Thermal Conductivity of Liquid – Inorganic Compounds

Chapter 8 THERMAL CONDUCTIVITY OF LIQUID -INORGANIC COMPOUNDS Carl L. Yaws Lamar University, Beaumont, Texas

Tabulation Results The results are given in Table 8. For the tabulation, thermal conductivity of liquid as a function of temperature is given by the equation shown below: k liq =A + B T + C T

2

(8)

kliq =thermal conductivity of liquid, W/(m K) A, B, and C regression coefficients for chemical compound T =temperature, K

where

=

The tabulation is arranged by alphabetical order (Ag, AI, Ar, , Zr ) to provide ease of use in quickly locating the data by using the chemical formula. The compound name and CAS No (Chemical Abstracts Registry Number) are next provided. Values for regression coefficients are given in the adjacent columns. The temperature range for use is given in the next columns (TMIN and TMAX). The equation should not be used for temperatures outside this range. The next column provides the code for the tabulation. The last three columns provide values for thermal conductivity of liquid at representative temperatures. In preparing the tabulation, a literature search was conducted to identify data source publications (1-46). Both experimental values for the property under consideration and parameter values for estimation of the property are included in the source publications. The publications were screened and copies of appropriate data were made. These data were then keyed into the computer to provide a database of values for compounds for which experimental data are available. The database also served as a basis to check the accuracy of the estimation methods. Upon completion of data collection, estimation of values for the remaining compounds was performed. The compilations of Beaton and Hewitt (2); Daubert and Danner (5); Ho, et al. (8-9); Vargaftik et al. (25-27); and Yaws (30-45) were used extensively for the tabulation. In the absence of experimental data for inorganic compounds, estimates of liquids were primarily based on modified Missenard method (15) and literature estimates. Experimental data and estimates were then regressed to provide the same equation for all compounds. A comparison of calculated and data values is shown in Figure 8 for a representative compound. The graph shows favorable agreement of equation and data.

Example In an engineering analysis, liquid thermal conductivity is needed for nitrogren (N2) at 80 K. Determine the thermal conductivity of liquid for nitrogen at this temperature. Substitution of the coefficients from the tabulation and temperature into the above equation yields: k1iq =0.2864 - 2.0105E-03*80 + 1.0855E-06*80

2

kliq = 0.1320 W/(m K)

References 1. 2. 3. 4. 5. 6.

ASHRAE Handbook - Fundamentals, 1989, 1993 and 2001 eds., ASHRAE, Atlanta, GA (1989, 1993, 2001). Beaton, C. F. and G. F. Hewitt, PHYSICAL PROPERTY DATA FOR THE DESIGN ENGINEER, Hemisphere Publishing Corp., Ney York, NY (1989). CRC HANDBOOK OF CHEMISTRY AND PHYSICS, 75th - 86th eds., CRC Press, Inc., Boca Raton, FL (1994-2006). CRC HANDBOOK OF THERMOPHYSICAL AND THERMOCHEMICAL DATA, CRC Press, Boca Raton, FL (1994). Daubert, T. E. and R. P. Danner, DATA COMPILATION OF PROPERTIES OF PURE COMPOUNDS, Parts 1, 2,3, and 4, Supplements 1 and 2, DIPPR Project, AIChE, New York, NY (1985-1994). Donnely, R. J. and C. F. Barenghi, "The Observed Properties of liqUid Helium at the Saturated Vapor Pressure", J. Phys. Chem. Ref. Data, 2Z, 1217-1274 (1998).

396

7. 8. 9. 10. 11.

12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39.

Grosse, A. V., "Electrical and Thermal Conductivities of Metals over Their Entire liquid Range", Rev. Hautes Temper. et Refract., 3,115-146 (1966). Hampel, C. A., THE ENCYCLOPEDIA OF THE CHEMICAl EI EMENTS, Reinhold Book Corp., New York, NY (1968). Ho, C. Y., R. W. Powell, and P. E Liley, 'Thermal Conductivity of the Elements", J. Phys. Chem. Ref. Data, 1 , No.2, 279-421 (1972). Ho, C. Y., editor, PROPERTIES OF INORGANIC AND ORGANIC FIIIIDS, Volume V-1, Hemisphere Publishing Corporation, New York, NY (1988). Janz, G. J. and Others, PHYSICAl PROPERTIES DATA COMPILATIONS REVEl ANT TO ENERGY STORAGE, Part II Molten Salts: Data on Single and Multi-ComonentSalt Systems, NSRDS-NBS 61, Part II, U. S. Dept. of Commerce, Washington, DC (1979). Landolt, H. and R. Bornstein, ZAHLENWERTE liND FUNKIONEN ANS PHYSIK, CHEMEI ASTRONOMIE UND TECHNIK, Springer-Verlag, Heidelberg, Germany (1971-2005). LANGE'S HANDBOOK OF CHEMISTRY, 13th, 14th, and 15th eds., McGraw-Hili, New York, NY (1985, 1992,1999). Lyon, R. N., ed., L10lJlD-METAI S HANDBOOK, 2nd ed. (revised), Office of Naval Research, Department of Navy, Super. Of Documents, US Govemment Printing Office, WaShington, DC (1954). Marsh, K. N., ed., RECOMMENDED REFERENCE MATERIAL S FOR THE REAliZATION OF PHYSICOCHEMICAl PROPERTIES, Blackwell Scientific Publications, Oxford, England (1987). Matsunaga, N. and A. Nagashima, "Transport Properties of Liquid and Gaseous 020 over a Wide Range of Temperature and Pressure", J. Phys. Chem. Ref. Data, 12,933 (1983). Ohse, R. W., ed., HANDBOOK OF THERMODYNAMIC AND TRANSPORT PROPERTIES OF ALKALI METAl S, Blackwell-Scientific PUblications, London, England (1985). Perry, D. L. and S. L. Phillips, editors, HANDBOOK OF INORGANIC COMpOIJNDS, CRC Press, Boca Raton, FL (1995). PERRY'S CHEMICAl ENGINEERING HANDBOOK, 6th and 7th eds., McGraw-Hili, New York, NY (1984, 1997). Poling, B. E, J. M. Prausnitz, and J. P. O'Connell, THE PROPERTIES OF GASES AND L10lJlDS, 5th ed., McGraw-Hili, New York, NY (2000). Reid, R. C., J. M. Prausnitz, and B. E. Poling, THE PROPERTIES OF GASES AND I 101llDS, 4th ed., McGraw-Hili, New York, NY (1987). Stephan, K. and T. Heckenberger, THERMAl CONPlJCTIVITY AND VISCOSITY DATA OF FllJID MIXTURES, Chemistry Data Series, Volume X, Part 1, DECHEMA, FrankurVMain, Germany (1988). THERMOPHYSICAI PROPERTIES DE MATTER, 1st and 2nd eds., IFI/Plenum, New York, NY (1970-1976). Tsederberg, N. V., THERMAL CONDIICTIVITY OE GASES AND I 101 liDS, MIT Press, Cambridge, MA (1965). Vargaftik, N. B., TABI ES ON THE THERMOPHYSICAI PROPERTIES OE I IQI liDS AND GASES, 2nd ed., English translation, Hemisphere Publishing Corporation, New York, NY (1975,1983). Vargaftik, N. B. and Others, HANDBOOK OE THERMAL CONDUCTIVITY OF I IOlJlDS AND GASES, Standards Press, Moscow, USSR (1978). Vargaftik, N. B. and Others, HANDBOOK OE THERMAl CONDIICTIVITY OF L10IJlDS AND GASES, CRC Press, Inc., Boca Raton, FL (1993). web site, WebElements, www.webelements.com (2008). web site, Wikipedia, the free encyclopedia, en.wikipedia.org (2008). Yaws, C. L. and Others, "Carbon Oxides (Carbon Monoxide and Dioxide) - Phy. and Thermo. Prop. (4)", Chem. Eng.,B1 (20),115 (Sept. 30, 1974). Yaws, C. L. and Others, "Ammonia and Hydrazine • Phy. and Thermo. Prop. (6)", Chem. Eng., 81 (25), 178 (Nov. 25,1974). Yaws, C. L. and Others, "Major Diatomic Gases (Hydrogen, Nitrogen and Oxygen) - Phy. and Thermo. Prop. (8)", Chem. Eng., B2 (2), 99 (Jan. 20,1975). Yaws, C. L. and Others, "N-Type Gas Phase Dopants - Physical and Thermodynamic Properties of Arsine, Phosphine and Stibine", Solid State Technology,1Z (1), 47 (1974). Yaws, C. L. and Others, "Oxides of Nitrogen (Nitrous Oxide, Nitric Oxide and Nitrogen Dioxide) - Phy. and Thermo. Prop. (3)", Chem. Eng., 81 (17),99 (August 19,1974). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silane", Solid State Techn., 2.1 (1), 43 (January, 1978). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silicon Tetrachloride", Solid State Techn., 22 (No.2), 65 (February, 1979). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silicon Tetrafluoride", J.Ch.l.Ch.E, 12 (1), 33 (1981). Yaws, C. L. and Others, "Pbyslcal and Thermodynamic Properties of Trichlorosilane", J.Ch.I.Ch.E, 14, 205 (1983). Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Dichlorosilane", Ind. Eng. Chem. Process Des. Dev., 23, 48 (1984).

