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Vibrations measured at surfaces by high resolution electron energy loss spectroscopy : updated review (1982–1985)
Journal of Electron Spectroscopy and Related Phenomena, 39 (1986) 273-288 Elsevier Science Publishers B.V., Amsterdam - Printed in The Netherlands
VIBRATIONS
MEASURED
AT SURFACES
: UPDATED
SPECTROSCOPY
REVIEW
BY HIGH RESOLUTION
ELECTRON
2’73
ENERGY LOSS
(1982-1985)*
P.A. Thiry Laboratoire Institute Facultes
de Spectroscopic
Electronique
for Research
in Interface
Universitaires
Notre-Dame
Sciences de la Paix, B-5000 Namur
(Belgium).
ABSTRACT A tabular review of HREELS measurements for the period 1982 to September 1985 is presented. It contains 291 references and a table of the systems (substrate-adsorbate) investigated.
INTRODUCTION This tabular
review
updates
of the third Conference Only new references ring continues
are presented
one published
at Surfaces
here in chronological
the substrates
new experimental
and the various
1982) (ref.1).
order and their numbe-
and theoretical
data. Table
adsorbates
in the Proceedings
(Asilomar,
the one of ref. 1. Review articles
included when they provide order,
the previous
on Vibrations
papers are
I lists in alphabetical
investigated,
respectively.
Fig. 1. Histogram showing the number of experimental HREELS papers published annually during the period 1967 to 1984. (see ref.1 for 1967 to 1982).
67
70
75
80
84
year REFERENCE 1 P.A. Thiry, J. Electron
Spectrosc.,
30 (1983) 261-,273.
*This work is supported by the Belgian Fund for Joint Basic Research Belgian Ministry for Science Policy (IRIS project).
0368s2048/86/$03.50
0 1986 Elsevier Science Publishers
B.V.
and by the
274 TABLE
1
Ag(llO)
Acetylene Carbon dioxide Carbon monoxide Ethylene Ethylene oxide Formaldehvde Formic a&d Oxygen
Ag(lll) Benzene Cyc7ohexane Hydrogen Oxygen Pyridine
Ag(311)
Ammonia Methyl isocyanide
Ag(films) Behenic acid Linolenic acid Nitrosen Oleic-acid
Oxygen
Stearic
acid
255. 318. 318. 318. 318. 237, 395. 285, 395. 237, 255, 285, 318, 395. 256. 256. 256. 256, 322. 256. 505. 519. 450. 450. 246. 450. 246. 450 0
Al(100) Water
249.
Af(ll0) Hydrogen Oxygen
483. 483.
Al(111)
Nitrogen Oxygen
Al oxide formic acid
326. 243, 259, 481. 445, 494. 376.
Au(ll0) Formic
acid
273.
Au( 111) Formic acid Oxygen
392, 393.
Bi2Ru207
350.
CaRuO3
350.
CdTe( 130)
257.
CdTe( 111)
257.
Cr( 110) Carbon monoxide Oxygen
496. 496.
Cu(lO0) Carbon monoxide Hydrogen Suffur Water
325, 382, 394. 307, 417, 436. 283, 307. 436. 361.
Cu(ll0) Ammonia Formaldehyde
462. 339, 476, 419, 476, 476, 343, 340.
lsocyanic-
acid
Methanol Methyl formate ~~~~~~ K/0.1(110) Carbon monoxide
464.
Cu( 111) Acetylene Oxygen
371. 238.
Cu(fi~ms) Carbon monoxide Nitrogen Oxygen
NalCu( 100) Carbon monoxide
343. 501. 420. 501. 501. 476, 501.
358. 246. 246. 347,
CuNi (110) Oxygen
Di amond( 111)
463.
291.
Fe( 110) Acetylene Ammonia D~azo~thane Ethylene Heptane
Kekene Methanol
240. 268, 316. 439. 240. 439. 439. 345.
Fef 111) Acetylene Carbon monoxide Ethylene Nitrogen Oxygen
431. 370. 431. 503. 503.
K/Fe( 111) Carbon monoxide Nitrogen
522. 503.
276 GaAs(lOO) Hydrogen
373.
