Physics Letters A 379 (2015) 1544–1548
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Physics Letters A www.elsevier.com/locate/pla
Rotational elastic waves in double wall tube M.O. Katanaev Steklov Mathematical Institute, ul. Gubkina, 8, Moscow, 119991, Russia
a r t i c l e
i n f o
Article history: Received 3 March 2015 Received in revised form 23 March 2015 Accepted 24 March 2015 Available online 27 March 2015 Communicated by V.M. Agranovich
a b s t r a c t We describe the double wall tube with cylindrical dislocation in the framework of the geometric theory of defects. The induced metric is found. The dispersion relation is obtained for the propagation of rotational elastic waves in the double wall tube. © 2015 Elsevier B.V. All rights reserved.
1. Introduction Ideal crystals are absent in nature, and most of their physical properties, such as plasticity, melting, growth, etc., are defined by defects of the crystalline structure. Therefore, a study of defects is a topical scientific question of importance for applications in the first place. At present, a fundamental theory of defects is absent in spite of the existence of dozens of monographs and thousands of articles. One of the most promising approaches to the theory of defects is based on Riemann–Cartan geometry, which involves nontrivial metric and torsion. In this approach, a crystal is considered as a continuous elastic medium with a spin structure. If the displacement vector field is a smooth function, then there are only elastic stresses corresponding to diffeomorphisms of the Euclidean space. If the displacement vector field has discontinuities, then we are saying that there are defects in the elastic structure. Defects in the elastic structure are called dislocations and lead to the appearance of nontrivial geometry. Precisely, they correspond to a nonzero torsion tensor, equal to the surface density of the Burgers vector. Defects in the spin structure are called disclinations. They correspond to nonzero curvature tensor, curvature tensor being the surface density of the Frank vector. The idea to relate torsion to dislocations appeared in the 1950s [1–4]. This approach is still being successfully developed (note reviews [5–11]), and is often called the gauge theory of dislocations. Some time ago we proposed the geometrical theory of defects [12–14]. Our approach is essentially different from others in two respects. Firstly, we do not have the displacement and rotational angle vector fields as independent variables because, in general, they are not continuous. Instead, the triad field and SO(3)-connection are considered as independent variables. If defects are absent, then the triad and SO(3)-connection reduce to
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partial derivatives of the displacement and rotational angle vector fields. In this case the latter can be reconstructed. Secondly, the set of equilibrium equations is different. We proposed purely geometric set which coincides with that of Euclidean three dimensional gravity with torsion. The nonlinear elasticity equations and principal chiral SO(3) model for the spin structure enter the model through the elastic and Lorentz gauge conditions [14–16] which allow to reconstruct the displacement and rotational angle vector fields in the absence of dislocations in full agreement with classical models. The advantage of the geometric theory of defects is that it allows one to describe single defects as well as their continuous distributions. In the present paper, we consider propagation of rotational elastic waves in double wall tube with cylindrical dislocation. This defect was first described in [17]. The Schrödinger equation for the double wall tube was solved in [18] and applied to double wall nanotubes. A similar problem was also solved for the cylindrical waveguide with wedge dislocation [19]. 1.1. Double wall tube Let us describe double wall tube with cylindrical dislocation in the framework of the geometric theory of defects. We consider cylindrical coordinates {xμ } = {r , ϕ , z}, μ = 1, 2, 3 in tree dimensional Euclidean space R3 . Let there be two thick tubes r0 ≤ r ≤ r1 and r2 ≤ r ≤ r3 of elastic media, each axis coinciding with the z axis. We suppose that r0 < r1 < r2 < r3 (see Fig. 1(a), where a section z = const is shown). Now we make one tube with the inside cylindrical dislocation in the following manner. We stretch symmetrically the inner tube and compress the outer one. Then glue together the external surface of the inner tube with the internal surface of the outer tube. Afterwards the media comes to some equilibrium state. Due to rotational and translational symmetry we obtain one tube rin ≤ r ≤ rex with the
M.O. Katanaev / Physics Letters A 379 (2015) 1544–1548
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Fig. 1. Section z = const of double wall tube before (a) and after (b) defect creation.
axis which coincides with the z axis (see Fig. 1(b)). Radii of cylinders constituting tube surfaces are mapped as follows
The divergence and Laplacian have the following form in cylindrical coordinates
r0 → rin ,
∇i u i = ∂r (rurˆ ) + ∂ϕ u ϕˆ + ∂z u zˆ ,
r1 , r2 → r∗ ,
r3 → rex .
