Probing the electronic environment of binary and ternary ionic liquid mixtures by X-ray photoelectron spectroscopy

Probing the electronic environment of binary and ternary ionic liquid mixtures by X-ray photoelectron spectroscopy

Accepted Manuscript Research paper Probing the electronic environment of binary and ternary ionic liquid mixtures by X-ray photoelectron spectroscopy ...

5MB Sizes 2 Downloads 77 Views

Accepted Manuscript Research paper Probing the electronic environment of binary and ternary ionic liquid mixtures by X-ray photoelectron spectroscopy Shuang Men, Peter Licence PII: DOI: Reference:

S0009-2614(17)30795-9 http://dx.doi.org/10.1016/j.cplett.2017.08.034 CPLETT 35044

To appear in:

Chemical Physics Letters

Received Date: Revised Date: Accepted Date:

11 July 2017 15 August 2017 18 August 2017

Please cite this article as: S. Men, P. Licence, Probing the electronic environment of binary and ternary ionic liquid mixtures by X-ray photoelectron spectroscopy, Chemical Physics Letters (2017), doi: http://dx.doi.org/10.1016/ j.cplett.2017.08.034

This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain.



































































































































































































































!



 

!

"

























#

%$

$

!

#

!

$ % 

!

!



&







 

!

(







)

























+







,













*





-



















*

.

/

n 0



1

´





+

2

3

4

,

5

6

2

7



4





















*

8

&

8

;

(

































2

7

4





9

,







:

























































'

&



&



&





=

>

!

=



!

>



=

>

=

>



?



=

&

>





&



!

=

>



=

>



&



!



>



=

>

&



8

&

=

!

2

7

&

4

9

:







&



!

=

>



=

>



@

$

#

$  &



!

&



A



&





=

>



!

=

>





=



>





 &

&



!

=

>



=

>

B













&







!

=

>



=



C

&

&

A



&

&



!

=

>



=

>





&

&

A



!

=

<

>



=

>

&





&



=

>



!

!

=

>



=

=

>

>

?





=

>





>



D

`

N

Z

`

L

^

_

]

L

]

^

^

K

]

N

]

Z

Z

^

L

L

L

K

K

K

^

^

\

]

\

]

Z

L

K

^

^

^

\

N

]

\

N

]

Z

\

]

N

L

K

R

P

P

Y

S

Y

T

Y

S

T

X

Y

S

Y

T

X

T

W

T

S

N

[

Z

N

[

Z

N

[

\

N

[

Z

V

V

Q

V

V

Q

O

V

U

Q

O

N

L

N

L

K

I

F

M

J

H

G

E

(































































!







 !





B











b





&



 

 =

>



!

>





 =

>





A



 =



!



 =

>



 =

>



!

 =

>







!

=

>



=

>

?

 !

&



!

=

>



=

>





&

a





=

>

&

 !

8



2

7

4

9

:









!





!

!

 !

&



A



 

!



 !



!

&



!

=

>



=

>



&



!

 

 

&





A



!

 



!





 



!



!

 !



&

-







&





















 &



A

&





A





 &







d



!

A



e





















c

;



















f

g

j

k

l

m

n

o

p

q

m

r

m

s

t

u

v

w

u

x

m

r

m

y

z

u

l

š

„

m

›

q

œ



u

ž

{

Ÿ

 

¡

|

¢

£

l

š

¤

u

¥

o

¦

§

v

¨

Ÿ

 

q

¡

¢



|

£

¦

s

§

 

u

¡

¢



£

Œ

‹

‡

‰

Š

ˆ

}

‡



‚

š

¤

¥

¦

§

š

¤

¥

¦

§

š

¤

¥

¦

§

¨

Ÿ

 

¡

¢

£

¡

¢



¡

¢

ª

¦

§

¦

§

¦

§

 

¡

¢

£

¡

¢

©

¡

¢

«

†

…

ƒ

„

ƒ

‚

€

¨

 

Ÿ

 



 ¨

Ÿ

 

 



¦

§

 

~



Ž





~

‘



}





’

“



”

•

’

–

—

”

˜

~

~

™

h

v

i

s

u

z

n

m

k

v

z

¬

¬

­

®

¯

°

¹

Å

³

¹

¬

²

°

»

µ

¯

Ê

´



Å

Õ

¾

¯





°

µ

» º

»

¹

°

º

º

Á

½



¯

´

¼

»

¹

Ç

¹

½

¯

½

¹

´

¹

³

¯



µ

º

¯

´

»



¹

Î

°

²

¯

»

¿

´

º

±

³

»

»

³

´

¹

µ

½

µ

¸

°

Ç

· ¶

Á

¯

¯

»

°

´

µ

°





Ç

¸

¹

Æ



¹



¾



º

»

º



³

º

µ

¹

» ¸

¹

½



µ

Á

À

¸

¯



²

½

¹

»

´

Ç

¹

¹

´

½

¸

±



´

¸

¼



µ

Á

µ

¹

º

È

°

»



¹

·

º





½

¯

· É

µ

¹

°

´

¯

´

²

±

¯

¸

¹

µ

´

¾

³

³

·



´

¯



µ

´



³

º

· ¶

µ

¸





°

µ

¹

¯

· ¶

¹

´

¸

°

µ

¹

µ

¯



´

¹

» ´

¸»



»

¹

¹

¸



» ¸

¿

»

¯

¹

·

´

»

¿

Â

»

¼

¹

À

¯

´

¹

» ½

À

À



¹

»

µ



Ã

¹

µ

´

µ

¼

Á

´

¯

¸



Á

º

°

¸

°

µ

» ´

¹

º

Ä

µ

»

´

¹

®

¾

°

º



½

Ä

µ

¯

°

µ

» ´

¹

´

Á

È

·

É

Ë

µ

³



À



°

º

¼

¯



½

¾

»

¹

½

»

¹

Ç



¹



¯

Ç

±

´

Á

Ì

Í

º

»

º

Ä

µ



µ

¯

´

´

»

¸

¼

µ

¸

´

µ



· ¶

· ¶

Á

¸

°

³



º

°

¹



´

¹

²

µ



µ

» ´



³

¸

³

´

À

Ç

» µ

³

¹



À

¬

±

½

»

½

¬

°





Ï

³

°

¯

Ç

½

µ

¹

Ð

Ñ

»

Ò

Æ

» ¶

¿

°

» µ

º

½

´

¹

³



¯

¹

½



È

µ

¸

À

³

¯



·



Ó

»

°

º

¹

²

¹



µ

¸

´

Ô

¯

Ñ



Á

Ò

°

°

¾

º

»

»

¹

¹

¹

» ´

½

Ç

»

´

¹

¹

®

Ç

Á

¾

°



µ

¹

³

º





¯



Æ

Ä

h

½

h

Ç

¸

» ¶



´

º

»

Ç

À

²

´

¹



¹

µ

»

º

°

· º

´

¸

´

À

²

°

¯



½

¾

°

º



½

¼

²

´

¹

Ä

³

µ

»

¹

Ç

´

Á

È

·

É

Ë

¾

´

µ

³

´

Á

µ

³



Î

¹

Ï

½

Ð

Ñ

Ò

°

¹

½

È

·

Ó

²

Ô

Ñ

Ò