Subject index to volume 2, 1972–1973

Subject IndextoVolume2,1!I72-1973 Acetate biosynthesis, corrin dependent, 93 Acid catalysis, of solvolysis of cupric ion displacement of a Zn-porphyrin, 281 Aging, of hydroxy-iron (III) polymers, 295 Albumin, Co(II) binding, 149 Alkylcobalamii. aikylcobaioximes, reductive deaikyiation of, 93,211 _ Analogs, of fen-it& cores, 295 Antitumor agents, platinum (II) complexes as, 137 Arsine, methylation by methylcobalomin and -cobaloxime, 93 Aspartic acid, interactions with =Wa+, 69 Aspergi&s fumigotus, ferricrocinof, 159 Autoreduction, in ferric fructose system, 311 Biological potency, of organic selenium compounds, 47 l3is-&methylglyoximatocobalt complexes; see cobaioximes 3-bromo&-tyrosine, in serum proteins, 167

Dietary depletion, of copper and zinc, effect on intestinal absorption, 255 N-Dihydrolipoylamin~tho~d~~~n, 135 Dihydroxyacetone phosphate, 75 Divaient cations, in r&anumlose-l-phosphate aidoiake activity, 75

i E!lectron p aratkgnetic resonancespectrum of copper(H) complexes in glycyiglycine crystals, 341 Energy transfer, between .iovaiently iinked metal porphyrins, 1 Enzyme dith&l criteria, 135 Europium(III), binding of, in yeast inorganic pyrophospbkses, 37 Ferric fructose system, 311 Ferritin cores, analogs of, 295 Ferricroein, structure of, 159 Glycylglycine crystals, complexes, 341

EPR

of

copper(n)

Cadmium, binding by N-dihydrolipoylaminoethoxydextran, 135 Cadmium complexes, of NTA, %3; exchangeable Iigands of, in human serum, I25 Cancer test, chemical interpretation, 329 Cataiysis, of hydrolysis of glycinates by Hgffchelates, 275 Cations, role in enzymic activity of L-rbamuiose l-phosphate aldolase, 7.5 chloro-(a ,$7* ,r8 tetraphenylchlorin)manganese(III), 231 Citric acid, SNa NMR studies with, 69 Cobalamins, 93,211 Cobaloximes, 93,211 Cobalt(H), binding by plasma proteins, 149 Complex formation, in ferric fNCtOS? system, 311 Copper, intestinal absorption, 255 Corrin dependent methyl group transfer reactions, 93 Cysteine, %a NMR studies with, 69

~rhamnulose-l-phosphate aidoiase from E. coli, divaieut cations in, 75 Lipoic acid, in Cd* and As+’ binding, 135

Dealkylation, reductive, of alkylcobalamins and aihylcobaioximes, 93; 211

Manganese porphyrin complexes, 231 Mercury(I1) cheiates, specific catalysis by, 275

363

Human plasma, or serum, -3-bromo-r=tyrosine in, 167; -Co* binding by, 149; exchsng+ abie copper, zinc and cadmium in, 125; selenium, cancer test, 329 Imidazole, association with tetraphenylporphyrin-Fe(III)-chloride, 263 Inorganic pyrophosphatases, of yeast, binding of E+, 87 Interpretation of a piasma cancer test, 329 Intestinal absorption, of copper and zinc, 255 Ion displacement reactions, of a zinc porphyrin, 281 Iron transport or storage compounds, 159, 295 Iron fructose system, 159

364

SUBJEET

INDEX

bietal complexes, group VIII, antitumor actitity, 187 Methane biosynthesis, 93,211 Methylamine bimthesis, 93 MethykeIenide biosynthesis, 93 Model compounds, of dithioi enzymeq 135; of ferritin cores, 295; of vitamin Bc, 93,211 X-dihydrolipoylaminoethoxydextran, 135 Nitrophenylcarboalkoxyglycinates, hydrolysis catalyzed by Hg++, 275 Organocobalt complexes, 93,211 OrganoseIenium compounds, bioIogical potenq- of, 47, 171

TO VOLUME

2, 1972-1973

Ribonucleotide reductase, corrin dependent, simulation of, 93 Rhamnulase, see I‘-rhamnulose Selenacarboqlic acids, acid amides, and related compounds, 47,171 Selenium, binding proteins in tissuesof normal and seIenium responsive myopathic lambs, 33; biopotency of organic compounds of 47, 171 Selenium and cancer, 329 Serum, see human plasma and serum Siderochromes, 159 Solvolysis, acid catalyzed, of a zinc porphyrin, 281 Sfrepfomycesgnkeus, ferricrocin from, 159

Plasma, see human plasma PIatinum complexes, antitumor activity, 187 Pol_ymerization,in the ferric fructose system, 311 Porphyrins, energy transfer between covalently linked, 1; of copper and zinc, 281; of Mn(III), 231 Proteins, Co* binding, in plasma, 149; selenium binding, 33 Potency of organic selenium compounds, 47, 171 Pyrophosphateses of yeast, Eu’3 binding by, 87

Vitamin Bn, xe cobalamins

Pats, intestinal absorption of copper and zinc, 2zi Reducti\-e dealkylation, of organocobalt compounds, 93,211

Zinc, intestinal absorption after dietary depletion, 255; and macromolecular ligands in human serum, 125; metalloenzyme, 75; w-&-r@ 231

Tetraphenylporphyrin iron(II1) chloride, association with imidazole, 263 T&sues, selenium binding proteins, of lambs, 33 Transfer, of energy, between covalently linked metal porphyrins, 1 Transfer reactions, of methyl group, 93 Transition metal complexes: antitumor activity of, 187