- Email: [email protected]
Cumulative Subject Index for Vols. 1–25
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25 of aldoses, 25, 109-179 of hexitols, 5, 191-228 of pentitols, 5, 191-228 Anhydro sugars. See Sugars, anhydro. Animals, conjugates of D-glUCUrOniC acid originating in, 9, 185-246 Antibiotic substances, chemistry of the amino sugars derived from, 18, 259-308 Apiose, 4, 57-74 Ascorbic acid, analogs of, 2, 79-106 Aromatic compounds, biosynthesis of, from D-glucose, 15, 235-
A
Acetals, cyclic, of the aldoses and aldosides, 20, 219-302 of hexitols, pentitols, and tetritols, 7, 137-207 Acetic acid, trifluoro-, anhydride, applications of, in carbohydrate chemistry, 16, 59-84 Acetolysis, 22, 11-23 Aconitic acid, 6, 231-249 Action pattern, of starch degrading and synthesizing enzymes, 23, 281-366 Adsorbents, 270 granular, for sugar refining, 6, 205-230 Alcohols, higher-carbon sugar, configurations of, B 1, 1-36 unsaturated polyhydric, 2, 107-118 Bacteria, glycolipides of acid-fast, 16, 207-238 Alditols, anhydrides, of, 25, 229-283 nucleosides and nucleotides of, 15, 201Aldonic acids, acylated nitriles of, 4, 119-151 234 Aldopentoses, polysaccharides from, 2,203-233; 3, 311methyl ethers of, 7, 1-36; 10, 257-272 336 Aldoses, oxirane derivatives of, 25, 109-179 polysaccharides of Gram-negative, 15, Aldoses and aldosides, 271-340 cyclic acetals of, 20, 219-302 Benzimidazoles, Alkaline degradation, 2-(aldo-polyhydroxyaIkyl)-,6, 175-203 of polysaccharides, 13, 289-329 Benzyl ethers, Altrose, of sugars, 12, 137-156 group of compounds related to, 1, 37-76 Biochemical aspects, Amadori rearrangement, 10, 169-205 of mutarotation of sugars in solution, Amino sugars. See Sugars, 2-amino-2-deoxy. 24, 13-65 Ammonia, aqueous, reactions with free Biochemical reductions, sugars, 25, 311.349 at the expense of sugars, 4, 75-117 Amylases, Biosynthesis, certain alpha, 5, 229-268 of aromatic compounds from D-ghlcOSe, Analysis, 15, 235-270 of crystal structure, in carbohydrate of hyaluronic acid, 12, 299-319 chemistry, 19, 7-22 of the monosaccharides, 11, 185-262 Anhydrides, of saccharides, from glycopyranosyl es2,5-, of sugars, 25, 181-228 ters of nucleotides, 18, 309-356 difructose, 2, 253-277 Blood groups, of alditols, 25, 229-283 polysaccharides of, 4,37-55
533
534
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25
Boric acid, for determining configuration of carbohydrates, 4, 189-210 Bourquelol, Emile, obituary of, 18, 1-8 Branched-chain sugars. S e e S u g a r s, branched-chain. C
Cane juice, composition of, 8,291-314 Cane molasses. See Molasses, cane. Carbohydrates, action of hydrogen peroxide on, 19, 149-179 application of reductive desulfurization by Raney nickel, in the field of, 5, 1-28 application of trifluoroacetic anhydride in chemistry of, 16,59.84 application of the 0x0 reaction to some derivatives of, 23, 59-114 as components of cardiac glycosides, 1, 147-173 carbonates of, 15, 91-158 chemistry of, Emil Fischer and his contribution to, 21, 1-38 complexes of, with alkali metals and alkaline-earth metals, 21, 209-271 compounds with proteins, in human urine, 24, 435-452 constitution of, 15, 11-51 crystal-structure analysis of, 19, 7-22 crystal-structure data for, 25, 53-107 degradation of, 19, 181-218 determination of configuration of, with boric acid, 4,189-210 dicarbonyl, 17,223-299 enzyme specificity in the domain of, 5, 49-78 formazan reaction, in research on, 13, 105-167 Friedel-Crafts and Grignard processes applied to, 6,251-289 gas-liquid chromatography of derivatives of, 19, 95-147 gel chromatography of, 25, 13-51 halogen oxidation of simple, 3, 129.184 halogenated, 22, 177-227
infrared spectra of, 12, 13-33 infrared spectroscopy of, 19,23-49 mass spectrometry of derivatives of, 21, 39-93 mechanisms of replacement reactions in chemistry of, 9, 1-57 metabolism of, 2, 119-160; 3, 229-250 orthoesters of, 1, 77-127 paper electrophoresis of, 18, 61-97 periodate oxidation of, 11, 1-41 the “dialdehydes” from, 16, 105-158 phenol derivatives, in higher plants, 20, 371-408 photochemistry of, 18,9-59 physicochemical properties of, 15, 11-51 radiation chemistry of, 16,13-58 and related compounds, action of hydrogen peroxide on, 19,149-179 paper chromatography of, 9, 303-353 relative reactivities of hydroxyl groups of, 8, 1-44 selective catalytic oxidation of, employing platinum catalysts, 17, 169-221 in the soil, 16,335-355 stereochemistry of cyclic derivatives of, 10,1-53 sulfonic esters of, 8, 107-215; 23, 233280; 24, 139-197 systems, effects of plant-growth substances on, 21, 377-430 thiocarbonates of, 15, 91-158 trityl ethers of, 3, 79-111 zone electrophoresis of, 12,81-115 Carbonates, of carbohydrates, 15, 91-158 Carboxymethyl ether, of cellulose, 9,285-302 Cardenolides. See also, Glycosides, cardiac. synthetic, 21, 273-321 Catalysts, effects of, in mutarotation of sugars in solution, 24, 13-65 platinum, in selective catalytic oxidation of carbohydrates, 17, 169-221 Cellulose, carboxymethyl-, 9,285-302 esters of, with organic acids, 1, 309-321 ethers of, 2, 279-294 molecular constitution of, 3, 185-228
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25 of wood, polysaccharides associated with, 10, 283-333 Celluloses, relative crystallinity of, 5, 103-126 some reactions of, 19,219-246 structure of, 19,219-246 Cellulosic materials, combustion and pyrolysis of, 23, 419474 Chemistry, of the amino sugars, 14,213-281 of the 2-amino sugars, 7, 247-288 of anhydro sugars, 2, 37-77 of carbohydrates, applications of trifluoroacetic anhydride in, 16, 59-84 Emil Fischer and his contribution to, 21, 1-38 crystal-structure analysis in, 19, 7-22 infrared spectroscopy and, 19, 23.49 some implications of theories relating to the mechanisms of replacement reactions in, 9, 1-57 of the cyclitols, 3, 45-77 of cyclitols containing four or five hydroxyl groups, 20, 11-65 of the 2-deoxy sugars, 8, 45-105 of heparin, 10, 335-368 of mucopolysaccharides and mucoproteins, 2, 161-201 of the nucleic acids, 1, 193-245 of osazones, 20, 139-181 of osotriazoles, 18, 99-121 of pectic materials, 2, 235-251 of ribose, 6, 135-174 of streptomycin, 3, 337-384 of thio sugars, 18, 123-199 physical, of carbohydrates, 15, 11-51 of starch, 11, 335-385 radiation, of carbohydrates, 16, 13-58 stereo-, of cyclic derivatives of carbohydrates, 10, 1-53 structural, of fungal polysaccharides, 23, 367-417 of the hemicelluloses, 14,429-468 of polysaccharides, 15, 53-89 Chitin, 15, 371-393 Chromatography, column. See Column chromatography. See Gas-liquid chromatog gas-liquid. raphy.
