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Prelims, contents pages
Polyhedron 23, issue 12, 29 July 2004 www.elsevier.com/locate/poly
Contents Papers Doyel Bose, Jaya Banerjee, Sk Hafijur Rahaman, Golam Mostafa, Hoong-Kun Fun, Rosa D. Bailey Walsh, Michael J. Zaworotko, Barindra Kumar Ghosh Polyhedron 23 (2004) 2045 Polymeric end-to-end bibridged cadmium(II)thiocyanates containing monodentate and bidentate N-donor organic blockers: supramolecular synthons based on p–p and/ or C–H p interactions
Qian-Ling Guo, Wen-Xiang Zhu, Ying-Chun Liu, Da-Qiang Yuan, Jing Zhang, Shu-Lan Ma Polyhedron 23 (2004) 2055 Anionic capsules of p-sulfonatothiacalix[4]arene with trivalent lanthanide ions and diaza-crown ether
Synthesis and X-ray structural characterisation of two neutral 1D polymers, [Cd(imH)2(NCS)(SCN)]n (1) and [Cd(pfan)(NCS)(SCN)]n (2) were carried out. In both polymers 1 and 2, octahedral CdII ions occupy centre of symmetry with a CdN4S2 chromophore. Supramers 1 and 2 display intraligand 1 ðp–p Þ fluorescence and intraligand 3 ðp–p Þ phosphorescence in glassy solutions (MeOH at 77 K).
The reaction of tetrasodium p-sulfonatothiacalix[4]arene and trivalent lanthanide ions in the presence of 4,13-diaza-18-crown-6 forms ionic capsules, and the diaza-crown ethers can also insert into the hydrophobic layers so that thiacalixarenes form irregular bi-layer structures.
SO 3 Na M(NO3)3+4 , 13 - diaza - 18 - Crown - 6+
S
pH < 3
4
OH
H 2O 3+
(M
3+
= La
OH OH OH S OH S S S
3 +)
SO 3
La(H2O)83+
OH OH OH S OH S S S
O HN
+
NH2
H 2N
O
SO3 +
S S OH
+
Eu(NO3)(H2O)72+
H 2N
+
2+
Eu(NO3)(H2O)7
O
SO 3
-
S OH S OH
O
SO-3
O3S
SO3SO3
OH
S S OH
S OH S OH OH
Soo Gyun Roh, Jong Uk Yoon, Jong Hwa Jeong Polyhedron 23 (2004) 2063 Synthesis and characterization of a chiral Zn(II) complex based on a trans-1,2-diaminocyclohexane derivative and catalytic reduction of acetophenone
Elsevier Ltd.
Reaction of ZnCl2with R; R-bmbcd (=N ; N 0 bis(4-methoxy-benzyl)-cyclohexane-1,2-diamine) yields the chiral [ZnCl2(R; R-bmbcd)] in which the Zn atom has a distorted tetrahedral geometry involving two nitrogen atoms of R; R-bmbcd and two chloro ligands. The catalytic enantioselective reduction of acetophenone promoted by R; R-bmbcd:Zn(OTf)2=1:1 mole ratio in the presence of catecholborane give (S)-())-1-phenylethanol in 48% ee with 77% yield.
O
.
.
.
. .
.
.
. .
.
Cl
N
Zn
. .
Cl
. N .
.
. . . .
.
. O
O O H2N
O
O NH2
La(H2O)83+
SO3-
SO-3
SO3-
+
O
SO-3
+
NH2 O O
-O S 3
O
O
O 3S
Eu )
O
SO-3
SO 3-
3+
NH O O
-O S 3
-
(M =
.
iv
Angela C. Raimondi, Vagner R. de Souza, Henrique E. Toma, Antonio S. Mangrich, Tai Hasegawa, F abio S. Nunes Polyhedron 23 (2004) 2069 An unusual vanadium(II) promoted hydrogenation of a magnesium tetraiminediphenolate compound yielding an asymmetric oxovanadium(IV) macrocyclic complex
Alexandra L. Pickering, Geoffrey J.T. Cooper, De-Liang Long, Leroy Cronin Polyhedron 23 (2004) 2075 Facile synthesis and structures of infinite one-dimensional silver(I) coordination polymers
Alan Hazell Polyhedron 23 (2004) 2081
Contents
The [VO(didadf)(H2O)](BF4)2(didadf=diiminediaminediphenolate ligand) complex and its characterization are described. This compound was obtained from the reaction between [V(H2O)6]2+ and the tetraiminediphenolate macrocyclic ligand under severe inert atmosphere conditions through an unusual hydrogenation reaction.