The gluing is performed along the cylinder r∗ , and there is cylindrical defect (dislocation) because part of the media between tubes is removed. The obtained double wall tube with cylindrical dislocation is rotationally and translationally symmetric. The constructed model of the tube with cylindrical dislocation can be considered as continuous model of double wall nanotube (for a general review, see [20–22]). Consider double wall nanotube having two atomic layers. Suppose the inner layer has 18 and outer layer has 20 atoms which are shown in Fig. 1(b) by points. Natural length measure here is the interatomic distance. Then the length of a circle has a jump when one goes from inner to outer layer. In the geometric theory of defects, it means that the metric component g ϕϕ is not continuous in cylindrical coordinates. The corresponding model will be described below. To find radii rin , r∗ , and rex we have to solve the classical elasticity problem. Let us define the displacement vector field by u i (x), i = 1, 2, 3,
y i → xi = y i + u i (x),
(1)
where y i and xi are coordinates of a point before and after deformation respectively. We consider the displacement field as a vector function on points of media after deformation and gluing. This is more adequate because the resulting media after gluing is a connected manifold (before the gluing procedure, each tube represents a connected component). In equilibrium state, the vector displacement field satisfies the equation
(1 − 2σ )u i + ∂i ∂ j u j = 0,
u = u rˆ erˆ + u ϕˆ e ϕˆ + u zˆ e zˆ , where
e ϕˆ =
1 r
∂ϕ ,
e zˆ = ∂z .
We denote indices with respect to the orthonormal basis by hat:
{i } = {ˆr , ϕˆ , zˆ },
1
r 1
r
1 2 1 2 2 ∂ urˆ + ∂zz u rˆ − 2 u rˆ − 2 ∂ϕ u ϕˆ , r 2 ϕϕ r r 1 2 1 2 2 u ϕˆ + ∂zz u ϕˆ − 2 u ϕˆ + 2 ∂ϕ u rˆ , u ϕˆ = ∂r (r ∂r u ϕˆ ) + 2 ∂ϕϕ r r r r 1 1 2 2 u zˆ + ∂zz u zˆ . u zˆ = ∂r (r ∂r u zˆ ) + 2 ∂ϕϕ r r
urˆ = ∂r (r ∂r urˆ ) + r 1
{μ} = {r , ϕ , z}.
The Latin indices referred to an orthonormal basis are raised and lowered by Kronecker symbol: u i := u j δ ji .
(3)
From the symmetry of the problem, we deduce that only radial component of the displacement field differs from zero, and it does not depend on the angle ϕ and z coordinates:
{u i } = {urˆ := u (r ), u ϕˆ = 0, u zˆ = 0}. Eq. (2) for zero u ϕˆ and u zˆ components is automatically satisfied. It is easy to check that the radial derivative of the divergence,
j
∂rˆ ∂ j u = ∂r
1 r
1 1 ∂r (ru ) = ∂rr2 u + ∂r u − 2 u , r
r
coincides with the Laplacian
1
1
r
r2
urˆ = ∂r (r ∂r u ) −
2 u = ∂rr u+
1 r
∂r u −
1 r2
u.
Therefore the radial component of Eq. (2) takes the form
∂r
1 r
∂r (ru ) = 0.
(4)
A general solution of this equation depends on two integration constants:
(2)
where σ is the Poisson ratio and is the Laplacian. For convenience, we consider components of the displacement vector field with respect to the orthonormal basis
erˆ = ∂r ,
1
u = c1 r +
c2 r
c 1,2 = const.
,
Note that the equilibrium equation (4) does not depend on the Poisson ratio σ . This means that the cylindrical dislocation is the geometrical defect. Boundary conditions have to be imposed to fix the integration constants. Let us introduce a notation for inner and outer tubes:
u=
u , in u ex ,
rin ≤ r ≤ r∗ , r∗ ≤ r ≤ rex .
Now boundary conditions are to be imposed. We assume that the surface of two wall nanotube is free, i.e. the deformation tensor is zero on the boundary:
= 0, dr r =rin
du in
= 0. dr r =rex
du ex
(5)
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M.O. Katanaev / Physics Letters A 379 (2015) 1544–1548
Fig. 2. Qualitative behaviour of the radial component of the displacement vector field for the double wall tube (a). The derivative of the displacement vector field (b).
