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Vapor Pressure – Inorganic Compounds
Chapter 2
Vapor Pressure – Inorganic Compounds Carl L. Yaws, Marco A. Satyro
TABULATION RESULTS
EXAMPLE
The tabulation is arranged by alphabetical order (Ac, Al, Am, ……) to provide ease of use in quickly locating the data by using the chemical formula. The compound name, chemical abstracts registry number (CAS No), and Antoine coefficients are provided in the adjacent columns. The range of application is denoted by minimum and maximum temperatures (TMIN and TMAX). Temperatures outside the range of application should not be used. The next column provides the code for the tabulation, which is based on both experimental data and estimated values. In preparing the tabulation, a literature search was conducted to identify data source publications (53–115). Both experimental values for the property under consideration and parameter values for estimation of the property are included in the source publications. The publications were screened and copies of appropriate data were made. These data were then keyed into the computer to provide a database of values for compounds for which experimental data are available. The database also served as a basis to check the accuracy of the estimation methods. Upon completion of data collection, estimation of values for the remaining compounds was performed. The estimates are primarily based on literature methods and empirical procedures developed by the author. If initial analysis using the estimates is favorable, follow-up experimental determination is recommended. This is especially true for highly polar and high molecular weight compounds. A code of 1 in the tabulation is based on experimental data. A code of 2 indicates an estimate. The estimates with a code of 3 should be considered rough approximations. The estimates with a code of 2 are more accurate. For those substances which undergo decomposition (such as nitro compounds with explosive decomposition and very large compounds with thermal decomposition) prior to attaining the boiling point temperature, the boiling point temperature is a hypothetical value. A comparison of calculated and data values is shown in Figure 2 for a representative compound. The graph discloses favorable agreement of equation and data.
Calculate the vapor pressure of oxygen (O2) at –178.24°C. Substitution of the Antoine coefficients from the table and temperature into the equation for vapor pressure yields:
The Yaws Handbook of Vapor Pressure. http://dx.doi.org/10.1016/B978-0-12-802999-2.00002-7 Copyright © 2015 Elsevier Inc. All rights reserved.
log10 P = 6.83706 – 339.2095/(–178.24 + 268.70) = 3.08738 P = 103.08738 = 1222.87 mmHg
FIGURE 2 Vapor Pressure of Oxygen
315
Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
FORMULA Ac Ag AgBr AgCl AgI Al AlB3H12 AlBr3 AlCl3 AlF3 AlI3 Al2O3 Al2S3O12 Am Ar As AsBr3 AsCl3 AsF3 AsF5 AsH3 AsI3 As2O3 At Au B BBr3 BCl3 BF3 BH2CO BI3 B2D6 B2F4 B2H5Br B2H6 B3H6N3 B4H10 B5H9 B5H11 B10H14 Ba BaF2 BaO Be BeB2H8 BeBr2 BeCl2 BeF2 BeI2 Bi BiBr3 BiCl3 BrFO3 BrF3 BrF5 Br2 C CCl2O CF2O CH4N2O CH4N2S CNBr CNCl CNF CO COS COSe CO2 CS2 C2N2 C3S2 Ca CaCl2 CaF2 Cd CdBr2 CdCl2 CdF2 CdI2 CdO
NAME actinium silver silver bromide silver chloride silver iodide aluminum aluminum borohydride aluminum bromide aluminum chloride aluminum fluoride aluminum iodide aluminum oxide aluminum sulfate americium argon arsenic arsenic bromide arsenic trichloride arsenic trifluoride arsenic pentafluoride arsine arsenic triiodide arsenic trioxide astatine gold boron boron tribromide boron trichloride boron trifluoride borine carbonyl boron triiodide diborane, deutero diborane, tetrafluoro diborane hydrobromide diborane borazine tetraborane pentaborane pentaborane decaborane barium barium fluoride barium oxide beryllium beryllium borohydride beryllium bromide beryllium chloride beryllium fluoride beryllium iodide bismuth bismuth tribromide bismuth trichloride perbromyl fluoride bromine trifluoride bromine pentafluoride bromine graphite carbonyl chloride carbonyl fluoride urea thiourea cyanogen bromide cyanogen chloride cyanogen fluoride carbon monoxide carbonyl sulfide carbon oxyselenide carbon dioxide carbon disulfide cyanogen carbon subsulfide calcium calcium chloride calcium fluoride cadmium cadmium bromide cadmium chloride cadmium fluoride cadmium iodide cadmium oxide
CAS No
A
B
C
TMIN
TMAX
code
7440-34-8 7440-22-4 7785-23-1 7783-90-6 7783-96-2 7429-90-5 16962-07-5 7727-15-3 7446-70-0 7784-18-1 7784-23-8 1344-28-1 10043-01-3 7440-35-9 7440-37-1 7440-38-3 7784-33-0 7784-34-1 7784-35-2 7784-36-3 7784-42-1 7784-45-4 1327-53-3 7440-68-8 7440-57-5 7440-42-8 10294-33-4 10294-34-5 7637-07-2 --13517-10-7 20396-66-1 13965-73-6 --19287-45-7 6569-51-3 18283-93-7 19624-22-7 18433-84-6 17702-41-9 7440-39-3 7787-32-8 1304-28-5 7440-41-7 17440-85-6 7787-46-4 7787-47-5 7787-49-7 7787-53-3 7440-69-9 7787-58-8 7787-60-2 25251-03-0 7787-71-5 7789-30-2 7726-95-6 7782-42-5 75-44-5 353-50-4 57-13-6 62-56-6 506-68-3 506-77-4 1495-50-7 630-08-0 463-58-1 1603-84-5 124-38-9 75-15-0 460-19-5 627-34-9 7440-70-2 10043-52-4 7789-75-5 7440-43-9 7789-42-6 10108-64-2 7790-79-6 7790-80-9 1306-19-0
8.85429 8.10019 6.21353 8.61748 6.93625 8.24073 7.55341 6.73909 15.75427 12.51245 6.93225 10.96973 -0.14253 9.46480 6.84064 10.60233 7.22542 7.44841 7.30253 5.74019 6.88872 7.30188 4.99289 9.64649 8.16676 9.44507 6.58372 6.82139 7.29112 7.47035 6.93670 6.30635 7.59073 7.79587 6.83515 7.19573 7.23266 6.46328 9.78620 4.60815 6.47688 8.20759 12.51502 8.08396 15.84584 11.58765 11.21338 9.03258 10.16571 7.90580 8.73564 7.31869 7.43651 7.72974 7.85138 7.27906 13.52595 7.14063 7.41143 10.45495 7.57639 6.36918 7.55525 6.75643 6.72527 7.00667 7.17236 7.58828 7.21790 7.04339 7.51838 7.10583 9.22000 7.47685 7.66023 10.71437 9.79511 8.15105 7.72916 9.13973
20734.8351 12288.3589 5179.6010 10917.5071 6695.6629 14524.8870 1419.8359 1552.6852 5649.0504 14983.2501 2000.0426 25616.3739 651.9161 14359.6923 340.2707 6313.8843 1953.4063 1670.0897 1189.5299 366.9598 790.0472 2551.7378 1001.4246 3910.8049 16053.2805 26209.9893 1114.5997 972.2015 618.3678 893.9306 1698.2347 512.0855 1126.3767 1454.1004 654.3293 1254.5863 1190.0772 948.6930 2656.8429 512.9508 7779.9111 12116.9768 21900.0000 13696.6102 6333.8132 6557.5715 6220.1613 7534.4285 5302.6269 9022.0737 4109.4999 2847.8317 1195.8000 1673.9500 1488.6143 1321.8955 41703.0146 1063.6278 765.5881 4591.7946 2173.4632 722.7494 1251.9891 689.9197 295.2279 833.0673 1024.3828 861.8205 1303.7883 770.7952 1986.8195 6959.2899 13570.0000 10678.0076 4757.6158 9463.5051 9774.8935 9504.5987 4256.7258 11107.3677
273.15 191.93 52.17 356.11 145.03 192.25 259.36 147.43 258.81 279.63 111.66 186.85 -975.34 273.15 271.80 216.09 228.62 235.64 211.22 181.14 259.60 209.53 6.99 244.23 180.98 190.34 210.01 234.22 240.01 258.95 210.58 241.99 273.15 279.55 257.97 237.76 255.46 204.82 321.75 48.92 266.45 20.38 273.15 148.52 398.57 274.67 264.49 55.76 240.89 231.44 248.90 194.71 260.10 219.48 258.99 241.80 280.60 242.13 252.08 273.76 198.99 142.72 254.99 224.02 268.24 252.06 260.38 271.88 254.39 206.27 250.50 162.92 273.15 -210.04 228.44 364.07 453.72 55.45 135.98 215.65
1599.85 1009.85 569.00 912.00 820.00 1209.00 -52.20 81.30 100.00 744.00 178.00 2147.95 572.00 965.85 -189.37 280.00 41.80 -11.40 -2.50 -117.90 -116.92 164.00 133.70 88.00 952.85 2075.00 -45.00 -107.00 -128.37 -139.20 43.00 -154.90 -40.00 -93.30 -165.50 -63.00 -90.90 -40.40 -50.20 60.00 638.00 1368.00 1950.00 823.85 1.00 289.00 291.00 686.00 283.00 668.00 261.00 230.50 -75.15 25.85 -69.30 -7.30 2565.85 -127.78 -111.26 67.50 181.00 -0.14 -6.50 -76.40 -205.00 -138.80 -120.00 -56.57 -111.57 -95.80 14.00 591.00 836.85 1417.85 119.85 373.00 618.00 1112.00 296.00 1000.00
3198.00 2180.00 1502.00 1547.00 1506.00 2517.66 44.50 255.00 180.00 1276.00 382.00 2980.00 770.05 1082.85 -122.29 601.00 221.00 130.00 57.80 -52.80 99.85 329.50 467.15 259.00 2856.00 3799.00 91.00 178.80 -12.25 -64.00 200.00 -92.50 -14.00 16.30 16.65 53.00 18.00 295.30 63.00 163.80 1897.00 2250.00 2000.00 2483.85 90.00 474.00 482.00 1169.00 487.00 1564.00 453.00 447.00 28.85 157.85 40.50 311.00 3634.85 181.85 23.85 94.90 580.85 39.94 175.85 -46.00 -140.23 105.65 -22.00 31.04 278.85 -21.10 130.80 1482.00 1007.85 2533.35 767.00 844.00 960.00 1748.00 742.00 1559.00
2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
316
Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160
FORMULA CdS Ce CeBr3 CeCl3 ClF ClFO2 ClFO3 ClF3 ClF5 ClNO2 ClO2 Cl2 Cl2O Cl2O4 Cl2O6 Cl2O7 Co CoCl2 CoNC3O4 Cr CrC6O6 CrCl2 CrCl3 CrO2Cl2 CrO3 Cs CsBr CsCl CsF CsI Cu CuBr CuCl CuCl2 CuI DBr DCN DCl DF DI D2 D2O Dy Er Eu FHO3S FNO FNO2 FNO3 F2 F2O F2O2 Fe FeC5O5 FeCl2 FeCl3 FeI2 Fr Ga GaBr3 GaCl3 Gd Ge GeBr4 GeCl4 GeHCl3 GeH4 GeS Ge2H6 Ge3H8 HBr HCN HCl HClO3S HClO4 HF HI HNO3 HN3 HPO2F2
NAME cadmium sulfide cerium cerium bromide cerium chloride chlorine monofluoride chloryl fluoride perchloryl fluoride chlorine trifluoride chlorine pentafluoride nitryl chloride chlorine dioxide chlorine chlorine monoxide chlorine perchlorate chlorine hexoxide chlorine heptoxide cobalt cobalt chloride cobalt nitrosyl tricarbonyl chromium chromium carbonyl chromium chloride chromium chloride chromium oxychloride chromium oxide cesium cesium bromide cesium chloride cesium fluoride cesium iodide copper cuprous bromide cuprous chloride cupric chloride copper iodide deuterium bromide deuterium cyanide deuterium chloride deuterium fluoride deuterium iodide deuterium deuterium oxide dysprosium erbium europium fluorosulfonic acid nitrosyl fluoride nitryl fluoride fluorine nitrate fluorine fluorine oxide difluorine dioxide iron iron pentacarbonyl ferrous chloride ferric chloride iron iodide francium gallium gallium bromide gallium trichloride gadolinium germanium germanium bromide germanium chloride germane trichloro germane germanium sulfide digermane trigermane hydrogen bromide hydrogen cyanide hydrogen chloride chlorosulfonic acid perchloric acid hydrogen fluoride hydrogen iodide nitric acid hydrazoic acid difluorophosphoric acid
CAS No
A
B
C
TMIN
TMAX
code
1306-23-6 7440-45-1 14457-87-5 7790-86-5 7790-89-8 13637-83-7 7616-94-6 7790-91-2 13637-63-3 13444-90-1 10049-04-4 7782-50-5 7791-21-1 27218-16-2 12442-63-6 10294-48-1 7440-48-4 7646-79-9 14096-82-3 7440-47-3 13007-92-6 10049-05-5 10025-73-7 14977-61-8 1333-82-0 7440-46-2 7787-69-1 7647-17-8 13400-13-0 7789-17-5 7440-50-8 7787-70-4 7758-89-6 7447-39-4 7681-65-4 13536-59-9 3017-23-0 7698-05-7 14333-26-7 14104-45-1 7782-39-0 7789-20-0 7429-91-6 7440-52-0 7440-53-1 7789-21-1 7789-25-5 10022-50-1 7789-26-6 7782-41-4 7783-41-7 7783-44-0 7439-89-6 13463-40-6 7758-94-3 7705-08-0 7783-86-0 7440-73-5 7440-55-3 13450-88-9 13450-90-3 7440-54-2 7440-56-4 13450-92-5 10038-98-9 1184-65-2 7782-65-2 12025-32-0 13818-89-8 14691-44-2 10035-10-6 74-90-8 7647-01-0 7790-94-5 7601-90-3 7664-39-3 10034-85-2 7697-37-2 7782-79-8 13779-41-4
