Journal of Fluorine Chemistry 126 (2005) 1596–1618
Subject Index of Volume 126 Ab initio Theoretical study on the (O2-HF) complex, (126) 313 Acetaldehyde Fluorine-doped TiO2 powders prepared by spray pyrolysis and their improved photocatalytic activity for decomposition of gas-phase acetaldehyde, (126) 69 Acetonitrile complex Rapid and high yield oxidation of phosphine, phosphite and phosphinite compounds to phosphine oxides, phosphates and phosphinates using hypofluorous acid–acetonitrile complex, (126) 1054 acidic catalysis Hydrolysis in the system LiPF6—propylene carbonate—dimethyl carbonate—H2O, (126) 27 Acridines Synthesis of new fluorine-containing dihydrobenzo[c]acridines from trifluoroacetyl dihydronaphthalene and substituted anilines, (126) 1384 Acrylate Aza-Morita-Baylis-Hillman reactions of N-(benzylidene)polyfluoroanilines with methyl acrylate and acrylonitrile, (126) 1215 Acrylation Novel fluoroacrylated copolymers: synthesis, characterization and properties, (126) 231 Acrylonitrile Aza-Morita-Baylis-Hillman reactions of N-(benzylidene)polyfluoroanilines with methyl acrylate and acrylonitrile, (126) 1215 Activated magnesium Preparation of fluorohalomethylmagnesium halides using highly active magnesium metal and their reactions, (126) 1390 Acyl fluorides Synthesis of perfluorinated carboxylic acid membrane monomers by utilizing liquid-phase direct fluorination, (126) 521 Acyl nitroxide EPR studies on H-abstraction from p-substituted benzaldehydes by new “Magic Blue” reagents and correlation analysis of aN values of -fluorosulfonylperfluoroalkyl p-substituted benzoyl nitroxides, (126) 333 Acylsilane A direct and rapid route to ,-difluoroacylsilanes from trifluoroethanol, (126) 611 Additivity rule Surface tension of fluoroalkanes in a liquid phase, (126) 379 Adhesion Direct fluorination—Useful tool to enhance commercial properties of polymer articles, (126) 251 Adiabatic decoupling Carbon–fluorine two-dimensional NMR correlation spectra, (126) 363 Adsorption Isomerization reaction of 1,1,2,2-tetrafluorethan on fluorinated chromia: A consideration of the adsorption behavior on the catalyst, (126) 1017 Air-conditioning Regulating to reduce emissions of fluorinated greenhouse gases, (126) 1457
doi:10.1016/S0022-1139(05)00318-0
Air–water interface Critical influence of the alkane length in surface and liquid–crystalline properties of perfluorodecyl-n-alkanes, (126) 79 AlCl3 Polyfluoroaromatic compounds with a –NCClR group—a reactive type of polyfluoroarene, (126) 860 Alcohol Fluorinated phosphorus compounds. Part 9. The reactions of bis(fluoroalkyl) phosphorochloridates with oxygen nucleophiles, (126) 892 Fluorochromate-catalyzed periodic acid oxidation of alcohols and aldehydes, (126) 1356 Aldehyde Some studies on nucleophilic trifluoromethylation using the shelf-stable trifluoromethylacetophenone-N,N-dimethyltrimethylsilylamine adduct, (126) 491 First asymmetric synthesis of -amino--trifluoromethylated aldehyde, (126) 705 Synthesis of gem-difluorides from aldehydes using DFMBA, (126) 721 Fluorochromate-catalyzed periodic acid oxidation of alcohols and aldehydes, (126) 1356 Aldol condensations Aldol condensations of aldehydes and ketones catalyzed by rare earth(III) perfluorooctane sulfonates in fluorous solvents, (126) 1553 Alkali halides A novel and simple synthetic route to perfluoroalkylacetaldehydes using commercially available alkali halides and metal oxides, (126) 1493 Alkylaluminum Intramolecular Diels–Alder reaction of -fluoroacrylate derivatives promoted by novel bidentate aluminum Lewis acid, (126) 709 Alkylating agents New catalytic alkylation of in situ generated perfluoro-alkyloxy-anions and perfluoro-carbanions, (126) 1578 Alkylation Synthesis of ,-dimethoxyfluoropolyethers: reaction mechanism and kinetics, (126) 633 F-Alkyl oxiranes Regioselective ring opening of [(perfluoroalkyl)methyl] oxiranes with Nnucleophiles, (126) 1274 Alkylphosphocholine Synthesis and characterization of photolabeling probes of miltefosine, (126) 739 Alkynyl dipolarophiles Highly fluoroalkylated amphiphilic triazoles: Regioselective synthesis and evaluation of physicochemical properties, (126) 715 Allylation A novel synthesis of fluorine-containing quaternary amino acid derivatives via palladium-catalyzed allylation reaction, (126) 1517 Amine First asymmetric synthesis of -amino--trifluoromethylated aldehyde, (126) 705 Mitsunobu synthesis of symmetrical alkyl and polyfluoroalkyl secondary amines, (126) 1524
Subject Index of Volume 126 Amine–HF complexes Selective anodic fluorination of electrophilic alkenes, (126) 753 Amino acid One-pot three-component reaction of C60, amino acid and fluorinated benzaldehyde to C60-pyrrolidine derivatives, (126) 349 Asymmetric synthesis of both enantiomers of syn-(3-trifluoromethyl)cysteine derivatives, (126) 499 Amino acid fluoroallylesters Synthesis of -fluoro--amino acids by Claisen rearrangement, (126) 557 Aminoalcohols Nucleophilic trifluoromethylation. Some recent reagents and their stereoselective aspects, (126) 173 Regioselective ring opening of [(perfluoroalkyl)methyl] oxiranes with N-nucleophiles, (126) 1274 2-Aminophenol Synthesis of 2,3-bis(perfluoroalkyl)quinoxalines and 2,3-bis(perfluoroalkyl)-1,4-benzoxazines from oxides of internal perfluoroolefins, (126) 976 6-Amino--cyclodextrin Synthesis of a new fluorinated fluorescent -cyclodextrin sensor, (126) 393 Aminophosphonate Synthesis and bioactivity of fluorine compounds containing isoxazolylamino and phosphonate groups, (126) 1419 Ammonium perfluorooctanoate Gas-phase NMR studies of the thermolysis of perfluorooctanoic acid, (126) 1510 Amphiphiles Spontaneous vesicles of single-chain sugar-based fluorocarbon surfactants, (126) 33 Characterization of hydrocarbon and fluorocarbon microdomains formed in aqueous solution of associative polymers: A molecular probe technique, (126) 1409 Amphiphilic Novel fluorinated block copolymer architectures fuelled by atom transfer radical polymerization, (126) 241 Anesthetics Fluorine chemistry at the millennium, (126) 157 Anilines Electrophilic aromatic fluorination with fluorine: meta-Directed fluorination of anilines, (126) 661 Anion binding agent Second sphere coordination in anion binding: Synthesis, spectroscopic characterization and single crystal X-ray structure determination of hexaamminecobalt(III) dichloride tetrafluoroborate, (126) 1543 Anode Surface-fluorinated graphite anode materials for Li-ion batteries, (126) 1111 Anode consumption Anodic behavior of nickel-based alloys in the electrolytic production of NF3, (126) 1101 Anodic fluorination Highly selective electrochemical fluorination of organic compounds in ionic liquids, (126) 181 Antibacterial activity Synthesis and biological activity of fluorinated 2-amino-4-aryl-3,4-dihydro[1,3,5]triazino[1,2-a]benzimidazoles, (126) 759 Synthesis and structure-activity relationship (SAR) of novel perfluoroalkylcontaining quaternary ammonium salts, (126) 1425 Antifungicidal activity Synthesis and fungicidal activity of fluorine-containing phenylimino-thiazolidines derivatives, (126) 297 Antimony pentafluoride Formation and skeletal transformations of perfluoroindan-1-one and perfluoroindan-1,3-dione in the reaction of perfluoroindan with SiO2/SbF5, (126) 437 Anti-progestins Beneficial effects of fluorine in the anti-progestin ZK 230211, (126) 217 Antitumor activity Synthesis and bioactivity of fluorine compounds containing isoxazolylamino and phosphonate groups, (126) 1419
1597
Antitumor bioactivity Synthesis and bioactivity of 2-cyanoacrylates containing a trifluoromethylphenyl moiety, (126) 87 Arene–perfluoroarene interactions 1:1 Complexes of octafluoronaphthalene with trans-stilbene and transazobenzene, (126) 515 Aromatic amines Facile synthesis of 2,2,2-trifluoroacetimidoyl chloride derivatives, (126) 1140 Aromatic interactions Supramolecular synthons in crystals of partially fluorinated fused aromatics: 1,2,3,4-Tetrafluoronaphthalene and its aza-analogue 1,3,4-trifluoroisoquinoline, (126) 1281 Aromatic perfluorocarbons A simple calculational model for predicting the site for nucleophilic substitution in aromatic perfluorocarbons, (126) 727 Arsenic pentafluoride A detailed account of a convenient lab-scale preparation of AsF5 via direct fluorination of AsF3, (126) 1368 A laboratory-scale synthesis of high-purity AsF5 by direct fluorination of AsF3, (126) 1373 Arsenic trifluoride A detailed account of a convenient lab-scale preparation of AsF5 via direct fluorination of AsF3, (126) 1368 A laboratory-scale synthesis of high-purity AsF5 by direct fluorination of AsF3, (126) 1373 Arsenic(V) fluoride Synthesis of arsenic pentafluoride by static fluorination of As2O3 in a closed system, (126) 1432 1-Aryl-1,2,2,2-tetrafluoroethane An efficient dehyrohalogenation method for the synthesis of ,,-trifluorostyrenes, -chloro-,-difluorostyrenes and E-1-arylperfluoroalkenes, (126) 1174 1-(Aryloxy)-2-chloro-1,2-difluoroethenes Synthesis and some chemical properties of 1-aryloxy-2-chloro-1,2-difluoroethenes, (126) 1307 1-Arylperfluoroalkene An efficient dehyrohalogenation method for the synthesis of ,,-trifluorostyrenes, -chloro-,-difluorostyrenes and E-1-arylperfluoroalkenes, (126) 1174 Aryl and alkyl stannanes Fluorinated stannanes. Part 2. The stereospecific synthesis of fluorinated stannanes via a Barbier-type reaction between fluorinated halides and tributyltin chloride mediated by zinc or cadmium, (126) 797 Arylboronic acids One-pot synthesis of bromodifluoroacetimidoyl halides and its Suzuki coupling reactions with aryl boronic acids, (126) 791 Asymmetric synthesis Asymmetric synthesis of both enantiomers of syn-(3-trifluoromethyl)cysteine derivatives, (126) 499 Asymmetric synthesis of -monofluoromethyl- and -difluoromethylbenzylamines through regioselective hydrogenolysis, (126) 385 First asymmetric synthesis of -amino--trifluoromethylated aldehyde, (126) 705 ATRP Novel fluorinated block copolymer architectures fuelled by atom transfer radical polymerization, (126) 241 Autocatalytic reaction Fluoride-induced nucleophilic (phenylthio)difluoromethylation of carbonyl compounds with [difluoro(phenylthio)methyl]trimethylsilane (TMS–CF2SPh), (126) 529 Axial dissymmetry Recycling of fluorinated axially dissymmetric ligand with fluorous solvent, (126) 415 8-Aza- and 1-thiochromones Nucleophilic trifluoromethylation of RF-containing 4-quinolones, 8-azaand 1-thiochromones with (trifluoromethyl)trimethylsilane, (126) 779
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Subject Index of Volume 126
Aza-Morita-Baylis-Hillman reactions Aza-Morita-Baylis-Hillman reactions of N-(benzylidene)polyfluoroanilines with methyl acrylate and acrylonitrile, (126) 1215 Barbier reactions Fluorinated stannanes. Part 2. The stereospecific synthesis of fluorinated stannanes via a Barbier-type reaction between fluorinated halides and tributyltin chloride mediated by zinc or cadmium, (126) 797 Benzoacridines Synthesis of new fluorine-containing dihydrobenzo[c]acridines from trifluoroacetyl dihydronaphthalene and substituted anilines, (126) 1384 Benzoxazole Syntheses of new difluoromethylene benzoxazole and 1,2,4-oxadiazole derivatives, as potent non-nucleoside HIV-1 reverse transcriptase inhibitors, (126) 535 BF3 A B3LYP study for the adsorption and catalytic ability of BF3 on NiO(0 0 1) surface, (126) 1463 Bidentate Lewis acid Intramolecular Diels–Alder reaction of -fluoroacrylate derivatives promoted by novel bidentate aluminum Lewis acid, (126) 709 1,1-Biphenyl-2,2-diol derivative Intramolecular Diels–Alder reaction of -fluoroacrylate derivatives promoted by novel bidentate aluminum Lewis acid, (126) 709 2,2-Bis(3-allyl-4-hydroxyphenyl)hexafluoropropane 2,2-Bis(3-allyl-4-hydroxyphenyl)hexafluoropropane and fluorosiloxane as coating materials for nerve agent sensors, (126) 1252 2,2-Bis(4-allyoxyphenyl)hexafluoropropane 2,2-Bis(3-allyl-4-hydroxyphenyl)hexafluoropropane and fluorosiloxane as coating materials for nerve agent sensors, (126) 1252 2,3-Bis(perfluoroalkyl)-1,4-benzoxazines Synthesis of 2,3-bis(perfluoroalkyl)quinoxalines and 2,3-bis(perfluoroalkyl)-1,4-benzoxazines from oxides of internal perfluoroolefins, (126) 976 2,3-Bis(perfluoroalkyl)quinoxalines Synthesis of 2,3-bis(perfluoroalkyl)quinoxalines and 2,3-bis(perfluoroalkyl)-1,4-benzoxazines from oxides of internal perfluoroolefins, (126) 976 Bis(fluoroalkyl) alkyl phosphate Fluorinated phosphorus compounds. Part 9. The reactions of bis(fluoroalkyl) phosphorochloridates with oxygen nucleophiles, (126) 892 Bis(fluoroalkyl) N-(fluoroalkyl)phosphoramidate Fluorinated phosphorus compounds. Part 11. The reactions of some fluorinated amines with dialkyl and bis(fluoroalkyl) phosphorochloridates, (126) 1144 Bis(fluoroalkyl) phosphite Fluorinated phosphorus compounds. Part 10. Bis(fluoroalkyl) S-alkyl phosphorothiolates and tris(fluoroalkyl) phosphorothionates, (126) 902 Bis(fluoroalkyl) phosphorochloridate Fluorinated phosphorus compounds. Part 9. The reactions of bis(fluoroalkyl) phosphorochloridates with oxygen nucleophiles, (126) 892 Bis(fluoroalkyl) S-alkyl phosphorothiolate Fluorinated phosphorus compounds. Part 10. Bis(fluoroalkyl) S-alkyl phosphorothiolates and tris(fluoroalkyl) phosphorothionates, (126) 902 Bis(imino)sulfinates [P3N3F5NS(O)Cl] and [{P4N4F6(NS(Cl)N)}2]2, the first chloro iminoand chloro bis(imino) sulfinates, (126) 1044 Bis(trifluoroethyl) phosphorofluoridate Fluorinated phosphorus compounds. Part 10. Bis(fluoroalkyl) S-alkyl phosphorothiolates and tris(fluoroalkyl) phosphorothionates, (126) 902 Bis{perfluoro[1-(2-fluorosulfonyl)ethoxy]ethyl}nitroxide EPR studies on H-abstraction from methylbenzenes by “magic blue” reagent, (126) 1130 Block copolymers Novel fluorinated block copolymer architectures fuelled by atom transfer radical polymerization, (126) 241 Boiling point Synthesis of novel lipophilic and/or fluorophilic ethers of perfluoro-tertbutyl alcohol, perfluoropinacol and hexafluoroacetone hydrate via a Mitsunobu reaction: Typical cases of ideal product separation, (126) 641
Bond dissociation energy Thermal stability and bond dissociation energy of fluorinated polymers: A critical evaluation, (126) 625 Boron trifluoride Highly fluorinated graphite prepared from graphite fluoride formed using BF3 catalyst, (126) 1078 Brönsted acid Comparative study of the ring opening of 1-CF3-epoxy ethers mediated by Brönsted acids and hexafluoro-2-propanol, (126) 551 Bromination New derivatives of poly-hexafluoropropylene oxide from the corresponding alcohol, (126) 281 Bromine trifluoride From ketones, aldehydes or alkyl halides to terminal 1,1-difluoroolefins using BrF3, (126) 1239 1-Bromo-1-fluoroalkene Chromium-mediated fluoroalkenylation reactions of 1,1-dibromo-1-fluoroalkane and 1-bromo-1-fluoroalkene derivatives, (126) 1166 Bromodifluoroacetimidoyl halide One-pot synthesis of bromodifluoroacetimidoyl halides and its Suzuki coupling reactions with aryl boronic acids, (126) 791 Bromodifluoromethyl phenyl sulfone Nucleophilic difluoromethylation and difluoromethylenation using bromodifluoromethyl phenyl sulfone, (126) 1361 Bromoester macroinitiators Novel fluorinated block copolymer architectures fuelled by atom transfer radical polymerization, (126) 241 Bromofluorination of alkene A mild method for halofluorination of alkenes with ionic liquid EMIMF(HF)2.3, (126) 121 -Butyrolactones A convenient synthesis of fluoroalkylated -butyrolactones from polyfluoroalkyl iodides and 4-pentenoic acid catalyzed by Pd(PPh3)4, (126) 319 113C 19F
and 13C spectra of fluorinated and partially fluorinated vinyl alkyl ethers, (126) 397 13C–19F coupling constants Carbon–fluorine two-dimensional NMR correlation spectra, (126) 363 C,N-ligand Double-C,N-chelated tri- and diorganotin(IV) fluorides, (126) 1531 C60 One-pot three-component reaction of C60, amino acid and fluorinated benzaldehyde to C60-pyrrolidine derivatives, (126) 349 C60F18 Novel facile routes for synthesis and isolation of fluorofullerenes C60F18 and C60F20 based on commercially available fluorinating reagents, (126) 1559 C60F20 Novel facile routes for synthesis and isolation of fluorofullerenes C60F18 and C60F20 based on commercially available fluorinating reagents, (126) 1559 C60F36 Novel facile routes for synthesis and isolation of fluorofullerenes C60F18 and C60F20 based on commercially available fluorinating reagents, (126) 1559 C60-pyrrolidines One-pot three-component reaction of C60, amino acid and fluorinated benzaldehyde to C60-pyrrolidine derivatives, (126) 349 Calcium hexafluoroarsenate Alkaline earth metal poly(hydrogen fluorides) hexafluoroarsenates(V) and hexafluorophosphate(V): M2(H2F3)(HF2)2(AF6) (M = Ca, A = As; M = Sr, A = As, P), (126) 1088 Calcium hydroxyapatite Synthesis of phosphate-type fluorocarbon–hydrocarbon hybrid surfactants and their adsorption onto calcium hydroxyapatite, (126) 301 Calculational method A simple calculational model for predicting the site for nucleophilic substitution in aromatic perfluorocarbons, (126) 727
