Suject index of volume 454

Journal of Organometallic

Chemistry,

454 (1993) C29-C32

C29

Subject Index of Volume 454

AIuminium Synthesis and molecular structure of AIMe[O=C(OMe)C,H,-o-01,. The first structurally characterized five-coordinated simple alkyaluminium chelate complex (J. Lewinski, J. Zachara, B. Mahk and S. Pasynkiewicz), 5 Dialan-Radikalanionen [R,Al-AIR,] - (W. Uhl, A. Vester, W. Kaim und J. Popped, 9

Antimony On tertiary stibine. 1. Reaction of w-bromoacetophenone hydes mediated by diphenylantimonyorganometallic J. Zhang and Y.-Z. Huangl, 101

with aldereagents CL.-

Chromium a-Addition von Aminen, Iminen und Hydrazinen an AllenylidenKomplexe - Bildung von Carben-, Azetidinylidenund NitrilKomplexen (H. Fischer, G. Roth, D. Reindl und C. Troll), 133 Dimethylencyclobuten als Komplexligand. Synthese und Struktur von Tricarbonyl(n’-diisopropylidencyclobutenlchrom und Bis(n’-dimethylencyclobutenXn’-indenylhhodium (D. Rau und U. Behrens), 151

(CO),(dppeXEMe,XSiR,) und Fe(COXdppe)Hz(EMe,XSiR,) (E = Sn, Pb) aus den korrespondierenden anionischen Komplexen (Il. Schubert, S. Gilbert und M. Knorr), 79 Substituted metal carbonyls. XXII. Synthesis of l,l’-bis(diphenylphosphinolferrocene-bridged complexes with two heterometallic Au-M (M = Mn and Re) bonds (P.M.N. Low, Y.K. Yan, H.S.O. Chan and T.S.A. Her), 205 The use of high reaction pressures in the synthesis of acetylide complexes of iron (L.D. Field and A.V. George), 217 Studies on binuclear complexes. Synthesis and catalytic behaviour of Fe-M complexes (M = MO, Ni, Rh, Cu, Hg) using transFe(Ph,Ppy)z(CO), [PhzPpy = 2-(diphenylphosphino)pyridine] as a neutral tridentate ligand. Molecular structure of FeHg(gPh,Ppy),(CO),(SCN), (Z.-Z. Zhang, H.-P. Xi, W.-J. Zhao, K.-Y. Jiang, R.-J. Wang, H.-G. Wang and Y. Wu), 221 Synthesis and molecular structures of SzFe,(CO), heterometallic derivatives, containing (Ph,P),Pt or CpRe(C0) fragments (A.A. Pasynskii, B.1. Kolobkov, S.E. Nefedov, I.L. Eremenko, E.S. Koltun, A.I. Yanovsky and Y.T. Struchkov), 229 The use of [(C,H,)Fe(CO),]+ as a recoverable protecting group in peptide synthesis (S. Fu, J.A. Carver and L.A.P. Kane-Maguire), Cl1

Lead

Cobalt Bidentate ligand substitution in PhCCo,(CO),. Synthesis, molecular structure, and redox reactivity of PhCCo,(CO),(cis-Ph,PCH=CHPPh,) (K. Yang, S.G. Bott and M.G. Richmond), 273

Copper Studies on binuclear complexes. Synthesis and catalytic behaviour of Fe-M complexes (M = MO, Ni, Rh, Cu, Hg) using transFe(PhzPpy)z(CO), [PhzPpy = 2-(diphenylphosphino)pyridine] as a neutral tridentate ligand. Molecular structure of FeHg&PhzPpy)z(COl&SCN), (Z-Z. Zhang, H.-P. Xi, W.-J. Zhao, K.-Y. Jiang, R.-J. Wang, H.-G. Wang and Y. Wu), 221

Ubergangsmetall-Silyl-Komplexe. XLVII. Deprotonierung der elektronenreichen Hydrido-SilylKomplexe Fe(CO),(dppe)(HXSiR,) und Fe(CO)(dppe)H,(SiR,); Darstellung der Komplexe Fe(CO)z(dppeXEMe,XSiR,) und Fe(COXdppe)H,(EMe3XSiR,) (E = Sn, Pb) aus den korrespondierenden anionischen Komplexen (U. Schubert, S. Gilbert und M. Knorr), 79

