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Coprocessing of 4-(1-naphthylmethyl)bibenzyl with waste tires using finely dispersed iron and molybdenum catalysts
02
Liquid fuels (derived liquid fuels)
95tQ2444 1995 Retall Marketing Sunroy Petroleum Review, Supplement, Mar. 1995, 49, (578), l-32. A 1995 UK Retail Marketing Survey of the petroleum industry.
Characterlstlcs of solid residue samples and Its evolution In a slmulatlon experiment of generation and mlgratlon of coal-formed hydrocarbon Lu, S. et al., Shiyou Kantan Yu Kaga, 1994, 21, (3), 46-51. (In Chinese)
The role of loglstlcs plannlng models In the downstream Industry
Based on data ac uired from a pressurized thermal simulation experiment in which both o 9 generation and expulsion from two brown coals are inspected, the characteristics of elemental composition and carbon isotope composition of kerogen as well as features of organic petrology and PYGC of simulated residue samples and its evolution are analyzed.
95102445
Sear, T. N. Petroleum Rev.. Feb. 1995, 49, (5771, 58, 60. In today’s climate the customer differentiates‘behcen suppliers as much by price as by brand. Minimisation of total supply chain costs therefore remains a high priority for petroleum product marketing companies. The article describes key logistrcs planning decisions facing the marketing company. The role of Logistics Planning Models in supply chain optimisation and marketing strategy are indicated.
The selection of staff for North Sea petroleum
95102446
lnstallatlons Whyte, F. et al., Petroleum Rev., Feb. 1995, 49, (577), 72-73. The article discusses the selection of personnel for offshore work.
Reader, C. Petroleum Review, Mar. 1995, 49, (578), p. 124. Reports that Syria wants to attract new investors in its oil and gas industry. The oil outuut for the country has tripled in the last 10 years and further expansion, is well as gas growth is p&ted. However, wtiile new discoveries are still being made, some foreign companies have chosen to leave and go elsewhere.
Derived Liquid Fuels
The effects of process variables on the activity of a CoMZSM-5 zeolite bifunctional catalyst for the conversion of syngas to hydrocarbons were studied. The catalyst was repared by incipient-wetness impregnation from aqueous solutions of wba Pt and thorium mtrate, the latter used as promoter. The reactions were carried out in a fixed-bed integral reactor.
95102455 Coal llquefactlon wlth controlled lrradlatlon of ultrasonlc wave Kawabata, M. et al., (Assigned to) Shinnippon Seitetsu KK, JAP. Pat. JP.O6,220,457, Aug. 1994. Coal slurry and solvent is liquefied in the presence of catalyst under hi@pressure of H, atmosphere with irradiation of ultrasonic wave for a period of time which is automated by pre-measuring viscosity of the slurry from the properties of the solvent followed by determining proper time from the viscosity and the amounts of the slurry.
The appllcatlon of PIXE/PIGE anslysls to Ilquefsc-
95102448
tlon studles Lafferty, C. J. et al., Prepr. Pap.-Am. Chem. Sot., Div. Fuel Chem., 1994, 39, (3), 810-814. Elemental analysis with a high energy charged-particle beam is a powerful analytical tool that has moved out of the realm of the specialized ‘nuclear’ laboratory and found widespread use among researchers in many different areas is described. 95102449 Aqueous organic chemistry. 8. Reactlvlty of blaryls Siskin, M. er aZ., Energy & Fuels, Mar.-Apr. 1995, 9, (2), 331-343. Biphenyl, or more accurately biaryl, linkages represent the most refractory cross-links in fossil fuel resources. They are essentially unreactive thermally and in supercritical water at 4@C. Many bia$s do, however, undergo bond cleavage and heteroatom removal under reducing conditions in supercritical water. 2-Arylpyridines, -quinolines, and -indoles are most reactive in 15% aqueous formic acid whereas the corresponding 2-arylthiophene and -benzothiophene derivatives are more reactive in 15% aqueous sodium formate. Major hydrocarbon products are benzene and naphthalene and their C,-C, alkylatcd derivatives. In most cases where conversion is not quantitative after lhr at 460°C the product slate consists of hydrogenated and cleaved products which, given more reaction time, are on the pathway toward complete heteroatom removal.
Assessment of donatable hydrogen content In solvents and heavy oils by catalytic al.,
Prepr.-Am.