397

40. 41.

42. 43.

44.

45. 46.

Yaws, C. L. and Others, "P·Type Gas Phase Dopants (Diborane and Pentaborane): Physical and Thermodynamic Properties", Solid State Technology, 11 (11),31 (1974). Yaws, C. L., PHYSICAL PROPERTIES, McGraw-Hili, New York, NY (1977). Yaws, C. L., HANDBOOK OE THERMAl CONDUCTIVITY, Vols. 1 and 4, Gulf Publishing Company, Houston, TX (1995,1997). Yaws, C. L., CHEMICAL PROPERTIES HANDBOOK, McGraw-Hili, New York, NY (1999). h Yaws, C. L., MATHESON GAS DATA BOOK, i ed., Matheson Tri-Gas (Parisppany, NJ), McGraw-Hili, New York, NY (2001). Yaws, C. L., YAWS HANDBOOK OE THERMODYNAMIC AND PHYSICAl PROPERTIES OE· CHEMICAL COMPOUNDS, electronic edition, www.knovel.com. knovel, Norwich, NY (2003-present). Yaws, C. L., YAWS HANDBOOK OE PHYSICAL PROPERTIES EOA HYDROCARBONS AND CHEMICAl S. Gulf Publishing Company, Houston, TX (2005).

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40

60

80

100

120

Temperature, K

Figure 8 Thermal Conductivity of Liquld for Nitrogen

398

140

Table 8 Thermal Conductivity of Liquid - Inorganic Compounds (kuc, - W/(m K), T - K)

~ =A+BT+Cr NO

10

1 2 3 4 5 8 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 36 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71

13 77 80 82 86 96 200 203 228 230 231 234 238 256 285 361 363 368 391 393 394 401 404 405 406 413 533 562 628 633 641 642 844 645 846 647 648 651 652 653 654 655 656 661 713 776 891 892 893 894 898 899 900 905 1002 1049 1099 1124 1169 1229 1298 1302 1303 1406 1409 1412 1420 1434 1575 1585 1639 1661 1668 1675 1686 1687 1691 1694 1695 1696

72 73 74 75 76 77 78 79 80

FORMULA Ag

PJ PJB3H12 PJBr3 PJC2H6CI PJC6H15 Ar

AsBr3 AsCI3 AsF3 AsF5 AsH3 Asl3 !'oJ BBr3 BCI3 BF3 BH2CO B2D6 B2H5Br B2H6 B3N3H6 B4Hl0 B5H9 B5Hll Bl0H14 BeB2H8 Bl BrF5 Br2 0020 CF20 CH4N20 CH4N2S CNBr CNCI CNF CN408 CO COS COSe CO2 CS2 C2N2 CaCI2 Cd CIF ClF03 CIF3 CIF5 CI02 CI2 CI20 CI207 CoNC304 CrC606 Cr02CI2 Cs Cu CuCl DeN 02 020 FNO F2 F20 Fe F8C505 Ga GaCI3 GeBr4 GeCI4 GeHCI3 GeH4 Ge2H6 Ge3H8 HBr HeN HCI HCI03S

NAME sliver aluminum aluminumborohydrlde aluminumbromide aluminum, dimethylchloride aluminum, triethyl argon arsenic (III)bromide arsenic trichloride arsenic trifluoride arsenic pentafluoride arsine arsenic triiodlde gold boron tribromide boron lrichloride boron trifluoride borine carbonyl dlborane, deutero diborane hydrobromide diborane borazlne lelraborane pentaborane pentaborane decaborane berylliumborohydride blsmulh brominepenlafluoride bromine carbonylchloride carbonyl fluoride urea Ihiourea cyanogenbromide cyanogenchloride cyanogenfluoride lelranltromethane carbon monolOde carbonylsulfide carbon oxyselenide carbon dlolOde carbondisulfide cyanogen calciumchloride cadmium chlorinernonofluoride perchioryl!Iuoride chlorine trifluoride chlorine pentafluoride chlorine dlolOde chlorine chlonne monolOde chlorine hep/olOde cobell nitrosyl tricarbonyl chromiumcarbonyl chromiumoxychloride cesium copper cuprouschlonde deuteriumcyanide deutarium deutenumolOde nitrosyl f1uonde fluorine fluonneolOde Iron Iron Denlacarbonyl aalllum galliumlrichloride germaniumbromide germaniumchlonde germane,Inchloro germane digermane lrigermane hydrogenbromide hydrogencyanide hydrogenchloride chlorosulfonicacid