535
gel. See Gel chromatography. paper. See Paper chromatography. Color, of sugar products, 9, 247-284 Column chromatography, of sugars and their derivatives, 10, 5594 Combustion, of cellulosic materials, 23, 419-474 Complexes, of carbohydrates, with alkali metals and alkaline-earth metals, 21, 209271 cuprammonium-glycoside, 6, 107-134 Composition, of sugar solutions, 23, 11-57 Configuration, of carbohydrates, determination of, 4, 189-210 of cyclitols, 3, 45-77 of higher-carbon sugar alcohols, 1, 1-36 of sucrose, 4, 1-35 Conformation, in formation of polysaccharide gels and networks, 24, 267-332 Conjugates, of D-glucuronic acid, 9, 185-246 of sugars with sphingosines, 24, 381-433 Constitution, of carbohydrates, 15, 11-51 Crystallinity, relative, of celluloses, 5, 103-126 Crystal-structure, analysis, in carbohydrate chemistry, 19, 7-22 data, for simple carbohydrates and their derivatives, 25, 53-107 Cuprammonium-glycoside complexes, 6, 107.134 Cyanohydrin synthesis, Fischer, 1, 1-36 Cyclic acetals, of the aldoses and aldosides, 20, 219302 of hexitols, pentitols, and tetritols, 7, 137-207 Cyclic derivatives, of carbohydrates, stereochemistry of, 10, 1-53
536
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25
Cyclic monosaccharides, having nitrogen or sulfur in the ring, 23, 115-232 Cyclitols, 14, 135-212 chemistry and configuration of, 3, 45-77 containing four or five hydroxyl groups, chemical and physical studies of, 20, 11-65
D Degradation, of acylated nitriles of aldonic acids, 4, 119-151 of carbohydrates, 19, 181-218 enzymic, of glycogen and starch, 3, 251-310; 17, 407-430 thermal, of starch, 22,483-515 3-Deoxyglycosones. See Glycosuloses, 3deoxy-. 3-Deoxyglycosuloses. See Glycosuloses, 3deoxy-. Deoxy sugars. See Sugars, deoxy. Desulfurization, reductive, by Raney nickel, 5, 1-28 Dextran, structure and synthesis of, 15, 341-369 Dextrins, the Schardinger, 12, 189-260 Dextrose, commercial production of crystalline, 5, 127-143 “Dialdehydes,” from the periodate oxidation of carbohydrates, 16, 105-158 Dicarbonyl derivatives, of Carbohydrates, 17,223-299 Difructose, anhydrides, 2, 253-277 Disaccharides, enzymic synthesis of, 5,29-48 trehalose, 18, 201-225
degradation by, of starch and glycogen, 3, 251-310; 17, 4Q7-430 specificity of, in the domain of carbohydrates, 5,499-78 starch degrading and synthesizing, 23, 281-366 synthesis by, of glycogen and starch, 17,371-407 of sucrose and other disaccharides, 5, 29-48 Esters, of cellulose, with organic acids, 1, 309327 glycopyranosyl, of nucleotides, 18, 309356 beta-ketonic (and related substances), reactions with monosaccharides, 11, 97.143 nitric, of starch, 13, 331-345 of starch, preparation and properties of, 1, 279-307 sulfonic, of carbohydrates, 8, 107-215; 23, 233-280; 24, 139-197 Ethanol, 2-nitro-, syntheses with, 6,291-318 Ethers, benzyl, of sugars, 12, 137-156 carboxymethyl, of cellulose, 9, 285-302 of cellulose, 2, 279-294 methyl, of the aldopentoses, 7, 1-36; 10, 257-272 of 2-amino-2-deoxy sugars, 13, 189214 of fucose, 7, 1-36; 10, 257-272 of o-galactose, 6, 11-25; 10, 273-282 of D-glucose, 5, 145-190 of hexuronic acids, 9, 131-148 of o-mannose, 8, 217-230 of rhamnose, 7, 1-36; 10, 257-272 trityl, of carbohydrates, 3, 79-111
E
F
Electrophoresis, of carbohydrates, paper, 18,61-97 zone, 12,81-115 Enzymes. See also, Amylases, Galactosidases, 8-Glucuronidase. acting on pectic substances, 5, 79-102
Fat, metabolism of, 2, 119-160 Fischer, Emil, and his contribution to carbohydrate chemistry, 21, 1-38 Fischer, Hermann Otto Laurenz, obituary of, 17, 1-14
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25 Formazan reaction, in carbohydrate research, 13, 105-167 Formulas, stereo-, writing of, in a plane, 3, 1-22 Fractionation, of starch, 1, 247-277; 16,299-333 Friedel-Crafts process, in the carbohydrate series, 6,251-289 Fructans, 2, 253-277 Fructofuranoside, a-D-glucopyranosyl P-D-, 4, 1-35 Fructosans, poly-. See Fructans. Fructose, and its derivatives, 7, 53-98; 22,229-305 di-, anhydrides, 2, 253-277 Fucose, methyl ethers of, 7, 1-36; 10, 257-272 Fungal polysaccharides, structural chemistry of, 23, 367-417 Furan compounds, formation from hexoses, 6,83-106
G Galactose, methyl ethers of D-, 6,11-25; 10, 273282 Galactosidases, 16,239-298 Gas-liquid chromatography, of carbohydrate derivatives, 19, 95-147 Gel chromatography, of carbohydrates, 25, 13-51 Gels, polysaccharide, 24,267-332 Glucose. See also, Dextrose. biosynthesis of aromatic compounds from D-, 15,235-270 methyl ethers of D-, 5, 145-190 Glucuronic acid, D-, chemical synthesis of, 8, 231-249 conjugates of, of animal origin, 9, 185246 in metabolism, 8,251-275 p-Glucuronidase, preparation and properties of, 14, 381428 Glutose, 3, 113-128 Glycals, 7, 209-245 -, 2-hydroxy-, 9,97-129 Glycofuranosides, 21, 95-142
537
Glycogens, enzymic degradation of, 3, 251-310; 17, 4Q7-430 enzymic synthesis of, 17,371-407 molecular structure of, 12, 261-298 Glycolipides, of acid-fast bacteria, 16,207-238 Glycoproteins. See Proteins, glyco-. Glycoside-cuprammoniurn complexes, 6, 107-134 G1ycosides, acid-catalyzed hydrolysis of, 22, 25-108 alkali-sensitive, 9, 59-95 cardiac, 1, 147-173 the sugars of, 17,65-120 methyl, of the common sugars, 12, 157187 of the parsley plant, 4, 57-74 phenyl, of the common sugars, 12, 157187 C-Glycosides. See C-Glycosyl compounds. Glycosiduronic acids, of animals, 9, 185-246 poly-, of plants, 1, 329-344 Glycosones, 3-deoxy-. See Glycosuloses, 3deoxy-. Glycosphingolipids, 24, 381-433 Glycosuloses, 3-deoxy-, and the degradation of carbohydrates, 19, 181-218 Glycosylamines, 10,95-168 Glycosyl azides, 16,85-103 C-Glycosyl compounds, naturally occurring, 18, 227-258; 20, 357-369 Glycosyl fluorides, 16,85-103 Glycosyl halides, and their derivatives, 10,207-256 Goepp, Rudolph Maximilian, Jr., obituary of, 3, xv-xxiii Grignard process, in the carbohydrate series, 6,251-289 Gums (see also, Hydrocolloids), 24, 333379 commercial, 13,265-287 of plants, 4,243-291
H Halogen oxidation. See Oxidation, halogen. Halogenated carbohydrates, 22, 177-227
538
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25
Haworth, Walter Norman, obituary of, 6, 1-9 Hemicelluloses, structural chemistry of, 14, 429-468 of wood, 19, 247-302; 20, 409-4.83 Heparin, chemistry of, 10, 335-368 Heuser. Emil, obituary of, 15, 1-9 Hexitols, acetals of, 7, 137-207 anhydrides of, 5, 191-228 and some of their derivatives, 4, 211-241 synthesis of, 2, 107-114 Hexofuranoses, 1,6-anhydro-, 7, 37-52 Hexosans, 7, 37-52 Hexoses. See also, Hexofuranoses. formation of furan compounds from, 6, 83-106 Hexuronic acids, methyl ethers of, 9, 131-148 Hibbert, Harold, obituary of, 16, 1-11 History, of mutarotation, 23, 11-57 Honey, the sugars of, 25, 285-309 Hudson, Claude Silbert, obituary of, 9, xiii-xviii Hyaluronic acid, biosynthesis of, 12, 299-319 Hydrazones, of sugars, 3, 23-44 Hy drocolloids, commercial, polysaccharidic, 13, 265287 Hydrogen peroxide, action on carbohydrates and related compounds, 19, 149.179 Hydrolysis, acid-catalyzed, of glycosides, 22, 25-108 Hydroxyl groups, relative reactivities of, 8, 1-44
I Infrared spectra, of Carbohydrates, 12, 13-33 Infrared spectroscopy, and carbohydrate chemistry, 19, 23-49
Irvine, James Colquhoun, obituary of, 8, xi-xvii Isotopes, effects of, in mutarotation of sugars in solution, 24, 13-65 Isotopic tracers. See Tracers, isotopic.
