; U.S. Appl. Mar. 30, 1990 N-containing components and dialkyl sulfides are removed from a hydrocarbon feedstock, prior to reacting the feedstock, by adsorption using a crystalline aluminosilicate, e.g., zeolite X, zeolite Y, zeolite L, zeolite Beta, and mordenite.
Separation of mixture components over a membrane composed of a pure molecular sieve W.O. Haag; J.G. Tsikoyiannis
Mobil Oil Corp. U,S. 5,069,794, Dec. 3, 1991; Appl. June 5, 1990; Cont.-in-part of U,S. 5,019,263 A process is provided for separation of components of a gaseous or liquid mixture that comprises contacting the mixture with a synthetic, noncomposited microporous membrance comprising a continuous array of crystalline (catalytic) zeolite molecular sieve material.
Preparation of an alcohol-free beer by adsorption of alcohol W.D. Einicke; R. Schoellner; M. Schmidt et al.
Chemiean/agenbau G.m.b.H. Leipzig-Grimma E. Ger. 295,866, Nov. 14, 1991; Appl. May 19, 1989 An alcohol-free beer is prepared from a normally brewed beer by adsorption of EtOH onto a (NaZSM-5, Si/AI -- 50) zeolite bound with a cellulose derivative. The pore size is large enough to admit EtOH but not molecules responsible for the flavor of the beer. The EtOH-saturated adsorbent can be regenerated by thermal desorption.
DETERGENTS Bleach-detergent compositions M. Kuroda; H. Araki; H. Otsuka et al.
Kao Corp. Jpn Kokai Tokkyo Koho 91,215,599, Sept. 20, 1991; Appl. Jan. 19, 1990
MISCELLANEOUS APPLICATIONS Desiccants for gas-fired cooling and dehumidification equipment S. Komarneni; P.B. Malla; S. Yamanaka
Gas Research Institute U.S. 5,052,188, Oct. 1, 1991; Appl. Oct. 24, 1990 The particulate desiccant for air conditioning systems comprises a modified aluminosilicate (e.g., zeolite 13Y, zeolite NaY, erionite) having an isotherm separation factor of 0.07-0.1, a SIO2/AI203 ratio of >~3:1, and a pore diameter of 4-10 A. To reduce the polarity on the inner surfaces, the aluminosilicate is treated with an aqueous acid or ammonium solution (e.g., NH4CI) for exchange of metal ions with protons and removal of a portion of the AI. The acid can be EDTA or HCi. C h r y s o z e o l i t e soil amendments R.L. Van Mao U.S. 5,082,488, Jan. 21, 1992; Appl. June 20, 1990 The chrysozeolites A and X, comprising a Mg-leached asbestos matrix with a zeolite crystal structure thereon, are soil conditioners, especially useful for enhancing the soil water-retention capacity.
Sterilization of contact lens by hydrogen peroxide M. Sakai
Tomei Sangyo K.K. Jpn Kokai Tokkyo Koho 91,275,063, Dec. 5, 1991; Appl. Mar. 24, 1990 Contact lenses are sterilized by H202 and subsequently the residual H202 is decomposed by Cu (OH)2 and/or Cu complex ion bound to zeolites. After sterilization of the lens by H202, the residual H202 is rapidly decomposed by Cu2+. Thus, a soft contact lens and Cu(OH)2bound zeolite were added to a HzO2 solution. The lens was sterilized and the residual H202 degraded by Cu2+ in the same solution.
Preparation of rubber articles w i t h d e l a y e d f i b r i n o l y t i c action S. Borgmann; P. Knop; W. Schunk et al.
Gummiwerke Thueringen G.m.b.H. E. Ger. 295,649, Nov. 7, 1991; Appl. Feb. 3, 1986 The title rubber articles, for use as prosthetics and implants, are prepared by combining a fibrinolytic-zeolite 13X adduct with a mixture of natural or synthetic rubber, vulcanizing agent, filler, dye, medicaments, etc., prior to vulcanization and vulcanizing.
Manufacture of ion exchanger containing palladium ions and other metallic ions for removal of ethylene gas R. Yoshii; M. l"akeuchi
Toray Industries/nc. Jpn Kokai Tokkyo Koho 91,280,827; 91,280,828, Dec. 11, 1991; Appls. Mar. 9, 1990 Ion exchangers in which most of the ions are exchanged with the ions of Pd or its complex salts and other metallic ions are provided for removing ethylene gas from vegetables, fruits, or flowers. Na-Y type synthetic zeolite was incubated with a tetraminedichloropalladium solution to exchange the ions for Pd. The exchanger was further incubated stepwise with a CuCI2 solution and a ZnCI2 solution to exchange with Cu2+ and Zn2+.
ZEOLITES, 1993, Vol 13, February
151
SEPARATION PROCESSES Zeolite adsorbent for vapors from fuels containing alcohols
The title compositions showing optimum bleach activator performance contain nonionic surfactant 8-35, zeolite 4A 20-60, a peroxide generating H202 in water 5-20, an organic peracid precursor that generates quaternary ammonium group-containing organic peracid upon reaction with H202 1-10, and a copolymer having -CH(COOM)CH(COOM)- unit (M = H, alkali metal, alkaline earth metal, ammonium) 1-5%, with phosphate salt content being < 0.1%.
T. Sugimoto; T. Kato; M. Harada et al.
Tosoh Corp. Ger. Often. 4,110,646, Oct. 24, 1991; Jpn. Appl. Apr. 4, 1990 Vapors from fuels such as gasoline containing MeOH or EtOH are adsorbed on a zeolite having a Si/AI ratio of ~> 10:1 in the crystal lattice, e.g., faujasite, mordenite, or zeolite ZSM-5.