Lutetium Metalcarbonylates of lanthanides. Unexpected formation of the trinuclear cluster [Na(DME),],[W,(CO),,] (I.P. Beletskaya, A.Z. Voskoboynikov. E.B. Chuklanova, AI. Gusev and A.V. Kisin), 1

Magnesium Germanium An easy route to I-germaindenes via a transmetallation zirconiumgermanium reaction (A. Kanj, P. Meunier, B. Gautheron, J. Dubac and J.-C. Daranl, 51

Manganese

Gold Substituted metal carbonyls. XXII. Synthesis of l,l’-bis(diphenylphosphino)ferrocene-bridged complexes with two heterometallic Au-M (M = Mn and Re) bonds (P.M.N. Low, Y.K. Yan, H.S.O. Chan and T.S.A. Horl, 205

Iron Ubergangsmetall-Silyl-Komplexe. tronenreichen Hydrido-Silylund Fe(COXdppe)H,(SiRs);

A titanium-magnesium complex containing perpendicularly bridging bis(trimethylsilyl)acetylene ligands: [(11’-C,H5)Ti][(~lS-C,H,)Mg][F-n2 : n*-C,(SiMe,),]z (V. Varga, K. Mach, G. Schmid and U. Thewalt), Cl

XLVII. Deprotonierung der elekKomplexe Fe(CO),(dppeXHXSiR,l Darstellung der Komplexe Fe-

Synthese und Struktur zweikerniger Cyclopentadienyltricarbonylmangan-Komplexe vom Typ (C0)3Mn[(llS-C,H,)-X-(~sC,H,)]Mn(CO), (S. Pitter, G. Huttner, 0. Walter und L. Zsolnail, 183 Photochemische Reaktionen von Ubergangsmetall-Organyl-Komplexen mit Olefinen. VII. Photoreaktionen von Tricarbonyl-n5dienyl-mangan-Komplexen mit 6,6-Dimethylfulven (C.G. Kreiter und K. Lehr), 199 Substituted metal carbonyls. XXII. Synthesis of l,l’-bistdiphenylphosphinolferrocene-bridged complexes with two heterometallic

Au-M

(M = Mn

Ghan

and T.S.A.

and Re) bonds Her).

(P.1M.N.

I.ow.

Y.K.

\ an. fI.S.0

205

Mercury Studies

on binuclear

Fe-M

complexes.

complexes

Fe(Ph,PpyJl(CO), a neutral

Ni,

[Ph,Ppq

tridentate

H-C;.

Cu.

Molecular

(Z-Z.

R.-J. Wang.

and catalytic

Rh.

hehaviour

fig)

using

ot

trwr\-

= 2-(diphcnylphosptlino)pqridine]

l&and.

Ph2Ppy):(C‘O),(SC‘N), Jiang.

Synthesis

(M 7 Mo.

Zhang.

Wang

\tructuw

II.-I’.

Xi. \t

and 1’. Wu).

a\

of

Fel I@(@-

-J. %ha~b. K. Y.

221

Metallocenes Preparation

and

aindane New

structure

CC;. Erkcr.

metallocene

zoalkane\

complexes

(D.A.

Kaaennova, Formation

b~s(rl’-mcthplcycJopentrldicn~l)titanand A.L. M.

and Y.T.

Putala.

with

tuncttonalizcd G.I.

Struchkov).

[cp2Zr(C=C’-SiMe,)l,

I I3

Rheingold).

of Nb and Ta with

Lemenocskii.

D.S. Yufit

of

conoccnc

of

U. Korek

N.B.

I3

from

trirneth~l~ilql;lcetyien~

tlia-

Nikonov.

the

reactlorl

(N, Metzlt~r

iuld

of II.

/IT-

Niith).

