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Cumulative subject index volumes 41–45
JOURNAL
OF SOLID
STATE
CHEMISTRY
45, 415-429 (1982)
Cumulative Subject Index’ Volumes 41-45 A
B
Alkaline earth fluorides MF,(M = Ca, Sr, Ba), analogs of rose center production by hydrolysis, Raman spectroscopy, 43, 181 Alumina AgI-A&OS, enhanced ionic conduction, 42, 107 CuO-ZnO-AlzO,, reduction processes in low-temperature methanol synthesis, 42, 120 B-Alumina doped with cerium, properties, 42, 170 Aluminum LaCor hydriding properties, modification by, 43,295 LizCr~-,AI\rrSbOs, hexagonal-spine1 transitions, 44, 282 M-Al-C (M = Ti, Zr, Hf, V, Nb, Ta, Cr, Mn, Ni), structural chemistry, 44, 126 NiA1204-Ni$iO, at high pressures and temperatures, 44, 257 Ammonia Co(NH,),CI,, structure, 43, 334 effect on thermal depolarization in ammonium chloride crystals, 44, 399 Ammonium chloride thermal depolarization, 44, 388 effect of HCl and NH,, 44, 399 Anions coordination and cation packing in oxides, 44, 24 Antimonates LiZCrj-J4,t1rSbOs (M”’ = Al, Fe, Ga), hexagonalspine1 transitions, 44, 282 Antimony CsJ#‘Xg (M”’ = Sb or Bi, X = Cl or Br), doping, 41, 143 MSbF2S04 (M = Rb, Cs), synthesis and structure, 43,81 SbrSe,, deposition of thin films, chemical methods, 44,425 tin-antimony-oxygen system, high-resolution electron microscopy, 44, 326 Apatites phosphate (Alo-&Q4,(P0,),Yr,, where A = Sr, Pb; Y = F, Cl; X = 1, 2), magnetic effect studies, 4391 rare-earth-substituted chloro-phosphate, preparation and X-ray diffraction, 41, 44 silicate (Sr2Ln8(Si0.J602, where Ln = Nd and Gd), magnetic effect studies, 43, 1
Barium A,BaCu05 (A = Y, Sm, Eu, Gd, Dy, Ho, Er, Yb), isolation, characterization, 43, 73 BaFe,~,Ru,O~~,, structure, 44, 366 BaO-Ge02, high-pressure transformations into BaGeOr, BaGerOS, and BarGeSOn, 44, 307 4HBaCrO,, crystal structure, 43, 309 Bal+xFeS4 Mossbauer spectra, magnetic and electrical behavior, 41, 124 phase relationship, 41, 114 Ba2Fe4S5, crystal structure, two-dimensional array of Fe& tetrahedra, 41, 104 Ba2Zn3Pk,0,,,, crystal structure, 45, 159 B&Or-BaO rhombohedral phase, electron microscope study, 41, 233 -doped Ni-Zn-Co fenites, transmission electron microscopy, 44, 208 Lnl-tiBa2+2xZnZ-x010-2r (Ln = La, Nd), preparation and characterization, 42, 176 Barium oxide Bi203-BaO rhombohedral phase, electron microscope study, 41, 233 Bismuth Biz-xLa,W06, structure, 41, 138 B&O,-BaO rhombohedral phase, electron microscope study, 41, 233 Bi2W06, polymorphrsm, 41, 160 BiSTiZW0r4F, synthesis and X-ray diffraction, 44, 169 Bi,TiSOrOF, synthesis and X-ray diffraction, 44, 169 Cs,-,KI+,BiCl,, solid solution, phase transition, 42, 130 Cs$frr”X9 (Mu’ = Sb or Bi, X = Cl or Br), doping, 41, 143 PbBirTiNbOsF, synthesis and X-ray diffraction, 44, 169 PbB&TiTaOsF, synthesis and X-ray diffraction, 44, 169 Tl-Bi-Te, phase transformation, electrical resistivity and thermoelectric measurements, 45, 99 Bismuth oxide Bi203-BaO rhombohedral phase, electron microscope study, 41, 233 solid-state reaction with molybdenum oxide, kinetics and mechanism, 42, 136
r Boldface numbers indicate the appropriate volume; lightface numbers indicate pagination. 415 Copyright 0 1982 by All rights of reproduction
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CUMULATIVE
416
SUBJECT INDEX
Bismuth tungstates rare-earth activated, luminescence, 42, 158 Bonding metal-metal, and A-chain integrity in superconducting A,B(B-tungsten) alloy, 45, 353 normal structural, and defects in covalent amorphous solids, 45,40 Boron B-rhombohedral, high-resolution electron microscope analysis of { lOO} twinning, 44, 374 Bromide MnB-FeB, phase diagram FeB, low-temperature modification and crystal structure, 41, 195 Bromine CrB-MnB, phase diagram, 41, 195 SrBr2-SrC&, phase relationships, 43, 271 C
Cadmium CaFz (Cl) and CdCl*, relationship, 45, 223 CdHo&, transition from spinel-type structure to rock&-type structure, electron microscopy/ diffraction, 42, 11 CdNbF6, crystallochemistry and spectroscopy, 43, 327 Cadmium selenide single crystals, high-temperature conductivity relaxation, 43, 320 Cadmium sulfide undoped CdS, high-temperature conductivity relaxation, 43, 320 Cadmium sulfoselenide electrodes photoluminescence in graded cadmium sulfoselenide electrodes, applications to photoelectrochemical cells, 45, 51 Calcium CaF2 (Cl) and CdC&, relationship, 45, 223 CaFezOd(FeO). (n = 1, 2, 3), relationship to CaTi204, 43, 222 CaLa,-,Y,Cr04 (0 IX 5 l), structural and magnetic study, 42, 75 CaMn02.5, new oxygen-defect perovskite-type oxide, 44, 89 CaMnO and CaMnOZ.J, structure determinations by x-ray and neutron methods, 45, 71 CaNbF6, crystallochemistry and spectroscopy, 43, 327 CaTiOx, electrical conductivity, 41, 185 Ca2Mn09.5, new oxygen-defect perovskite-type oxide, 44, 89 Ca14YSF43,crystal structure, 44, 75 (Lar-,Ca,)CoOs (0.1 5 x 5 0.5), electrical properties, 44, 254
Cadmium-strontium phosphate apatites infrared spectra, 43, 237 Calcium titanate with nonideal cationic ratio, defect structure, 43, 196 Carbon M-Al-C (M = Ti, Zr, Hf, V, Nb, Ta, Cr, Mn, Ni), structural chemistry, 44, 126 Cations packing and anion coordination, 44, 24 Cells photoelectrochemical, photoluminescence and electroluminescence in graded cadmium sulfoselenide electrodes, 45, 51 Cerium CeT(Mo0&(Mo207), crystal structure, 44, 156 -doped p-alumina, preparatiorr, properties, 42, 170 Cs2-,K,+,BiC16, solid solution, phase transitions, 42, 130 Cs&i”& (M1rr = Sb or Bi, X = Cl or Br), doping, 41, 143 CsNbdO,,, hydratation, 43, 346 CsSbF2S04, synthesis and structure, 43, 81 CsVF3, high-resolution electron microscopic study, 45, 259 Cesium ytterbium fluoride crystal structure, isotype composition, 42, 80 Chlorides CaF2 (C 1) and CdC12, relationship, 45, 223 Co(NH&CIS, structure, 43, 334 Cs2-xKl+xBiC16r solid solution, phase transitions, 42, 130 KMnC&, structure types and phase transformations, 43, 107 La~WO&&U, luminescence properties, 4.4, 162 SrBr2-SrQ, phase relationships, 43, 271 TlMnCl,, structure types and phase transformations, 43, 107 Chlorotungstates CepWO&, structure and luminescence, 44, 99 Eu9W06Cl,, structure and luminescence, 44, 99 GdSW06C19, structure and luminescence, 44, 99 LaSW06C19, structure and luminescence, 44, 99 NdSW06Clj, structure and luminescence, 44, 99 Pr~WO&, structure and luminescence, 44, 99 SmlW06ClJ, structure and luminescence, 44, 99 Chromium Cr-Al-C, structural chemistry, 44, 126 CrB-MnB, phase diagram, 41, 195 Cr,TiSez (0 < x < l), phase diagram and magnetic properties, 45, 411 CuCr,O, spine1 catalyst, electrical resistivity, 43, 261 Cu.&&,,&, structure and magnetic properties, 41, 174
CUMULATIVE doped V203 effect on crystal structure, 44, 192 TEM observation of high-temperature metal-insulator transition, 45, 241 KPbCr2F9, structural and magnetic properties, 41, 272 Li2CrJ+,M~“SbOs (Ml” = Al, Fe, Ga), hexagonalspine1 transitions, 44, 282 Chromium fluoride Cr$, quintet-triplet electronic transitions and nephelauxetic effects, SCF MO calculation, 42, 28 Chromium oxide 4H BaCrOr, crystal structure, 43, 309 CaLa]-,Y,Cr04 (0 5 x 5 1), structural and magnetic study, 42, 75 Yb203-Ga203-M0 and Yb203-Crz03-M0 (M: Co, Ni, Cu, and Zn), phase formation in air at high temperature, 43, 278 Cobalt CoNbF6, crystallochemistry and spectroscopy, 43, 327 Co(NHJ)&13, structure, 43, 334 ColVS,, structure and electronic properties, 44, 119 LaCoS hydriding properties, modification by partial substitutions (LaCoS&4, with M = Al, Ga), 43, 295 (La,+,Ca,)CoOr (0.1 5 x 5 0.5) electrical properties, 44, 254 (Nil-,Co,)rMnSn, ferromagnetic and paramagnetic properties, 43, 354 Ybz0&a203-Co0 and Yb203-CrzOr-Coo, phase formation in air at high temperature, 43, 278 Co ion relations between structure and physical properties in KrNiF&ype oxides, 44, 82 Cobalt oxide YbZ03-Fe203-COO, phase relations in air at high temperatures, 42, 22 Columns “pentagonal”, as building unit in crystal and defect structures of some groups of transition metal compounds, 44, 32 Conductivity and chain integrity in ArB(P-tungsten) alloy, relationship, 45, 353 Conductor mixed, phenomenological model for semiconductor-metal transition, 41, 333 Copper AzBaCuOS (A = Y, Sm, Eu, Gd, Dy, Ho, Er, Yb), isolation, characterization, 43, 73 Cu(2,2’-bipyridine) (Hz0)rS04, linear-chain transition metal complexes, low-dimensionality magnetic interactions, 44, 141
417
SUBJECT INDEX
CuCr204 spine1 catalyst, electrical resistivity, 43, 261 structure and magnetic properties, Cuo.50Cr0.50Ps3, 41, 174
CuInSez-ZnSe-InzSe3, structure study, 45, 200 CU~MO~O,~, reaction with Or, kinetics and mechanism, 44, 291 CuSTa1,030, structure, 41, 286 Copper ion Du and C,, distorted complexes, crystal field theory and EPR parameters, 44, 343 distribution in spine1 ferrites, Ni*+ ion effect, 41, 63 Copper oxide CuO-ZnO-A1203, reduction processes in low-temperature methanol synthesis, 42, 120 Yb203-FezOr-CuO, phase relations in air at high temperatures, 42, 22 Copper tantalum oxide Cu5Ta,,0so, structure, 41, 286 Crystal field theory and EPR parameters in Dzd and C,, distorted tetrahedral copper complexes, 44, 343 Crystallographic shear Nb205-W03 and Ta20S-W03 systems, 44, 60 Crystal structure A$CloOzo (A = Sr, Ba, Pb; B = Ti, Ge, Sn; and C = Al, Ga), luminescence, 41, 39 BarFe&, two-dimensional array of Fe& tetrahedra, 41, 104 CuAlOr, 41, 132 indium p-alumina, 43, 227 Li3,75S~.7SP0,2504rand ionic conductivity in tetrahedral structures, 44, 50 Ln3W06C13 (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd), luminescence, 44, 99 Cyclooctasulfur and nickel oxide, kinetics and mechanism of solidstate reaction, 45, 381 D
Decametaphosphate Ba2Zn3PloO~, crystal structure, 45, 159 Dehydration topotactic, KV03 . H20, mechanism, 41, 205 Delafossites CuAlOr, high temperature structural investigation, 41, 132
Dielectrical constant electron-electron interactions, 45, 63 Diffraction CdHo& transition from spinel-type structure to rocksalt-type structure, 42, 11 neutron, in HTiNbOr, 41, 57
418
CUMULATIVE
Dihydrogeno-sulfato-iodate K.+H2(SZ12014),crystal structure, 41, 262 2,CDinitrotoluene solid-state reaction with diphenylamine as n and n donor, 44, 186 Diphenylamine n and TI donor in solid-state reaction of 2,4-dinitrotoluene with diphenylamine, 44, 186 Disilicides transition metal, binding, 43, 97 Doping Cr, effect on V203 crystal structure, 44, 192 Ti, effect on V203 crystal structure, 44, 192 Dysprosium (DySbTe,+,, order-disorder phenomena, 45, 140, 146 E Electrical conductivity CaTiO,, 41, 185 La,,&q.,&nO~, structure, 42, 125 Electrical resistivity CuCr204 spine1 catalyst, 43, 261 (La,-,Ca,)CoOs (0.1 5 x 5 0.5), 44, 254 Electrical transitions FerO.,, 45, 1 v203,45, 1 v305,45, 1 Electroluminescence and photoluminescence in graded cadmium sulfoselenide electrodes, applications to photoelectrochemical cells, 45, 51 Electrolytes fast-ion, silver iodo-phosphate phase diagram and electrical characteristics, 42, 191 Electronic conductivity CaTiOs with nonideal cationic ratio, 43, 196 Electronic expansion factor tungsten bronzes, vegard relationships, 41, 227 Electronic transitions quintet-triplet, CrFh- and nephelauxetic effects, SCF MO calculation, 42, 28 Electron microscopy AxP.+Os(WO&,,, (A = K, Rb), structure, 43, 299 binary tungsten-oxygen system, phases in W09WOz, 41, 293 CdHo& transition from spinel-type structure to rocksalt-type structure, 42, 11 high resolution electron beam-induced reduction of higher oxides of rare earths, 42,47 VnOan-, microsyntactic growth, 43, 33 W18049 crystal formation by gaseous reduction of WO,, 45, 324
SUBJECT INDEX defects and disorder introduced by partial oxidation, 45, 334 Electrons states of solids by electron spectroscopy, 45, 14 Electron spectroscopy states of solids, 45, 14 Electron spin resonance Mo5+ in VYO4, substitutional off-center ion, 45, 93 Erbium Er3+ optical transition probabilities in fluoride glasses, 41, 253 (ErS)*Te,+,, order-disorder phenomena, 45, 140, 146 Ethylenediamine intercalation in 2H-Nb& crystal chemical and thermogravimetric study, 45, 119 lT-Ta&, crystal chemical and thermogravimetric study, 45, 119 TiSr, crystal chemical and thermogravimetric study, 45, 119 Europium lanthanum p-alumina phase doped with, optical investigation by dye laser site-selective excitation, 41, 27 Ln2Mo06: Eu’+ (Ln = La, Gd, Y), spectroscopic properties, 43, 87 Excitation site-selective, (La) B-alumina doped with Eu, optical investigation by dye laser, 41, 27 F Ferrites Ba-doped Ni-Zn-Co, transmission electron microscopy, 44,208 Ferromagnetic resonance polycrystalline magnesium nickel ferrites, 42, 206 Films thin, chemical methods for deposition of Sb,Sej, 44, 425 Fluoride glasses Er3+ optical transition probabilities, 41, 253 Fluorides Ag,IF.HrO crystal structure, A& grouping, 42, 1 BiJTi2W01.+F, synthesis and X-ray diffraction, 44, 169 Bi;TiTOrOF, synthesis and X-ray diffraction, 44, 169 CaF2 (C 1) and Cd& relationship, 45, 223 Ca14YSF43rcrystal structure, 44, 75 CsYblFlO, crystal structure, isotype composition, 42, 80 KPbCr,F,, structural and magnetic properties, 41, 272 K*NiF,-type oxides, relations between structures and physical properties, 44, 82