Subject Index of Volume 126 Carbanion process Study the reactions of fluoroalkanesulfonyl azides with N-alkylindoles, (126) 113 Carbon electrode Surface fluorination and electrochemical behavior of petroleum cokes graphitized at medium and high temperatures for secondary lithium battery, (126) 1028 Carbon nucleophiles Reaction of octafluorocyclopentene with various carbon nucleophiles, (126) 125 Carbonimidoyl dichlorides Polyfluoroaromatic compounds with a –NCClR group—a reactive type of polyfluoroarene, (126) 860 Carbonyl compounds Fluoride-induced nucleophilic (phenylthio)difluoromethylation of carbonyl compounds with [difluoro(phenylthio)methyl]trimethylsilane (TMS–CF2SPh), (126) 529 The catalytic olefination reaction of aldehydes and ketones with CBr3CF3, (126) 907 Trifluoromethylation of carbonyl compounds with sodium trifluoroacetate, (126) 937 Carboxylic acids Fluorochromate-catalyzed periodic acid oxidation of alcohols and aldehydes, (126) 1356 Cast membrane Synthesis and characterization of fluorinated copolyetherimides with –CH2–C6F13 side chains based on the ULTEM™ structure, (126) 1476 Catalysis The catalytic olefination reaction of aldehydes and ketones with CBr3CF3, (126) 907 Fluorochromate-catalyzed periodic acid oxidation of alcohols and aldehydes, (126) 1356 Catalytic ability A B3LYP study for the adsorption and catalytic ability of BF3 on NiO(0 0 1) surface, (126) 1463 C–C bond formation Synthesis of 2-chloro-1,1-difluoroallyl mesylates through novel rearrangement and C–C bond formation by their Pd-catalyzed reaction with diethylzinc, (126) 765 CCSD Theoretical study on the (O2-HF) complex, (126) 313 C–F bond activation A rich chemistry of fluorinated imidoyl halides, (126) 165 Characterization Novel fluoroacrylated copolymers: synthesis, characterization and properties, (126) 231 -Branched-perfluorodiacyl peroxides: preparation and characterization, (126) 587 Synthesis and characterization of soluble polyimides based on trifluoromethylated aromatic dianhydride and substitutional diaminetriphenylmethanes, (126) 819 Chemical state analysis Chemical state analysis of fluorine in various compounds using X-ray fluorescence spectra, (126) 1048 Chiral Recycling of fluorinated axially dissymmetric ligand with fluorous solvent, (126) 415 Chiral auxiliary New derivatives of trifluoroacetyl acetaldehyde and trifluoroaldol, (126) 355 New derivatives of trifluoroacetyl acetaldehyde and trifluoroaldol, (126) 543 Chiral derivatizing agent Synthesis, reactions, and applications of fluorine-containing multifunctional carbon compounds, (126) 941 Chiral fluorinated compounds Synthesis of stereocontrolled ,-difluoro--hydroxycarbonyl materials, (126) 17
1599
Chiral recognition Intermolecular-medium and intramolecular-weak hydrogen bonding chains in the crystals of chiral trifluoromethylated amino alcohols, (126) 1134 -Chloro-,-difluorostyrene Room temperature preparation of -chloro-,-difluoroethenylzinc reagent (CF2CClZnCl) by the metallation of HCFC-133a (CF3CH2Cl) and a high yield one-pot synthesis of -chloro-,-difluorostyrenes, (126) 833 1-Chloro-1-aryl-2,2,2-trifluoroethane An efficient dehyrohalogenation method for the synthesis of ,,-trifluorostyrenes, -chloro-,-difluorostyrenes and E-1-arylperfluoroalkenes, (126) 1174 1-Chloro-2,2,2-trifluoroethane propenyl sulfones An easy preparation of per- and poly-fluoroalkyl propenyl sulfones, (126) 877 1-Chloro-2,2-difluorostyrene An efficient dehyrohalogenation method for the synthesis of ,,-trifluorostyrenes, -chloro-,-difluorostyrenes and E-1-arylperfluoroalkenes, (126) 1174 Chloroacetylenes Re-identification of C3HClF2 by analysis of its Diels-Alder products, (126) 1549 Chlorodifluoromethylation Synthesis of lactones with a chlorodifluoromethyl group, (126) 135 Chlorodifluorovinyllithium Room temperature preparation of -chloro-,-difluoroethenylzinc reagent (CF2CClZnCl) by the metallation of HCFC-133a (CF3CH2Cl) and a high yield one-pot synthesis of -chloro-,-difluorostyrenes, (126) 833 Chlorodifluorovinylzinc Room temperature preparation of -chloro-,-difluoroethenylzinc reagent (CF2CClZnCl) by the metallation of HCFC-133a (CF3CH2Cl) and a high yield one-pot synthesis of -chloro-,-difluorostyrenes, (126) 833 Chromium chloride Chromium-mediated fluoroalkenylation reactions of 1,1-dibromo-1-fluoroalkane and 1-bromo-1-fluoroalkene derivatives, (126) 1166 Cobalt fluoride Investigation of reactions between [60]fullerene and molecular fluorine in a CoF2 matrix, (126) 785 Cobalt(III) First X-ray structure of hexaamminecobalt(III) salt with complex fluoroanion: Synthesis and characterization of [Co(NH3)6]X·SiF6·nH2O, where X = Cl, Br, I and NO3 and crystal structure of [Co(NH3)6]Cl·SiF6·2H2O, (126) 967 Second sphere coordination in anion binding: Synthesis, spectroscopic characterization and single crystal X-ray structure determination of hexaamminecobalt(III) dichloride tetrafluoroborate, (126) 1543 Cocatalysis hypervalent anions of tin Cocatalysis in phase-transfer catalyzed fluorination of alkyl halides and sulfonates, (126) 209 Cohesion parameters Synthesis of novel lipophilic and/or fluorophilic ethers of perfluoro-tertbutyl alcohol, perfluoropinacol and hexafluoroacetone hydrate via a Mitsunobu reaction: Typical cases of ideal product separation, (126) 641 Complex Theoretical study on the (O2-HF) complex, (126) 313 Conductivity New ionic liquids with tris(perfluoroalkyl)trifluorophosphate (FAP) anions, (126) 1150 Conjugated diene Stereoselective synthesis of insect sex pheromone analogs having a fluorine atom on their double bonds, (126) 1185 Contact angle Novel fluorinated block copolymer architectures fuelled by atom transfer radical polymerization, (126) 241 Contact angle hysteresis Surface immobilization of perfluorinated acrylate copolymers by selfcrosslinking, (126) 1570
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Subject Index of Volume 126
Coordination chemistry Synthesis and coordination chemistry of perfluoroalkylated dithiophosphate ligands, (126) 507 Synthesis and coordination chemistry of fluorinated xanthate ligands, (126) 1117 Copolymerisation Radical solution copolymerisation of vinylidene fluoride with hexafluoropropene, (126) 577 Copolymerization Novel fluoroacrylated copolymers: synthesis, characterization and properties, (126) 231 Copper The catalytic olefination reaction of aldehydes and ketones with CBr3CF3, (126) 907 Copper hexafluoroantimonate Copper(I) hexafluoroantimonate – an example of a compound with CuI in a solely fluorine environment, (126) 803 Copper monofluoride Copper(I) hexafluoroantimonate – an example of a compound with CuI in a solely fluorine environment, (126) 803 Correlation analysis EPR studies on H-abstraction from p-substituted benzaldehydes by new “Magic Blue” reagents and correlation analysis of aN values of -fluorosulfonylperfluoroalkyl p-substituted benzoyl nitroxides, (126) 333 Coumarin Direct fluorination of coumarin, 6-methyl-coumarin and 7-alkoxycoumarins, (126) 1377 Cross-coupling reaction Stereoselective synthesis of insect sex pheromone analogs having a fluorine atom on their double bonds, (126) 1185 Crystal engineering Pentaerythritol tetrakis(4-iodo-2,3,5,6-tetrafluorophenyl) ether: a tecton for the self-assembly of double strand 1D infinite chains, (126) 197 Supramolecular synthons in crystals of partially fluorinated fused aromatics: 1,2,3,4-Tetrafluoronaphthalene and its aza-analogue 1,3,4-trifluoroisoquinoline, (126) 1281 Crystal structure 1:1 Complexes of octafluoronaphthalene with trans-stilbene and transazobenzene, (126) 515 Copper(I) hexafluoroantimonate – an example of a compound with CuI in a solely fluorine environment, (126) 803 Alkaline earth metal poly(hydrogen fluorides) hexafluoroarsenates(V) and hexafluorophosphate(V): M2(H2F3)(HF2)2(AF6) (M = Ca, A = As; M = Sr, A = As, P), (126) 1088 Two tantalum fluorides templated with tren: [H4tren](TaF7)2·H2O and [H4tren](TaF7)2, (126) 1246 Current efficiency for formation of nitrogen trifluoride Anodic behavior of nickel-based alloys in the electrolytic production of NF3, (126) 1101 2-Cyanoacrylates Synthesis and herbicidal activity of 2-cyano-3-(2-fluoro-5-pyridyl)methylaminoacrylates, (126) 345 Cyclen Acyclic tertiary diamines and 1,4,7,10-tetraazacyclododecane with fluorine-containing -diketones: Leading to low melting ionic adducts, (126) 1222 Cyclizations Synthesis and the reactions of trifluoromethylated 1,2,3-triketones 2(het)arylhydrazones and 4,7-dihydroazolo[5,1-c]triazines, (126) 1230 Cycloaddition to: tetrafluoroethylene, hexafluoropropene, F-butene-2, F-2methylpentene-2, tetrakis(trifluoromethyl)ethylene Cycloaddition reaction of quadricyclane and fluoroolefins, (126) 601 Cycloalkanones Synthesis, 17O NMR spectroscopy and structure of 2-trifluoroacetyl-1methoxycycloalkenes, (126) 1396 Cyclocondensation Synthesis and biological activity of fluorinated 2-amino-4-aryl-3,4-dihydro[1,3,5]triazino[1,2-a]benzimidazoles, (126) 759
Cyclohexene Convenient synthesis of fluorinated alkanes and cycloalkanes by hydrogenation of perfluoroalkylalkenes under ultrasound irradiation, (126) 1347 1,3-Cyclohexadiene An unusual fluoroketene reaction product, (126) 1496 Cyclopolymerization Perfluorocyclobutyl (PFCB) aromatic polyethers: Synthesis and characterization of new sulfonimide containing monomers and fluoropolymers, (126) 653 Cyclopropyl radical Sulfinatodehalogenation reactions of gem-aryl disubstituted methylenecyclopropanes with perfluoroiodoalkanes, (126) 809 Cysteine Asymmetric synthesis of both enantiomers of syn-(3-trifluoromethyl)cysteine derivatives, (126) 499 DAST An efficient dehyrohalogenation method for the synthesis of ,,-trifluorostyrenes, -chloro-,-difluorostyrenes and E-1-arylperfluoroalkenes, (126) 1174 Defluorination A rich chemistry of fluorinated imidoyl halides, (126) 165 Microbial cleavage of C–F bond, (126) 425 Dehydration Conservation of [(C2H4NH3)3N]2·(ZrF7)2·H2O layers during the topotactic dehydration of [(C2H4NH3)3N]2·(ZrF7)2·9H2O, (126) 1072 Dehydrofluorination An efficient dehyrohalogenation method for the synthesis of ,,-trifluorostyrenes, -chloro-,-difluorostyrenes and E-1-arylperfluoroalkenes, (126) 1174 Dehydrofluorination/metallation A direct and rapid route to ,-difluoroacylsilanes from trifluoroethanol, (126) 611 Dehydrofluorinative carbon–carbon coupling Group 9 complexes of an N-heterocycle carbene bearing a pentafluorobenzyl substituent: attempted dehydrofluorinative coupling of cyclopentadienyl and N-heterocycle carbene ligands, (126) 451 Dehydrohalogenation An efficient dehyrohalogenation method for the synthesis of ,,-trifluorostyrenes, -chloro-,-difluorostyrenes and E-1-arylperfluoroalkenes, (126) 1174 Dehydroxylation Syntheses of new difluoromethylene benzoxazole and 1,2,4-oxadiazole derivatives, as potent non-nucleoside HIV-1 reverse transcriptase inhibitors, (126) 535 Density functional calculations Bis(trifluoromethyl)dicarbonate, CF3OC(O)OC(O)OCF3, (126) 984 Density functional theory A B3LYP study for the adsorption and catalytic ability of BF3 on NiO(0 0 1) surface, (126) 1463 Dental health Fluoride in water: A UK perspective, (126) 1448 Deuterium New derivatives of poly-hexafluoropropylene oxide from the corresponding alcohol, (126) 281 Deuterium labeling Competitive kinetic processes in the thermal rearrangement of 1,1-difluoro2-(dideuteriomethylene)-cyclopropane, (126) 339 Dialkyl N-(fluoroalkyl)phosphoramidate Fluorinated phosphorus compounds. Part 11. The reactions of some fluorinated amines with dialkyl and bis(fluoroalkyl) phosphorochloridates, (126) 1144 1,2-Di(aryloxy)-1,2-difluoroethenes Synthesis and some chemical properties of 1-aryloxy-2-chloro-1,2-difluoroethenes, (126) 1307 Diastereomerically pure bis(-methylbenzyl)amine derivative Asymmetric synthesis of -monofluoromethyl- and -difluoromethylbenzylamines through regioselective hydrogenolysis, (126) 385
Subject Index of Volume 126 Diastereoselectivity The effect of fluoromethyl groups on the diastereoselectivity in the electrophilic alkylation, (126) 918 Diazo transfer Study the reactions of fluoroalkanesulfonyl azides with N-alkylindoles, (126) 113 Study on the reactions of fluoroalkanesulfonyl azides with indole derivatives, (126) 824 1,1-Dibromo-1-fluoroalkane Chromium-mediated fluoroalkenylation reactions of 1,1-dibromo-1-fluoroalkane and 1-bromo-1-fluoroalkene derivatives, (126) 1166 1,2-Dibromotetrafluoroethane N-(2-bromotetrafluoroethyl) derivatives of five-membered nitrogen-containing heterocycles, (126) 1342 1,3-Dicarbonyl compounds Microwave-assisted rapid electrophilic fluorination of 1,3-dicarbonyl derivatives with Selectfluor®, (126) 475 1,2-Dichloro-1,2-difluoroethene Synthesis and some chemical properties of 1-aryloxy-2-chloro-1,2-difluoroethenes, (126) 1307 Dicyclophane Suzuki aryl cross-coupling chemistry using derivatives of 1,1,2,2,9,9,10,10octafluoro[2.2]paracyclophane, (126) 483 Diels-Alder Re-identification of C3HClF2 by analysis of its Diels-Alder products, (126) 1549 Diels–Alder reaction Intramolecular Diels–Alder reaction of -fluoroacrylate derivatives promoted by novel bidentate aluminum Lewis acid, (126) 709 Diethyl phosphite Reactions of 4-ethoxy-l,l,l-trifluoro-3-buten-2-one with phosphorous nucleophiles: Diethyl phosphite, tributyl phosphine and tris(diethylamino) phosphine, (126) 931 Diethylzinc Synthesis of 2-chloro-1,1-difluoroallyl mesylates through novel rearrangement and C–C bond formation by their Pd-catalyzed reaction with diethylzinc, (126) 765 vic-Difluoride Direct conversion of epoxides to vic-difluorides, (126) 962 Difluoro A direct and rapid route to ,-difluoroacylsilanes from trifluoroethanol, (126) 611 ,-Difluoro--butyrolactone Synthesis of ,-difluoro--butyrolactones via ethyl iododifluoroacetate, (126) 63 3,3-Difluoro-1-iodocyclopropenes Difluorocarbene chemistry: synthesis of gem-difluorocyclopropenylalkynes and 3,3,3,3-tetrafluorobicyclopropyl-1,1-dienes, (126) 39 Difluorocarbene chemistry: synthesis of gem-difluorocyclopropenylalkynes and 3,3,3,3-tetrafluorobicyclopropyl-1,1-dienes, (126) 93 1,1-Difluoro-1-alkene Nucleophilic difluoromethylation and difluoromethylenation using bromodifluoromethyl phenyl sulfone, (126) 1361 Difluorocarbene Difluorocarbene chemistry: synthesis of gem-difluorocyclopropenylalkynes and 3,3,3,3-tetrafluorobicyclopropyl-1,1-dienes, (126) 39 Difluorocarbene chemistry: synthesis of gem-difluorocyclopropenylalkynes and 3,3,3,3-tetrafluorobicyclopropyl-1,1-dienes, (126) 93 Insertion reactions of difluorocarbene generated by pyrolysis of hexafluoropropene oxide to O–H bond, (126) 373 A new synthesis of 2-fluoro-1-naphthols, (126) 479 Reactions of some nitrogen heterocycles with chlorodifluoromethane under conditions of phase-transfer catalysis, (126) 1587 Difluoromethyl alcohol Nucleophilic difluoromethylation and difluoromethylenation using bromodifluoromethyl phenyl sulfone, (126) 1361 -Difluoromethylbenzylamine Asymmetric synthesis of -monofluoromethyl- and -difluoromethylbenzylamines through regioselective hydrogenolysis, (126) 385
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Difluoromethyl heterocycles Syntheses of new difluoromethylene benzoxazole and 1,2,4-oxadiazole derivatives, as potent non-nucleoside HIV-1 reverse transcriptase inhibitors, (126) 535 Difluoromethylated alkene An efficient stereoselective synthesis of difluoromethylated alkenes in a microreactor, (126) 59 Difluoroolefin From ketones, aldehydes or alkyl halides to terminal 1,1-difluoroolefins using BrF3, (126) 1239 [Difluoro(phenylthio)methyl]trimethylsilane Fluoride-induced nucleophilic (phenylthio)difluoromethylation of carbonyl compounds with [difluoro(phenylthio)methyl]trimethylsilane (TMS–CF2SPh), (126) 529 Difluorophosphonoacetic acid Synthesis of -fluorinated phosphonoacetate derivatives using electrophilic fluorine reagents: perchloryl fluoride versus 1-chloromethyl-4-fluoro1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor®), (126) 1467 Difluoroquinolines Regioselectivity and relative substrate activity of difluoroquinolines containing fluorine atoms in benzene ring in reaction with sodium methoxide, (126) 1502 Dihydrofolate reductase inhibition Synthesis and biological activity of fluorinated 2-amino-4-aryl-3,4-dihydro[1,3,5]triazino[1,2-a]benzimidazoles, (126) 759 Diketones Acyclic tertiary diamines and 1,4,7,10-tetraazacyclododecane with fluorine-containing -diketones: Leading to low melting ionic adducts, (126) 1222 , -Dimethoxyfluoropolyethers Physical properties of four , -dimethoxyfluoropolyethers, (126) 465 Dimethoxyfluoropolyethers Synthesis of ,-dimethoxyfluoropolyethers: reaction mechanism and kinetics, (126) 633 Dipentaerythritol Novel fluorinated block copolymer architectures fuelled by atom transfer radical polymerization, (126) 241 1,3-Dipolar cycloaddition Study the reactions of fluoroalkanesulfonyl azides with N-alkylindoles, (126) 113 One-pot three-component reaction of C60, amino acid and fluorinated benzaldehyde to C60-pyrrolidine derivatives, (126) 349 Highly fluoroalkylated amphiphilic triazoles: Regioselective synthesis and evaluation of physicochemical properties, (126) 715 Study on the reactions of fluoroalkanesulfonyl azides with indole derivatives, (126) 824 Direct fluorination Synthesis of perfluorinated carboxylic acid membrane monomers by utilizing liquid-phase direct fluorination, (126) 521 Direct fluorination of polymers Direct fluorination—Useful tool to enhance commercial properties of polymer articles, (126) 251 Disorder 1:1 Complexes of octafluoronaphthalene with trans-stilbene and transazobenzene, (126) 515 Dithioesters A new method for the preparation of polyfluoroalkanedithiocarboxylates, (126) 369 Dithiophosphoric acids Synthesis and coordination chemistry of perfluoroalkylated dithiophosphate ligands, (126) 507 DMF 2,2-Bis(3-allyl-4-hydroxyphenyl)hexafluoropropane and fluorosiloxane as coating materials for nerve agent sensors, (126) 1252 Double-tail methacrylates Perfluoroalkylated diblock-alkyl methacrylate monomers for biomedical applications. Wettability of their copolymers with HEMA and DEGMA, (126) 595