Phosphorus

(‘5

~Jbt.rga~lgsmetaIl-SiJyl-Komplexe. tronenrcichcn

Molybdenum

und

Organometallic

chemistry

troscopic

studies

of diphoaphwanes.

and

crystal

(R.P.K.

of

13&u.

S.S. Krishnamurthy

spec--

f;rc.-[Mo(C‘O),-

an
(MeCN)[PhzPN(‘Pr)f’tPhKL)MP)}], phosphines

V111. Synthesis.

ctructurc

aith

Nethaii).

157

plexen

Dcsalkylierungsreaktioncn des Molybdans

und Wolfram\.

: ~‘-C~fId~‘Mc~<‘i,tIh)Mo(<‘O~,.

(vi

II,)W(c‘C))3

und

on hinuclear

Fe-M

Kogcry;).

Synthesis

CM = MO.

Fe(Ph,Ppy),(C‘O),

[Ph,Pp)

tridentate

Ni.

v!-(.‘.I1

van

,(‘Me,(.,,-

(‘u.

hehabiour

I+)

using

(Z.-Z.

of hydrosilylation. unusual

Zhang.

structure

a\

of

Fe-M

K.-Y.

and

dcrivatlvc\. P;taynskii.

27 I

[Ph,Ppy

tridentate

(Z.-Z.

R.-J. Wang,

~bergangsmelallall~l~. (R. Goddard.

Wilke).

(‘20

Cu.

by

nickel

45

and catalytic

Rh.

Molecular Zhang.

H.-G.

Wang

VII.

Synthrse

lytpalJadiumkomplexen ganden

Ni.

at silicon

catalysed

behalour

IIg)

using

of rrnns-

= 2-(diphenylphosphinoJpyridinc1

I~gand.

Ph2Ppy),((‘O),(SC‘N), Jiang.

Synthesis

CM = MO.

complexes

of subhtitucnts

vinylsilanrs

and H. Maciyewski).

complexc~.

Fe(Ph2Ppy)&CC), a neutral

Effect

of

(B. Marciniec

on hinucleur

structuic

I I.-f’.

721

q ‘-AJJylnickcl~

mit .I-rifluor~tcrt:ltgruppcn C‘. Kriigcr.

FeHg(p-

Xi. \hi -.1 %h;ro. K.-Y

and Y. Wul van

ot

as

R. Mynoti.

und 7 ‘-A-

aI5 Brilckcnli-

M. Neum;~nn

und Ci.

Cp A2Nb(aL-S,)H Niobocensulfiden metallocene

zoalkanes Ka~ennova.

Cp * ?Nb,S,,:

(H. Brunner.

und B. Nuber). New

zu

Reaktivit:itsstudien

G. Gehart.

W. Meier.

an

.J. Wachter

I17 comptcxcs

(D.A.

of Nb and Ta H.ith functionalized

Lemenovskii.

D.S. Yuflt

Wrl-kung

lill:icl\.

~7

\i’~ktr[,skopiaclle ctnt\

11 ‘Llichalik.

I!ntc~--

ncucn

chtralen

I). J,tnshc

und Il.

molecular

structure\

contaimng

(I’h ,f’): Pt or C‘pRc(U))

13.1 Kc~lohhw. ,\.I.

J’ho\(ioc+

and Y.T

M.

Put&.

Struchkoc).

Ci.1. Nikonov. 171

diaN.B.

1’,rnir\sk!

0I

S.I.

?ietetlo\.

I,

:tn,t L

S, te,(CO),,

hetcrometallic J’rapment~ (AA.

1.1.. J:,Icmcnkc,,

Sit-uchho\).

1: S

73

Rhenium Syntheses

and ractions

of metal

tl-~methylsilylmett~~l

ligand:

trimethylsilylmrthyl f3-(~‘. fiuang. Suhstitutcd

groups

\ 9.

metal

carbonyl lJ.-D.

I.in ;mcJ \

carbtrnyl\.

Au--M

S\(ll.

Synthr\r\

01’ thz

btructurcb

1Lu.

I.-Y.

Wu.