The synthesis and structural characterization of three new silver(I) coordination compounds are reported. Each represents an infinite tubular coordination network that is isolated within a three-dimensional hydrogen-bonded network involving counter ions. Both the silver(I) ions and the two triamino ligands are three-connected nodes, forming a 42 6 topological network.
Deviations from planarity of the bipyridine ligand are discussed in terms of bow and twist angles and an S-shaped deformation.
N 50 45 40
Is bipyridine planar in metal complexes?
35 30 25 20 15 10 5 0 0.0
Chang-Yan Sun, Lin-Pei Jin Polyhedron 23 (2004) 2085 Hydrothermal synthesis and characterization of the first examples of lanthanide(III) isoorotates with a 3D supramolecular network
The structures of the first examples of lanthanide(III) isoorotates are reported. Their 3D supramolecular networks are formed by O–H O, N–H O and/or N–H N hydrogen bonds, and/or p–p stacking interactions.
3.0
6.0
9.0
12.0
15.0
18.0
21.0
24.0
27.0
Angle between planes φ
Contents
Polyhedron 23 (2004) 2095 Synthesis, characterization, thermodynamic and thermal studies of Zn(II) complexes with di-2-pyridyl ketone salicyloylhydrazone
Zinc(II) in aqueous/ethanolic (50% V/V), pH 4.5, solution forms with di-2-pyridyl ketone salicyloylhydrazone (DPKSH) two complexes, [Zn(C18H13N4O2)]+ and [Zn(C18H13N4O2)2], which were characterized by electron ionization and electrospray mass spectra, IR, thermogravimetry (TG) and differential scanning calorimetry (DSC). The overall formation constants and the molar absorptivies were obtained for both of the complexes.
100
80 Zn(II)(DPKSH)2
Zn(II)
60 α(%)
Ivanise Gaubeur, Ma´rcia Guekezian, ´ vila Terra, Lu´cia H.S. A Maria Carolina B. Moraes, Claudimir L. Lago, Jivaldo R. Matos, Maria Encarnacio´n V. Sua´rez-Iha
v
40
20 Zn(II)DPKSH
0 -7
-6
-5
-4
-3
log[DPKSH] mol/L
Synthesis, characterisation and thermal decomposition of tin(IV) dithiocarbamate derivatives – single source precursors for tin sulfide powders
Sung-Nak Choi, Woo-Sung Jung, Min-Joo Lee, Yong-Min Lee, Young-Inn Kim Polyhedron 23 (2004) 2111 Synthesis and physicochemical properties of charge transfer compounds derived from the reaction of tetrathiafulvalene with copper(II)
The powdered electrical conductivities of some (TTF)4CuX2 (X=NCS, NO3, Br and Cl) compounds are in the semiconductor region (rr.t=100–101 S cm)1), whereas the other compounds (X=NCO and NO2) are in the insulator range (rr.t<10)4 S cm)1) at room temperature.
4
(TTF)4Cu(NCS)2
3
Cu(Sp)(NCS)2
Absorbance
Polyhedron 23 (2004) 2103
The reaction of ammonium pyrrolidinedithiocarbamate with SnPh2Cl2 and SnPh3Cl produced in good yield the compounds [Sn{S2CN(CH2)4}2{C6H5}2]Ætoluene (1) and Sn{S2CN(CH2)4}{C6H5}3 (2). They were fully characterised by multinuclear NMR [1H,13C{1H} and 119Sn{1H}] and 119 Sn Mo¨ssbauer spectroscopies.
Absorbance
D.C. Menezes, G.M. de Lima, A.O. Porto, C.L. Donnici, J.D. Ardisson, A.C. Doriguetto, J. Ellena
0.6
(f)
0.4
(e) (d) (c) (b)
0.2
(a)
2 0.0 540
570
600
Wavelength (nm)
1
TTF
0 400
500
600
Wavelength (nm)
700
vi
Contents
The Publisher encourages the submission of articles in electronic form thus saving time and avoiding rekeying errors. For detailed instructions on the preparation of manuscripts and of electronic artwork, consult the Author Gateway for Elsevier at http://authors.elsevier.com
Full text of this journal is available, on-line from ScienceDirect. Visit www.sciencedirect.com for more information.
