The future of reverse osmosis in water desalination

The future of reverse osmosis in water desalination

Des&mtion,30(1979)64-74 OElsevierScientific PublishingCompany.Am&x&m-PrintedinTl~eNetherlands THE EUKJRE OF REVERSE~ISINW?YfERD~INATloN DR. JORK K...

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Des&mtion,30(1979)64-74 OElsevierScientific PublishingCompany.Am&x&m-PrintedinTl~eNetherlands

THE EUKJRE

OF REVERSE~ISINW?YfERD~INATloN

DR. JORK K. BEASJXY E-1. du Pant de Nenkxrs&co.,

Wilmington, Delaware USA

Water desalination has emerged as one of the nrxst iqortant Watef shortages through the world. osmosis

Arrong Water desalination

(R9, is one of the nvst innovative and promising.

Since 1970, nvre than

3,000 new RO plants desalting brackish water have been built. RO plants are operating

in nore than 20 countries.

methods of alleviating techniques, reverse

(ref. 1) Seawater

By the end of 1979, about 12

million gallons per day of seawater Rc capacity will be installed_

(ref, 2)

Between the late 1960's and 1977, FCI has grown even faster than desalination generally, which grew nearly 40 percent per year.

(ref. 3)

In the foreseeable future, reverse osnosis is expected to grow at a rate of between 20 to 30 percent and will constitute the major portion of new brackish water capacity.

Seawater FCI is expected to grow at an even faster rate.

This RU groWth will be sustained during the coming years in at least two ways: m First, expansion of installed capacity based on the current state of the art involving applications similar to those underway naw, sonxs newer applications like water x-use

and the construction of larger plants, and

_ Second, innovations in the state of the art leading to better rerrbranes and plant design which will make RCI even nore economically attractive. trJ0ways, innovation will have the greatest impact.

Of the

I will discuss it first

and then turn to expansion based on the current state cf the art.

-'Ihe improved nembranes of the 1980's will reject nore salt, permit the flow of n-ore water , andbenoredurable. central wurse

In these respects, they will be part of the

of Ro innovation typified by Reid and Breton in 1958 and Lomb and

Sourirajan in 1960 who developed n-erbranes which effectively separated salt from water and set the stage for the conmercial applications of the 70's. Theenhanceddurabilitywillbepartof pioneered by 0.1 mnt

(ref. 4)

a trend trrward tougharamidmxrdxanes

in the late 60's and early 70's. 69

Iiopefully, the new menbranes

70

BEASLE!Z

of the 80's will mer

K. C. Qmmbasam's

which he issued in 1976.

call for new and better membranes.

(ref. 5)

Better salt rejection, productivity and durability are the crane the 80's because, with their achievemnt, be reduced.

the real wst

This will permit even broader use of the technology.

better salt rejection could elimina te theneedand desalt very high salinity seawater.

goaL= of

of lU) pm%XX!d

water will

kr

ezranple,

cost of tklopass systests to

Better salt rejection plus better productivity

could permit lower pressure operation and thus reduce energy requiremnts, already are half those of mlti-stage

!l!he growth of R0 will depend on achieving these advance swhich, depend on major

which

flash (MSF) distillation.

research efforts by industry and governsent.

inturn,wil.l

In fact, thiswas

a conclusion of a recent study of RO undertaken by the Fluor corporation. 3zsearch efforts are underway and they will be expanded. DLI Ppnt are comnitted to RO research.

Du Fmt,

(ref. 6)

For inslxnce,weat

noted for its innovatiorbhas

major l33 research programs underway at its manufacturing pIantS and its corporate research facilities at the EU Pbnt Experimzntal Station in Wilmington, Delaware. Other organizations also are making similar comaitnents.

Wearealreadyseeing

soltvz of the results in papers presented at this IDEA Cohference and those published elsewhere. This research will. include a great deal of new work on reverse osmosis membranes, but will also include research on the construction of permators, of water for reverse osmsis,

on the pretreatment

and on the design and construction of all the

components of a complete desalination plant. In this paper, I will briefly examine two areas:

membrane materials and better

energy efficiency in system design. Aramid polymers will continue to replace cellulose acetate polymers in mnbrane manufacture because they resist mechanical change, as well as chemical and biological attack.

As I reported tothisconference

tsmyearsago,duringextensive~~t

research programs in which sore than 100 different polymrs nmbranes

were evaluated,

of cellulose acetate and other cellulose esters shmed

considerable

promise in initial tests but frequently deteriorated during extended testing. Cellulose acetate rmrbranes are subject to biological attack and mst within a narrow pH range to prevent hydrolysis.