CUMULATIVE LiMnFeF6, dimorphism, cationic order in structural type NaZSiFB, 45, 127 MSbF2S04 (M = Rb, Cs), synthesis and structure, 43, 81 PbBi2TiNbOsF, synthesis and X-ray diffraction, 44, 169 PbBi;TiTa08F, synthesis and X-ray diffraction, 44, 169 a-UF5 crystallographic parameters by multiphase refmement of high-resolution neutron powder data, 45, 396 UP, crystallographic parameters by multiphase retinement of high-resolution neutron powder data, 45,396 Fluoroniobates MNbF6 (M = Mg, Ca, Mn, Fe, Co, Ni, Zn, Cd), crystallochemistry and spectroscopy, 43, 327 Fluorooxovanadates green CS2 [VOF,(HZO)], crystal structure and relation to blue CSr [VOF.,(H20)], 45, 154 Fly ash AgI-fly ash, enhanced ionic conduction, 42, 107 G Gadolinium GdzMo06 : Eu3+, spectroscopic properties, 43, 87 La,Gd,-,TiOj, magnetic behavior, 43, 204 Gallium Gaz09, Raman spectra and valence force field, 45, 180 GaSe,-,S,, polytype phase transition, 41, 97 B-Ga2Se3, crystal structure, 43, 339 LaCos hydriding properties, modification by, 43,295 LirCrr-,Gai”SbOr,, hexagonal-spine1 transitions, 44, 282 Li3Ga14, synthesis and X-ray crystal structure, 45, 290 Gallium oxide Yb203-GarO+fO and Yb203-Cr203-MO (M: Co, Ni, Cu, and Zn), phase formation in air at high temperature, 43, 278 Germanates Nd2Ge20r, structure determination, 45, 293 Germanium BaO-GeOr, high-pressure transformations into BaGeOl, BaGerOJ, and Ba2GeSOn, 44, 307 Ge-W-O system near W09, phase analysis, 43,251 Ge02-ZnO-FezOs, system at lOOO”C, 44,426 Li~+tiZni-,GeO~, ionic conductivity of LISICON solid solutions, 44, 354 solid solubility in Fe203 and photoelectric behavior, 41, 90
419
SUBJECT INDEX H
Hafnium Hf-Al-C, structural chemistry, 44, 126 HfOS, synthesis, 43, 225 Halides Cs&@!‘X9 (Mrii = Sb or Bi, X = Cl or Br), doping, 41, 143 High-resolution microscopy . nHzO (B = Al, Ga, C = Si, Ge), surM’LG-x02m prises in structural chemistry, 45, 368 structures of hexagonal vanadium fluoride bronzes, 45,259 tin-antimony-oxygen system, 44, 326 {lOO} twinning in B-rhombohedral boron, 44, 374 High-resolution neutron powder diffraction crystallographic parameters in u-UF5 and U2F, by multiphase refinement of, 45, 396 High-temperature conductivity relaxation CdSe single crystals, 43, 320 undoped CdS, 43,320 Hollandite relationship between CaFe*O, and rutile, 41, 23 Holmium CdHo& transition from spinel-type structure to rock&-type structure, electron microscopy/ diffraction, 42, 11 (HoS)2Tel+r, order-disorder phenomena, 45, 140, 146 Hydratation A4Nb40,, (A = K, Rb, Cs), 43, 346 Hydrates WOj . $H20, powder form, wide-band proton NMR study, 45, 193 Hydrides LaH,, anomalous site disorder, 43, 5 YH,, anomalous site disorder, 43, 5 Hydriding LaCos, modification by partial substitution (La Co5-&, where M = Al, Ga), 43, 295 Hydrochloric acid effect on thermal depolarization in ammonium chloride crystals, 44,399 Hydrogen localization in layer oxide HTiNbOs, 41, 57 Hydrosulfates Np(OH)$Od, synthesis and characterization, 45, 235 I Indium CuInSe*-ZnSe-InrSe,, structure study, 45, 200 Indium @hnnina single crystals, preparation and physical properties, 43.227
420
CUMULATIVE
Iridium monoselenide pressure-induced nonlayered structure, 43, 140 Infrared spectroscopy dehydrated magnesium formate, structure and characterization, 41, 67 lanthanum molybdate, 42, 158 Interactions electron-electron, in expanded metal compounds, 45,63 Intergrowth ACU&O~~ (A = K, Rb, Cs, Tl; M = Nb, Ta), 41, 221 Iodine Ag*IF.HrO crystal structure, A& grouping, 42, 1 Ag&P207, single-crystal growth and structure determination, 42, 183 K&(IOJOH)r + 8H20, preparation and structure, 44,201 Ion exchange HNb03 from LiNb03, 41, 308 HTaOJ from LiTa03, 41, 308 Ionic conduction AgI-AgBr, 42, 107 AgI-A&O,, 42, 107 AgI-fly ash, 42, 107 AgI-SiOz, 42, 107 Li3.7sS&.7~P0.2J0,,crystal structure, 44, 50 Li2+&ri-FeOr, 44, 354 and Raman spectroscopy in (1 - x)AgPOs-xAg2S04 glasses, 45, 309 Iron BaFe,-,Ru,O,-,, structure, 44, 366 Jh+,F& Mdssbauer spectra, magnetic and electrical behavior, 41, 124 phase relationship, 41, 114 BazFe&, crystal structure, two-dimensional array of Fe& tetrahedra, 41, 104 CaFerO,(FeO).(n = 1,2,3), relationship to CaTi20d, 43,222 Fe(2,2’-bipyridine) (H,O)rSO,, linear-chain transition metal complexes, low-dimensionality magnetic interactions, 44, 141 Fe*+ ions, availability in Cr- or Al-substituted magnetites with relevance to oxidation processes in defect phase y, 45, 317 “Fe isomer, Mossbauer shit? as measure of valence in mixed-valence iron sulfides, 41, 1 Fe-Mn-Ti-0 system, phase equilibria for composition FQ.-M&.~-T&.~-O, 43,267 Fe!riMo\vOs single crystals, growth and physical properties, 42, 242 FeNbF6, crystallochemistry and spectroscopy, 43, 327 Fe-I%-0 and Fe-W-O, structural and electronic relationships, 44, 113
SUBJECT INDEX FelO.,, electrical transitions, 45, 1 Fe-substituted V60u, preparation and properties, 42,212 Fe,VS*, structure and electronic properties, 44, 119 GeOr-ZnO-Fez03, system at 1OOO”C,44,426 Li-Fe-S system, conductivities and electronic structures of phases, 43, 163 LiFeSnO,, structural relationships in close-packed A&O, oxides, 45, 280 LiMnFeF6, dimorphism, cationic order in structural type NarSiS, 45, 127 LirCrr-Pef”SbOs, hexagonal-spine1 transitions, 44, 282 MnB-FeB, phase diagram FeB, low-temperature modification and crystal structure, 41, 195 unusual oxidation states and electronic configurations, 45, 88 Iron ion relations between structure and physical properties in K2NiF4-type oxides, 44, 82 Iron oxide Fe203, Ge, Si, and Mg solid solubility and photoelectric behavior, 41, 90 unusual oxidation states and electronic configurations, 45,88 YbOj-Fe203-M0 systems (M: Co, Ni, Cu, and Zn), phase relations in air at high temperatures, 42,22 Iron sulfides mixed-valence, Mossbatter “Fe isomer shift as measured of valence, 41, 1 Iron tungstates preparation and characterization, 42,41 L Lanthanide sulfotellurides (L&Tei+x (L = Tb, Dy, Ho, Er, Tm, Y), orderdisorder phenomena, 45, 140, 146 Lanthanum Bir-,La,WOs, structure, 41, 138 CaLa,-,Y,CrO, (0 5 x 5 l), structural and magnetic study, 42, 75 (La-Ca,)CoOr (0.1 5 x 5 0.5), electrical properties, 44, 254 La3WO&ls-U, luminescence properties, 44, 162 La,-kBa2+tiZn2-x010-ti, preparation, characterization, 42, 176 LaCo5, hydriding properties, modification by partial substitutions (LaCos-,M, with M = Al, Ga), 43,295 La,Gd,-,Ti03, magnetic behavior, 43, 204 La2MoOs : Eu3+, spectroscopic properties, 43, 87 ~,&O.,,@nO~, structure and electrical conductivity, 42, 125
CUMULATIVE LaWO&l, structure and luminescence, 45, 80 La,Y i-,TiO,, magnetic behavior, 43, 244 MliLaTh(VO&, (M = Sr, Pb), dimorphism, 45, 135 Pbo.94L~.M(Zro.ssTi.~~)~.~*~O~,piezoelectrical properties, comparison with PZT substitutes, 45, 164 Lanthanum B-alumina doped with europium, optical investigation by dye laser site-selective excitation, 41, 27 Lanthanum molybdate Raman and infrared spectra, 42, 158 Laser dye, (La)&tlumina phase doped with Eu under siteselective excitation, 41, 27 Lead KPbCr2F9, structural and magnetic properties, 41, 272 PbB&TiNbOsF, synthesis and X-ray diffraction, 44, 169 PbB&TiTaOsF, synthesis and X-ray diffraction, 44, 169 PbLaTh(VO&, dimorpism, 45, 135 Pb~.~ULao.~(Zr~.~~T~.~~)~.~~~O~, piezoelectric properties, comparison with PZT substitutes, 45, 164 PbO-Ta20S, pyrochlore-related phases, 43, 131 PbO-V20J equimolar system, new phases, 43, 63 Pb-Sn-Te system, lattice matching and thermal expansion, 43, 364 Pb(Zr0.~T&.0r5)0r, pressure-temperature phase diagram, 43, 285 Lead oxide PbO, vibrational study, force constants, 45, 343 PbOB vibrational study, force constants, 45, 343 Lithium expanded compounds, electron-electron interactions, 45, 63 Li-Fe-S system, conductivities and electronic structures of phases, 43, 163 LiFeSnOd, structural relationships in close-packed AB204 oxides, 45, 280 Li3Gai4, synthesis and X-ray crystal structure, 45, 290 LiMnFeF,,, dimorphism, cationic order in structural type Na$iS, 45, 127 LiPNr, crystal chemistry, 43, 126 LiReOr, structure, 42, 251 Li2Crz-,M~“SbOs (Ml” = Al, Fe, Ga), hexagonalspine1 transitions, 44, 282 L&ReO,, structure, 42, 251 LirSnOA, neutron profile refinement, 45, 170 Li3.7sS&.7JP0.zs04,crystal structure and ionic conductivity in tetrahedral structures, 44, 50 Li,+,Zni-,GeO,, ionic conductivity of LISICON solid solutions, 44, 354 L&ZtQ, neutron profile refinement, 45, 170
421
SUBJECT INDEX
Li,VOr (0 < x 5 l), preparation, 42, 217 Lithium hexathiohypodiphosphate synthesis, crystalline structure, and vibrational analysis, 43, 151 Luminescence A$K1002,, (A = Sr, Ba, Pb; B = Ti, Ge, Sn; and C = Al, Ga), crystal structure and luminescence, 41, 39 LarWO&-U, crystal structure, 44, 162 rare-earth activated bismuth tungstates, 42, 163 and structure of orthorhombic LnWO,Cl-type rare earth halo tungstates (Ln = La, Sm), 45, 80 and structure of rare earth halotungstates, 44, 99 M Magnesium Mg2+ ion distribution in spine1 ferrites, Ni*+ ion effect, 41, 63 MgNbFb, crystallochemistry and spectroscopy, 43, 327 solid solubility in FezOr and photoelectric behavior,
41, 90 Sr&Ig,, and SrMg4, structural relationship, 41, 111 Magnesium formate dehydrated, preparation and characterization, 41,67 Magnesium nickel ferrites polycrystalline, ferromagnetic resonance studies, 42,206 Magnetic properties CaLa,-,Y,CrOl (0 5 x 5 l), structural study, 42, 75 Magnetic susceptibility M(2,2’-bipyridine) (Hz0)#04 (M = Fe, Ni, Cu), 44, 141 Magnetites Al-substituted, availability of Fez+ ions with relevance to oxidation process in defect phase y, 45,317 Cr-substituted, availability of Fez+ ions with relevance to oxidation process in defect phase y, 45,317 Manganese CaMOS and CaMnOz.J by x-ray and neutron methods, 45, 71 CaMnOl.r, new oxygen-defect perovskite-type oxide, 44, 89 Ca2MnOr.S, new oxygen-defect perovskite-type oxide, 44, 89 CrB-MnB, phase diagram, 41, 195 Fe-Mn-Ti-0 system, phase equilibria for composition Fe0.297-Mb.09.7-Ti,,M)6-01 43, 267 KMnC&, structure types and phase transformations, 43, 107 L~.s.&.lsMnOS, structure and electrical conductivity, 42, 125
422
CUMULATIVE
LiMnFeF,, dimorphism, cationic order in structural type NarSiF,, 45, 127 Mn-AI-C, structural chemistry, 44, 126 MnB-FeB, phase diagram FeB, low-temperature modification and crystal structure, 41, 195 MnNbS, crystallochemistry and spectroscopy, 43, 327 (Nil-$o,)rMnSn, ferromagnetic and paramagnetic properties, 43,354 TlMnClr, structure types and phase transformations, 43, 107 Mercury( 11) amidonitrate naturally occurring, crystal structure, 42, 221 Metal chalcogenides mechanochemical synthesis, mechanism, 41, 244 Methanol low-temperature synthesis on CuO-ZnO-A&Or, reduction processes, 42, 120 Molybdates Cer(MoO&(MqO,), crystal structure, 44, 156 Molybdenum Cu2Mor01,,, reaction with Or, kinetics and mechanism, 44,291 Fe\‘Mo\“Os single crystals, growth and physical properties, 42,242 &Moos: Eu3+ (Ln = La, Gd, Y), spectroscopic properties, 43, 87 Molybdenum oxide solid-state reaction with bismuth oxide, kinetics and mechanism, 42, 136 Monolithium cryptate electride electron-electron interactions, 45, 63 Miissbauer spectroscopy Ba,+rFe& magnetic and electrical behavior, 41, 124 “Fe isomer shift as measure of valence in mixedvalence iron sulfides, 41, 1 *i9Sn in SnS-BaS, 41, 50 SnS-T&S, 41,50 N Neodymium Nci-zrBa2+2rZnZ-x010-2, preparation, characterization, 42, 176 Nd2Ge207, structure determination, 45, 293 Neodymium nitrate hexahydrate crystallographic study, 42, 325 Nephelauxetic effects CrFt-, quintet-triplet electronic transitions, SCF MO calculation, 42,28 Neptunium Np(OH)rSO,, synthesis and characterization, 45, 235
SUBJECT INDEX Neutron powder diffraction HTaW06, 41,277 HTaWO+HrO, 41, 277 HrTa,O,, 41, 277 Me&O4 (Pbr04, SnPb20d, NiSbzOd, ZnSbrOd thermal expansion, vibration, and rigidity, 43, 12 structure determination of CaMnOS and CaMnOZ,S, 45,71 TaWOr.S, 41, 277 Neutron profile refinement dehydrated Na zeolite A (Si/Al = 1.09), structure, 44,245 Nickel K,NiF,-type oxides, relations between structure and physical properties, 44, 82 Ni-Al-C, structural chemistry, 44, 126 NiAlrO.,-NirSiO, at high pressures and temperatures, 44, 257 Ni (2,2’-bipyridine) (H20)rS04, linear-chain transition metal complexes, low-dimensionality magnetic interactions, 44, 141 Ni*+ ion effect on Mg2+ and Cu2+ ion distribution in spine1 fenites, 41, 63 NiNbS, crystallochemistry and spectroscopy, 43, 327 Ni-Zn-Co Ba-doped fenites, transmission electron microscopy, 44, 208 (Nil-,Co,)rMnSn, ferromagnetic and paramagnetic properties, 43, 354 Ni,VSr, structure and electronic properties, 44, 119 Rh-Ni alloys, thermodynamic properties, 45, 303 Yb*Or-GarOr-NiO and Yb203-CrrOr-NiO, phase formation in air at high temperature, 43, 278 Nickel ions complexes of different symmetries, transferability of empirical crystal-field parameters, 44, 298 relations between structures and physical properties in KrNiF&ype oxides, 44, 82 Nickel niobate as photoanode, water photoelectrolysis, 44, 150 Nickel oxide and cyclooctasulfur, kinetics and mechanism of solid-state reaction, 45, 381 Yb203-Fe203-NiO, phase relations in air at high temperatures, 42, 22 Nickel titanate as photoanode, water photoelectrolysis, 44, 150 Niobium A,Nb,O,, (A = K, Rb, Cs), hydratation, 43, 346 Fe-Nb-0 and Fe-W-O, structural and electronic relationships, 44, 113 Nb-Al-C, structural chemistry, 44, 126 Nb20J-WOr and Ta20S-WOr systems, crystallographic shear, 44,60 selenide system, 41, 323