10.87780 8.54474 11.23239 10.38288 6.90617 6.67696 7.08309 7.34481 6.87794 5.37230 7.29962 7.06306 7.70028 7.53867 5.83238 7.59797 8.85240 7.04947 3.05780 8.48706 10.71935 12.16568 10.96666 6.76400 20.14000 6.67520 7.70150 7.74073 7.54319 7.64311 8.30991 5.01163 4.45573 -4.76869 4.81291 6.16238 6.25464 6.93596 7.21704 5.60474 6.31539 8.06347 6.67690 7.07492 6.80515 7.39950 7.88277 6.94723 6.53787 6.89461 7.29316 6.77902 8.37930 9.24491 7.23943 28.93093 7.09897 6.28464 8.24091 7.64043 7.54055 8.09461 8.39437 6.92749 6.27456 7.29569 7.08333 6.81801 6.98641 7.19898 6.93857 8.08422 7.25303 7.47025 6.71471 8.12392 6.99067 7.56453 6.65340 6.73530
10021.4278 20813.1074 14449.4770 15005.2628 644.1798 809.7800 854.6155 1086.4081 896.9883 395.4000 1033.2300 906.7031 1296.5974 1404.1800 1400.9600 1583.6401 18477.2528 4946.1939 9.5159 15307.9218 3410.1719 12935.2174 12720.2532 1231.6008 10300.0000 3515.7582 7132.1044 7233.7811 6579.0903 6849.9814 15006.7869 2858.6991 2327.4421 3645.4156 2646.3848 505.6800 689.1316 668.2000 1268.3700 414.6800 92.2133 1708.9717 9758.5876 12618.2924 6548.9117 1521.0000 986.5042 685.0522 721.4837 320.1001 580.8480 756.3900 16213.5121 2718.2717 4667.3502 32484.7863 4398.3915 3099.3568 13438.1916 2477.2199 2005.3675 18125.4084 16953.3407 1650.1032 971.2957 1304.6359 732.4097 6765.5528 1189.4193 1588.2499 704.4329 1655.8693 764.8366 1749.2078 1348.2463 1680.6466 881.4677 1431.7460 979.1881 1342.9000
273.15 231.68 273.15 273.15 249.77 218.96 250.03 231.62 237.51 174.00 222.93 250.83 266.83 257.00 273.15 253.72 166.22 137.52 6.92 59.51 280.20 273.15 273.15 200.16 273.15 255.57 179.48 191.46 160.10 158.38 202.14 -3.41 -12.18 -999.92 33.70 220.60 178.31 249.50 273.87 187.87 276.35 228.35 3.70 140.57 143.35 174.00 257.12 240.87 243.29 267.95 276.45 250.16 88.52 324.13 46.98 928.01 107.58 237.55 259.39 205.34 229.36 210.60 240.64 221.42 199.65 220.21 262.43 214.38 258.91 257.31 240.30 292.23 259.93 227.29 239.81 301.02 250.08 222.69 223.46 232.00
930.00 1719.00 1407.00 1677.00 -158.15 -82.15 -147.74 -73.70 -79.20 -87.15 -59.60 -101.03 -98.50 -44.15 151.50 -45.30 1517.00 770.00 -1.30 1383.00 36.00 1070.00 1250.00 -18.40 174.85 21.85 748.00 744.00 712.00 738.00 1216.00 572.00 429.85 309.70 610.00 -88.15 -68.90 -115.15 -84.15 -55.15 -254.42 3.82 1105.00 1231.00 590.00 64.85 -132.00 -156.00 -160.00 -219.67 -198.15 -125.15 1435.00 -6.50 700.00 108.00 587.00 121.00 1037.00 121.50 77.75 1563.00 1371.00 43.30 -45.00 -41.30 -165.89 615.00 -88.70 -36.90 -88.00 -13.32 -114.18 -80.00 -101.20 -83.36 -50.77 -41.60 -79.00 4.85
980.00 3443.00 1457.00 1727.00 26.85 21.85 95.25 11.75 24.80 -21.15 191.85 144.00 2.20 74.85 201.50 82.00 2925.00 1049.00 80.00 2671.00 151.00 1120.00 1300.00 117.00 194.85 671.00 1300.00 1297.00 1251.00 1280.00 2562.00 1345.00 1490.00 521.00 1336.00 -51.15 26.20 -62.15 49.85 -7.15 -234.80 370.74 2567.00 2868.00 1523.00 192.85 -59.90 -72.40 -46.00 -128.84 -63.15 -80.15 2860.20 103.00 1023.85 319.00 926.85 673.00 2245.00 226.85 420.85 3262.00 2833.00 186.35 86.55 75.30 34.85 726.85 30.80 110.50 90.00 183.50 51.50 426.85 357.85 188.00 150.70 102.95 35.70 151.85
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
317
Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240
FORMULA H2 H2O H2O2 H2S H2SO4 H2S2 H2S3 H2S4 H2S5 H2Se H2Te H3NO H3SNO3 He He Hf HfCl4 HfI3 Hg HgBr2 HgCl2 HgI2 Ho ICl IF5 IF7 I2 In InBr InBr3 InCl InCl3 Ir IrF6 K KBr KCl KF KI KOH Kr La LaBr3 LaCl3 Li LiBr LiCl LiF LiI Lu Mg MgBr2 MgCl2 MgF2 MgI2 MgO Mn MnCl2 MnF2 Mo MoCl5 MoF5 MoF6 MoOF4 MoO3 NClO NCl3 ND3 NF3 NF3S NH3 NH4Br NH4Cl NH4I NH5O NH5S NO NO2 N2 N2F4
NAME hydrogen water hydrogen peroxide hydrogen sulfide sulfuric acid hydrogen disulfide dihydrogen trisulfide dihydrogen tetrasulfide dihydrogen pentasulfide hydrogen selenide hydrogen telluride hydroxylamine sulfamic acid helium-3 helium-4 hafnium hafnium chloride hafnium iodide mercury mercuric bromide mercuric chloride mercuric iodide holmium iodine chloride iodine pentafluoride iodine heptafluoride iodine indium indium bromide indium bromide indium chloride indium chloride iridium iridium fluoride potassium potassium bromide potassium chloride potassium fluoride potassium iodide potassium hydroxide krypton lanthanum lanthanum bromide lanthanum chloride lithium lithium bromide lithium chloride lithium fluoride lithium iodide lutetium magnesium magnesium bromide magnesium chloride magnesium fluoride magnesium iodide magnesium oxide manganese manganese chloride manganese fluoride molybdenum molybdenum chloride molybdenum fluoride molybdenum fluoride molybdenum oxytetrafluoride molybdenum oxide nitrosyl chloride nitrogen trichloride heavy ammonia nitrogen trifluoride nitrogen fluoride sulfide ammonia ammonium bromide ammonium chloride ammonium iodide ammonium hydroxide ammonium hydrogensulfide nitric oxide nitrogen dioxide nitrogen tetrafluorohydrazine
CAS No
A
B
C
TMIN
TMAX
code
1333-74-0 7732-18-5 7722-84-1 7783-06-4 7664-93-9 13465-07-1 13845-23-3 13845-25-5 13845-24-4 7783-07-5 7783-09-7 7803-49-8 5329-14-6 14762-55-1 7440-59-7 7440-58-6 13499-05-3 13779-73-2 7439-97-6 7789-47-1 7487-94-7 7774-29-0 7440-60-0 7790-99-0 7783-66-6 16921-96-3 7553-56-2 7440-74-6 14280-53-6 13465-09-3 13465-10-6 10025-82-8 7439-88-5 7783-75-7 7440-09-7 7758-02-3 7447-40-7 7789-23-3 7681-11-0 1310-58-3 7439-90-9 7439-91-0 13536-79-3 10099-58-8 7439-93-2 7550-35-8 7447-41-8 7789-24-4 10377-51-2 7439-94-3 7439-95-4 7789-48-2 7786-30-3 7783-40-6 10377-58-9 1309-48-4 7439-96-5 7773-01-5 7782-64-1 7439-98-7 10241-05-1 13819-84-6 7783-77-9 14459-59-7 1313-27-5 2696-92-6 10025-85-1 13550-49-7 7783-54-2 15930-75-3 7664-41-7 12124-97-9 12125-02-9 12027-06-4 1336-21-6 12124-99-1 10102-43-9 10102-44-0 7727-37-9 10036-47-2
6.14858 8.05573 8.07489 7.11958 8.28538 7.02654 6.80710 6.94510 7.32010 6.46297 5.90921 11.71366 0.11312 4.82950 5.27120 9.06491 11.71000 19.56000 7.89458 5.56804 12.19380 7.11921 6.66154 7.69746 7.24100 8.58999 7.10736 7.98843 19.02460 5.89173 8.03000 13.62000 9.63425 8.56221 6.97431 7.60549 6.93314 7.61993 6.57543 7.08223 7.01408 8.57782 10.98826 14.66261 7.80332 7.57994 7.53439 8.71722 8.49354 7.83211 7.16078 7.38742 7.13801 7.87219 6.92855 6.92276 7.50506 7.03063 16.16514 8.64938 6.29946 8.49628 7.06989 8.53528 6.05246 7.83560 7.00316 6.83776 7.01648 6.88510 7.58743 9.74168 8.93371 10.40721 7.47687 8.96559 7.70299 9.74325 6.72531 7.41740
80.9480 1723.6425 1958.1824 802.2266 2976.8370 1242.2189 1488.0000 1772.0000 2104.0000 587.4538 586.0450 3155.6880 684.4925 8.5576 13.5171 30232.9115 5197.0000 10700.0000 3147.6142 974.6103 6369.7914 2015.6871 10226.4211 1515.4000 1387.0000 1562.5974 1556.9694 11856.7391 15000.0000 727.4250 4640.0000 8270.0000 30934.6262 1717.5557 4143.9271 7291.2713 5810.3508 7726.2515 5053.2934 6300.4849 511.6161 21096.9943 15000.0000 15000.0000 7953.8982 6947.3452 7299.6503 11054.9564 7459.8616 17422.3777 5253.0612 6095.1378 6696.7751 12036.3932 4121.1468 13862.2156 9853.7049 5467.6217 15000.0000 26943.1312 1850.0000 2709.7945 1018.5440 2492.6355 2898.1602 1314.8605 1212.7111 746.0100 559.5184 888.5000 1013.7815 4588.8568 3215.2979 5286.5838 1118.7172 1598.3103 473.0296 2289.6342 285.5727 952.4783
277.53 233.08 226.80 249.61 213.95 228.94 209.00 196.00 189.00 205.99 195.52 247.42 273.15 274.36 274.58 285.82 273.15 273.15 271.10 40.68 379.97 121.58 4.88 216.80 213.62 268.90 183.97 249.38 273.15 -183.70 273.15 273.15 190.68 248.71 254.47 163.23 17.98 128.32 22.90 172.76 277.13 239.17 273.15 273.15 276.84 168.43 185.61 221.14 155.25 116.75 137.71 104.02 161.05 82.67 109.39 -170.46 68.23 127.56 273.15 31.68 273.15 268.96 209.14 254.83 -233.00 270.75 223.18 221.53 264.35 245.00 248.83 272.85 192.35 297.41 245.15 229.34 249.87 312.65 270.09 284.15
-259.20 0.01 -0.41 -85.47 25.00 -40.00 54.85 110.85 152.85 -115.30 -96.40 33.10 20.00 -272.15 -271.39 2416.00 202.85 301.85 -38.84 136.50 136.20 157.50 1159.00 13.85 9.85 -87.00 -31.15 900.00 626.00 304.60 211.00 226.85 2440.00 -88.00 63.20 795.00 770.85 885.00 745.00 405.85 -157.37 1650.00 1547.00 970.00 524.30 748.00 783.00 1047.00 723.00 1600.00 428.00 711.00 778.00 1262.85 634.00 2831.85 955.00 736.00 826.00 2400.00 218.00 86.60 -65.50 -21.00 801.00 -59.60 -27.00 -74.00 -206.79 -94.15 -77.74 198.30 280.00 210.90 -70.00 -51.10 -163.65 -11.20 -210.00 -161.50
-239.97 373.98 457.00 100.38 336.85 70.70 200.85 273.85 318.85 -42.00 -2.00 109.85 100.00 -269.83 -267.95 4603.00 310.00 323.85 1461.85 322.00 304.00 354.00 2700.00 123.85 134.85 4.80 546.00 2072.00 656.00 364.80 576.85 426.85 4386.00 53.60 1949.85 1380.00 3196.85 1502.00 1344.85 1326.85 -63.80 3464.00 1577.00 1000.00 1337.10 1310.00 1383.00 1673.00 1173.85 3402.00 1088.00 1226.85 1412.00 2126.85 876.85 5676.85 2060.00 1190.00 856.00 4950.00 268.00 213.60 34.00 186.00 1140.00 167.50 94.00 -33.00 -39.30 1.85 132.50 396.00 520.00 405.00 80.00 33.30 -93.00 158.20 -147.05 36.20
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 2 1,2 1,2 1,2 1,2
318
Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 241 242 243 244 245 246 247 248 249 250 251 252 253 254 255 256 257 258 259 260 261 262 263 264 265 266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282 283 284 285 286 287 288 289 290 291 292 293 294 295 296 297 298 299 300 301 302 303 304 305 306 307 308 309 310 311 312 313 314 315 316 317 318 319 320
FORMULA N2H4 N2H4C N2H6CO2 N2O N2O3 N2O4 N2O5 Na NaBr NaCN NaCl NaF NaI NaOH Na2SO4 Nb NbBr5 NbCl4 NbCl5 NbF5 Nd NdBr3 NdCl3 Ne Ni NiC4O4 NiCl2 NiF2 Np NpF6 O2 O3 Os OsF5 OsF6 OsOF5 OsO4 P P PBrF2 PBr2F PBr3 PBr5 PClF2 PCl2F PCl2F3 PCl3 PCl5 PF3 PF3O PF5 PH3 PH4Br PH4Cl PH4I POBrClF POBrCl2 POBrF2 POBr3 POClF2 POCl2F POCl3 PSBr3 PSCl3 P2O3 P2O5 P2S5 P4O6 Pb PbBr2 PbCl2 PbF2 PbI2 PbO PbO PbS Pd Po PoCl4 Pr