CAS No 7440-22-4 7429-90-5 16962-07·5 7727-15-3 1184-58·3 97·93-8 7440-37-1 7784·33-0 7784-34-1 7784-35-2 7784-36-3 7784-42·1 7784-45-4 7440-57-5 10294-33-4 10294-34-5 7637-07-2

A 88.4609 45.3604 0.2804 0.1529 0.2111 0.2076 0.1855 0.1354 0.1764 0.1960 0.1668 0.2485 0.1112 50.2409 0.1521 0.1682 0.0203 0.3691 20396-66-1 0.3928 0.2333 19287-45-7 0.4585 6569-51-3 0.2637 18283-93-7 0.3332 19624-22-7 0.2850 18433-84-6 0.2933 _ 0.2059 1744o-B5·6 0.2938 7440-69-9 4.9793 7789-30-2 0.1878 7726-95-6 0.1474 75·44-5 0.1682 353-SO-4 0.3069 57-13-6 0.2888 0.2411 62·56-6 506-68-3 0.1964 506-77·4 0.2423 1495·50-7 0.3512 509-14-8 0.1992 630-08-0 0.2855 463-58-1 0.2505 1603-84-5 0.2346 124-36-9 0.4320 75-15-0 0.2333 460·19-5 0.2905 10043-52-4 ·137.8039 7440-43-9 14.2893 779()..89-8 0.3103 7616-94·6 2.3320 7790-91-2 0.2454 13637-63-3 0.2040 10049-04-4 0.2778 7782·SO-5 0.2045 7791·21-1 0.2588 10294-46-1 0.1808 14096-82-3 0.1759 13007-92-6 0.1353 14977-61-6 0.1988 7440-46·2 16.9940 7440-50-8 75.7224 7758-89-6 ·0.1651 3017-23-0 0.4128 7782-39-0 0.0480 7789-20-0 -0.0035 7789-25-5 0.3380 7782-41-4 0.2637 7783-41-7 0.3292 7439-89·6 5.7318 13483-4o-B 0.1692 7440-55-3 7.8447 13450-9()..3 0.1857 13450-92-5 0.1301 10038-98-9 0.1695 1184·65-2 0.1801 7782·65·2 0.2693 13818-89-8 0.1977 14891-44-2 0.1650 10035-1 o-e 0.2340 74·9()..8 0.3333 7647-01·0 0.4593 7790-94·5 0.2244

..-

---

..

399

B

9.5576E-Q2 6.0944E-02 -1.4584E-04 -2.3596E-05 -2.4150E-04 -2.16ooE-04 -3.5091 E·04 -4.9347E-05 -7.6933E-05 -4.8443E·05 -2.7463E-05 -1.6905E-04 -2.9772E-05 5.3871E-02 ·7.4015E-05 -2.1950E·04

o.oooos-oo -2.9796E-04 -2.6308E-04 -1.5623E·04 ·4.8053E-04 -1.322OE-04 -2.4373E-04 -l.3884E-04 -l.3966E-04 -4.8187E-05 2.0204E-04 1.5785E-02 ·8.5540E-05 2.8333E-05 1.1873E-04 ·5.3980E·05 1.1326E-05 ·2.0469E-04 4.5432E-05 3.7906E·05 ·2.5473E-04 -2.7540E-04 -1.7840E-03 -2.7500E-04 ·1.9839E·04 -1.1929E-03 -2.75OOE-04 6.6083E·05 2.4507E-Ol 4.7559E-02 -2.3025E-04 ·4.4045E-03 -1.3866E-04 -1.oo74E·04 -1.2070E-04 5.8607E-05 -1.8841E-04 -1.1071E-04 -6.1478E·05 2.8624E-05 -1.1915E-04 1.1937E-02 9.4252E·02 5.06ooE-04 -4.9224E-05 5.5833E-03 3.2810E-03 -2.6904E-Q4 ·1.0460E-03 -6.2445E-04 2.7812E-02 ·7.1906E-05 6.9862E-02 -3.4299E·05 -1.4oooE-04 ·2.4914E-04 -1.oo85E-Q4 ·2.8399E-04 ·1.3548E-04 -1.0229E-04 -4.6360E-04 1.5737E-06 -1.6539E-04 -2.2000E-04

C -2.0653E-05 -1.3256E-05 -5.3593E-07 -1.6993E-07

TMIN

TMAX cocIe ....OTMIN k..025C k,.. OTMAX

1235.08 2273.20 933.52 2473.20 209.00 462.00 390.00 687.00 o.oooos-oo 252.15 399.15 O.OoooE+OO 220.65 467.15 -4.1077E-06 84.00 150.00 -1.0551 E-07 306.00 710.00 -2.0083E-07 255.00 589.00 -4.4249E-Q7 267.00 477.00 -9.1562E-07 193.00 322.00 -9.2454E-07 156.00 336.00 -4.3803E-08 419.00 991.00 -9.6607E-oB 1373.20 2600.00 -2.2066E-Q7 228.00 523.00 o.ooeos-oo 166.15 285.65 o.oooos-eo 144.79 173.35 -1.5882E-06 136.00 306.00 -2.6052E-06 136.00 264.00 ·4.9250E·07 169.00 420.00 ·2.5611E-06 108.00 261.00 -4.9540E·07 215.00 469.00 -6.6177E-07 153.00 420.00 ·4.3683E·07 226.00 512.00 -5.0069E·07 226.00 492.00 -1.9149E-07 373.00 713.00 -9.5365E-07 396.00 532.00 -3.9647E-06 544.59 1300.00 -4.7230E-07 212.00 423.00 ·3.6111E·07 266.00 580.00 -8.4939E-07 145.00 410.00 -2.4657E-06 162.00 267.00 -4.5537E·07 406.00 635.00 o.ooooe-oo 454.15 536.00 -5.7894E-Q7 331.00 491.00 -9.9081 E-07 267.00 404.00 -1.3047E-06 150.00 332.00 O.OOOOE+OO 287.05 398.85 o.eooos-oo 70.00 125.00 uooooa-oo 161.11 400.00 ·8.1505E-07 134.00 366.00 O.OOOOE+OO 216.55 300.00 O.OOOOE+OO 161.11 319.37 -1.5309E-06 239.00 360.00 -1.0769E-04 1070.00 1130.00 -1.6287E-05 594.26 900.00 -2.1802E-06 128.00 254.00 uooooe-oo 125.41 226.49 -5.9536E-Q7 190.00 413.00 ·6.6485E-07 190.00 374.00 ·7.2849E-07 214.00 419.00 -9.7115E·07 172.00 410.00 -5.9294E·07 157.00 400.00 -2.4145E-07 182.00 509.00 -3.1136E-07 262.00 511.00 ·2.5348E-07 424.00 622.00 -2.0211E·07 177.00 564.00 -9.8498E-06 301.90 573.20 -2.0444E-05 1357.80 2173.20 o.ooooe-oo 703.00 900.00 -1.2473E-06 261.00 434.00 ·8.3333E·05 19.00 27.00 -4.258OE·06 276.97 374.55 -1.3357E-06 139.00 317.00 ·2.2847E-06 53.50 140.00 -2.8048E-06 49.00 194.00 -4.8139E-06 1810.00 2873.20 -2.3565E-07 252.00 546.00 -9.8935E-06 302.93 700.00 ·2.4565E·07 351.00 625.00 5.3235E-18 300.00 360.00 5.3333E-06 248.15 373.15 ·2.6414E-07 202.00 504.00 -1.2736E-06 107.00 277.00 -3.5845E-07 164.00 442.00 ·1.7027E-07 168.00 555.00 e.ooooe-oo 194.17 290.62 -1.2143E-06 260.00 411.00 ·2.5781E·06 188.00 323.15 o.ooooe-oo 193.15 427.00

