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Synthesis and structure-properties relationship studies of biodegradable hydroxylammonium-based protic ionic liquids
Synthesis and Structure-Properties Relationship Studies of Biodegradable Hydroxylammonium-based Protic Ionic Liquids Andromachi Tzani, Marianthi Elmaloglou, Charαlampos Kyriazis, Dionysia Aravopoulou, Ioannis Kleidas, Achilleas Papadopoulos, Efstathia Ioannou, Apostolos Kyritsis, Epaminondas Voutsas, Anastasia Detsi PII: DOI: Reference:
S0167-7322(16)31868-2 doi:10.1016/j.molliq.2016.09.086 MOLLIQ 6364
To appear in:
Journal of Molecular Liquids
Received date: Accepted date:
11 July 2016 9 September 2016
Please cite this article as: Andromachi Tzani, Marianthi Elmaloglou, Charlampos Kyriazis, Dionysia Aravopoulou, Ioannis Kleidas, Achilleas Papadopoulos, Efstathia Ioannou, Apostolos Kyritsis, Epaminondas Voutsas, Anastasia Detsi, Synthesis and StructureProperties Relationship Studies of Biodegradable Hydroxylammonium-based Protic Ionic Liquids, Journal of Molecular Liquids (2016), doi:10.1016/j.molliq.2016.09.086
This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain.
ACCEPTED MANUSCRIPT Synthesis and Structure-Properties Relationship Studies of Biodegradable Hydroxylammonium-
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the weakening of the interionic H-bond interaction in D2O. If this hypothesis is true, then it means
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that the H-D exchange process in this case is very slow, a phenomenon that has been recently reported for imidazolium-based room temperature ionic liquids.[20],[21] In any case, this is an interesting
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A series of 16 protic ionic liquids (PILs) have been synthesized and characterized. The studied PILs show biodegradability levels between 41-64% (BOD5 method). PILs possessing the cyclopentane carboxylate anion are not toxic to A.sallina. Tg and viscosity data provide evidence that the studied PILs exhibit fragile behaviour.
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S0167-7322(16)31868-2 doi:10.1016/j.molliq.2016.09.086 MOLLIQ 6364
To appear in:
Journal of Molecular Liquids
Received date: Accepted date:
11 July 2016 9 September 2016
Please cite this article as: Andromachi Tzani, Marianthi Elmaloglou, Charlampos Kyriazis, Dionysia Aravopoulou, Ioannis Kleidas, Achilleas Papadopoulos, Efstathia Ioannou, Apostolos Kyritsis, Epaminondas Voutsas, Anastasia Detsi, Synthesis and StructureProperties Relationship Studies of Biodegradable Hydroxylammonium-based Protic Ionic Liquids, Journal of Molecular Liquids (2016), doi:10.1016/j.molliq.2016.09.086
This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain.
ACCEPTED MANUSCRIPT Synthesis and Structure-Properties Relationship Studies of Biodegradable Hydroxylammonium-
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the weakening of the interionic H-bond interaction in D2O. If this hypothesis is true, then it means
MA
that the H-D exchange process in this case is very slow, a phenomenon that has been recently reported for imidazolium-based room temperature ionic liquids.[20],[21] In any case, this is an interesting
D
observation that definitely merits further investigation which is currently in progress by our research
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1143,0
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22,6
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186,0
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256,5
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183,9
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28,9
507,7
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17,1
24,5
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32,8
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26,7
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A series of 16 protic ionic liquids (PILs) have been synthesized and characterized. The studied PILs show biodegradability levels between 41-64% (BOD5 method). PILs possessing the cyclopentane carboxylate anion are not toxic to A.sallina. Tg and viscosity data provide evidence that the studied PILs exhibit fragile behaviour.
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