K Ketals. See Acetals. Kinetics, basic, of mutarotation, 23, 11-57 Kojic acid, 11, 145-183 Kuhn, Richard, obituary of, 24, 1-12
L Lactose, 16, 159-206 Lead tetraacetate, action of, on the sugars, 14, 9-61 Levene, Phoebus Aaron Theodor, obituary of, 12, 1-12 Lipids, glyco-. See Glycolipids. glycosphingo-. See Glycosphingolipids. Lobry de Bruyn-Alberda van Ekenstein transformation, 13, 63-103
M Maillard reaction, 14, 63-134 Mannose, methyl ethers of D-, 8, 217-230 Mass spectrometry, of carbohydrate derivatives, 21, 39.93 Materials, cellulosic, combustion and pyrolysis of, 23, 419.474 Mechanism, in the formation of polysaccharide gels and networks, 24, 267-332 of replacement reactions in carbohydrate chemistry, 9, 1-57 Melezitose, 2, 1-36 structure of, 8, 277-290 Metabolism, of carbohydrates, 2, 119-160 use of isotopic tracers in studying, 3, 229.250 of fat, 2, 119-160 of glycoproteins, 25, 407-478
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25 of the sugar alcohols and their deriva tives, 1, 175-192 u-glucuronic acid in, 8, 251-275 Methane, nitro-, syntheses with, 6, 291-318 Methods, in structural polysaccharide chemistry, 15,53-89 Methyl ethers. See Ethers, methyl. Meyer, Kurt Heinrich, obituary of, 11, xiii-xviii )Molasses, cane, 3, 113-128 cane final, composition of, 8, 291-314 Molecular structure, of glycogens, 12, 261-298 Mononucleotides, 22, 307-419 Monosaccharides, biosynthesis of, 11, 185-262 cyclic, having nitrogen or sulfur in the ring, 23, 115-232 reactions of, with beta-ketonic esters and related substances, 11, 97-143 Mucilages (see also, Hydrocolloids), 24, 333-379 commercial, 13, 265-287 of plants, 4, 243-291 Mucopolysaccharides. See PoIysaccharides, mnco-. Mucoproteins. See Proteins, muco-. Mu tarotation, of sugars in solution: Part I. History, basic kinetics, and composition of sugar solutions, 23, 11-57 Part 11. Catalytic processes, isotope effects, reaction mechanisms, and biochemical aspects, 24, 13-65 Mycobacterium tuberculosis, polysaccharides of, 3, 311-336
N Neighboringgroup participation, in sugars, 22, 109-175 Networks, polysaccharide, 24, 267.332 Neuberg, Carl, obituary of, 13, 1-7 Neuraminic acids, and related compounds, 13, 237-263
539
NickeI, Raney. See Raney nickel. Nitrates, of starch, 13, 331-345 of sugars, 12, 117-135 Nitriles, acylated, of aldonic acids, 4, 119-151 Nitrogen heterocycles, synthesis from saccharide derivatives, 25, 351-405 Nitro sugars. See Sugars, nitro. Nonulosaminic acids, 13, 237-263 Nuclear magnetic resonance, 19, 51-93 Nucleic acids, 1, 193-245; 11, 285-333 Nucleosides, bacterial, 15, 201-234 purine, 17, 301-369 pyrimidine, 14,283-380 Nucleotides, bacterial, 15,201-234 glycopyranosyl esters of, 18, 309-356 mono-, 22, 307-419
0 Obituary, of Emile Bourquelot, 18,1-8 of Emil Fischer, 21, 1-38 of Hermann Otto Laurenz Fischer, 17, 1-14 of Rudolph Maximilian Goepp, Jr., 3, xv-xxiii of Walter Norman Haworth, 6, 1-9 of Emil Heuser, 15, 1-9 of Harold Hibbert, 16, 1-11 of Claude Silbert Hudson, 9, xiii-xviii of James Colquhoun Irvine, 8, xi-xvii of Richard Kuhn, 24, 1-12 of Phoebus Aaron Theodor Levene, 12, 1-12 of Kurt Heinrich Meyer, 11, xiii-xviii of Carl Neuberg, 13, 1-7 of Stanley Peat, 25, 1-12 of Edmund George Vincent Percival, 10, xiii-xx of Clifford Burrough Purves, 23, 1-10 of Fred Smith, 22, 1-10 of John Clinton Sowden, 20, 1-10 of Alva Thompson, 19, 1-6 of G b a Zemplkn, 14, 1-8 Oligosaccharides, 17, 121-167 the raffinose family of, 9, 149-184
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25
540
synthesis of, 6, 27-81 Orthoesters, of carbohydrates, 1, 77-127 Osazones, Chemistry of, 20, 139-181 of sugars, 3, 23-44 Osones, 11, 43-96 Osotriazoles, chemistry of, 18, 99-121 Oxidation, halogen, of simple carbohydrates, 3,
129-148 lead tetraacetate, of sugars, 14, 9-61 periodate, of carbohydrates, 11, 1-41 the “dialdehydes” from, 16, 105-158 selective catalytic, of carbohydrates, employing platinum catalysts, 17,
169-221 Oxirane derivatives, of aldoses, 25,109-179 0 x 0 reaction, application to some carbohydrate derivatives, 23,59-114 Oxygen ring, formation and cleavage of, in sugars,
13. 9-61 P Paper chromatography, of carbohydrates and related compounds, 9, 303-353 Paper electrophoresis, of carbohydrates, 18, 61-97 Parsley, glycosides of the plant, 4,57-74 Participation, neighboringgroup, in sugars, 22, 109.
175 Peat, Stanley, obituary of, 25, 1-12 Pectic materials, chemistry of, 2, 235-251 enzymes acting on, 5, 79-102 Pentitols, acetals of, 7, 137-207 anhydrides of, 5, 191-228 synthesis of, 2, 107-118 Percival, Edmund George Vincent, obituary of, 10, xiii-xx Periodate oxidation. See Oxidation, periodate.