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Subject Index of Volume 126
Drinking water Fluoride in water: A UK perspective, (126) 1448 EI/FTICRMS Study on the reactions of pyridine with fluorine-containing compounds in the gas-phase by electron impact/Fourier transfer ion cyclotron resonance mass spectrometry, (126) 107 Electrochemical fluorination Electrochemical fluorination of several esters derived from oxolane-2-ylcarboxylic acid, oxolane-2-yl-methanol and oxane-2-yl-methanol, (126) 325 Electrochemical partial fluorination Selective anodic fluorination of electrophilic alkenes, (126) 753 Electrochemical stability New ionic liquids with tris(perfluoroalkyl)trifluorophosphate (FAP) anions, (126) 1150 Electron paramagnetic resonance Highly fluorinated graphite prepared from graphite fluoride formed using BF3 catalyst, (126) 1078 Electrophilic alkenes Selective anodic fluorination of electrophilic alkenes, (126) 753 Electrophilic alkylation The effect of fluoromethyl groups on the diastereoselectivity in the electrophilic alkylation, (126) 918 Electrophilic fluorination Microwave-assisted rapid electrophilic fluorination of 1,3-dicarbonyl derivatives with Selectfluor®, (126) 475 Synthesis of -fluorinated phosphonoacetate derivatives using electrophilic fluorine reagents: perchloryl fluoride versus 1-chloromethyl-4-fluoro1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor®), (126) 1467 Electrophilic substitution Direct fluorination of coumarin, 6-methyl-coumarin and 7-alkoxycoumarins, (126) 1377 End group Structure determination of the amorphous perfluorinated homopolymer: Poly[perfluoro(4-vinyloxyl-1-butene)], (126) 1403 Enones Synthesis, 17O NMR spectroscopy and structure of 2-trifluoroacetyl-1methoxycycloalkenes, (126) 1396 Enthalpic control Regioselectivity and relative substrate activity of difluoroquinolines containing fluorine atoms in benzene ring in reaction with sodium methoxide, (126) 1502 Enzymatic resolution Synthesis of stereocontrolled ,-difluoro--hydroxycarbonyl materials, (126) 17 Epoxide Direct conversion of epoxides to vic-difluorides, (126) 962 Epoxide ring opening Perfluoroalkylated diblock-alkyl methacrylate monomers for biomedical applications. Wettability of their copolymers with HEMA and DEGMA, (126) 595 Equilibrium constant Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 99 Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 289 E-selective An efficient stereoselective synthesis of difluoromethylated alkenes in a microreactor, (126) 59 Ester enolate Claisen rearrangement Synthesis of -fluoro--amino acids by Claisen rearrangement, (126) 557 Ethers 19F and 13C spectra of fluorinated and partially fluorinated vinyl alkyl ethers, (126) 397 1-Ethyl-3-methylimidazolium A new room temperature ionic liquid of oxyfluorometallate anion: 1-Ethyl3-methylimidazolium oxypentafluorotungstate (EMImWOF5), (126) 1095
Ethyl iododifluoroacetate Synthesis of ,-difluoro--butyrolactones via ethyl iododifluoroacetate, (126) 63 European Union Regulating to reduce emissions of fluorinated greenhouse gases, (126) 1457 Exposure Fluoride in water: A UK perspective, (126) 1448 F K Chemical state analysis of fluorine in various compounds using X-ray fluorescence spectra, (126) 1048 19F and 51V NMR spectrocopies NMR study of the [VO(O2)2F]2 ion in solution: Synthesis, vibrational spectra and crystal structure of [NH3CH2CH2NH3][VO(O2)2F], (126) 1297 FF-TEM Functions of fluorosurfactants 1: Surface activities-improved and vesicle formation of the short-tailed chain sulfonate salt mixed with a fluorosurfactant, (126) 1266 Fluoral From fluoral to heterocycles: a survey of polyfluorinated iminiums chemistry, (126) 189 Fluorescence probes Characterization of hydrocarbon and fluorocarbon microdomains formed in aqueous solution of associative polymers: A molecular probe technique, (126) 1409 Fluoridation Fluoride in water: A UK perspective, (126) 1448 Fluoride Fluoride-induced nucleophilic (phenylthio)difluoromethylation of carbonyl compounds with [difluoro(phenylthio)methyl]trimethylsilane (TMS–CF2SPh), (126) 529 X-ray crystal structures on the hydrolysis path of [{Ti(C5Me4R)F3}2]: Water adduct [{Ti(C5Me4Et)F3}2(H2O)]·(H2O), oxoaqua complex [Ti7F21O(C5Me4Et)5(H2O)2] and oxo complex [Ti8F22O2(C5Me4H)6]·2CHCl3, (126) 1065 Two tantalum fluorides templated with tren: [H4tren](TaF7)2·H2O and [H4tren](TaF7)2, (126) 1246 Fluoride in water: A UK perspective, (126) 1448 Double-C,N-chelated tri- and diorganotin(IV) fluorides, (126) 1531 Fluoride catalysts New catalytic alkylation of in situ generated perfluoro-alkyloxy-anions and perfluoro-carbanions, (126) 1578 Fluoride ion New fluoride ion reagent from pentafluoropyridine, (126) 571 Fluorinated Synthesis of a novel type of hybrid fluorocarbon ionic surfactants containing polyoxyethlene chain, (126) 888 Fluorinated ,-unsaturated ketone Reactions of 4-ethoxy-l,l,l-trifluoro-3-buten-2-one with phosphorous nucleophiles: Diethyl phosphite, tributyl phosphine and tris(diethylamino) phosphine, (126) 931 Fluorinated acetylenes Re-identification of C3HClF2 by analysis of its Diels-Alder products, (126) 1549 Fluorinated alcohols Comparative study of the ring opening of 1-CF3-epoxy ethers mediated by Brönsted acids and hexafluoro-2-propanol, (126) 551 Fluorinated amine Fluorinated phosphorus compounds. Part 11. The reactions of some fluorinated amines with dialkyl and bis(fluoroalkyl) phosphorochloridates, (126) 1144 Fluorinated amino acids Synthesis of -fluoro--amino acids by Claisen rearrangement, (126) 557 New synthesis of polyfluoroalkyl racemic -amino acids, (126) 1487 Fluorinated -alkoxyvinyl ketones New derivatives of trifluoroacetyl acetaldehyde and trifluoroaldol, (126) 355
Subject Index of Volume 126 New derivatives of trifluoroacetyl acetaldehyde and trifluoroaldol, (126) 543 Fluorinated benzaldehyde One-pot three-component reaction of C60, amino acid and fluorinated benzaldehyde to C60-pyrrolidine derivatives, (126) 349 Fluorinated bioactive compounds From fluoral to heterocycles: a survey of polyfluorinated iminiums chemistry, (126) 189 Fluorinated -keto acetals New derivatives of trifluoroacetyl acetaldehyde and trifluoroaldol, (126) 355 New derivatives of trifluoroacetyl acetaldehyde and trifluoroaldol, (126) 543 Fluorinated block copolymers Update on fluoroelastomers: from perfluoroelastomers to fluorosilicones and fluorophosphazenes, (126) 221 Fluorinated carbon Effect of surface fluorination on the electrochemical behavior of petroleum cokes for lithium ion battery, (126) 265 Fluorinated chromia catalyst Isomerization reaction of 1,1,2,2-tetrafluorethan on fluorinated chromia: A consideration of the adsorption behavior on the catalyst, (126) 1017 Fluorinated diol Fluorinated phosphorus compounds. Part 9. The reactions of bis(fluoroalkyl) phosphorochloridates with oxygen nucleophiles, (126) 892 Fluorinated ether Insertion reactions of difluorocarbene generated by pyrolysis of hexafluoropropene oxide to O–H bond, (126) 373 Fluorinated fatty acids The structure and properties of hybrid fluorous-hydrocarbon fatty acids, (126) 673 Fluorinated fluids Physical properties of four , -dimethoxyfluoropolyethers, (126) 465 Synthesis of ,-dimethoxyfluoropolyethers: reaction mechanism and kinetics, (126) 633 Fluorinated graft copolymers Update on fluoroelastomers: from perfluoroelastomers to fluorosilicones and fluorophosphazenes, (126) 221 Fluorinated nanoparticles Novel fluorinated block copolymer architectures fuelled by atom transfer radical polymerization, (126) 241 Fluorinated polyetherimide Synthesis and characterization of fluorinated copolyetherimides with –CH2–C6F13 side chains based on the ULTEM™ structure, (126) 1476 Fluorinated polymers Thermal stability and bond dissociation energy of fluorinated polymers: A critical evaluation, (126) 625 Fluorinated siloxane 2,2-Bis(3-allyl-4-hydroxyphenyl)hexafluoropropane and fluorosiloxane as coating materials for nerve agent sensors, (126) 1252 Fluorinated surfactants Regioselective ring opening of [(perfluoroalkyl)methyl] oxiranes with Nnucleophiles, (126) 1274 Fluorinated telomers Update on fluoroelastomers: from perfluoroelastomers to fluorosilicones and fluorophosphazenes, (126) 221 Fluorinated vinyl Fluorinated stannanes. Part 2. The stereospecific synthesis of fluorinated stannanes via a Barbier-type reaction between fluorinated halides and tributyltin chloride mediated by zinc or cadmium, (126) 797 Fluorination Cocatalysis in phase-transfer catalyzed fluorination of alkyl halides and sulfonates, (126) 209 Effect of surface fluorination on the electrochemical behavior of petroleum cokes for lithium ion battery, (126) 265 Syntheses of new difluoromethylene benzoxazole and 1,2,4-oxadiazole derivatives, as potent non-nucleoside HIV-1 reverse transcriptase inhibitors, (126) 535
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New fluoride ion reagent from pentafluoropyridine, (126) 571 Electrophilic aromatic fluorination with fluorine: meta-Directed fluorination of anilines, (126) 661 Synthesis of gem-difluorides from aldehydes using DFMBA, (126) 721 Investigation of reactions between [60]fullerene and molecular fluorine in a CoF2 matrix, (126) 785 Direct conversion of epoxides to vic-difluorides, (126) 962 Highly fluorinated graphite prepared from graphite fluoride formed using BF3 catalyst, (126) 1078 Surface fluorination and electrochemical behavior of petroleum cokes graphitized at medium and high temperatures for secondary lithium battery, (126) 1028 A detailed account of a convenient lab-scale preparation of AsF5 via direct fluorination of AsF3, (126) 1368 Novel facile routes for synthesis and isolation of fluorofullerenes C60F18 and C60F20 based on commercially available fluorinating reagents, (126) 1559 Fluorine Fluorine chemistry at the millennium, (126) 157 Pentaerythritol tetrakis(4-iodo-2,3,5,6-tetrafluorophenyl) ether: a tecton for the self-assembly of double strand 1D infinite chains, (126) 197 Direct fluorination—Useful tool to enhance commercial properties of polymer articles, (126) 251 19F and 13C spectra of fluorinated and partially fluorinated vinyl alkyl ethers, (126) 397 Synthesis of perfluorinated carboxylic acid membrane monomers by utilizing liquid-phase direct fluorination, (126) 521 Recycling of fluorinated axially dissymmetric ligand with fluorous solvent, (126) 415 Electrophilic aromatic fluorination with fluorine: meta-Directed fluorination of anilines, (126) 661 Synthesis of 2-chloro-1,1-difluoroallyl mesylates through novel rearrangement and C–C bond formation by their Pd-catalyzed reaction with diethylzinc, (126) 765 Surface-fluorinated graphite anode materials for Li-ion batteries, (126) 1111 Stereoselective synthesis of insect sex pheromone analogs having a fluorine atom on their double bonds, (126) 1185 A detailed account of a convenient lab-scale preparation of AsF5 via direct fluorination of AsF3, (126) 1368 Direct fluorination of coumarin, 6-methyl-coumarin and 7-alkoxycoumarins, (126) 1377 Nucleophilic difluoromethylation and difluoromethylenation using bromodifluoromethyl phenyl sulfone, (126) 1361 Synthesis and bioactivity of fluorine compounds containing isoxazolylamino and phosphonate groups, (126) 1419 Fluorine addition Preparation of polyfluorinated cycloalk-1-enyl-, alk-1-enyl-, and alkyliodine tetrafluorides using XeF2 in the presence of appropriate Lewis acids as fluorooxidant, (126) 1036 Fluorine doping Fluorine-doped TiO2 powders prepared by spray pyrolysis and their improved photocatalytic activity for decomposition of gas-phase acetaldehyde, (126) 69 Fluorine–carbon correlations Carbon–fluorine two-dimensional NMR correlation spectra, (126) 363 Fluorine-containing monomer Synthesis and characterization of soluble polyimides based on trifluoromethylated aromatic dianhydride and substitutional diaminetriphenylmethanes, (126) 819 Fluorine-containing multifunctional carbon compound Synthesis, reactions, and applications of fluorine-containing multifunctional carbon compounds, (126) 941 Fluorine-containing polyimide Synthesis and characterization of soluble polyimides based on trifluoromethylated aromatic dianhydride and substitutional diaminetriphenylmethanes, (126) 819 Fluorine-containing quaternary amino acids A novel synthesis of fluorine-containing quaternary amino acid derivatives via palladium-catalyzed allylation reaction, (126) 1517
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Subject Index of Volume 126
Fluoro Grignard reagent Preparation of fluorohalomethylmagnesium halides using highly active magnesium metal and their reactions, (126) 1390 Fluoroalkanes Surface tension of fluoroalkanes in a liquid phase, (126) 379 Fluoroalkanesulfonyl azide Study on the reactions of pyridine with fluorine-containing compounds in the gas-phase by electron impact/Fourier transfer ion cyclotron resonance mass spectrometry, (126) 107 Study the reactions of fluoroalkanesulfonyl azides with N-alkylindoles, (126) 113 Study on the reactions of fluoroalkanesulfonyl azides with indole derivatives, (126) 824 -Fluoroacrylate Intramolecular Diels–Alder reaction of -fluoroacrylate derivatives promoted by novel bidentate aluminum Lewis acid, (126) 709 Fluoroalkenes Novel fluoroacrylated copolymers: synthesis, characterization and properties, (126) 231 The catalytic olefination reaction of aldehydes and ketones with CBr3CF3, (126) 907 2-Fluoro-5-pyridylmethylamine Synthesis and herbicidal activity of 2-cyano-3-(2-fluoro-5-pyridyl)methylaminoacrylates, (126) 345 2-Fluoroallylic alcohol Chromium-mediated fluoroalkenylation reactions of 1,1-dibromo-1-fluoroalkane and 1-bromo-1-fluoroalkene derivatives, (126) 1166 3-Fluoropenta-1,3-diene Synthesis of 2-chloro-1,1-difluoroallyl mesylates through novel rearrangement and C–C bond formation by their Pd-catalyzed reaction with diethylzinc, (126) 765 3-Fluoropyridine Fluorinated pyridine derivatives. Part 1. The synthesis of some mono- and bis-quaternary pyridine salts of potential use in the treatment of nerve agent poisoning, (126) 1160 Fluoroalkenylation Chromium-mediated fluoroalkenylation reactions of 1,1-dibromo-1-fluoroalkane and 1-bromo-1-fluoroalkene derivatives, (126) 1166 Fluoroalkyl halides Reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with nucleophilic reagents, (126) 445 Fluoroalkylated 1,2,3,4-tetrahydropyrimidine A convenient three-component reaction for the construction of multifunctional 6-fluoroalkyl-1,2,3,4-tetrahydropyrimidines, (126) 1539 Fluoroalkylated oligomer Preparation of magnetic nanoparticles by the use of self-assembled fluorinated oligomeric aggregates—A new approach to the dispersion of magnetic particles on poly(methyl methacrylate) film surface, (126) 914 Fluoroalkylporphyrins Fluoroalkylation of porphyrins: Preparation and characterization of mesoand -fluoroalkyl-5,15-diarylporphyrins, (126) 1321 -Fluoroalkylenaminoketone A convenient three-component reaction for the construction of multifunctional 6-fluoroalkyl-1,2,3,4-tetrahydropyrimidines, (126) 1539 Fluoroamine Fluorinated phosphorus compounds. Part 11. The reactions of some fluorinated amines with dialkyl and bis(fluoroalkyl) phosphorochloridates, (126) 1144 Fluoroanilines Electrophilic aromatic fluorination with fluorine: meta-Directed fluorination of anilines, (126) 661 Fluoroaromatics A new synthesis of 2-fluoro-1-naphthols, (126) 479 Fluorocarbon Spontaneous vesicles of single-chain sugar-based fluorocarbon surfactants, (126) 33 Synthesis of phosphate-type fluorocarbon–hydrocarbon hybrid surfactants and their adsorption onto calcium hydroxyapatite, (126) 301