(ref. 7)

be used

R. L. Riley also has reported that

the family of aromatic polyamides is "destined to dominate the reverse -is scene because their transport, mechanical, biological and chemical properties are generally superior to cellulose acetate." Rnergy recovery devices will beama streamtoapermzator solution.

must be rejectedwith

This rejectstreamhas

its pressure mltiplied

(ref. 8)

increasingly inportant. allof

apotentially

by its volume.

Partofthe

thedissolvedsalts

still in

recoverableenergyfx@valentto

Recoveryof

thisenergymaynotbevery

important in the desalination of brackish water at high conversions.

feed

Rut in

BEASLEY

71

reverse osmsis of seawater, the reject stream is about two-thirds of the feed StlZalll. I fOreCc%St that devices will be developxl to recover this energy frQn

therejects~eamandtousethisenergytohelpplmp energy recoverydeviceand

the feedstream.

the feedpmpmyactuallybe

The

xmuntedonthe-

punping of the feed stream cunsums less net

shaft, with the net result that

-gYDevelcment efforts by several RO system manufacturers are rapidly leading toconmxcially

feasible energyrecoverydevicescapableofcapturingmchof

thehydraulicpressureenergyavailable

in theconcentratedischarge

Calculations indicate thattheenergyconsumd canbecutinhalf

to17

systemscurrentlyunder demmstratingthis

to20

stream.

by seawater rewseosllosis

kw/l000gallonsofproduct.

tests~rtthisconclusionand

systems

Energy recovery commzrcialplants

concept are under construction.

Stork Werkspoor Water of Pmsterdamhas incorporated energy recovery ina seawater FKD plant it is buildixq on &rto gpdplantwillconsistof

is to be used for driving the pmp

ExPzANs1oxBAsFDcJN

Santa, Madeira,

(ref. 9)

T%e 130,000

The reject water from three of the units

four units.

of the fourth unit by mans

of a water turbine.

c!uFmmm-~

The expansion of water desalting, based on current Ef) technolcgy, will also boost the n&r technolqy

and size of FU3 plants,

will contribute

Becauseof

thenmhlar

New aqlications

based on current

too.

natureof

into plants of any desired size.

reverseosmsis Aspeoplegain

units, theycanbe

ass&lec?

experience in building andoperating

larger and larger plants, still largeroneswi~bepLannedandconstructed. Thistmndhasalreadybegun.

Figure 1 shows the largest m

plants plotted

against their year of construction.

Flpum I

Largest

RO~laf&nstallatlon

1970

1972 1974 1976 1976 1980 1962 Yearof Construction

BRAS=

72

Plant sizes havegrawn

fromsmall

gallonsper

day (GPD) experimentalplants

toa~th60millionC;PD~icipalmrplexscheduledtobeginaperat~this year

in Etiydah,

Saudi Arabia.

(ref. 10)

l%e U.S. Covernnmnt plans to mtruct

a 92 million GPD cc.a@ex in Yuma, Ariz., with start-upscheduled 1980's.

inearly

(ref. ll)

The world's largest industrial KC desalination plant is now under construction and will begin operating facility at mstaganem,

in early 1980.

(ref. 12)

This aultimillion dollar

Algeria, willbecapableofpurifying

llmilliongXUcns

of brackish surface water daily, for useatapaparmilloperatedby firm, Societe Rationale des Industries de la Cellulose the Riyadh comlex,

theAlgerian

(SONIC).

This plant, like

is being built by Degrenont, S.A. of Prance with "Fernmsep"

permeators. In 1979, the world's largest seawater R0 plant was comnissioned by Saudi Arabia. This plant provides 3.2 CGPD of p&able

water to the inhabitants of Jeddah.

In 1960, the first of nine seawater -R0 desalination Machinoinport, started up.

(ref. 13)

units purchased by V/O

a foreign trade organization of the Soviet government, will be (ref. 14)

These plants, which will use IXI Pant's B-10 "Pennasep"

permeators, will provide 3.3 million gallons per day of desalted water.

This water

will be converted to steam and then injected into oil wells to reduce crude oil viscosity and thus increase oil production rates.

The amplex

of desalination

units, built by Water Services of America, Milwaukee, Wis., will be located near the Caspian Sea in the U.S.S.R. Several desalting firms have completed designs for large, 10 million GPD ship/ barge rrounted RO desalination plants.