Chem. Sot., Div. Pet Chem.,
Coal llquefactlon wlth emphasis on a swelling
95102456
phenomenon Sakaki, T. Kagaku Kogaku, 1994, 58, (12), 964-969. (In Japanese) The paper discusses coal swelling phenomena and improving coal liquefaction characteristics by using solvent swelling. Coal liquefying reaction inside a preheater, swelling and dissolving and collapsing of coal particles, changes of viscosity and heat transfer coefficients of coal slurries, coal swelling during heating, and swelling in improving coal liquefaction characteristics.
Corn arlson by g.c.-m.8. of llquefactlon extracts 95102457 from coal maceraPconcentrates Brodzki, D. et a& Fuel, Mar. 1995, 74, (3), 407-415. Differences between the compositions of partly hydrocracked hexane-soluble extract fractions from the liquefaction of maceral wncentrates were investigated by gas chromatography-mass spectrometry. The technique identifies components within only a relatively narrow range of molecular masses, but some systematic differences were nevertheless observed. Dibenzofuran derivates were significantly more abundant in extracts derived from inertinite wncentrate than in liptinite or vitrinite extracts. Within the retention time interval where dibenzofiuan and its derivatives were identified in inertinite extracts, products prepared from liptinite and vitrinite concentrates were found primarily to contain biphenyls and acenaphthene derivatives.
1994, 39, (3).
Donatabie hydrogen content in coal, recycle solvents and heavy oils is studied by using catalytic dehydro enation. Discusses the nature of hydrogen donors in the direct coal hque Baction and the effect of phenolic Groups on catalytic removal of hydroaromatic hydrogen, and determination of hydrogen donor ability of recycle oils. 95102451 Acldlanus
95102454 Co/HZSM-5 catalyst for syngar converslon: Influence of process variables Calleja,G. et al., Fuel, Mar. 1995, 74, (3), 445-451.
Syria wants to attract new Investors
95102447
I$,;26el
95102453
Blo eneratlon of Iron-based catalyst precursors by brler Beyi on high- and low-pyrite coals for direct
Competltlve converslon of nltro en and sulfur 95102458 compounds In naphtha with transltlon metal susfide catalysts I_F6;&
J. et al., Piepr.-Am.
The paper discusses supported catalysts for the denitrogenation naphtha.
Chem. Sot., Div. Pet. Chem., 1994, 39, (4), transition metal sulphides as prospective and hydrodesulphurization of coal-derived
llquefactlon Murty, M. V. et al., Energy & Fuels, Mar.-Apr. 1995, 9, (2), 308-313. Discusses the treatment of high-pyrite, high-sulphur Illmois coals and pyrite-free Blind Canyon coal with added pyrite in the presence of Acidianus brierlyi showed formation of iron oxyhydroxide particles and subsequent sulpluding caused enhancement in liquefaction and oil yield.
Catalvtlc behavlour of carbon-supported FeM (M=Ru, Pt) In pyrldine hydrodenltrogenatlon _
95102452
Guerrero-Ruiz. A. et al.. Fuel. Feb. 1995. 74. (21. 279-283. Carbon-supported one-&mpon&t (Fe, Ru, ‘Pt) andtwo-component (FeRu and FePt) catalysts were used for hydrodenitrogenation of pyridine (HDN) at 3.0 MPa and 573K. The Fe catalyst was less active for pyridine wnversion and less selective for the formation of n-pentane than the noble metal catalyst were. For the two-component catalysts, activity was closely related to that of the noble metal component, although the C, hydrocarbon distribution was intermediate between that for the single components. Photoelectron spectra of sulphided and used catalysts showed that iron and ruthenium monowmponent catalysts are sulphided to a large extent, but platinum preserves in part its metallic character, although the situation differs from the platinum-iron catalysts.
95102459 Coproceaslng of 4-(1.naphthylmethyl)blbenzyl with waste tires uelng finely dispersed Iron and molybdenum catalysts Tang, Y. and Curtis, C. W. Prepr. Pap.-Am. Chem. Sot., Div. Fuel Chem., 1994, 39, (3), 865-869. To evaluate the effect of waste tyres on coal liquefaction, waste tyre and of 4-(1carbon black were reacted in the naphthylmethyl)bibenzyl, a model coal compound Ei$TE hydrocrack at liquefaction conditions.
95102460 CPMAS and DDMAS “C NMR analysis of coal Ilquefactlon residues Song,C. er al., Prepr.Pap.-Am Chem. Sot., Div. Fuel Chem., 1994, 39, (31. 782-786. ?& work describes solid-state 13C NMR studies of residues of two subbituminous coals from their liquefaction at 300-425’C, using cross-polarization, dipolar, dephasing and inagic-angle-spinning techniques. Three types of samples were examined in the study.