17

S)ntherl\

ctmple\e\

01 I.!‘-hi~(dlphcnqJ~

uith

(P.MN.

p~eu~~~~h~illdc-dir~itr~)gc~i

_J (Y

0f the I~othioc!an;rtc

Frailsto

(‘.-K.

the

aasistcd 17) the

twl

1.w.

hctcrometallic

Y.K.

Y;III.

fI.S.0.

I Icu !. 30’

fN,~(I’h,J’(‘JI,<‘tJ.I’l’I!,~. J.J.R.

ctmtainlng

reactwns

(‘hen.

Wang).

(M = Mn :md Re) bond\

C‘han and T’.S.;\.

complexa

(~‘0 rnaertion

pho~phinci)ferrtrccllz-hrid~e(J

A. ‘I iripicchioi.

Niobium Von

S>nthcsc.

%\lcischalcnIlho~-

Platinum Sqnthesii

FeHg(p

11.-I’. Xi. W -.i. Zhao.

anti ‘1. Wu).

XXIII.

hydrosilylation

acctylacetonatc Studies

und J %ic:!!lcr).

III.

70

aktiw

ot

watw

Nickel on

Optisch

+

Klrltun.

Catalysis

J. t.rir\t

und hatalytwhe

t ,I

und M. Knorr).

l..YNNJ.

ti,ll
phanliganden rnann).

S. (illbert

11l.(G: ,AIt.

and catalytic

Rh.

Molecular

I I.-G. Wang

R.-J. Wang.

(11. Prunnihr.

iI

Komplcw

der

kol-r~rporiciier~lidel~

Katalyse.

Asymmctri~chc

Dar\tellung

<) und f-e((‘OHdppc‘)I~I~(I:Mc ,)(SiR :) .inionlachen Kon-

den

Schtd~ert.

Fnalltiocclcktiw

suchunpcn

= ?-(diphcnylphosphillo)pyridine]

ligand.

Ph,Ppy)L(C<>),(S(IN), Jiany.

(7’

(I:.

au\

;):

der rleh-

Fe((‘Ol,(dp~~e)(f~l)(SiR

105

complexes.

complexes

a neutral

Fluor-

Molekiil\truktulen

[(~~~(‘~II~(~‘Il,~i~~,~H,I~W(~‘OI,ll

J.S. f3an und R.D. Studies

und

C:~clopentadienqltric‘arhonql-Methq.1.

enyl-funktionalisierten komplexen

an Jndcnyl-

Pb)

Dcprotonierung

Komplcxc

;(SiR

Fc(<‘O),(~lppe~(J~,Mr;)!SiR

phinv

Photoinduziertc

Fe(C‘O)(dppe)JI

tE --- Sn.

tertiar)

and M.

NLVJI.

Hydride-Silyl-

Da Silv;i. 21

I

complexes

rr-rwv-[Rex-

UC-S.NC0 or-h-:) ar11lUyLll and wide.

-\...I I.. Pombrirt~.

cimtplcxe\ >I,;\.

0’.

Pclllnphelii

Wang, :~nd

c31 ple bond. A reformulation, pound (J.J.R. Frahsto Pombeiro, R.L. Richards,

and X-ray structure of the MO comda Silva, M.A. Pellinghelli, A.J.L. A. Tiripicchio and Y. Wang), C8

Rhodium Asymmetrische Katalyse. III. Synthese, spektroskopische Untersuchungen und katalytische Wirkung eines neuen chiralen Phosphanliganden (A. Tillack, M. Michalik, D. Fenske und H. Goesmann), 9.5 Dimethylencyclobuten als Komplexligand. Synthese und Struktur von Tricarbonyl(nh-diisopropylidencyclobutenkhrom und Bis(n’-dimethylencyclobuten)(?75-indenyl)rhodium (D. Rau und U. Behrens), 151 Studies on binuclear complexes. Synthesis and catalytic behaviour of Fe-M complexes (M = MO. Ni, Rh, Cu. Hg) using [runsFe(Ph,Ppyl,(CO), [PhzPpy = 2-(diphenylphosphino)pyridine] as a neutral tridentate ligand. Molecular structure of FeHg(FPhzPpy),(CO),(SCN), (Z.-Z. Zhang. H.-P. Xi, W.-J. Zhao, K.-Y. Jiang, R.-J. Wang, H.-G. Wang and Y. Wu), 221 Syntheses of nitrogen heterocycles by means of amine-directed carbonylation and hydrocarbonylation (Z. Zhang and I. Ojima), 281