The self

contained,

relccatableplants,

with construction Periods of less than two years ,areexpectedtomakelargeinroads into the seawater. market previously dominated by nn.rlti-stageflash (MSF) distillation. In addition to the water desalting application represented by these plants, reverse osmosis merrhranes will be used for other applications.

They can, for exanple,

be used to separate water and dissolved organic compounds and to separate organics from organics.

Hcwever, the treaunent of waste water streams will receive more

attention. In a recent waste water application , aTexas England is using "Permasep" permeators, -ether

Instruments, Ltd.,

pl.antinBedford,

with associated filtration, chemical

testing and cleaning eguipnent, to recover up to 70 Percent of the 20,000 gallons per hour of fonzrly

discharged waste water.

(ref. 15)

The plant

was supplied and

installed by Permutit & Roby, a mznber of the Portals Water Treatment Croup.

73

BEASLEY

CXXCXUSION Newapplicaticmsofexisting

RQtechnology suchas thewastewater

plantin

Bedford, ?zilgland.The expansion of water desalination generally and RU innovation will be the prime engines of FO growth in the 1980's. That growth is expected to be between 20 aud 30 percent with seawater RO dfmand growing at an even faster rate. Achievenest of this growth will depend, in large part, on the develoL.mantof new mnbranes with better salt rejection, productivity and durability. The widespread adoption of man+xane materials similar to aramid polymers could lead tothesebreakthroughs. FuTthenmre, advances in RO design, suchasenergyrecoverysystems,should bringbothcapitalandoperatingcmstsof FinaYy,

thet&logydowneven

further.

these advances will be the result of research ccmnitmnts by industry

and governments. Research will mke

the FG~technology of the 80's even mre

ecouomicalthan the ROtechnolcqyof

the 70's. Du Font already has a major research

prqram

underway, both at our manufacturing plants and at our coqxxate research

facilities at the Du Font E%perirrentalStation in Wilmington, Delaware,

Desalting Plants Inventory Report No. 6, Office of Water Research and Technology, U.S. Department of the Interior, *tober 1977. R.A. Kellar, Seawater RO Desalting Mxing Into Big League, World Water, 2(1979) 44-45, Liverpool, England. J.D. Birkett, Wxldwide atlook for Desalination Industry Through 1985, A.D. Little l%pact Services, Inc., Canbridge, M& USA, October 13, 1978. C-E. Reid and E.J. Breton, J. Applied FoIy Sci l(1959) 133. S. Loeb and S. Sourirajan, Pdvan. Chem. Sci. 38(1963) ll7K-C. channaba%ppa, Need for New and Better Menbranes, Desalination, 18(1976) 15-42. Desalting Plans and Progress, an Evaluation of the State of the Art and l%ture Research and Develmt Requiremmts, Fluor mgineers and Constructors, Inc., IKVine, California, prepared for Office of Water Research and Techmlogy, U.S. Department of the Interior, (MRT Contract 14-34-1001-7707,Jarmarx 1978. J.K. Beasley, The Evaluation and Selection of pblymeric IG&erials for Reverse Osmsis Nambranes, Desalination, 22(1977) 181-189, R.L. Riley, et. al., Spiral-M Poly (Ether/Amide)'Iih-Film Coqmsite Membrane System, Hznbrane Separation Technology Conference, Clemson University, __ Clemson, South Carolina, August 2-6, 1976. 9 R. Seaton, et. al., The mrld's First Large Seawater Reverse Osmxiis Desalination Plant at Jeddah, Kingdcm of Saudi Arabia, Prcceedings Sixth International symp>sium, Fresh Water from the Sea, 1978. 10 J.J. Allard, et. al., Pbtable Water Supply of Riyadh (The Saudi Arabia Kingdm'sCapitalCity) by ReverseOsnvsisDesalting Plants. Proceedingsof the First D%alination Congress of the American Continent, Mexico City, October 24-29, i976, Desalination, ZO(1976) 227-238, B. EXics.son,Riyadh's Record Plant Takes Shape,~rldWater, 2 (1979) 4&43, Liverpool, -land. llDesaltingTrendSetat9!5-nqdPlant, EhgineeringNewsRecord,hkxember 3, 1977, P. lx. I.2Desalination in Algeria, Middle East Week, London, June 29, 1978.

74

BZASLEP

I_3 R-E, Seaton, Largest Seawater EU3 Plant Uses NS Menkane Material, World Water, 2 (1979)38-39. 14 Reverse Omvsis to be used for Soviet Oil Recovery Project, NiSIA Newsletter, 6(1979) 4. I5 Reverse Osmxis Saves Water, ConsultingEngineer,kxdon, April 1979.