Fluorocyclobutanones An unusual fluoroketene reaction product, (126) 1496 Synthesis of fluorocyclobutanones and their use in the synthesis of fluoronucleosides, (126) 1565 Fluorocyclopropanes Competitive kinetic processes in the thermal rearrangement of 1,1-difluoro2-(dideuteriomethylene)-cyclopropane, (126) 339 Fluorodesulfurization Highly selective electrochemical fluorination of organic compounds in ionic liquids, (126) 181 Fluoroelastomers Update on fluoroelastomers: from perfluoroelastomers to fluorosilicones and fluorophosphazenes, (126) 221 Fluoroformates New catalytic alkylation of in situ generated perfluoro-alkyloxy-anions and perfluoro-carbanions, (126) 1578 Fluorofullerenes Investigation of reactions between [60]fullerene and molecular fluorine in a CoF2 matrix, (126) 785 Novel facile routes for synthesis and isolation of fluorofullerenes C60F18 and C60F20 based on commercially available fluorinating reagents, (126) 1559 Fluorohaloalcohol Preparation of fluorohalomethylmagnesium halides using highly active magnesium metal and their reactions, (126) 1390 Fluorohalomethane Preparation of fluorohalomethylmagnesium halides using highly active magnesium metal and their reactions, (126) 1390 Fluorohalomethylmagnesium halide Preparation of fluorohalomethylmagnesium halides using highly active magnesium metal and their reactions, (126) 1390 Fluorohalomethylsilane Preparation of fluorohalomethylmagnesium halides using highly active magnesium metal and their reactions, (126) 1390 Fluoroketene An unusual fluoroketene reaction product, (126) 1496 Synthesis of fluorocyclobutanones and their use in the synthesis of fluoronucleosides, (126) 1565 Fluoromethylmagnesium halide Preparation of fluorohalomethylmagnesium halides using highly active magnesium metal and their reactions, (126) 1390 Fluoronucleosides Synthesis of fluorocyclobutanones and their use in the synthesis of fluoronucleosides, (126) 1565 Fluorophilic Reactions of 2-(perfluoroalkyl)ethane thiols with 1,6-heptadiene and 4-substituted 1,6-heptadienes: the synthesis of RFethanethio-cyclopentanoic and -dioic acids; and, “geminal-twin-tail” bis-(perfluoroalkylethanethio)alkanoic acids, (126) 7 Fluorophilicity Synthesis of novel lipophilic and/or fluorophilic ethers of perfluoro-tertbutyl alcohol, perfluoropinacol and hexafluoroacetone hydrate via a Mitsunobu reaction: Typical cases of ideal product separation, (126) 641 Mitsunobu synthesis of symmetrical alkyl and polyfluoroalkyl secondary amines, (126) 1524 Fluorophosphazenes Update on fluoroelastomers: from perfluoroelastomers to fluorosilicones and fluorophosphazenes, (126) 221 Fluorophosphonoacetic acid Synthesis of -fluorinated phosphonoacetate derivatives using electrophilic fluorine reagents: perchloryl fluoride versus 1-chloromethyl-4-fluoro1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor®), (126) 1467 Fluoropolymers Fluorine chemistry at the millennium, (126) 157 Characterization of hydrocarbon and fluorocarbon microdomains formed in aqueous solution of associative polymers: A molecular probe technique, (126) 1409
Subject Index of Volume 126 Fluoro-polyphosphate The preparation and analysis of fluoro-polyphosphates by 19F, 31P, 2D 19F–31P HETCOR and 2D 31P–31P COSY NMR, (126) 883 Fluorosilicones Update on fluoroelastomers: from perfluoroelastomers to fluorosilicones and fluorophosphazenes, (126) 221 Fluorosurfactants Functions of fluorosurfactants 1: Surface activities-improved and vesicle formation of the short-tailed chain sulfonate salt mixed with a fluorosurfactant, (126) 1266 Fluorotelomer alcohols Gas phase UV and IR absorption spectra of CF3CH2CH2OH and F(CF2CF2)xCH2CH2OH (x = 2, 3, 4), (126) 1288 Fluorous Synthesis and coordination chemistry of perfluoroalkylated dithiophosphate ligands, (126) 507 Synthesis and coordination chemistry of fluorinated xanthate ligands, (126) 1117 Fluorous biphase synthesis The synthesis and application of fluorous boronates without perfluorinated solvents, (126) 996 Fluorous biphasic catalysis Rare earth(III) perfluorooctanesulfonates catalyzed Friedel–Crafts alkylation in fluorous biphase system, (126) 830 Rare earth(III) perfluorooctane sulfonates and perfluorooctanesulfonic acid in fluorous solvents: Novel and recyclable catalytic systems for FriedelCrafts acylation of unactivated benzenes, (126) 1191 Aldol condensations of aldehydes and ketones catalyzed by rare earth(III) perfluorooctane sulfonates in fluorous solvents, (126) 1553 Fluorous blocks The structure and properties of hybrid fluorous-hydrocarbon fatty acids, (126) 673 Fluorous boronates The synthesis and application of fluorous boronates without perfluorinated solvents, (126) 996 Fluorous compounds Gold nanoparticles entrapped in heavily fluorinated compounds, (126) 1435 Fluorous solvent Recycling of fluorinated axially dissymmetric ligand with fluorous solvent, (126) 415 Formaldehyde A convenient three-component reaction for the construction of multifunctional 6-fluoroalkyl-1,2,3,4-tetrahydropyrimidines, (126) 1539 Friedel-Crafts acylation Rare earth(III) perfluorooctane sulfonates and perfluorooctanesulfonic acid in fluorous solvents: Novel and recyclable catalytic systems for FriedelCrafts acylation of unactivated benzenes, (126) 1191 Friedel–Crafts alkylation Rare earth(III) perfluorooctanesulfonates catalyzed Friedel–Crafts alkylation in fluorous biphase system, (126) 830 Fuel cells Perfluorocyclobutyl (PFCB) aromatic polyethers: Synthesis and characterization of new sulfonimide containing monomers and fluoropolymers, (126) 653 Fullerenes Novel facile routes for synthesis and isolation of fluorofullerenes C60F18 and C60F20 based on commercially available fluorinating reagents, (126) 1559 gem-Difluoride Synthesis of gem-difluorides from aldehydes using DFMBA, (126) 721 Geminal-twin-tail 2,2-[bis-(perfluoroalkyl)alkylthio]ethanoic acid Reactions of 2-(perfluoroalkyl)ethane thiols with 1,6-heptadiene and 4-substituted 1,6-heptadienes: the synthesis of RFethanethio-cyclopentanoic and -dioic acids; and, “geminal-twin-tail” bis-(perfluoroalkylethanethio)alkanoic acids, (126) 7 Germanium Cocatalysis in phase-transfer catalyzed fluorination of alkyl halides and sulfonates, (126) 209
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Glass transition temperature Radical solution copolymerisation of vinylidene fluoride with hexafluoropropene, (126) 577 Glymes New catalytic alkylation of in situ generated perfluoro-alkyloxy-anions and perfluoro-carbanions, (126) 1578 Gold nanoparticles Gold nanoparticles entrapped in heavily fluorinated compounds, (126) 1435 Graphite Surface-fluorinated graphite anode materials for Li-ion batteries, (126) 1111 Graphite fluoride Highly fluorinated graphite prepared from graphite fluoride formed using BF3 catalyst, (126) 1078 Graphite intercalation compounds Highly fluorinated graphite prepared from graphite fluoride formed using BF3 catalyst, (126) 1078 Grignard reagents Reaction of octafluorocyclopentene with various carbon nucleophiles, (126) 125 Group contributions Physical properties of four , -dimethoxyfluoropolyethers, (126) 465 2-Guanidinobenzimidazole Synthesis and biological activity of fluorinated 2-amino-4-aryl-3,4-dihydro[1,3,5]triazino[1,2-a]benzimidazoles, (126) 759 Halogen bonding Pentaerythritol tetrakis(4-iodo-2,3,5,6-tetrafluorophenyl) ether: a tecton for the self-assembly of double strand 1D infinite chains, (126) 197 Halothane™ Room temperature preparation of -chloro-,-difluoroethenylzinc reagent (CF2CClZnCl) by the metallation of HCFC-133a (CF3CH2Cl) and a high yield one-pot synthesis of -chloro-,-difluorostyrenes, (126) 833 HCFC-133a Room temperature preparation of -chloro-,-difluoroethenylzinc reagent (CF2CClZnCl) by the metallation of HCFC-133a (CF3CH2Cl) and a high yield one-pot synthesis of -chloro-,-difluorostyrenes, (126) 833 Health effects Fluoride in water: A UK perspective, (126) 1448 Hemiaminal From fluoral to heterocycles: a survey of polyfluorinated iminiums chemistry, (126) 189 Hemiaminal equilibrium Methyl 3,3,3-trifluoropyruvate hemiaminals: Stability and transaminations, (126) 745 1,6-Heptadiene cyclization Reactions of 2-(perfluoroalkyl)ethane thiols with 1,6-heptadiene and 4-substituted 1,6-heptadienes: the synthesis of RFethanethio-cyclopentanoic and -dioic acids; and, “geminal-twin-tail” bis-(perfluoroalkylethanethio)alkanoic acids, (126) 7 Herbicidal activity Synthesis and herbicidal activity of 2-cyano-3-(2-fluoro-5-pyridyl)methylaminoacrylates, (126) 345 Heteroatom Synthesis, reactions, and applications of fluorine-containing multifunctional carbon compounds, (126) 941 Heterocycle Polyhalogenated heterocyclic compounds. Part 52. [1] Macrocycles from 3,5-dichloro-2,4,6-trifluoropyridine, (126) 1002 Synthesis and the reactions of trifluoromethylated 1,2,3-triketones 2(het)arylhydrazones and 4,7-dihydroazolo[5,1-c]triazines, (126) 1230 Direct fluorination of coumarin, 6-methyl-coumarin and 7-alkoxycoumarins, (126) 1377 Hexa-cyclic Structure determination of the amorphous perfluorinated homopolymer: Poly[perfluoro(4-vinyloxyl-1-butene)], (126) 1403
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Subject Index of Volume 126
Hexafluoro-2-propanol Comparative study of the ring opening of 1-CF3-epoxy ethers mediated by Brönsted acids and hexafluoro-2-propanol, (126) 551 Hexafluoropropene oxide Insertion reactions of difluorocarbene generated by pyrolysis of hexafluoropropene oxide to O–H bond, (126) 373 Hexafluoropropylene Radical solution copolymerisation of vinylidene fluoride with hexafluoropropene, (126) 577 Hexafluorosilicate First X-ray structure of hexaamminecobalt(III) salt with complex fluoroanion: Synthesis and characterization of [Co(NH3)6]X·SiF6·nH2O, where X = Cl, Br, I and NO3 and crystal structure of [Co(NH3)6]Cl·SiF6·2H2O, (126) 967 HF Theoretical study on the (O2-HF) complex, (126) 313 High-purity AsF5 A laboratory-scale synthesis of high-purity AsF5 by direct fluorination of AsF3, (126) 1373 High-temperature gas-phase NMR Gas-phase NMR studies of the thermolysis of perfluorooctanoic acid, (126) 1510 HIV Syntheses of new difluoromethylene benzoxazole and 1,2,4-oxadiazole derivatives, as potent non-nucleoside HIV-1 reverse transcriptase inhibitors, (126) 535 Hot isostactic pressing (HIP) Anodic behavior of nickel-based alloys in the electrolytic production of NF3, (126) 1101 Human teeth Synthesis of phosphate-type fluorocarbon–hydrocarbon hybrid surfactants and their adsorption onto calcium hydroxyapatite, (126) 301 Hybrid Synthesis of a novel type of hybrid fluorocarbon ionic surfactants containing polyoxyethlene chain, (126) 888 Hybrid fluorides Conservation of [(C2H4NH3)3N]2·(ZrF7)2·H2O layers during the topotactic dehydration of [(C2H4NH3)3N]2·(ZrF7)2·9H2O, (126) 1072 Hybrid surfactant Synthesis of phosphate-type fluorocarbon–hydrocarbon hybrid surfactants and their adsorption onto calcium hydroxyapatite, (126) 301 Hydro- and lipophobic surface Synthesis of phosphate-type fluorocarbon–hydrocarbon hybrid surfactants and their adsorption onto calcium hydroxyapatite, (126) 301 Hydrofluorocarbon Regulating to reduce emissions of fluorinated greenhouse gases, (126) 1457 Hydrofluoroethers Physical properties of four , -dimethoxyfluoropolyethers, (126) 465 New catalytic alkylation of in situ generated perfluoro-alkyloxy-anions and perfluoro-carbanions, (126) 1578 Hydrofluoropolyethers Synthesis of ,-dimethoxyfluoropolyethers: reaction mechanism and kinetics, (126) 633 Hydrogen abstraction EPR studies on H-abstraction from p-substituted benzaldehydes by new “Magic Blue” reagents and correlation analysis of aN values of -fluoro-sulfonylperfluoroalkyl p-substituted benzoyl nitroxides, (126) 333 EPR studies on H-abstraction from methylbenzenes by “magic blue” reagent, (126) 1130 Hydrogen bond Intermolecular-medium and intramolecular-weak hydrogen bonding chains in the crystals of chiral trifluoromethylated amino alcohols, (126) 1134 Hydrogen bonding chain Intermolecular-medium and intramolecular-weak hydrogen bonding chains in the crystals of chiral trifluoromethylated amino alcohols, (126) 1134 Hydrogen bonds Comparative study of the ring opening of 1-CF3-epoxy ethers mediated by Brönsted acids and hexafluoro-2-propanol, (126) 551
Hydrogen fluoride A mild method for halofluorination of alkenes with ionic liquid EMIMF(HF)2.3, (126) 121 Hydrogenation Convenient synthesis of fluorinated alkanes and cycloalkanes by hydrogenation of perfluoroalkylalkenes under ultrasound irradiation, (126) 1347 Hydrogen-bonded conformation Gas phase UV and IR absorption spectra of CF3CH2CH2OH and F(CF2CF2)xCH2CH2OH (x = 2, 3, 4), (126) 1288 Hydrolysis -Branched-perfluorodiacyl peroxides: preparation and characterization, (126) 587 X-ray crystal structures on the hydrolysis path of [{Ti(C5Me4R)F3}2]: Water adduct [{Ti(C5Me4Et)F3}2(H2O)]·(H2O), oxoaqua complex [Ti7F21O(C5Me4Et)5(H2O)2] and oxo complex [Ti8F22O2(C5Me4H)6]·2CHCl3, (126) 1065 Hydrolysis in the system LiPF6—propylene carbonate—dimethyl carbonate—H2O, (126) 27 2-Hydroperfluorooct-1-ene Synthesis and copolymerisation of fluorinated monomers bearing a reactive lateral group. Part 21. Radical copolymerisation of vinylidene fluoride with 2-hydroperfluorooct-1-ene, (126) 1009 Hydrophobic non-porous films Synthesis and characterization of fluorinated copolyetherimides with –CH2–C6F13 side chains based on the ULTEM™ structure, (126) 1476 Hydrothermal synthesis Conservation of [(C2H4NH3)3N]2·(ZrF7)2·H2O layers during the topotactic dehydration of [(C2H4NH3)3N]2·(ZrF7)2·9H2O, (126) 1072 Hypofluorous acid Rapid and high yield oxidation of phosphine, phosphite and phosphinite compounds to phosphine oxides, phosphates and phosphinates using hypofluorous acid–acetonitrile complex, (126) 1054 From ketones, aldehydes or alkyl halides to terminal 1,1-difluoroolefins using BrF3, (126) 1239 2-Hydroxy-N-perfluoroalkanoylanilines Synthesis of 2,3-bis(perfluoroalkyl)quinoxalines and 2,3-bis(perfluoroalkyl)-1,4-benzoxazines from oxides of internal perfluoroolefins, (126) 976 Ideal separation Synthesis of novel lipophilic and/or fluorophilic ethers of perfluoro-tertbutyl alcohol, perfluoropinacol and hexafluoroacetone hydrate via a Mitsunobu reaction: Typical cases of ideal product separation, (126) 641 Mitsunobu synthesis of symmetrical alkyl and polyfluoroalkyl secondary amines, (126) 1524 Imidazole Group 9 complexes of an N-heterocycle carbene bearing a pentafluorobenzyl substituent: attempted dehydrofluorinative coupling of cyclopentadienyl and N-heterocycle carbene ligands, (126) 451 Imidazolium salts Novel ionic liquids—Imidazolium salts with a difluoromethylene fragment directly bonded to the nitrogen atom, (126) 669 Imidoylchlorides Polyfluoroaromatic compounds with a –NCClR group—a reactive type of polyfluoroarene, (126) 860 Imine One-pot synthesis of bromodifluoroacetimidoyl halides and its Suzuki coupling reactions with aryl boronic acids, (126) 791 Imines Some studies on nucleophilic trifluoromethylation using the shelf-stable trifluoromethylacetophenone-N,N-dimethyltrimethylsilylamine adduct, (126) 491 Iminium From fluoral to heterocycles: a survey of polyfluorinated iminiums chemistry, (126) 189 Iminosulfinates [P3N3F5NS(O)Cl] and [{P4N4F6(NS(Cl)N)}2]2, the first chloro iminoand chloro bis(imino) sulfinates, (126) 1044
Subject Index of Volume 126 Indanone A new synthesis of 2-fluoro-1-naphthols, (126) 479 Indole derivatives Study on the reactions of fluoroalkanesulfonyl azides with indole derivatives, (126) 824 Indolizine Synthesis of a new fluorinated fluorescent -cyclodextrin sensor, (126) 393 Infrared spectroscopy First X-ray structure of hexaamminecobalt(III) salt with complex fluoroanion: Synthesis and characterization of [Co(NH3)6]X·SiF6·nH2O, where X = Cl, Br, I and NO3 and crystal structure of [Co(NH3)6]Cl·SiF6·2H2O, (126) 967 Second sphere coordination in anion binding: Synthesis, spectroscopic characterization and single crystal X-ray structure determination of hexaamminecobalt(III) dichloride tetrafluoroborate, (126) 1543 Inorganic synthesis First X-ray structure of hexaamminecobalt(III) salt with complex fluoroanion: Synthesis and characterization of [Co(NH3)6]X·SiF6·nH2O, where X = Cl, Br, I and NO3 and crystal structure of [Co(NH3)6]Cl·SiF6·2H2O, (126) 967 Insect-flight Synthesis and biological activities of hydroxyl-protected fluorine-containing 4,4-dihydroxylmethyl-2-aryl-iminothiazolidines, (126) 53 Insertion reaction Insertion reactions of difluorocarbene generated by pyrolysis of hexafluoropropene oxide to O–H bond, (126) 373 Intermolecular interaction Intermolecular interaction between the pendant chain of perfluorinated ionomer and methanol, (126) 1312 Iodine Pentaerythritol tetrakis(4-iodo-2,3,5,6-tetrafluorophenyl) ether: a tecton for the self-assembly of double strand 1D infinite chains, (126) 197 2-Iodo-1,1,1-trifluoroethane The first preparation of the -iodo-,-difluorovinylzinc reagent (CF2CIZnCl) and a high-yield one-pot synthesis of -iodo-,-difluorostyrenes, (126) 457 -Iodo-,-difluorostyrene The first preparation of the -iodo-,-difluorovinylzinc reagent (CF2CIZnCl) and a high-yield one-pot synthesis of -iodo-,-difluorostyrenes, (126) 457 Iododifluorovinyllithium The first preparation of the -iodo-,-difluorovinylzinc reagent (CF2CIZnCl) and a high-yield one-pot synthesis of -iodo-,-difluorostyrenes, (126) 457 Iododifluorovinylzinc The first preparation of the -iodo-,-difluorovinylzinc reagent (CF2CIZnCl) and a high-yield one-pot synthesis of -iodo-,-difluorostyrenes, (126) 457 Iodofluorination of alkene A mild method for halofluorination of alkenes with ionic liquid EMIMF(HF)2.3, (126) 121 Ion exchange polymer Self-emulsifying polymerization (SEP) of 3,6-dioxa- 7-4-trifluoromethyl perfluorooctyl trifluoromethyl sulfonimide with tetrafluoroethylene, (126) 1057 Ionic liquid A mild method for halofluorination of alkenes with ionic liquid EMIMF(HF)2.3, (126) 121 Highly selective electrochemical fluorination of organic compounds in ionic liquids, (126) 181 Novel ionic liquids—Imidazolium salts with a difluoromethylene fragment directly bonded to the nitrogen atom, (126) 669 A new room temperature ionic liquid of oxyfluorometallate anion: 1-Ethyl3-methylimidazolium oxypentafluorotungstate (EMImWOF5), (126) 1095 New ionic liquids with tris(perfluoroalkyl)trifluorophosphate (FAP) anions, (126) 1150