(E = Sn, Pb) aus den korrespondierenden anionischen Komplexen (U. Schubert, S. Gilbert und M. Knorr), 79 Synthesis and characterization of ansa-dimethylsilylbiscyclopentadienyl titanium(IIJ complexes. Crystal structure of [Ti(Me,Si(CsH,),){CN(2,6-Me,C~H~))*] (T. Cuenca, R. Gomez, P. Gomez-Sal and P. Royo), 105 Formation of [cpzZrfC%C-SiMe,)], from the reaction of zirconocene with trimethylsilylacetylene (N. Metzler and H. Noth), CS

Sodium Metalcarbonylates of lanthanides. Unexpected formation of the trinuclear cluster [Na(DME),],[W,(CO),,] (I.P. Beletskaya, A.Z. Voskoboynikov, E.B. Chuklanova, A.I. Gusev and A.V. Kisin), 1

Tantalum New metallocene complexes of Nb and Ta with functionalized zoalkanes (D.A. Lemenovskii, M. Putala, G.I. Nikonov, Kazennova, D.S. Yufit and Y.T. Struchkov). 123

diaN.B.

Tin Ruthenium Syntheses and reactions of metal carbonyl complexes containing the trimethylsilylmethyl ligand; CO insertion reactions assisted by the trimethylsilylmethyl groups (J.-D. Chen, C.-K. Wu, I.-Y. Wu, B.-C. Huang, Y.-C. Lin and Y. Wang), 173 Paramagnetic organometallics formed by o-metallation of phenolic Schiff bases by rutheniumfIB) (P. Ghosh, A. Pramanik, N. Bag, G.K. Lahiri and A. Chakravorty), 237 Reaktionen der Aren(carbonyl)ruthenium-Komplexe [C,Me,Ru(CO)Cl,] und [(Mes)Ru(CO)Cl,] mit Alkyl- und Allyl-Grignardreagenzien. Die Kristallund Molekiilstruktur von ([n5C,Me,(CH,CH=CH,)]Ru(~.~~-?7’-C,H,XCO)) (H. Werner, G. Brauers und 0. Niirnberg), 247 Regiospecific Cp’Ru + mediated codimerization of conjugated dienes. with non-conjugated 1,5-dienes and its application to catalytic cooligomerization (K. Masuda, H. Ohkita. S. Kurumatani and K. Itoh), Cl3 A ruthenium dihydrogen complex as intermediate in the synthesis of [RuH(CO),fMeCO,)(P”Bu,),] from [Ru(H)~(CO),(P”BU,)~] (P. Frediani, A. Salvini. M. Bianchi and F. Piacenti), Cl7

Silicon Dialan-Radikalanionen [R,AI-AIR,](W. Uhl, A. Vester, W. Kaim und J. Poppe), 9 AM1 and PM3 semiempirical molecular orbital study of silatranes. III. I-chlorosilatrane (G.I. Csonka and P. Hencsei), 15 Synthesis and crystal structure of par-a-substituted diphenylsilanes of interest for nonlinear optics: sulfonyl acceptor groups (D. Hissink, P.F. van Hutten, G. Hadziioannou and F. van Bolhuis), 25 Siliciumverbindungen mit starken intramolekularen sterischen Wechselwirkungen. L. Reaktionen von Silylenen und Disilenen mit 2,2’-Bipyridyl, Pyridin-2-aldiminen und a-Ketoiminen: Cy cloadditionen ~‘crsus C-H-Insertion (M. Weidenbruch, H. Piel, A. Lesch, K. Peters und H.G. von Schnering), 35 Catalysis of hydrosilylation. XXIII. Effect of substituents at silicon on unusual hydrosilylation of vinylsilanes catalysed by nickel acetylacetonate (B. Marciniec and H. Maciejewski), 45 Ubergangsmetall-Silyl-Komplexe. XLVII. Deprotonierung der elektronenreichen Hydrido-SilylKomplexe Fe(CO),fdppeXH)(SiR,) und Fe(CO)(dppe)Hs(SiR J): Darstellung der Komplexe Fe(CO),(dppe)(EMe,XSiR,) und Fe(CO)(dppe)H,(EMe,XSiR,I