CUMULATIVE TiNb20,, coordination of cations by Raman spectroscopy, 45,216 Niobium sulfide intercalation phases with ethylenediamine, crystal chemical and thermo: gravimetric study, 45, 119 trimethylenediamine, crystal chemical and thermogravimetric study, 45, 119 Nitrogen presence within microscopic cavities in single crystalline NiO, 41, 147 RbOsOrN, crystal structure, 43, 29 0 Olivines A&O4 close-packed oxides, structural relationships, 45, 280 Optical transition Er3+ in fluoride glasses, 41, 253 Orbital symmetry conservation, pressure-induced black phosphorus to A7 (arsenic) phase transformation, 44, 415 Orthophosphates transition metals, preparation, magnetic properties, 45,252 Osmium RbOsOSN, crystal structure, 43, 29 Oxidation hydrocarbons over Pt on PbzPb,Ruz-,Os+.,, 44, 108 Oxides AzBaCuOS (A = Y, Sm, Eu, Gd, Dy, Ho, Er, Yb), isolation, characterization, 43, 73 A$Clo02,,, crystal structure and luminescence (A = Sr, Ba, Pb; B = Ti, Ge, Sn; and C = Al, Ga), 41, 39 ACug14~02, (A = K, Rb, Cs, Tl; M = Nb, Ta), intergrowth, 41, 221 Agr6112P207. single-crystal growth and structure determination, 42, 183 A4Nb40n (A = K, Rb, Cs), hydratation, 43, 346 anion coordination and cation packing, 44, 24 BaFe,+Rt@-,, structure, 44, 366 CaFezO,(FeO), (n = 1, 2, 3) relationship to Ca Ti204, 43, 222 CaMnO*,,, new oxygen-defect perovskite-type oxide, 44, 89 CaMnO, and CaMn02.S, structure determination by x-ray and neutron methods, 45, 71 Ca2Mn0,,,, new oxygen-defect perovskite-type oxide, 44, 89 CuCrzOl spine1 catalyst, electrical resistivity, 43, 261 Fe:‘Mo\“Os single crystals, growth and physical properties, 42, 242
SUBJECT INDEX
423
Fer04, electrical transitions, 45, 1 Fe-substituted V60n, preparation and properties, 42, 212 Gaz03, Raman spectra and valence force field, 45, 180 Ge02-ZnO-Fe203, system at lOOO”C, 44,426 HTiNbOs, H2 localization, 41, 57 KxP1W40,6r bronze with tunnel structure built up from POa tetrahedra and W06 octahedra, 44, 407 La,GdI+,Ti03, magnetic behavior, 43, 204 Lq,,SrO,,,,MnOJ, structure and electrical conductivity, 42, 125 La,Y,-,TiO,, magnetic behavior, 43, 244 LiFeSn04, structural relationships in close-packed AB204 oxides, 45, 280 LiRe03, structure, 42, 251 LipeO,, structure, 42, 251 LizSn03, neutron profile refinement, 45, 170 Li2Zr03, neutron profile refinement, 45, 170 Lij,,&,,7JP0.2504r crystal structure and ionic conductivity in tetrahedral structures, 44, 50 Li,VO* (0 < x 5 l), preparation, 42, 217 Lnl-zxBa2+tiZn2-,010-~ (Ln = La, Nd), preparation and characterization, 42, 176 MoJ+ in YVOI, substitutional off-center, ESR, 45, 93 NiO single crystals, experimental study of gases occluded within microscopic cavities, 41, 147 PbO,r,dLa,,os(Zr~.~~T~.~,).~~,03, piezoelectrical properties, comparison with PZT substitutes, 45, 164 Pb(ZrO,%ST&.&O1, pressure-temperature phase diagram, 43,285 rare-earth, electron beam-induced reduction, highresolution electron microscopy, 42, 47 TbO,, intermediate phases, structure, 41, 75 TiNb*O,, coordination of cations by Raman spectroscopy, 45, 276 vzo, Cr-doped, TEM observation of high-temperature transition, 45, 241 electrical transitions, 45, 1 VJ05, electrical transitions, 45, 1 V,,Oz,-, microsyntactic intergrowth, high-resolution electron microscopy, 43, 33 WOj . fHIO, powder form, wide-band proton NMR study, 45, 193 WI8049 crystal formation by gaseous reduction of WO1, 45, 324 defects and disorder introduced by partial oxidation, 45, 334 Oxygen BisTi2W0r4F, synthesis and X-ray diffraction, 44, 169 Bi7TiS020F, synthesis and X-ray diffraction, 44, 169
424
CUMULATIVE
Cu2Moj0i0 interaction, kinetics and mechanism, 44, 291 Fe-Mn-Ti-0 system, phase equilibria for composition Fer,297-M&.os7-T&.a-0, 43, 267 Fe-Nb-0 and Fe-W-O, structural and electronic relationships, 44, 113 Ge-W-O system near W09, phase analysis, 43,251 PbB&TiNbOsF, synthesis and X-ray diffraction, 44, 169 PbB&TiTaOsF, synthesis and X-ray diffraction, 44, 169 presence within microscopic cavities in single crystalline NiO, 41, 147 RbOs03N, crystal structure, 43, 29 tin-antimony-oxygen system, high-resolution electron microscopy, 44, 326 Oxyphosphate Fe4(P0&0, preparation and characterization, 42, 149 Oxysulfides HfOS, synthesis, 43, 225
P Palladium PdPSe single crystals, preparation and properties, 44, 382 Perovskites A:+B2+M:+09, (where A 2+= Ba, Sr; B2+ = Mn, CO, Ni, Zn; MS+ = Nb, Ta), order-disorder phenomena, 43, 51 HNbOJ, preparation from LiNbOr via ion exchange,
41, 308 HTaOr, preparation from LiTaOr via ion exchange,
41, 308 (La,-,Ca,)CoOr(O
5 X 5 0.6), magnetic properties,
41,329 Phase analysis of Ge-W-O system near WO,, 43,251 formation in Yb203-Cr203-MO and Yb203-Cr20jMO (M: Co, Ni, Cu, Zn) in air at high temperature, 43, 278 intermetallic, method for prediction, 42, 89 relationships in SrBr2-SrC12, 43, 271 Yb20s-Fe203-MO systems in air at high temperatures (M: Co, Ni, Cu, and Zn), 42, 22 Phase diagrams and magnetic properties of Cr,TiSe2 (0 < x < 1), 45, 411 Pb(Zro,%5Tia.0~s)Os,calorimetry and phase transition, 43, 285 Phase equilibria Fe-Mn-Ti-0 system for compositions FQ.~Mn,,.097-T&.m-0, 43,267 Phase transformation
SUBJECT INDEX pressure-induced black phosphorus to A,, orbital symmetry conservation analysis, 44, 415 Phase transitions Cs2-,Ki+,BiC& solid solution, 42, 130 in GaSe,+,S,, X-ray diffractometry, 41, 97 Phosphates (1 - x)AgPOx-xAg2S04 glasses, ionic conductivity and Raman spectroscopy, 45, 309 Phosphorus Ag16112P207rsingle-crystal growth and structure determination, 42, 183 black, pressure-induced phase transformation to A,, orbital symmetry conservation analysis, 44,415 CuO.sOCrO.sOPSz, structure and magnetic properties,
41, 174 KxP2W40i6, bronze with tunnel structure built up from PO4 tetrahedra and W06 octahedra, 44, 407 LiPN2, crystal chemistry, 43, 126 Lil.7sSi0.7sP0.2504,crystal structure and ionic conductivity in tetrahedral structures, 44, 50 PdWi003sr structure, 44, 318 PdPSe single crystals, preparation and properties, 44, 382 Photoelectric behavior Ge solid solubility in Fe2O3, 41, 90 Mg solid solubility in Fe203, 41, 90 Si solid solubility in Fe203, 41, 90 Photoelectrolysis water NiNb20e as photoanode, 44, 150 NiTiOS as photoanode, 44, 150 Photoluminescence and electroluminescence in graded cadmium sulfoselenide electrodes, applications to photoelectrochemical cells, 45, 51 Platinum Pb2Pb,Ru2-,0s+s support in hydrocarbon oxidation, 44, 108 Potassium Cs2-xKl+xBiC16, solid solution, phase transition, 42, 130 KMnC&, structure types and phase transformations, 43, 107 K2NiFctype oxides, relations between structure and physical properties, 44,82 &Nb40n, hydratation, 43, 346 Kag(IOrOH)2 . 8H2O, preparation and structure, 44, 201 KxP2W40i6, bronze with tunnel structure built up from PO4 tetrahedra and W06 octahedra, 44, 407 KPbCr2F9, structural and magnetic properties, 41, 272 KxP408(W0&,,,, electron microscopy, 43, 299 KVFJ, high-resolution electron microscopic study, 45, 259
CUMULATIVE KVOr . HzO, topotactic dehydration,
mechanism,
41, 205 Powder X-ray diffraction binary tungsten-oxygen system, phases in WO3W02, 41, 293 dehydrated magnesium formate, structure and characterization, 41, 67 Pyrochlores H2Ta206, neutron diffraction study, 41, 277 HTaW06, neutron diffraction study, 41, 277 HTaW06 . HrO, neutron diffraction study, 41, 277 PbrPb,Rur-,06+, support for Pt in hydrocarbon oxidation, 44, 108 -related phases in PbO-TazOS, 43, 131 (Re)ZVZ07 (Re = Yb, Tm), magnetic behavior, crystal field effects, 43, 175 TaWOr,r, neutron diffraction study, 41, 277 Pyrophosphate NaFePrO,, cage structure, 45, 389
R Raman spectroscopy and ionic conductivity in (1 - x)AgPOs-xAgrSO1 glasses, 45, 309 lanthanum molybdate, 42, 158 TiNbzO,, coordination of cations, 45, 276 and valence force field of GarOr, 45, 180 Rare-earth metal oxides Ln2Cu20s [Ln: Lu, Yb, Tm, Ho, Er, Tb, and Yl, crystal data, 42, 322 Ln(GaM2+)04 and Ln(AlMn2+)04, where Ln = Lu, Yb, Tm, Er, Ho, and Y, and M = Mg, Mn, Co, Cu, and Zn, preparation, 41, 166 Rare earth phosphates KCaLn(PO&, Nd3+, Eu3+, and Gdr+ ions as local probes, 43, 190 Na,Sr3-&z,(PO.&, Nd3+, Eu3+, and Gd3+ ions as local probes, 43, 190 Rhenium LtReOS, structure, 42, 251 L&ReO,, structure, 42, 251 ReO&ructured nonstoichiometric oxides, extended defect formation, 44, 174 Rhodium Rh-Ni alloys, thermodynamic properties, 45, 303 Rigidity MeX204 (Pb301, SnPbtOd, NiSb204, ZnSb,O,), thermal expansion, vibration, and neutron diffraction, 43, 12 Rubidium RbdNb40i7, hydratation, 43, 346 RbOsO,N, crystal structure, 43, 29 Rb,P40s(W03)~, electron microscopy, 43, 299 RbSbF2S04, synthesis and structure, 43, 81
425
SUBJECT INDEX
RbVF,, high-resolution electron microscopic study, 45,259 Ruthenium BaFei-,Ru,03-,, structure, 44, 366 Rutile relationship between CaFezOI and hollandite, 41,23 S Samarium SmWO,Cl, structure and luminescence, 45, 80 SCF MO calculation CrF$, quintet-triplet electronic transitions and nephelauxetic effects, 42, 28 Selenate vibrations, solid-state effects on, 43, 359 yttrium, vibrations, solid-state effects on, 43, 359 Selenides p-Ga2Se3, crystal structure, 43, 339 Selenium Cr,TiSet (0 < x < l), phase diagram and magnetic properties, 45,411 CuInSez-ZnSe-InzSe3, structure study, 45, 200 GaSei-,S,, polytype phase transition, 41, 97 PdPSe single crystals, preparation and properties, 44, 382 SbrSe, deposition of thin films, chemical methods, 44,425 Semiconductor -metal transition in mixed conductors, phenomenological model, 41, 333 SilenitesBi,,[A+,~~‘~,~Ora, AO, and B04 characterization by vibrational spectroscopy, 43, 45 Silica AgI-SiOr, enhanced ionic conduction, 42, 107 Li3,7SSit,7rP0.2504rcrystal structure and ionic conductivity in tetrahedral structures, 44, 50 NiA1204-Ni2Si04 at high pressures and temperatures, 44, 257 solid solubility in FeZO, and photoelectric behavior,
41, 90 Silver (1 - x)AgPOx-xAgzS04, ionic conductivity and Raman spectroscopy, 45, 309 Ag,IF.H*O crystal structure, A$ grouping, 42, 1 Ag&P207, single-crystal growth and structure determination, 42, 183 KSAg(IOSOH)2 . 8HrO inorganic complex, preparation and structure, 44, 201 Silver bromide AgI-AgBr, enhanced ionic conduction, 42, 107 Silver iodide AgI-AgBr, enhanced ionic conduction, 42, 107 AgI-A1203, enhanced ionic conduction, 42, 107 AgI-fly ash, enhanced ionic conduction, 42, 107 AgI-SiOr, enhanced ionic conduction, 42, 107
426
CUMULATIVE
Silver iodo-phosphate fast ion electrolytes, phase diagram and electrical characteristics, 42, 191 Silver oxalate thermal decomposition under nonisothermal conditions, effect of mechanical pretreatment, 41, 266 Sodium ions diffusion process in transition of bronze-type sodium titanium dioxide, 44, 337 Sodium titanium dioxide bronze-type, transition, diffusion of Na-ions, 44,337 Solids covalent amorphous, normal structural bonding and defects, 45, 40 electron states by electron spectroscopy, 45, 14 Solid solubility Ge in Fe203 and photoelectric behavior, 41, 90 Mg in Fe20, and photoelectric behavior, 41, 90 Si in Fe203 and photoelectric behavior, 41, 90 Spinels A&O4 close-packed oxides, structural relationships, 45, 280 Fe3-,Cr,04, heat capacity, 41, 213 N?+ ion effect on MgZ+ and Cu2+ ion distribution, 41, 63 Strontium La&r0.16Mn09, structure and electrical conductivity, 42, 125 SrBrr-SK&, phase relationships, 43, 271 SrLaTh(VO&, dimorphism, 45, 135 SrMg,, and SrM&, structural relationship, 41, 111 Strontium titanate with nonideal cationic ratio, electrical conductivity, 42, 227 Structure maps transition metal-main group MX and MX, compounds, electronic influences on crystal chemistry, 45, 399 Sulfates (1 - x)AgPO,-xAg2SOd glasses, ionic conductivity and Raman spectroscopy, 45, 309 MSbF2S04 (M = Rb, Cs), synthesis and structure, 43,81 Sulfides SnS-BaS, rr9Sn Miissbauer spectroscopy, 41, 50 SnS-T&S, ‘19Sn Miissbauer spectroscopy, 41, 50 Sulfur
Bal+,Fe2S4 Mossbauer spectra, magnetic and electrical behavior, 41, 124 phase relationship, 41, 114 Ba2Fe&, crystal structure, two-dimensional array of Fe& tetrahedra, 41, 104 CdHo& transition from spine&type structure to rocksah-type structure, electron microscopy/