We assume also that the media is in equilibrium. It means that elastic forces on the gluing surface must be equal to zero:
du ex = . dr r =r∗ dr r =r∗
du in
(6)
Each of boundary conditions (5) defines one integration constant for internal and external solutions:
u in = a r +
u ex = −b
1 r
2 rin
r
+
r
b = const > 0.
< 0,
2 rex
(7)
Signs of the integration constants a and b are chosen in such a way that displacement vector is positive and negative for inner and outer tubes respectively. This is in agreement with the imposed problem. Substitution of obtained solutions (7) into the gluing condition (6) defines the ratio of integration constants: 2 r∗2 = rex
2 arin +b 2 arex
2 b = arex
⇔
+b
2 r∗2 − rin 2 rex − r∗2
.
(8)
The entirety condition for the media is
r∗ = r1 + a r∗ +
r∗ = r2 − b
1 r∗
2 rin
+
r∗ r∗ 2 rex
,
l
2 rex − r∗2
(9)
.
2 2 rex − rin 2 rex − r∗2
2 2 2r∗ rex − rin
b=
,
(10)
,
2 r2 − r2 lrex ∗ in . 2 2 2r∗ rex − rin
(11)
(13)
r∗ ≤ r ≤ rex ,
l := r2 − r1 = u in (r∗ ) − u ex (r∗ ). Since vector field u has discontinuity at the point r∗ , the formal derivative of u contains δ(r − r∗ ). This δ -function is thrown away in the geometric theory of defects [14]. Double wall tube with cylindrical dislocation is parameterised by four constants r0 , r1 , r2 , r3 or rin , r∗ , rex , l. Formulae (11) define constants a, b and, consequently, the displacement vector field through the second set of parameters. It follows from the definition (1) that there is one-to-one correspondence between two sets of parameters. Now we calculate the metric induced in double wall tube. By definition, it has the form
∂ yρ ∂ yσ ◦ g ρσ ( y ), ∂ xμ ∂ xν
(14)
⎧ 2 ⎪ ⎨ a r + rin > 0, r u (r ) =
⎪ ⎩ −b 1 + r < 0, 2 r
rin ≤ r < r∗ ,
where g ρσ ( y ) is the Euclidean metric in cylindrical coordinates. The relation between coordinates before and after defect creation is given by equality (1). Let cylindrical coordinates before and after defect creation be { y μ } = {˜r , ϕ , z} and {xμ } = {r , ϕ , z}, respectively. Note that the displacement vector field is considered in coordinates r, ϕ , z after defect creation. Then the original Euclidean metric is ◦
ds2 = g μν dy μ dy ν = dr˜ 2 + r˜ 2 dϕ 2 + dz2 . Substituting here r˜ = r − u, where the displacement vector is given by Eq. (12) we find the induced metric in the double wall tube
ds2 = (1 − v )2 dr 2 + (r − u )2 dϕ 2 + dz2 .
(15)
The component grr = (1 − v ) of this metric is continuous function but its derivative has a jump at r∗ . The component g ϕϕ = (r − u )2 is discontinuous at the point r = r∗ . The volume element for metric (15) is 2
Thus we find the displacement vector field
rex
rin ≤ r ≤ r∗ ,
◦
where expression for b (8) is used. Afterwards we find the integration constants:
a=
rex
g μν (x) =
These equations allow to find the distance between initial tubes which characterise the cylindrical dislocation:
l := r2 − r1 = 2ar∗
⎧ 2 rin ⎪ ⎨ > 0, a 1 − du r2 v (r ) := =
⎪ dr ⎩ b 1 − 1 > 0, 2 r2
which is depicted in Fig. 2(b). Note that the media entirety condition (9) leads to the jump of the displacement vector field at the point r∗ :
a = const > 0,
> 0,
Fig. 2(a). Differentiation of this vector field in domains rin < r < r∗ , r∗ < r < rex and its extension to the point r∗ by continuity yields the function
(12)
r∗ < r ≤ rex
for double wall tube where constants a and b are given by Eqs. (11). Qualitative behaviour of this vector field is shown in
√
| g | = (1 − v )(r
− u ).
