KEYWORD INDEX ABW, 149 Acidity, 54,397 Acid strength, 59,7 10 Activation energy, 12 Additives, 169 Adsorption, 98,345,380,684,798,832 Adsorption of organic molecules on HNaZSM-5 zeolite, 35 Adsorption under elevated pressures, 846 AEI, 654 AFI, 438 “Al and ‘HMAS n.m.r., 491 “Al MAS n.m.r., 549 “AI n.m.r., 583 AINaZSM-5 zeolite, 497 AINaZSM-5 zeolites, 49 1 AIPO,-14A, 477 AlPOd-16, 502 AlPOd- 18,654 A1P04-5, 380,401 AIP04-5 synthesis, 443 A1P04-8, 534,583 AlPOd dense phases, 142 AIZSM-5,837 Al-free ZSM-5,318 Alkali cations, 202 Alkali glass corrosion, 758 Alkali metal cocations, 854 Alkylation, 59, 169,254 Aluminophosphate, 477,502 Aluminophosphate molecular sieve, 37 I Aluminophosphate synthesis, 308,460,654 Aluminosilicate gel, 767 Aluminum-alkanolamine chelate, 178 Aluminum distributions, 329 Aluminum location, 376 Aluminum phosphate, 401 Ambient temperature, 48 Ammonia pretreatment, 854 Analcime, 164 Analytical electron microscopy, 472 Argon adsorption, 27 Aromatics, 380,699 Asbestos-derived zeolite, 804 Assessment of Bronsted acidity, 850 Atomic force microscopy, 429 Autocatalytic nucleation, 776 4A zeolite, 846 Beckmann rearrangement, 593 Benzene, 434,666,699 Benzene hydrogenation, 12,483 Beryllium phosphate, 364 Beta, 202,792 Binary adsorption, 3 14 Boron, 371 Breakthrough curves, 3 14 Bromination, 617 Briinsted acidity, 85,607 Briinsted acid site, 827 Bronsted sites, 293 l- and 2- butanol, 73 P-butyne, 684
Volume
II
Calorimetric heat of adsorption, 742 Cancrinite, 248 Catalytic, 617 Catalytic sites, 325 Cation location, 270 Cation migration, 239 Cation mobility, 265 Cation site, 376 Cation solvation, 507 CeS+ exchange, 2 Cesium, 248 Chabazite, 742,758 Characterization, 2,477,854 Chemical properties, 767 Clathrate, 502 “C n.m.r., 418 CO adsorption, 497 Cobalt silicoaluminophosphate, 192 Coke, 483 Coke deposition, 337 Coking, 103 Competitive sorption, 699 Compositional analyses, 277 Compositional heterogeneity, 472 Computer simulation, 337 Coordination, 155 Copper, 155,449 CoSAPO-34, I92 “C CP-MAS n.m.r., 69, 107,573 Cracking, 745 Critical phenomena for adsorbate, 846 Crystal dimensions, 443 Crystal growth, 539,776,792 Crystallinity, 54,466 Crystallite size variation, 5 11 Crystallization, 142,720,758 Crystal orientation, 816 Crystal size, 202 Crystal-size distribution, 792 Crystal structure, 124,622 CSZ- I,27 CsZSM-5,376 Cu’+-ZSM-5,77 Cubic, 98 Cu crystallite size, 854 Cu-e.s.r., 184 CuY, 854 Cyclohexanone oxime, 593 DBDMA ion, 69 Deactivation, 337 Dealuminated faujasites, 314 Dealuminated Y zeolites, 360 Dealuminated zeolites, 391 Dealuminated ZSM-5 zeolite, 85 Dealumination, 116,232 Defects, 598 Dehydration, 287 Dense systems, 52 1 Deposition, 356 Desorption and conversion of acetone diethyl ketone, 822 Dielectric relaxation, 517
Diethylbenzene, 59 Diffuse reflectance spectroscopy, 155 Diffusion, 337,380,647,666,684 Diffusion anisotropy, 816 Diffusion rates, 699 Di-n-propylamine, 460 Dissolution, 258,810 DRIFT spectroscopy, 694 Dynamic behavior, 434 Dynamics of occluded organic material, s-caprolactam, 593 Electric fields, 368 Electron microscopy, 466 Electron spin resonance, 155 Electrostatic-field gradient, 607 ENDOR, 282 Erionite, 8 1,694,758 ESCA, 77 E.s.r., 282 E.s.r. of supported molybdenum Ethylbenzene, 59,647 EXAFS, 662 Extraframework debris, 391 FALJ, 27 Faujasite, 98,429,607 Fe-mordenite zeolite synthesis, Ferrisilicate, 2 14 Ferrisilicate Beta zeolite, 2 1 1 Ferrisilicate ZSM- 11,553 Fe-ZSM-22.7 10 Film, 842 Fluoride ions, 732 Framework Fe (III), 214 Framework geometry, 622 Framework modeling method, Frequency response, 666,684 F7i.r.. 293,401 FTi.r. spectroscopy, 694 FT-i.r. study, 48