-------

2 175.0000 1,2 90.7000 0.2265 0.1893 2 0.1179 2 0.1502 0.1391 2 0.1431 0.1599 2 1,2 0.1270 0.1104 2 0.1437 0.1356 2 0.1515 0.1422 2 0.0772 2 0.1274 0.1996 0.1159 2 0.0910 2 2 106.0000 0.1104 0.1238 2 1,2 0.1318 1,2 0.0203 0.1391 0.2992 2 2 0.3088 0.1429 2 0.1928 0.3767 2 0.2124 0.1802 2 0.2017 2 0.2804 0.2048 2 0.2313 0.2072 2 0.2362 0.1613 2 0.2243 2 1,2 12.4000 0.1484 0.1203 2 0.1237 1,2 0.1294 0.1676 0.1281 2 0.2334 2 2 0.2183 0.1481 2 0.1480 2 0.1655 2 0.1818 0.1593 0.2836 2 0.1171 0.1201 2 1,2 0.1606 1,2 0.2062 0.1685 0.1972 0.1214 2 0.0763 1,2 0.1737 0.1513 2 0.1890 0.1741 0.2188 2 1,2 1.1221 1,2 36.8000 0.2451 2 2 1.7796 0.1976 0.1511 2 0.1609 0.1149 2 0.2186 0.1771 2 1,2 0.1858 0.1356 2 0.2149 0.1505 2 0.1527 0.1263 2 0.1384 0.1299 0.1019 2 0.1453 2 0.1714 1,2 19.7000 .1,2 166.0000 1,2 0.1906 2 0.3150 0.2872 1,2 0.1240 1,2 0.5786 0.5962 0.2748 0.1391 2 1,2 0.2012 2 0.2923 1,2 40.3000 0.1361 0.1268 2 1,2 28.1000 2 0.1434 0.0881 2 1,2 0.1110 0.1000 0.1490 0.1266 2 2 0.2243 0.1658 0.1254 2 2 0.1430 0.1194 1,2 0.1440 0.2516 2 0.2258 0.1806 1,2 0.3371 2 0.1819 0.1588

----

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199.0000 115.0000 0.0986 0.0565 0.1147 0.1066 0.0404 0.0472 0.0614 0.0722 0.0630 0.0873 0.0387 125.0000 0.0530 0.1055 0.0203 0.1292 0.1418 0.0808 0.1586 0.0927 0.1141 0.0994 0.1034 0.0742 0.1314 18.8000 0.0871 0.0423 0.0741 0.1167 0.1124 0.1313 0.0791 0.0959 0.1228 0.0894 0.0625 0.1405 0.0803 0.0741 0.1455 0.1159 1.6107 43.9000 0.1112 1.3344 0.0866 0.0733 0.0993 0.0652 0.0894 0.0619 0.0632 0.0550 0.0673 20.8000 184.0000 0.2903 0.1565 0.1380 0.6281 0.1185 0.0725 0.1100 45.9000 0.0597 51.9000 0.0683 0.0797 0.0840 0.0622 0.0929 0.0678 0.0558 0.0993 0.1288 0.1366 0.1305

Table 8 Thermal Conductivity of liquid -Inorganic Compounds (k lla - W/(m K), T • K)

kll =A+BT+Cy2 NO 81 82 83 84

85 86 87

88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160

10

FORMULA

1697 HCI04 1698 HF 1699 HI 1702 HN03 1709 H2 1712 H2O 1713 H202 1714 H2S 1716 H2SO4 1718 H2S2 1719 H2Se 1721 H2Te 1722 H3NO 1725 H3P04 1738 He 1739 He 1771 Hg 1869 IF7 1873 12 1877 In 1960 K 2009 KCI 2012 KCI03 2042 KN03 2162 Kr 2203 U 2213 UBr 2253 UCI 2261 UF 2270 UI 2274 UN03 2283 U2C03 2335 Mg 2392 MgCI2 2573 MoF6 2607 NCIO 2608 NCI3 2610 ND3 2613 NF3 2619 NH3 2645 NH5S 2674 NO 2676 N02 2678 N2 2684 N2F4 2685 N2H4 2686 N2H4C 2699 N2H6C02 2747 N20 2748 N203 2749 N204 2750 N205 2781 Na 2800 NaBr 2855 NaCI 2864 NaF 2875 NaHS04 2888 Nal 2894 NaN03 2897 NaOH 2916 Na2C03 3037 NbF5 3091 Ne 3105 NiC404 3198 02 3199 03 3222 Os04 3223 OsOF5 3234 P 3238 PBr3 3252 PC3H904 3280 PC6Hl504 3380 PCI2F3 3381 PCi3 3382 PCI5 3389 PH3 3390 PH4Br 3391 PH4CI 3392 PH41 3396 POCI3

NAME perchloric acid hydrogen fluoride hydrogen Iodide nitric acid hydrogen water hydrogen peroxide hydrogen sulfide sulfuric acid hydrogen disulfide hydrogen selenide hydrogen telluride hydroxylamine phosphoric acid hellu m-3 heliu m-4 mercury iodine heptafluoride iodina Indium potessium potassium chloride potassium chlorate potassium nitrate krypton lithium lithium bromide lithium chloride lithium fluoride lithium Iodide lithium nitrate lithium carbonate magnesium magnesium chloride molybdenum fluoride nitrosyl chloride nitrogen trichloride heavy ammonia nitrogen trifluoride ammonia ammonium hydrogensulfide nilric oxide nitrogen dioxide nilrogen tetrafluorohydrazine hydrazlne ammonium cyanida ammonium carbamate nitrous oxide nitrogen trioxide nitrogen tetraoxide nitrogen pentoxide sodium sodium bromide sodium chloride sodium fluoride sodium hydrogen sulfate sodium iodida sodium nitrate sodium hydroxide sodium carbonate niobium (v) fluoride

neon nickel carbonyl oxygen

ozone osmium tetroxide osmium oxide pentafluorida phosphorus (white) phosphorus tribromide phosphate, trimethyl phosphate, triethyl phosphorus (v) dichloride trifluoride phosphorus (iii) chloride phosphorus pentachloride phosphine phosphonium bromide phosphonium chloride phosphonium iodide lohosohorus OXYChloride

