- Email: [email protected]
Zeolite-containing anode for sealed lead-acid batteries
Patent
Report
Maltose is separated from glucose and other polysaccharides by adsorption on dealuminated Y zeolites (6-9 Al atoms/unit cell) and desorption with HzO. A Y zeolite with 15 Al atoms/unit cell separated disaccharides from higher saccharides, but did not separate maltose from glucose.
compositions
in transparent
T. Watanabe; K. Mukoyama; K. Umehara Lion Corp. Jpn Kokkai Tokkyo Koho 87212,500, Sept. 1986
18, 1987;
contain-
Appl.
Mar.
12,
High-density powder detergent compositions showing good u.v.induced discoloration resistance were prepared by coating powdered mixtures of anionic and nonionic surfactants and fluorescent brighteners with zeolite A powder (average particle diameter < 10 microns) and placed in a transparent plastic container with 350 nm light transmittance < 1%. The detergent showed no discoloration even after one month in outdoor storage test.
Granular
non-phosphate
detergent
J.G. De Bernat; I.D. Robb; R.J. Wilde Unilever N. V.: Unilever P/c Eur. Pat. Appl. 241,962, Oct. 21, 1987;
bleach
J.G. De Bernat; I.D. Robb; R.J. Wilde Unilever N. V.: Unilever Plc. Eur. Pat. Appl. 240,057, Oct. 7, 1987;
U.K. Appl.
Mar.
25, 1986
bleach
activator
detergent
U.K. Appl.
Mar.
25, 1986
powders
J.H. Eertink; A. Maiguzzi; SD. Liem et a/. Unilever P/c; Unilever N. V. Eur. Pat. Appl. 240,356, Oct. 7, 1987; U.K. Appl.
Apr.
4, 1986
An aqueous slurry containing a zeolite, a polymeric powder structurant and other detergent components is spray dried and mixed with particulate Na silicate to give a laundry detergent powder that contains little or no P and has a satisfactory structure, i.e., the particles are resistant to crushing in handling of the powder.
detergents
M. Kuroda; F. Sai; M. Murata Kao Corp. Jpn Kokai Tokkyo Koho 87,240,397,
Oct. 21,1987;
Appl. Apr. 11,1986
Detergents contain (a) 3-30% C,+,s straightor branched-chain alkylbenzene sulphonic acid Na salts, (b) l-30% Na alkyl sulphates having mol wt. 290-335 and even-number alkyl groups (C,z I 50%. Crs + C,s I 50%), and (c) 5-30% crystalline aluminosilicates NazO.AlzOs.nSiOz.wHzO (n = 1.8-3.0, w = 0, integers), at (a)-(b) ratio l-10:1-2.
ZEOLITES,
1988, Vol8,
Preparation gents N. Tokina; Lion Corp. Jpn Kokai 1986
of zeolite
et al. Appl.
H. Iwabuchi; Tokkyo
particles
June
13, 1986
November
and their
use in deter-
M. Nakamura
Koho
87,275,016,
Nov.
30, 1987;
Appl.
Jan. 23,
Zeolite particles, which are mixed with surfactant to form a detergent composition, are prepared by reacting a mixed solution of Na silicate and Na aluminate with mol ratios Sioz/AlzOz = 1.5-2.5, NazO/SiOz = 2-10, and HzO/NazO = 8-30.
MISCELLANEOUS
APPLICATIONS anode
for sealed
T. Inoue; K. Kobayashi; K. Matsuo Matsushiti Electric Industrial Co. Ltd. Jpn Kokai Tokkyo Koho 87,193,060, Aug. 1986
lead-acid
24, 1987;
batteries
Appl.
Feb. 18,
Spongy Pb anodes of sealed Pb-acid batteries contain 2-10 wt.% crystalline zeolite. The addition of zeolite enhances the absorption of 0 and supresses the evolution of H. When cycled at I-A charging for 60 minutes and 0.8-A discharging to 10.8-V cutoff, batteries [I2 V, 10-h rate capacity 1 .O A-h) using anodes of the invention had longer cycle lives than batteries using anodes without zeolite.
Biaxially
stretched
polyester
films
K. Yasumura; S. Otonari Diafoil Co. Ltd. Jpn Kokai Tokkyo Koho 87,223,239,
Granular compositions are prepared that contain finely divided bleach activator, an inert, non-alkaline, P-free, water-soluble salt, a water-soluble film-forming polymer, and a smectite or aluminosilicate clay material. The granules are useful in the preparation of detergent bleach compositions that have good storage stability and provide good bleaching activity during laundering. The granules were added (3%) to a P-free laundry detergent containing 30% zeolite and 4% N(CHzCOzNa)s as builders and 5.5% Na perborate monohydrate.