Phenol-carbohydrate derivatives, in higher plants, 20, 371-408 Photochemistry, of carbohydrates, 18, 9-59 Physical chemistry, of Carbohydrates, 15, 11-51 of starch, 11, 335-385 Physical properties, of solutions of polysaccharides, 18, 357-
398 Physical studies, of cyclitols containing four or five hydroxyl groups, 20, 11-65 Plant-growth substances, effect on carbohydrate systems, 21, 377-
430 Plants, glycosides of parsley, 4,57-74 gums of, 4,243-291 mucilages of, 4,243-291 polyuronides of, 1, 329-344 Platinum. See Catalysts. Pneumococcal polysaccharides, 19, 303-
357 Polyfructosans. See Fructans. Polyglycosiduronic acids. See Glycosiduronic acids, poly-. Polysaccharides. See also, Carbohydrates, Cellulose, Dextran, Dextrins, Fructans, Glycogen, Glycosiduronic acids (poly-), Pectic materials, Starch, and Xylan. alkaline degradation of, 13, 289-329 associated with wood cellulose, 10, 283-
333 bacterial, 2, 203-233;15, 271-340 blood-group, 4, 37-55 chemical synthesis of, 21, 431-512 fungal, structural chemistry of, 23, 367-
417 gels and networks, role of structure, conformation, and mechanism, 24,
267-332 hydrocolloidal, 13, 265-287 methods in structural chemistry of, 15,
53-89 muco., chemistry of, 2, 161.201 of Gram-negative bacteria, 15, 271-340 of Mycobacterium tuberculosis, 3, 311-
336
of seaweeds, 8, 315-350
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25
541
physical properties of solutions of, 18, Reactions, 357-398 mechanisms of, in mutarotation of sugars pneumococcal, 19,303-357 in solution, 24, 13-65 shape and size of molecules of, 7, 289of amino sugars with beta-dicarhonyl 332; 11, 385-393 compounds, 20, 303-355 x-ray structure of, 22, 421-482 of cellulose, 19,219-246 Polyuronides, of free sugars with aqueous ammonia, of plants, 1, 329-344 25, 311-349 Preparation, of monosaccharides with beta-ketonic of esters of starch, 1, 279-307 esters and related substances, 11, of p-glucuronidase, 14,391-428 97-143 Properties, Reactivities, of 2-amino-2-deoxy sugars and their relative, of hydroxyl groups of carboderivatives, 15, 159-200 hydrates, 8, 1-44 of esters of starch, 1, 279-307 Rearrangement, the Amadori, 10, 169-205 of @-glucuronidase, 14,381-428 Reductions, physical, of solutions of polysaccharides, 18, biochemical, at the expense of sugars, 357-398 4,75-117 physicochemical, of carbohydrates, 15, Replacement reactions, 11-51 mechanisms of, in carbohydrate chemProteins, istry, 9, 1-57 compounds with carbohydrates, in hu- Rhamnose, methyl ethers of, 7, 1-36; 10, 257-272 man urine, 24, 435-452 Ribose, glyco-, aspects of the structure and chemistry of, 6, 135-174 metabolism of, 25, 407-88 muco-, chemistry of, 2, 161-201 S Psicose, 7, 99-136 Purines, Saccharides, nucleosides of, 17, 301-369 biosynthesis of, from glycopyranosyl Purves, Clifford Burrough, esters of nucleotides, 18, 309-356 obituary of, 23, 1-10 synthesis of nitrogen heterocycles from, Pyrimidines, 25, 3 5 1 4 5 nucleosides of, 14,283-380 Saccharification, Pyrolysis, of cellulosic materials, 23, 419of wood, 4, 153-188 474 Saccharinic acids, 12, 35-79 four-carbon, 13, 169-188 R Schardinger dextrins, 12, 189-260 Radiation, Seaweeds, chemistry of carbohydrates, 16, 13-58 polysaccharides of, 8, 315-350 Raffinose, Seleno sugars. See Sugars, seleno. family of oligosaccharides, 9, 149-184 Shape, Raney nickel, of some polysaccharide molecules, 7, reductive desulfurization by, 5, 1-28 289.332; 11, 385-393 Reaction, Sialic acids, 13, 237-263 the formazan, in carbohydrate research, Size, 13, 105-167 of some polysaccharide molecules, 7. the Maillard, 14,63-134 289-332; 11, 385-393 the 0x0, application to some carbo- Smith, Fred, obituary of, 22, 1-10 hydrate derivatives, 23, 59-114
542
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25
Soil, carbohydrates in, 16, 335-355 Solutions, of polysaccharides, physical properties of, 18, 357-398 of sugars, mutarotation of, 23, 11-57; 24, 13-65 Sorbose, 7,99-136 Sowden, John Clinton, obituary of, 20, 1-10 Specificity, of enzymes, in the domain of carbohydrates, 5, 49-78 Spectra, infrared, of carbohydrates, 12, 13-33 Spectrometry, mass, of carbohydrate derivatives, 21, 39-93 Spectroscopy, infrared, and carbohydrate chemistry, 19, 23-49 nuclear magnetic resonance, 19, 51-93 Sphingosines, conjugates with sugars, 24, 381-433 Starch, degrading and synthesizing enzymes, 23, 28 1-366 enzymic degradation of, 3, 251.310; 17, 407-430 enzymic synthesis of, 17, 371-407 fractionation of, 1, 247-277; 16,299.333 nitrates of, 13, 331-345 physical chemistry of, 11, 335-385 preparation and properties of esters of, 1, 279.307 thermal degradation of, 22, 483-515 Stereochemistry, of cyclic derivatives of carbohydrates, 10, 1-53 formulas, writing of, in a plane, 3, 1-22 Streptomycin, chemistry of, 3, 337-384 Structural chemistry, of fungal polysaccharides, 23, 367-417 of the hemicelluloses, 14,429-468 Structure, molecular, of cellulose, 19, 219-246 of dextran, 15, 341-369 of glycogens, 12, 261-298 of glycoproteins, 25, 4Q7-478 of polysaccharide gels and networks, 24,
267*332 of sucrose, 4, 1-35 x-ray, of polysaccharides, 22, 421-482 Sucrose. See also, Sugar. enzymic synthesis of, 5, 29-48 structure and configuration of, 4, 1-35 utilization of, 4, 293-336 Sugar, aconitic acid as by-product in manufacture of, 6, 231-249 Sugar alcohols, higher-carbon, configurations of, 1, 1-36 and their derivatives, metabolism of, 1, 175-192 “Sugar nucleotides.” See Nucleotides, glycopyranosyl esters of. Sugar products, color and turbidity of, 9, 247-284 Sugar refining, granular adsorbents for, 6, 205-230 Sugars, action of lead tetraacetate on, 14, 9-61 amino, aspects of the chemistry of, 14, 213281 derived from antibiotic substances, 18,259-308 methyl ethers of, 13, 189-214 properties of, 15, 159-200 reactions with beta-dicarbonyl compounds, 20, 303-355 2-amino. See Sugars, 2-amino-2-deoxy. 2-amino-2-deoxy, 7, 247-288 2,5-anhydrides of, 25, 181-228 anhydro, chemistry of, 2, 37-77 benzyl ethers of, 12, 137-156 biochemical reductions at the expense of, 4,75-117 branched-chain, of natural occurrence, 11, 263-283 of the cardiac glycosides, 17, 65-120 conjugates, with sphingosines, 24, 381433 deoxy, 21, 143.207 2-deoxy, 8, 45-105 free, reactions with aqueous ammonia, 25,311-349 higher-carbon, 17, 15-63 configurations of, 1, 1-36
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25 of honey, 25, 285-309 hydrazones of, 3, 23-44 methyl glycosides of the common, 12, 157-187 neighboringgroup participation in, 22, 109-175 nitrates of, 12, 117-135 nitro, 24, 67-138 osazones of, 3, 23-44 oxygen ring in, formation and cleavage of, 13, 9-61 phenyl glycosides of the common, 12, 157-187 related to altrose, 1, 37-76 seleno, 1, 144-145 solutions of, mutarotation of, 23, 11.57; 24, 13-65 sulfates of the simple, 20, 183-218 and their derivatives, column chroma. tography of, 10, 55-94 thio, 1, 129-144 developments in the chemistry of, 18, 123-159 unsaturated, 20, 67-137; 24, 199-266 Sulfates, of the simple sugars, 20, 183-218 Sulfonic esters, of carbohydrates, 8, 107-215; 23, 233. 280; 24, 139-197 Synthesis, biochemical, of monosaccharides, 11, 185-262 of cardenolides, 21, 273-321 chemical, of D-g~UCUrOnic acid, 8, 231. 249 of polysaccharides, 21, 431-512 of dextran, 15, 341-369 enzymic, of glycogen and starch, 17, 371-407 of sucrose and other disaccharides, 5, 29-48 of nitrogen heterocycles from saccharide derivatives, 25, 351-405