CAS No

A

B

7601·90-3 7664-39'3 10034-85-2 7697·37·2 1333-74'0 7732·18·5 7722·84·1 7783·06·4 7664·93-9 13465-07-1 7783.07-5 7783.09-7 7803-49-8 7664·38·2 14762-55-1 7440-59-7 7439·97·6 16921-96-3 7553·56·2 7440-74·6 7440-09-7 7447·40-7 3811-04·9 7757·79-1 7439-90-9 7439·93·2 7550-35·8 7447-41·8 7789-24·4 10377·51-2 7790·69·4 554·13-2 7439-95·4 7786-30·3 7783-77·9 2696·92-6 10025·85-1

0.2347 0.7516 0.0541 0.1211

·2.5520E·04 ·1.0874E-Q3 1.oo76E·04 5.383OE·04 1.3017E-Q2 4.7054E·03 3.2525E-03 .1. 1840E-03 1.0763E·03 ·1.8376E·04 -3.6294E-04 ·5.2407E-05 ·5.2700E·05 7.24ooE-04 5.1690E·03 1.0990E·02 2.8862E-02 5.0118E-05 1.0778E-04 4.0151E·02 -4.5986E·02 1.8259E·03 2.27nE·04 2.8842E·04 ·6.6125E·04 5.1719E·02 4.3613E·06 2.8052E·04 4.1868E·05 ·7.7112E-05 2.0934E·04 3.3069E·03 7.8956E·02 4.6271E·03 1.3643E·05 ·1.0288E·04 -8.6655E-05 -1.4733E-04 -4.6529E-04 ·2.3140E·03 6.3855E-04 1.0293E-Q3 -6.0000E·04 -2.0105E-03 ·6.4680E·04 ·1.5895E·03 1.2592E·04 8.2829E·06 5.4127E·05 ·1.8315E·04 6.9938E·05 2.4661E-Q5 ·5.9790E-Q2 ·3.3985E-05 2.8121E·04 5.8615E-03

...

7783·54·2 7664·41-7 12124-99·1 10102-43'9 10102-44-0 7727·37-9 10036-47-2 302·01·2 12211·52-8 1111·78-0 10024-97-2 10544·73-7 10544·72-6 10102-03-1 7440-23·5 7647·15·6 7647·14·5 7681·49-4 7681·38·1 7681·82·5 7631·99-4 1310-73·2 497·19·8 7783-68·8 7440-01·9 13463-39·3 7782-44·7 10028-15-6 20816-12-0

...

7723-14·0 7789-60-8 512-56·1 78-40·0 13454-99-4 7719-12·2 10026-13-8 7803-51·2

...

24567-53-1 12125-09-6 10025·87·3

·0.0485 ·0.2987 ·0.1697 0.4842 0.0142 0.2990 0.2102 0.1961 0.4095 0.2098 0.0050 ·0.0028 1.1875 0.1238 0.1169 23.2122 69.3309 ·1.0459 0.0096 0.2617 0.1707 22.1660 0.3906 0.1910 1.6813 0.2641 0.4999 ·1.3470 10.5381 -3.5481 0.1450 0.2767 0.2102 0.4969 0.2908 1.1690 0.1661 0.1878 0.3050 0.2864 0.2860 1.3675 0.2982 0.2382 0.2539 0.2831 0.2401 0.2011 109.2678 0.3616 0.7327 ·6.1797 0.2575 0.2205 0.4106 0.1600 0.5227 0.1696 0.0524 0.1740 0.2276 0.1748 0.1401 0.1242 0.2270 0.1502 0.1702 0.1524 0.1669 0.2008 0.1371 0.4714 0.1966 0.2092 0.1722 0.1912

400

C

o.ocoos-oo

o.ooooe-oo -4.5588E·07

o.oeoos-oo ·2.8333E·04 ·5.6209E-06 -3.5066E·06

e.oooos-oo

o.oooos-co ·4.4762E-Q7

e.ooooe-oo ·6.6190E·07 ·8.5576E·07

e.oooos-oc

e.oooos-oo ·1.36ooE-03 ·1.7847E-05 ·5.7268E-07 ·2.8486E-Q7 ·1.2282E·05 8.4395E·06 -4.4859E-oB

uooooe-oo 5.815OE·08 ·9.3750E·08 ·1.3753E-Q5 ·2.4093E·20 2.2204E·20 ·4.4409E·18

o.ooooa-oo 2.2429E·21 1.1215E-Q8 ·5.1984E·06 3.4890E·08 -4.6861 E-07 ·8.5984E·07 ·3.5545E-07 ·2. 1397E-06 ·2.1267E·06 O.OOOOE+OO ·1.6809E·06 ·9.43OOE·06

e.ooooe-oo 1.0855E-06

e.ooooa-oo e.coooe-oo ·1.1749E·06 ·6.3390E·07 ·2.1713E·06 ·7.7909E·07 ·1.1302E·06 ·6.1811 E·07 8.8222E-06 ·7.3045E·09 ·3.4890E·08 1.8504E·19

s.oooos-o, c.ocoos-oo 5.2632E·05 2.4911E·04 1.2400E·03 1.1314E·03 ·5.0359E·05 6.0425E·03 ·5.4156E·05 ·4.3647E·04 7.5288E·04 ·2.8986E·05 ·8.9873E·06 ·l.3684E·04 ·7.2169E·05 ·1.6289E·04 ·1.3982E-04 1.4694E·05 ·2.4654E·04 8.7024E-05 ·1.0173E·03 1.5528E-05 8.6905E·04 ·1.8856E·05 ·2.2692E·04

o.ooooe-oo 9.9686E·09

o.ooooe-oo 1.9937E-Q8 ·1.3656E·07 -1.3968E-04 ·4.0987E-07 ·4.4947E·06 ·2.5228E·06 ·2.0468E·07 ·2.4035E·07 3.3495E-oB ·1.2836E·07

o.ooooe-oe o.oooos-oe -6.3564E-07

o.oooos-oo ·3.7396E·07

e.ooooe-oc ·6.2075E·07 ·4.0096E·06 -4.1517E-07

o.oooos-oc

TMIN

TMAX code k",0TMIN k",025C k,1o0™AX

171.95 385.00 189.79 394.45 225.19 420.42 233.15 433.15 13.00 31.00 273.16 633.15 272.74 623.15 193.15 320.00 273.59 371.32 183.00 488.00 207.45 231.15 224.00 394.00 306.00 517.00 323.00 423.00 1.01 2.50 2.00 4.00 234.29 770.00 279.00 403.00 386.80 785.00 429.78 900.00 336.80 1473.20 1050.00 1200.00 1007.15 1108.15 610.00 730.00 116.00 205.00 453.70 1800.00 878.00 974.00 943.00 1043.00 1143.001153.00 742.00 1447.00 530.00 730.00 1000.00 1300.00 923.20 1200.00 1020.001120.00 290.00 448.00 214.00 397.00 246.00 508.00 199.00 350.00 66.00 210.00 195.41 400.05 391.00 449.00 110.00 176.40 270.00 350.00 63.00 125.00 111.65 198.95 274.69 623.15 309.00 442.00 309.00 486.00 182.00 279.00 170.00 383.00 262.00 388.00 303.00 464.00 371.00 1373.20 1020.003858.00 1100.00 1200.00 1270.00 1330.00 459.15 518.30 933.00 1100.00 590.00 740.00 473.15 873.15 1140.001280.00 349.00 24.00 248.00 55.00 77.35 329.00 333.00 317.30 233.00 227.00 216.65 265.00 181.15 433.00 139.37 291.00 245.00 292.00 274.33