NAME hydrazine ammonium cyanide ammonium carbamate nitrous oxide nitrogen trioxide nitrogen tetraoxide nitrogen pentoxide sodium sodium bromide sodium cyanide sodium chloride sodium fluoride sodium iodide sodium hydroxide sodium sulfate niobium niobium bromide niobium chloride niobium chloride niobium fluoride neodymium neodymium tribromide neodymium trichloride neon nickel nickel carbonyl nickel chloride nickel fluoride neptunium neptunium hexafluoride oxygen ozone osmium osmium fluoride osmium fluoride osmium oxide pentafluoride osmium tetroxide phosphorus (white) phosphorus (red) phosphorus bromide difluoride phosphorus dibromide fluoride phosphorus tribromide phosphorus bromide phosphorus chloride difluoride phosphorus dichloride fluoride phosphorus dichloride trifluoride phosphorus chloride phosphorus pentachloride phosphorus fluoride phosphorus oxyfluoride phosphorus fluoride phosphine phosphonium bromide phosphonium chloride phosphonium iodide phosphoryl bromide chloride fluoride phosphoryl bromide dichloride phosphoryl bromide difluoride phosphorus oxybromide phosphoryl chloride difluoride phosphoryl dichloride fluoride phosphorus oxychloride phosphorus thiobromide phosphorus thiochloride phosphorus trioxide phosphorus pentoxide phosphorus sulfide phosphorous oxide lead lead bromide lead chloride lead fluoride lead iodide lead oxide lead oxide (massicot) lead sulfide palladium polonium polonium tetrachloride praseodymium
CAS No
A
B
C
TMIN
TMAX
code
302-01-2 12211-52-8 1111-78-0 10024-97-2 10544-73-7 10544-72-6 10102-03-1 7440-23-5 7647-15-6 143-33-9 7647-14-5 7681-49-4 7681-82-5 1310-73-2 7757-82-6 7440-03-1 13478-45-0 13569-70-5 10026-12-7 7783-68-8 7440-00-8 13536-80-6 10024-93-8 7440-01-9 7440-02-0 13463-39-3 7718-54-9 10028-18-9 7439-99-8 14521-05-2 7782-44-7 10028-15-6 7440-04-2 31576-40-6 13768-38-2 --20816-12-0 7723-14-0 7723-14-0 15597-40-7 15597-39-4 7789-60-8 7789-69-7 14335-40-1 15597-63-4 13454-99-4 7719-12-2 10026-13-8 7783-55-3 13478-20-1 7647-19-0 7803-51-2 --24567-53-1 12125-09-6 14518-81-1 13455-03-3 14014-18-7 7789-59-5 13769-75-0 13769-76-1 10025-87-3 3931-89-3 3982-91-0 1314-24-5 1314-56-3 1314-80-3 12440-00-5 7439-92-1 10031-22-8 7758-95-4 7783-46-2 10101-63-0 1317-36-8 1317-36-8 1314-87-0 7440-05-3 7440-08-6 10026-02-5 7440-10-0
7.82877 9.16524 10.32341 6.81488 7.60164 4.09407 11.93250 7.33576 7.54103 7.38628 7.96318 8.61974 7.89004 7.46511 11.40104 9.92532 9.33000 12.30000 8.37000 6.88947 6.95222 11.15371 10.88871 6.74431 8.74585 7.64987 10.25227 8.31881 7.90387 7.19634 6.83706 7.15980 9.76546 9.75828 8.26547 3.06277 4.72185 7.00000 11.39619 6.90420 6.85800 7.35097 10.31441 7.34733 7.11413 7.38018 6.87188 10.28827 7.06415 10.28247 9.61509 6.98375 10.09866 9.08492 10.23174 6.91410 6.92410 7.10190 7.13796 6.92660 7.08465 7.05109 9.40218 7.11462 8.39335 10.74529 9.02309 8.35860 7.46345 8.87105 7.64617 7.62479 6.76027 9.24183 9.33076 8.84745 8.56766 7.18388 9.33621 6.78062
1698.5808 1644.6341 2267.7036 550.6045 1109.3200 97.8287 2617.6543 5060.9675 7142.9394 7836.8557 8432.2350 11408.3735 7361.9912 7606.4353 15657.1880 35189.3422 4085.0000 6870.0000 2870.0000 1791.5982 12884.3059 15000.0000 15000.0000 115.3285 17882.3827 1479.9228 8220.2197 7276.8348 22003.2016 1271.8225 339.2095 618.6072 34751.0553 3432.7793 1525.6447 47.1535 404.5748 2016.5981 5737.7187 885.1200 1210.3000 1883.6717 2746.6473 1041.3236 1120.6064 1175.5119 1218.9462 2973.0094 651.8743 1549.5473 1143.4832 724.4708 2085.9953 1255.1903 2291.9882 1214.0000 1411.0000 1118.9000 1697.4936 946.9600 1201.8600 1390.0324 2659.4144 1501.0578 2597.3392 6470.4817 4959.9962 2568.0727 9131.8353 6987.2446 5101.5890 6525.7272 3580.4550 10820.2993 11048.8015 7859.9264 18403.4082 5265.0104 4280.8340 14030.7383
229.79 230.00 245.93 228.44 232.98 59.47 256.19 254.35 142.08 243.41 194.07 278.32 165.84 280.16 273.15 251.22 273.15 273.15 273.15 217.93 97.12 273.15 273.15 275.91 134.99 267.82 130.14 -160.62 273.15 239.53 268.70 255.87 35.61 273.23 235.83 1.04 84.75 215.00 242.50 236.00 226.00 248.44 259.11 280.39 250.71 257.82 229.32 241.50 257.33 248.89 254.40 264.31 250.37 229.31 249.30 222.00 213.00 233.00 207.04 231.00 233.00 227.82 232.93 229.54 298.17 217.75 293.52 295.82 243.70 274.44 119.56 82.58 50.32 227.03 240.48 36.31 273.13 261.55 273.15 77.80
1.53 -50.60 -26.10 -90.85 -103.15 -11.25 -36.80 280.60 746.85 563.70 800.75 995.85 767.00 500.00 1514.50 2669.00 254.00 303.85 204.70 86.30 1322.30 1510.00 1570.00 -248.59 1510.00 -23.00 534.00 1077.00 1726.85 54.85 -218.80 -193.00 2600.00 74.10 -89.00 31.65 3.20 69.00 181.85 -91.15 -18.15 7.80 -19.00 -119.50 -71.10 -79.80 -92.00 -12.00 -152.00 -124.00 -157.00 -133.78 -43.70 -91.00 -25.20 -10.15 31.85 -44.15 64.00 -76.15 -40.15 1.18 50.00 -36.20 47.30 230.00 288.00 39.70 434.85 513.00 547.00 861.00 479.00 943.00 724.00 852.00 1300.00 500.00 300.60 1497.70
380.00 31.70 58.30 36.42 151.85 47.50 33.00 926.85 1446.85 1496.00 1465.05 1786.85 1303.85 1600.00 1564.50 4740.00 360.00 377.85 246.85 229.00 3063.00 1540.00 1600.00 -228.75 2911.00 42.50 985.00 1283.00 2226.85 76.85 -118.57 -12.15 5400.00 225.90 47.50 57.75 135.00 317.00 431.00 10.85 109.85 172.95 110.10 89.25 189.85 -22.80 101.00 159.85 -1.95 -39.70 -84.60 51.60 38.30 -27.00 62.50 102.85 162.85 51.85 191.70 30.85 84.85 105.50 175.00 125.00 173.00 700.00 1017.85 173.00 1749.00 892.00 951.00 1293.00 872.00 1474.00 1471.00 1281.00 3400.00 1050.00 410.00 3520.00
1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
319
Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 321 322 323 324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 340 341 342 343 344 345 346 347 348 349 350 351 352 353 354 355 356 357 358 359 360 361 362 363 364 365 366 367 368 369 370 371 372 373 374 375 376 377 378 379 380 381 382 383 384 385 386 387 388 389 390 391 392 393 394 395 396 397 398 399 400
FORMULA PrCl3 Pt Pu PuBr3 PuCl3 PuF3 Ra Rb RbBr RbCl RbF RbI Re ReF5 ReF6 ReF7 ReOF4 ReOF5 ReO2F3 Re2O7 Rh Rn Ru RuF5 S SCl2 SFN SF2N2 SF4 SF6 SOBr2 SOClF SOCl2 SOF2 SOF4 SO2 SO2BrF SO2ClF SO2Cl2 SO2F2 SO3 S2Br2 S2Cl2 S2F2 S2F10 S2O2F10 S2O5ClF S2O5Cl2 S2O5F2 S2O5F4 S3O8F2 Sb SbBr3 SbCl3 SbCl5 SbH3 SbI3 Sb2O3 Sc ScBr3 ScCl3 ScI3 Se SeCS SeCl4 SeF4 SeF6 SeOCl2 SeOF2 SeO2 Si SiBrCl2F SiBr2ClF SiCCl3N SiCCl3NS SiCH2Cl4O SiCH3Cl2F SiCH3Cl3 SiCH3F3 SiCH4ClF
NAME praseodymium chloride platinum plutonium plutonium bromide plutonium chloride plutonium fluoride radium rubidium rubidium bromide rubidium chloride rubidium fluoride rubidium iodide rhenium rhenium fluoride rhenium fluoride rhenium fluoride rhenium oxytetrafluoride rhenium oxypentafluoride rhenium dioxytrifluoride rhenium heptoxide rhodium radon ruthenium ruthenium fluoride sulfur sulfur dichloride thiazyl fluoride dinitrogen sulfur difluoride sulfur tetrafluoride sulfur hexafluoride thionyl bromide thionyl chloride fluoride thionyl chloride thionyl fluoride sulfur oxide tetrafluoride sulfur dioxide sulfuryl bromide fluoride sulfuryl chloride fluoride sulfuryl chloride sulfuryl fluoride sulfur trioxide sulfur bromide sulfur monochloride disulfur difluoride sulfur decafluoride thiosulfuryl decafluoride pyrosulfuryl chloride fluoride pyrosulfuryl chloride pyrosulfuryl difluoride disulfur pentoxide tetrafluoride trisulfur octoxide difluoride antimony antimony tribromide antimony trichloride antimony pentachloride stibine antimony triiodide antimony oxide scandium scandium bromide scandium chloride scandium iodide selenium (gray) carbonyl selenide sulfide selenium tetrachloride selenium tetrafluoride selenium hexafluoride selenium oxychloride selenium oxyfluoride selenium dioxide silicon silane bromodichlorofluoro silane dibromochlorofluoro silane trichloro-carbonitrile silane trichloroisothio-cyanato silane trichloro(chloro-methoxy) silane dichlorofluoro-methyl silane methyltrichloro silane trifluoromethyl silane chlorofluoro-methyl
CAS No
A
B
C
TMIN
TMAX
code
10361-79-2 7440-06-4 7440-07-5 15752-46-2 13569-62-5 13842-83-6 7440-14-4 7440-17-7 7789-39-1 7791-11-9 13446-74-7 7790-29-6 7440-15-5 30937-52-1 10049-17-9 17029-21-9 17026-29-8 23377-53-9 57246-89-6 1314-68-7 7440-16-6 10043-92-2 7440-18-8 14521-18-7 7704-34-9 10545-99-0 18820-63-8 500010-01-5 7783-60-0 2551-62-4 507-16-4 14177-25-4 7719-09-7 7783-42-8 13709-54-1 7446-09-5 13536-61-3 13637-84-8 7791-25-5 2699-79-8 7446-11-9 13172-31-1 10025-67-9 16860-99-4 5714-22-7 12395-41-4 13637-85-9 7791-27-7 13036-75-4 44982-62-9 13709-33-6 7440-36-0 7789-61-9 10025-91-9 7647-18-9 7803-52-3 7790-44-5 1309-64-4 7440-20-2 13465-59-3 10361-84-9 14474-33-0 7782-49-2 5951-19-9 10026-03-6 13465-66-2 7783-79-1 7791-23-3 7783-43-9 7446-08-4 7440-21-3 ----18157-01-2 18157-00-1 18157-08-9 420-58-6 75-79-6 373-74-0 373-67-1
10.44454 8.58584 8.08674 8.15259 7.22981 9.39122 6.71596 6.99992 8.13532 7.05736 6.21681 7.66815 8.97642 8.98978 8.47754 11.47517 9.45214 7.90580 10.36000 10.48807 9.68520 6.58011 9.33600 7.56315 7.86630 8.36643 6.48180 6.78280 7.02242 6.87699 8.17193 7.17310 7.27960 6.28388 7.07180 7.33311 7.14280 6.52150 6.94482 6.90700 6.85638 7.17834 7.04178 6.68410 7.06760 6.87410 7.01560 7.01910 6.88110 6.88510 6.99010 5.88125 8.00960 6.91949 7.76515 7.20112 7.55355 4.06652 7.72648 14.35000 14.37000 14.17000 7.05403 6.89093 10.79338 7.61816 6.99021 7.90109 7.42010 18.01392 8.71307 7.51839 7.26677 7.75100 7.99850 8.39500 7.74530 7.18818 7.97520 7.60660
15000.0000 22055.7478 18531.9774 8352.8990 8007.1303 14145.3938 6622.4566 3926.1751 8288.1158 6116.0391 3433.9886 7039.8460 34838.4703 3010.3083 1550.5300 5114.2585 2533.4840 1772.1930 3437.0000 4082.7928 26833.7062 651.6732 26794.4200 2037.5032 3464.9835 1559.0062 877.1000 901.0000 882.8300 676.2391 2202.4959 1100.1000 1415.8028 569.2883 840.3000 1013.4609 1155.0000 793.7300 1194.8068 784.3000 754.8178 1664.6387 1466.8804 628.0000 1100.6000 1110.0000 1257.4000 1460.0000 1120.0000 1140.0000 1360.0000 4984.6752 2654.1840 1709.1498 2046.6707 1062.6666 2915.0705 1464.9462 13961.2550 13780.0000 14200.0000 13340.0000 3441.9628 1274.4371 3477.8728 1471.6008 727.3425 1958.4938 1380.0000 11598.1403 20614.1581 1472.7873 1379.5487 1687.0000 2060.0000 2159.0000 1472.3000 1370.6632 1238.1000 1296.6000
273.15 41.02 331.78 93.61 48.46 49.57 200.78 265.16 237.34 74.38 -380.62 170.51 119.34 271.47 243.24 521.55 213.84 279.68 273.15 176.70 248.59 237.86 33.09 196.96 250.34 224.60 239.00 242.00 253.61 233.12 276.26 244.00 246.26 211.09 249.00 237.65 231.00 210.70 224.60 250.00 145.11 185.93 215.53 256.00 234.00 229.00 204.00 202.00 229.00 227.00 211.00 74.32 237.51 202.95 240.86 263.97 222.85 -189.49 45.18 273.15 273.15 273.15 139.77 232.21 248.14 204.64 222.79 213.12 178.00 451.41 267.17 282.18 255.04 273.15 273.15 273.15 273.15 251.81 273.15 273.15
1680.00 2057.00 1483.00 681.00 760.00 1396.00 546.00 160.40 781.00 792.00 921.00 748.00 3030.00 58.80 -97.00 48.30 5.00 -103.00 90.00 120.00 2015.00 -163.00 2315.00 49.60 102.00 -76.00 -8.15 -83.15 -100.00 -168.00 -6.70 -65.15 -101.15 -98.73 -113.15 -75.48 -45.15 -72.15 -51.15 -121.15 16.80 -7.00 -7.40 -120.15 -47.15 -34.15 4.85 47.85 -33.15 -27.15 22.85 534.00 93.90 73.40 22.70 -95.28 163.60 400.00 1300.00 768.85 791.85 736.85 227.00 -47.30 74.00 13.60 -153.00 34.80 36.85 115.00 1634.85 -86.50 -65.20 -46.15 66.85 -0.15 -30.15 -77.80 -60.15 -75.15