SUBJECT INDEX diffraction, 42, 11 Cu,,.&rO.sOPS1, structure and magnetic properties, 41, 174 GaSei-,S,, polytype phase transition, 41, 97 Li-Fe-S system, conductivities and electronic structures of phases, 43, 163 T Tantalum Cu~TatIO~O, structure, 41, 286 PbO-TaZOZ, pyrochlore-related phases, 43, 131 selenide system, 41, 323 Ta-AI-C, structural chemistry, 44, 126 Tantalum sulfide intercalation phases with ethylenediamine, crystal chemical and thermogravimetric study, 45, 119 trimethylenediamine, crystal chemical and thermogravimetric study, 45, 119 Ta20S-WO, and Nb20J-W03 systems, crystallographic shear, 44,60 Technetium phosphides preparation and crystal structure, 44, 134 Tellurium Pb-Sn-Te system, lattice matching and thermal expansion, 43, 364 Tl-Bi-Te, phase transformations, electrical resistivity and thermoelectric measurements, 45,99 TIMnQ, structure types and phase transformations, 43, 107 Terbium (TbS)lTe,+., order-disorder phenomena, 45, 140, 146 Terbium oxides intermediate phases, structure, 41, 75 Tetrakisammonialithium electron-electron interactions in expanded metal compounds, 45,63 Tetrakismethylaminelithium electron-electron interactions, 45, 63 Tetrametaphosphate tellurate (NH&P40n. 2Te(OH)6 . 2Hz0, 41, 153 Thallium Tl-Bi-Te, phase transformation, electrical resistivity and thermoelectric measurements, 45, 99 TlVFs, high-resolution electron microscopic study, 45, 259 Thermal depolarization, see also Ionic thermoconductivity in ammonium chloride crystals, 44, 388 effect of HCl and NHs, 44, 399 Thermal expansion Pb-Sn-Te system, lattice matching, 43, 364 ThermoditTerential analysis dehydrated magnesium formate, structure and characterization, 41, 67
CUMULATIVE Thermogravimetry dehydrated magnesium formate, structure and characterization, 41, 67 Thorium MrrLaTh(VO&, (M = Sr, Pb), dimorphism, 45, 135 Thulium phenomena, 45, 140, (TmSM’e~+,, order-disorder 146 Tin LiFeSnO,, structural relationships in close-packed A&O4 oxides, 45, 280 LirSnO,, neutron profile refinement, 45, 170 (Ni,+,Co,),MnSn, ferromagnetic and paramagnetic properties, 43, 354 Pb-Sn-Te system, lattice matching and thermal expansion, 43, 364 tin-antimony-oxygen system, high-resolution electron microscopy, 44, 326 Titanates CaTiO,, electrical conductivity, 41, 185 Titanium BiSTi2W0r4F, synthesis and X-ray diffraction, 44, 169 Bi7TiS0r0F2, synthesis and X-ray diffraction 44, 169 Cr,TiSel (0 < x < 1), phase diagram and magnetic properties, 45,411 doping, effect on V203 crystal structure, 44, 192 Fe-Mn-Ti-0 system, phase equihbria for composition Fe,,29,-Mn0.0s,-Ti0.~-0, 43, 267 La@-,TiOr, magnetic behavior, 43, 204 La,Y, -ITiOj, magnetic behavior, 43, 244 PbBirTiNbOaF, synthesis and X-ray diffraction, 44, 169 PbBi2TiTaOsF, synthesis and X-ray diffraction, 44, 169 Pb~.94Lao.os(Zro.J8Ti~.~~)~,~*~O~, piezoelectrical properties, comparison with PZT substitutes, 45, 164 Pb(Zro.%sTi,,ops)Oj, pressure-temperature phase diagram, 43,285 Ti-Al-C, structural chemistry, 44, 126 TiNb*O,, coordination of cations by Raman spectroscopy, 45, 276 TiP04, preparation, magnetic properties, 45, 252 Ti&, XPS study of one-dimensional compounds, 44, 268 Titanium dioxide Raman spectra, 42, 276 Titanium oxide Ti.O+, (4H), magneli phases, cell and structure comparison, 43, 314 TinOzml, 4 5 n 5 9, refinements and structure, 44, 273
SUBJECT INDEX
427
Titanium sulfide intercalation phases with ethylenediamine crystal chemical and thermogravimetric study, 45, 119 trimethylenediamine, crystal chemical and thermogravimetric study, 45, 119 Transition metal -main group metal alloys, electronic influences on crystal chemistry, 45, 399 “pentagonal column” as building unit in crystal and defect structures, 44, 32 Transmission electron microscopy Ba-doped Ni-Zn-Co ferrites, 44, 208 Vz03. nonstoichiometry and defects, 44, 230 V90r7, nonstoichiometry and defects, 44, 212 Trichalcogenides NbS,, high-pressure synthesis, 41, 315 NbSes with NbSe3-type crystal structure, high-pressure synthesis, 41, 315 TaSr, high-pressure synthesis, 41, 315 TaSe,, high-pressure synthesis, 41, 315 Trihalides crystal chemistry, lone pair, stereochemistry, and structural relationships, 44, 1 Va elements, lone pair, stereochemistry, and structural relationships, 44, 1 Trimethylenediamine intercalation in 2H-NbSr, crystal chemical and thermogravimetric study, 45, 119 intercalation in IT-TaSr, crystal chemical and thermogravimetric study, 45, 119 intercalation in TiS2, crystal and chemical thermogravimetric study, 45, 119 Tungstates Bir-,La,WOs, structure, 41, 138 Bi2W06, polymorphism, 41, 160 orthorhombic rare earth (Ln = La, Sm), structure and luminescence, 45, 80 Tungsten AjB(P-tungsten) alloy, multiple metal-metal bonding and A-chain integrity, 45, 353 Fe-Nb-0 and Fe-W-O, structural and electronic relationships, 44, 113 Ge-W-O system near WO1, phase analysis, 43,251 KxPrW40r6, bronze with tunnel structure built up from PO4 tetrahedra and W06 octahedra, 44, 407 LarWO&-U, luminescence properties, 44, 162 P4Wr00r8, structure, 44, 318 W18049 defects and disorder introduced by partial oxidation, 45, 334 electron microscopy, crystal formation by gaseous reduction of WOx, 45,324 Tungsten bronzes Vegard relationships, 41, 227
428
CUMULATIVE
Tungsten oxides P4Wr003s, structure, 44, 318 Tungsten-oxygen phases in W09-W02, electron microscopy and powder X-ray diffraction, 41, 293 Tungstophosphates AxP40a(W0&,,, (A = K, Rb), electron microscopy, 43,299 Tveitite crystal structure, 44, 75 U
Uranium -activated La3W06Cl,, luminescence properties, 44, 162 crystallographic parameters by multiphase refinement of high-resolution neutron powder data a-US, 45, 396 UzF,, crystallographic parameters by multiphase refinement of high-resolution neutron powder data, 45, 3% V Valence bands electron spectroscopy of solids, 45, 14 Vanadates KV09 . HzO, topotactic dehydration, mechanism, 41,205 PbLaTh(VO&, dimorphism, 45, 135 SrLaTh(VO&, dimorphism, 45, 135 Vanadium Fe-substituted V60u, preparation and properties, 42, 212 Li,V02 (0 < x 5 1), preparation, 42, 217 MO’+ in YV04, substitutional off-center, ESR, 45, 93 PbO-VZOI, equimolar system, new phases, 43, 63 V-.41-C, structural chemistry, 44, 126 VP04, preparation, magnetic properties, 45, 252 V203, Cr-doped, TEM observation of high-temperature transition, 45, 241 V30s, electrical transitions, 45, 1 V,,OZ.-, microsyntactic intergrowth, high resolution electron microscopy, 43, 33 Vanadium fluoride bronzes A,VFj (A = K, Rb, Cs, Tl), high-resolution electron microscopic study, 45, 259 Vanadium oxide v203
effect of Cr doping, 44, 192 effect of Ti doping, 44, 192 nonstoichiometry and defects, 44, 230 V204, oxidized surface state model and application to catalysis, 42, 263
SUBJECT INDEX V205, oxidized surface state model and application to catalysis, 42, 263 V60r3, oxidized surface state model and application to catalysis, 42, 263 v9017
nonstoichiometry and defects, 44, 212 Vanadium sulfides M,VS2 (M = Fe, Co, Ni), structure and electronic properties, 44, 119 Vanadyl sulfate hydrates VOSO., . 2H20, thermal dehydration and structural model, 45, 112 VOS04 . 3H20, thermal dehydration and structural model, 45, 112 Vibration MeX20d (Pb304, SnPb204, NiSb204, ZnSb204), thermal expansion, rigidity, and neutron diffraction, 43, 12 Vibrational spectroscopy Bi,2[,$j~1&$020, A04 and B04 characterization, 43, 45 W Weberite Na,MgAlF,, space group analysis, 43, 213 Wolfram W09 . fH20, powder form, wide-band proton NMR study, 45, 193 Wurtzite derivatives and related dipolar tetrahedral structures, 42, 300 derivatives with unit cells having composition ABX2, AB2X3, A&X4. or Al?CzX4, enumeration and related dipolar tetrahedral structures, 42, 283 X X-Ray diffraction BiSTi2WO14F, synthesis, 44, 169 Bi,TiT02,,F, synthesis, 44, 169 GaSe,-,S,, phase transition, 41, 97 PbBi2TiNbOsF, synthesis, 44, 169 PbBhTiTaOsF, synthesis, 44, 169 X-Ray photoelectron spectroscopy Ti&, 44, 268 Y Ytterbium CsYbjF,O, crystal structure, isotype composition, 42,80 Ytterbium oxide Yb20g-Fe20g-MO systems (M: Co, Ni, Cu, and Zn), phase relations in air at high temperatures, 42, 22
CUMULATIVE Yb203-Ga203-MO and Yb203-Cr~O&f0 (M: Co, Ni, Cu, and Zn), phase formation in air at high temperature, 43, 278 Yttrium CaLa,-,Y,Cr04 (0 5 x 5 l), structural and magnetic study, 42, 75 Cai4YSFe, crystal structure, 44, 75 La,Y,-,TiOS, magnetic behavior, 43, 244 MO’+ in YVOI, substitutional off-center ion, ESR, 45,93 Y2Mo06 : Eu3+, spectroscopic properties, 43,87 (YS);Te,+,, order-disorder phenomena, 45,140, 146 2 Zeolites &B,Cm-x02, . nHZO (B = Al, Ga, C = Si, Ge), structure by high-resolution microscopy, 45, 368 A&A13Si30nI, formation, 42, 328 network, constituent units and framework conformations, 44, 41 Zeolites A dehydrated Na zeolite A (WA1 = 1.09), structure by neutron profile refinement, 44, 245
SUBJECT INDEX
429
zinc Ba;lZn3P100m, crystal structure, 45, 159 CuInSez-ZnSe-In,Se3, structure study, 45, 200 Ge02-ZnO-Fe203, system at lOOO’C, 44,426 Li2+&Zn1-,Ge04, ionic conductivity of LISICON solid solutions, 44, 354 Lnd-tiBaZ+LrZn2-x010-zr (Ln = La, Nd), preparation and characterization, 42, 176 Ni-Zn-Co Ba-doped ferrites, transmission electron microscopy, 44, 208 ZnNbS, crystallochemistry and spectroscopy, 43, 327 Zinc oxide CuO-ZnO-A&03, reduction processes in low-temperature methanol synthesis, 42, 120 Yb203-Fe203-ZnO, phase relations in air at high temperatures, 42, 22 Zirconium LizZr03, neutron profile refinement, 45, 170 Pbo.~L~.m(Zr~,,,T~.~~)~.~~O~, piezoelectrical properties, comparison with PZT substitutes, 45, 164 Pb(Zr,,w~T&.03s)0,, pressure-temperature phase diagram, 43,285 Zr-AI-C, structural chemistry, 44, 126
OF SOLID
STATE
CHEMISTRY
45, 415-429 (1982)
Cumulative Subject Index’ Volumes 41-45 A
B
Alkaline earth fluorides MF,(M = Ca, Sr, Ba), analogs of rose center production by hydrolysis, Raman spectroscopy, 43, 181 Alumina AgI-A&OS, enhanced ionic conduction, 42, 107 CuO-ZnO-AlzO,, reduction processes in low-temperature methanol synthesis, 42, 120 B-Alumina doped with cerium, properties, 42, 170 Aluminum LaCor hydriding properties, modification by, 43,295 LizCr~-,AI\rrSbOs, hexagonal-spine1 transitions, 44, 282 M-Al-C (M = Ti, Zr, Hf, V, Nb, Ta, Cr, Mn, Ni), structural chemistry, 44, 126 NiA1204-Ni$iO, at high pressures and temperatures, 44, 257 Ammonia Co(NH,),CI,, structure, 43, 334 effect on thermal depolarization in ammonium chloride crystals, 44, 399 Ammonium chloride thermal depolarization, 44, 388 effect of HCl and NH,, 44, 399 Anions coordination and cation packing in oxides, 44, 24 Antimonates LiZCrj-J4,t1rSbOs (M”’ = Al, Fe, Ga), hexagonalspine1 transitions, 44, 282 Antimony CsJ#‘Xg (M”’ = Sb or Bi, X = Cl or Br), doping, 41, 143 MSbF2S04 (M = Rb, Cs), synthesis and structure, 43,81 SbrSe,, deposition of thin films, chemical methods, 44,425 tin-antimony-oxygen system, high-resolution electron microscopy, 44, 326 Apatites phosphate (Alo-&Q4,(P0,),Yr,, where A = Sr, Pb; Y = F, Cl; X = 1, 2), magnetic effect studies, 4391 rare-earth-substituted chloro-phosphate, preparation and X-ray diffraction, 41, 44 silicate (Sr2Ln8(Si0.J602, where Ln = Nd and Gd), magnetic effect studies, 43, 1
Barium A,BaCu05 (A = Y, Sm, Eu, Gd, Dy, Ho, Er, Yb), isolation, characterization, 43, 73 BaFe,~,Ru,O~~,, structure, 44, 366 BaO-Ge02, high-pressure transformations into BaGeOr, BaGerOS, and BarGeSOn, 44, 307 4HBaCrO,, crystal structure, 43, 309 Bal+xFeS4 Mossbauer spectra, magnetic and electrical behavior, 41, 124 phase relationship, 41, 114 Ba2Fe4S5, crystal structure, two-dimensional array of Fe& tetrahedra, 41, 104 Ba2Zn3Pk,0,,,, crystal structure, 45, 159 B&Or-BaO rhombohedral phase, electron microscope study, 41, 233 -doped Ni-Zn-Co fenites, transmission electron microscopy, 44, 208 Lnl-tiBa2+2xZnZ-x010-2r (Ln = La, Nd), preparation and characterization, 42, 176 Barium oxide Bi203-BaO rhombohedral phase, electron microscope study, 41, 233 Bismuth Biz-xLa,W06, structure, 41, 138 B&O,-BaO rhombohedral phase, electron microscope study, 41, 233 Bi2W06, polymorphrsm, 41, 160 BiSTiZW0r4F, synthesis and X-ray diffraction, 44, 169 Bi,TiSOrOF, synthesis and X-ray diffraction, 44, 169 Cs,-,KI+,BiCl,, solid solution, phase transition, 42, 130 Cs$frr”X9 (Mu’ = Sb or Bi, X = Cl or Br), doping, 41, 143 PbBirTiNbOsF, synthesis and X-ray diffraction, 44, 169 PbB&TiTaOsF, synthesis and X-ray diffraction, 44, 169 Tl-Bi-Te, phase transformation, electrical resistivity and thermoelectric measurements, 45, 99 Bismuth oxide Bi203-BaO rhombohedral phase, electron microscope study, 41, 233 solid-state reaction with molybdenum oxide, kinetics and mechanism, 42, 136
r Boldface numbers indicate the appropriate volume; lightface numbers indicate pagination. 415 Copyright 0 1982 by All rights of reproduction
Academic Press, Inc. in any form reserved.