Ag/GaAs(lOO)
367, 378.
GaAs(ll0) Formic acid
292, 294. 292.
wk(lil),(iii)
509. 509.
Hydrogen
257.
GaP(111) Oxygen
257, 257.
Ge(ll1)
368.
InP(100) Oxygen
257. 257.
292, 294, 379, 469, 511. 511. InSb(ll1) ,(iii) Hydrogen
469. 469. 396. 261.
MgO(001)
383.
Mo(100) Formic acid Methanol Oxygen
313. 264, 314. 313, 314. 338, 391. 338.
NaxW03
349.
Ni(lOO) Acetylene Carbon monoxide Ethylene Hydrogen Hydrogen sulfide Methane Nitrogen oxide Oxygen Pyridine Sulfur
286, 308, 301, 493. 301, 441. 514. 358. 330, 358, 357,
Ni(ll0) Acetylene Ammonia Carbon monoxide Ethylene Formic acid Hydrogen
409, 371, 266. 285, 276, 285, 270,
287, 366, 382, 394, 404, 461, 468, 485, 524. 317, 493. 331, 358, 405, 436. 331, 441.
334, 357, 401, 404, 408, 436, 449, 468, 497, 514. 375, 411. 405, 441, 459. 462. 440. 289, 482, 488. 440, 289, 495. 364, 451, 458, 491, 498.
277
Ni(ll0) (continued) Methanol Oxygen Water
430, 454, 482, 489, 495, 502, 521. 297, 495, 502. 508.
C/Ni(llO) Ethylene
276.
Ni(ll1) Ammonia Carbon monoxide Hydrazine Hydrogen Nickel Carbonyl Oxygen
266. 311, 331, 492. 518. 331. 311. 497.
NiO(001)
466, 467.
NiO(ll1)
467.
Nisi
(loo),
(111)
Casbon Methanol Oxygen
306. 306. 306. 306.
Pb2Ru207
350.
Pd(lOO) Acetylene Benzene Carbon monoxide Ethylene Hydrogen Oxygen Water
279, 413, 327, 279, 244, 244, 361,
Pd(ll0) Acetylene Hydrogen
371. 513.
Pd( 111) Acetylene Benzene Ethylene Methanol Oxygen
275, 369, 377. 473, 515; 239. 275. 344: 344.
Polypyrrole
470.
348, 473, 421. 446, 260, 260, 372,
369, 377. 515. 465, 474, 520. 296, 319, 372, 446. 296, 372, 421, 422, 446, 465, 520. 422.
Pt(ll0) Benzene Carbon monoxide Formic acid Hydrogen Isocyanic acid Phenol Pyridine
419, 420. 339. 339, 475.
Pt(ll1) Acetone Acetonitrile
271. 263, 290, 332. 323, 480.
299, 339, 475. 235, 315, 412. 337, 339.
299;
278 Pt~~~~~n~continued) Carbon monoxide Cyclopentene Dimethyl sulfoxide Dinitrogen oxide Formic acid Hexafluoroacetone Isocyanic acid Methyl isocyanide Oxygen Sulfuric acid Thiophene Water
523. 254, 284, 457, 480, 523. 362, 427. 280. 333. 282. 443. 420. 407. 251, 271, 282, 284, 310, 457, 47 1. 359. 437. 471.
Pt(6(111)x(1000)) Acetaldehyde Oxygen
455. 455.
Pt(films) Carbon monoxide Nitrogen
435. 300, 435.
K,'Pt(lll) Carbon monoxide
242.
Pt(321) Carbon monoxide Oxygen
302, 355. 262, 281.
Benzene Carbon monoxide Ethylene
295. 356. 295.
Pt10Ni90(111) Carbon monoxide
356.
Re(OOO1) Acetylene Carbon monoxide
360. 321.
Rh(100) Carbon Oxygen Sulfur
250. 250. 250.
Rh(ll1) Benzene Carbon monoxide Ethylene Hydrogen Methyl isocyanide Oxygen
272, 320, 423. 423. 305, 236,
K/Rh(lll) Carbon monoxide
374, 428.
342, 388, 523. 523.
320. 320.