1710.00 3825.00 3228.00 1476.85 1776.85 1726.85 1526.00 688.00 1340.00 1390.00 1410.00 1300.00 5681.00 221.30 33.80 71.85 171.70 73.00 181.85 500.00 3695.00 103.85 4115.00 156.80 444.00 59.60 29.85 8.85 -40.45 45.54 140.00 36.85 99.00 -43.80 -25.15 157.60 67.85 36.85 271.85 -32.15 217.70 200.90 137.00 -77.15 48.85 70.85 130.85 177.85 72.85 79.85 145.85 1587.00 280.00 520.85 114.10 167.20 401.00 1550.00 3200.00 926.85 959.85 906.85 685.00 85.60 191.40 106.00 72.35 177.00 152.85 335.00 3264.85 201.15 242.77 73.24 129.38 118.39 -27.15 243.85 -57.15 1.22
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
320
Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 401 402 403 404 405 406 407 408 409 410 411 412 413 414 415 416 417 418 419 420 421 422 423 424 425 426 427 428 429 430 431 432 433 434 435 436 437 438 439 440 441 442 443 444 445 446 447 448 449 450 451 452 453 454 455 456 457 458 459 460 461 462 463 464 465 466 467 468 469 470 471 472 473 474 475 476 477 478 479 480
FORMULA SiCH4Cl2 SiCH4F2 SiCH5Cl SiCH5Cl SiCH6 SiCH6O SiC2H8 SiC3H10 SiC4H12 SiClF3 SiCl2F2 SiCl3F SiCl4 SiF4 SiHBr3 SiHCl3 SiHF3 SiH2Br2 SiH2Cl2 SiH2F2 SiH2I2 SiH3Br SiH3Cl SiH3F SiH3I SiH4 SiI4 SiO2 Si2CH3Cl5 Si2CH7Cl Si2CH7Cl Si2C2H4Cl6 Si2C2H4Cl6 Si2C2H6Cl4 Si2C2H9FO Si2Cl3F3O Si2Cl6 Si2Cl6O Si2F6 Si2H6 Si2H6O Si3Cl8 Si3H8 Si3H9N Si4H10 Sm Sn SnBr4 SnCl2 SnCl4 SnH4 SnI4 SnS Sr SrF2 SrO Ta TaBr5 TaCl5 TaF5 Tb Tc Tc2O7 Te TeCl2 TeCl4 TeF4 TeF6 TeO2 Te2F10 Th ThBr4 ThCl4 ThI4 ThO2 Ti TiBr4 TiCl2 TiCl4 TiF4
NAME silane methyl dichloro silane difluoromethyl silane methyl chloro silane (chloromethyl) silane methyl methyl silyl ether silane dimethyl silane trimethyl silane tetramethyl silane chlorotrifluoro silane dichlorodifluoro silane trichlorofluoro silicon tetrachloride silicon tetrafluoride silane tribromo silane trichloro silane trifluoro silane dibromo silane dichloro silane difluoro silane diiodo silane monobromo silane monochloro silane monofluoro silane iodo silane silane tetraiodo silicon dioxide (alpha quartz) silane pentachloromethyl-di silane [(chlorosilyl)methyl]silane (chloromethyl)-di 1,2-bis(trichlorosilyl)ethane 1,1,1,3,3,3-hexachloro-2-methyl-1,3-disilapropane silane 1,2,2,2-tetrachloro-1,1-dimethyldi 1-fluoro-1,3-dimethyldisiloxane disiloxane, trichlorotrifluoro disilane hexachloro disiloxane, hexachloro disilane hexafluoro disilane disiloxane octachlorotrisilane trisilane trisilazane tetrasilane samarium tin (white) stannic bromide stannous chloride stannic chloride stannane stannic iodide tin sulfide strontium strontium fluoride strontium oxide tantalum tantalum bromide tantalum chloride tantalum fluoride terbium technetium technetium heptoxide tellurium tellurium dichloride tellurium tetrachloride tellurium tetrafluoride tellurium hexafluoride tellurium dioxide tellurium decafluoride thorium thorium bromide thorium chloride thorium iodide thorium oxide titanium titanium bromide titanium chloride titanium tetrachloride titanium fluoride
CAS No
A
B
C
TMIN
TMAX
code
75-54-7 420-34-8 993-00-0 10112-09-1 992-94-9 2171-96-2 1111-74-6 993-07-7 75-76-3 14049-36-6 18356-71-3 14965-52-7 10026-04-7 7783-61-1 7789-57-3 10025-78-2 13465-71-9 13768-94-0 4109-96-0 13824-36-7 13760-02-6 13465-73-1 13465-78-6 13537-33-2 13598-42-0 7803-62-5 13465-84-4 14808-60-7 26980-40-5 35483-45-5 54713-74-5 2504-64-5 18076-92-1 26980-43-8 35192-38-2 --13465-77-5 14986-21-1 --1590-87-0 13597-73-4 13596-23-1 7783-26-8 --7783-29-1 7440-19-9 7440-31-5 7789-67-5 7772-99-8 7646-78-8 2406-52-2 7790-47-8 1314-95-0 7440-24-6 7783-48-4 1314-11-0 7440-25-7 13451-11-1 7721-01-9 7783-71-3 7440-27-9 7440-26-8 --13494-80-9 10025-71-5 10026-07-0 15192-26-4 7783-80-4 7446-07-3 53214-07-6 7440-29-1 13453-49-1 10026-08-1 7790-49-0 1314-20-1 7440-32-6 7789-68-6 10049-06-6 7550-45-0 7783-63-3
7.23413 7.76550 7.04725 8.09302 7.10688 3.98012 6.73312 6.90193 6.87190 7.06315 7.33305 7.15967 7.00381 6.72479 6.97115 7.10586 6.50485 7.05269 6.98538 6.68670 7.36622 7.24230 6.76710 6.29474 7.04589 7.12525 6.97269 9.87451 7.91847 7.83841 8.09282 7.82031 8.10890 7.14487 6.32253 9.03398 7.36013 7.12363 12.22960 7.00941 7.42748 8.65954 7.22385 7.15693 6.54087 6.72424 8.54915 7.14579 7.51627 6.85720 7.15934 6.06085 9.97000 6.83233 8.06789 7.51441 8.73303 8.14000 11.98340 6.45981 7.41799 26.08539 9.00000 6.63850 8.51000 8.59582 5.64000 8.65918 12.76126 6.90180 8.08673 9.56000 9.57000 9.09000 9.64285 8.90223 6.97018 8.35740 7.29500 10.87761
1272.2113 1160.4000 1054.7751 1719.2800 873.3901 185.6317 853.3608 1030.4100 1060.6645 761.3693 1054.7676 1116.6266 1205.9453 459.3741 1382.4891 1191.2883 466.9478 1295.7656 1032.4344 609.3862 2014.1634 1152.7870 797.8130 412.9780 1204.6095 704.8874 1909.4768 16418.2297 2186.1100 1674.1300 1875.0700 2242.0000 2425.0000 1680.7900 1162.7400 2311.2185 1615.6257 1465.7767 2464.6767 1015.4056 1137.4567 2872.1180 1329.1653 1247.8657 1122.5646 7242.8476 16655.8123 1846.6483 3705.3738 1294.1344 937.8599 1628.2894 10460.0000 6128.6851 12904.6141 9499.3367 31263.6507 3260.0000 4654.0000 1797.9105 14824.6184 236826.8849 3570.0000 4084.3774 3350.0000 3538.9650 1787.0000 1258.5289 15000.0000 1150.0000 25785.3686 7550.0000 7980.0000 6890.0000 31600.0000 20948.9918 1791.8855 10003.3561 1668.8244 4455.4168
250.69 273.15 244.46 298.60 263.57 149.98 241.12 249.55 239.11 252.04 268.91 248.71 235.64 215.21 228.99 250.11 223.85 244.60 243.23 237.92 299.05 261.91 235.69 218.97 243.82 278.22 201.81 117.52 281.29 273.15 273.15 251.00 273.15 236.84 274.47 332.87 215.69 210.43 282.54 260.09 265.37 285.62 253.14 243.12 199.31 90.48 336.40 227.98 176.36 211.30 271.00 147.69 273.15 168.97 3.46 -803.52 -115.81 273.15 273.15 273.15 37.37 5941.04 273.15 98.94 273.15 232.24 273.15 256.70 273.15 227.00 165.09 273.15 273.15 273.15 273.15 190.76 205.54 174.30 242.21 273.15
-90.60 -75.15 -134.10 -27.15 -156.81 -90.20 -150.22 -135.89 -99.08 -144.00 -124.70 -92.60 -68.85 -156.00 -30.50 -128.20 -152.00 -60.90 -122.00 -146.70 3.80 -85.70 -117.80 -153.00 -53.00 -185.00 120.50 1609.85 34.85 -0.15 -23.15 90.85 54.85 26.85 -78.15 -38.00 4.00 -5.00 -81.00 -129.30 -112.50 46.30 -68.90 -68.70 -27.70 700.00 1150.00 58.30 316.00 -22.70 -140.00 156.00 726.85 523.00 1477.00 1750.00 3024.00 265.00 188.13 119.00 1516.10 2400.00 118.85 502.00 208.00 233.00 129.00 -111.30 1215.00 -33.15 2360.00 679.00 770.00 582.85 4350.00 1709.00 39.00 1035.00 -24.10 234.00
209.85 -35.59 168.85 31.26 79.35 18.88 128.85 158.85 177.25 35.68 94.20 161.70 233.85 -14.15 344.35 205.85 3.50 286.09 175.85 37.60 410.66 182.00 123.64 12.72 251.44 -3.45 256.85 2230.05 37.85 64.54 86.61 202.89 190.69 157.34 63.37 42.74 145.00 135.60 -18.90 158.85 -15.20 211.40 52.90 48.70 107.40 2000.00 2800.00 205.00 623.00 114.15 -51.80 364.35 1026.85 1382.00 2426.85 2700.00 5458.00 336.85 238.13 249.20 3230.00 4400.00 306.85 988.00 316.85 387.00 196.85 -38.90 1245.00 89.85 4788.00 852.85 912.85 833.85 4400.00 3285.00 228.85 1426.85 364.85 284.00
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
321
Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 481 482 483 484 485 486 487 488 489 490 491 492 493 494 495 496 497 498 499 500 501 502 503 504 505 506 507 508 509 510 511 512 513 514 515 516 517 518 519 520 521 522 523 524 525
FORMULA TiI4 Tl TlBr TlCl TlF TlI Tm U UBr3 UBr4 UCl4 UCl6 UF4 UF6 UI4 V VCl4 VF5 VOCl3 V2O5 W WCl4 WCl5 WCl6 WF6 WOF4 WO3 Xe XeF2 XeF4 Y Yb Zn ZnBr2 ZnCl2 ZnF2 ZnI2 ZnO ZnS ZnSO4 Zr ZrBr4 ZrCl4 ZrF4 ZrI4
NAME titanium iodide thallium thallous bromide thallium chloride thallium fluoride thallium iodide thulium uranium uranium bromide uranium bromide uranium chloride uranium chloride uranium fluoride uranium fluoride uranium iodide vanadium vanadium tetrachloride vanadium fluoride vanadium oxytrichloride vanadium oxide tungsten tungsten chloride tungsten chloride tungsten chloride tungsten fluoride tungsten oxytetrafluoride tungsten oxide xenon xenon difluoride xenon tetrafluoride yttrium ytterbium zinc zinc bromide zinc chloride zinc fluoride zinc iodide zinc oxide zinc sulfide (wurtzite) zinc sulfate zirconium zirconium bromide zirconium chloride zirconium fluoride zirconium iodide
CAS No
A
B
C
TMIN
TMAX
code
7720-83-4 7440-28-0 7789-40-4 7791-12-0 7789-27-7 7790-30-9 7440-30-4 7440-61-1 13470-19-4 13470-20-7 10026-10-5 13763-23-0 10049-14-6 7783-81-5 13470-22-9 7440-62-2 7632-51-1 7783-72-4 7727-18-6 1314-62-1 7440-33-7 13470-13-8 13470-14-9 13283-01-7 7783-82-6 13520-79-1 1314-35-8 7440-63-3 13709-36-9 13709-61-0 7440-65-5 7440-64-4 7440-66-6 7699-45-8 7646-85-7 7783-49-5 10139-47-6 1314-13-2 1314-98-3 7733-02-0 7440-67-7 13777-25-8 10026-11-6 7783-64-4 13986-26-0
7.57600 7.58000 7.32435 -5.69389 9.88714 7.34352 7.82243 7.77000 9.06095 8.12161 9.01541 7.87988 8.93038 8.47645 8.81552 9.18000 7.32955 10.43000 7.02483 5.05000 9.98307 8.19500 7.72000 7.87000 7.07104 9.32296 14.53875 7.02795 6.96427 10.91390 8.00530 7.28084 7.57409 8.49304 8.50869 6.56144 18.01392 9.97977 12.46830 8.74032 9.12202 10.28269 11.44848 15.61264 11.20709
3054.0000 8060.0496 4432.7693 6065.8547 6902.2858 4374.7071 10435.3130 23272.8375 10506.7518 4834.9448 5767.4399 4000.0000 9333.8078 1568.8742 5446.7685 22303.0522 1823.3734 2423.0000 1518.9432 7100.0000 40387.9650 3253.0000 2760.0000 3050.0000 907.7240 2709.3726 24600.0000 701.1036 1073.3758 3095.0600 17991.8060 6060.1722 5241.2423 4782.6046 5054.5539 4368.9367 19725.9709 15781.3538 13980.0000 2215.7753 28773.5320 4025.9186 4801.8756 15000.0000 5397.4287
273.15 229.50 178.58 -1427.41 273.15 156.28 205.05 600.00 178.05 143.94 147.57 273.15 95.95 223.87 159.45 133.69 258.01 273.15 239.69 273.15 131.64 273.15 273.15 273.15 199.53 234.67 273.15 277.06 148.51 269.56 165.95 181.30 203.39 185.14 166.13 -312.99 678.50 273.15 273.15 273.15 201.25 183.91 229.46 273.15 217.24
156.85 609.00 490.00 504.00 662.00 440.00 844.00 2052.00 727.00 519.00 590.00 477.00 1036.00 -38.80 506.00 1828.00 -25.70 19.50 -79.50 670.00 3204.00 281.85 242.00 275.00 -71.60 2.00 1787.00 -111.75 2.90 35.85 1610.10 463.00 337.00 397.85 428.00 970.00 301.00 1499.95 1135.00 20.00 2366.00 207.00 190.00 875.00 264.00
369.85 1485.00 819.00 720.00 712.00 824.00 1297.00 4129.00 926.85 766.85 770.00 527.00 1400.00 56.50 726.85 3406.85 423.85 45.00 126.85 1226.85 5555.00 326.85 280.00 340.00 17.10 185.90 1837.00 16.55 357.85 117.85 3345.00 1196.00 912.00 561.85 732.00 1500.00 625.00 1949.95 1185.00 105.00 4409.00 360.00 331.00 905.00 431.00
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 2 2 1,2 1,2 1,2 1,2 1,2
Code: 1 - data, 2 - estimate, 3 - rough estimate. P - vapor pressure, mmHg. A, B, and C - Antoine coefficients for chemical compound. T - temperature, °C. TMIN - minimum temperature, °C. TMAX - maximum temperature, °C.