730.00 43.00 458.00 150.00 161.85 591.00 548.00 600.00 640.00 470.35 488.15 411.00 349.25 582.00 185.42 452.00 290.00 486.00 378.65

2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 2 2 2 1,2 1,2 1,2 1,2 2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 1,2 2 1,2 2 2 2 2 2 1,2 2 1,2 1,2 1,2 2 1,2 2 2 2 2 2 2 1,2 2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 2 1,2 2 1,2 1,2 2 2 2 2 2 2 2 2 2 2 2 2 2 2

0.1908 0.5452 0.0537 0.2466 0.0779 0.5672 0.4565 0.2555 0.3087 0.2504 0.1349 0.1511 0.3132 0.4436 0.0102 0.0137 6.9700 0.0932 0.1160 38.2000 54.8000 0.8219 0.2390 0.4593 0.0927 42.8000 0.3944 0.4555 1.7291 0.2069 0.6109 1.9711 79.0000 1.2079 0.1095 0.2153 0.1674 0.3828 0.2508 0.7168 0.1588 0.1869 0.1430 0.1640 0.2138 0.9309 0.2249 0.1802 0.1918 0.2294 0.1808 0.1518 88.3000 0.3193 0.9998 1.2644 0.4871 0.2696 0.5610 0.7467 1.8384 0.1354 0.1170 0.1354 0.1900 0.2180 0.1084 0.0946 0.1870 0.1264 0.1332 0.1221 0.1262 0.1562 0.1047 0.3296 0.1486 0.1814 0.1313 0.1290

0.1586 0.4274 0.0436 0.2816

...

0.6045 0.4883 0.1312 0.3351 0.2044

...

0.1216

... ...

_.

--

8.2064 0.0878

_.

... ...

---.... .....

... .-. ... ...

... ... ....

0.1074 0.1696 0.1528 0.2628

...

0.4791

...

... 0.1261 ... ...

0.8936

...

...

_.

0.1592 0.1605

... ... ... ... ... ... .., ... _.

...

... ..0.1214

... ... ...

... ...

0.1173 0.1216 0.1107 0.1148 0.1273

-'

... 0.1460

...

0.1297 0.1236

0.1364 0.3227 0.0159 0.3542 0.0779 0.4272 0.4954 0.1053 0.4139 0.1027 0.1263 0.0727 0.1535 0.5160 0.0179 0.0194 12.8300 0.0510 0.0260 49.4000 19.9000 1.0806 0.2620 0.5033 0.0312 70.7000 0.3948 0.4836 1.7296 0.1526 0.6527 2.9710 97.8000 1.6781 0.0571 0.1003 0.0745 0.1832 0.0993 0.2433 0.1139 0.0759 0.0950 0.0520 0.1573 0.3770 0.1243 0.0925 0.1000 0.0987 0.0971 0.0795 43.8000 0.1218 1.0199 1.6161 0.5167 0.2784 0.6004 1.2427 1.9799 0.0601 0.0540 0.0632 0.0610 0.2306 0.0515 0.0471 0.1570 0.0514 0.0935 0.0841 0.0656 0.1147 0.0611 0.2828 0.0768 0.1240 0.0650 0.1053

Table 8 Thermal Conductivity of Liquid· Inorganic Compounds k NO 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 168 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 218 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240

ID 3397 3398 3451 3461 3483 3504 3637 3781 3940 3974 3991 3994 3996 3998 4001 4004 4005 4006 4007 4008 4010 4013 4023 4025 4042 4044 4047 4049 4089 4107 4110 4115 4143 4143.1 4144 4149 4150 4152 4153 4157 4187 4196 4238 4240 4241 4243 4244 4245 4246 4247 4248 4250 4251 4252 4253 4257 4258 4259 4260 4261 4274 4275 4288 4287 4288 4288.1 4289 4290 4291 4295 4298 4297 4300 4333 4335 4422 4424 4431 4433 4515

FORMULA PSBr3 PSCI3 P2S5 P406 Pb PbC8H20 Pm Ab An AuF5 S SCI2 SCI20 SF4 SF6 SOBr2 SOCl2 5OF2 S02 S02C12 503 S2CI2 Sb SbBr3 SbCI3 SbCI5 SbH3 Sbl3

Sees seCI4 SeF6

seooa SiBrCI2F SiBrF3 SIBr2CIF SiCH3C13 SICH4CI2 SIC2H5CI3 SIC2H6CI2 SiC3Hl0 SIC7H8CI2 SIC8H20 SICIC3H9 SiCIF3 SiCl2F2 SICI3F SiCI4 SiF4 S1HBr3 S1HCI3 SiHF3 SIH2Br2 SIH2CI2 SIH2F2 SIH212 SIH3Br SiH3CI SIH3F SiH31 SiH4 S12C8H180 S12C6H19N S12CI6 Si2CI60 Si2F6 Si2H5CI SI2H6 Si2H60 Si2OCl3F3 Si3CI8 Si3H8 Si3H9N Si4Hl0 Sn SnBr4 SnCI2 SnCI4 SnH4 Snl4 T2

NAME phosphorusthiobromide phosphorusthiochloride phosphorus(v) sulfide phosphorous(III)oldde lead tetraethyllead promethium rubidium radon ruthenium(v) fluoride sulfur sulfur dichloride thlonyl chloride sulfur tetrafluoride sulfur hexafluoride thlonyl bromide thlonyl chloride thlonyl fluoride sulfur dioldde sulfuryl chloride sulfur trioldde sulfur monochloride antimony antimonytribromlde antimonytrichloride antimonypentachloride stibine antimonytriiodide selenosulflde, carbon seleniumtetrachloride seleniumhexafluoride seleniumoxychloride silane, bromodichlorofluoro silane, bromotrifluoro silane, dlbromochlorofluoro silane, methyltrichloro silane, methyldichloro silane, ethyltrichloro silane, dlmethyldlchloro silane, trimethyl silane, methylphenyldlchloro silane, tetraethyl chlorotrimethylsllane silane, chlorotrifluoro silane, dlchlorodifluoro silane, trichlorofluoro silicon tetrachloride silicon tetrafluoride silane, tribromo silane, trichloro silane, trifluoro silane, dlbromo silane, dlchloro silane, dlfluoro silane, dliodo silane, monobromo silane, monochloro silane, monofluoro sllane,lado silane dlslloxane,hexamethyl disllazane,hexamethyl disllane,hexachloro d1slloxane, hexachloro disilane, hexafluoro disllane,chloro dlsilane disiloxane disiloxane,trichlorotrifluoro oc1achlorotrisilane trisilane trisllazane tetrasllane tin (gray) stannic bromide stannouschloride stannicchloride stannane stannic Iodide tritium