Gas adsorbent element for air purification T. Kuma
Seibu Giken K.K. PCT Int. Appl. 91,16,971, Nov. 14, 1991; Jpn. Appl. May 2, 1990 The adsorbent element for removing noxious gases, organic solvent vapors, and malodors from polluted air comprises dealuminated high-silica zeolite NaY powder loaded in the pore surface of a refractory honeycomb core block that is preferably prepared from corrugated inorganic fibre sheets having thickness 0.10-0.30, pitch width 2.5-4.5, pitch height 1.0-3.0, and pore size 100-150 ram.
Removal of nitrogenous components of a hydrocarbon feedstream D.D. Rosenfeld; J.Y. Ou
Exxon Chemical Patents Inc. PCT Int. Appl. 91,15,449, Oct. 17, 1991; U.S. Appl. Mar. 30, 1990 N-containing components and dialkyl sulfides are removed from a hydrocarbon feedstock, prior to reacting the feedstock, by adsorption using a crystalline aluminosilicate, e.g., zeolite X, zeolite Y, zeolite L, zeolite Beta, and mordenite.
Separation of mixture components over a membrane composed of a pure molecular sieve W.O. Haag; J.G. Tsikoyiannis
Mobil Oil Corp. U,S. 5,069,794, Dec. 3, 1991; Appl. June 5, 1990; Cont.-in-part of U,S. 5,019,263 A process is provided for separation of components of a gaseous or liquid mixture that comprises contacting the mixture with a synthetic, noncomposited microporous membrance comprising a continuous array of crystalline (catalytic) zeolite molecular sieve material.
Preparation of an alcohol-free beer by adsorption of alcohol W.D. Einicke; R. Schoellner; M. Schmidt et al.
Chemiean/agenbau G.m.b.H. Leipzig-Grimma E. Ger. 295,866, Nov. 14, 1991; Appl. May 19, 1989 An alcohol-free beer is prepared from a normally brewed beer by adsorption of EtOH onto a (NaZSM-5, Si/AI -- 50) zeolite bound with a cellulose derivative. The pore size is large enough to admit EtOH but not molecules responsible for the flavor of the beer. The EtOH-saturated adsorbent can be regenerated by thermal desorption.
DETERGENTS Bleach-detergent compositions M. Kuroda; H. Araki; H. Otsuka et al.
Kao Corp. Jpn Kokai Tokkyo Koho 91,215,599, Sept. 20, 1991; Appl. Jan. 19, 1990
MISCELLANEOUS APPLICATIONS Desiccants for gas-fired cooling and dehumidification equipment S. Komarneni; P.B. Malla; S. Yamanaka
Gas Research Institute U.S. 5,052,188, Oct. 1, 1991; Appl. Oct. 24, 1990 The particulate desiccant for air conditioning systems comprises a modified aluminosilicate (e.g., zeolite 13Y, zeolite NaY, erionite) having an isotherm separation factor of 0.07-0.1, a SIO2/AI203 ratio of >~3:1, and a pore diameter of 4-10 A. To reduce the polarity on the inner surfaces, the aluminosilicate is treated with an aqueous acid or ammonium solution (e.g., NH4CI) for exchange of metal ions with protons and removal of a portion of the AI. The acid can be EDTA or HCi. C h r y s o z e o l i t e soil amendments R.L. Van Mao U.S. 5,082,488, Jan. 21, 1992; Appl. June 20, 1990 The chrysozeolites A and X, comprising a Mg-leached asbestos matrix with a zeolite crystal structure thereon, are soil conditioners, especially useful for enhancing the soil water-retention capacity.
Sterilization of contact lens by hydrogen peroxide M. Sakai
Tomei Sangyo K.K. Jpn Kokai Tokkyo Koho 91,275,063, Dec. 5, 1991; Appl. Mar. 24, 1990 Contact lenses are sterilized by H202 and subsequently the residual H202 is decomposed by Cu (OH)2 and/or Cu complex ion bound to zeolites. After sterilization of the lens by H202, the residual H202 is rapidly decomposed by Cu2+. Thus, a soft contact lens and Cu(OH)2bound zeolite were added to a HzO2 solution. The lens was sterilized and the residual H202 degraded by Cu2+ in the same solution.
Preparation of rubber articles w i t h d e l a y e d f i b r i n o l y t i c action S. Borgmann; P. Knop; W. Schunk et al.
Gummiwerke Thueringen G.m.b.H. E. Ger. 295,649, Nov. 7, 1991; Appl. Feb. 3, 1986 The title rubber articles, for use as prosthetics and implants, are prepared by combining a fibrinolytic-zeolite 13X adduct with a mixture of natural or synthetic rubber, vulcanizing agent, filler, dye, medicaments, etc., prior to vulcanization and vulcanizing.
Manufacture of ion exchanger containing palladium ions and other metallic ions for removal of ethylene gas R. Yoshii; M. l"akeuchi
Toray Industries/nc. Jpn Kokai Tokkyo Koho 91,280,827; 91,280,828, Dec. 11, 1991; Appls. Mar. 9, 1990 Ion exchangers in which most of the ions are exchanged with the ions of Pd or its complex salts and other metallic ions are provided for removing ethylene gas from vegetables, fruits, or flowers. Na-Y type synthetic zeolite was incubated with a tetraminedichloropalladium solution to exchange the ions for Pd. The exchanger was further incubated stepwise with a CuCI2 solution and a ZnCI2 solution to exchange with Cu2+ and Zn2+.
ZEOLITES, 1993, Vol 13, February
151