T Tagatose, 7, 99-136 Teichoie acids, 21, 323-375 Tetritols, acetals of, 7, 137-207
543
Thiocarbonates, of carbohydrates, 15, 91-158 Thio sugars. See Sugars, thio. Thompson, Alva, obituary of, 19, 1-6 Tracers, isotopic, 3, 229-250 Transformation, the Lobry de Bruyn-Alberda van Ekenstein, 13, 63-103 Trehaloses, 18, 201-225 Trityl ethers, of carbohydrates, 3, 79-111 Turanose, 2, 1-36 Turbidity, of sugar products, 9, 247-284
U Unsaturated sugars. See Sugars, unsaturated. Ureides, glycosyl, 13, 215-236 Urine, human, protein-carbohydrate compounds in, 24, 435-452
W Wood, hemicelluloses of, 19, 247-302; 20, 409483 polysaccharides associated with cellulose of, 10, 283-333 saccharification of, 4, 153-188
X X-Rays, crystal-structure analysis by, 19, 7-22 Xylan, 5, 269-290
Z Zemplin, Giza, obituary of, 14, 1-8 Zone electrophoresis, of carbohydrates, 12, 81-115
A
Acetals, cyclic, of the aldoses and aldosides, 20, 219-302 of hexitols, pentitols, and tetritols, 7, 137-207 Acetic acid, trifluoro-, anhydride, applications of, in carbohydrate chemistry, 16, 59-84 Acetolysis, 22, 11-23 Aconitic acid, 6, 231-249 Action pattern, of starch degrading and synthesizing enzymes, 23, 281-366 Adsorbents, 270 granular, for sugar refining, 6, 205-230 Alcohols, higher-carbon sugar, configurations of, B 1, 1-36 unsaturated polyhydric, 2, 107-118 Bacteria, glycolipides of acid-fast, 16, 207-238 Alditols, anhydrides, of, 25, 229-283 nucleosides and nucleotides of, 15, 201Aldonic acids, acylated nitriles of, 4, 119-151 234 Aldopentoses, polysaccharides from, 2,203-233; 3, 311methyl ethers of, 7, 1-36; 10, 257-272 336 Aldoses, oxirane derivatives of, 25, 109-179 polysaccharides of Gram-negative, 15, Aldoses and aldosides, 271-340 cyclic acetals of, 20, 219-302 Benzimidazoles, Alkaline degradation, 2-(aldo-polyhydroxyaIkyl)-,6, 175-203 of polysaccharides, 13, 289-329 Benzyl ethers, Altrose, of sugars, 12, 137-156 group of compounds related to, 1, 37-76 Biochemical aspects, Amadori rearrangement, 10, 169-205 of mutarotation of sugars in solution, Amino sugars. See Sugars, 2-amino-2-deoxy. 24, 13-65 Ammonia, aqueous, reactions with free Biochemical reductions, sugars, 25, 311.349 at the expense of sugars, 4, 75-117 Amylases, Biosynthesis, certain alpha, 5, 229-268 of aromatic compounds from D-ghlcOSe, Analysis, 15, 235-270 of crystal structure, in carbohydrate of hyaluronic acid, 12, 299-319 chemistry, 19, 7-22 of the monosaccharides, 11, 185-262 Anhydrides, of saccharides, from glycopyranosyl es2,5-, of sugars, 25, 181-228 ters of nucleotides, 18, 309-356 difructose, 2, 253-277 Blood groups, of alditols, 25, 229-283 polysaccharides of, 4,37-55
533
534
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25
Boric acid, for determining configuration of carbohydrates, 4, 189-210 Bourquelol, Emile, obituary of, 18, 1-8 Branched-chain sugars. S e e S u g a r s, branched-chain. C
Cane juice, composition of, 8,291-314 Cane molasses. See Molasses, cane. Carbohydrates, action of hydrogen peroxide on, 19, 149-179 application of reductive desulfurization by Raney nickel, in the field of, 5, 1-28 application of trifluoroacetic anhydride in chemistry of, 16,59.84 application of the 0x0 reaction to some derivatives of, 23, 59-114 as components of cardiac glycosides, 1, 147-173 carbonates of, 15, 91-158 chemistry of, Emil Fischer and his contribution to, 21, 1-38 complexes of, with alkali metals and alkaline-earth metals, 21, 209-271 compounds with proteins, in human urine, 24, 435-452 constitution of, 15, 11-51 crystal-structure analysis of, 19, 7-22 crystal-structure data for, 25, 53-107 degradation of, 19, 181-218 determination of configuration of, with boric acid, 4,189-210 dicarbonyl, 17,223-299 enzyme specificity in the domain of, 5, 49-78 formazan reaction, in research on, 13, 105-167 Friedel-Crafts and Grignard processes applied to, 6,251-289 gas-liquid chromatography of derivatives of, 19, 95-147 gel chromatography of, 25, 13-51 halogen oxidation of simple, 3, 129.184 halogenated, 22, 177-227
infrared spectra of, 12, 13-33 infrared spectroscopy of, 19,23-49 mass spectrometry of derivatives of, 21, 39-93 mechanisms of replacement reactions in chemistry of, 9, 1-57 metabolism of, 2, 119-160; 3, 229-250 orthoesters of, 1, 77-127 paper electrophoresis of, 18, 61-97 periodate oxidation of, 11, 1-41 the “dialdehydes” from, 16, 105-158 phenol derivatives, in higher plants, 20, 371-408 photochemistry of, 18,9-59 physicochemical properties of, 15, 11-51 radiation chemistry of, 16,13-58 and related compounds, action of hydrogen peroxide on, 19,149-179 paper chromatography of, 9, 303-353 relative reactivities of hydroxyl groups of, 8, 1-44 selective catalytic oxidation of, employing platinum catalysts, 17, 169-221 in the soil, 16,335-355 stereochemistry of cyclic derivatives of, 10,1-53 sulfonic esters of, 8, 107-215; 23, 233280; 24, 139-197 systems, effects of plant-growth substances on, 21, 377-430 thiocarbonates of, 15, 91-158 trityl ethers of, 3, 79-111 zone electrophoresis of, 12,81-115 Carbonates, of carbohydrates, 15, 91-158 Carboxymethyl ether, of cellulose, 9,285-302 Cardenolides. See also, Glycosides, cardiac. synthetic, 21, 273-321 Catalysts, effects of, in mutarotation of sugars in solution, 24, 13-65 platinum, in selective catalytic oxidation of carbohydrates, 17, 169-221 Cellulose, carboxymethyl-, 9,285-302 esters of, with organic acids, 1, 309-321 ethers of, 2, 279-294 molecular constitution of, 3, 185-228
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25 of wood, polysaccharides associated with, 10, 283-333 Celluloses, relative crystallinity of, 5, 103-126 some reactions of, 19,219-246 structure of, 19,219-246 Cellulosic materials, combustion and pyrolysis of, 23, 419474 Chemistry, of the amino sugars, 14,213-281 of the 2-amino sugars, 7, 247-288 of anhydro sugars, 2, 37-77 of carbohydrates, applications of trifluoroacetic anhydride in, 16, 59-84 Emil Fischer and his contribution to, 21, 1-38 crystal-structure analysis in, 19, 7-22 infrared spectroscopy and, 19, 23.49 some implications of theories relating to the mechanisms of replacement reactions in, 9, 1-57 of the cyclitols, 3, 45-77 of cyclitols containing four or five hydroxyl groups, 20, 11-65 of the 2-deoxy sugars, 8, 45-105 of heparin, 10, 335-368 of mucopolysaccharides and mucoproteins, 2, 161-201 of the nucleic acids, 1, 193-245 of osazones, 20, 139-181 of osotriazoles, 18, 99-121 of pectic materials, 2, 235-251 of ribose, 6, 135-174 of streptomycin, 3, 337-384 of thio sugars, 18, 123-199 physical, of carbohydrates, 15, 11-51 of starch, 11, 335-385 radiation, of carbohydrates, 16, 13-58 stereo-, of cyclic derivatives of carbohydrates, 10, 1-53 structural, of fungal polysaccharides, 23, 367-417 of the hemicelluloses, 14,429-468 of polysaccharides, 15, 53-89 Chitin, 15, 371-393 Chromatography, column. See Column chromatography. See Gas-liquid chromatog gas-liquid. raphy.