CAS No 3931-89-3 3982'91-0 1314-80-3 1244(}OO-5 7439-92-1 78-00-2 7440-12-2 744lJ.17·7 10043-92-2 14521-18-7 7704-34-9 10545-99-0 7719-09-7 7783-6lJ.0 2551-62-4 507-16-4 7719-09·7 7783-42-8 7446·09-5 7791-25-5 7448-11-9 10025-67·9 7440-36-0 7789-61-9 10025-91-9 7647-18-9 7803-52-3 779lJ.44-5 5951-19-9 10026-03-6 7783-79-1 7791-23-3

---

--._75-79-6 75-54-7 115-21-9 75'78-5 933-07·7 149-74-6 631-36·7 75-77-4 14049-38-6 18356-71-3 t4965-52-7 tOO28-04-7 7763-61-1 7789-57-3 10025-78-2 13485-71-9 13768-94-0 4109-96.0 13824-38-7 1376lJ.02-6 13485-73-1 13485-78-8 13537-33-2 13598-42-0 7803-62-5 107-46-0 999-97·3 13465-77-5 14986-21-1

---

-1590-87-0 13597-73-4

-.. --7783-26-8 ---

7783-29-1 744lJ.31-5 7789-67-5 7772-99-8 7646-78-8 2406-52-2 779lJ.47-8 10028-17-8

A 0.1338 0.1853 0.2546 0.1602 -2.3034 0.1315 9.0978 38.3835 0.0955 0.1703 0.4295 0.2020 0.2181 0.2341 0.2544 0.1694 0.1974 0.2505 0.3822 0.2085 0.9288 0.2125 8.9936 0.1232 0.1604 0.1370 0.1999 0.1050 0.2191 0.1615 0.1378 0.1855 0.1734 0.1695 0.1568 0.2438 0.2196 0.1977 0.2214 0.2137 0.1728 0.1939 0.2234 0.2150 0.2064 0.1963 0.1370 0.2899 0.1508 0.2127 0.2423 0.1755 0.3105 0.2752 0.1443 0.2219 0.2890 0.3051 0.1870 0.2764 0.2206 0.1593 0.1448 0.1432 0.1535 0.2293 0.3005 0.2760 0.1471 0.1278 0.2559 0.2358 0.2225 19.9363 0.1980 0.1616 0.1736 0.2175 0.0936 -0.0020

401

2

=A+BT+CT B -4.4935E-05 -8.8258E-05 -1.3963E-04 -5.8241 E-05 3.6419E-02 ·1.4067E-04 6.3362E-G3 -1.6160E-02 -1.2434E-04 -5.3488E-05 -1.6117E·03 -2.5630E-04 -2.6516E-04 -1.6998E-04 -6.5950E-04 -8.6221 E-05 ·1.2157E-04 -1.5546E-04 -6.2540E-04 -2.7033E-04 -3.0803E-03 -1.1856E-04 2.5476E·02 -3.5768E·05 -1.4350E-04 -5.3077E-05 -1.1437E-04 -2.6214E-05 ·1.2504E-04 -6.1998E-05 1.0612E-04 -7.2606E-05 ·1.2039E-04 ·2.7093E-G5 -l.0064E·04 -3.3250E-04 -3.2153E-04 -1.7713E-04 -3.0075E·04 ·3.4520E-04 -1.7793E-04 ·2.2692E-04 -3.2106E-04 ·1.8107E-04 ·1.7459E-04 -1.4463E-04 ·1.2600E·04 ·1.0100E-03 -8.4590E-05 -3.2198E-04 -1.3314E-04 -9.7668E·05 -5.1350E-04 -1.5536E-04 -5.7123E-05 -1.3708E-04 -2.0728E-04 -6.0560E-05 -9.1803E-05 -9.8563E-04 -3.0769E-04 ·2.1825E-04 -5.7491E-05 -6.7458E-05 6.2233E-05 -6.1631E-05 -2.3899E-04 -2.3576E-04 -4.0323E-05 -5.6357E-05 -l.7790E-04 ·1.5710E-04 -1.3484E-04 2.0522E-02 ·2.0000E-04 -1.1786E-04 -1.9086E-04 ·l.9936E-04 ·2.4132E-05 9.2976E-03

(kna • W/(m K). T • K)

TMIN TMAX C -1.3213E-07 311.00 657.00 -2.1280E-07 237.00 575.00 O.OOOOE+OO 561.15 787.15 -1.8033E-07 296.00 643.00 -1.4616E-05 600.65 1000.00 O.OOOOE+OO 139.41 473.15 ·9.3220E-08 1353.00 2253.00 -4.1911E-07 312.04 1500.00 -1.9950E-07 211.00 360.00 -8.3035E-08 360.00 880.00 2.1742E-06 388.00 483.00 O.OOOOE+OO 151.15 332.65 O.OOOOE+OO 168.65 348.75 -8.9665E-07 149.00 328.00 O.OOOOE+OO 223.15 318.69 -1.6895E-07 221.00 596.00 -2.5795E-07 172.00 510.00 -9.8143E-07 163.00 334.00 O.OOOOE+OO 197.67 400.00 O.OOOOE+OO 219.00 342.55 2.6800E-06 289.95 481.47 -1.9856E·07 193.00 593.00 -7.3694E-06 903.89 1100.00 -7.9151E·08 370.00 803.00 O.OOOOE+OO 346.55 493.40 ·1.6073E-G7 276.00 596.00 -5.3519E-07 185.00 396.00 -4.3393E·08 440.00 968.00 -2.9305E-07 198.00 519.00 ·1.4201E-07 290.00 670.00 ·1.0358E-06 238.00 332.00 ·1.8405E·07 282.00 636.00 -3.0074E-07 161.00 447.00 -8.4434E-07 203.00 338.00 -2.3517E-07 174.00 482.00 O.OOOOE+OO 195.35 339.55 O.OOOOE+OO 182.55 314.70 -1.5448E-07 167.55 371.05 O.OOOOE+OO 197.05 343.35 O.OOOOE+OO 137.26 279.85 O.OOOOE+OO 229.65 477.35 O.OOOOE+OO 190.65 426.56 O.OOOOE+OO 215.45 330.75 -9.7185E-07 131.00 297.00 -5.9819E-07 133.00 352.00 -4.0204E·07 152.00 414.00 O.OOOOE+OO 283.15 330.00 O.OOOOE+OO 168.00 258.00 ·1.7490E-07 200.00 549.00 O.OOOOE+OO 144.95 378.00 -1.7375E-06 142.00 262.00 ·2.7088E·07 203.00 495.00 O.OOOOE+OO 151.15 413.15 -1.5992E-06 151.00 286.00 -1.6897E-07 272.00 594.00 -5.2949E-07 179.00 409.00 -8.9603E-07 155.00 357.00 ·2.6235E·06 155.00 258.00 -3.6543E-07 218.00 464.00 O.OOOOE+OO 88.15 161.00 O.OOOOE+OO 204.93 414.96 O.OOOOE+OO 293.15 399.15 -1.6883E-07 272.00 595.00 ·1.5464E-07 240.00 590.00 -8.2874E-07 255.00 370.00 ·5.6190E-07 254.00 456.00 -6.9282E-G7 141.00 389.00 -6.6397E-07 129.00 375.00 -3.5605E-07 254.00 458.00 -9.1772E-08 254.00 698.00 -3.7982E-G7 156.00 473.00 -3.7591E-07 167.00 466.00 -2.5461E-07 180.00 539.00 -8.3114E·09 505.12 1500.00 3.3437E-18 260.00 340.00 -1.7857E-07 260.00 340.00 -5.3333E-08 248.15 373.15 -7.5278E-G7 123.00 323.00 -4.6721E·08 418.00 910.00 -1.5476E-04 21.00 28.00