4 18
sulfides,
I8
42
502
Gallosilicate-MFI, 827 Gas chromatography, 784 Gaseous products, 822 Gel aging, 539 Gel chemistry, 142 Gel composition, 443 Germanium, 662 Gmelinite, 164
and
ZEOLITES,
Halide aluminosilicate sodalites, 622 HBeta, 391 Heat treatment of coke from acetone, Heterogeneity, 739 Heterogeneous nucleation, 539 Highly siliceous MFI zeolites, 598 High-silica zeolites, 438.573.633 HNaY, 593 ‘H n.m.r., 418 HSZM-5,837 HY, 391 Hydrogen bonding, 739
1991, Vol 11, November/December
I35
665
index Molecular dynamics, 4 I8 Molecular mechanics, 434 Molecular sieve, 563 Molecular sieves, 466,472,612 Molecular sieve synthesis, 477 Molybdenum, 54 Molybdenum-loaded Y-zeolites, Mordenite, 155,607, 745 Morphology, 745,842 Mossbauer spectroscopy, 2 I4 Mossbauer studies, 2 1 I
Hydrophobic zeolites, 3 14 Hydrothermal crystallization, I I6 Hydrothermal stability, 223,549 Hydroxyl groups, 293 HY zeolites, 850 HZSM-5,73,699,837 HZSM-5 zeolite, 822 HZSM-5 zeolites, 132 Impregnation, 2 Infrared, 85 Infrared spectroscopy, I I6 Initial breeding, 318 Interaction complexes, 48 Intergrowth formation, 356 Intermediates, 483 Ion exchange, 116,329,401 Ionic conductivity, 81 I.r., 73,98, 349 1.r. microscopy, 454 Iron coordination, 214 Iron silicates, 42,466,472 1.r. spectra, 491,497 1.r. spectroscopy, 35,397.739 Isomeric butenes, 73 Isomorphous substitution, 690 Isomorphous substitution by Fe, 42 Isomorphous substitution in MEL topology, 553 Isotropic chemical shifts, 622 Isotypes, 438 K-, Rb-, Cs-exchanged NaX zeolite, Ketones on ZSM-5 zeolites, 48 Kinetics, 12,258,539,8 IO KX, 254 KZSM-5,254 Lewis acidic sites, 132 Lewis acidity, 85 Lewis sites, 282 ‘Li, ‘“Na, and “AI MAS n.m.r. satellite transitions, 622 Linde 5A, 5 I7 Linde Q, I24 Liquid phase, 6 I7 Lithium, 248,371 Ludox, 672
Magic-angle spinning n.m.r., 827 MAS n.m.r., 223 MAS n.m.r. spectroscopy, 116, 124 Mass spectrometry, 784 MCM-S/VPI-5,583 Mechanism, 258,810 Mechanisms, 483 Metallosilicate, 59 Methane, 8 16 Methanol, 254 Methanol conversion, 337,5 I 1 2-Methylthiophene from 2-methylfuran, MFI-type, 662 MFI-type zeolites, 107, 784 Micropore filling, 345 Microporous aluminophosphate, 443 Microstructure, 466 Mild dealumination, 132 Model, 563,720
866
ZEOLITES,
18 Quadrupolar Quinones, Quinuclidine
Octahedral Al, 308 Offretite, 8I OH characterization, 39 1 OH group, 387 OH groups, 739 Order/disorder. 558 Organic base, 142 Organic template, 612 Orientational disorder of guest atoms sodalite cage, 558
of
64
in
Pahasapaite, 364 Paraffin cracking, 132 Prim-selectivity, 59, 169 jr-bromotoluene, 6 17 pH, 142,401 Phase transition, 729 Phillipsite, 680, 758 Photoemission, 694 “P n.m.r., 583 Polarized Raman spectra, 387 Positron annihilation spectroscopy, 607 Powder X-ray diffraction, 360,376 Precursors, 539 Preparation, 842 Prismatic and cube-shaped single crystals, 184 Propan-2-01 dehydration, 850
1991, Vol 17, November/December
coupling
parameters,
template,
502
622
282
Radical cations, 282 Raman, 672 Raman spectra, 349 Raman spectroscopy, 694 Rare-earth zeolites, 239 Rate maxima, I2 Reaction orders, I2 Reaction with ammonia, 244 Realumination, 232 Reduction, 54 Relaxation domain separation, 517 RHO, 364 Rietveld refinement, 308,438,502,654