535
gel. See Gel chromatography. paper. See Paper chromatography. Color, of sugar products, 9, 247-284 Column chromatography, of sugars and their derivatives, 10, 5594 Combustion, of cellulosic materials, 23, 419-474 Complexes, of carbohydrates, with alkali metals and alkaline-earth metals, 21, 209271 cuprammonium-glycoside, 6, 107-134 Composition, of sugar solutions, 23, 11-57 Configuration, of carbohydrates, determination of, 4, 189-210 of cyclitols, 3, 45-77 of higher-carbon sugar alcohols, 1, 1-36 of sucrose, 4, 1-35 Conformation, in formation of polysaccharide gels and networks, 24, 267-332 Conjugates, of D-glucuronic acid, 9, 185-246 of sugars with sphingosines, 24, 381-433 Constitution, of carbohydrates, 15, 11-51 Crystallinity, relative, of celluloses, 5, 103-126 Crystal-structure, analysis, in carbohydrate chemistry, 19, 7-22 data, for simple carbohydrates and their derivatives, 25, 53-107 Cuprammonium-glycoside complexes, 6, 107.134 Cyanohydrin synthesis, Fischer, 1, 1-36 Cyclic acetals, of the aldoses and aldosides, 20, 219302 of hexitols, pentitols, and tetritols, 7, 137-207 Cyclic derivatives, of carbohydrates, stereochemistry of, 10, 1-53
536
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25
Cyclic monosaccharides, having nitrogen or sulfur in the ring, 23, 115-232 Cyclitols, 14, 135-212 chemistry and configuration of, 3, 45-77 containing four or five hydroxyl groups, chemical and physical studies of, 20, 11-65
D Degradation, of acylated nitriles of aldonic acids, 4, 119-151 of carbohydrates, 19, 181-218 enzymic, of glycogen and starch, 3, 251-310; 17, 407-430 thermal, of starch, 22,483-515 3-Deoxyglycosones. See Glycosuloses, 3deoxy-. 3-Deoxyglycosuloses. See Glycosuloses, 3deoxy-. Deoxy sugars. See Sugars, deoxy. Desulfurization, reductive, by Raney nickel, 5, 1-28 Dextran, structure and synthesis of, 15, 341-369 Dextrins, the Schardinger, 12, 189-260 Dextrose, commercial production of crystalline, 5, 127-143 “Dialdehydes,” from the periodate oxidation of carbohydrates, 16, 105-158 Dicarbonyl derivatives, of Carbohydrates, 17,223-299 Difructose, anhydrides, 2, 253-277 Disaccharides, enzymic synthesis of, 5,29-48 trehalose, 18, 201-225
degradation by, of starch and glycogen, 3, 251-310; 17, 4Q7-430 specificity of, in the domain of carbohydrates, 5,499-78 starch degrading and synthesizing, 23, 281-366 synthesis by, of glycogen and starch, 17,371-407 of sucrose and other disaccharides, 5, 29-48 Esters, of cellulose, with organic acids, 1, 309327 glycopyranosyl, of nucleotides, 18, 309356 beta-ketonic (and related substances), reactions with monosaccharides, 11, 97.143 nitric, of starch, 13, 331-345 of starch, preparation and properties of, 1, 279-307 sulfonic, of carbohydrates, 8, 107-215; 23, 233-280; 24, 139-197 Ethanol, 2-nitro-, syntheses with, 6,291-318 Ethers, benzyl, of sugars, 12, 137-156 carboxymethyl, of cellulose, 9, 285-302 of cellulose, 2, 279-294 methyl, of the aldopentoses, 7, 1-36; 10, 257-272 of 2-amino-2-deoxy sugars, 13, 189214 of fucose, 7, 1-36; 10, 257-272 of o-galactose, 6, 11-25; 10, 273-282 of D-glucose, 5, 145-190 of hexuronic acids, 9, 131-148 of o-mannose, 8, 217-230 of rhamnose, 7, 1-36; 10, 257-272 trityl, of carbohydrates, 3, 79-111
E
F
Electrophoresis, of carbohydrates, paper, 18,61-97 zone, 12,81-115 Enzymes. See also, Amylases, Galactosidases, 8-Glucuronidase. acting on pectic substances, 5, 79-102
Fat, metabolism of, 2, 119-160 Fischer, Emil, and his contribution to carbohydrate chemistry, 21, 1-38 Fischer, Hermann Otto Laurenz, obituary of, 17, 1-14
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25 Formazan reaction, in carbohydrate research, 13, 105-167 Formulas, stereo-, writing of, in a plane, 3, 1-22 Fractionation, of starch, 1, 247-277; 16,299-333 Friedel-Crafts process, in the carbohydrate series, 6,251-289 Fructans, 2, 253-277 Fructofuranoside, a-D-glucopyranosyl P-D-, 4, 1-35 Fructosans, poly-. See Fructans. Fructose, and its derivatives, 7, 53-98; 22,229-305 di-, anhydrides, 2, 253-277 Fucose, methyl ethers of, 7, 1-36; 10, 257-272 Fungal polysaccharides, structural chemistry of, 23, 367-417 Furan compounds, formation from hexoses, 6,83-106
G Galactose, methyl ethers of D-, 6,11-25; 10, 273282 Galactosidases, 16,239-298 Gas-liquid chromatography, of carbohydrate derivatives, 19, 95-147 Gel chromatography, of carbohydrates, 25, 13-51 Gels, polysaccharide, 24,267-332 Glucose. See also, Dextrose. biosynthesis of aromatic compounds from D-, 15,235-270 methyl ethers of D-, 5, 145-190 Glucuronic acid, D-, chemical synthesis of, 8, 231-249 conjugates of, of animal origin, 9, 185246 in metabolism, 8,251-275 p-Glucuronidase, preparation and properties of, 14, 381428 Glutose, 3, 113-128 Glycals, 7, 209-245 -, 2-hydroxy-, 9,97-129 Glycofuranosides, 21, 95-142
537
Glycogens, enzymic degradation of, 3, 251-310; 17, 4Q7-430 enzymic synthesis of, 17,371-407 molecular structure of, 12, 261-298 Glycolipides, of acid-fast bacteria, 16,207-238 Glycoproteins. See Proteins, glyco-. Glycoside-cuprammoniurn complexes, 6, 107-134 G1ycosides, acid-catalyzed hydrolysis of, 22, 25-108 alkali-sensitive, 9, 59-95 cardiac, 1, 147-173 the sugars of, 17,65-120 methyl, of the common sugars, 12, 157187 of the parsley plant, 4, 57-74 phenyl, of the common sugars, 12, 157187 C-Glycosides. See C-Glycosyl compounds. Glycosiduronic acids, of animals, 9, 185-246 poly-, of plants, 1, 329-344 Glycosones, 3-deoxy-. See Glycosuloses, 3deoxy-. Glycosphingolipids, 24, 381-433 Glycosuloses, 3-deoxy-, and the degradation of carbohydrates, 19, 181-218 Glycosylamines, 10,95-168 Glycosyl azides, 16,85-103 C-Glycosyl compounds, naturally occurring, 18, 227-258; 20, 357-369 Glycosyl fluorides, 16,85-103 Glycosyl halides, and their derivatives, 10,207-256 Goepp, Rudolph Maximilian, Jr., obituary of, 3, xv-xxiii Grignard process, in the carbohydrate series, 6,251-289 Gums (see also, Hydrocolloids), 24, 333379 commercial, 13,265-287 of plants, 4,243-291
H Halogen oxidation. See Oxidation, halogen. Halogenated carbohydrates, 22, 177-227
538
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25
Haworth, Walter Norman, obituary of, 6, 1-9 Hemicelluloses, structural chemistry of, 14, 429-468 of wood, 19, 247-302; 20, 409-4.83 Heparin, chemistry of, 10, 335-368 Heuser. Emil, obituary of, 15, 1-9 Hexitols, acetals of, 7, 137-207 anhydrides of, 5, 191-228 and some of their derivatives, 4, 211-241 synthesis of, 2, 107-114 Hexofuranoses, 1,6-anhydro-, 7, 37-52 Hexosans, 7, 37-52 Hexoses. See also, Hexofuranoses. formation of furan compounds from, 6, 83-106 Hexuronic acids, methyl ethers of, 9, 131-148 Hibbert, Harold, obituary of, 16, 1-11 History, of mutarotation, 23, 11-57 Honey, the sugars of, 25, 285-309 Hudson, Claude Silbert, obituary of, 9, xiii-xviii Hyaluronic acid, biosynthesis of, 12, 299-319 Hydrazones, of sugars, 3, 23-44 Hy drocolloids, commercial, polysaccharidic, 13, 265287 Hydrogen peroxide, action on carbohydrates and related compounds, 19, 149.179 Hydrolysis, acid-catalyzed, of glycosides, 22, 25-108 Hydroxyl groups, relative reactivities of, 8, 1-44
I Infrared spectra, of Carbohydrates, 12, 13-33 Infrared spectroscopy, and carbohydrate chemistry, 19, 23-49
Irvine, James Colquhoun, obituary of, 8, xi-xvii Isotopes, effects of, in mutarotation of sugars in solution, 24, 13-65 Isotopic tracers. See Tracers, isotopic.