The right hand side of this relation is positive because both multipliers are positive. The second multiplier r − u = y > 0 is positive
M.O. Katanaev / Physics Letters A 379 (2015) 1544–1548
by construction. The first multiplier is also positive. Indeed, the function v has the maximum at r = r∗ . At this point, the following inequality holds
v (r∗ ) = a
2 r∗2 − rin
r2 ∗
=
2 r∗ − r1 r∗2 − rin
r∗
2 r∗2 + rin
< 1,
where expression (9) for a is used. is a geometric invariant. It is equal to The circumference 2π r − u (r ) for metric (14). When we go from the inner tube to the outer one it has the jump 2π l where l is the distance between tubes before the dislocation is made. This observation agrees with the continuous model of double wall tube. Metric (15) was obtained entirely within the linear elasticity theory. It’s a surprise that precisely this metric satisfies nonlinear three dimensional Einstein’s equations with δ -function source at the gluing surface. This was proved in [17] for r0 = 0 and r3 = ∞. One may check that the proof is also valid for double wall tube with finite r0 and r3 . Indeed, the Einstein tensor vanishes everywhere (it is zero for flat space) except the gluing surface, and the singularity here is the same. This observation makes the connection to the geometric theory of defects because we say that metric (15) follows from the geometric theory of defects as the solution of Einstein’s equations. Note, that this is an exception in favour of the geometric theory of defects. In general, the induced metric obtained within the elasticity theory differs from that in the geometric theory of defects. For example, the metric for the wedge dislocation obtained within the elasticity theory reproduces only the linear approximation for the metric given by the geometric theory of defects [14].
ρ0 w¨ i − μ w i − (λ + μ)∇i ∇ j w j = 0,
In the geometric theory of defects, we may consider elastic deformation in media which already contains defects. The total displacement vector field is the sum u i + w i where u i is the displacement vector field corresponding to creation of dislocations and w i is the displacement vector field for elastic deformations of the media which contains dislocations. The vector field u is not continuous and therefore is replaced by the triad field e μ i , which equals simply to e μ i = ∂μ y i outside dislocations. This triad field produces nontrivial metric g μν := e μ i e ν j δi j . And this is all what is left after creation of dislocations. Now we describe elastic deformations on this nontrivial background by an extra smooth displacement vector field w i . Note, that the metric in the geometric theory of defects is obtained as a solution of equilibrium equations and is essentially unique due to the elastic gauge condition [15]. Therefore the decomposition u i + w i does not matter because the only independent variables are e μ i (or g μν ) and w i . For simplicity, we consider elastic media without spin structure. Therefore there are no disclinations, and the curvature tensor for the SO(3)-connection ωμi j is identically zero. So, without loss of generality we can put ωμi j = 0. This procedure is consistent with equilibrium equations in the geometric theory of defects [12]. Afterwards one may compute torsion tensor for a given triad e μ i which yields the surface density of the Burgers vector. Of course, the Riemannian curvature tensor for the metric g μν is nontrivial in general. The situation here is similar to the teleparallel formulation of general relativity. Now we consider rotational waves in the double wall tube with cylindrical dislocation described in the previous section. We denote the displacement vector field by the new letter w because the letter u was used in the previous section for the displacements corresponding to the defect creation. By definition, the displacement vector field w satisfies the wave equation
(16)
where ρ0 is the mass density of media, λ, μ are Lame coefficients, and the covariant derivative ∇i := e μ j ∇μ and Laplace–Beltrami operator := g μν ∇μ ∇ν are defined by metric (15) of double wall j