CUMULATIVE
416
SUBJECT INDEX
Bismuth tungstates rare-earth activated, luminescence, 42, 158 Bonding metal-metal, and A-chain integrity in superconducting A,B(B-tungsten) alloy, 45, 353 normal structural, and defects in covalent amorphous solids, 45,40 Boron B-rhombohedral, high-resolution electron microscope analysis of { lOO} twinning, 44, 374 Bromide MnB-FeB, phase diagram FeB, low-temperature modification and crystal structure, 41, 195 Bromine CrB-MnB, phase diagram, 41, 195 SrBr2-SrC&, phase relationships, 43, 271 C
Cadmium CaFz (Cl) and CdCl*, relationship, 45, 223 CdHo&, transition from spinel-type structure to rock&-type structure, electron microscopy/ diffraction, 42, 11 CdNbF6, crystallochemistry and spectroscopy, 43, 327 Cadmium selenide single crystals, high-temperature conductivity relaxation, 43, 320 Cadmium sulfide undoped CdS, high-temperature conductivity relaxation, 43, 320 Cadmium sulfoselenide electrodes photoluminescence in graded cadmium sulfoselenide electrodes, applications to photoelectrochemical cells, 45, 51 Calcium CaF2 (Cl) and CdC&, relationship, 45, 223 CaFezOd(FeO). (n = 1, 2, 3), relationship to CaTi204, 43, 222 CaLa,-,Y,Cr04 (0 IX 5 l), structural and magnetic study, 42, 75 CaMn02.5, new oxygen-defect perovskite-type oxide, 44, 89 CaMnO and CaMnOZ.J, structure determinations by x-ray and neutron methods, 45, 71 CaNbF6, crystallochemistry and spectroscopy, 43, 327 CaTiOx, electrical conductivity, 41, 185 Ca2Mn09.5, new oxygen-defect perovskite-type oxide, 44, 89 Ca14YSF43,crystal structure, 44, 75 (Lar-,Ca,)CoOs (0.1 5 x 5 0.5), electrical properties, 44, 254
Cadmium-strontium phosphate apatites infrared spectra, 43, 237 Calcium titanate with nonideal cationic ratio, defect structure, 43, 196 Carbon M-Al-C (M = Ti, Zr, Hf, V, Nb, Ta, Cr, Mn, Ni), structural chemistry, 44, 126 Cations packing and anion coordination, 44, 24 Cells photoelectrochemical, photoluminescence and electroluminescence in graded cadmium sulfoselenide electrodes, 45, 51 Cerium CeT(Mo0&(Mo207), crystal structure, 44, 156 -doped p-alumina, preparatiorr, properties, 42, 170 Cs2-,K,+,BiC16, solid solution, phase transitions, 42, 130 Cs&i”& (M1rr = Sb or Bi, X = Cl or Br), doping, 41, 143 CsNbdO,,, hydratation, 43, 346 CsSbF2S04, synthesis and structure, 43, 81 CsVF3, high-resolution electron microscopic study, 45, 259 Cesium ytterbium fluoride crystal structure, isotype composition, 42, 80 Chlorides CaF2 (C 1) and CdC12, relationship, 45, 223 Co(NH&CIS, structure, 43, 334 Cs2-xKl+xBiC16r solid solution, phase transitions, 42, 130 KMnC&, structure types and phase transformations, 43, 107 La~WO&&U, luminescence properties, 4.4, 162 SrBr2-SrQ, phase relationships, 43, 271 TlMnCl,, structure types and phase transformations, 43, 107 Chlorotungstates CepWO&, structure and luminescence, 44, 99 Eu9W06Cl,, structure and luminescence, 44, 99 GdSW06C19, structure and luminescence, 44, 99 LaSW06C19, structure and luminescence, 44, 99 NdSW06Clj, structure and luminescence, 44, 99 Pr~WO&, structure and luminescence, 44, 99 SmlW06ClJ, structure and luminescence, 44, 99 Chromium Cr-Al-C, structural chemistry, 44, 126 CrB-MnB, phase diagram, 41, 195 Cr,TiSez (0 < x < l), phase diagram and magnetic properties, 45, 411 CuCr,O, spine1 catalyst, electrical resistivity, 43, 261 Cu.&&,,&, structure and magnetic properties, 41, 174
CUMULATIVE doped V203 effect on crystal structure, 44, 192 TEM observation of high-temperature metal-insulator transition, 45, 241 KPbCr2F9, structural and magnetic properties, 41, 272 Li2CrJ+,M~“SbOs (Ml” = Al, Fe, Ga), hexagonalspine1 transitions, 44, 282 Chromium fluoride Cr$, quintet-triplet electronic transitions and nephelauxetic effects, SCF MO calculation, 42, 28 Chromium oxide 4H BaCrOr, crystal structure, 43, 309 CaLa]-,Y,Cr04 (0 5 x 5 1), structural and magnetic study, 42, 75 Yb203-Ga203-M0 and Yb203-Crz03-M0 (M: Co, Ni, Cu, and Zn), phase formation in air at high temperature, 43, 278 Cobalt CoNbF6, crystallochemistry and spectroscopy, 43, 327 Co(NHJ)&13, structure, 43, 334 ColVS,, structure and electronic properties, 44, 119 LaCoS hydriding properties, modification by partial substitutions (LaCoS&4, with M = Al, Ga), 43, 295 (La,+,Ca,)CoOr (0.1 5 x 5 0.5) electrical properties, 44, 254 (Nil-,Co,)rMnSn, ferromagnetic and paramagnetic properties, 43, 354 Ybz0&a203-Co0 and Yb203-CrzOr-Coo, phase formation in air at high temperature, 43, 278 Co ion relations between structure and physical properties in KrNiF&ype oxides, 44, 82 Cobalt oxide YbZ03-Fe203-COO, phase relations in air at high temperatures, 42, 22 Columns “pentagonal”, as building unit in crystal and defect structures of some groups of transition metal compounds, 44, 32 Conductivity and chain integrity in ArB(P-tungsten) alloy, relationship, 45, 353 Conductor mixed, phenomenological model for semiconductor-metal transition, 41, 333 Copper AzBaCuOS (A = Y, Sm, Eu, Gd, Dy, Ho, Er, Yb), isolation, characterization, 43, 73 Cu(2,2’-bipyridine) (Hz0)rS04, linear-chain transition metal complexes, low-dimensionality magnetic interactions, 44, 141
417
SUBJECT INDEX
CuCr204 spine1 catalyst, electrical resistivity, 43, 261 structure and magnetic properties, Cuo.50Cr0.50Ps3, 41, 174
CuInSez-ZnSe-InzSe3, structure study, 45, 200 CU~MO~O,~, reaction with Or, kinetics and mechanism, 44, 291 CuSTa1,030, structure, 41, 286 Copper ion Du and C,, distorted complexes, crystal field theory and EPR parameters, 44, 343 distribution in spine1 ferrites, Ni*+ ion effect, 41, 63 Copper oxide CuO-ZnO-A1203, reduction processes in low-temperature methanol synthesis, 42, 120 Yb203-FezOr-CuO, phase relations in air at high temperatures, 42, 22 Copper tantalum oxide Cu5Ta,,0so, structure, 41, 286 Crystal field theory and EPR parameters in Dzd and C,, distorted tetrahedral copper complexes, 44, 343 Crystallographic shear Nb205-W03 and Ta20S-W03 systems, 44, 60 Crystal structure A$CloOzo (A = Sr, Ba, Pb; B = Ti, Ge, Sn; and C = Al, Ga), luminescence, 41, 39 BarFe&, two-dimensional array of Fe& tetrahedra, 41, 104 CuAlOr, 41, 132 indium p-alumina, 43, 227 Li3,75S~.7SP0,2504rand ionic conductivity in tetrahedral structures, 44, 50 Ln3W06C13 (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd), luminescence, 44, 99 Cyclooctasulfur and nickel oxide, kinetics and mechanism of solidstate reaction, 45, 381 D
Decametaphosphate Ba2Zn3PloO~, crystal structure, 45, 159 Dehydration topotactic, KV03 . H20, mechanism, 41, 205 Delafossites CuAlOr, high temperature structural investigation, 41, 132
Dielectrical constant electron-electron interactions, 45, 63 Diffraction CdHo& transition from spinel-type structure to rocksalt-type structure, 42, 11 neutron, in HTiNbOr, 41, 57
418
CUMULATIVE
Dihydrogeno-sulfato-iodate K.+H2(SZ12014),crystal structure, 41, 262 2,CDinitrotoluene solid-state reaction with diphenylamine as n and n donor, 44, 186 Diphenylamine n and TI donor in solid-state reaction of 2,4-dinitrotoluene with diphenylamine, 44, 186 Disilicides transition metal, binding, 43, 97 Doping Cr, effect on V203 crystal structure, 44, 192 Ti, effect on V203 crystal structure, 44, 192 Dysprosium (DySbTe,+,, order-disorder phenomena, 45, 140, 146 E Electrical conductivity CaTiO,, 41, 185 La,,&q.,&nO~, structure, 42, 125 Electrical resistivity CuCr204 spine1 catalyst, 43, 261 (La,-,Ca,)CoOs (0.1 5 x 5 0.5), 44, 254 Electrical transitions FerO.,, 45, 1 v203,45, 1 v305,45, 1 Electroluminescence and photoluminescence in graded cadmium sulfoselenide electrodes, applications to photoelectrochemical cells, 45, 51 Electrolytes fast-ion, silver iodo-phosphate phase diagram and electrical characteristics, 42, 191 Electronic conductivity CaTiOs with nonideal cationic ratio, 43, 196 Electronic expansion factor tungsten bronzes, vegard relationships, 41, 227 Electronic transitions quintet-triplet, CrFh- and nephelauxetic effects, SCF MO calculation, 42, 28 Electron microscopy AxP.+Os(WO&,,, (A = K, Rb), structure, 43, 299 binary tungsten-oxygen system, phases in W09WOz, 41, 293 CdHo& transition from spinel-type structure to rocksalt-type structure, 42, 11 high resolution electron beam-induced reduction of higher oxides of rare earths, 42,47 VnOan-, microsyntactic growth, 43, 33 W18049 crystal formation by gaseous reduction of WO,, 45, 324
SUBJECT INDEX defects and disorder introduced by partial oxidation, 45, 334 Electrons states of solids by electron spectroscopy, 45, 14 Electron spectroscopy states of solids, 45, 14 Electron spin resonance Mo5+ in VYO4, substitutional off-center ion, 45, 93 Erbium Er3+ optical transition probabilities in fluoride glasses, 41, 253 (ErS)*Te,+,, order-disorder phenomena, 45, 140, 146 Ethylenediamine intercalation in 2H-Nb& crystal chemical and thermogravimetric study, 45, 119 lT-Ta&, crystal chemical and thermogravimetric study, 45, 119 TiSr, crystal chemical and thermogravimetric study, 45, 119 Europium lanthanum p-alumina phase doped with, optical investigation by dye laser site-selective excitation, 41, 27 Ln2Mo06: Eu’+ (Ln = La, Gd, Y), spectroscopic properties, 43, 87 Excitation site-selective, (La) B-alumina doped with Eu, optical investigation by dye laser, 41, 27 F Ferrites Ba-doped Ni-Zn-Co, transmission electron microscopy, 44,208 Ferromagnetic resonance polycrystalline magnesium nickel ferrites, 42, 206 Films thin, chemical methods for deposition of Sb,Sej, 44, 425 Fluoride glasses Er3+ optical transition probabilities, 41, 253 Fluorides Ag,IF.HrO crystal structure, A& grouping, 42, 1 BiJTi2W01.+F, synthesis and X-ray diffraction, 44, 169 Bi;TiTOrOF, synthesis and X-ray diffraction, 44, 169 CaF2 (C 1) and Cd& relationship, 45, 223 Ca14YSF43rcrystal structure, 44, 75 CsYblFlO, crystal structure, isotype composition, 42, 80 KPbCr,F,, structural and magnetic properties, 41, 272 K*NiF,-type oxides, relations between structures and physical properties, 44, 82
CUMULATIVE LiMnFeF6, dimorphism, cationic order in structural type NaZSiFB, 45, 127 MSbF2S04 (M = Rb, Cs), synthesis and structure, 43, 81 PbBi2TiNbOsF, synthesis and X-ray diffraction, 44, 169 PbBi;TiTa08F, synthesis and X-ray diffraction, 44, 169 a-UF5 crystallographic parameters by multiphase refmement of high-resolution neutron powder data, 45, 396 UP, crystallographic parameters by multiphase retinement of high-resolution neutron powder data, 45,396 Fluoroniobates MNbF6 (M = Mg, Ca, Mn, Fe, Co, Ni, Zn, Cd), crystallochemistry and spectroscopy, 43, 327 Fluorooxovanadates green CS2 [VOF,(HZO)], crystal structure and relation to blue CSr [VOF.,(H20)], 45, 154 Fly ash AgI-fly ash, enhanced ionic conduction, 42, 107 G Gadolinium GdzMo06 : Eu3+, spectroscopic properties, 43, 87 La,Gd,-,TiOj, magnetic behavior, 43, 204 Gallium Gaz09, Raman spectra and valence force field, 45, 180 GaSe,-,S,, polytype phase transition, 41, 97 B-Ga2Se3, crystal structure, 43, 339 LaCos hydriding properties, modification by, 43,295 LirCrr-,Gai”SbOr,, hexagonal-spine1 transitions, 44, 282 Li3Ga14, synthesis and X-ray crystal structure, 45, 290 Gallium oxide Yb203-GarO+fO and Yb203-Cr203-MO (M: Co, Ni, Cu, and Zn), phase formation in air at high temperature, 43, 278 Germanates Nd2Ge20r, structure determination, 45, 293 Germanium BaO-GeOr, high-pressure transformations into BaGeOl, BaGerOJ, and Ba2GeSOn, 44, 307 Ge-W-O system near W09, phase analysis, 43,251 Ge02-ZnO-FezOs, system at lOOO”C, 44,426 Li~+tiZni-,GeO~, ionic conductivity of LISICON solid solutions, 44, 354 solid solubility in Fe203 and photoelectric behavior, 41, 90