Fuel and Energy Abstracts Msy 1995
181
Liquid fuels (derived liquid fuels)
95tQ2444 1995 Retall Marketing Sunroy Petroleum Review, Supplement, Mar. 1995, 49, (578), l-32. A 1995 UK Retail Marketing Survey of the petroleum industry.
Characterlstlcs of solid residue samples and Its evolution In a slmulatlon experiment of generation and mlgratlon of coal-formed hydrocarbon Lu, S. et al., Shiyou Kantan Yu Kaga, 1994, 21, (3), 46-51. (In Chinese)
The role of loglstlcs plannlng models In the downstream Industry
Based on data ac uired from a pressurized thermal simulation experiment in which both o 9 generation and expulsion from two brown coals are inspected, the characteristics of elemental composition and carbon isotope composition of kerogen as well as features of organic petrology and PYGC of simulated residue samples and its evolution are analyzed.
95102445
Sear, T. N. Petroleum Rev.. Feb. 1995, 49, (5771, 58, 60. In today’s climate the customer differentiates‘behcen suppliers as much by price as by brand. Minimisation of total supply chain costs therefore remains a high priority for petroleum product marketing companies. The article describes key logistrcs planning decisions facing the marketing company. The role of Logistics Planning Models in supply chain optimisation and marketing strategy are indicated.
The selection of staff for North Sea petroleum
95102446
lnstallatlons Whyte, F. et al., Petroleum Rev., Feb. 1995, 49, (577), 72-73. The article discusses the selection of personnel for offshore work.
Reader, C. Petroleum Review, Mar. 1995, 49, (578), p. 124. Reports that Syria wants to attract new investors in its oil and gas industry. The oil outuut for the country has tripled in the last 10 years and further expansion, is well as gas growth is p&ted. However, wtiile new discoveries are still being made, some foreign companies have chosen to leave and go elsewhere.
Derived Liquid Fuels
The effects of process variables on the activity of a CoMZSM-5 zeolite bifunctional catalyst for the conversion of syngas to hydrocarbons were studied. The catalyst was repared by incipient-wetness impregnation from aqueous solutions of wba Pt and thorium mtrate, the latter used as promoter. The reactions were carried out in a fixed-bed integral reactor.
95102455 Coal llquefactlon wlth controlled lrradlatlon of ultrasonlc wave Kawabata, M. et al., (Assigned to) Shinnippon Seitetsu KK, JAP. Pat. JP.O6,220,457, Aug. 1994. Coal slurry and solvent is liquefied in the presence of catalyst under hi@pressure of H, atmosphere with irradiation of ultrasonic wave for a period of time which is automated by pre-measuring viscosity of the slurry from the properties of the solvent followed by determining proper time from the viscosity and the amounts of the slurry.
The appllcatlon of PIXE/PIGE anslysls to Ilquefsc-
95102448
tlon studles Lafferty, C. J. et al., Prepr. Pap.-Am. Chem. Sot., Div. Fuel Chem., 1994, 39, (3), 810-814. Elemental analysis with a high energy charged-particle beam is a powerful analytical tool that has moved out of the realm of the specialized ‘nuclear’ laboratory and found widespread use among researchers in many different areas is described. 95102449 Aqueous organic chemistry. 8. Reactlvlty of blaryls Siskin, M. er aZ., Energy & Fuels, Mar.-Apr. 1995, 9, (2), 331-343. Biphenyl, or more accurately biaryl, linkages represent the most refractory cross-links in fossil fuel resources. They are essentially unreactive thermally and in supercritical water at 4@C. Many bia$s do, however, undergo bond cleavage and heteroatom removal under reducing conditions in supercritical water. 2-Arylpyridines, -quinolines, and -indoles are most reactive in 15% aqueous formic acid whereas the corresponding 2-arylthiophene and -benzothiophene derivatives are more reactive in 15% aqueous sodium formate. Major hydrocarbon products are benzene and naphthalene and their C,-C, alkylatcd derivatives. In most cases where conversion is not quantitative after lhr at 460°C the product slate consists of hydrogenated and cleaved products which, given more reaction time, are on the pathway toward complete heteroatom removal.
Assessment of donatable hydrogen content In solvents and heavy oils by catalytic al.,
Prepr.-Am.
Chem. Sot., Div. Pet Chem.,
Coal llquefactlon wlth emphasis on a swelling
95102456
phenomenon Sakaki, T. Kagaku Kogaku, 1994, 58, (12), 964-969. (In Japanese) The paper discusses coal swelling phenomena and improving coal liquefaction characteristics by using solvent swelling. Coal liquefying reaction inside a preheater, swelling and dissolving and collapsing of coal particles, changes of viscosity and heat transfer coefficients of coal slurries, coal swelling during heating, and swelling in improving coal liquefaction characteristics.
