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SPECIAL ISSUE CONTENTS PAGE
Applied Catalysis A: General 256 (2003) vi–vii
Special Issue
Heteropoly Acids Contents Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1
Friedel^Crafts acylation and related reactions catalysed by heteropoly acids I.V. Kozhevnikov (UK). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3
Review^Acid catalysis by heteropoly acids M.N. Timofeeva (Russia) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
19
The state of the art on Wells^Dawson heteropoly-compounds. A review of their properties and applications L.E. Briand, G.T. Baronetti and H.J. Thomas (Argentina) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
37
A computational and experimental study of anhydrous phosphotungstic acid and its interaction with water molecules M.J. Janik, K.A. Campbell, B.B. Bardin, R.J. Davis and M. Neurock (USA) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
51
Anchored homogeneous catalysts: the role of the heteropoly acid anchoring agent R.L. Augustine, S.K. Tanielyan, N. Mahata, Y. Gao, A. Zsigmond and H. Yang (USA) . . . . . . . . . . . . . . . . . . . . . . . . .
69
Heteropolyacid (HPA)-polymer composite films as heterogeneous catalysts and catalytic membranes I.K. Song and W.Y. Lee (South Korea) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
77
Immobilization of heteropoly acids in the network structure of carbon gels S.R. Mukai, T. Sugiyama and H. Tamon (Japan) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
99
Improvement of the preparation method of ‘‘ship-in-the-bottle’’ type 12-molybdophosphoric acid encaged Y-type zeolite catalysts S.R. Mukai, M. Shimoda, L. Lin, H. Tamon and T. Masuda (Japan). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
107
Heteropoly compounds incorporated into mesoporous material structure K. Nowin¤ska, R. Fo¤rmaniak, W. Kaleta and A. Wa˛cław (Poland) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
115
Supported Keggin type heteropolycompounds for ecofriendly reactions L.R. Pizzio, P.G. Va¤zquez, C.V. Ca¤ceres and M.N. Blanco (Argentina) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
125
Catalytic performance of the dodecatungstophosphoric acid on different supports J. Haber, K. Pamin, L. Matachowski and D. Mucha (Poland). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
141
The formation of MTBE on supported and unsupported H4SiW12O40 A. Bielan¤ski, A. Lubanska, J. Pozniczek and A. Micek-Ilnicka (Poland) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
153
Catalytic properties of heteropoly acid/zeolite hybrid materials: toluene disproportionation and transalkylation with 1,2,4-trimethylbenzene B. Sulikowski and R. Rachwalik (Poland) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
173
Immobilization of 12-molybdophosphoric and 12-tungstophosphoric acids on metal-substituted hexagonal mesoporous silica S. Damyanova, L. Dimitrov, R. Mariscal, J.L.G. Fierro, L. Petrov and I. Sobrados (Bulgaria, Spain) . . . . . . . . . . . . . . .
183
doi:10.1016/S0926-860X(03)00961-X
Contents
vii
An efficient method for acetolysis of cyclic ethers catalyzed by heteropolyacid Y. Izumi, K. Iida, K. Usami and T. Nagata (Japan) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
199
Synthesis of dimethyl carbonate from methanol and carbon dioxide in the presence of polyoxometalates under mild conditions C. Jiang, Y. Guo, C. Wang, C. Hu, Y. Wu and E. Wang (PR China) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
203
Microporous heteropoly compounds and their shape selective catalysis T. Okuhara (Japan) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
213
Mechanism of propene hydration over heteropolyacid catalysts A.V. Ivanov, E. Zausa, Y. Ben Taa“rit and N. Essayem (Russia, France) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
225
1
n-Butane isomerization over Cs-salts of H3PW12O40: a mechanistic study by C MAS NMR Z. Ma, W. Hua, Y. Ren, H. He and Z. Gao (PR China) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
243
Properties of Cs2.5 salts of transition metal M substituted Keggin-type M1 xPV1MxMo11 xO40 heteropolyoxometallates in propane oxidation N. Dimitratos and J.C. Ve¤drine (UK, France) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
251
Selective oxidation of limonene over sodium salt of cobalt containing sandwich-type polyoxotungstate [WCo3(H2O)2{W9CoO34}2]10 N.K. Kala Raj, V.G. Puranik, C. Gopinathan and A.V. Ramaswamy (India) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
265
Chemical^physical characterization of Fe-doped, Keggin-type P/Mo polyoxometalates, catalysts for the selective oxidation of isobutane to methacrylic acid E. Etienne, F. Cavani, R. Mezzogori, F. Trifiro', G. Calestani, L. Gengembre and M. Guelton (France, Italy) . . . . . . . . . .
275
The structure of molybdenum-heteropoly acids under conditions of gas-phase selective oxidation catalysis: a multi-method in situ study F.C. Jentoft, S. Klokishner, J. Kro«hnert, J. Melsheimer, T. Ressler, O. Timpe, J. Wienold and R. Schlo«gl (Germany) . . . .