419
SUBJECT INDEX H
Hafnium Hf-Al-C, structural chemistry, 44, 126 HfOS, synthesis, 43, 225 Halides Cs&@!‘X9 (Mrii = Sb or Bi, X = Cl or Br), doping, 41, 143 High-resolution microscopy . nHzO (B = Al, Ga, C = Si, Ge), surM’LG-x02m prises in structural chemistry, 45, 368 structures of hexagonal vanadium fluoride bronzes, 45,259 tin-antimony-oxygen system, 44, 326 {lOO} twinning in B-rhombohedral boron, 44, 374 High-resolution neutron powder diffraction crystallographic parameters in u-UF5 and U2F, by multiphase refinement of, 45, 396 High-temperature conductivity relaxation CdSe single crystals, 43, 320 undoped CdS, 43,320 Hollandite relationship between CaFe*O, and rutile, 41, 23 Holmium CdHo& transition from spinel-type structure to rock&-type structure, electron microscopy/ diffraction, 42, 11 (HoS)2Tel+r, order-disorder phenomena, 45, 140, 146 Hydratation A4Nb40,, (A = K, Rb, Cs), 43, 346 Hydrates WOj . $H20, powder form, wide-band proton NMR study, 45, 193 Hydrides LaH,, anomalous site disorder, 43, 5 YH,, anomalous site disorder, 43, 5 Hydriding LaCos, modification by partial substitution (La Co5-&, where M = Al, Ga), 43, 295 Hydrochloric acid effect on thermal depolarization in ammonium chloride crystals, 44,399 Hydrogen localization in layer oxide HTiNbOs, 41, 57 Hydrosulfates Np(OH)$Od, synthesis and characterization, 45, 235 I Indium CuInSe*-ZnSe-InrSe,, structure study, 45, 200 Indium @hnnina single crystals, preparation and physical properties, 43.227
420
CUMULATIVE
Iridium monoselenide pressure-induced nonlayered structure, 43, 140 Infrared spectroscopy dehydrated magnesium formate, structure and characterization, 41, 67 lanthanum molybdate, 42, 158 Interactions electron-electron, in expanded metal compounds, 45,63 Intergrowth ACU&O~~ (A = K, Rb, Cs, Tl; M = Nb, Ta), 41, 221 Iodine Ag*IF.HrO crystal structure, A& grouping, 42, 1 Ag&P207, single-crystal growth and structure determination, 42, 183 K&(IOJOH)r + 8H20, preparation and structure, 44,201 Ion exchange HNb03 from LiNb03, 41, 308 HTaOJ from LiTa03, 41, 308 Ionic conduction AgI-AgBr, 42, 107 AgI-A&O,, 42, 107 AgI-fly ash, 42, 107 AgI-SiOz, 42, 107 Li3.7sS&.7~P0.2J0,,crystal structure, 44, 50 Li2+&ri-FeOr, 44, 354 and Raman spectroscopy in (1 - x)AgPOs-xAg2S04 glasses, 45, 309 Iron BaFe,-,Ru,O,-,, structure, 44, 366 Jh+,F& Mdssbauer spectra, magnetic and electrical behavior, 41, 124 phase relationship, 41, 114 BazFe&, crystal structure, two-dimensional array of Fe& tetrahedra, 41, 104 CaFerO,(FeO).(n = 1,2,3), relationship to CaTi20d, 43,222 Fe(2,2’-bipyridine) (H,O)rSO,, linear-chain transition metal complexes, low-dimensionality magnetic interactions, 44, 141 Fe*+ ions, availability in Cr- or Al-substituted magnetites with relevance to oxidation processes in defect phase y, 45, 317 “Fe isomer, Mossbauer shit? as measure of valence in mixed-valence iron sulfides, 41, 1 Fe-Mn-Ti-0 system, phase equilibria for composition FQ.-M&.~-T&.~-O, 43,267 Fe!riMo\vOs single crystals, growth and physical properties, 42, 242 FeNbF6, crystallochemistry and spectroscopy, 43, 327 Fe-I%-0 and Fe-W-O, structural and electronic relationships, 44, 113
SUBJECT INDEX FelO.,, electrical transitions, 45, 1 Fe-substituted V60u, preparation and properties, 42,212 Fe,VS*, structure and electronic properties, 44, 119 GeOr-ZnO-Fez03, system at 1OOO”C,44,426 Li-Fe-S system, conductivities and electronic structures of phases, 43, 163 LiFeSnO,, structural relationships in close-packed A&O, oxides, 45, 280 LiMnFeF6, dimorphism, cationic order in structural type NarSiS, 45, 127 LirCrr-Pef”SbOs, hexagonal-spine1 transitions, 44, 282 MnB-FeB, phase diagram FeB, low-temperature modification and crystal structure, 41, 195 unusual oxidation states and electronic configurations, 45, 88 Iron ion relations between structure and physical properties in K2NiF4-type oxides, 44, 82 Iron oxide Fe203, Ge, Si, and Mg solid solubility and photoelectric behavior, 41, 90 unusual oxidation states and electronic configurations, 45,88 YbOj-Fe203-M0 systems (M: Co, Ni, Cu, and Zn), phase relations in air at high temperatures, 42,22 Iron sulfides mixed-valence, Mossbatter “Fe isomer shift as measured of valence, 41, 1 Iron tungstates preparation and characterization, 42,41 L Lanthanide sulfotellurides (L&Tei+x (L = Tb, Dy, Ho, Er, Tm, Y), orderdisorder phenomena, 45, 140, 146 Lanthanum Bir-,La,WOs, structure, 41, 138 CaLa,-,Y,CrO, (0 5 x 5 l), structural and magnetic study, 42, 75 (La-Ca,)CoOr (0.1 5 x 5 0.5), electrical properties, 44, 254 La3WO&ls-U, luminescence properties, 44, 162 La,-kBa2+tiZn2-x010-ti, preparation, characterization, 42, 176 LaCo5, hydriding properties, modification by partial substitutions (LaCos-,M, with M = Al, Ga), 43,295 La,Gd,-,Ti03, magnetic behavior, 43, 204 La2MoOs : Eu3+, spectroscopic properties, 43, 87 ~,&O.,,@nO~, structure and electrical conductivity, 42, 125
CUMULATIVE LaWO&l, structure and luminescence, 45, 80 La,Y i-,TiO,, magnetic behavior, 43, 244 MliLaTh(VO&, (M = Sr, Pb), dimorphism, 45, 135 Pbo.94L~.M(Zro.ssTi.~~)~.~*~O~,piezoelectrical properties, comparison with PZT substitutes, 45, 164 Lanthanum B-alumina doped with europium, optical investigation by dye laser site-selective excitation, 41, 27 Lanthanum molybdate Raman and infrared spectra, 42, 158 Laser dye, (La)&tlumina phase doped with Eu under siteselective excitation, 41, 27 Lead KPbCr2F9, structural and magnetic properties, 41, 272 PbB&TiNbOsF, synthesis and X-ray diffraction, 44, 169 PbB&TiTaOsF, synthesis and X-ray diffraction, 44, 169 PbLaTh(VO&, dimorpism, 45, 135 Pb~.~ULao.~(Zr~.~~T~.~~)~.~~~O~, piezoelectric properties, comparison with PZT substitutes, 45, 164 PbO-Ta20S, pyrochlore-related phases, 43, 131 PbO-V20J equimolar system, new phases, 43, 63 Pb-Sn-Te system, lattice matching and thermal expansion, 43, 364 Pb(Zr0.~T&.0r5)0r, pressure-temperature phase diagram, 43, 285 Lead oxide PbO, vibrational study, force constants, 45, 343 PbOB vibrational study, force constants, 45, 343 Lithium expanded compounds, electron-electron interactions, 45, 63 Li-Fe-S system, conductivities and electronic structures of phases, 43, 163 LiFeSnOd, structural relationships in close-packed AB204 oxides, 45, 280 Li3Gai4, synthesis and X-ray crystal structure, 45, 290 LiMnFeF,,, dimorphism, cationic order in structural type Na$iS, 45, 127 LiPNr, crystal chemistry, 43, 126 LiReOr, structure, 42, 251 Li2Crz-,M~“SbOs (Ml” = Al, Fe, Ga), hexagonalspine1 transitions, 44, 282 L&ReO,, structure, 42, 251 LirSnOA, neutron profile refinement, 45, 170 Li3.7sS&.7JP0.zs04,crystal structure and ionic conductivity in tetrahedral structures, 44, 50 Li,+,Zni-,GeO,, ionic conductivity of LISICON solid solutions, 44, 354 L&ZtQ, neutron profile refinement, 45, 170
421
SUBJECT INDEX
Li,VOr (0 < x 5 l), preparation, 42, 217 Lithium hexathiohypodiphosphate synthesis, crystalline structure, and vibrational analysis, 43, 151 Luminescence A$K1002,, (A = Sr, Ba, Pb; B = Ti, Ge, Sn; and C = Al, Ga), crystal structure and luminescence, 41, 39 LarWO&-U, crystal structure, 44, 162 rare-earth activated bismuth tungstates, 42, 163 and structure of orthorhombic LnWO,Cl-type rare earth halo tungstates (Ln = La, Sm), 45, 80 and structure of rare earth halotungstates, 44, 99 M Magnesium Mg2+ ion distribution in spine1 ferrites, Ni*+ ion effect, 41, 63 MgNbFb, crystallochemistry and spectroscopy, 43, 327 solid solubility in FezOr and photoelectric behavior,
41, 90 Sr&Ig,, and SrMg4, structural relationship, 41, 111 Magnesium formate dehydrated, preparation and characterization, 41,67 Magnesium nickel ferrites polycrystalline, ferromagnetic resonance studies, 42,206 Magnetic properties CaLa,-,Y,CrOl (0 5 x 5 l), structural study, 42, 75 Magnetic susceptibility M(2,2’-bipyridine) (Hz0)#04 (M = Fe, Ni, Cu), 44, 141 Magnetites Al-substituted, availability of Fez+ ions with relevance to oxidation process in defect phase y, 45,317 Cr-substituted, availability of Fez+ ions with relevance to oxidation process in defect phase y, 45,317 Manganese CaMOS and CaMnOz.J by x-ray and neutron methods, 45, 71 CaMnOl.r, new oxygen-defect perovskite-type oxide, 44, 89 Ca2MnOr.S, new oxygen-defect perovskite-type oxide, 44, 89 CrB-MnB, phase diagram, 41, 195 Fe-Mn-Ti-0 system, phase equilibria for composition Fe0.297-Mb.09.7-Ti,,M)6-01 43, 267 KMnC&, structure types and phase transformations, 43, 107 L~.s.&.lsMnOS, structure and electrical conductivity, 42, 125
422
CUMULATIVE
LiMnFeF,, dimorphism, cationic order in structural type NarSiF,, 45, 127 Mn-AI-C, structural chemistry, 44, 126 MnB-FeB, phase diagram FeB, low-temperature modification and crystal structure, 41, 195 MnNbS, crystallochemistry and spectroscopy, 43, 327 (Nil-$o,)rMnSn, ferromagnetic and paramagnetic properties, 43,354 TlMnClr, structure types and phase transformations, 43, 107 Mercury( 11) amidonitrate naturally occurring, crystal structure, 42, 221 Metal chalcogenides mechanochemical synthesis, mechanism, 41, 244 Methanol low-temperature synthesis on CuO-ZnO-A&Or, reduction processes, 42, 120 Molybdates Cer(MoO&(MqO,), crystal structure, 44, 156 Molybdenum Cu2Mor01,,, reaction with Or, kinetics and mechanism, 44,291 Fe\‘Mo\“Os single crystals, growth and physical properties, 42,242 &Moos: Eu3+ (Ln = La, Gd, Y), spectroscopic properties, 43, 87 Molybdenum oxide solid-state reaction with bismuth oxide, kinetics and mechanism, 42, 136 Monolithium cryptate electride electron-electron interactions, 45, 63 Miissbauer spectroscopy Ba,+rFe& magnetic and electrical behavior, 41, 124 “Fe isomer shift as measure of valence in mixedvalence iron sulfides, 41, 1 *i9Sn in SnS-BaS, 41, 50 SnS-T&S, 41,50 N Neodymium Nci-zrBa2+2rZnZ-x010-2, preparation, characterization, 42, 176 Nd2Ge207, structure determination, 45, 293 Neodymium nitrate hexahydrate crystallographic study, 42, 325 Nephelauxetic effects CrFt-, quintet-triplet electronic transitions, SCF MO calculation, 42,28 Neptunium Np(OH)rSO,, synthesis and characterization, 45, 235
SUBJECT INDEX Neutron powder diffraction HTaW06, 41,277 HTaWO+HrO, 41, 277 HrTa,O,, 41, 277 Me&O4 (Pbr04, SnPb20d, NiSbzOd, ZnSbrOd thermal expansion, vibration, and rigidity, 43, 12 structure determination of CaMnOS and CaMnOZ,S, 45,71 TaWOr.S, 41, 277 Neutron profile refinement dehydrated Na zeolite A (Si/Al = 1.09), structure, 44,245 Nickel K,NiF,-type oxides, relations between structure and physical properties, 44, 82 Ni-Al-C, structural chemistry, 44, 126 NiAlrO.,-NirSiO, at high pressures and temperatures, 44, 257 Ni (2,2’-bipyridine) (H20)rS04, linear-chain transition metal complexes, low-dimensionality magnetic interactions, 44, 141 Ni*+ ion effect on Mg2+ and Cu2+ ion distribution in spine1 fenites, 41, 63 NiNbS, crystallochemistry and spectroscopy, 43, 327 Ni-Zn-Co Ba-doped fenites, transmission electron microscopy, 44, 208 (Nil-,Co,)rMnSn, ferromagnetic and paramagnetic properties, 43, 354 Ni,VSr, structure and electronic properties, 44, 119 Rh-Ni alloys, thermodynamic properties, 45, 303 Yb*Or-GarOr-NiO and Yb203-CrrOr-NiO, phase formation in air at high temperature, 43, 278 Nickel ions complexes of different symmetries, transferability of empirical crystal-field parameters, 44, 298 relations between structures and physical properties in KrNiF&ype oxides, 44, 82 Nickel niobate as photoanode, water photoelectrolysis, 44, 150 Nickel oxide and cyclooctasulfur, kinetics and mechanism of solid-state reaction, 45, 381 Yb203-Fe203-NiO, phase relations in air at high temperatures, 42, 22 Nickel titanate as photoanode, water photoelectrolysis, 44, 150 Niobium A,Nb,O,, (A = K, Rb, Cs), hydratation, 43, 346 Fe-Nb-0 and Fe-W-O, structural and electronic relationships, 44, 113 Nb-Al-C, structural chemistry, 44, 126 Nb20J-WOr and Ta20S-WOr systems, crystallographic shear, 44,60 selenide system, 41, 323