Tin(IV) and organotin(IV) complexes with heterocyclic p-diketonates. I. Bis-[4(1-phenyl-3-methylpyrazol-5-one)]-dioxoalkane derivatives (C. Pettinari, F. Marchetti, A. Cingolani, D. Leonesi, G. Gioia Lobbia and A. Lorenzotti), 59 A complex salt formed in reactions of “BuSnCl, with l-(2-methyl2,3-dihydrobenzothiazol-2-yll-2-ketones (S.-B. Teo, S-G. Teoh, R.C. Okechukwu and H.-K. Fun), 67 The structures of the adducts formed from organotin moieties and I-[(4-methoxyphenylimino)methyl]-2-naphthol. Crystal structure of chloro-trimethyl[l-[~4-methoxyphenylimino~methyl]-2-naphthol]tin(IV): Me,SnCI [HOC,,,H,CH : NC,H,OCH,l (S-G. Teoh, S.-B. Teo, G.-Y. Yeap, H.-K. Fun and P.J. Smith), 73 Ubergangsmetall-Silyl-Komplexe. XLVII. Deprotonierung der elektronenreichen Hydrido-SilylKomplexe Fe(CO),(dppe)(HXSiR3) und Fe(CO)(dppe)H &SiR ,); Darstellung der Komplexe Fe(CO),(dppeXEMe&SiR,) und Fe(COXdppe)H,(EMe,NSiR,) (E = Sn, Pb) aus den korrespondierenden anionischen Komplexen (U. Schubert, S. Gilbert und M. Knorr), 79

Titanium Synthesis and characterization of ansa-dimethylsilylbiscyclopentadienyl titanium(B) complexes. Crystal structure of [Ti{Me,Si(C,H,),}{CN(2.6-Me~C~H~)]z] (T. Cuenca, R. Gomez, P. Gomez-Sal and P. Royal, 105 Preparation and structure of bis(q’-methylcyclopentadienylkitanaindane (G. Erker, U. Korek and A.L. Rheingold), 113 A titanium-magnesium complex containing perpendicularly bridging bis(trimethylsilyl)acetylene ligands: [(11’-CsH,)Ti][(71r-CsHs)Mg][p-n2 : n2-C,(SiMe,),], (V. Varga, K. Mach, G. Schmid and U. Thewalt), Cl

Tungsten Metalcarbonylates of lanthanides. Unexpected formation of the trinuclear cluster [Na(DME),],[W,(CO),,] (1.P. Beletskaya, A.Z. Voskoboynikov, E.B. Chuklanova, A.I. Gusev and A.V. K&in), 1 o-Addition von Aminen, Iminen und Hydrazinen an AllenylidenKomplexe - Bildung von Carben-, Azetidinylidenund NitrilKomplexen (H. Fischer, G. Roth, D. Reindl und C. Troll), 133 Photoinduzierte Desalkylierungsreaktionen an Indenylund Fluorenyl-funktionalisierten Cyclopentadienyltricarbonyl-Methylkomplexen des Molybdans und Wolframs. Molekiilstrukturen von

Syntheses

and reactions of metal carhonyl complexes contalninp the

trimethylsilylmethyl trimethylsilylmcthyl B.-C.

ligand; CO insertion groups

Huang. Y.-C‘. tin

(J.-D.

rextions

Chen.

and Y. Wang).

(‘.-I(.

as\i\ted by the Wu.

I.-\

Wu.

173

Zirconium An easy route to I-germaindenes germanium

reaction

(A.

Duhac and J.-c‘. Daran).

Kani. 51

via a transmetallation T’. Mcunier,

R.

Lirconium--

Gautheron,

J.

Book review