530
Diekoetta
Dec. 17, 1987;
Zeolite-containing
Granular non-phosphorus-containing compositions
Laundering
F.W.D.
compositions
Detergent bleach compositions are prepared that contain a detergent-active material, a carbonate builder, seed crystals for CaCOs (e.g. calcite) and peroxggen bleaching agent as well as granules comprising a bleach activator 5(r-90, an inert nonphosphate salt 5-45, and a film-forming polymer containing few or no carboxy groups l-15 wt.%. The granules do not affect the ability of the seed crystals to decrease water hardness. Crystalline zeolite builders can be used instead of the carbonate builder-seed crystal system.
Phosphate-free
detergents
J. Jacobs; H. Kruse; Henkel K.-G.a.A Ger. Offen. 3,620,009,
Water-free, finely divided sodium metasilicate is treated with a flowable aqueous suspension of a crystalline zeolite NaA in a mixer and dried or mixed with a dry crystalline zeolite to prepare granules which are especially useful in detergents for machine dishwashing.
DETERGENTS Powder.detergent ers
Dishwashing
Oct. 1,1987;
Appt.
Mar.
25, 1986
Films, useful in preparing magnetic tapes with good running durability, are prepared by biaxially stretching polyester [having mainly ethylene-terephthalate units] films containing silane-treated crystalline zeolite.
Body deodorant
powder
containing
zeolites
Y. Nakahara; Y. Shimai; T. Yoshikawa Agency of Industrial Sciences and Technology; Pias Co. Ltd. Jpn Kokai Tokkyo Koho 87,212,316, Sept. 18, 1987; Appl. Mar. 1986
13,
A powder deodorant contains microcapsules [av. diameter l-10 microns] prepared by encapsulating crystalline zeolite particles [e.g., Cu-exchanged A-type zeolite] with an inorganic compound selected from silica, Mg silicate, Ca silicate and Ca carbonate.
Adhesive
tapes for topical
application
T. Matsumiya; A. Hata Sekisui Chemical Co. Ltd. Jpn Kokai Tokkyo Kbho 87,153,215, The support chloride-ethylene tate copolymer type A-zeolite.
Antiblocking B.W. Sands PQ Corp. U.S. 4,704,424,
July 8,1987;
layer
for a topical adhesive copolymer, ethylene-carbon and HzO-containing crystalline
polyethylene
Nov.
3, 1987;
Appl.
Dec. 26,1985
tape contains monoxide-vinyl aluminosilicates,
vinyl acee.g.,
films and sheets
Appl.
May
21, 1986
Films and sheets with good processibility and antiblocking property are prepared from low-density polyethylene and a powdered
Report
Maltose is separated from glucose and other polysaccharides by adsorption on dealuminated Y zeolites (6-9 Al atoms/unit cell) and desorption with HzO. A Y zeolite with 15 Al atoms/unit cell separated disaccharides from higher saccharides, but did not separate maltose from glucose.
compositions
in transparent
T. Watanabe; K. Mukoyama; K. Umehara Lion Corp. Jpn Kokkai Tokkyo Koho 87212,500, Sept. 1986
18, 1987;
contain-
Appl.
Mar.
12,
High-density powder detergent compositions showing good u.v.induced discoloration resistance were prepared by coating powdered mixtures of anionic and nonionic surfactants and fluorescent brighteners with zeolite A powder (average particle diameter < 10 microns) and placed in a transparent plastic container with 350 nm light transmittance < 1%. The detergent showed no discoloration even after one month in outdoor storage test.
Granular
non-phosphate
detergent
J.G. De Bernat; I.D. Robb; R.J. Wilde Unilever N. V.: Unilever P/c Eur. Pat. Appl. 241,962, Oct. 21, 1987;
bleach
J.G. De Bernat; I.D. Robb; R.J. Wilde Unilever N. V.: Unilever Plc. Eur. Pat. Appl. 240,057, Oct. 7, 1987;
U.K. Appl.
Mar.
25, 1986
bleach
activator
detergent
U.K. Appl.
Mar.
25, 1986
powders
J.H. Eertink; A. Maiguzzi; SD. Liem et a/. Unilever P/c; Unilever N. V. Eur. Pat. Appl. 240,356, Oct. 7, 1987; U.K. Appl.
Apr.
4, 1986
An aqueous slurry containing a zeolite, a polymeric powder structurant and other detergent components is spray dried and mixed with particulate Na silicate to give a laundry detergent powder that contains little or no P and has a satisfactory structure, i.e., the particles are resistant to crushing in handling of the powder.
detergents
M. Kuroda; F. Sai; M. Murata Kao Corp. Jpn Kokai Tokkyo Koho 87,240,397,
Oct. 21,1987;
Appl. Apr. 11,1986
Detergents contain (a) 3-30% C,+,s straightor branched-chain alkylbenzene sulphonic acid Na salts, (b) l-30% Na alkyl sulphates having mol wt. 290-335 and even-number alkyl groups (C,z I 50%. Crs + C,s I 50%), and (c) 5-30% crystalline aluminosilicates NazO.AlzOs.nSiOz.wHzO (n = 1.8-3.0, w = 0, integers), at (a)-(b) ratio l-10:1-2.