279
Ru(001) Acetone Acetylene Carbon monoxide Cyclohexane Cyclopentane Cyclopropane Diazomethane Dinitrogen oxide Ethylene Formic acid Hydrogen Methanol Nitrogen Nitrogen oxide Oxygen Water
263, 332. 293; 500.
329. 274. 328. 293. 303. 429. 245, 346; 304, 258. 267, 267, 389.
277. 429, 442. 415. 414, 424. 351, 414, 429.
K/Ru(OOl) Carbon monoxide Water
380, 387, 398, 403, 456, 500. 397.
Si(lO0) Hydrogen Oxygen Water
402, 335, 247, 399,
448. 384, 386, 399, 432, 448. 384, 399, 504. 406.
Si(ll0) Hydrogen
432.
Si(ll1) Benzene Carbon monoxide Hydrogen Methanol Nitrogen oxide Oxygen Pyridine Water
252, 410. 358. 288, 418, 363, 247, 516. 399,
292, 294, 309, 336, 354, 434, 438, 447, 448, 460, 4 '2.
Ag/Si( 111)
352.
Al/Si( 111)
487, 517.
Au/Si(lll)
400, 434, 452, 453, 477.
Ge/Si(lll)
487.
In/Si (111)
517.
Pd/Si( 111)
400, 434, 452, 453, 477, 478.
324, 399, 400, 432, 433, 448, 452, 477, 506. 479. 506. 399, 433, 486, 507, 512. 447, 484, 506.
SiC( 100) SiO,(OOOl)
510.
Si02
510.
Sn02( 110)
341.
Sn02(films)
248, 253.
280 SrRuO3
350.
SrTi03(100)
241, 265, 466.
Water
241, 265, 466.
T&(100)
426.
Ti(OOO1) Oxygen
481.
TiC(111) Hydrogen
353.
Ti02(110)
381, 416.
Hydrogen
416.
Ni/TiO2 Carbon monoxide Hydrogen Oxygen
425. 425. 425,
W(lO0) Carbon monoxide Hydrogen
499. 269, 298, 339, 390, 490, 525.
Y(110) Hydrogen Oxygen
278. 385.
wO3
391.
Y2Ru207
350.
ZnO
292, 294, 365.
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VIBRATIONS
MEASURED
AT SURFACES
: UPDATED
SPECTROSCOPY
REVIEW
BY HIGH RESOLUTION
ELECTRON
2’73
ENERGY LOSS
(1982-1985)*
P.A. Thiry Laboratoire Institute Facultes
de Spectroscopic
Electronique
for Research
in Interface
Universitaires
Notre-Dame
Sciences de la Paix, B-5000 Namur
(Belgium).
ABSTRACT A tabular review of HREELS measurements for the period 1982 to September 1985 is presented. It contains 291 references and a table of the systems (substrate-adsorbate) investigated.
INTRODUCTION This tabular
review
updates
of the third Conference Only new references ring continues
are presented
one published
at Surfaces
here in chronological
the substrates
new experimental
and the various
1982) (ref.1).
order and their numbe-
and theoretical
data. Table
adsorbates
in the Proceedings
(Asilomar,
the one of ref. 1. Review articles
included when they provide order,
the previous
on Vibrations
papers are
I lists in alphabetical
investigated,
respectively.
Fig. 1. Histogram showing the number of experimental HREELS papers published annually during the period 1967 to 1984. (see ref.1 for 1967 to 1982).
67
70
75
80
84
year REFERENCE 1 P.A. Thiry, J. Electron
Spectrosc.,
30 (1983) 261-,273.
*This work is supported by the Belgian Fund for Joint Basic Research Belgian Ministry for Science Policy (IRIS project).
0368s2048/86/$03.50
0 1986 Elsevier Science Publishers
B.V.
and by the
274 TABLE
1
Ag(llO)
Acetylene Carbon dioxide Carbon monoxide Ethylene Ethylene oxide Formaldehvde Formic a&d Oxygen
Ag(lll) Benzene Cyc7ohexane Hydrogen Oxygen Pyridine
Ag(311)
Ammonia Methyl isocyanide
Ag(films) Behenic acid Linolenic acid Nitrosen Oleic-acid
Oxygen
Stearic
acid
255. 318. 318. 318. 318. 237, 395. 285, 395. 237, 255, 285, 318, 395. 256. 256. 256. 256, 322. 256. 505. 519. 450. 450. 246. 450. 246. 450 0
Al(100) Water
249.