K Ketals. See Acetals. Kinetics, basic, of mutarotation, 23, 11-57 Kojic acid, 11, 145-183 Kuhn, Richard, obituary of, 24, 1-12
L Lactose, 16, 159-206 Lead tetraacetate, action of, on the sugars, 14, 9-61 Levene, Phoebus Aaron Theodor, obituary of, 12, 1-12 Lipids, glyco-. See Glycolipids. glycosphingo-. See Glycosphingolipids. Lobry de Bruyn-Alberda van Ekenstein transformation, 13, 63-103
M Maillard reaction, 14, 63-134 Mannose, methyl ethers of D-, 8, 217-230 Mass spectrometry, of carbohydrate derivatives, 21, 39.93 Materials, cellulosic, combustion and pyrolysis of, 23, 419.474 Mechanism, in the formation of polysaccharide gels and networks, 24, 267-332 of replacement reactions in carbohydrate chemistry, 9, 1-57 Melezitose, 2, 1-36 structure of, 8, 277-290 Metabolism, of carbohydrates, 2, 119-160 use of isotopic tracers in studying, 3, 229.250 of fat, 2, 119-160 of glycoproteins, 25, 407-478
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25 of the sugar alcohols and their deriva tives, 1, 175-192 u-glucuronic acid in, 8, 251-275 Methane, nitro-, syntheses with, 6, 291-318 Methods, in structural polysaccharide chemistry, 15,53-89 Methyl ethers. See Ethers, methyl. Meyer, Kurt Heinrich, obituary of, 11, xiii-xviii )Molasses, cane, 3, 113-128 cane final, composition of, 8, 291-314 Molecular structure, of glycogens, 12, 261-298 Mononucleotides, 22, 307-419 Monosaccharides, biosynthesis of, 11, 185-262 cyclic, having nitrogen or sulfur in the ring, 23, 115-232 reactions of, with beta-ketonic esters and related substances, 11, 97-143 Mucilages (see also, Hydrocolloids), 24, 333-379 commercial, 13, 265-287 of plants, 4, 243-291 Mucopolysaccharides. See PoIysaccharides, mnco-. Mucoproteins. See Proteins, muco-. Mu tarotation, of sugars in solution: Part I. History, basic kinetics, and composition of sugar solutions, 23, 11-57 Part 11. Catalytic processes, isotope effects, reaction mechanisms, and biochemical aspects, 24, 13-65 Mycobacterium tuberculosis, polysaccharides of, 3, 311-336
N Neighboringgroup participation, in sugars, 22, 109-175 Networks, polysaccharide, 24, 267.332 Neuberg, Carl, obituary of, 13, 1-7 Neuraminic acids, and related compounds, 13, 237-263
539
NickeI, Raney. See Raney nickel. Nitrates, of starch, 13, 331-345 of sugars, 12, 117-135 Nitriles, acylated, of aldonic acids, 4, 119-151 Nitrogen heterocycles, synthesis from saccharide derivatives, 25, 351-405 Nitro sugars. See Sugars, nitro. Nonulosaminic acids, 13, 237-263 Nuclear magnetic resonance, 19, 51-93 Nucleic acids, 1, 193-245; 11, 285-333 Nucleosides, bacterial, 15, 201-234 purine, 17, 301-369 pyrimidine, 14,283-380 Nucleotides, bacterial, 15,201-234 glycopyranosyl esters of, 18, 309-356 mono-, 22, 307-419
0 Obituary, of Emile Bourquelot, 18,1-8 of Emil Fischer, 21, 1-38 of Hermann Otto Laurenz Fischer, 17, 1-14 of Rudolph Maximilian Goepp, Jr., 3, xv-xxiii of Walter Norman Haworth, 6, 1-9 of Emil Heuser, 15, 1-9 of Harold Hibbert, 16, 1-11 of Claude Silbert Hudson, 9, xiii-xviii of James Colquhoun Irvine, 8, xi-xvii of Richard Kuhn, 24, 1-12 of Phoebus Aaron Theodor Levene, 12, 1-12 of Kurt Heinrich Meyer, 11, xiii-xviii of Carl Neuberg, 13, 1-7 of Stanley Peat, 25, 1-12 of Edmund George Vincent Percival, 10, xiii-xx of Clifford Burrough Purves, 23, 1-10 of Fred Smith, 22, 1-10 of John Clinton Sowden, 20, 1-10 of Alva Thompson, 19, 1-6 of G b a Zemplkn, 14, 1-8 Oligosaccharides, 17, 121-167 the raffinose family of, 9, 149-184
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25
540
synthesis of, 6, 27-81 Orthoesters, of carbohydrates, 1, 77-127 Osazones, Chemistry of, 20, 139-181 of sugars, 3, 23-44 Osones, 11, 43-96 Osotriazoles, chemistry of, 18, 99-121 Oxidation, halogen, of simple carbohydrates, 3,
129-148 lead tetraacetate, of sugars, 14, 9-61 periodate, of carbohydrates, 11, 1-41 the “dialdehydes” from, 16, 105-158 selective catalytic, of carbohydrates, employing platinum catalysts, 17,
169-221 Oxirane derivatives, of aldoses, 25,109-179 0 x 0 reaction, application to some carbohydrate derivatives, 23,59-114 Oxygen ring, formation and cleavage of, in sugars,
13. 9-61 P Paper chromatography, of carbohydrates and related compounds, 9, 303-353 Paper electrophoresis, of carbohydrates, 18, 61-97 Parsley, glycosides of the plant, 4,57-74 Participation, neighboringgroup, in sugars, 22, 109.
175 Peat, Stanley, obituary of, 25, 1-12 Pectic materials, chemistry of, 2, 235-251 enzymes acting on, 5, 79-102 Pentitols, acetals of, 7, 137-207 anhydrides of, 5, 191-228 synthesis of, 2, 107-118 Percival, Edmund George Vincent, obituary of, 10, xiii-xx Periodate oxidation. See Oxidation, periodate.