Corn arlson by g.c.-m.8. of llquefactlon extracts 95102457 from coal maceraPconcentrates Brodzki, D. et a& Fuel, Mar. 1995, 74, (3), 407-415. Differences between the compositions of partly hydrocracked hexane-soluble extract fractions from the liquefaction of maceral wncentrates were investigated by gas chromatography-mass spectrometry. The technique identifies components within only a relatively narrow range of molecular masses, but some systematic differences were nevertheless observed. Dibenzofuran derivates were significantly more abundant in extracts derived from inertinite wncentrate than in liptinite or vitrinite extracts. Within the retention time interval where dibenzofiuan and its derivatives were identified in inertinite extracts, products prepared from liptinite and vitrinite concentrates were found primarily to contain biphenyls and acenaphthene derivatives.
1994, 39, (3).
Donatabie hydrogen content in coal, recycle solvents and heavy oils is studied by using catalytic dehydro enation. Discusses the nature of hydrogen donors in the direct coal hque Baction and the effect of phenolic Groups on catalytic removal of hydroaromatic hydrogen, and determination of hydrogen donor ability of recycle oils. 95102451 Acldlanus
95102454 Co/HZSM-5 catalyst for syngar converslon: Influence of process variables Calleja,G. et al., Fuel, Mar. 1995, 74, (3), 445-451.
Syria wants to attract new Investors
95102447
I$,;26el
95102453
Blo eneratlon of Iron-based catalyst precursors by brler Beyi on high- and low-pyrite coals for direct
Competltlve converslon of nltro en and sulfur 95102458 compounds In naphtha with transltlon metal susfide catalysts I_F6;&
J. et al., Piepr.-Am.
The paper discusses supported catalysts for the denitrogenation naphtha.
Chem. Sot., Div. Pet. Chem., 1994, 39, (4), transition metal sulphides as prospective and hydrodesulphurization of coal-derived
llquefactlon Murty, M. V. et al., Energy & Fuels, Mar.-Apr. 1995, 9, (2), 308-313. Discusses the treatment of high-pyrite, high-sulphur Illmois coals and pyrite-free Blind Canyon coal with added pyrite in the presence of Acidianus brierlyi showed formation of iron oxyhydroxide particles and subsequent sulpluding caused enhancement in liquefaction and oil yield.
Catalvtlc behavlour of carbon-supported FeM (M=Ru, Pt) In pyrldine hydrodenltrogenatlon _
95102452
Guerrero-Ruiz. A. et al.. Fuel. Feb. 1995. 74. (21. 279-283. Carbon-supported one-&mpon&t (Fe, Ru, ‘Pt) andtwo-component (FeRu and FePt) catalysts were used for hydrodenitrogenation of pyridine (HDN) at 3.0 MPa and 573K. The Fe catalyst was less active for pyridine wnversion and less selective for the formation of n-pentane than the noble metal catalyst were. For the two-component catalysts, activity was closely related to that of the noble metal component, although the C, hydrocarbon distribution was intermediate between that for the single components. Photoelectron spectra of sulphided and used catalysts showed that iron and ruthenium monowmponent catalysts are sulphided to a large extent, but platinum preserves in part its metallic character, although the situation differs from the platinum-iron catalysts.
95102459 Coproceaslng of 4-(1.naphthylmethyl)blbenzyl with waste tires uelng finely dispersed Iron and molybdenum catalysts Tang, Y. and Curtis, C. W. Prepr. Pap.-Am. Chem. Sot., Div. Fuel Chem., 1994, 39, (3), 865-869. To evaluate the effect of waste tyres on coal liquefaction, waste tyre and of 4-(1carbon black were reacted in the naphthylmethyl)bibenzyl, a model coal compound Ei$TE hydrocrack at liquefaction conditions.
95102460 CPMAS and DDMAS “C NMR analysis of coal Ilquefactlon residues Song,C. er al., Prepr.Pap.-Am Chem. Sot., Div. Fuel Chem., 1994, 39, (31. 782-786. ?& work describes solid-state 13C NMR studies of residues of two subbituminous coals from their liquefaction at 300-425’C, using cross-polarization, dipolar, dephasing and inagic-angle-spinning techniques. Three types of samples were examined in the study.
Fuel and Energy Abstracts Msy 1995
181