Af(ll0) Hydrogen Oxygen
483. 483.
Al(111)
Nitrogen Oxygen
Al oxide formic acid
326. 243, 259, 481. 445, 494. 376.
Au(ll0) Formic
acid
273.
Au( 111) Formic acid Oxygen
392, 393.
Bi2Ru207
350.
CaRuO3
350.
CdTe( 130)
257.
CdTe( 111)
257.
Cr( 110) Carbon monoxide Oxygen
496. 496.
Cu(lO0) Carbon monoxide Hydrogen Suffur Water
325, 382, 394. 307, 417, 436. 283, 307. 436. 361.
Cu(ll0) Ammonia Formaldehyde
462. 339, 476, 419, 476, 476, 343, 340.
lsocyanic-
acid
Methanol Methyl formate ~~~~~~ K/0.1(110) Carbon monoxide
464.
Cu( 111) Acetylene Oxygen
371. 238.
Cu(fi~ms) Carbon monoxide Nitrogen Oxygen
NalCu( 100) Carbon monoxide
343. 501. 420. 501. 501. 476, 501.
358. 246. 246. 347,
CuNi (110) Oxygen
Di amond( 111)
463.
291.
Fe( 110) Acetylene Ammonia D~azo~thane Ethylene Heptane
Kekene Methanol
240. 268, 316. 439. 240. 439. 439. 345.
Fef 111) Acetylene Carbon monoxide Ethylene Nitrogen Oxygen
431. 370. 431. 503. 503.
K/Fe( 111) Carbon monoxide Nitrogen
522. 503.
276 GaAs(lOO) Hydrogen
373.
Ag/GaAs(lOO)
367, 378.
GaAs(ll0) Formic acid
292, 294. 292.
wk(lil),(iii)
509. 509.
Hydrogen
257.
GaP(111) Oxygen
257, 257.
Ge(ll1)
368.
InP(100) Oxygen
257. 257.
292, 294, 379, 469, 511. 511. InSb(ll1) ,(iii) Hydrogen
469. 469. 396. 261.
MgO(001)
383.
Mo(100) Formic acid Methanol Oxygen
313. 264, 314. 313, 314. 338, 391. 338.
NaxW03
349.
Ni(lOO) Acetylene Carbon monoxide Ethylene Hydrogen Hydrogen sulfide Methane Nitrogen oxide Oxygen Pyridine Sulfur
286, 308, 301, 493. 301, 441. 514. 358. 330, 358, 357,
Ni(ll0) Acetylene Ammonia Carbon monoxide Ethylene Formic acid Hydrogen
409, 371, 266. 285, 276, 285, 270,
287, 366, 382, 394, 404, 461, 468, 485, 524. 317, 493. 331, 358, 405, 436. 331, 441.
334, 357, 401, 404, 408, 436, 449, 468, 497, 514. 375, 411. 405, 441, 459. 462. 440. 289, 482, 488. 440, 289, 495. 364, 451, 458, 491, 498.
277
Ni(ll0) (continued) Methanol Oxygen Water
430, 454, 482, 489, 495, 502, 521. 297, 495, 502. 508.
C/Ni(llO) Ethylene
276.
Ni(ll1) Ammonia Carbon monoxide Hydrazine Hydrogen Nickel Carbonyl Oxygen
266. 311, 331, 492. 518. 331. 311. 497.
NiO(001)
466, 467.
NiO(ll1)
467.
Nisi
(loo),
(111)
Casbon Methanol Oxygen
306. 306. 306. 306.
Pb2Ru207
350.
Pd(lOO) Acetylene Benzene Carbon monoxide Ethylene Hydrogen Oxygen Water
279, 413, 327, 279, 244, 244, 361,
Pd(ll0) Acetylene Hydrogen
371. 513.