code k,o,0TMIN k,o,025C ..,.. OTMAX

2 2 2 2 1,2 2 2 1,2 2 2 1,2 2 2 2 2 2 2 2 1,2 2 1,2 2 1,2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 1,2 2 2 2 2 2 1,2 2 2 2 2 2 2 1,2 2 2 2 2 2 2 2 2 2 2 2 2 2 1,2 2 2 1,2 2 2 2

0.1070 0.1524 0.1762 0.1289 15.5000 0.1119 17.5000 33.3000 0.0604 0.1403 0.1315 0.1633 0.1734 0.1689 0.1072 0.1421 0.1689 0.1991 0.2586 0.1492 0.2593 0.1822 25.9000 0.0991 0.1106 0.1101 0.1604 0.0851 0.1829 0.1316 0.1044 0.1504 0.1462 0.1292 0.1321 0.1768 0.1609 0.1637 0.1621 0.1663 0.1319 0.1507 0.1542 0.1746 0.1726 0.1650 0.1013 0.1000 0.1269 0.1660 0.1884 0.1445 0.2329 0.2153 0.1163 0.1804 0.2353 0.2327 0.1501 0.1895 0.1575 0.0954 0.1167 0.1181 0.1155 0.1774 0.2530 0.2345 0.1139 0.1076 0.2189 0.1989 0.1900 30.3000 0.1460 0.1189 0.1230 0.1816 0.0753 0.1250

-_.

0.1401

----0.0896 ----0.0407 ----0.1286

0.1256 0.1390 0.1037 0.0578 0.1287 0.1362 0.1169 0.1957 0.1279 0.2469 0.1595

... ...

---

0.1069 0.1182 _

..

0.1558 0.1304 0.0774 0.1475 0.1108 0.0864 0.1058 0.1447 0.1237 0.1311 0.1317

---

0.1197 0.1263 0.1277

---

0.1012 0.1174 0.0994

.-

0.1100 0.1167

--.

0.1223 0.1574

---

0.1122 0.1340 0.1475

-----

0.1271 0.1288 0.0943 0.1127 0.1093 0.0984 0.1610 0.1677 0.1467 0.1034 0.1028 0.1691 0.1553 0.1597

_.-

0.1364 0.1106 0.1120 0.0911

..-

...

0.0472 0.0642 0.1446 0.0565 21.5000 0.0650 22.9000 13.2000 0.0249 0.0589 0.1583 0.1168 0.1256 0.0819 0.0442 0.0580 0.0683 0.0891 0.1320 0.1158 0.0624 0.0724 28.0000 0.0434 0.0895 0.0483 0.0707 0.0367 0.0753 0.0562 0.0589 0.0649 0.0595 0.0639 0.0536 0.1309 0.1184 0.1107 0.1181 0.1171 0.0878 0.0971 0.1172 0.0755 0.G708 0.0675 0.0954 0.0293 0.0516 0.0910 0.0681 0.0608 0.0983 0.1000 0.0508 0.0773 0.1008 0.1148 0.0657 0.1177 0.0929 0.0722 0.0508 0.0498 0.0631 0.0844 0.1027 0.0942 0.0539 0.0438 0.0868 0.0808 0.0759 50.7000 0.1300 0.1009 0.0950 0.0746 0.0330 0.1370

Table 8 Thermal Conductivity of Liquid - Inorganic Compounds (kuc, • W/(m K), T· K)

k. =A+BT+Cr NO

FORMULA tellurium 4583 Te 10

NAME

241 242 4590 TeF6 tellurium hexafluoride 243 4678 TiCI4 titanium tetrachloride 244 4860 VCI4 vanadium tetrachloride 245 4880 VOCI3 vanadium oxytrichloride 246 4899 W tungsten 247 4917 WF6 tungsten fluoride 248 4945 Xe xenon 249 5021 Zn zinc code: 1 - data, 2 - estimate k", - thermal conductivity of liquid, W/(m K) A. B, and C - regression coefficients for chemical compound T • temperature, K TMIN - minirrom temperature, K TMAX • maxlrrom temperature, K

A

CAS No 13494-80-9 7783-80-4 7550-45-0 7632-51-1 7727-18-6 7440.33-7 7783-82-6 7440.83-3 7440-66-6

B

C

-20.1697 4.5598E-02 -1.8924E-05 0.1286 5.6649E-05 -8. 1322E-07 -6.0740E-05 0.1745 0.1821 ·1.8219E-04 -1.9597E-04 e.ooooe-oo 0.1796 25.2529 1.7042E-02 -1.2785E-06 1.1726E-05 -4.4358E-07 0.1217 0.1465 ·4.8185E-04 1.9703E-07 8.7886 5.9442E-02 -9.7110E-07

402

-a.ooeoa-oz o.eooos-oo

TMIN 722.70 235.00 273.15 247.45 193.65 3660.00 273.00 161.00 692.73

TMAX code k",,0TMIN k",,025C k,.. OTMAX 1100.00 1,2 7.0900 2.9000 0.0970 0.0732 0.0529 342.00 2 373.15 1,2 0.1430 0.1386 0.1240 0.1047 425.00 2 0.1370 0.1278 0.1416 0.1211 0.1012 400.00 2 7000.00 2 81.9000 70.5000 0.0477 422.00 2 0.0918 0.0858 0.0270 280.00 1,2 0.0740 1100.00 1,2 49.5000 73.0000

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