322
Vapor Pressure – Inorganic Compounds Carl L. Yaws, Marco A. Satyro
TABULATION RESULTS
EXAMPLE
The tabulation is arranged by alphabetical order (Ac, Al, Am, ……) to provide ease of use in quickly locating the data by using the chemical formula. The compound name, chemical abstracts registry number (CAS No), and Antoine coefficients are provided in the adjacent columns. The range of application is denoted by minimum and maximum temperatures (TMIN and TMAX). Temperatures outside the range of application should not be used. The next column provides the code for the tabulation, which is based on both experimental data and estimated values. In preparing the tabulation, a literature search was conducted to identify data source publications (53–115). Both experimental values for the property under consideration and parameter values for estimation of the property are included in the source publications. The publications were screened and copies of appropriate data were made. These data were then keyed into the computer to provide a database of values for compounds for which experimental data are available. The database also served as a basis to check the accuracy of the estimation methods. Upon completion of data collection, estimation of values for the remaining compounds was performed. The estimates are primarily based on literature methods and empirical procedures developed by the author. If initial analysis using the estimates is favorable, follow-up experimental determination is recommended. This is especially true for highly polar and high molecular weight compounds. A code of 1 in the tabulation is based on experimental data. A code of 2 indicates an estimate. The estimates with a code of 3 should be considered rough approximations. The estimates with a code of 2 are more accurate. For those substances which undergo decomposition (such as nitro compounds with explosive decomposition and very large compounds with thermal decomposition) prior to attaining the boiling point temperature, the boiling point temperature is a hypothetical value. A comparison of calculated and data values is shown in Figure 2 for a representative compound. The graph discloses favorable agreement of equation and data.
Calculate the vapor pressure of oxygen (O2) at –178.24°C. Substitution of the Antoine coefficients from the table and temperature into the equation for vapor pressure yields:
The Yaws Handbook of Vapor Pressure. http://dx.doi.org/10.1016/B978-0-12-802999-2.00002-7 Copyright © 2015 Elsevier Inc. All rights reserved.
log10 P = 6.83706 – 339.2095/(–178.24 + 268.70) = 3.08738 P = 103.08738 = 1222.87 mmHg
FIGURE 2 Vapor Pressure of Oxygen
315
Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
FORMULA Ac Ag AgBr AgCl AgI Al AlB3H12 AlBr3 AlCl3 AlF3 AlI3 Al2O3 Al2S3O12 Am Ar As AsBr3 AsCl3 AsF3 AsF5 AsH3 AsI3 As2O3 At Au B BBr3 BCl3 BF3 BH2CO BI3 B2D6 B2F4 B2H5Br B2H6 B3H6N3 B4H10 B5H9 B5H11 B10H14 Ba BaF2 BaO Be BeB2H8 BeBr2 BeCl2 BeF2 BeI2 Bi BiBr3 BiCl3 BrFO3 BrF3 BrF5 Br2 C CCl2O CF2O CH4N2O CH4N2S CNBr CNCl CNF CO COS COSe CO2 CS2 C2N2 C3S2 Ca CaCl2 CaF2 Cd CdBr2 CdCl2 CdF2 CdI2 CdO
NAME actinium silver silver bromide silver chloride silver iodide aluminum aluminum borohydride aluminum bromide aluminum chloride aluminum fluoride aluminum iodide aluminum oxide aluminum sulfate americium argon arsenic arsenic bromide arsenic trichloride arsenic trifluoride arsenic pentafluoride arsine arsenic triiodide arsenic trioxide astatine gold boron boron tribromide boron trichloride boron trifluoride borine carbonyl boron triiodide diborane, deutero diborane, tetrafluoro diborane hydrobromide diborane borazine tetraborane pentaborane pentaborane decaborane barium barium fluoride barium oxide beryllium beryllium borohydride beryllium bromide beryllium chloride beryllium fluoride beryllium iodide bismuth bismuth tribromide bismuth trichloride perbromyl fluoride bromine trifluoride bromine pentafluoride bromine graphite carbonyl chloride carbonyl fluoride urea thiourea cyanogen bromide cyanogen chloride cyanogen fluoride carbon monoxide carbonyl sulfide carbon oxyselenide carbon dioxide carbon disulfide cyanogen carbon subsulfide calcium calcium chloride calcium fluoride cadmium cadmium bromide cadmium chloride cadmium fluoride cadmium iodide cadmium oxide
CAS No
A
B
C
TMIN
TMAX
code
7440-34-8 7440-22-4 7785-23-1 7783-90-6 7783-96-2 7429-90-5 16962-07-5 7727-15-3 7446-70-0 7784-18-1 7784-23-8 1344-28-1 10043-01-3 7440-35-9 7440-37-1 7440-38-3 7784-33-0 7784-34-1 7784-35-2 7784-36-3 7784-42-1 7784-45-4 1327-53-3 7440-68-8 7440-57-5 7440-42-8 10294-33-4 10294-34-5 7637-07-2 --13517-10-7 20396-66-1 13965-73-6 --19287-45-7 6569-51-3 18283-93-7 19624-22-7 18433-84-6 17702-41-9 7440-39-3 7787-32-8 1304-28-5 7440-41-7 17440-85-6 7787-46-4 7787-47-5 7787-49-7 7787-53-3 7440-69-9 7787-58-8 7787-60-2 25251-03-0 7787-71-5 7789-30-2 7726-95-6 7782-42-5 75-44-5 353-50-4 57-13-6 62-56-6 506-68-3 506-77-4 1495-50-7 630-08-0 463-58-1 1603-84-5 124-38-9 75-15-0 460-19-5 627-34-9 7440-70-2 10043-52-4 7789-75-5 7440-43-9 7789-42-6 10108-64-2 7790-79-6 7790-80-9 1306-19-0
8.85429 8.10019 6.21353 8.61748 6.93625 8.24073 7.55341 6.73909 15.75427 12.51245 6.93225 10.96973 -0.14253 9.46480 6.84064 10.60233 7.22542 7.44841 7.30253 5.74019 6.88872 7.30188 4.99289 9.64649 8.16676 9.44507 6.58372 6.82139 7.29112 7.47035 6.93670 6.30635 7.59073 7.79587 6.83515 7.19573 7.23266 6.46328 9.78620 4.60815 6.47688 8.20759 12.51502 8.08396 15.84584 11.58765 11.21338 9.03258 10.16571 7.90580 8.73564 7.31869 7.43651 7.72974 7.85138 7.27906 13.52595 7.14063 7.41143 10.45495 7.57639 6.36918 7.55525 6.75643 6.72527 7.00667 7.17236 7.58828 7.21790 7.04339 7.51838 7.10583 9.22000 7.47685 7.66023 10.71437 9.79511 8.15105 7.72916 9.13973
20734.8351 12288.3589 5179.6010 10917.5071 6695.6629 14524.8870 1419.8359 1552.6852 5649.0504 14983.2501 2000.0426 25616.3739 651.9161 14359.6923 340.2707 6313.8843 1953.4063 1670.0897 1189.5299 366.9598 790.0472 2551.7378 1001.4246 3910.8049 16053.2805 26209.9893 1114.5997 972.2015 618.3678 893.9306 1698.2347 512.0855 1126.3767 1454.1004 654.3293 1254.5863 1190.0772 948.6930 2656.8429 512.9508 7779.9111 12116.9768 21900.0000 13696.6102 6333.8132 6557.5715 6220.1613 7534.4285 5302.6269 9022.0737 4109.4999 2847.8317 1195.8000 1673.9500 1488.6143 1321.8955 41703.0146 1063.6278 765.5881 4591.7946 2173.4632 722.7494 1251.9891 689.9197 295.2279 833.0673 1024.3828 861.8205 1303.7883 770.7952 1986.8195 6959.2899 13570.0000 10678.0076 4757.6158 9463.5051 9774.8935 9504.5987 4256.7258 11107.3677
273.15 191.93 52.17 356.11 145.03 192.25 259.36 147.43 258.81 279.63 111.66 186.85 -975.34 273.15 271.80 216.09 228.62 235.64 211.22 181.14 259.60 209.53 6.99 244.23 180.98 190.34 210.01 234.22 240.01 258.95 210.58 241.99 273.15 279.55 257.97 237.76 255.46 204.82 321.75 48.92 266.45 20.38 273.15 148.52 398.57 274.67 264.49 55.76 240.89 231.44 248.90 194.71 260.10 219.48 258.99 241.80 280.60 242.13 252.08 273.76 198.99 142.72 254.99 224.02 268.24 252.06 260.38 271.88 254.39 206.27 250.50 162.92 273.15 -210.04 228.44 364.07 453.72 55.45 135.98 215.65
1599.85 1009.85 569.00 912.00 820.00 1209.00 -52.20 81.30 100.00 744.00 178.00 2147.95 572.00 965.85 -189.37 280.00 41.80 -11.40 -2.50 -117.90 -116.92 164.00 133.70 88.00 952.85 2075.00 -45.00 -107.00 -128.37 -139.20 43.00 -154.90 -40.00 -93.30 -165.50 -63.00 -90.90 -40.40 -50.20 60.00 638.00 1368.00 1950.00 823.85 1.00 289.00 291.00 686.00 283.00 668.00 261.00 230.50 -75.15 25.85 -69.30 -7.30 2565.85 -127.78 -111.26 67.50 181.00 -0.14 -6.50 -76.40 -205.00 -138.80 -120.00 -56.57 -111.57 -95.80 14.00 591.00 836.85 1417.85 119.85 373.00 618.00 1112.00 296.00 1000.00
3198.00 2180.00 1502.00 1547.00 1506.00 2517.66 44.50 255.00 180.00 1276.00 382.00 2980.00 770.05 1082.85 -122.29 601.00 221.00 130.00 57.80 -52.80 99.85 329.50 467.15 259.00 2856.00 3799.00 91.00 178.80 -12.25 -64.00 200.00 -92.50 -14.00 16.30 16.65 53.00 18.00 295.30 63.00 163.80 1897.00 2250.00 2000.00 2483.85 90.00 474.00 482.00 1169.00 487.00 1564.00 453.00 447.00 28.85 157.85 40.50 311.00 3634.85 181.85 23.85 94.90 580.85 39.94 175.85 -46.00 -140.23 105.65 -22.00 31.04 278.85 -21.10 130.80 1482.00 1007.85 2533.35 767.00 844.00 960.00 1748.00 742.00 1559.00
2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
316
Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160
FORMULA CdS Ce CeBr3 CeCl3 ClF ClFO2 ClFO3 ClF3 ClF5 ClNO2 ClO2 Cl2 Cl2O Cl2O4 Cl2O6 Cl2O7 Co CoCl2 CoNC3O4 Cr CrC6O6 CrCl2 CrCl3 CrO2Cl2 CrO3 Cs CsBr CsCl CsF CsI Cu CuBr CuCl CuCl2 CuI DBr DCN DCl DF DI D2 D2O Dy Er Eu FHO3S FNO FNO2 FNO3 F2 F2O F2O2 Fe FeC5O5 FeCl2 FeCl3 FeI2 Fr Ga GaBr3 GaCl3 Gd Ge GeBr4 GeCl4 GeHCl3 GeH4 GeS Ge2H6 Ge3H8 HBr HCN HCl HClO3S HClO4 HF HI HNO3 HN3 HPO2F2
NAME cadmium sulfide cerium cerium bromide cerium chloride chlorine monofluoride chloryl fluoride perchloryl fluoride chlorine trifluoride chlorine pentafluoride nitryl chloride chlorine dioxide chlorine chlorine monoxide chlorine perchlorate chlorine hexoxide chlorine heptoxide cobalt cobalt chloride cobalt nitrosyl tricarbonyl chromium chromium carbonyl chromium chloride chromium chloride chromium oxychloride chromium oxide cesium cesium bromide cesium chloride cesium fluoride cesium iodide copper cuprous bromide cuprous chloride cupric chloride copper iodide deuterium bromide deuterium cyanide deuterium chloride deuterium fluoride deuterium iodide deuterium deuterium oxide dysprosium erbium europium fluorosulfonic acid nitrosyl fluoride nitryl fluoride fluorine nitrate fluorine fluorine oxide difluorine dioxide iron iron pentacarbonyl ferrous chloride ferric chloride iron iodide francium gallium gallium bromide gallium trichloride gadolinium germanium germanium bromide germanium chloride germane trichloro germane germanium sulfide digermane trigermane hydrogen bromide hydrogen cyanide hydrogen chloride chlorosulfonic acid perchloric acid hydrogen fluoride hydrogen iodide nitric acid hydrazoic acid difluorophosphoric acid
CAS No
A
B
C
TMIN
TMAX
code
1306-23-6 7440-45-1 14457-87-5 7790-86-5 7790-89-8 13637-83-7 7616-94-6 7790-91-2 13637-63-3 13444-90-1 10049-04-4 7782-50-5 7791-21-1 27218-16-2 12442-63-6 10294-48-1 7440-48-4 7646-79-9 14096-82-3 7440-47-3 13007-92-6 10049-05-5 10025-73-7 14977-61-8 1333-82-0 7440-46-2 7787-69-1 7647-17-8 13400-13-0 7789-17-5 7440-50-8 7787-70-4 7758-89-6 7447-39-4 7681-65-4 13536-59-9 3017-23-0 7698-05-7 14333-26-7 14104-45-1 7782-39-0 7789-20-0 7429-91-6 7440-52-0 7440-53-1 7789-21-1 7789-25-5 10022-50-1 7789-26-6 7782-41-4 7783-41-7 7783-44-0 7439-89-6 13463-40-6 7758-94-3 7705-08-0 7783-86-0 7440-73-5 7440-55-3 13450-88-9 13450-90-3 7440-54-2 7440-56-4 13450-92-5 10038-98-9 1184-65-2 7782-65-2 12025-32-0 13818-89-8 14691-44-2 10035-10-6 74-90-8 7647-01-0 7790-94-5 7601-90-3 7664-39-3 10034-85-2 7697-37-2 7782-79-8 13779-41-4