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Ionic surfactant Synthesis of a novel type of hybrid fluorocarbon ionic surfactants containing polyoxyethlene chain, (126) 888 Ion-molecule reaction Study on the reactions of pyridine with fluorine-containing compounds in the gas-phase by electron impact/Fourier transfer ion cyclotron resonance mass spectrometry, (126) 107 Ionomer Intermolecular interaction between the pendant chain of perfluorinated ionomer and methanol, (126) 1312 IR measurements Gas phase UV and IR absorption spectra of CF3CH2CH2OH and F(CF2CF2)xCH2CH2OH (x = 2, 3, 4), (126) 1288 Isomerization of 1,1,2,2 tetrafluoroethane Isomerization reaction of 1,1,2,2-tetrafluorethan on fluorinated chromia: A consideration of the adsorption behavior on the catalyst, (126) 1017 Isomers Synthesis and the reactions of trifluoromethylated 1,2,3-triketones 2(het)arylhydrazones and 4,7-dihydroazolo[5,1-c]triazines, (126) 1230 Isotope effects 19F and 13C spectra of fluorinated and partially fluorinated vinyl alkyl ethers, (126) 397 Isoxazole Synthesis and bioactivity of fluorine compounds containing isoxazolylamino and phosphonate groups, (126) 1419 Ketones Some studies on nucleophilic trifluoromethylation using the shelf-stable trifluoromethylacetophenone-N,N-dimethyltrimethylsilylamine adduct, (126) 491 Fluorochromate-catalyzed periodic acid oxidation of alcohols and aldehydes, (126) 1356 KF Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 99 Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 289 Kinetic NMR Gas-phase NMR studies of the thermolysis of perfluorooctanoic acid, (126) 1510 Kinetics Competitive kinetic processes in the thermal rearrangement of 1,1-difluoro2-(dideuteriomethylene)-cyclopropane, (126) 339 Lactam From fluoral to heterocycles: a survey of polyfluorinated iminiums chemistry, (126) 189 Lactobionate Spontaneous vesicles of single-chain sugar-based fluorocarbon surfactants, (126) 33 Lactone Synthesis of lactones with a chlorodifluoromethyl group, (126) 135 Lactonization Synthesis of lactones with a chlorodifluoromethyl group, (126) 135 Langmuir isotherms The structure and properties of hybrid fluorous-hydrocarbon fatty acids, (126) 673 Langmuir monolayers Critical influence of the alkane length in surface and liquid–crystalline properties of perfluorodecyl-n-alkanes, (126) 79 Legislation Regulating to reduce emissions of fluorinated greenhouse gases, (126) 1457 Lewis base Aza-Morita-Baylis-Hillman reactions of N-(benzylidene)polyfluoroanilines with methyl acrylate and acrylonitrile, (126) 1215 LHMDS An efficient dehyrohalogenation method for the synthesis of ,,-trifluorostyrenes, -chloro-,-difluorostyrenes and E-1-arylperfluoroalkenes, (126) 1174
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Subject Index of Volume 126
Ligand Recycling of fluorinated axially dissymmetric ligand with fluorous solvent, (126) 415 Li-ion battery Surface-fluorinated graphite anode materials for Li-ion batteries, (126) 1111 Linear/cyclic adduct Reactions of 2-(perfluoroalkyl)ethane thiols with 1,6-heptadiene and 4-substituted 1,6-heptadienes: the synthesis of RFethanethio-cyclopentanoic and -dioic acids; and, “geminal-twin-tail” bis-(perfluoroalkylethanethio)alkanoic acids, (126) 7 Liquid ammonia Regioselectivity and relative substrate activity of difluoroquinolines containing fluorine atoms in benzene ring in reaction with sodium methoxide, (126) 1502 Liquid crystals Critical influence of the alkane length in surface and liquid–crystalline properties of perfluorodecyl-n-alkanes, (126) 79 Fluorine chemistry at the millennium, (126) 157 Lithium Surface-fluorinated graphite anode materials for Li-ion batteries, (126) 1111 Lithium bis(pentafluorophenylsulfonyl)imide New fluorine-containing plasticized low lattice energy lithium salt for plastic batteries, (126) 842 Lithium hexafluorophosphate Hydrolysis in the system LiPF6—propylene carbonate—dimethyl carbonate—H2O, (126) 27 Lithium rechargeable battery Effect of surface fluorination on the electrochemical behavior of petroleum cokes for lithium ion battery, (126) 265 Lithium-ion batteries New fluorine-containing plasticized low lattice energy lithium salt for plastic batteries, (126) 842 Low-temperature synthesis of AsF5 A laboratory-scale synthesis of high-purity AsF5 by direct fluorination of AsF3, (126) 1373 Macrocycle Polyhalogenated heterocyclic compounds. Part 52. [1] Macrocycles from 3,5-dichloro-2,4,6-trifluoropyridine, (126) 1002 Magic Blue EPR studies on H-abstraction from p-substituted benzaldehydes by new “Magic Blue” reagents and correlation analysis of aN values of -fluorosulfonylperfluoroalkyl p-substituted benzoyl nitroxides, (126) 333 Magnetite Preparation of magnetic nanoparticles by the use of self-assembled fluorinated oligomeric aggregates—A new approach to the dispersion of magnetic particles on poly(methyl methacrylate) film surface, (126) 914 Manganese(III) acetate Manganese(III) acetate mediated synthesis of 3-trifluoroacetyl-4,5-dihydrofurans and 3-(dihydrofuran-2(3H)-ylidene)-1,1,1-trifluoroacetones by free radical cyclization. Part 1, (126) 409 Mechanism Trifluoromethylation of carbonyl compounds with sodium trifluoroacetate, (126) 937 Medium hydrogen bond Intermolecular-medium and intramolecular-weak hydrogen bonding chains in the crystals of chiral trifluoromethylated amino alcohols, (126) 1134 Melting point Synthesis of novel lipophilic and/or fluorophilic ethers of perfluoro-tertbutyl alcohol, perfluoropinacol and hexafluoroacetone hydrate via a Mitsunobu reaction: Typical cases of ideal product separation, (126) 641 Membrane Synthesis of perfluorinated carboxylic acid membrane monomers by utilizing liquid-phase direct fluorination, (126) 521 Perfluorocyclobutyl (PFCB) aromatic polyethers: Synthesis and characterization of new sulfonimide containing monomers and fluoropolymers, (126) 653
Membrane separation Direct fluorination—Useful tool to enhance commercial properties of polymer articles, (126) 251 Metallation Room temperature preparation of -chloro-,-difluoroethenylzinc reagent (CF2CClZnCl) by the metallation of HCFC-133a (CF3CH2Cl) and a high yield one-pot synthesis of -chloro-,-difluorostyrenes, (126) 833 Metallic oxides A novel and simple synthetic route to perfluoroalkylacetaldehydes using commercially available alkali halides and metal oxides, (126) 1493 Methanesulfonate Synthesis of 2-chloro-1,1-difluoroallyl mesylates through novel rearrangement and C–C bond formation by their Pd-catalyzed reaction with diethylzinc, (126) 765 Methoxycycloalkenes Synthesis, 17O NMR spectroscopy and structure of 2-trifluoroacetyl-1methoxycycloalkenes, (126) 1396 Methoxydefluorination Regioselectivity and relative substrate activity of difluoroquinolines containing fluorine atoms in benzene ring in reaction with sodium methoxide, (126) 1502 Methyl 3,3,3-trifluoro-2-oxopropanoate Methyl 3,3,3-trifluoropyruvate hemiaminals: Stability and transaminations, (126) 745 Methyl 3,3,3-trifluoropyruvate Methyl 3,3,3-trifluoropyruvate hemiaminals: Stability and transaminations, (126) 745 Methyl fluoroformate Synthesis of ,-dimethoxyfluoropolyethers: reaction mechanism and kinetics, (126) 633 Methylbenzenes EPR studies on H-abstraction from methylbenzenes by “magic blue” reagent, (126) 1130 Methylenecyclopropane Competitive kinetic processes in the thermal rearrangement of 1,1-difluoro2-(dideuteriomethylene)-cyclopropane, (126) 339 Micro structural analysis Peroxidic perfluoropolyether from tetrafluoroethylene oxidation: micro structural analysis by NMR spectroscopy and mechanistic considerations, (126) 141 Peroxidic perfluoropolyether from tetrafluoroethylene oxidation: micro structural analysis by NMR spectroscopy and mechanistic considerations, (126) 685 Microbial Microbial cleavage of C–F bond, (126) 425 Microreactor An efficient stereoselective synthesis of difluoromethylated alkenes in a microreactor, (126) 59 The synthesis of fluorinated materials in microreactors, (126) 956 Microstructure Radical solution copolymerisation of vinylidene fluoride with hexafluoropropene, (126) 577 Microwave Microwave-assisted rapid electrophilic fluorination of 1,3-dicarbonyl derivatives with Selectfluor®, (126) 475 Microwave heating Conservation of [(C2H4NH3)3N]2·(ZrF7)2·H2O layers during the topotactic dehydration of [(C2H4NH3)3N]2·(ZrF7)2·9H2O, (126) 1072 Microwave irradiation Green chemical multi-component one-pot synthesis of fluorinated 2,3-disubstituted quinazolin-4(3H)-ones under solvent-free conditions and their anti-fungal activity, (126) 307 Microwave-irradiation Synthesis of gem-difluorides from aldehydes using DFMBA, (126) 721 Direct conversion of epoxides to vic-difluorides, (126) 962 Miltefosine Synthesis and characterization of photolabeling probes of miltefosine, (126) 739
Subject Index of Volume 126 Mitsunobu ether synthesis Synthesis of novel lipophilic and/or fluorophilic ethers of perfluorotert-butyl alcohol, perfluoropinacol and hexafluoroacetone hydrate via a Mitsunobu reaction: Typical cases of ideal product separation, (126) 641 Mitsunobu reaction Mitsunobu synthesis of symmetrical alkyl and polyfluoroalkyl secondary amines, (126) 1524 Modeling Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 99 Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 289 Molecular complexes 1:1 Complexes of octafluoronaphthalene with trans-stilbene and transazobenzene, (126) 515 Molecular dynamics simulation Intermolecular interaction between the pendant chain of perfluorinated ionomer and methanol, (126) 1312 Molecular fluorine Investigation of reactions between [60]fullerene and molecular fluorine in a CoF2 matrix, (126) 785 Molecular geometry 19F and 13C spectra of fluorinated and partially fluorinated vinyl alkyl ethers, (126) 397 Molecular orbital calculation Intermolecular interaction between the pendant chain of perfluorinated ionomer and methanol, (126) 1312 Monofluoro building block Synthesis, reactions, and applications of fluorine-containing multifunctional carbon compounds, (126) 941 Monomers 19F and 13C spectra of fluorinated and partially fluorinated vinyl alkyl ethers, (126) 397 -Monofluoromethylbenzylamine Asymmetric synthesis of -monofluoromethyl- and -difluoromethylbenzylamines through regioselective hydrogenolysis, (126) 385 Monosubstituted perfluorocyclopentene Reaction of octafluorocyclopentene with various carbon nucleophiles, (126) 125 N,N,N,N-Tetramethylalkanediamines Acyclic tertiary diamines and 1,4,7,10-tetraazacyclododecane with fluorine-containing -diketones: Leading to low melting ionic adducts, (126) 1222 N-alkylindoles Study the reactions of fluoroalkanesulfonyl azides with N-alkylindoles, (126) 113 Nanoparticles Preparation of magnetic nanoparticles by the use of self-assembled fluorinated oligomeric aggregates—A new approach to the dispersion of magnetic particles on poly(methyl methacrylate) film surface, (126) 914 Naphthalene Synthesis of new fluorine-containing dihydrobenzo[c]acridines from trifluoroacetyl dihydronaphthalene and substituted anilines, (126) 1384 Naphthylamine Synthesis of new fluorine-containing dihydrobenzo[c]acridines from trifluoroacetyl dihydronaphthalene and substituted anilines, (126) 1384 N-(Benzylidene)polyfluoroanilines Aza-Morita-Baylis-Hillman reactions of N-(benzylidene)polyfluoroanilines with methyl acrylate and acrylonitrile, (126) 1215 N-chlorosuccinimide A general method for the preparation of perfluoroalkanesulfonyl chlorides, (126) 1196 N-difluoromethylation Reactions of some nitrogen heterocycles with chlorodifluoromethane under conditions of phase-transfer catalysis, (126) 1587
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Nerve agent Fluorinated pyridine derivatives. Part 1. The synthesis of some mono- and bis-quaternary pyridine salts of potential use in the treatment of nerve agent poisoning, (126) 1160 N-heterocycle carbene Group 9 complexes of an N-heterocycle carbene bearing a pentafluorobenzyl substituent: attempted dehydrofluorinative coupling of cyclopentadienyl and N-heterocycle carbene ligands, (126) 451 Nickel-based alloy anode Anodic behavior of nickel-based alloys in the electrolytic production of NF3, (126) 1101 NiO(0 0 1) surface A B3LYP study for the adsorption and catalytic ability of BF3 on NiO(0 0 1) surface, (126) 1463 Nitroaldol reaction The synthesis of fluorinated materials in microreactors, (126) 956 Nitrogen heterocycles From fluoral to heterocycles: a survey of polyfluorinated iminiums chemistry, (126) 189 Reactions of some nitrogen heterocycles with chlorodifluoromethane under conditions of phase-transfer catalysis, (126) 1587 Nitrogen trifluoride Anodic behavior of nickel-based alloys in the electrolytic production of NF3, (126) 1101 Nitrogen-containing heterocycles N-(2-bromotetrafluoroethyl) derivatives of five-membered nitrogen-containing heterocycles, (126) 1342 NMR Synthesis, 17O NMR spectroscopy and structure of 2-trifluoroacetyl-1methoxycycloalkenes, (126) 1396 NMR analysis Radical solution copolymerisation of vinylidene fluoride with hexafluoropropene, (126) 577 NMR spectra 19F and 13C spectra of fluorinated and partially fluorinated vinyl alkyl ethers, (126) 397 NMR spectroscopy Peroxidic perfluoropolyether from tetrafluoroethylene oxidation: micro structural analysis by NMR spectroscopy and mechanistic considerations, (126) 141 Formation and skeletal transformations of perfluoroindan-1-one and perfluoroindan-1,3-dione in the reaction of perfluoroindan with SiO2/SbF5, (126) 437 Peroxidic perfluoropolyether from tetrafluoroethylene oxidation: micro structural analysis by NMR spectroscopy and mechanistic considerations, (126) 685 Synthesis and copolymerisation of fluorinated monomers bearing a reactive lateral group. Part 21. Radical copolymerisation of vinylidene fluoride with 2-hydroperfluorooct-1-ene, (126) 1009 Nuclear magnetic resonance Highly fluorinated graphite prepared from graphite fluoride formed using BF3 catalyst, (126) 1078 Nucleophilic 1,4- and 1,2-trifluoromethylation Nucleophilic trifluoromethylation of RF-containing 4-quinolones, 8-azaand 1-thiochromones with (trifluoromethyl)trimethylsilane, (126) 779 Nucleophilic addition Preparation of fluorohalomethylmagnesium halides using highly active magnesium metal and their reactions, (126) 1390 Nucleophilic aromatic substitution Polyhalogenated heterocyclic compounds. Part 52. [1] Macrocycles from 3,5-dichloro-2,4,6-trifluoropyridine, (126) 1002 Nucleophilic fluorinating agents New fluoride ion reagent from pentafluoropyridine, (126) 571 Nucleophilic reaction Reactions of 4-ethoxy-l,l,l-trifluoro-3-buten-2-one with phosphorous nucleophiles: Diethyl phosphite, tributyl phosphine and tris(diethylamino) phosphine, (126) 931
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Subject Index of Volume 126
Nucleophilic reagents Reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with nucleophilic reagents, (126) 445 Nucleophilic substitution Reaction of octafluorocyclopentene with various carbon nucleophiles, (126) 125 A simple calculational model for predicting the site for nucleophilic substitution in aromatic perfluorocarbons, (126) 727 Fluorinated phosphorus compounds. Part 9. The reactions of bis(fluoro-alkyl) phosphorochloridates with oxygen nucleophiles, (126) 892 Preparation of fluorohalomethylmagnesium halides using highly active magnesium metal and their reactions, (126) 1390 Nucleophilic trifluoromethylation Some studies on nucleophilic trifluoromethylation using the shelf-stable trifluoromethylacetophenone-N,N-dimethyltrimethylsilylamine adduct, (126) 491 O2