CUMULATIVE TiNb20,, coordination of cations by Raman spectroscopy, 45,216 Niobium sulfide intercalation phases with ethylenediamine, crystal chemical and thermo: gravimetric study, 45, 119 trimethylenediamine, crystal chemical and thermogravimetric study, 45, 119 Nitrogen presence within microscopic cavities in single crystalline NiO, 41, 147 RbOsOrN, crystal structure, 43, 29 0 Olivines A&O4 close-packed oxides, structural relationships, 45, 280 Optical transition Er3+ in fluoride glasses, 41, 253 Orbital symmetry conservation, pressure-induced black phosphorus to A7 (arsenic) phase transformation, 44, 415 Orthophosphates transition metals, preparation, magnetic properties, 45,252 Osmium RbOsOSN, crystal structure, 43, 29 Oxidation hydrocarbons over Pt on PbzPb,Ruz-,Os+.,, 44, 108 Oxides AzBaCuOS (A = Y, Sm, Eu, Gd, Dy, Ho, Er, Yb), isolation, characterization, 43, 73 A$Clo02,,, crystal structure and luminescence (A = Sr, Ba, Pb; B = Ti, Ge, Sn; and C = Al, Ga), 41, 39 ACug14~02, (A = K, Rb, Cs, Tl; M = Nb, Ta), intergrowth, 41, 221 Agr6112P207. single-crystal growth and structure determination, 42, 183 A4Nb40n (A = K, Rb, Cs), hydratation, 43, 346 anion coordination and cation packing, 44, 24 BaFe,+Rt@-,, structure, 44, 366 CaFezO,(FeO), (n = 1, 2, 3) relationship to Ca Ti204, 43, 222 CaMnO*,,, new oxygen-defect perovskite-type oxide, 44, 89 CaMnO, and CaMn02.S, structure determination by x-ray and neutron methods, 45, 71 Ca2Mn0,,,, new oxygen-defect perovskite-type oxide, 44, 89 CuCrzOl spine1 catalyst, electrical resistivity, 43, 261 Fe:‘Mo\“Os single crystals, growth and physical properties, 42, 242
SUBJECT INDEX
423
Fer04, electrical transitions, 45, 1 Fe-substituted V60n, preparation and properties, 42, 212 Gaz03, Raman spectra and valence force field, 45, 180 Ge02-ZnO-Fe203, system at lOOO”C, 44,426 HTiNbOs, H2 localization, 41, 57 KxP1W40,6r bronze with tunnel structure built up from POa tetrahedra and W06 octahedra, 44, 407 La,GdI+,Ti03, magnetic behavior, 43, 204 Lq,,SrO,,,,MnOJ, structure and electrical conductivity, 42, 125 La,Y,-,TiO,, magnetic behavior, 43, 244 LiFeSn04, structural relationships in close-packed AB204 oxides, 45, 280 LiRe03, structure, 42, 251 LipeO,, structure, 42, 251 LizSn03, neutron profile refinement, 45, 170 Li2Zr03, neutron profile refinement, 45, 170 Lij,,&,,7JP0.2504r crystal structure and ionic conductivity in tetrahedral structures, 44, 50 Li,VO* (0 < x 5 l), preparation, 42, 217 Lnl-zxBa2+tiZn2-,010-~ (Ln = La, Nd), preparation and characterization, 42, 176 MoJ+ in YVOI, substitutional off-center, ESR, 45, 93 NiO single crystals, experimental study of gases occluded within microscopic cavities, 41, 147 PbO,r,dLa,,os(Zr~.~~T~.~,).~~,03, piezoelectrical properties, comparison with PZT substitutes, 45, 164 Pb(ZrO,%ST&.&O1, pressure-temperature phase diagram, 43,285 rare-earth, electron beam-induced reduction, highresolution electron microscopy, 42, 47 TbO,, intermediate phases, structure, 41, 75 TiNb*O,, coordination of cations by Raman spectroscopy, 45, 276 vzo, Cr-doped, TEM observation of high-temperature transition, 45, 241 electrical transitions, 45, 1 VJ05, electrical transitions, 45, 1 V,,Oz,-, microsyntactic intergrowth, high-resolution electron microscopy, 43, 33 WOj . fHIO, powder form, wide-band proton NMR study, 45, 193 WI8049 crystal formation by gaseous reduction of WO1, 45, 324 defects and disorder introduced by partial oxidation, 45, 334 Oxygen BisTi2W0r4F, synthesis and X-ray diffraction, 44, 169 Bi7TiS020F, synthesis and X-ray diffraction, 44, 169
424
CUMULATIVE
Cu2Moj0i0 interaction, kinetics and mechanism, 44, 291 Fe-Mn-Ti-0 system, phase equilibria for composition Fer,297-M&.os7-T&.a-0, 43, 267 Fe-Nb-0 and Fe-W-O, structural and electronic relationships, 44, 113 Ge-W-O system near W09, phase analysis, 43,251 PbB&TiNbOsF, synthesis and X-ray diffraction, 44, 169 PbB&TiTaOsF, synthesis and X-ray diffraction, 44, 169 presence within microscopic cavities in single crystalline NiO, 41, 147 RbOs03N, crystal structure, 43, 29 tin-antimony-oxygen system, high-resolution electron microscopy, 44, 326 Oxyphosphate Fe4(P0&0, preparation and characterization, 42, 149 Oxysulfides HfOS, synthesis, 43, 225
P Palladium PdPSe single crystals, preparation and properties, 44, 382 Perovskites A:+B2+M:+09, (where A 2+= Ba, Sr; B2+ = Mn, CO, Ni, Zn; MS+ = Nb, Ta), order-disorder phenomena, 43, 51 HNbOJ, preparation from LiNbOr via ion exchange,
41, 308 HTaOr, preparation from LiTaOr via ion exchange,
41, 308 (La,-,Ca,)CoOr(O
5 X 5 0.6), magnetic properties,
41,329 Phase analysis of Ge-W-O system near WO,, 43,251 formation in Yb203-Cr203-MO and Yb203-Cr20jMO (M: Co, Ni, Cu, Zn) in air at high temperature, 43, 278 intermetallic, method for prediction, 42, 89 relationships in SrBr2-SrC12, 43, 271 Yb20s-Fe203-MO systems in air at high temperatures (M: Co, Ni, Cu, and Zn), 42, 22 Phase diagrams and magnetic properties of Cr,TiSe2 (0 < x < 1), 45, 411 Pb(Zro,%5Tia.0~s)Os,calorimetry and phase transition, 43, 285 Phase equilibria Fe-Mn-Ti-0 system for compositions FQ.~Mn,,.097-T&.m-0, 43,267 Phase transformation
SUBJECT INDEX pressure-induced black phosphorus to A,, orbital symmetry conservation analysis, 44, 415 Phase transitions Cs2-,Ki+,BiC& solid solution, 42, 130 in GaSe,+,S,, X-ray diffractometry, 41, 97 Phosphates (1 - x)AgPOx-xAg2S04 glasses, ionic conductivity and Raman spectroscopy, 45, 309 Phosphorus Ag16112P207rsingle-crystal growth and structure determination, 42, 183 black, pressure-induced phase transformation to A,, orbital symmetry conservation analysis, 44,415 CuO.sOCrO.sOPSz, structure and magnetic properties,
41, 174 KxP2W40i6, bronze with tunnel structure built up from PO4 tetrahedra and W06 octahedra, 44, 407 LiPN2, crystal chemistry, 43, 126 Lil.7sSi0.7sP0.2504,crystal structure and ionic conductivity in tetrahedral structures, 44, 50 PdWi003sr structure, 44, 318 PdPSe single crystals, preparation and properties, 44, 382 Photoelectric behavior Ge solid solubility in Fe2O3, 41, 90 Mg solid solubility in Fe203, 41, 90 Si solid solubility in Fe203, 41, 90 Photoelectrolysis water NiNb20e as photoanode, 44, 150 NiTiOS as photoanode, 44, 150 Photoluminescence and electroluminescence in graded cadmium sulfoselenide electrodes, applications to photoelectrochemical cells, 45, 51 Platinum Pb2Pb,Ru2-,0s+s support in hydrocarbon oxidation, 44, 108 Potassium Cs2-xKl+xBiC16, solid solution, phase transition, 42, 130 KMnC&, structure types and phase transformations, 43, 107 K2NiFctype oxides, relations between structure and physical properties, 44,82 &Nb40n, hydratation, 43, 346 Kag(IOrOH)2 . 8H2O, preparation and structure, 44, 201 KxP2W40i6, bronze with tunnel structure built up from PO4 tetrahedra and W06 octahedra, 44, 407 KPbCr2F9, structural and magnetic properties, 41, 272 KxP408(W0&,,,, electron microscopy, 43, 299 KVFJ, high-resolution electron microscopic study, 45, 259
CUMULATIVE KVOr . HzO, topotactic dehydration,
mechanism,
41, 205 Powder X-ray diffraction binary tungsten-oxygen system, phases in WO3W02, 41, 293 dehydrated magnesium formate, structure and characterization, 41, 67 Pyrochlores H2Ta206, neutron diffraction study, 41, 277 HTaW06, neutron diffraction study, 41, 277 HTaW06 . HrO, neutron diffraction study, 41, 277 PbrPb,Rur-,06+, support for Pt in hydrocarbon oxidation, 44, 108 -related phases in PbO-TazOS, 43, 131 (Re)ZVZ07 (Re = Yb, Tm), magnetic behavior, crystal field effects, 43, 175 TaWOr,r, neutron diffraction study, 41, 277 Pyrophosphate NaFePrO,, cage structure, 45, 389
R Raman spectroscopy and ionic conductivity in (1 - x)AgPOs-xAgrSO1 glasses, 45, 309 lanthanum molybdate, 42, 158 TiNbzO,, coordination of cations, 45, 276 and valence force field of GarOr, 45, 180 Rare-earth metal oxides Ln2Cu20s [Ln: Lu, Yb, Tm, Ho, Er, Tb, and Yl, crystal data, 42, 322 Ln(GaM2+)04 and Ln(AlMn2+)04, where Ln = Lu, Yb, Tm, Er, Ho, and Y, and M = Mg, Mn, Co, Cu, and Zn, preparation, 41, 166 Rare earth phosphates KCaLn(PO&, Nd3+, Eu3+, and Gdr+ ions as local probes, 43, 190 Na,Sr3-&z,(PO.&, Nd3+, Eu3+, and Gd3+ ions as local probes, 43, 190 Rhenium LtReOS, structure, 42, 251 L&ReO,, structure, 42, 251 ReO&ructured nonstoichiometric oxides, extended defect formation, 44, 174 Rhodium Rh-Ni alloys, thermodynamic properties, 45, 303 Rigidity MeX204 (Pb301, SnPbtOd, NiSb204, ZnSb,O,), thermal expansion, vibration, and neutron diffraction, 43, 12 Rubidium RbdNb40i7, hydratation, 43, 346 RbOsO,N, crystal structure, 43, 29 Rb,P40s(W03)~, electron microscopy, 43, 299 RbSbF2S04, synthesis and structure, 43, 81
425
SUBJECT INDEX
RbVF,, high-resolution electron microscopic study, 45,259 Ruthenium BaFei-,Ru,03-,, structure, 44, 366 Rutile relationship between CaFezOI and hollandite, 41,23 S Samarium SmWO,Cl, structure and luminescence, 45, 80 SCF MO calculation CrF$, quintet-triplet electronic transitions and nephelauxetic effects, 42, 28 Selenate vibrations, solid-state effects on, 43, 359 yttrium, vibrations, solid-state effects on, 43, 359 Selenides p-Ga2Se3, crystal structure, 43, 339 Selenium Cr,TiSet (0 < x < l), phase diagram and magnetic properties, 45,411 CuInSez-ZnSe-InzSe3, structure study, 45, 200 GaSei-,S,, polytype phase transition, 41, 97 PdPSe single crystals, preparation and properties, 44, 382 SbrSe, deposition of thin films, chemical methods, 44,425 Semiconductor -metal transition in mixed conductors, phenomenological model, 41, 333 SilenitesBi,,[A+,~~‘~,~Ora, AO, and B04 characterization by vibrational spectroscopy, 43, 45 Silica AgI-SiOr, enhanced ionic conduction, 42, 107 Li3,7SSit,7rP0.2504rcrystal structure and ionic conductivity in tetrahedral structures, 44, 50 NiA1204-Ni2Si04 at high pressures and temperatures, 44, 257 solid solubility in FeZO, and photoelectric behavior,
41, 90 Silver (1 - x)AgPOx-xAgzS04, ionic conductivity and Raman spectroscopy, 45, 309 Ag,IF.H*O crystal structure, A$ grouping, 42, 1 Ag&P207, single-crystal growth and structure determination, 42, 183 KSAg(IOSOH)2 . 8HrO inorganic complex, preparation and structure, 44, 201 Silver bromide AgI-AgBr, enhanced ionic conduction, 42, 107 Silver iodide AgI-AgBr, enhanced ionic conduction, 42, 107 AgI-A1203, enhanced ionic conduction, 42, 107 AgI-fly ash, enhanced ionic conduction, 42, 107 AgI-SiOr, enhanced ionic conduction, 42, 107
426
CUMULATIVE