10.87780 8.54474 11.23239 10.38288 6.90617 6.67696 7.08309 7.34481 6.87794 5.37230 7.29962 7.06306 7.70028 7.53867 5.83238 7.59797 8.85240 7.04947 3.05780 8.48706 10.71935 12.16568 10.96666 6.76400 20.14000 6.67520 7.70150 7.74073 7.54319 7.64311 8.30991 5.01163 4.45573 -4.76869 4.81291 6.16238 6.25464 6.93596 7.21704 5.60474 6.31539 8.06347 6.67690 7.07492 6.80515 7.39950 7.88277 6.94723 6.53787 6.89461 7.29316 6.77902 8.37930 9.24491 7.23943 28.93093 7.09897 6.28464 8.24091 7.64043 7.54055 8.09461 8.39437 6.92749 6.27456 7.29569 7.08333 6.81801 6.98641 7.19898 6.93857 8.08422 7.25303 7.47025 6.71471 8.12392 6.99067 7.56453 6.65340 6.73530
10021.4278 20813.1074 14449.4770 15005.2628 644.1798 809.7800 854.6155 1086.4081 896.9883 395.4000 1033.2300 906.7031 1296.5974 1404.1800 1400.9600 1583.6401 18477.2528 4946.1939 9.5159 15307.9218 3410.1719 12935.2174 12720.2532 1231.6008 10300.0000 3515.7582 7132.1044 7233.7811 6579.0903 6849.9814 15006.7869 2858.6991 2327.4421 3645.4156 2646.3848 505.6800 689.1316 668.2000 1268.3700 414.6800 92.2133 1708.9717 9758.5876 12618.2924 6548.9117 1521.0000 986.5042 685.0522 721.4837 320.1001 580.8480 756.3900 16213.5121 2718.2717 4667.3502 32484.7863 4398.3915 3099.3568 13438.1916 2477.2199 2005.3675 18125.4084 16953.3407 1650.1032 971.2957 1304.6359 732.4097 6765.5528 1189.4193 1588.2499 704.4329 1655.8693 764.8366 1749.2078 1348.2463 1680.6466 881.4677 1431.7460 979.1881 1342.9000
273.15 231.68 273.15 273.15 249.77 218.96 250.03 231.62 237.51 174.00 222.93 250.83 266.83 257.00 273.15 253.72 166.22 137.52 6.92 59.51 280.20 273.15 273.15 200.16 273.15 255.57 179.48 191.46 160.10 158.38 202.14 -3.41 -12.18 -999.92 33.70 220.60 178.31 249.50 273.87 187.87 276.35 228.35 3.70 140.57 143.35 174.00 257.12 240.87 243.29 267.95 276.45 250.16 88.52 324.13 46.98 928.01 107.58 237.55 259.39 205.34 229.36 210.60 240.64 221.42 199.65 220.21 262.43 214.38 258.91 257.31 240.30 292.23 259.93 227.29 239.81 301.02 250.08 222.69 223.46 232.00
930.00 1719.00 1407.00 1677.00 -158.15 -82.15 -147.74 -73.70 -79.20 -87.15 -59.60 -101.03 -98.50 -44.15 151.50 -45.30 1517.00 770.00 -1.30 1383.00 36.00 1070.00 1250.00 -18.40 174.85 21.85 748.00 744.00 712.00 738.00 1216.00 572.00 429.85 309.70 610.00 -88.15 -68.90 -115.15 -84.15 -55.15 -254.42 3.82 1105.00 1231.00 590.00 64.85 -132.00 -156.00 -160.00 -219.67 -198.15 -125.15 1435.00 -6.50 700.00 108.00 587.00 121.00 1037.00 121.50 77.75 1563.00 1371.00 43.30 -45.00 -41.30 -165.89 615.00 -88.70 -36.90 -88.00 -13.32 -114.18 -80.00 -101.20 -83.36 -50.77 -41.60 -79.00 4.85
980.00 3443.00 1457.00 1727.00 26.85 21.85 95.25 11.75 24.80 -21.15 191.85 144.00 2.20 74.85 201.50 82.00 2925.00 1049.00 80.00 2671.00 151.00 1120.00 1300.00 117.00 194.85 671.00 1300.00 1297.00 1251.00 1280.00 2562.00 1345.00 1490.00 521.00 1336.00 -51.15 26.20 -62.15 49.85 -7.15 -234.80 370.74 2567.00 2868.00 1523.00 192.85 -59.90 -72.40 -46.00 -128.84 -63.15 -80.15 2860.20 103.00 1023.85 319.00 926.85 673.00 2245.00 226.85 420.85 3262.00 2833.00 186.35 86.55 75.30 34.85 726.85 30.80 110.50 90.00 183.50 51.50 426.85 357.85 188.00 150.70 102.95 35.70 151.85
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
317
Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240
FORMULA H2 H2O H2O2 H2S H2SO4 H2S2 H2S3 H2S4 H2S5 H2Se H2Te H3NO H3SNO3 He He Hf HfCl4 HfI3 Hg HgBr2 HgCl2 HgI2 Ho ICl IF5 IF7 I2 In InBr InBr3 InCl InCl3 Ir IrF6 K KBr KCl KF KI KOH Kr La LaBr3 LaCl3 Li LiBr LiCl LiF LiI Lu Mg MgBr2 MgCl2 MgF2 MgI2 MgO Mn MnCl2 MnF2 Mo MoCl5 MoF5 MoF6 MoOF4 MoO3 NClO NCl3 ND3 NF3 NF3S NH3 NH4Br NH4Cl NH4I NH5O NH5S NO NO2 N2 N2F4
NAME hydrogen water hydrogen peroxide hydrogen sulfide sulfuric acid hydrogen disulfide dihydrogen trisulfide dihydrogen tetrasulfide dihydrogen pentasulfide hydrogen selenide hydrogen telluride hydroxylamine sulfamic acid helium-3 helium-4 hafnium hafnium chloride hafnium iodide mercury mercuric bromide mercuric chloride mercuric iodide holmium iodine chloride iodine pentafluoride iodine heptafluoride iodine indium indium bromide indium bromide indium chloride indium chloride iridium iridium fluoride potassium potassium bromide potassium chloride potassium fluoride potassium iodide potassium hydroxide krypton lanthanum lanthanum bromide lanthanum chloride lithium lithium bromide lithium chloride lithium fluoride lithium iodide lutetium magnesium magnesium bromide magnesium chloride magnesium fluoride magnesium iodide magnesium oxide manganese manganese chloride manganese fluoride molybdenum molybdenum chloride molybdenum fluoride molybdenum fluoride molybdenum oxytetrafluoride molybdenum oxide nitrosyl chloride nitrogen trichloride heavy ammonia nitrogen trifluoride nitrogen fluoride sulfide ammonia ammonium bromide ammonium chloride ammonium iodide ammonium hydroxide ammonium hydrogensulfide nitric oxide nitrogen dioxide nitrogen tetrafluorohydrazine
CAS No
A
B
C
TMIN
TMAX
code
1333-74-0 7732-18-5 7722-84-1 7783-06-4 7664-93-9 13465-07-1 13845-23-3 13845-25-5 13845-24-4 7783-07-5 7783-09-7 7803-49-8 5329-14-6 14762-55-1 7440-59-7 7440-58-6 13499-05-3 13779-73-2 7439-97-6 7789-47-1 7487-94-7 7774-29-0 7440-60-0 7790-99-0 7783-66-6 16921-96-3 7553-56-2 7440-74-6 14280-53-6 13465-09-3 13465-10-6 10025-82-8 7439-88-5 7783-75-7 7440-09-7 7758-02-3 7447-40-7 7789-23-3 7681-11-0 1310-58-3 7439-90-9 7439-91-0 13536-79-3 10099-58-8 7439-93-2 7550-35-8 7447-41-8 7789-24-4 10377-51-2 7439-94-3 7439-95-4 7789-48-2 7786-30-3 7783-40-6 10377-58-9 1309-48-4 7439-96-5 7773-01-5 7782-64-1 7439-98-7 10241-05-1 13819-84-6 7783-77-9 14459-59-7 1313-27-5 2696-92-6 10025-85-1 13550-49-7 7783-54-2 15930-75-3 7664-41-7 12124-97-9 12125-02-9 12027-06-4 1336-21-6 12124-99-1 10102-43-9 10102-44-0 7727-37-9 10036-47-2
6.14858 8.05573 8.07489 7.11958 8.28538 7.02654 6.80710 6.94510 7.32010 6.46297 5.90921 11.71366 0.11312 4.82950 5.27120 9.06491 11.71000 19.56000 7.89458 5.56804 12.19380 7.11921 6.66154 7.69746 7.24100 8.58999 7.10736 7.98843 19.02460 5.89173 8.03000 13.62000 9.63425 8.56221 6.97431 7.60549 6.93314 7.61993 6.57543 7.08223 7.01408 8.57782 10.98826 14.66261 7.80332 7.57994 7.53439 8.71722 8.49354 7.83211 7.16078 7.38742 7.13801 7.87219 6.92855 6.92276 7.50506 7.03063 16.16514 8.64938 6.29946 8.49628 7.06989 8.53528 6.05246 7.83560 7.00316 6.83776 7.01648 6.88510 7.58743 9.74168 8.93371 10.40721 7.47687 8.96559 7.70299 9.74325 6.72531 7.41740
80.9480 1723.6425 1958.1824 802.2266 2976.8370 1242.2189 1488.0000 1772.0000 2104.0000 587.4538 586.0450 3155.6880 684.4925 8.5576 13.5171 30232.9115 5197.0000 10700.0000 3147.6142 974.6103 6369.7914 2015.6871 10226.4211 1515.4000 1387.0000 1562.5974 1556.9694 11856.7391 15000.0000 727.4250 4640.0000 8270.0000 30934.6262 1717.5557 4143.9271 7291.2713 5810.3508 7726.2515 5053.2934 6300.4849 511.6161 21096.9943 15000.0000 15000.0000 7953.8982 6947.3452 7299.6503 11054.9564 7459.8616 17422.3777 5253.0612 6095.1378 6696.7751 12036.3932 4121.1468 13862.2156 9853.7049 5467.6217 15000.0000 26943.1312 1850.0000 2709.7945 1018.5440 2492.6355 2898.1602 1314.8605 1212.7111 746.0100 559.5184 888.5000 1013.7815 4588.8568 3215.2979 5286.5838 1118.7172 1598.3103 473.0296 2289.6342 285.5727 952.4783
277.53 233.08 226.80 249.61 213.95 228.94 209.00 196.00 189.00 205.99 195.52 247.42 273.15 274.36 274.58 285.82 273.15 273.15 271.10 40.68 379.97 121.58 4.88 216.80 213.62 268.90 183.97 249.38 273.15 -183.70 273.15 273.15 190.68 248.71 254.47 163.23 17.98 128.32 22.90 172.76 277.13 239.17 273.15 273.15 276.84 168.43 185.61 221.14 155.25 116.75 137.71 104.02 161.05 82.67 109.39 -170.46 68.23 127.56 273.15 31.68 273.15 268.96 209.14 254.83 -233.00 270.75 223.18 221.53 264.35 245.00 248.83 272.85 192.35 297.41 245.15 229.34 249.87 312.65 270.09 284.15
-259.20 0.01 -0.41 -85.47 25.00 -40.00 54.85 110.85 152.85 -115.30 -96.40 33.10 20.00 -272.15 -271.39 2416.00 202.85 301.85 -38.84 136.50 136.20 157.50 1159.00 13.85 9.85 -87.00 -31.15 900.00 626.00 304.60 211.00 226.85 2440.00 -88.00 63.20 795.00 770.85 885.00 745.00 405.85 -157.37 1650.00 1547.00 970.00 524.30 748.00 783.00 1047.00 723.00 1600.00 428.00 711.00 778.00 1262.85 634.00 2831.85 955.00 736.00 826.00 2400.00 218.00 86.60 -65.50 -21.00 801.00 -59.60 -27.00 -74.00 -206.79 -94.15 -77.74 198.30 280.00 210.90 -70.00 -51.10 -163.65 -11.20 -210.00 -161.50
-239.97 373.98 457.00 100.38 336.85 70.70 200.85 273.85 318.85 -42.00 -2.00 109.85 100.00 -269.83 -267.95 4603.00 310.00 323.85 1461.85 322.00 304.00 354.00 2700.00 123.85 134.85 4.80 546.00 2072.00 656.00 364.80 576.85 426.85 4386.00 53.60 1949.85 1380.00 3196.85 1502.00 1344.85 1326.85 -63.80 3464.00 1577.00 1000.00 1337.10 1310.00 1383.00 1673.00 1173.85 3402.00 1088.00 1226.85 1412.00 2126.85 876.85 5676.85 2060.00 1190.00 856.00 4950.00 268.00 213.60 34.00 186.00 1140.00 167.50 94.00 -33.00 -39.30 1.85 132.50 396.00 520.00 405.00 80.00 33.30 -93.00 158.20 -147.05 36.20
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 2 1,2 1,2 1,2 1,2
318
Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 241 242 243 244 245 246 247 248 249 250 251 252 253 254 255 256 257 258 259 260 261 262 263 264 265 266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282 283 284 285 286 287 288 289 290 291 292 293 294 295 296 297 298 299 300 301 302 303 304 305 306 307 308 309 310 311 312 313 314 315 316 317 318 319 320
FORMULA N2H4 N2H4C N2H6CO2 N2O N2O3 N2O4 N2O5 Na NaBr NaCN NaCl NaF NaI NaOH Na2SO4 Nb NbBr5 NbCl4 NbCl5 NbF5 Nd NdBr3 NdCl3 Ne Ni NiC4O4 NiCl2 NiF2 Np NpF6 O2 O3 Os OsF5 OsF6 OsOF5 OsO4 P P PBrF2 PBr2F PBr3 PBr5 PClF2 PCl2F PCl2F3 PCl3 PCl5 PF3 PF3O PF5 PH3 PH4Br PH4Cl PH4I POBrClF POBrCl2 POBrF2 POBr3 POClF2 POCl2F POCl3 PSBr3 PSCl3 P2O3 P2O5 P2S5 P4O6 Pb PbBr2 PbCl2 PbF2 PbI2 PbO PbO PbS Pd Po PoCl4 Pr
NAME hydrazine ammonium cyanide ammonium carbamate nitrous oxide nitrogen trioxide nitrogen tetraoxide nitrogen pentoxide sodium sodium bromide sodium cyanide sodium chloride sodium fluoride sodium iodide sodium hydroxide sodium sulfate niobium niobium bromide niobium chloride niobium chloride niobium fluoride neodymium neodymium tribromide neodymium trichloride neon nickel nickel carbonyl nickel chloride nickel fluoride neptunium neptunium hexafluoride oxygen ozone osmium osmium fluoride osmium fluoride osmium oxide pentafluoride osmium tetroxide phosphorus (white) phosphorus (red) phosphorus bromide difluoride phosphorus dibromide fluoride phosphorus tribromide phosphorus bromide phosphorus chloride difluoride phosphorus dichloride fluoride phosphorus dichloride trifluoride phosphorus chloride phosphorus pentachloride phosphorus fluoride phosphorus oxyfluoride phosphorus fluoride phosphine phosphonium bromide phosphonium chloride phosphonium iodide phosphoryl bromide chloride fluoride phosphoryl bromide dichloride phosphoryl bromide difluoride phosphorus oxybromide phosphoryl chloride difluoride phosphoryl dichloride fluoride phosphorus oxychloride phosphorus thiobromide phosphorus thiochloride phosphorus trioxide phosphorus pentoxide phosphorus sulfide phosphorous oxide lead lead bromide lead chloride lead fluoride lead iodide lead oxide lead oxide (massicot) lead sulfide palladium polonium polonium tetrachloride praseodymium