tube. Here e μ i is the inverse triad, e μ i e μ j = δi . This equation is covariant with respect to changing of coordinate systems. It can be solved in cylindrical coordinates r, ϕ , z after the defect creation with metric (15). However it is easier to follow another way. We solve the wave equation in the original cylindrical coordinates y := r˜ , ϕ , z where y now denotes the old radial coordinate before the defect creation
y := r − u , and afterwards impose necessary boundary conditions. It is easier because the metric is Euclidean in the initial coordinate system. Let us consider rotational waves. In this case only angular component of the displacement vector field differs from zero:
{ w i } = { w rˆ = 0, w ϕˆ = w ϕˆ (t , r , z), w zˆ = 0}. From symmetry consideration, the angular component w ϕˆ does not depend on ϕ . For this vector field the rˆ and zˆ components of Eq. (16) are automatically satisfied. It follows that the dilation for rotational waves is equal to zero
:= ∂i w i = 0, and consequently rotational waves take place without media compression. We look for solution of Eq. (16) in the plain wave form
1.2. Rotational waves
1547
w ϕˆ = re W ( y ) ei (kz−ωt ) ,
(17)
where W ( y ) is the amplitude, k ∈ R is the wave vector, and ω ∈ R is the frequency of the wave. Then wave equation (16) in cylindrical coordinates reduces to the Bessel equation
y2
d2 W
+y
dy 2
dW dy
+ (κ 2 y 2 − 1) W = 0,
(18)
μ . ρ0
(19)
where
κ 2 :=
ω2 2
ct
− k2 ,
c t2 :=
A general solution of this equation depends on two integration constants. Therefore general solutions for inner and outer tubes are
W =
W in = C 1 J 1 (κ y ) + C 2 N 1 (κ y ), r0 ≤ y ≤ r1 , W ex = C 3 J 1 (κ y ) + C 4 N 1 (κ y ), r2 ≤ y ≤ r3 ,
(20)
where J 1 is the Bessel function of the first kind and first order, N 1 is the Neumann function of the first order (see, i.e. [23]), and C 1,2,3,4 are integration constants. To find the integration constants we impose boundary conditions. The boundary surfaces are assumed to be free, i.e. the deformation tensor on the boundary must be zero
= 0, dr r =rin
dW in
= 0. dr r =rex
dW ex
Because
dW dr
=
dy dW dr dy
= (1 − v )
dW dy
,
and v (rin ) = v (rex ) = 0, these equalities in the initial coordinates take the form
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M.O. Katanaev / Physics Letters A 379 (2015) 1544–1548
C 1 J 1 ( z0 ) + C 2 N 1 ( z0 ) = 0
C 3 J 1 ( z 3 ) + C 4 N 1 ( z 3 ) = 0, where
z := κ y , and prime denotes differentiation with respect to the argument z. These equalities define two integration constants:
C 2 = −k0 C 1 ,
k0 :=
C 4 = −k3 C 1 ,
k3 :=
J 1 ( z0 )
N 1 ( z0 ) J (z 1
3)
1
3)
N (z
, (21)
.
dW ex . dr r =r∗ dr r =r∗
dW in
(22)
As a result we get two equations
C 1 J 1 ( z 1 ) − k 0 N 1 ( z 1 ) − C 3 J 1 ( z 2 ) − k 3 N 1 ( z 2 ) = 0, C 1 J 1 ( z1 ) − k0 N 1 ( z1 ) − C 3 J 1 ( z2 ) − k3 N 1 ( z2 ) = 0.
(23)
The necessary and sufficient condition for this system to have a nontrivial solution is the equality of its determinant to zero:
J 1 ( z1 ) − k0 N 1 ( z1 )
J 1 ( z2 ) − k3 N 1 ( z2 ) −
− J 1 ( z2 ) − k3 N 1 ( z2 ) J 1 ( z1 ) − k0 N 1 ( z1 ) = 0.
(24)
For given parameters of the double wall tube r0 , r1 , r2 , r3 , the obtained relation is the equation for the constant κ . Let κ be a root of Eq. (24), then the equality
ω = c t k2 + κ 2
(25)
defines the dispersion relation. The phase velocity of rotational waves v := ω/k is easily found from dispersion relation (25):
v = ct 1 +
κ2 k2
.
(26)
The group velocity is also easily found
v g :=
dω dk
2
c = t. v
Acknowledgement This work was supported by the Russian Science Foundation (project 14-11-00687) in Steklov Mathematical Institute.
On the gluing surface, we impose two conditions: entirety and equality of stresses,
W in (r∗ ) = W ex (r∗ ),
functions, the three dimensional Einstein equations are well defined [17]. Afterwards propagation of rotational waves in double wall tube is described. The presence of the cylindrical dislocation inside the double wall tube leads to changing of the dispersion relation. Double wall tube may be useful as a continuous model of double wall nanotubes.