Theoretical study on the (O2-HF) complex, (126) 313 O2 Theoretical study on the (O2-HF) complex, (126) 313 Octafluoro[2.2]paracyclophane Suzuki aryl cross-coupling chemistry using derivatives of 1,1,2,2,9,9,10,10octafluoro[2.2]paracyclophane, (126) 483 Octafluorocyclopentene Reaction of octafluorocyclopentene with various carbon nucleophiles, (126) 125 Octafluoronaphthalene 1:1 Complexes of octafluoronaphthalene with trans-stilbene and transazobenzene, (126) 515 OFP Suzuki aryl cross-coupling chemistry using derivatives of 1,1,2,2,9,9,10,10octafluoro[2.2]paracyclophane, (126) 483 Olefination The catalytic olefination reaction of aldehydes and ketones with CBr3CF3, (126) 907 O-nucleophiles New derivatives of trifluoroacetyl acetaldehyde and trifluoroaldol, (126) 355 New derivatives of trifluoroacetyl acetaldehyde and trifluoroaldol, (126) 543 17O NMR Synthesis, 17O NMR spectroscopy and structure of 2-trifluoroacetyl-1methoxycycloalkenes, (126) 1396 O-phenylenediamine Synthesis of 2,3-bis(perfluoroalkyl)quinoxalines and 2,3-bis(perfluoroalkyl)-1,4-benzoxazines from oxides of internal perfluoroolefins, (126) 976 Opposite asymmetric induction Asymmetric synthesis of -monofluoromethyl- and -difluoromethylbenzylamines through regioselective hydrogenolysis, (126) 385 Optical waveguides Novel fluoroacrylated copolymers: synthesis, characterization and properties, (126) 231 Organofluorine Microbial cleavage of C–F bond, (126) 425 Organofluorine compound Electrochemical fluorination of several esters derived from oxolane-2-ylcarboxylic acid, oxolane-2-yl-methanol and oxane-2-yl-methanol, (126) 325 Organoiodine(V) tetrafluorides Preparation of polyfluorinated cycloalk-1-enyl-, alk-1-enyl-, and alkyliodine tetrafluorides using XeF2 in the presence of appropriate Lewis acids as fluorooxidant, (126) 1036 Organolithium reagents Reaction of octafluorocyclopentene with various carbon nucleophiles, (126) 125
Organophosphorus compounds Rapid and high yield oxidation of phosphine, phosphite and phosphinite compounds to phosphine oxides, phosphates and phosphinates using hypofluorous acid–acetonitrile complex, (126) 1054 Organotin(IV) compounds Double-C,N-chelated tri- and diorganotin(IV) fluorides, (126) 1531 1,2,4-Oxadiazole Syntheses of new difluoromethylene benzoxazole and 1,2,4-oxadiazole derivatives, as potent non-nucleoside HIV-1 reverse transcriptase inhibitors, (126) 535 Oxidation Syntheses of new difluoromethylene benzoxazole and 1,2,4-oxadiazole derivatives, as potent non-nucleoside HIV-1 reverse transcriptase inhibitors, (126) 535 Rapid and high yield oxidation of phosphine, phosphite and phosphinite compounds to phosphine oxides, phosphates and phosphinates using hypofluorous acid–acetonitrile complex, (126) 1054 Fluorochromate-catalyzed periodic acid oxidation of alcohols and aldehydes, (126) 1356 Oxidative addition Manganese(III) acetate mediated synthesis of 3-trifluoroacetyl-4,5-dihydrofurans and 3-(dihydrofuran-2(3H)-ylidene)-1,1,1-trifluoroacetones by free radical cyclization. Part 1, (126) 409 Oxide fluoride glass Chemical state analysis of fluorine in various compounds using X-ray fluorescence spectra, (126) 1048 Oxides of internal perfluoroolefins Synthesis of 2,3-bis(perfluoroalkyl)quinoxalines and 2,3-bis(perfluoroalkyl)-1,4-benzoxazines from oxides of internal perfluoroolefins, (126) 976 Oxirane ring-opening Comparative study of the ring opening of 1-CF3-epoxy ethers mediated by Brönsted acids and hexafluoro-2-propanol, (126) 551 Oxypentafluorotungstate A new room temperature ionic liquid of oxyfluorometallate anion: 1-Ethyl3-methylimidazolium oxypentafluorotungstate (EMImWOF5), (126) 1095 31P–19F
HETCOR NMR The preparation and analysis of fluoro-polyphosphates by 19F, 31P, 2D 19F–31P HETCOR and 2D 31P–31P COSY NMR, (126) 883 31P–31P COSY NMR The preparation and analysis of fluoro-polyphosphates by 19F, 31P, 2D 19F–31P HETCOR and 2D 31P–31P COSY NMR, (126) 883 Palladium Synthesis of 2-chloro-1,1-difluoroallyl mesylates through novel rearrangement and C–C bond formation by their Pd-catalyzed reaction with diethylzinc, (126) 765 A novel synthesis of fluorine-containing quaternary amino acid derivatives via palladium-catalyzed allylation reaction, (126) 1517 Parachor Surface tension of fluoroalkanes in a liquid phase, (126) 379 Paracyclophane Suzuki aryl cross-coupling chemistry using derivatives of 1,1,2,2,9,9,10,10octafluoro[2.2]paracyclophane, (126) 483 Partially fluorinated methyl group Asymmetric synthesis of -monofluoromethyl- and -difluoromethylbenzylamines through regioselective hydrogenolysis, (126) 385 Pd(0) coupling The first preparation of the -iodo-,-difluorovinylzinc reagent (CF2CIZnCl) and a high-yield one-pot synthesis of -iodo-,-difluorostyrenes, (126) 457 Room temperature preparation of -chloro-,-difluoroethenylzinc reagent (CF2CClZnCl) by the metallation of HCFC-133a (CF3CH2Cl) and a high yield one-pot synthesis of -chloro-,-difluorostyrenes, (126) 833 PEG-400 Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 99
Subject Index of Volume 126 Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 289 Penta-cyclic Structure determination of the amorphous perfluorinated homopolymer: Poly[perfluoro(4-vinyloxyl-1-butene)], (126) 1403 Pentafluoroethyl alkene Convenient synthesis of fluorinated alkanes and cycloalkanes by hydrogenation of perfluoroalkylalkenes under ultrasound irradiation, (126) 1347 Pentafluoroethyl lithium Beneficial effects of fluorine in the anti-progestin ZK 230211, (126) 217 Pentafluorophenones Silver compounds in synthetic chemistry. Part 2: A convenient synthesis of 2,3,4,5,6-pentafluorophenones, C6F5COR, from pentafluorophenylsilver, AgC6F5, and the corresponding acid chlorides, RCOCl, (126) 1327 2,2,3,3,3-Pentafluoropropylamine Fluorinated phosphorus compounds. Part 11. The reactions of some fluorinated amines with dialkyl and bis(fluoroalkyl) phosphorochloridates, (126) 1144 Pentafluoropyridine New fluoride ion reagent from pentafluoropyridine, (126) 571 Pentafluorostyrene Novel fluorinated block copolymer architectures fuelled by atom transfer radical polymerization, (126) 241 4-Pentenoic acid A convenient synthesis of fluoroalkylated -butyrolactones from polyfluoroalkyl iodides and 4-pentenoic acid catalyzed by Pd(PPh3)4, (126) 319 Perchloryl fluoride Synthesis of -fluorinated phosphonoacetate derivatives using electrophilic fluorine reagents: perchloryl fluoride versus 1-chloromethyl-4-fluoro1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor®), (126) 1467 Perfluorinated acrylate (FA) Surface immobilization of perfluorinated acrylate copolymers by selfcrosslinking, (126) 1570 Perfluorinated ionomers Self-emulsifying polymerization (SEP) of 3,6-dioxa- 7-4-trifluoromethyl perfluorooctyl trifluoromethyl sulfonimide with tetrafluoroethylene, (126) 1057 Perfluorinated surfactant Highly fluoroalkylated amphiphilic triazoles: Regioselective synthesis and evaluation of physicochemical properties, (126) 715 Perfluoro[1-(2-fluorosulfonyl)ethoxy]ethyl benzyl nitroxides EPR studies on H-abstraction from methylbenzenes by “magic blue” reagent, (126) 1130 Perfluoro-1-nitroso-1-[1-(2-fluorosulfonyl)ethoxy]ethane EPR studies on H-abstraction from methylbenzenes by “magic blue” reagent, (126) 1130 Perfluoro(4-vinyloxyl-1-butene) Structure determination of the amorphous perfluorinated homopolymer: Poly[perfluoro(4-vinyloxyl-1-butene)], (126) 1403 2-(Perfluoroalkyl)benzimidazoles Synthesis of 2,3-bis(perfluoroalkyl)quinoxalines and 2,3-bis(perfluoroalkyl)-1,4-benzoxazines from oxides of internal perfluoroolefins, (126) 976 2-Perfluoroalkyl-ethyl-azides Highly fluoroalkylated amphiphilic triazoles: Regioselective synthesis and evaluation of physicochemical properties, (126) 715 Perfluoroalkanesulfonyl chlorides A general method for the preparation of perfluoroalkanesulfonyl chlorides, (126) 1196 Perfluoroalkyl iodide New synthesis of polyfluoroalkyl racemic -amino acids, (126) 1487 Perfluoroalkyl propenyl sulfones An easy preparation of per- and poly-fluoroalkyl propenyl sulfones, (126) 877 Perfluoroalkylated methacrylates Perfluoroalkylated diblock-alkyl methacrylate monomers for biomedical applications. Wettability of their copolymers with HEMA and DEGMA, (126) 595
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Perfluoroalkylated oligoethers Perfluoroalkylated diblock-alkyl methacrylate monomers for biomedical applications. Wettability of their copolymers with HEMA and DEGMA, (126) 595 Perfluoroalkyl-containing compounds Synthesis and structure-activity relationship (SAR) of novel perfluoroalkylcontaining quaternary ammonium salts, (126) 1425 Perfluoroalkylethanals A novel and simple synthetic route to perfluoroalkylacetaldehydes using commercially available alkali halides and metal oxides, (126) 1493 Perfluoroallylation The perfluoroallylation of alkynes and transformation of the products, (126) 771 Perfluorocarbon Rare earth(III) perfluorooctanesulfonates catalyzed Friedel–Crafts alkylation in fluorous biphase system, (126) 830 Rare earth(III) perfluorooctane sulfonates and perfluorooctanesulfonic acid in fluorous solvents: Novel and recyclable catalytic systems for FriedelCrafts acylation of unactivated benzenes, (126) 1191 Regulating to reduce emissions of fluorinated greenhouse gases, (126) 1457 Aldol condensations of aldehydes and ketones catalyzed by rare earth(III) perfluorooctane sulfonates in fluorous solvents, (126) 1553 Perfluorocyclobutyl aryl ethers Perfluorocyclobutyl (PFCB) aromatic polyethers: Synthesis and characterization of new sulfonimide containing monomers and fluoropolymers, (126) 653 Perfluorodiacyl peroxides -Branched-perfluorodiacyl peroxides: preparation and characterization, (126) 587 Perfluoroheterocycle Polyhalogenated heterocyclic compounds. Part 52. [1] Macrocycles from 3,5-dichloro-2,4,6-trifluoropyridine, (126) 1002 Perfluoroindan Formation and skeletal transformations of perfluoroindan-1-one and perfluoroindan-1,3-dione in the reaction of perfluoroindan with SiO2/SbF5, (126) 437 Perfluoroindan-1,3-dione Formation and skeletal transformations of perfluoroindan-1-one and perfluoroindan-1,3-dione in the reaction of perfluoroindan with SiO2/SbF5, (126) 437 Perfluoroindan-1-one Formation and skeletal transformations of perfluoroindan-1-one and perfluoroindan-1,3-dione in the reaction of perfluoroindan with SiO2/SbF5, (126) 437 Perfluoroiodoalkanes Sulfinatodehalogenation reactions of gem-aryl disubstituted methylenecyclopropanes with perfluoroiodoalkanes, (126) 809 Perfluorooctanesulfonic acid Rare earth(III) perfluorooctane sulfonates and perfluorooctanesulfonic acid in fluorous solvents: Novel and recyclable catalytic systems for FriedelCrafts acylation of unactivated benzenes, (126) 1191 Perfluorooxane-2-yl-carbonylfluoride Electrochemical fluorination of several esters derived from oxolane-2-ylcarboxylic acid, oxolane-2-yl-methanol and oxane-2-yl-methanol, (126) 325 Perfluorooxolane-2-yl-carbonyl fluoride Electrochemical fluorination of several esters derived from oxolane-2-ylcarboxylic acid, oxolane-2-yl-methanol and oxane-2-yl-methanol, (126) 325 Perfluoropolyether diiodides Synthesis of , perfluoropolyether iodides, (126) 45 Perfluoropolyethers Peroxidic perfluoropolyether from tetrafluoroethylene oxidation: micro structural analysis by NMR spectroscopy and mechanistic considerations, (126) 141 Peroxidic perfluoropolyether from tetrafluoroethylene oxidation: micro structural analysis by NMR spectroscopy and mechanistic considerations, (126) 685
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Subject Index of Volume 126
Perfluorospiroether Electrochemical fluorination of several esters derived from oxolane-2-ylcarboxylic acid, oxolane-2-yl-methanol and oxane-2-yl-methanol, (126) 325 [(Perfuoroalkyl)methyl]oxiranes Regioselective ring opening of [(perfluoroalkyl)methyl] oxiranes with Nnucleophiles, (126) 1274 Periodic acid Fluorochromate-catalyzed periodic acid oxidation of alcohols and aldehydes, (126) 1356 Peroxide Peroxidic perfluoropolyether from tetrafluoroethylene oxidation: micro structural analysis by NMR spectroscopy and mechanistic considerations, (126) 141 Peroxidic perfluoropolyether from tetrafluoroethylene oxidation: micro structural analysis by NMR spectroscopy and mechanistic considerations, (126) 685 Peroxovanadium complexes NMR study of the [VO(O2)2F]2 ion in solution: Synthesis, vibrational spectra and crystal structure of [NH3CH2CH2NH3][VO(O2)2F], (126) 1297 PET Fluorine chemistry at the millennium, (126) 157 PFTBA Study on the reactions of pyridine with fluorine-containing compounds in the gas-phase by electron impact/Fourier transfer ion cyclotron resonance mass spectrometry, (126) 107 Pharmaceuticals Fluorine chemistry at the millennium, (126) 157 Phase behavior Functions of fluorosurfactants 1: Surface activities-improved and vesicle formation of the short-tailed chain sulfonate salt mixed with a fluorosurfactant, (126) 1266 Phase-transfer catalysis Cocatalysis in phase-transfer catalyzed fluorination of alkyl halides and sulfonates, (126) 209 Reactions of some nitrogen heterocycles with chlorodifluoromethane under conditions of phase-transfer catalysis, (126) 1587 Phenols Synthesis and some chemical properties of 1-aryloxy-2-chloro-1,2-difluoroethenes, (126) 1307 Phenylimino-thiazolidines Synthesis and fungicidal activity of fluorine-containing phenylimino-thiazolidines derivatives, (126) 297 (Phenylthio)difluoromethylation Fluoride-induced nucleophilic (phenylthio)difluoromethylation of carbonyl compounds with [difluoro(phenylthio)methyl]trimethylsilane (TMS–CF2SPh), (126) 529 Pheromone analogs Stereoselective synthesis of insect sex pheromone analogs having a fluorine atom on their double bonds, (126) 1185 Phosphate-type Synthesis of phosphate-type fluorocarbon–hydrocarbon hybrid surfactants and their adsorption onto calcium hydroxyapatite, (126) 301 Phosphazenates [P3N3F5NS(O)Cl] and [{P4N4F6(NS(Cl)N)}2]2, the first chloro iminoand chloro bis(imino) sulfinates, (126) 1044 Phosphazenophane [P3N3F5NS(O)Cl] and [{P4N4F6(NS(Cl)N)}2]2, the first chloro iminoand chloro bis(imino) sulfinates, (126) 1044 Photocatalysis Fluorine-doped TiO2 powders prepared by spray pyrolysis and their improved photocatalytic activity for decomposition of gas-phase acetaldehyde, (126) 69 Photochemistry Bis(trifluoromethyl)dicarbonate, CF3OC(O)OC(O)OCF3, (126) 984
Synthesis of fluorocyclobutanones and their use in the synthesis of fluoronucleosides, (126) 1565 Photocrosslinking Novel fluoroacrylated copolymers: synthesis, characterization and properties, (126) 231 Photolabeling Synthesis and characterization of photolabeling probes of miltefosine, (126) 739 Photolabeling probes Synthesis and characterization of photolabeling probes of miltefosine, (126) 739 Physical properties Physical properties of four , -dimethoxyfluoropolyethers, (126) 465 Piezoelectric detector 2,2-Bis(3-allyl-4-hydroxyphenyl)hexafluoropropane and fluorosiloxane as coating materials for nerve agent sensors, (126) 1252 Piperazine From fluoral to heterocycles: a survey of polyfluorinated iminiums chemistry, (126) 189 Piperidine From fluoral to heterocycles: a survey of polyfluorinated iminiums chemistry, (126) 189 Plaque-controlling surface Synthesis of phosphate-type fluorocarbon–hydrocarbon hybrid surfactants and their adsorption onto calcium hydroxyapatite, (126) 301 Plasticized fluorinated lithium salt New fluorine-containing plasticized low lattice energy lithium salt for plastic batteries, (126) 842 Polar effects EPR studies on H-abstraction from p-substituted benzaldehydes by new “Magic Blue” reagents and correlation analysis of aN values of -fluorosulfonylperfluoroalkyl p-substituted benzoyl nitroxides, (126) 333 Polycondensation Synthesis and characterization of soluble polyimides based on trifluoromethylated aromatic dianhydride and substitutional diaminetriphenylmethanes, (126) 819 Polyether blocks Novel fluorinated block copolymer architectures fuelled by atom transfer radical polymerization, (126) 241 Polyfluoroalkyl iodides A convenient synthesis of fluoroalkylated -butyrolactones from polyfluoroalkyl iodides and 4-pentenoic acid catalyzed by Pd(PPh3)4, (126) 319 Polyfluoroarenes Polyfluoroaromatic compounds with a –NCClR group—a reactive type of polyfluoroarene, (126) 860 Poly-hexafluoropropylene oxide New derivatives of poly-hexafluoropropylene oxide from the corresponding alcohol, (126) 281 Poly-HFPO New derivatives of poly-hexafluoropropylene oxide from the corresponding alcohol, (126) 281 Poly-HFPO acetate New derivatives of poly-hexafluoropropylene oxide from the corresponding alcohol, (126) 281 Poly-HFPO alcohol sodium salt New derivatives of poly-hexafluoropropylene oxide from the corresponding alcohol, (126) 281 Poly-HFPO allyl ether New derivatives of poly-hexafluoropropylene oxide from the corresponding alcohol, (126) 281 Poly(hydrogen fluorides) Alkaline earth metal poly(hydrogen fluorides) hexafluoroarsenates(V) and hexafluorophosphate(V): M2(H2F3)(HF2)2(AF6) (M = Ca, A = As; M = Sr, A = As, P), (126) 1088 Polyimide Synthesis and characterization of soluble polyimides based on trifluoromethylated aromatic dianhydride and substitutional diaminetriphenylmethanes, (126) 819