CAS No
A
B
C
TMIN
TMAX
code
302-01-2 12211-52-8 1111-78-0 10024-97-2 10544-73-7 10544-72-6 10102-03-1 7440-23-5 7647-15-6 143-33-9 7647-14-5 7681-49-4 7681-82-5 1310-73-2 7757-82-6 7440-03-1 13478-45-0 13569-70-5 10026-12-7 7783-68-8 7440-00-8 13536-80-6 10024-93-8 7440-01-9 7440-02-0 13463-39-3 7718-54-9 10028-18-9 7439-99-8 14521-05-2 7782-44-7 10028-15-6 7440-04-2 31576-40-6 13768-38-2 --20816-12-0 7723-14-0 7723-14-0 15597-40-7 15597-39-4 7789-60-8 7789-69-7 14335-40-1 15597-63-4 13454-99-4 7719-12-2 10026-13-8 7783-55-3 13478-20-1 7647-19-0 7803-51-2 --24567-53-1 12125-09-6 14518-81-1 13455-03-3 14014-18-7 7789-59-5 13769-75-0 13769-76-1 10025-87-3 3931-89-3 3982-91-0 1314-24-5 1314-56-3 1314-80-3 12440-00-5 7439-92-1 10031-22-8 7758-95-4 7783-46-2 10101-63-0 1317-36-8 1317-36-8 1314-87-0 7440-05-3 7440-08-6 10026-02-5 7440-10-0
7.82877 9.16524 10.32341 6.81488 7.60164 4.09407 11.93250 7.33576 7.54103 7.38628 7.96318 8.61974 7.89004 7.46511 11.40104 9.92532 9.33000 12.30000 8.37000 6.88947 6.95222 11.15371 10.88871 6.74431 8.74585 7.64987 10.25227 8.31881 7.90387 7.19634 6.83706 7.15980 9.76546 9.75828 8.26547 3.06277 4.72185 7.00000 11.39619 6.90420 6.85800 7.35097 10.31441 7.34733 7.11413 7.38018 6.87188 10.28827 7.06415 10.28247 9.61509 6.98375 10.09866 9.08492 10.23174 6.91410 6.92410 7.10190 7.13796 6.92660 7.08465 7.05109 9.40218 7.11462 8.39335 10.74529 9.02309 8.35860 7.46345 8.87105 7.64617 7.62479 6.76027 9.24183 9.33076 8.84745 8.56766 7.18388 9.33621 6.78062
1698.5808 1644.6341 2267.7036 550.6045 1109.3200 97.8287 2617.6543 5060.9675 7142.9394 7836.8557 8432.2350 11408.3735 7361.9912 7606.4353 15657.1880 35189.3422 4085.0000 6870.0000 2870.0000 1791.5982 12884.3059 15000.0000 15000.0000 115.3285 17882.3827 1479.9228 8220.2197 7276.8348 22003.2016 1271.8225 339.2095 618.6072 34751.0553 3432.7793 1525.6447 47.1535 404.5748 2016.5981 5737.7187 885.1200 1210.3000 1883.6717 2746.6473 1041.3236 1120.6064 1175.5119 1218.9462 2973.0094 651.8743 1549.5473 1143.4832 724.4708 2085.9953 1255.1903 2291.9882 1214.0000 1411.0000 1118.9000 1697.4936 946.9600 1201.8600 1390.0324 2659.4144 1501.0578 2597.3392 6470.4817 4959.9962 2568.0727 9131.8353 6987.2446 5101.5890 6525.7272 3580.4550 10820.2993 11048.8015 7859.9264 18403.4082 5265.0104 4280.8340 14030.7383
229.79 230.00 245.93 228.44 232.98 59.47 256.19 254.35 142.08 243.41 194.07 278.32 165.84 280.16 273.15 251.22 273.15 273.15 273.15 217.93 97.12 273.15 273.15 275.91 134.99 267.82 130.14 -160.62 273.15 239.53 268.70 255.87 35.61 273.23 235.83 1.04 84.75 215.00 242.50 236.00 226.00 248.44 259.11 280.39 250.71 257.82 229.32 241.50 257.33 248.89 254.40 264.31 250.37 229.31 249.30 222.00 213.00 233.00 207.04 231.00 233.00 227.82 232.93 229.54 298.17 217.75 293.52 295.82 243.70 274.44 119.56 82.58 50.32 227.03 240.48 36.31 273.13 261.55 273.15 77.80
1.53 -50.60 -26.10 -90.85 -103.15 -11.25 -36.80 280.60 746.85 563.70 800.75 995.85 767.00 500.00 1514.50 2669.00 254.00 303.85 204.70 86.30 1322.30 1510.00 1570.00 -248.59 1510.00 -23.00 534.00 1077.00 1726.85 54.85 -218.80 -193.00 2600.00 74.10 -89.00 31.65 3.20 69.00 181.85 -91.15 -18.15 7.80 -19.00 -119.50 -71.10 -79.80 -92.00 -12.00 -152.00 -124.00 -157.00 -133.78 -43.70 -91.00 -25.20 -10.15 31.85 -44.15 64.00 -76.15 -40.15 1.18 50.00 -36.20 47.30 230.00 288.00 39.70 434.85 513.00 547.00 861.00 479.00 943.00 724.00 852.00 1300.00 500.00 300.60 1497.70
380.00 31.70 58.30 36.42 151.85 47.50 33.00 926.85 1446.85 1496.00 1465.05 1786.85 1303.85 1600.00 1564.50 4740.00 360.00 377.85 246.85 229.00 3063.00 1540.00 1600.00 -228.75 2911.00 42.50 985.00 1283.00 2226.85 76.85 -118.57 -12.15 5400.00 225.90 47.50 57.75 135.00 317.00 431.00 10.85 109.85 172.95 110.10 89.25 189.85 -22.80 101.00 159.85 -1.95 -39.70 -84.60 51.60 38.30 -27.00 62.50 102.85 162.85 51.85 191.70 30.85 84.85 105.50 175.00 125.00 173.00 700.00 1017.85 173.00 1749.00 892.00 951.00 1293.00 872.00 1474.00 1471.00 1281.00 3400.00 1050.00 410.00 3520.00
1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
319
Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 321 322 323 324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 340 341 342 343 344 345 346 347 348 349 350 351 352 353 354 355 356 357 358 359 360 361 362 363 364 365 366 367 368 369 370 371 372 373 374 375 376 377 378 379 380 381 382 383 384 385 386 387 388 389 390 391 392 393 394 395 396 397 398 399 400
FORMULA PrCl3 Pt Pu PuBr3 PuCl3 PuF3 Ra Rb RbBr RbCl RbF RbI Re ReF5 ReF6 ReF7 ReOF4 ReOF5 ReO2F3 Re2O7 Rh Rn Ru RuF5 S SCl2 SFN SF2N2 SF4 SF6 SOBr2 SOClF SOCl2 SOF2 SOF4 SO2 SO2BrF SO2ClF SO2Cl2 SO2F2 SO3 S2Br2 S2Cl2 S2F2 S2F10 S2O2F10 S2O5ClF S2O5Cl2 S2O5F2 S2O5F4 S3O8F2 Sb SbBr3 SbCl3 SbCl5 SbH3 SbI3 Sb2O3 Sc ScBr3 ScCl3 ScI3 Se SeCS SeCl4 SeF4 SeF6 SeOCl2 SeOF2 SeO2 Si SiBrCl2F SiBr2ClF SiCCl3N SiCCl3NS SiCH2Cl4O SiCH3Cl2F SiCH3Cl3 SiCH3F3 SiCH4ClF
NAME praseodymium chloride platinum plutonium plutonium bromide plutonium chloride plutonium fluoride radium rubidium rubidium bromide rubidium chloride rubidium fluoride rubidium iodide rhenium rhenium fluoride rhenium fluoride rhenium fluoride rhenium oxytetrafluoride rhenium oxypentafluoride rhenium dioxytrifluoride rhenium heptoxide rhodium radon ruthenium ruthenium fluoride sulfur sulfur dichloride thiazyl fluoride dinitrogen sulfur difluoride sulfur tetrafluoride sulfur hexafluoride thionyl bromide thionyl chloride fluoride thionyl chloride thionyl fluoride sulfur oxide tetrafluoride sulfur dioxide sulfuryl bromide fluoride sulfuryl chloride fluoride sulfuryl chloride sulfuryl fluoride sulfur trioxide sulfur bromide sulfur monochloride disulfur difluoride sulfur decafluoride thiosulfuryl decafluoride pyrosulfuryl chloride fluoride pyrosulfuryl chloride pyrosulfuryl difluoride disulfur pentoxide tetrafluoride trisulfur octoxide difluoride antimony antimony tribromide antimony trichloride antimony pentachloride stibine antimony triiodide antimony oxide scandium scandium bromide scandium chloride scandium iodide selenium (gray) carbonyl selenide sulfide selenium tetrachloride selenium tetrafluoride selenium hexafluoride selenium oxychloride selenium oxyfluoride selenium dioxide silicon silane bromodichlorofluoro silane dibromochlorofluoro silane trichloro-carbonitrile silane trichloroisothio-cyanato silane trichloro(chloro-methoxy) silane dichlorofluoro-methyl silane methyltrichloro silane trifluoromethyl silane chlorofluoro-methyl
CAS No
A
B
C
TMIN
TMAX
code
10361-79-2 7440-06-4 7440-07-5 15752-46-2 13569-62-5 13842-83-6 7440-14-4 7440-17-7 7789-39-1 7791-11-9 13446-74-7 7790-29-6 7440-15-5 30937-52-1 10049-17-9 17029-21-9 17026-29-8 23377-53-9 57246-89-6 1314-68-7 7440-16-6 10043-92-2 7440-18-8 14521-18-7 7704-34-9 10545-99-0 18820-63-8 500010-01-5 7783-60-0 2551-62-4 507-16-4 14177-25-4 7719-09-7 7783-42-8 13709-54-1 7446-09-5 13536-61-3 13637-84-8 7791-25-5 2699-79-8 7446-11-9 13172-31-1 10025-67-9 16860-99-4 5714-22-7 12395-41-4 13637-85-9 7791-27-7 13036-75-4 44982-62-9 13709-33-6 7440-36-0 7789-61-9 10025-91-9 7647-18-9 7803-52-3 7790-44-5 1309-64-4 7440-20-2 13465-59-3 10361-84-9 14474-33-0 7782-49-2 5951-19-9 10026-03-6 13465-66-2 7783-79-1 7791-23-3 7783-43-9 7446-08-4 7440-21-3 ----18157-01-2 18157-00-1 18157-08-9 420-58-6 75-79-6 373-74-0 373-67-1
10.44454 8.58584 8.08674 8.15259 7.22981 9.39122 6.71596 6.99992 8.13532 7.05736 6.21681 7.66815 8.97642 8.98978 8.47754 11.47517 9.45214 7.90580 10.36000 10.48807 9.68520 6.58011 9.33600 7.56315 7.86630 8.36643 6.48180 6.78280 7.02242 6.87699 8.17193 7.17310 7.27960 6.28388 7.07180 7.33311 7.14280 6.52150 6.94482 6.90700 6.85638 7.17834 7.04178 6.68410 7.06760 6.87410 7.01560 7.01910 6.88110 6.88510 6.99010 5.88125 8.00960 6.91949 7.76515 7.20112 7.55355 4.06652 7.72648 14.35000 14.37000 14.17000 7.05403 6.89093 10.79338 7.61816 6.99021 7.90109 7.42010 18.01392 8.71307 7.51839 7.26677 7.75100 7.99850 8.39500 7.74530 7.18818 7.97520 7.60660
15000.0000 22055.7478 18531.9774 8352.8990 8007.1303 14145.3938 6622.4566 3926.1751 8288.1158 6116.0391 3433.9886 7039.8460 34838.4703 3010.3083 1550.5300 5114.2585 2533.4840 1772.1930 3437.0000 4082.7928 26833.7062 651.6732 26794.4200 2037.5032 3464.9835 1559.0062 877.1000 901.0000 882.8300 676.2391 2202.4959 1100.1000 1415.8028 569.2883 840.3000 1013.4609 1155.0000 793.7300 1194.8068 784.3000 754.8178 1664.6387 1466.8804 628.0000 1100.6000 1110.0000 1257.4000 1460.0000 1120.0000 1140.0000 1360.0000 4984.6752 2654.1840 1709.1498 2046.6707 1062.6666 2915.0705 1464.9462 13961.2550 13780.0000 14200.0000 13340.0000 3441.9628 1274.4371 3477.8728 1471.6008 727.3425 1958.4938 1380.0000 11598.1403 20614.1581 1472.7873 1379.5487 1687.0000 2060.0000 2159.0000 1472.3000 1370.6632 1238.1000 1296.6000
273.15 41.02 331.78 93.61 48.46 49.57 200.78 265.16 237.34 74.38 -380.62 170.51 119.34 271.47 243.24 521.55 213.84 279.68 273.15 176.70 248.59 237.86 33.09 196.96 250.34 224.60 239.00 242.00 253.61 233.12 276.26 244.00 246.26 211.09 249.00 237.65 231.00 210.70 224.60 250.00 145.11 185.93 215.53 256.00 234.00 229.00 204.00 202.00 229.00 227.00 211.00 74.32 237.51 202.95 240.86 263.97 222.85 -189.49 45.18 273.15 273.15 273.15 139.77 232.21 248.14 204.64 222.79 213.12 178.00 451.41 267.17 282.18 255.04 273.15 273.15 273.15 273.15 251.81 273.15 273.15
1680.00 2057.00 1483.00 681.00 760.00 1396.00 546.00 160.40 781.00 792.00 921.00 748.00 3030.00 58.80 -97.00 48.30 5.00 -103.00 90.00 120.00 2015.00 -163.00 2315.00 49.60 102.00 -76.00 -8.15 -83.15 -100.00 -168.00 -6.70 -65.15 -101.15 -98.73 -113.15 -75.48 -45.15 -72.15 -51.15 -121.15 16.80 -7.00 -7.40 -120.15 -47.15 -34.15 4.85 47.85 -33.15 -27.15 22.85 534.00 93.90 73.40 22.70 -95.28 163.60 400.00 1300.00 768.85 791.85 736.85 227.00 -47.30 74.00 13.60 -153.00 34.80 36.85 115.00 1634.85 -86.50 -65.20 -46.15 66.85 -0.15 -30.15 -77.80 -60.15 -75.15