291
Calendar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
319
Author Index of Volume 256 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
320
Subject Index of Volume 256 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
323
Special Issue
Heteropoly Acids Contents Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1
Friedel^Crafts acylation and related reactions catalysed by heteropoly acids I.V. Kozhevnikov (UK). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3
Review^Acid catalysis by heteropoly acids M.N. Timofeeva (Russia) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
19
The state of the art on Wells^Dawson heteropoly-compounds. A review of their properties and applications L.E. Briand, G.T. Baronetti and H.J. Thomas (Argentina) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
37
A computational and experimental study of anhydrous phosphotungstic acid and its interaction with water molecules M.J. Janik, K.A. Campbell, B.B. Bardin, R.J. Davis and M. Neurock (USA) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
51
Anchored homogeneous catalysts: the role of the heteropoly acid anchoring agent R.L. Augustine, S.K. Tanielyan, N. Mahata, Y. Gao, A. Zsigmond and H. Yang (USA) . . . . . . . . . . . . . . . . . . . . . . . . .
69
Heteropolyacid (HPA)-polymer composite films as heterogeneous catalysts and catalytic membranes I.K. Song and W.Y. Lee (South Korea) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
77
Immobilization of heteropoly acids in the network structure of carbon gels S.R. Mukai, T. Sugiyama and H. Tamon (Japan) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
99
Improvement of the preparation method of ‘‘ship-in-the-bottle’’ type 12-molybdophosphoric acid encaged Y-type zeolite catalysts S.R. Mukai, M. Shimoda, L. Lin, H. Tamon and T. Masuda (Japan). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
107
Heteropoly compounds incorporated into mesoporous material structure K. Nowin¤ska, R. Fo¤rmaniak, W. Kaleta and A. Wa˛cław (Poland) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
115
Supported Keggin type heteropolycompounds for ecofriendly reactions L.R. Pizzio, P.G. Va¤zquez, C.V. Ca¤ceres and M.N. Blanco (Argentina) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
125
Catalytic performance of the dodecatungstophosphoric acid on different supports J. Haber, K. Pamin, L. Matachowski and D. Mucha (Poland). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
141
The formation of MTBE on supported and unsupported H4SiW12O40 A. Bielan¤ski, A. Lubanska, J. Pozniczek and A. Micek-Ilnicka (Poland) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
153
Catalytic properties of heteropoly acid/zeolite hybrid materials: toluene disproportionation and transalkylation with 1,2,4-trimethylbenzene B. Sulikowski and R. Rachwalik (Poland) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
173
Immobilization of 12-molybdophosphoric and 12-tungstophosphoric acids on metal-substituted hexagonal mesoporous silica S. Damyanova, L. Dimitrov, R. Mariscal, J.L.G. Fierro, L. Petrov and I. Sobrados (Bulgaria, Spain) . . . . . . . . . . . . . . .
183
doi:10.1016/S0926-860X(03)00961-X
Contents
vii
An efficient method for acetolysis of cyclic ethers catalyzed by heteropolyacid Y. Izumi, K. Iida, K. Usami and T. Nagata (Japan) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
199
Synthesis of dimethyl carbonate from methanol and carbon dioxide in the presence of polyoxometalates under mild conditions C. Jiang, Y. Guo, C. Wang, C. Hu, Y. Wu and E. Wang (PR China) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
203
Microporous heteropoly compounds and their shape selective catalysis T. Okuhara (Japan) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
213
Mechanism of propene hydration over heteropolyacid catalysts A.V. Ivanov, E. Zausa, Y. Ben Taa“rit and N. Essayem (Russia, France) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
225
1
n-Butane isomerization over Cs-salts of H3PW12O40: a mechanistic study by C MAS NMR Z. Ma, W. Hua, Y. Ren, H. He and Z. Gao (PR China) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
243
Properties of Cs2.5 salts of transition metal M substituted Keggin-type M1 xPV1MxMo11 xO40 heteropolyoxometallates in propane oxidation N. Dimitratos and J.C. Ve¤drine (UK, France) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
251
Selective oxidation of limonene over sodium salt of cobalt containing sandwich-type polyoxotungstate [WCo3(H2O)2{W9CoO34}2]10 N.K. Kala Raj, V.G. Puranik, C. Gopinathan and A.V. Ramaswamy (India) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
265
Chemical^physical characterization of Fe-doped, Keggin-type P/Mo polyoxometalates, catalysts for the selective oxidation of isobutane to methacrylic acid E. Etienne, F. Cavani, R. Mezzogori, F. Trifiro', G. Calestani, L. Gengembre and M. Guelton (France, Italy) . . . . . . . . . .
275
The structure of molybdenum-heteropoly acids under conditions of gas-phase selective oxidation catalysis: a multi-method in situ study F.C. Jentoft, S. Klokishner, J. Kro«hnert, J. Melsheimer, T. Ressler, O. Timpe, J. Wienold and R. Schlo«gl (Germany) . . . .
291
Calendar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
319
Author Index of Volume 256 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
320
Subject Index of Volume 256 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
323