(27)
We see that the phase velocity of rotational waves is always greater than the velocity of transverse waves, and group velocity is smaller. Dispersion relation (25) does depend on double wall parameters through Eq. (24). 2. Conclusion We found the induced metric in double wall tube with cylindrical dislocation in the framework of the geometrical theory of defect. Though components of this metric are not continuous
References [1] K. Kondo, On the geometrical and physical foundations of the theory of yielding, in: Proc. 2nd Japan Nat. Congr. Applied Mechanics, Tokyo, 1952, pp. 41–47. [2] J.F. Nye, Some geometrical relations in dislocated media, Acta Metall. 1 (1953) 153. [3] B.A. Bilby, R. Bullough, E. Smith, Continuous distributions of dislocations: a new application of the methods of non-Riemannian geometry, Proc. R. Soc. Lond. A 231 (1955) 263–273. [4] E. Kröner, Kontinums Theories der Versetzungen und Eigenspanungen, Springer-Verlag, Berlin–Heidelberg, 1958. [5] L.I. Sedov, V.L. Berditchevski, A dynamical theory of dislocations, in: E. Kröner (Ed.), Mechanics of Generalized Continua, IUTAM Symposium, 1967, pp. 214–238. [6] M. Kléman, The general theory of dislocations, in: F.R.N. Nabarro (Ed.), Dislocations in Solids, vol. 5, North-Holland Publishing Company, Amsterdam, 1980, pp. 243–297. [7] E. Kröner, Continuum theory of defects, in: R. Balian, et al. (Eds.), Les Houches, Session XXXV, 1980 – Physics of Defects, North-Holland Publishing Company, 1981, pp. 282–315. [8] I.E. Dzyaloshinskii, G.E. Volovik, Poisson brackets in condensed matter physics, Ann. Phys. 125 (1) (1988) 67. ´ D.G.B. Edelen, A Gauge Theory of Dislocations and Disclinations, [9] A. Kadic, Springer-Verlag, Berlin–Heidelberg, 1983. [10] I.A. Kunin, B.I. Kunin, Gauge theories in mechanics, in: Trends in Application of Pure Mathematics to Mechanics, in: Lect. Notes Phys., vol. 249, Springer-Verlag, Berlin–Heidelberg, 1986, pp. 246–249. [11] H. Kleinert, Gauge Fields in Condensed Matter, vol. 2, World Scientific, Singapore, 1990. [12] M.O. Katanaev, I.V. Volovich, Theory of defects in solids and three-dimensional gravity, Ann. Phys. 216 (1) (1992) 1–28. [13] M.O. Katanaev, I.V. Volovich, Scattering on dislocations and cosmic strings in the geometric theory of defects, Ann. Phys. 271 (1999) 203–232. [14] M.O. Katanaev, Geometric theory of defects, Phys. Usp. 48 (7) (2005) 675–701. [15] M.O. Katanaev, Wedge dislocation in the geometric theory of defects, Theor. Math. Phys. 135 (2) (2003) 733–744. [16] M.O. Katanaev, One-dimensional topologically nontrivial solutions in the Skyrme model, Theor. Math. Phys. 138 (2) (2004) 163–176. [17] G. de Berredo-Peixoto, M.O. Katanaev, Tube dislocations in gravity, J. Math. Phys. 50 (2009) 042501, arXiv:0810.0243 [gr-qc]. [18] G. de Berredo-Peixoto, M.O. Katanaev, E. Konstantinova, I.L. Shapiro, Schrödinger equation in the space with cylindrical geometric defect and possible application to multi-wall nanotubes, Nuovo Cimento B 125 (8) (2010) 915–931, arXiv:1010.2913 [cond-mat.mes-hall]. [19] M.O. Katanaev, Rotational elastic waves in cylindrical waveguide with wedge dislocation, arXiv:1502.07935 [cond-mat.mtrl-sci], 2015. [20] A.S. Ebessen (Ed.), Carbon Nanotubes. Preparation and Properties, CRC Press, Boca Raton–New York–London–Tokyo, 1997. [21] R. Saito, G. Dresselhaus, M.S. Dresselhaus, Physical Properties of Carbon Nanotubes, Imperial College, London, 1998. [22] P.J.F. Harris, Carbon Nanotubes and Related Structures: New Materials for the Twenty-First Century, Cambridge University Press, Cambridge, 1999. [23] E. Janke, F. Emde, F. Lösch, Tafeln Höherer Funktionen, sechste edition, B.G. Teubner Verlagsgesellschaft, Stuttgart, 1960.