Subject Index of Volume 126 Polymer film Preparation of magnetic nanoparticles by the use of self-assembled fluorinated oligomeric aggregates—A new approach to the dispersion of magnetic particles on poly(methyl methacrylate) film surface, (126) 914 Polymerisation On the attempted synthesis of salts with the trimethyl[bis(pentafluorophenyl)]silicate ion, [Me3Si(C6F5)2]—A polyphenyl problem, (126) 1303 PPA Synthesis of new fluorine-containing dihydrobenzo[c]acridines from trifluoroacetyl dihydronaphthalene and substituted anilines, (126) 1384 Preparation -Branched-perfluorodiacyl peroxides: preparation and characterization, (126) 587 Primary amine A convenient three-component reaction for the construction of multifunctional 6-fluoroalkyl-1,2,3,4-tetrahydropyrimidines, (126) 1539 Primary and secondary aliphatic amines Regioselective ring opening of [(perfluoroalkyl)methyl] oxiranes with Nnucleophiles, (126) 1274 Proton exchange membrane Self-emulsifying polymerization (SEP) of 3,6-dioxa- 7-4-trifluoromethyl perfluorooctyl trifluoromethyl sulfonimide with tetrafluoroethylene, (126) 1057 p-Toluenesulfonyl fluoride Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 99 Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 289 Pyridine Study on the reactions of pyridine with fluorine-containing compounds in the gas-phase by electron impact/Fourier transfer ion cyclotron resonance mass spectrometry, (126) 107 Polyhalogenated heterocyclic compounds. Part 52. [1] Macrocycles from 3,5-dichloro-2,4,6-trifluoropyridine, (126) 1002 Pyridinium fluorochromate (PFC) Fluorochromate-catalyzed periodic acid oxidation of alcohols and aldehydes, (126) 1356 Pyrolysis of perfluorooctanoic acid Gas-phase NMR studies of the thermolysis of perfluorooctanoic acid, (126) 1510 Quadricyclane Cycloaddition reaction of quadricyclane and fluoroolefins, (126) 601 Reaction of quadricyclane with fluorinated sulfur-containing compounds, (126) 1332 Quaternary ammonium salt Synthesis and structure-activity relationship (SAR) of novel perfluoroalkylcontaining quaternary ammonium salts, (126) 1425 Quaternization Acyclic tertiary diamines and 1,4,7,10-tetraazacyclododecane with fluorine-containing -diketones: Leading to low melting ionic adducts, (126) 1222 Quinazolines Green chemical multi-component one-pot synthesis of fluorinated 2,3-disubstituted quinazolin-4(3H)-ones under solvent-free conditions and their anti-fungal activity, (126) 307 Radical copolymerisation Synthesis and copolymerisation of fluorinated monomers bearing a reactive lateral group. Part 21. Radical copolymerisation of vinylidene fluoride with 2-hydroperfluorooct-1-ene, (126) 1009 Radical cyclization Manganese(III) acetate mediated synthesis of 3-trifluoroacetyl-4,5-dihydrofurans and 3-(dihydrofuran-2(3H)-ylidene)-1,1,1-trifluoroacetones by free radical cyclization. Part 1, (126) 409 Radical initiation New synthesis of polyfluoroalkyl racemic -amino acids, (126) 1487
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Radical transformation Sulfinatodehalogenation reactions of gem-aryl disubstituted methylenecyclopropanes with perfluoroiodoalkanes, (126) 809 Radicals Bis(trifluoromethyl)dicarbonate, CF3OC(O)OC(O)OCF3, (126) 984 Raman spectrum Alkaline earth metal poly(hydrogen fluorides) hexafluoroarsenates(V) and hexafluorophosphate(V): M2(H2F3)(HF2)2(AF6) (M = Ca, A = As; M = Sr, A = As, P), (126) 1088 Rare earth Chemical state analysis of fluorine in various compounds using X-ray fluorescence spectra, (126) 1048 Rare earth(III) perfluorooctanesulfonates Rare earth(III) perfluorooctanesulfonates catalyzed Friedel–Crafts alkylation in fluorous biphase system, (126) 830 Rare earth(III) perfluorooctane sulfonates and perfluorooctanesulfonic acid in fluorous solvents: Novel and recyclable catalytic systems for FriedelCrafts acylation of unactivated benzenes, (126) 1191 Aldol condensations of aldehydes and ketones catalyzed by rare earth(III) perfluorooctane sulfonates in fluorous solvents, (126) 1553 Rate constant Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 99 Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 289 Reaction mechanism Isomerization reaction of 1,1,2,2-tetrafluorethan on fluorinated chromia: A consideration of the adsorption behavior on the catalyst, (126) 1017 Reaction rate Synthesis of ,-dimethoxyfluoropolyethers: reaction mechanism and kinetics, (126) 633 Reaction with polyfluorinated sulfides, disulfides and sulfonyl chlorides Reaction of quadricyclane with fluorinated sulfur-containing compounds, (126) 1332 Reactivity ratio Radical solution copolymerisation of vinylidene fluoride with hexafluoropropene, (126) 577 Synthesis and copolymerisation of fluorinated monomers bearing a reactive lateral group. Part 21. Radical copolymerisation of vinylidene fluoride with 2-hydroperfluorooct-1-ene, (126) 1009 Recycling Recycling of fluorinated axially dissymmetric ligand with fluorous solvent, (126) 415 Reduction New derivatives of trifluoroacetyl acetaldehyde and trifluoroaldol, (126) 355 New derivatives of trifluoroacetyl acetaldehyde and trifluoroaldol, (126) 543 Refrigeration Regulating to reduce emissions of fluorinated greenhouse gases, (126) 1457 Regioselective hydrogenolysis Asymmetric synthesis of -monofluoromethyl- and -difluoromethylbenzylamines through regioselective hydrogenolysis, (126) 385 Regioselectivity Highly fluoroalkylated amphiphilic triazoles: Regioselective synthesis and evaluation of physicochemical properties, (126) 715 Regioselectivity and relative substrate activity of difluoroquinolines containing fluorine atoms in benzene ring in reaction with sodium methoxide, (126) 1502 Regio-selectivity Synthesis and the reactions of trifluoromethylated 1,2,3-triketones 2(het)arylhydrazones and 4,7-dihydroazolo[5,1-c]triazines, (126) 1230 RF-containing 4-quinolones Nucleophilic trifluoromethylation of RF-containing 4-quinolones, 8-aza- and 1-thiochromones with (trifluoromethyl)trimethylsilane, (126) 779 Rieke magnesium Preparation of fluorohalomethylmagnesium halides using highly active magnesium metal and their reactions, (126) 1390
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Subject Index of Volume 126
Ring opening Regioselective ring opening of [(perfluoroalkyl)methyl] oxiranes with Nnucleophiles, (126) 1274 Ring-opening reaction of MCPs Sulfinatodehalogenation reactions of gem-aryl disubstituted methylenecyclopropanes with perfluoroiodoalkanes, (126) 809 Room temperature ionic liquid A new room temperature ionic liquid of oxyfluorometallate anion: 1Ethyl-3-methylimidazolium oxypentafluorotungstate (EMImWOF5), (126) 1095 Room temperature molten salt A new room temperature ionic liquid of oxyfluorometallate anion: 1-Ethyl3-methylimidazolium oxypentafluorotungstate (EMImWOF5), (126) 1095 Ruppert’s reagent Beneficial effects of fluorine in the anti-progestin ZK 230211, (126) 217 Second sphere coordination Second sphere coordination in anion binding: Synthesis, spectroscopic characterization and single crystal X-ray structure determination of hexaamminecobalt(III) dichloride tetrafluoroborate, (126) 1543 Secondary lithium battery Surface fluorination and electrochemical behavior of petroleum cokes graphitized at medium and high temperatures for secondary lithium battery, (126) 1028 Selectfluor Microwave-assisted rapid electrophilic fluorination of 1,3-dicarbonyl derivatives with Selectfluor®, (126) 475 Selectfluor® Synthesis of -fluorinated phosphonoacetate derivatives using electrophilic fluorine reagents: perchloryl fluoride versus 1-chloromethyl-4-fluoro1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor®), (126) 1467 Selective fluorination Direct fluorination of coumarin, 6-methyl-coumarin and 7-alkoxycoumarins, (126) 1377 Selective formation Investigation of reactions between [60]fullerene and molecular fluorine in a CoF2 matrix, (126) 785 Self-assembly Pentaerythritol tetrakis(4-iodo-2,3,5,6-tetrafluorophenyl) ether: a tecton for the self-assembly of double strand 1D infinite chains, (126) 197 Self-crosslinking Surface immobilization of perfluorinated acrylate copolymers by selfcrosslinking, (126) 1570 Self-emulsifying polymerization Self-emulsifying polymerization (SEP) of 3,6-dioxa- 7-4-trifluoromethyl perfluorooctyl trifluoromethyl sulfonimide with tetrafluoroethylene, (126) 1057 Self-organization Characterization of hydrocarbon and fluorocarbon microdomains formed in aqueous solution of associative polymers: A molecular probe technique, (126) 1409 Semifluorinated alkanes Critical influence of the alkane length in surface and liquid–crystalline properties of perfluorodecyl-n-alkanes, (126) 79 Sensor Synthesis of a new fluorinated fluorescent -cyclodextrin sensor, (126) 393 SEP Self-emulsifying polymerization (SEP) of 3,6-dioxa- 7-4-trifluoromethyl perfluorooctyl trifluoromethyl sulfonimide with tetrafluoroethylene, (126) 1057 SF5-fluoroalkyl aromatics Site directed synthesis of mono and disubstituted SF5-polyfluoroalkyl benzenes, (126) 1202 [3,3] Sigmatropic rearrangement Synthesis of 2-chloro-1,1-difluoroallyl mesylates through novel rearrangement and C–C bond formation by their Pd-catalyzed reaction with diethylzinc, (126) 765
Silicon Cocatalysis in phase-transfer catalyzed fluorination of alkyl halides and sulfonates, (126) 209 Silicon dioxide Formation and skeletal transformations of perfluoroindan-1-one and perfluoroindan-1,3-dione in the reaction of perfluoroindan with SiO2/SbF5, (126) 437 Silver Silver compounds in synthetic chemistry. Part 2: A convenient synthesis of 2,3,4,5,6-pentafluorophenones, C6F5COR, from pentafluorophenylsilver, AgC6F5, and the corresponding acid chlorides, RCOCl, (126) 1327 Skeletal transformations Formation and skeletal transformations of perfluoroindan-1-one and perfluoroindan-1,3-dione in the reaction of perfluoroindan with SiO2/SbF5, (126) 437 Sodium 1-chloro-2,2,2-trifluoroethanesulfinate An easy preparation of per- and poly-fluoroalkyl propenyl sulfones, (126) 877 Sodium dithionite Synthesis of ,-difluoro--butyrolactones via ethyl iododifluoroacetate, (126) 63 Sulfinatodehalogenation reactions of gem-aryl disubstituted methylenecyclopropanes with perfluoroiodoalkanes, (126) 809 Sodium perfluoroalkyl-sulfinates An easy preparation of per- and poly-fluoroalkyl propenyl sulfones, (126) 877 Sodium trifluoroacetate Trifluoromethylation of carbonyl compounds with sodium trifluoroacetate, (126) 937 Solid polymer electrolyte Self-emulsifying polymerization (SEP) of 3,6-dioxa- 7-4-trifluoromethyl perfluorooctyl trifluoromethyl sulfonimide with tetrafluoroethylene, (126) 1057 New fluorine-containing plasticized low lattice energy lithium salt for plastic batteries, (126) 842 Solid–liquid phase transfer catalysis Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 99 Novelties of solid–liquid phase transfer catalysed synthesis of p-toluenesulfonyl fluoride from p-toluenesulfonyl chloride, (126) 289 Solubility Synthesis of novel lipophilic and/or fluorophilic ethers of perfluoro-tertbutyl alcohol, perfluoropinacol and hexafluoroacetone hydrate via a Mitsunobu reaction: Typical cases of ideal product separation, (126) 641 Synthesis and characterization of soluble polyimides based on trifluoromethylated aromatic dianhydride and substitutional diaminetriphenylmethanes, (126) 819 Sonogashira cross-coupling reaction The perfluoroallylation of alkynes and transformation of the products, (126) 771 Sonogashira reaction Difluorocarbene chemistry: synthesis of gem-difluorocyclopropenylalkynes and 3,3,3,3-tetrafluorobicyclopropyl-1,1-dienes, (126) 39 Difluorocarbene chemistry: synthesis of gem-difluorocyclopropenylalkynes and 3,3,3,3-tetrafluorobicyclopropyl-1,1-dienes, (126) 93 19Sn NMR spectra Fluorinated stannanes. Part 2. The stereospecific synthesis of fluorinated stannanes via a Barbier-type reaction between fluorinated halides and tributyltin chloride mediated by zinc or cadmium, (126) 797 Spin trapping EPR studies on H-abstraction from methylbenzenes by “magic blue” reagent, (126) 1130 Spin-delocalization EPR studies on H-abstraction from p-substituted benzaldehydes by new “Magic Blue” reagents and correlation analysis of aN values of -fluorosulfonylperfluoroalkyl p-substituted benzoyl nitroxides, (126) 333 Spin–spin coupling
Subject Index of Volume 126 19F
and 13C spectra of fluorinated and partially fluorinated vinyl alkyl ethers, (126) 397 Spray pyrolysis Fluorine-doped TiO2 powders prepared by spray pyrolysis and their improved photocatalytic activity for decomposition of gas-phase acetaldehyde, (126) 69 Stacking interactions Supramolecular synthons in crystals of partially fluorinated fused aromatics: 1,2,3,4-Tetrafluoronaphthalene and its aza-analogue 1,3,4-trifluoroisoquinoline, (126) 1281 Star-shaped polymers Novel fluorinated block copolymer architectures fuelled by atom transfer radical polymerization, (126) 241 Steam distillation Synthesis of novel lipophilic and/or fluorophilic ethers of perfluoro-tertbutyl alcohol, perfluoropinacol and hexafluoroacetone hydrate via a Mitsunobu reaction: Typical cases of ideal product separation, (126) 641 Stereochemistry Synthesis of -fluoro--amino acids by Claisen rearrangement, (126) 557 Stereoselectivity Nucleophilic trifluoromethylation. Some recent reagents and their stereoselective aspects, (126) 173 s-Triazino[1,2-a]benzimidazole Synthesis and biological activity of fluorinated 2-amino-4-aryl-3,4-dihydro[1,3,5]triazino[1,2-a]benzimidazoles, (126) 759 Strontium hexafluoroarsenate and hexafluorophosphate Alkaline earth metal poly(hydrogen fluorides) hexafluoroarsenates(V) and hexafluorophosphate(V): M2(H2F3)(HF2)2(AF6) (M = Ca, A = As; M = Sr, A = As, P), (126) 1088 Structure Double-C,N-chelated tri- and diorganotin(IV) fluorides, (126) 1531 Structure of hydrogen bond Intermolecular-medium and intramolecular-weak hydrogen bonding chains in the crystals of chiral trifluoromethylated amino alcohols, (126) 1134 Structure-property correlation Synthesis of novel lipophilic and/or fluorophilic ethers of perfluoro-tertbutyl alcohol, perfluoropinacol and hexafluoroacetone hydrate via a Mitsunobu reaction: Typical cases of ideal product separation, (126) 641 Substitution reaction Reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with nucleophilic reagents, (126) 445 Sulfenylchlorides A new method for the preparation of polyfluoroalkanedithiocarboxylates, (126) 369 Sulfinatodehalogenation Sulfinatodehalogenation reactions of gem-aryl disubstituted methylenecyclopropanes with perfluoroiodoalkanes, (126) 809 Fluoroalkylation of porphyrins: Preparation and characterization of mesoand -fluoroalkyl-5,15-diarylporphyrins, (126) 1321 Sulfonimide Self-emulsifying polymerization (SEP) of 3,6-dioxa- 7-4-trifluoromethyl perfluorooctyl trifluoromethyl sulfonimide with tetrafluoroethylene, (126) 1057 Sulfonimides Perfluorocyclobutyl (PFCB) aromatic polyethers: Synthesis and characterization of new sulfonimide containing monomers and fluoropolymers, (126) 653 Sulfur hexafluoride Regulating to reduce emissions of fluorinated greenhouse gases, (126) 1457 Sulfur hexafluoride derivatives Site directed synthesis of mono and disubstituted SF5-polyfluoroalkyl benzenes, (126) 1202 Supercritical conditions Synthesis of , perfluoropolyether iodides, (126) 45 Supramolecular synthons Supramolecular synthons in crystals of partially fluorinated fused aromatics: 1,2,3,4-Tetrafluoronaphthalene and its aza-analogue 1,3,4-trifluoroisoquinoline, (126) 1281
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Surface dispersion Preparation of magnetic nanoparticles by the use of self-assembled fluorinated oligomeric aggregates—A new approach to the dispersion of magnetic particles on poly(methyl methacrylate) film surface, (126) 914 Surface modification Effect of surface fluorination on the electrochemical behavior of petroleum cokes for lithium ion battery, (126) 265 Surface fluorination and electrochemical behavior of petroleum cokes graphitized at medium and high temperatures for secondary lithium battery, (126) 1028 Surface-fluorinated graphite anode materials for Li-ion batteries, (126) 1111 Surface modification of polymers Direct fluorination—Useful tool to enhance commercial properties of polymer articles, (126) 251 Surface tension Surface tension of fluoroalkanes in a liquid phase, (126) 379 Synthesis of a novel type of hybrid fluorocarbon ionic surfactants containing polyoxyethlene chain, (126) 888 Surface-activity Functions of fluorosurfactants 1: Surface activities-improved and vesicle formation of the short-tailed chain sulfonate salt mixed with a fluorosurfactant, (126) 1266 Suzuki aryl cross-coupling Suzuki aryl cross-coupling chemistry using derivatives of 1,1,2,2,9,9,10,10octafluoro[2.2]paracyclophane, (126) 483 Suzuki coupling reaction One-pot synthesis of bromodifluoroacetimidoyl halides and its Suzuki coupling reactions with aryl boronic acids, (126) 791 The synthesis and application of fluorous boronates without perfluorinated solvents, (126) 996 Suzuki cross-coupling reaction The perfluoroallylation of alkynes and transformation of the products, (126) 771 Symmetrical disubstituted perfluorocyclopentene Reaction of octafluorocyclopentene with various carbon nucleophiles, (126) 125 Synthesis Synthesis of , perfluoropolyether iodides, (126) 45 Synthesis and biological activities of hydroxyl-protected fluorine-containing 4,4-dihydroxylmethyl-2-aryl-iminothiazolidines, (126) 53 Synthesis of ,-difluoro--butyrolactones via ethyl iododifluoroacetate, (126) 63 Synthesis and bioactivity of 2-cyanoacrylates containing a trifluoromethylphenyl moiety, (126) 87 Fluorine chemistry at the millennium, (126) 157 Synthesis and fungicidal activity of fluorine-containing phenylimino-thiazolidines derivatives, (126) 297 Synthesis of perfluorinated carboxylic acid membrane monomers by utilizing liquid-phase direct fluorination, (126) 521 A direct and rapid route to ,-difluoroacylsilanes from trifluoroethanol, (126) 611 Silver compounds in synthetic chemistry. Part 2: A convenient synthesis of 2,3,4,5,6-pentafluorophenones, C6F5COR, from pentafluorophenylsilver, AgC6F5, and the corresponding acid chlorides, RCOCl, (126) 1327 A detailed account of a convenient lab-scale preparation of AsF5 via direct fluorination of AsF3, (126) 1368 Synthesis and bioactivity of fluorine compounds containing isoxazolylamino and phosphonate groups, (126) 1419 Synthesis of arsenic pentafluoride by static fluorination of As2O3 in a closed system, (126) 1432 Tantalum Two tantalum fluorides templated with tren: [H4tren](TaF7)2·H2O and [H4tren](TaF7)2, (126) 1246 TAS fluoride [P3N3F5NS(O)Cl] and [{P4N4F6(NS(Cl)N)}2]2, the first chloro iminoand chloro bis(imino) sulfinates, (126) 1044