1710.00 3825.00 3228.00 1476.85 1776.85 1726.85 1526.00 688.00 1340.00 1390.00 1410.00 1300.00 5681.00 221.30 33.80 71.85 171.70 73.00 181.85 500.00 3695.00 103.85 4115.00 156.80 444.00 59.60 29.85 8.85 -40.45 45.54 140.00 36.85 99.00 -43.80 -25.15 157.60 67.85 36.85 271.85 -32.15 217.70 200.90 137.00 -77.15 48.85 70.85 130.85 177.85 72.85 79.85 145.85 1587.00 280.00 520.85 114.10 167.20 401.00 1550.00 3200.00 926.85 959.85 906.85 685.00 85.60 191.40 106.00 72.35 177.00 152.85 335.00 3264.85 201.15 242.77 73.24 129.38 118.39 -27.15 243.85 -57.15 1.22
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
320
Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 401 402 403 404 405 406 407 408 409 410 411 412 413 414 415 416 417 418 419 420 421 422 423 424 425 426 427 428 429 430 431 432 433 434 435 436 437 438 439 440 441 442 443 444 445 446 447 448 449 450 451 452 453 454 455 456 457 458 459 460 461 462 463 464 465 466 467 468 469 470 471 472 473 474 475 476 477 478 479 480
FORMULA SiCH4Cl2 SiCH4F2 SiCH5Cl SiCH5Cl SiCH6 SiCH6O SiC2H8 SiC3H10 SiC4H12 SiClF3 SiCl2F2 SiCl3F SiCl4 SiF4 SiHBr3 SiHCl3 SiHF3 SiH2Br2 SiH2Cl2 SiH2F2 SiH2I2 SiH3Br SiH3Cl SiH3F SiH3I SiH4 SiI4 SiO2 Si2CH3Cl5 Si2CH7Cl Si2CH7Cl Si2C2H4Cl6 Si2C2H4Cl6 Si2C2H6Cl4 Si2C2H9FO Si2Cl3F3O Si2Cl6 Si2Cl6O Si2F6 Si2H6 Si2H6O Si3Cl8 Si3H8 Si3H9N Si4H10 Sm Sn SnBr4 SnCl2 SnCl4 SnH4 SnI4 SnS Sr SrF2 SrO Ta TaBr5 TaCl5 TaF5 Tb Tc Tc2O7 Te TeCl2 TeCl4 TeF4 TeF6 TeO2 Te2F10 Th ThBr4 ThCl4 ThI4 ThO2 Ti TiBr4 TiCl2 TiCl4 TiF4
NAME silane methyl dichloro silane difluoromethyl silane methyl chloro silane (chloromethyl) silane methyl methyl silyl ether silane dimethyl silane trimethyl silane tetramethyl silane chlorotrifluoro silane dichlorodifluoro silane trichlorofluoro silicon tetrachloride silicon tetrafluoride silane tribromo silane trichloro silane trifluoro silane dibromo silane dichloro silane difluoro silane diiodo silane monobromo silane monochloro silane monofluoro silane iodo silane silane tetraiodo silicon dioxide (alpha quartz) silane pentachloromethyl-di silane [(chlorosilyl)methyl]silane (chloromethyl)-di 1,2-bis(trichlorosilyl)ethane 1,1,1,3,3,3-hexachloro-2-methyl-1,3-disilapropane silane 1,2,2,2-tetrachloro-1,1-dimethyldi 1-fluoro-1,3-dimethyldisiloxane disiloxane, trichlorotrifluoro disilane hexachloro disiloxane, hexachloro disilane hexafluoro disilane disiloxane octachlorotrisilane trisilane trisilazane tetrasilane samarium tin (white) stannic bromide stannous chloride stannic chloride stannane stannic iodide tin sulfide strontium strontium fluoride strontium oxide tantalum tantalum bromide tantalum chloride tantalum fluoride terbium technetium technetium heptoxide tellurium tellurium dichloride tellurium tetrachloride tellurium tetrafluoride tellurium hexafluoride tellurium dioxide tellurium decafluoride thorium thorium bromide thorium chloride thorium iodide thorium oxide titanium titanium bromide titanium chloride titanium tetrachloride titanium fluoride
CAS No
A
B
C
TMIN
TMAX
code
75-54-7 420-34-8 993-00-0 10112-09-1 992-94-9 2171-96-2 1111-74-6 993-07-7 75-76-3 14049-36-6 18356-71-3 14965-52-7 10026-04-7 7783-61-1 7789-57-3 10025-78-2 13465-71-9 13768-94-0 4109-96-0 13824-36-7 13760-02-6 13465-73-1 13465-78-6 13537-33-2 13598-42-0 7803-62-5 13465-84-4 14808-60-7 26980-40-5 35483-45-5 54713-74-5 2504-64-5 18076-92-1 26980-43-8 35192-38-2 --13465-77-5 14986-21-1 --1590-87-0 13597-73-4 13596-23-1 7783-26-8 --7783-29-1 7440-19-9 7440-31-5 7789-67-5 7772-99-8 7646-78-8 2406-52-2 7790-47-8 1314-95-0 7440-24-6 7783-48-4 1314-11-0 7440-25-7 13451-11-1 7721-01-9 7783-71-3 7440-27-9 7440-26-8 --13494-80-9 10025-71-5 10026-07-0 15192-26-4 7783-80-4 7446-07-3 53214-07-6 7440-29-1 13453-49-1 10026-08-1 7790-49-0 1314-20-1 7440-32-6 7789-68-6 10049-06-6 7550-45-0 7783-63-3
7.23413 7.76550 7.04725 8.09302 7.10688 3.98012 6.73312 6.90193 6.87190 7.06315 7.33305 7.15967 7.00381 6.72479 6.97115 7.10586 6.50485 7.05269 6.98538 6.68670 7.36622 7.24230 6.76710 6.29474 7.04589 7.12525 6.97269 9.87451 7.91847 7.83841 8.09282 7.82031 8.10890 7.14487 6.32253 9.03398 7.36013 7.12363 12.22960 7.00941 7.42748 8.65954 7.22385 7.15693 6.54087 6.72424 8.54915 7.14579 7.51627 6.85720 7.15934 6.06085 9.97000 6.83233 8.06789 7.51441 8.73303 8.14000 11.98340 6.45981 7.41799 26.08539 9.00000 6.63850 8.51000 8.59582 5.64000 8.65918 12.76126 6.90180 8.08673 9.56000 9.57000 9.09000 9.64285 8.90223 6.97018 8.35740 7.29500 10.87761
1272.2113 1160.4000 1054.7751 1719.2800 873.3901 185.6317 853.3608 1030.4100 1060.6645 761.3693 1054.7676 1116.6266 1205.9453 459.3741 1382.4891 1191.2883 466.9478 1295.7656 1032.4344 609.3862 2014.1634 1152.7870 797.8130 412.9780 1204.6095 704.8874 1909.4768 16418.2297 2186.1100 1674.1300 1875.0700 2242.0000 2425.0000 1680.7900 1162.7400 2311.2185 1615.6257 1465.7767 2464.6767 1015.4056 1137.4567 2872.1180 1329.1653 1247.8657 1122.5646 7242.8476 16655.8123 1846.6483 3705.3738 1294.1344 937.8599 1628.2894 10460.0000 6128.6851 12904.6141 9499.3367 31263.6507 3260.0000 4654.0000 1797.9105 14824.6184 236826.8849 3570.0000 4084.3774 3350.0000 3538.9650 1787.0000 1258.5289 15000.0000 1150.0000 25785.3686 7550.0000 7980.0000 6890.0000 31600.0000 20948.9918 1791.8855 10003.3561 1668.8244 4455.4168
250.69 273.15 244.46 298.60 263.57 149.98 241.12 249.55 239.11 252.04 268.91 248.71 235.64 215.21 228.99 250.11 223.85 244.60 243.23 237.92 299.05 261.91 235.69 218.97 243.82 278.22 201.81 117.52 281.29 273.15 273.15 251.00 273.15 236.84 274.47 332.87 215.69 210.43 282.54 260.09 265.37 285.62 253.14 243.12 199.31 90.48 336.40 227.98 176.36 211.30 271.00 147.69 273.15 168.97 3.46 -803.52 -115.81 273.15 273.15 273.15 37.37 5941.04 273.15 98.94 273.15 232.24 273.15 256.70 273.15 227.00 165.09 273.15 273.15 273.15 273.15 190.76 205.54 174.30 242.21 273.15
-90.60 -75.15 -134.10 -27.15 -156.81 -90.20 -150.22 -135.89 -99.08 -144.00 -124.70 -92.60 -68.85 -156.00 -30.50 -128.20 -152.00 -60.90 -122.00 -146.70 3.80 -85.70 -117.80 -153.00 -53.00 -185.00 120.50 1609.85 34.85 -0.15 -23.15 90.85 54.85 26.85 -78.15 -38.00 4.00 -5.00 -81.00 -129.30 -112.50 46.30 -68.90 -68.70 -27.70 700.00 1150.00 58.30 316.00 -22.70 -140.00 156.00 726.85 523.00 1477.00 1750.00 3024.00 265.00 188.13 119.00 1516.10 2400.00 118.85 502.00 208.00 233.00 129.00 -111.30 1215.00 -33.15 2360.00 679.00 770.00 582.85 4350.00 1709.00 39.00 1035.00 -24.10 234.00
209.85 -35.59 168.85 31.26 79.35 18.88 128.85 158.85 177.25 35.68 94.20 161.70 233.85 -14.15 344.35 205.85 3.50 286.09 175.85 37.60 410.66 182.00 123.64 12.72 251.44 -3.45 256.85 2230.05 37.85 64.54 86.61 202.89 190.69 157.34 63.37 42.74 145.00 135.60 -18.90 158.85 -15.20 211.40 52.90 48.70 107.40 2000.00 2800.00 205.00 623.00 114.15 -51.80 364.35 1026.85 1382.00 2426.85 2700.00 5458.00 336.85 238.13 249.20 3230.00 4400.00 306.85 988.00 316.85 387.00 196.85 -38.90 1245.00 89.85 4788.00 852.85 912.85 833.85 4400.00 3285.00 228.85 1426.85 364.85 284.00
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
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Table 2 Vapor Pressure – Inorganic Compounds log10 P = A - B/(T + C) (P - mmHg, T - C) NO 481 482 483 484 485 486 487 488 489 490 491 492 493 494 495 496 497 498 499 500 501 502 503 504 505 506 507 508 509 510 511 512 513 514 515 516 517 518 519 520 521 522 523 524 525
FORMULA TiI4 Tl TlBr TlCl TlF TlI Tm U UBr3 UBr4 UCl4 UCl6 UF4 UF6 UI4 V VCl4 VF5 VOCl3 V2O5 W WCl4 WCl5 WCl6 WF6 WOF4 WO3 Xe XeF2 XeF4 Y Yb Zn ZnBr2 ZnCl2 ZnF2 ZnI2 ZnO ZnS ZnSO4 Zr ZrBr4 ZrCl4 ZrF4 ZrI4
NAME titanium iodide thallium thallous bromide thallium chloride thallium fluoride thallium iodide thulium uranium uranium bromide uranium bromide uranium chloride uranium chloride uranium fluoride uranium fluoride uranium iodide vanadium vanadium tetrachloride vanadium fluoride vanadium oxytrichloride vanadium oxide tungsten tungsten chloride tungsten chloride tungsten chloride tungsten fluoride tungsten oxytetrafluoride tungsten oxide xenon xenon difluoride xenon tetrafluoride yttrium ytterbium zinc zinc bromide zinc chloride zinc fluoride zinc iodide zinc oxide zinc sulfide (wurtzite) zinc sulfate zirconium zirconium bromide zirconium chloride zirconium fluoride zirconium iodide
CAS No
A
B
C
TMIN
TMAX
code
7720-83-4 7440-28-0 7789-40-4 7791-12-0 7789-27-7 7790-30-9 7440-30-4 7440-61-1 13470-19-4 13470-20-7 10026-10-5 13763-23-0 10049-14-6 7783-81-5 13470-22-9 7440-62-2 7632-51-1 7783-72-4 7727-18-6 1314-62-1 7440-33-7 13470-13-8 13470-14-9 13283-01-7 7783-82-6 13520-79-1 1314-35-8 7440-63-3 13709-36-9 13709-61-0 7440-65-5 7440-64-4 7440-66-6 7699-45-8 7646-85-7 7783-49-5 10139-47-6 1314-13-2 1314-98-3 7733-02-0 7440-67-7 13777-25-8 10026-11-6 7783-64-4 13986-26-0
7.57600 7.58000 7.32435 -5.69389 9.88714 7.34352 7.82243 7.77000 9.06095 8.12161 9.01541 7.87988 8.93038 8.47645 8.81552 9.18000 7.32955 10.43000 7.02483 5.05000 9.98307 8.19500 7.72000 7.87000 7.07104 9.32296 14.53875 7.02795 6.96427 10.91390 8.00530 7.28084 7.57409 8.49304 8.50869 6.56144 18.01392 9.97977 12.46830 8.74032 9.12202 10.28269 11.44848 15.61264 11.20709
3054.0000 8060.0496 4432.7693 6065.8547 6902.2858 4374.7071 10435.3130 23272.8375 10506.7518 4834.9448 5767.4399 4000.0000 9333.8078 1568.8742 5446.7685 22303.0522 1823.3734 2423.0000 1518.9432 7100.0000 40387.9650 3253.0000 2760.0000 3050.0000 907.7240 2709.3726 24600.0000 701.1036 1073.3758 3095.0600 17991.8060 6060.1722 5241.2423 4782.6046 5054.5539 4368.9367 19725.9709 15781.3538 13980.0000 2215.7753 28773.5320 4025.9186 4801.8756 15000.0000 5397.4287
273.15 229.50 178.58 -1427.41 273.15 156.28 205.05 600.00 178.05 143.94 147.57 273.15 95.95 223.87 159.45 133.69 258.01 273.15 239.69 273.15 131.64 273.15 273.15 273.15 199.53 234.67 273.15 277.06 148.51 269.56 165.95 181.30 203.39 185.14 166.13 -312.99 678.50 273.15 273.15 273.15 201.25 183.91 229.46 273.15 217.24
156.85 609.00 490.00 504.00 662.00 440.00 844.00 2052.00 727.00 519.00 590.00 477.00 1036.00 -38.80 506.00 1828.00 -25.70 19.50 -79.50 670.00 3204.00 281.85 242.00 275.00 -71.60 2.00 1787.00 -111.75 2.90 35.85 1610.10 463.00 337.00 397.85 428.00 970.00 301.00 1499.95 1135.00 20.00 2366.00 207.00 190.00 875.00 264.00
369.85 1485.00 819.00 720.00 712.00 824.00 1297.00 4129.00 926.85 766.85 770.00 527.00 1400.00 56.50 726.85 3406.85 423.85 45.00 126.85 1226.85 5555.00 326.85 280.00 340.00 17.10 185.90 1837.00 16.55 357.85 117.85 3345.00 1196.00 912.00 561.85 732.00 1500.00 625.00 1949.95 1185.00 105.00 4409.00 360.00 331.00 905.00 431.00
1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 2 2 1,2 1,2 1,2 1,2 1,2
Code: 1 - data, 2 - estimate, 3 - rough estimate. P - vapor pressure, mmHg. A, B, and C - Antoine coefficients for chemical compound. T - temperature, °C. TMIN - minimum temperature, °C. TMAX - maximum temperature, °C.
322