Pd( 111) Acetylene Benzene Ethylene Methanol Oxygen
275, 369, 377. 473, 515; 239. 275. 344: 344.
Polypyrrole
470.
348, 473, 421. 446, 260, 260, 372,
369, 377. 515. 465, 474, 520. 296, 319, 372, 446. 296, 372, 421, 422, 446, 465, 520. 422.
Pt(ll0) Benzene Carbon monoxide Formic acid Hydrogen Isocyanic acid Phenol Pyridine
419, 420. 339. 339, 475.
Pt(ll1) Acetone Acetonitrile
271. 263, 290, 332. 323, 480.
299, 339, 475. 235, 315, 412. 337, 339.
299;
278 Pt~~~~~n~continued) Carbon monoxide Cyclopentene Dimethyl sulfoxide Dinitrogen oxide Formic acid Hexafluoroacetone Isocyanic acid Methyl isocyanide Oxygen Sulfuric acid Thiophene Water
523. 254, 284, 457, 480, 523. 362, 427. 280. 333. 282. 443. 420. 407. 251, 271, 282, 284, 310, 457, 47 1. 359. 437. 471.
Pt(6(111)x(1000)) Acetaldehyde Oxygen
455. 455.
Pt(films) Carbon monoxide Nitrogen
435. 300, 435.
K,'Pt(lll) Carbon monoxide
242.
Pt(321) Carbon monoxide Oxygen
302, 355. 262, 281.
Benzene Carbon monoxide Ethylene
295. 356. 295.
Pt10Ni90(111) Carbon monoxide
356.
Re(OOO1) Acetylene Carbon monoxide
360. 321.
Rh(100) Carbon Oxygen Sulfur
250. 250. 250.
Rh(ll1) Benzene Carbon monoxide Ethylene Hydrogen Methyl isocyanide Oxygen
272, 320, 423. 423. 305, 236,
K/Rh(lll) Carbon monoxide
374, 428.
342, 388, 523. 523.
320. 320.
279
Ru(001) Acetone Acetylene Carbon monoxide Cyclohexane Cyclopentane Cyclopropane Diazomethane Dinitrogen oxide Ethylene Formic acid Hydrogen Methanol Nitrogen Nitrogen oxide Oxygen Water
263, 332. 293; 500.
329. 274. 328. 293. 303. 429. 245, 346; 304, 258. 267, 267, 389.
277. 429, 442. 415. 414, 424. 351, 414, 429.
K/Ru(OOl) Carbon monoxide Water
380, 387, 398, 403, 456, 500. 397.
Si(lO0) Hydrogen Oxygen Water
402, 335, 247, 399,
448. 384, 386, 399, 432, 448. 384, 399, 504. 406.
Si(ll0) Hydrogen
432.
Si(ll1) Benzene Carbon monoxide Hydrogen Methanol Nitrogen oxide Oxygen Pyridine Water
252, 410. 358. 288, 418, 363, 247, 516. 399,
292, 294, 309, 336, 354, 434, 438, 447, 448, 460, 4 '2.
Ag/Si( 111)
352.
Al/Si( 111)
487, 517.
Au/Si(lll)
400, 434, 452, 453, 477.
Ge/Si(lll)
487.
In/Si (111)
517.
Pd/Si( 111)
400, 434, 452, 453, 477, 478.
324, 399, 400, 432, 433, 448, 452, 477, 506. 479. 506. 399, 433, 486, 507, 512. 447, 484, 506.
SiC( 100) SiO,(OOOl)
510.
Si02
510.
Sn02( 110)
341.
Sn02(films)
248, 253.
280 SrRuO3
350.
SrTi03(100)
241, 265, 466.
Water
241, 265, 466.
T&(100)
426.
Ti(OOO1) Oxygen
481.
TiC(111) Hydrogen
353.
Ti02(110)
381, 416.
Hydrogen
416.
Ni/TiO2 Carbon monoxide Hydrogen Oxygen
425. 425. 425,
W(lO0) Carbon monoxide Hydrogen
499. 269, 298, 339, 390, 490, 525.
Y(110) Hydrogen Oxygen
278. 385.
wO3
391.
Y2Ru207
350.
ZnO
292, 294, 365.
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