(Na,K)-system, 758 Na and CaA zeolites, 804 NaHA zeolite, 739 NalK system, 577 NaX, 666 NaX zeolite catalyst, 64 NaY zeolite, 265 N-Brand, 672 n-butane, 684 Neutron diffraction, 832 ?I-hexane cracking, 325 NiAPO-12,612 NiAPO-21,612 Nickel, 54 Nickel metal crystallites, 2 Ni(I1) coordination, 612 NiKY, 12,483 N.i.r., 837 Nitrite sodalite, 558 Nitrogen, 846 NiY, 2 N.m.r., 265.401.837 Nonalkaline fluoride media, 798 Noncompetitive adsorption, 483 Nonframework alumina species, 360 Nucleation kinetics, 776 Nutation, 265
287
spectra
Propene and methanol transformation, 491 Propylammonium templates, 107,784 Pulsed-field gradient (p.f.g.) n.m.r., 816 Pulse-field gradient n.m.r., 103 Pyridine, 85 Pyrrolidine, 573
SAPO-37,563 SAXS, 449 Scolecite, 429 Selectivity, 617 Self-bonded pellets, 52 I SEM, 401 ‘“Si, s3Na MAS n.m.r., 558 Side reactions, 169 Silanols, 391 Silicalite, 356,647 Silicalite- 1,684,699 Silicalite-2,699.732 Silicalite-I, 666 Silica molecular sieves, 438 Siliceous MFI zeolite, 729 Silicon, 37 I “Si MAS n.m.r., 563,598 Si-MAS-n.m.r., 184 Single crystals, 37 1 Siting, 155 Sodium-23,265 Solid-state n.m.r., 98, 729 Sorption equilibrium, 699 Sorption properties, 5I 1 SSZ-24,438 Stacking faults, 8 1 Steaming, 325 Stilbite, 429 STM, 306 Structural defects, 81 Structure, 149, 192,248,438,767 Structure determination, 654 Surface complexes, 822 Surfaces, 429 Surface species from acetone on HZSM-5, 244 Synchrotron radiation, 308 Synchrotron X-ray powder diffraction, 502 Synthesis, 149, 184,202,248,349,371,438, 539,633,745,758,792 Synthesis mechanism, 672 Synthesis of aluminophosphate, 142 Synthesis of hexagonal, 98
Index Synthesis of SAPO-5,277 Synthesis-structure relationships, Synthesis with seeds, 577
Tailoring, 443 Temperature-programmed desorption, Template decomposition in HZSM-5,454 Templates, 633 Tetraethylammonium. 705 Tetramethylammonium, 705 Thallium, 149,248 Thermal decomposition. 107,784 Thermal properties, 767 Thermal stability, 680, 745 Thiophene hydrodesulfurization, 18 Toluene, 169.254,434,699 Toluene methylation and disproportionation. 5I 1 Topology, 563 Toxicity tests, 804 Transformation. 583 US-Ex, 223 USY, 549 Vacancy, 232 VPI-5,308,534 Water, 293,401 Water/ethanol separation, Water-gas shift, I8
3 I4
Water location, Water-retention Water structure,
460
827
270 capacity 308
in soil, 804
XANES, 662 ‘*“Xe n.m.r., 27, 103,239,368,534 XPS, 77,710 X-ray diffraction, 40 I, 729 X-ray powder diffraction Rietveld crystal structure analysis, 558 X-ray single-crystal diffraction, 364 X-ray single-crystal structure, 287 X-ray structure refinements, 622 XRD, 270 XRD line broadening, 2,854 Xylene, 647,699 X-zeolite. 720 Y-type zeolite, Y zeolite, 345
54
Zeolite, 254, 306.449.5 17,617,842 Zeolite A, 258 Zeolite A synthesis, 577 Zeolite crystallization, 178, 3 18 Zeolite crystals, 429 Zeolite EU- I,69 Zeolite HY, 293 Zeolitelike structure, 502 Zeolite mordenite, 42 Zeolite NaA, I78
ZEOLITES,
Zeolite NaY, 832 Zeolite nucleation, 507 Zeolite-organic interactions, 4 18 Zeolite Phi, 349 Zeolite rehydration, 239 Zeolite rho, 364 Zeolites, 103, 135, 149,248,593,662, 742 Zeolite single crystals, 454 Zeolite surface, 77 Zeolite synthesis, 4 18,798 Zeolite T, 8 1,758 Zeolite TON, 539 Zeolite X, 8 10 Zeolite Y, 232 Zeolite ZSM-5,59 Zeolitic phase transformation, 164 Zirconium molecular sieves, 690 Zirconium silicates, 690 [Zr]-ZSM-5,690 ZSM- 11,368 ZSM-20,345 ZSM-22,710 ZSM-39,387 ZSM-48,732 ZSM-5, 169, 184,270,325,329,337,356, 368,434,52 1,593,666,705,8 16,842 ZSM-5 synthesis, 5 1 I ZSM-5-type zeolite, 54 ZSM-5 zeolite, 776 ZSM-5 zeolites, 397
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