Contents Papers Doyel Bose, Jaya Banerjee, Sk Hafijur Rahaman, Golam Mostafa, Hoong-Kun Fun, Rosa D. Bailey Walsh, Michael J. Zaworotko, Barindra Kumar Ghosh Polyhedron 23 (2004) 2045 Polymeric end-to-end bibridged cadmium(II)thiocyanates containing monodentate and bidentate N-donor organic blockers: supramolecular synthons based on p–p and/ or C–H p interactions
Qian-Ling Guo, Wen-Xiang Zhu, Ying-Chun Liu, Da-Qiang Yuan, Jing Zhang, Shu-Lan Ma Polyhedron 23 (2004) 2055 Anionic capsules of p-sulfonatothiacalix[4]arene with trivalent lanthanide ions and diaza-crown ether
Synthesis and X-ray structural characterisation of two neutral 1D polymers, [Cd(imH)2(NCS)(SCN)]n (1) and [Cd(pfan)(NCS)(SCN)]n (2) were carried out. In both polymers 1 and 2, octahedral CdII ions occupy centre of symmetry with a CdN4S2 chromophore. Supramers 1 and 2 display intraligand 1 ðp–p Þ fluorescence and intraligand 3 ðp–p Þ phosphorescence in glassy solutions (MeOH at 77 K).
The reaction of tetrasodium p-sulfonatothiacalix[4]arene and trivalent lanthanide ions in the presence of 4,13-diaza-18-crown-6 forms ionic capsules, and the diaza-crown ethers can also insert into the hydrophobic layers so that thiacalixarenes form irregular bi-layer structures.
SO 3 Na M(NO3)3+4 , 13 - diaza - 18 - Crown - 6+
S
pH < 3
4
OH
H 2O 3+
(M
3+
= La
OH OH OH S OH S S S
3 +)
SO 3
La(H2O)83+
OH OH OH S OH S S S
O HN
+
NH2
H 2N
O
SO3 +
S S OH
+
Eu(NO3)(H2O)72+
H 2N
+
2+
Eu(NO3)(H2O)7
O
SO 3
-
S OH S OH
O
SO-3
O3S
SO3SO3
OH
S S OH
S OH S OH OH
Soo Gyun Roh, Jong Uk Yoon, Jong Hwa Jeong Polyhedron 23 (2004) 2063 Synthesis and characterization of a chiral Zn(II) complex based on a trans-1,2-diaminocyclohexane derivative and catalytic reduction of acetophenone
Elsevier Ltd.
Reaction of ZnCl2with R; R-bmbcd (=N ; N 0 bis(4-methoxy-benzyl)-cyclohexane-1,2-diamine) yields the chiral [ZnCl2(R; R-bmbcd)] in which the Zn atom has a distorted tetrahedral geometry involving two nitrogen atoms of R; R-bmbcd and two chloro ligands. The catalytic enantioselective reduction of acetophenone promoted by R; R-bmbcd:Zn(OTf)2=1:1 mole ratio in the presence of catecholborane give (S)-())-1-phenylethanol in 48% ee with 77% yield.
O
.
.
.
. .
.
.
. .
.
Cl
N
Zn
. .
Cl
. N .
.
. . . .
.
. O
O O H2N
O
O NH2
La(H2O)83+
SO3-
SO-3
SO3-
+
O
SO-3
+
NH2 O O
-O S 3
O
O
O 3S
Eu )
O
SO-3
SO 3-
3+
NH O O
-O S 3
-
(M =
.
iv
Angela C. Raimondi, Vagner R. de Souza, Henrique E. Toma, Antonio S. Mangrich, Tai Hasegawa, F abio S. Nunes Polyhedron 23 (2004) 2069 An unusual vanadium(II) promoted hydrogenation of a magnesium tetraiminediphenolate compound yielding an asymmetric oxovanadium(IV) macrocyclic complex
Alexandra L. Pickering, Geoffrey J.T. Cooper, De-Liang Long, Leroy Cronin Polyhedron 23 (2004) 2075 Facile synthesis and structures of infinite one-dimensional silver(I) coordination polymers
Alan Hazell Polyhedron 23 (2004) 2081
Contents
The [VO(didadf)(H2O)](BF4)2(didadf=diiminediaminediphenolate ligand) complex and its characterization are described. This compound was obtained from the reaction between [V(H2O)6]2+ and the tetraiminediphenolate macrocyclic ligand under severe inert atmosphere conditions through an unusual hydrogenation reaction.