ZEOLITES,
1988, Vol8,
Preparation gents N. Tokina; Lion Corp. Jpn Kokai 1986
of zeolite
et al. Appl.
H. Iwabuchi; Tokkyo
particles
June
13, 1986
November
and their
use in deter-
M. Nakamura
Koho
87,275,016,
Nov.
30, 1987;
Appl.
Jan. 23,
Zeolite particles, which are mixed with surfactant to form a detergent composition, are prepared by reacting a mixed solution of Na silicate and Na aluminate with mol ratios Sioz/AlzOz = 1.5-2.5, NazO/SiOz = 2-10, and HzO/NazO = 8-30.
MISCELLANEOUS
APPLICATIONS anode
for sealed
T. Inoue; K. Kobayashi; K. Matsuo Matsushiti Electric Industrial Co. Ltd. Jpn Kokai Tokkyo Koho 87,193,060, Aug. 1986
lead-acid
24, 1987;
batteries
Appl.
Feb. 18,
Spongy Pb anodes of sealed Pb-acid batteries contain 2-10 wt.% crystalline zeolite. The addition of zeolite enhances the absorption of 0 and supresses the evolution of H. When cycled at I-A charging for 60 minutes and 0.8-A discharging to 10.8-V cutoff, batteries [I2 V, 10-h rate capacity 1 .O A-h) using anodes of the invention had longer cycle lives than batteries using anodes without zeolite.
Biaxially
stretched
polyester
films
K. Yasumura; S. Otonari Diafoil Co. Ltd. Jpn Kokai Tokkyo Koho 87,223,239,
Granular compositions are prepared that contain finely divided bleach activator, an inert, non-alkaline, P-free, water-soluble salt, a water-soluble film-forming polymer, and a smectite or aluminosilicate clay material. The granules are useful in the preparation of detergent bleach compositions that have good storage stability and provide good bleaching activity during laundering. The granules were added (3%) to a P-free laundry detergent containing 30% zeolite and 4% N(CHzCOzNa)s as builders and 5.5% Na perborate monohydrate.
530
Diekoetta
Dec. 17, 1987;
Zeolite-containing
Granular non-phosphorus-containing compositions
Laundering
F.W.D.
compositions
Detergent bleach compositions are prepared that contain a detergent-active material, a carbonate builder, seed crystals for CaCOs (e.g. calcite) and peroxggen bleaching agent as well as granules comprising a bleach activator 5(r-90, an inert nonphosphate salt 5-45, and a film-forming polymer containing few or no carboxy groups l-15 wt.%. The granules do not affect the ability of the seed crystals to decrease water hardness. Crystalline zeolite builders can be used instead of the carbonate builder-seed crystal system.
Phosphate-free
detergents
J. Jacobs; H. Kruse; Henkel K.-G.a.A Ger. Offen. 3,620,009,
Water-free, finely divided sodium metasilicate is treated with a flowable aqueous suspension of a crystalline zeolite NaA in a mixer and dried or mixed with a dry crystalline zeolite to prepare granules which are especially useful in detergents for machine dishwashing.
DETERGENTS Powder.detergent ers
Dishwashing
Oct. 1,1987;
Appt.
Mar.
25, 1986
Films, useful in preparing magnetic tapes with good running durability, are prepared by biaxially stretching polyester [having mainly ethylene-terephthalate units] films containing silane-treated crystalline zeolite.
Body deodorant
powder
containing
zeolites
Y. Nakahara; Y. Shimai; T. Yoshikawa Agency of Industrial Sciences and Technology; Pias Co. Ltd. Jpn Kokai Tokkyo Koho 87,212,316, Sept. 18, 1987; Appl. Mar. 1986
13,
A powder deodorant contains microcapsules [av. diameter l-10 microns] prepared by encapsulating crystalline zeolite particles [e.g., Cu-exchanged A-type zeolite] with an inorganic compound selected from silica, Mg silicate, Ca silicate and Ca carbonate.
Adhesive
tapes for topical
application
T. Matsumiya; A. Hata Sekisui Chemical Co. Ltd. Jpn Kokai Tokkyo Kbho 87,153,215, The support chloride-ethylene tate copolymer type A-zeolite.
Antiblocking B.W. Sands PQ Corp. U.S. 4,704,424,
July 8,1987;
layer
for a topical adhesive copolymer, ethylene-carbon and HzO-containing crystalline
polyethylene
Nov.
3, 1987;
Appl.
Dec. 26,1985
tape contains monoxide-vinyl aluminosilicates,
vinyl acee.g.,
films and sheets
Appl.
May
21, 1986
Films and sheets with good processibility and antiblocking property are prepared from low-density polyethylene and a powdered