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Subject Index of Volume 126
Teflon® Fluorine chemistry at the millennium, (126) 157 3-Trifluoroacetyl-4,5-dihydrofuran Manganese(III) acetate mediated synthesis of 3-trifluoroacetyl-4,5-dihydrofurans and 3-(dihydrofuran-2(3H)-ylidene)-1,1,1-trifluoroacetones by free radical cyclization. Part 1, (126) 409 3,3,3,3-Tetrafluorobicyclopropyl-1,1-dienes Difluorocarbene chemistry: synthesis of gem-difluorocyclopropenylalkynes and 3,3,3,3-tetrafluorobicyclopropyl-1,1-dienes, (126) 39 Difluorocarbene chemistry: synthesis of gem-difluorocyclopropenylalkynes and 3,3,3,3-tetrafluorobicyclopropyl-1,1-dienes, (126) 93 4,4,4-Trifluorobutan-2-one The synthesis of fluorinated materials in microreactors, (126) 956 4-(Trifluoromethyl)pyridine Fluorinated pyridine derivatives. Part 1. The synthesis of some mono- and bis-quaternary pyridine salts of potential use in the treatment of nerve agent poisoning, (126) 1160 Tetrafluoroborate ion Second sphere coordination in anion binding: Synthesis, spectroscopic characterization and single crystal X-ray structure determination of hexaamminecobalt(III) dichloride tetrafluoroborate, (126) 1543 Tetrafluoroethylene Novel ionic liquids—Imidazolium salts with a difluoromethylene fragment directly bonded to the nitrogen atom, (126) 669 Tetrafluorophenylazides Synthesis and characterization of photolabeling probes of miltefosine, (126) 739 Tetrakis(triphenylphosphine)palladium A convenient synthesis of fluoroalkylated -butyrolactones from polyfluoroalkyl iodides and 4-pentenoic acid catalyzed by Pd(PPh3)4, (126) 319 Thermal stability Thermal stability and bond dissociation energy of fluorinated polymers: A critical evaluation, (126) 625 Thermal treatment Highly fluorinated graphite prepared from graphite fluoride formed using BF3 catalyst, (126) 1078 Thermodynamic properties Physical properties of four , -dimethoxyfluoropolyethers, (126) 465 Thermolysis -Branched-perfluorodiacyl peroxides: preparation and characterization, (126) 587 Thermostability Synthesis and characterization of soluble polyimides based on trifluoromethylated aromatic dianhydride and substitutional diaminetriphenylmethanes, (126) 819 Thiol addition reactions Reactions of 2-(perfluoroalkyl)ethane thiols with 1,6-heptadiene and 4-substituted 1,6-heptadienes: the synthesis of RFethanethio-cyclopentanoic and -dioic acids; and, “geminal-twin-tail” bis-(perfluoroalkylethanethio)alkanoic acids, (126) 7 Thiopyran A new method for the preparation of polyfluoroalkanedithiocarboxylates, (126) 369 Three-component system Green chemical multi-component one-pot synthesis of fluorinated 2,3-disubstituted quinazolin-4(3H)-ones under solvent-free conditions and their anti-fungal activity, (126) 307 Tin compounds Cocatalysis in phase-transfer catalyzed fluorination of alkyl halides and sulfonates, (126) 209 Titanium X-ray crystal structures on the hydrolysis path of [{Ti(C5Me4R)F3}2]: Water adduct [{Ti(C5Me4Et)F3}2(H2O)]·(H2O), oxoaqua complex [Ti7F21O(C5Me4Et)5(H2O)2] and oxo complex [Ti8F22O2(C5Me4H)6]·2CHCl3, (126) 1065 Titanium dioxide Fluorine-doped TiO2 powders prepared by spray pyrolysis and their improved photocatalytic activity for decomposition of gas-phase acetaldehyde, (126) 69
Transmetallation Room temperature preparation of -chloro-,-difluoroethenylzinc reagent (CF2CClZnCl) by the metallation of HCFC-133a (CF3CH2Cl) and a high yield one-pot synthesis of -chloro-,-difluorostyrenes, (126) 833 Trehalase inhibitors Synthesis and biological activities of hydroxyl-protected fluorine-containing 4,4-dihydroxylmethyl-2-aryl-iminothiazolidines, (126) 53 Tren Two tantalum fluorides templated with tren: [H4tren](TaF7)2·H2O and [H4tren](TaF7)2, (126) 1246 1,2,3-Triazoles Highly fluoroalkylated amphiphilic triazoles: Regioselective synthesis and evaluation of physicochemical properties, (126) 715 Triazolines Study on the reactions of fluoroalkanesulfonyl azides with indole derivatives, (126) 824 Tributyl phosphine Reactions of 4-ethoxy-l,l,l-trifluoro-3-buten-2-one with phosphorous nucleophiles: Diethyl phosphite, tributyl phosphine and tris(diethylamino) phosphine, (126) 931 Tributyltin hydride New synthesis of polyfluoroalkyl racemic -amino acids, (126) 1487 Triethyl difluorophosphonoacetate Synthesis of -fluorinated phosphonoacetate derivatives using electrophilic fluorine reagents: perchloryl fluoride versus 1-chloromethyl-4-fluoro1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor®), (126) 1467 Triethyl fluorophosphonoacetate Synthesis of -fluorinated phosphonoacetate derivatives using electrophilic fluorine reagents: perchloryl fluoride versus 1-chloromethyl-4-fluoro1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor®), (126) 1467 Triethyl fluorophosphonopropionate Synthesis of -fluorinated phosphonoacetate derivatives using electrophilic fluorine reagents: perchloryl fluoride versus 1-chloromethyl-4-fluoro1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor®), (126) 1467 Triethylborane New synthesis of polyfluoroalkyl racemic -amino acids, (126) 1487 Triflic acid Electrophilic aromatic fluorination with fluorine: meta-Directed fluorination of anilines, (126) 661 Trifluoroacetamides Nucleophilic trifluoromethylation. Some recent reagents and their stereoselective aspects, (126) 173 Trifluoroacetic acid Facile synthesis of 2,2,2-trifluoroacetimidoyl chloride derivatives, (126) 1140 Trifluoroacetimidoyl chloride Facile synthesis of 2,2,2-trifluoroacetimidoyl chloride derivatives, (126) 1140 Trifluoroacetimidoyl metals A rich chemistry of fluorinated imidoyl halides, (126) 165 Trifluoroacetyl Synthesis of a new fluorinated fluorescent -cyclodextrin sensor, (126) 393 Trifluoroacetylcycloalkenes Synthesis, 17O NMR spectroscopy and structure of 2-trifluoroacetyl-1methoxycycloalkenes, (126) 1396 Trifluoroethanol A direct and rapid route to ,-difluoroacylsilanes from trifluoroethanol, (126) 611 2,2,2-Trifluoroethylamine Fluorinated phosphorus compounds. Part 11. The reactions of some fluorinated amines with dialkyl and bis(fluoroalkyl) phosphorochloridates, (126) 1144 Trifluorolactic acid A rich chemistry of fluorinated imidoyl halides, (126) 165
Subject Index of Volume 126 Trifluoromethanesulfinamides Nucleophilic trifluoromethylation. Some recent reagents and their stereoselective aspects, (126) 173 Trifluoromethanesulfonamide Mitsunobu synthesis of symmetrical alkyl and polyfluoroalkyl secondary amines, (126) 1524 -(Trifluoromethyl)carbinols Nucleophilic trifluoromethylation. Some recent reagents and their stereoselective aspects, (126) 173 Trifluoromethyl First asymmetric synthesis of -amino--trifluoromethylated aldehyde, (126) 705 Trifluoromethyl alkene Convenient synthesis of fluorinated alkanes and cycloalkanes by hydrogenation of perfluoroalkylalkenes under ultrasound irradiation, (126) 1347 Trifluoromethyl carbinols Some studies on nucleophilic trifluoromethylation using the shelf-stable trifluoromethylacetophenone-N,N-dimethyltrimethylsilylamine adduct, (126) 491 Trifluoromethyl ketones Comparative study of the ring opening of 1-CF3-epoxy ethers mediated by Brönsted acids and hexafluoro-2-propanol, (126) 551 Trifluoromethyl synthon Methyl 3,3,3-trifluoropyruvate hemiaminals: Stability and transaminations, (126) 745 Trifluoromethyl-1,3-dicarbonyl Manganese(III) acetate mediated synthesis of 3-trifluoroacetyl-4,5-dihydrofurans and 3-(dihydrofuran-2(3H)-ylidene)-1,1,1-trifluoroacetones by free radical cyclization. Part 1, (126) 409 Trifluoromethylated amino alcohols Intermolecular-medium and intramolecular-weak hydrogen bonding chains in the crystals of chiral trifluoromethylated amino alcohols, (126) 1134 Trifluoromethylated compounds Asymmetric synthesis of both enantiomers of syn-(3-trifluoromethyl)cysteine derivatives, (126) 499 Trifluoromethylated leucine analogue A novel synthesis of fluorine-containing quaternary amino acid derivatives via palladium-catalyzed allylation reaction, (126) 1517 Trifluoromethylation Nucleophilic trifluoromethylation. Some recent reagents and their stereoselective aspects, (126) 173 Trifluoromethylation of carbonyl compounds with sodium trifluoroacetate, (126) 937 Trifluoromethyl-epoxy ethers Comparative study of the ring opening of 1-CF3-epoxy ethers mediated by Brönsted acids and hexafluoro-2-propanol, (126) 551 Trifluoromethylketone An efficient dehyrohalogenation method for the synthesis of ,,-trifluorostyrenes, -chloro-,-difluorostyrenes and E-1-arylperfluoroalkenes, (126) 1174 Trifluoromethylphenylcyanoacrylate Synthesis and bioactivity of 2-cyanoacrylates containing a trifluoromethylphenyl moiety, (126) 87 (Trifluoromethyl)trimethylsilane Nucleophilic trifluoromethylation of RF-containing 4-quinolones, 8-azaand 1-thiochromones with (trifluoromethyl)trimethylsilane, (126) 779 Trifluorostyrenes Site directed synthesis of mono and disubstituted SF5-polyfluoroalkyl benzenes, (126) 1202 1,2,2-Trifluorostyrene An efficient dehyrohalogenation method for the synthesis of ,,-trifluorostyrenes, -chloro-,-difluorostyrenes and E-1-arylperfluoroalkenes, (126) 1174 Trifluorovinyl aryl ethers Perfluorocyclobutyl (PFCB) aromatic polyethers: Synthesis and characterization of new sulfonimide containing monomers and fluoropolymers, (126) 653
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Trifluorovinyllithium The first preparation of the -iodo-,-difluorovinylzinc reagent (CF2CIZnCl) and a high-yield one-pot synthesis of -iodo-,-difluorostyrenes, (126) 457 Trimethyl(pentafluorophenyl)silane On the attempted synthesis of salts with the trimethyl[bis(pentafluorophenyl)]silicate ion, [Me3Si(C6F5)2]—A polyphenyl problem, (126) 1303 Tri-n-butyltin chloride Fluorinated stannanes. Part 2. The stereospecific synthesis of fluorinated stannanes via a Barbier-type reaction between fluorinated halides and tributyltin chloride mediated by zinc or cadmium, (126) 797 Tris(diethylamino) phosphine Reactions of 4-ethoxy-l,l,l-trifluoro-3-buten-2-one with phosphorous nucleophiles: Diethyl phosphite, tributyl phosphine and tris(diethylamino) phosphine, (126) 931 Tris(fluoroalkyl) phosphite Fluorinated phosphorus compounds. Part 10. Bis(fluoroalkyl) S-alkyl phosphorothiolates and tris(fluoroalkyl) phosphorothionates, (126) 902 Tris(fluoroalkyl) phosphorothionate Fluorinated phosphorus compounds. Part 10. Bis(fluoroalkyl) S-alkyl phosphorothiolates and tris(fluoroalkyl) phosphorothionates, (126) 902 Tris(perfluoroalkyl)trifluorophosphate New ionic liquids with tris(perfluoroalkyl)trifluorophosphate (FAP) anions, (126) 1150 Tungsten oxide fluoride A new room temperature ionic liquid of oxyfluorometallate anion: 1-Ethyl3-methylimidazolium oxypentafluorotungstate (EMImWOF5), (126) 1095 Two-dimensional NMR Carbon–fluorine two-dimensional NMR correlation spectra, (126) 363 Ultrasonication Highly selective electrochemical fluorination of organic compounds in ionic liquids, (126) 181 Ultrasound Convenient synthesis of fluorinated alkanes and cycloalkanes by hydrogenation of perfluoroalkylalkenes under ultrasound irradiation, (126) 1347 Ultrasound irradiation Synthesis and bioactivity of fluorine compounds containing isoxazolylamino and phosphonate groups, (126) 1419 Unsymmetrical disubstituted perfluorocyclopentene Reaction of octafluorocyclopentene with various carbon nucleophiles, (126) 125 Vesicles Functions of fluorosurfactants 1: Surface activities-improved and vesicle formation of the short-tailed chain sulfonate salt mixed with a fluorosurfactant, (126) 1266 Vibrational spectroscopy Copper(I) hexafluoroantimonate – an example of a compound with CuI in a solely fluorine environment, (126) 803 Bis(trifluoromethyl)dicarbonate, CF3OC(O)OC(O)OCF3, (126) 984 Vinyl compounds 19F and 13C spectra of fluorinated and partially fluorinated vinyl alkyl ethers, (126) 397 Vinyl fluorides Synthesis of -fluoro--amino acids by Claisen rearrangement, (126) 557 Vinylene carbonate Novel fluoroacrylated copolymers: synthesis, characterization and properties, (126) 231 Vinylidene fluoride Radical solution copolymerisation of vinylidene fluoride with hexafluoropropene, (126) 577 Synthesis and copolymerisation of fluorinated monomers bearing a reactive lateral group. Part 21. Radical copolymerisation of vinylidene fluoride with 2-hydroperfluorooct-1-ene, (126) 1009
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Subject Index of Volume 126
Viscosity New ionic liquids with tris(perfluoroalkyl)trifluorophosphate (FAP) anions, (126) 1150 Water-soluble polymers Characterization of hydrocarbon and fluorocarbon microdomains formed in aqueous solution of associative polymers: A molecular probe technique, (126) 1409 WDX–XRF Chemical state analysis of fluorine in various compounds using X-ray fluorescence spectra, (126) 1048 Weak hydrogen bond Intermolecular-medium and intramolecular-weak hydrogen bonding chains in the crystals of chiral trifluoromethylated amino alcohols, (126) 1134 Well-architectured fluoropolymers Update on fluoroelastomers: from perfluoroelastomers to fluorosilicones and fluorophosphazenes, (126) 221 Wettability of methacrylate copolymers Perfluoroalkylated diblock-alkyl methacrylate monomers for biomedical applications. Wettability of their copolymers with HEMA and DEGMA, (126) 595 WOF4 A new room temperature ionic liquid of oxyfluorometallate anion: 1-Ethyl3-methylimidazolium oxypentafluorotungstate (EMImWOF5), (126) 1095 WOF5 A new room temperature ionic liquid of oxyfluorometallate anion: 1-Ethyl3-methylimidazolium oxypentafluorotungstate (EMImWOF5), (126) 1095 Xanthates Synthesis and coordination chemistry of fluorinated xanthate ligands, (126) 1117 Xenon difluoride Preparation of polyfluorinated cycloalk-1-enyl-, alk-1-enyl-, and alkyliodine tetrafluorides using XeF2 in the presence of appropriate Lewis acids as fluorooxidant, (126) 1036
X-ray crystallography First X-ray structure of hexaamminecobalt(III) salt with complex fluoroanion: Synthesis and characterization of [Co(NH3)6]X·SiF6·nH2O, where X = Cl, Br, I and NO3 and crystal structure of [Co(NH3)6]Cl·SiF6·2H2O, (126) 967 [P3N3F5NS(O)Cl] and [{P4N4F6(NS(Cl)N)}2]2, the first chloro iminoand chloro bis(imino) sulfinates, (126) 1044 Second sphere coordination in anion binding: Synthesis, spectroscopic characterization and single crystal X-ray structure determination of hexaamminecobalt(III) dichloride tetrafluoroborate, (126) 1543 X-ray diffraction Bis(trifluoromethyl)dicarbonate, CF3OC(O)OC(O)OCF3, (126) 984 Gold nanoparticles entrapped in heavily fluorinated compounds, (126) 1435 X-ray structure Synthesis and coordination chemistry of perfluoroalkylated dithiophosphate ligands, (126) 507 Polyhalogenated heterocyclic compounds. Part 52. [1] Macrocycles from 3,5-dichloro-2,4,6-trifluoropyridine, (126) 1002 X-ray crystal structures on the hydrolysis path of [{Ti(C5Me4R)F3}2]: Water adduct [{Ti(C5Me4Et)F3}2(H2O)]·(H2O), oxoaqua complex [Ti7F21O(C5Me4Et)5(H2O)2] and oxo complex [Ti8F22O2(C5Me4H)6]·2CHCl3, (126) 1065 Synthesis and coordination chemistry of fluorinated xanthate ligands, (126) 1117 Supramolecular synthons in crystals of partially fluorinated fused aromatics: 1,2,3,4-Tetrafluoronaphthalene and its aza-analogue 1,3,4-trifluoroisoquinoline, (126) 1281 An unusual fluoroketene reaction product, (126) 1496 X-ray structure determination NMR study of the [VO(O2)2F]2 ion in solution: Synthesis, vibrational spectra and crystal structure of [NH3CH2CH2NH3][VO(O2)2F], (126) 1297 X-ray structures Zinc chloride A new method for the preparation of polyfluoroalkanedithiocarboxylates, (126) 369