The synthesis and structural characterization of three new silver(I) coordination compounds are reported. Each represents an infinite tubular coordination network that is isolated within a three-dimensional hydrogen-bonded network involving counter ions. Both the silver(I) ions and the two triamino ligands are three-connected nodes, forming a 42 6 topological network.
Deviations from planarity of the bipyridine ligand are discussed in terms of bow and twist angles and an S-shaped deformation.
N 50 45 40
Is bipyridine planar in metal complexes?
35 30 25 20 15 10 5 0 0.0
Chang-Yan Sun, Lin-Pei Jin Polyhedron 23 (2004) 2085 Hydrothermal synthesis and characterization of the first examples of lanthanide(III) isoorotates with a 3D supramolecular network
The structures of the first examples of lanthanide(III) isoorotates are reported. Their 3D supramolecular networks are formed by O–H O, N–H O and/or N–H N hydrogen bonds, and/or p–p stacking interactions.
3.0
6.0
9.0
12.0
15.0
18.0
21.0
24.0
27.0
Angle between planes φ
Contents
Polyhedron 23 (2004) 2095 Synthesis, characterization, thermodynamic and thermal studies of Zn(II) complexes with di-2-pyridyl ketone salicyloylhydrazone
Zinc(II) in aqueous/ethanolic (50% V/V), pH 4.5, solution forms with di-2-pyridyl ketone salicyloylhydrazone (DPKSH) two complexes, [Zn(C18H13N4O2)]+ and [Zn(C18H13N4O2)2], which were characterized by electron ionization and electrospray mass spectra, IR, thermogravimetry (TG) and differential scanning calorimetry (DSC). The overall formation constants and the molar absorptivies were obtained for both of the complexes.
100
80 Zn(II)(DPKSH)2
Zn(II)
60 α(%)
Ivanise Gaubeur, Ma´rcia Guekezian, ´ vila Terra, Lu´cia H.S. A Maria Carolina B. Moraes, Claudimir L. Lago, Jivaldo R. Matos, Maria Encarnacio´n V. Sua´rez-Iha
v
40
20 Zn(II)DPKSH
0 -7
-6
-5
-4
-3
log[DPKSH] mol/L
Synthesis, characterisation and thermal decomposition of tin(IV) dithiocarbamate derivatives – single source precursors for tin sulfide powders
Sung-Nak Choi, Woo-Sung Jung, Min-Joo Lee, Yong-Min Lee, Young-Inn Kim Polyhedron 23 (2004) 2111 Synthesis and physicochemical properties of charge transfer compounds derived from the reaction of tetrathiafulvalene with copper(II)
The powdered electrical conductivities of some (TTF)4CuX2 (X=NCS, NO3, Br and Cl) compounds are in the semiconductor region (rr.t=100–101 S cm)1), whereas the other compounds (X=NCO and NO2) are in the insulator range (rr.t<10)4 S cm)1) at room temperature.
4
(TTF)4Cu(NCS)2
3
Cu(Sp)(NCS)2
Absorbance
Polyhedron 23 (2004) 2103
The reaction of ammonium pyrrolidinedithiocarbamate with SnPh2Cl2 and SnPh3Cl produced in good yield the compounds [Sn{S2CN(CH2)4}2{C6H5}2]Ætoluene (1) and Sn{S2CN(CH2)4}{C6H5}3 (2). They were fully characterised by multinuclear NMR [1H,13C{1H} and 119Sn{1H}] and 119 Sn Mo¨ssbauer spectroscopies.
Absorbance
D.C. Menezes, G.M. de Lima, A.O. Porto, C.L. Donnici, J.D. Ardisson, A.C. Doriguetto, J. Ellena
0.6
(f)
0.4
(e) (d) (c) (b)
0.2
(a)
2 0.0 540
570
600
Wavelength (nm)
1
TTF
0 400
500
600
Wavelength (nm)
700
vi
Contents
The Publisher encourages the submission of articles in electronic form thus saving time and avoiding rekeying errors. For detailed instructions on the preparation of manuscripts and of electronic artwork, consult the Author Gateway for Elsevier at http://authors.elsevier.com
Full text of this journal is available, on-line from ScienceDirect. Visit www.sciencedirect.com for more information.