Phenol-carbohydrate derivatives, in higher plants, 20, 371-408 Photochemistry, of carbohydrates, 18, 9-59 Physical chemistry, of Carbohydrates, 15, 11-51 of starch, 11, 335-385 Physical properties, of solutions of polysaccharides, 18, 357-
398 Physical studies, of cyclitols containing four or five hydroxyl groups, 20, 11-65 Plant-growth substances, effect on carbohydrate systems, 21, 377-
430 Plants, glycosides of parsley, 4,57-74 gums of, 4,243-291 mucilages of, 4,243-291 polyuronides of, 1, 329-344 Platinum. See Catalysts. Pneumococcal polysaccharides, 19, 303-
357 Polyfructosans. See Fructans. Polyglycosiduronic acids. See Glycosiduronic acids, poly-. Polysaccharides. See also, Carbohydrates, Cellulose, Dextran, Dextrins, Fructans, Glycogen, Glycosiduronic acids (poly-), Pectic materials, Starch, and Xylan. alkaline degradation of, 13, 289-329 associated with wood cellulose, 10, 283-
333 bacterial, 2, 203-233;15, 271-340 blood-group, 4, 37-55 chemical synthesis of, 21, 431-512 fungal, structural chemistry of, 23, 367-
417 gels and networks, role of structure, conformation, and mechanism, 24,
267-332 hydrocolloidal, 13, 265-287 methods in structural chemistry of, 15,
53-89 muco., chemistry of, 2, 161.201 of Gram-negative bacteria, 15, 271-340 of Mycobacterium tuberculosis, 3, 311-
336
of seaweeds, 8, 315-350
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25
541
physical properties of solutions of, 18, Reactions, 357-398 mechanisms of, in mutarotation of sugars pneumococcal, 19,303-357 in solution, 24, 13-65 shape and size of molecules of, 7, 289of amino sugars with beta-dicarhonyl 332; 11, 385-393 compounds, 20, 303-355 x-ray structure of, 22, 421-482 of cellulose, 19,219-246 Polyuronides, of free sugars with aqueous ammonia, of plants, 1, 329-344 25, 311-349 Preparation, of monosaccharides with beta-ketonic of esters of starch, 1, 279-307 esters and related substances, 11, of p-glucuronidase, 14,391-428 97-143 Properties, Reactivities, of 2-amino-2-deoxy sugars and their relative, of hydroxyl groups of carboderivatives, 15, 159-200 hydrates, 8, 1-44 of esters of starch, 1, 279-307 Rearrangement, the Amadori, 10, 169-205 of @-glucuronidase, 14,381-428 Reductions, physical, of solutions of polysaccharides, 18, biochemical, at the expense of sugars, 357-398 4,75-117 physicochemical, of carbohydrates, 15, Replacement reactions, 11-51 mechanisms of, in carbohydrate chemProteins, istry, 9, 1-57 compounds with carbohydrates, in hu- Rhamnose, methyl ethers of, 7, 1-36; 10, 257-272 man urine, 24, 435-452 Ribose, glyco-, aspects of the structure and chemistry of, 6, 135-174 metabolism of, 25, 407-88 muco-, chemistry of, 2, 161-201 S Psicose, 7, 99-136 Purines, Saccharides, nucleosides of, 17, 301-369 biosynthesis of, from glycopyranosyl Purves, Clifford Burrough, esters of nucleotides, 18, 309-356 obituary of, 23, 1-10 synthesis of nitrogen heterocycles from, Pyrimidines, 25, 3 5 1 4 5 nucleosides of, 14,283-380 Saccharification, Pyrolysis, of cellulosic materials, 23, 419of wood, 4, 153-188 474 Saccharinic acids, 12, 35-79 four-carbon, 13, 169-188 R Schardinger dextrins, 12, 189-260 Radiation, Seaweeds, chemistry of carbohydrates, 16, 13-58 polysaccharides of, 8, 315-350 Raffinose, Seleno sugars. See Sugars, seleno. family of oligosaccharides, 9, 149-184 Shape, Raney nickel, of some polysaccharide molecules, 7, reductive desulfurization by, 5, 1-28 289.332; 11, 385-393 Reaction, Sialic acids, 13, 237-263 the formazan, in carbohydrate research, Size, 13, 105-167 of some polysaccharide molecules, 7. the Maillard, 14,63-134 289-332; 11, 385-393 the 0x0, application to some carbo- Smith, Fred, obituary of, 22, 1-10 hydrate derivatives, 23, 59-114
542
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25
Soil, carbohydrates in, 16, 335-355 Solutions, of polysaccharides, physical properties of, 18, 357-398 of sugars, mutarotation of, 23, 11-57; 24, 13-65 Sorbose, 7,99-136 Sowden, John Clinton, obituary of, 20, 1-10 Specificity, of enzymes, in the domain of carbohydrates, 5, 49-78 Spectra, infrared, of carbohydrates, 12, 13-33 Spectrometry, mass, of carbohydrate derivatives, 21, 39-93 Spectroscopy, infrared, and carbohydrate chemistry, 19, 23-49 nuclear magnetic resonance, 19, 51-93 Sphingosines, conjugates with sugars, 24, 381-433 Starch, degrading and synthesizing enzymes, 23, 28 1-366 enzymic degradation of, 3, 251.310; 17, 407-430 enzymic synthesis of, 17, 371-407 fractionation of, 1, 247-277; 16,299.333 nitrates of, 13, 331-345 physical chemistry of, 11, 335-385 preparation and properties of esters of, 1, 279.307 thermal degradation of, 22, 483-515 Stereochemistry, of cyclic derivatives of carbohydrates, 10, 1-53 formulas, writing of, in a plane, 3, 1-22 Streptomycin, chemistry of, 3, 337-384 Structural chemistry, of fungal polysaccharides, 23, 367-417 of the hemicelluloses, 14,429-468 Structure, molecular, of cellulose, 19, 219-246 of dextran, 15, 341-369 of glycogens, 12, 261-298 of glycoproteins, 25, 4Q7-478 of polysaccharide gels and networks, 24,
267*332 of sucrose, 4, 1-35 x-ray, of polysaccharides, 22, 421-482 Sucrose. See also, Sugar. enzymic synthesis of, 5, 29-48 structure and configuration of, 4, 1-35 utilization of, 4, 293-336 Sugar, aconitic acid as by-product in manufacture of, 6, 231-249 Sugar alcohols, higher-carbon, configurations of, 1, 1-36 and their derivatives, metabolism of, 1, 175-192 “Sugar nucleotides.” See Nucleotides, glycopyranosyl esters of. Sugar products, color and turbidity of, 9, 247-284 Sugar refining, granular adsorbents for, 6, 205-230 Sugars, action of lead tetraacetate on, 14, 9-61 amino, aspects of the chemistry of, 14, 213281 derived from antibiotic substances, 18,259-308 methyl ethers of, 13, 189-214 properties of, 15, 159-200 reactions with beta-dicarbonyl compounds, 20, 303-355 2-amino. See Sugars, 2-amino-2-deoxy. 2-amino-2-deoxy, 7, 247-288 2,5-anhydrides of, 25, 181-228 anhydro, chemistry of, 2, 37-77 benzyl ethers of, 12, 137-156 biochemical reductions at the expense of, 4,75-117 branched-chain, of natural occurrence, 11, 263-283 of the cardiac glycosides, 17, 65-120 conjugates, with sphingosines, 24, 381433 deoxy, 21, 143.207 2-deoxy, 8, 45-105 free, reactions with aqueous ammonia, 25,311-349 higher-carbon, 17, 15-63 configurations of, 1, 1-36
CUMULATIVE SUBJECT INDEX FOR VOLS. 1-25 of honey, 25, 285-309 hydrazones of, 3, 23-44 methyl glycosides of the common, 12, 157-187 neighboringgroup participation in, 22, 109-175 nitrates of, 12, 117-135 nitro, 24, 67-138 osazones of, 3, 23-44 oxygen ring in, formation and cleavage of, 13, 9-61 phenyl glycosides of the common, 12, 157-187 related to altrose, 1, 37-76 seleno, 1, 144-145 solutions of, mutarotation of, 23, 11.57; 24, 13-65 sulfates of the simple, 20, 183-218 and their derivatives, column chroma. tography of, 10, 55-94 thio, 1, 129-144 developments in the chemistry of, 18, 123-159 unsaturated, 20, 67-137; 24, 199-266 Sulfates, of the simple sugars, 20, 183-218 Sulfonic esters, of carbohydrates, 8, 107-215; 23, 233. 280; 24, 139-197 Synthesis, biochemical, of monosaccharides, 11, 185-262 of cardenolides, 21, 273-321 chemical, of D-g~UCUrOnic acid, 8, 231. 249 of polysaccharides, 21, 431-512 of dextran, 15, 341-369 enzymic, of glycogen and starch, 17, 371-407 of sucrose and other disaccharides, 5, 29-48 of nitrogen heterocycles from saccharide derivatives, 25, 351-405
T Tagatose, 7, 99-136 Teichoie acids, 21, 323-375 Tetritols, acetals of, 7, 137-207
543
Thiocarbonates, of carbohydrates, 15, 91-158 Thio sugars. See Sugars, thio. Thompson, Alva, obituary of, 19, 1-6 Tracers, isotopic, 3, 229-250 Transformation, the Lobry de Bruyn-Alberda van Ekenstein, 13, 63-103 Trehaloses, 18, 201-225 Trityl ethers, of carbohydrates, 3, 79-111 Turanose, 2, 1-36 Turbidity, of sugar products, 9, 247-284
U Unsaturated sugars. See Sugars, unsaturated. Ureides, glycosyl, 13, 215-236 Urine, human, protein-carbohydrate compounds in, 24, 435-452
W Wood, hemicelluloses of, 19, 247-302; 20, 409483 polysaccharides associated with cellulose of, 10, 283-333 saccharification of, 4, 153-188
X X-Rays, crystal-structure analysis by, 19, 7-22 Xylan, 5, 269-290
Z Zemplin, Giza, obituary of, 14, 1-8 Zone electrophoresis, of carbohydrates, 12, 81-115