Silver iodo-phosphate fast ion electrolytes, phase diagram and electrical characteristics, 42, 191 Silver oxalate thermal decomposition under nonisothermal conditions, effect of mechanical pretreatment, 41, 266 Sodium ions diffusion process in transition of bronze-type sodium titanium dioxide, 44, 337 Sodium titanium dioxide bronze-type, transition, diffusion of Na-ions, 44,337 Solids covalent amorphous, normal structural bonding and defects, 45, 40 electron states by electron spectroscopy, 45, 14 Solid solubility Ge in Fe203 and photoelectric behavior, 41, 90 Mg in Fe20, and photoelectric behavior, 41, 90 Si in Fe203 and photoelectric behavior, 41, 90 Spinels A&O4 close-packed oxides, structural relationships, 45, 280 Fe3-,Cr,04, heat capacity, 41, 213 N?+ ion effect on MgZ+ and Cu2+ ion distribution, 41, 63 Strontium La&r0.16Mn09, structure and electrical conductivity, 42, 125 SrBrr-SK&, phase relationships, 43, 271 SrLaTh(VO&, dimorphism, 45, 135 SrMg,, and SrM&, structural relationship, 41, 111 Strontium titanate with nonideal cationic ratio, electrical conductivity, 42, 227 Structure maps transition metal-main group MX and MX, compounds, electronic influences on crystal chemistry, 45, 399 Sulfates (1 - x)AgPO,-xAg2SOd glasses, ionic conductivity and Raman spectroscopy, 45, 309 MSbF2S04 (M = Rb, Cs), synthesis and structure, 43,81 Sulfides SnS-BaS, rr9Sn Miissbauer spectroscopy, 41, 50 SnS-T&S, ‘19Sn Miissbauer spectroscopy, 41, 50 Sulfur
Bal+,Fe2S4 Mossbauer spectra, magnetic and electrical behavior, 41, 124 phase relationship, 41, 114 Ba2Fe&, crystal structure, two-dimensional array of Fe& tetrahedra, 41, 104 CdHo& transition from spine&type structure to rocksah-type structure, electron microscopy/
SUBJECT INDEX diffraction, 42, 11 Cu,,.&rO.sOPS1, structure and magnetic properties, 41, 174 GaSei-,S,, polytype phase transition, 41, 97 Li-Fe-S system, conductivities and electronic structures of phases, 43, 163 T Tantalum Cu~TatIO~O, structure, 41, 286 PbO-TaZOZ, pyrochlore-related phases, 43, 131 selenide system, 41, 323 Ta-AI-C, structural chemistry, 44, 126 Tantalum sulfide intercalation phases with ethylenediamine, crystal chemical and thermogravimetric study, 45, 119 trimethylenediamine, crystal chemical and thermogravimetric study, 45, 119 Ta20S-WO, and Nb20J-W03 systems, crystallographic shear, 44,60 Technetium phosphides preparation and crystal structure, 44, 134 Tellurium Pb-Sn-Te system, lattice matching and thermal expansion, 43, 364 Tl-Bi-Te, phase transformations, electrical resistivity and thermoelectric measurements, 45,99 TIMnQ, structure types and phase transformations, 43, 107 Terbium (TbS)lTe,+., order-disorder phenomena, 45, 140, 146 Terbium oxides intermediate phases, structure, 41, 75 Tetrakisammonialithium electron-electron interactions in expanded metal compounds, 45,63 Tetrakismethylaminelithium electron-electron interactions, 45, 63 Tetrametaphosphate tellurate (NH&P40n. 2Te(OH)6 . 2Hz0, 41, 153 Thallium Tl-Bi-Te, phase transformation, electrical resistivity and thermoelectric measurements, 45, 99 TlVFs, high-resolution electron microscopic study, 45, 259 Thermal depolarization, see also Ionic thermoconductivity in ammonium chloride crystals, 44, 388 effect of HCl and NHs, 44, 399 Thermal expansion Pb-Sn-Te system, lattice matching, 43, 364 ThermoditTerential analysis dehydrated magnesium formate, structure and characterization, 41, 67
CUMULATIVE Thermogravimetry dehydrated magnesium formate, structure and characterization, 41, 67 Thorium MrrLaTh(VO&, (M = Sr, Pb), dimorphism, 45, 135 Thulium phenomena, 45, 140, (TmSM’e~+,, order-disorder 146 Tin LiFeSnO,, structural relationships in close-packed A&O4 oxides, 45, 280 LirSnO,, neutron profile refinement, 45, 170 (Ni,+,Co,),MnSn, ferromagnetic and paramagnetic properties, 43, 354 Pb-Sn-Te system, lattice matching and thermal expansion, 43, 364 tin-antimony-oxygen system, high-resolution electron microscopy, 44, 326 Titanates CaTiO,, electrical conductivity, 41, 185 Titanium BiSTi2W0r4F, synthesis and X-ray diffraction, 44, 169 Bi7TiS0r0F2, synthesis and X-ray diffraction 44, 169 Cr,TiSel (0 < x < 1), phase diagram and magnetic properties, 45,411 doping, effect on V203 crystal structure, 44, 192 Fe-Mn-Ti-0 system, phase equihbria for composition Fe,,29,-Mn0.0s,-Ti0.~-0, 43, 267 La@-,TiOr, magnetic behavior, 43, 204 La,Y, -ITiOj, magnetic behavior, 43, 244 PbBirTiNbOaF, synthesis and X-ray diffraction, 44, 169 PbBi2TiTaOsF, synthesis and X-ray diffraction, 44, 169 Pb~.94Lao.os(Zro.J8Ti~.~~)~,~*~O~, piezoelectrical properties, comparison with PZT substitutes, 45, 164 Pb(Zro.%sTi,,ops)Oj, pressure-temperature phase diagram, 43,285 Ti-Al-C, structural chemistry, 44, 126 TiNb*O,, coordination of cations by Raman spectroscopy, 45, 276 TiP04, preparation, magnetic properties, 45, 252 Ti&, XPS study of one-dimensional compounds, 44, 268 Titanium dioxide Raman spectra, 42, 276 Titanium oxide Ti.O+, (4H), magneli phases, cell and structure comparison, 43, 314 TinOzml, 4 5 n 5 9, refinements and structure, 44, 273
SUBJECT INDEX
427
Titanium sulfide intercalation phases with ethylenediamine crystal chemical and thermogravimetric study, 45, 119 trimethylenediamine, crystal chemical and thermogravimetric study, 45, 119 Transition metal -main group metal alloys, electronic influences on crystal chemistry, 45, 399 “pentagonal column” as building unit in crystal and defect structures, 44, 32 Transmission electron microscopy Ba-doped Ni-Zn-Co ferrites, 44, 208 Vz03. nonstoichiometry and defects, 44, 230 V90r7, nonstoichiometry and defects, 44, 212 Trichalcogenides NbS,, high-pressure synthesis, 41, 315 NbSes with NbSe3-type crystal structure, high-pressure synthesis, 41, 315 TaSr, high-pressure synthesis, 41, 315 TaSe,, high-pressure synthesis, 41, 315 Trihalides crystal chemistry, lone pair, stereochemistry, and structural relationships, 44, 1 Va elements, lone pair, stereochemistry, and structural relationships, 44, 1 Trimethylenediamine intercalation in 2H-NbSr, crystal chemical and thermogravimetric study, 45, 119 intercalation in IT-TaSr, crystal chemical and thermogravimetric study, 45, 119 intercalation in TiS2, crystal and chemical thermogravimetric study, 45, 119 Tungstates Bir-,La,WOs, structure, 41, 138 Bi2W06, polymorphism, 41, 160 orthorhombic rare earth (Ln = La, Sm), structure and luminescence, 45, 80 Tungsten AjB(P-tungsten) alloy, multiple metal-metal bonding and A-chain integrity, 45, 353 Fe-Nb-0 and Fe-W-O, structural and electronic relationships, 44, 113 Ge-W-O system near WO1, phase analysis, 43,251 KxPrW40r6, bronze with tunnel structure built up from PO4 tetrahedra and W06 octahedra, 44, 407 LarWO&-U, luminescence properties, 44, 162 P4Wr00r8, structure, 44, 318 W18049 defects and disorder introduced by partial oxidation, 45, 334 electron microscopy, crystal formation by gaseous reduction of WOx, 45,324 Tungsten bronzes Vegard relationships, 41, 227
428
CUMULATIVE
Tungsten oxides P4Wr003s, structure, 44, 318 Tungsten-oxygen phases in W09-W02, electron microscopy and powder X-ray diffraction, 41, 293 Tungstophosphates AxP40a(W0&,,, (A = K, Rb), electron microscopy, 43,299 Tveitite crystal structure, 44, 75 U
Uranium -activated La3W06Cl,, luminescence properties, 44, 162 crystallographic parameters by multiphase refinement of high-resolution neutron powder data a-US, 45, 396 UzF,, crystallographic parameters by multiphase refinement of high-resolution neutron powder data, 45, 3% V Valence bands electron spectroscopy of solids, 45, 14 Vanadates KV09 . HzO, topotactic dehydration, mechanism, 41,205 PbLaTh(VO&, dimorphism, 45, 135 SrLaTh(VO&, dimorphism, 45, 135 Vanadium Fe-substituted V60u, preparation and properties, 42, 212 Li,V02 (0 < x 5 1), preparation, 42, 217 MO’+ in YV04, substitutional off-center, ESR, 45, 93 PbO-VZOI, equimolar system, new phases, 43, 63 V-.41-C, structural chemistry, 44, 126 VP04, preparation, magnetic properties, 45, 252 V203, Cr-doped, TEM observation of high-temperature transition, 45, 241 V30s, electrical transitions, 45, 1 V,,OZ.-, microsyntactic intergrowth, high resolution electron microscopy, 43, 33 Vanadium fluoride bronzes A,VFj (A = K, Rb, Cs, Tl), high-resolution electron microscopic study, 45, 259 Vanadium oxide v203
effect of Cr doping, 44, 192 effect of Ti doping, 44, 192 nonstoichiometry and defects, 44, 230 V204, oxidized surface state model and application to catalysis, 42, 263
SUBJECT INDEX V205, oxidized surface state model and application to catalysis, 42, 263 V60r3, oxidized surface state model and application to catalysis, 42, 263 v9017
nonstoichiometry and defects, 44, 212 Vanadium sulfides M,VS2 (M = Fe, Co, Ni), structure and electronic properties, 44, 119 Vanadyl sulfate hydrates VOSO., . 2H20, thermal dehydration and structural model, 45, 112 VOS04 . 3H20, thermal dehydration and structural model, 45, 112 Vibration MeX20d (Pb304, SnPb204, NiSb204, ZnSb204), thermal expansion, rigidity, and neutron diffraction, 43, 12 Vibrational spectroscopy Bi,2[,$j~1&$020, A04 and B04 characterization, 43, 45 W Weberite Na,MgAlF,, space group analysis, 43, 213 Wolfram W09 . fH20, powder form, wide-band proton NMR study, 45, 193 Wurtzite derivatives and related dipolar tetrahedral structures, 42, 300 derivatives with unit cells having composition ABX2, AB2X3, A&X4. or Al?CzX4, enumeration and related dipolar tetrahedral structures, 42, 283 X X-Ray diffraction BiSTi2WO14F, synthesis, 44, 169 Bi,TiT02,,F, synthesis, 44, 169 GaSe,-,S,, phase transition, 41, 97 PbBi2TiNbOsF, synthesis, 44, 169 PbBhTiTaOsF, synthesis, 44, 169 X-Ray photoelectron spectroscopy Ti&, 44, 268 Y Ytterbium CsYbjF,O, crystal structure, isotype composition, 42,80 Ytterbium oxide Yb20g-Fe20g-MO systems (M: Co, Ni, Cu, and Zn), phase relations in air at high temperatures, 42, 22
CUMULATIVE Yb203-Ga203-MO and Yb203-Cr~O&f0 (M: Co, Ni, Cu, and Zn), phase formation in air at high temperature, 43, 278 Yttrium CaLa,-,Y,Cr04 (0 5 x 5 l), structural and magnetic study, 42, 75 Cai4YSFe, crystal structure, 44, 75 La,Y,-,TiOS, magnetic behavior, 43, 244 MO’+ in YVOI, substitutional off-center ion, ESR, 45,93 Y2Mo06 : Eu3+, spectroscopic properties, 43,87 (YS);Te,+,, order-disorder phenomena, 45,140, 146 2 Zeolites &B,Cm-x02, . nHZO (B = Al, Ga, C = Si, Ge), structure by high-resolution microscopy, 45, 368 A&A13Si30nI, formation, 42, 328 network, constituent units and framework conformations, 44, 41 Zeolites A dehydrated Na zeolite A (WA1 = 1.09), structure by neutron profile refinement, 44, 245
SUBJECT INDEX
429
zinc Ba;lZn3P100m, crystal structure, 45, 159 CuInSez-ZnSe-In,Se3, structure study, 45, 200 Ge02-ZnO-Fe203, system at lOOO’C, 44,426 Li2+&Zn1-,Ge04, ionic conductivity of LISICON solid solutions, 44, 354 Lnd-tiBaZ+LrZn2-x010-zr (Ln = La, Nd), preparation and characterization, 42, 176 Ni-Zn-Co Ba-doped ferrites, transmission electron microscopy, 44, 208 ZnNbS, crystallochemistry and spectroscopy, 43, 327 Zinc oxide CuO-ZnO-A&03, reduction processes in low-temperature methanol synthesis, 42, 120 Yb203-Fe203-ZnO, phase relations in air at high temperatures, 42, 22 Zirconium LizZr03, neutron profile refinement, 45, 170 Pbo.~L~.m(Zr~,,,T~.~~)~.~~O~, piezoelectrical properties, comparison with PZT substitutes, 45, 164 Pb(Zr,,w~T&.03s)0,, pressure-temperature phase diagram, 43,285 Zr-AI-C, structural chemistry, 44, 126