Step-free wide-bandgap heteroepitaxy

Step-free wide-bandgap heteroepitaxy

Step-free wide-bandgap NASA’s Glenn ReXarch heteroepitaxy Center fdms by flattening (Cleveland, OH, USA) led by Philip Neudeck hexagonal - toget...

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Step-free wide-bandgap NASA’s Glenn ReXarch

heteroepitaxy

Center

fdms by flattening

(Cleveland, OH, USA) led by Philip Neudeck

hexagonal

- together with

scientists

from Ohio Aerospace

Institute

(Cleveland, OH, USA)

by changing temperature nucleation

have described throughs

NY, USA)

a

The films formed were free

-

both of defects propagated

two break-

from the substrate

that may enable more

reliable wide-bandgap

and

rate, depositing

thin film of cubic 3CSiC.

and the State University of New York (Stony Brook,

mesas of

4H- or 6H-Sic then,

and of pla-

nar defects, i.e. in the order

devices: SEM of thin lateral W-X cantilever emanating from mesa top after 30 minutes of growth. (Courtesy NASA Glenn)

(stacking

wafers by creating a pattern of

ing from adjacent legs grew

crystal nucleation

square, device-size

together to form a web cover-

stages is the likely cause of pla-

ing the area between

nar defects,” said Neudeck.

l

In 2000 the team announced

a web growth process

which

extends the size of atomically flat (or step-free)

commercial

mesas on

“For cubic SIC films, too rapid

the legs

ing the steps on those mesas to

and producing

the edges.

flat surface larger than the orig-

Unexpectedly

the crystals grew

laterally beyond the mesa edges and formed thin cantilevers overhanging

the sidewalls. For

open-geometry and crosses)

mesas (e.g. vees cantilevers

extend-

bound-

aries) of crystal planes.

areas on Sic

wafers, then grow-

faults) or alignment

(double positioning

an atomically

The team will use step-free surface heteroepitaxy

inal mesa (and possibly over areas containing

in the early

wide-bandgap

inherent

with other

films on hexago-

nal Sic to investigate

defects).

the feasi-

bility of industrial fabrication

More recently they created

a wider range of much

step-free surface heteroepitaxy,

improved wide-bandgap

l

eliminating

of

devices.

defects in deposited

__

More precise crystal growth university of

from one crystalAs

wisconsin-

Madison Materials Science Engineering

professor

and

Sindo

Kou ([email protected])

and

bottom of the crucible

a crystal

grows, it rejects impurities

into

holds a

solid material identical in com-

the melt, so the melt composi-

position

tion and therefore

the upper part holds the melt.

crystal com-

graduate student Jia-Jie He have

position

devised a method to ensure

They first lengthened

can change.

to the desired crystal;

As the crystal grows and the the cru-

melt level decreases,

an existing

cible in which the materials

mechanism

the growth of single-crystal

melt then added a low-tempera-

upward so that the solid materi-

alloy semiconductors

ture heater around the cru-

al gradually enters the high-

stant along its length, avoiding

cible’s lower half and moved

temperature

inconstencies

in performance

the existing high-temperature

and keeps the melt composi-

of devices made from wafers

heater to the upper halfThe

tion constant.

that the melt composition

in

stays con-

_____._.____-_._-__~--

pushes the crucible

heat zone, melts

----

3 inch Sic substrates Uniroyal Technology

Cooperative

pling 3” 6H-polytype

DAAD17-0O-C-0111).

semi-insulating Research

ADVANCED

SEMICONDUCTOR

expansion

3” 4H-polytype

semiconducting connection

SIC semi-

Laboratory

Contract/

Agreement

number

substrates.

by developing

’ ‘I

and US Army

Inc (Sarasota, FL, USA) is sam-

It plans to continue

REVIEW

F33615-99-C-5317 Research

conducting

Ill-Vs

Corp sub

sidiary Sterling Semiconductor

substrates substrates

and (in

with US Air Force Laboratory

MAGAZINE

Contract

VOL 15 - NO I

Sterling recently

extended

its

the expansion business

of semi-insulating

substrates.

pleted the sale of its Specialty Adhesives

segment

~~$2I.bm

- “another step in

for about

assets into the Compound for

of its Sic wafer

and its development

Corp

(Sarasota, FL, USA) has com-

the re-deployment of our

leases on its facilities in Danbury, CT and Sterling,VI,

* Uniroyal Technology

Semiconductor and Optoelectronics business segment,” says chairman Howard R Curd.

and CEO