LIST OF CONTENTS Volume 3 SUBJECT INDEX Acids in dimethyl formamide, High-frequency titration . . . Activation analysis for determination of cobalt . . . . Alcohols, 3 :%Dinitrobenzoate esters . . . . Alkali methoxides for high-frequency titrations . . . Aluminium, Partition chromatography . , . . Amalgam exchange for radiochemical separations . . . Ammonia, Titrimetric determination . . . . . Ammonium ions, Titrimetric determination . . . . Ammonium phospho-12-molybdate, Precipitation , . . . Ammonium pyrophosphate for spectrophotometric determination of copper o-Arsonophenylazochromotropic acid for spectrophotometric determination
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240 255 .. 307 . 240 . 131 . 298 1 1 . 219 . 351 . 155
Blocking of indicators . . . . . . . . . . . . . 91 Blood sugar, Fluorimetric determination with S-hydroxy-1-tetralone . 151 . . Book Reviews : Advances in Inorganic Chemistry and Radiochemistry, Vol. I: Edited by H. J. Emeleus and A. G. Sharpe . . . . . . . . . . . . . 109 Analytical Chemistry in Nuclear Reactor Technology, 1st Conference, 1957 . . . 213 Chemistry of the Co-ordinate Compounds, Vol. I: Edited by H. Taube and A. G. Maddock 214 Column Chromatography in Pharmaceutical Analysis: J. A. P. Stroes . . . . 375 Comprehensive Analytical Chemistry, Vol. IA: CIassical Analysis: Edited by Cecil L. Wilson and David W. Wilson . . . . . . . . . . . . 302 Electrophoresis, Theory, Methods and Applications: Edited by Milan Bier . . . 375 Gaschromatographie: A. I. M. Keulemans, translated by E. Cremer . . . . 213 Laboratory Glassblowing: L. M. Parr and C. A. Hendley . . . . . . 303 Treatise on Analvtical Chemistrv: Part I. Theorv and Practice. Vol. 1: Edited by I. M. Kolthoff, Philip J. Elving and Ernest B. Sandill . 374 . Boron, Spectrophotometric determination with carminic acid . 311 Boron, Spectrophotometric determination with dianthrimide 138, 203 Bromocyanogen in determination of selenite . 27, 31 . . 2:3-Butanediamine-N:N:N’:N’-acetic acid, Isomeric forms . . 201 Carminic acid, Calorimetric reagent for boron . . . Cathode ray polarography of mercury fulminate . Cathode ray polarography of nitroglycerine . . . Cobalt, Determination by activation analysis . . Cobalt, Oxidation with iron-l :IO-phenanthroline . . Cobalt, Oxidation with molybdicyanide . . . Cobalt, Sulphur in . . . . . . . Calorimetric determination of boron with carminic acid . Complexans, Isomeric . . . . . . Complexans, Terminology . . . . . Complexone mixtures, Analysis . . . . . Complexometry . . . . . . . . Co-ordination of the NO group . . . . Copper, Precipitation by thioacetamide . . . Copper, Spectrophotometric determination with ammonium pyrophosphate Coulometric analysis, Current integrator . . . . . Coulometric determination of cobalt with molybdicyanide . . . Current integrator for coulometric analysis . . . . .
. 311
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127 160 . 255 . 102 . 346 . 232 . 311 . 201 . 218 47 91,200 . 113 . 296 . 351 . 14 . 346 . 14
Desiccant, Indicating magnesium perchlorate . . . . . . . Detection of selenite . . . . . . . . . . Deuterium in organic compounds, Infra-red spectrophotometry . . . Dianthrimide for spectrophotometric determination of boron . . . Dimethylphenylbenzylammonium chloride for gravimetric determination of platinum 3 :5Dinitrobenzoate derivatives, Titrimetric determination . . .
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Ethers, 3 :5_Dinitrobenzoate esters . Explosives, Cathode ray polarography Explosives, Thermal stability . .
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Ferricyanide, Quantitative oxidations by . Ferroln iodide for extraction of iron . Fluorescein complexone . . .
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107 31 138, 203 356
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364 307
127, 307 160 . 210
. 261 . 72 370
Gallium, Partition chromatography . . . . . . . Gamma-ray absorptiometry for determination of heavy elements . . . Gravimetric determination of platinum with dimethylphenylbenzylammonium chloride .
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Hafnium, Spectrophotometric determination with Xylenol Orange Heavy elements, Determination by gamma-ray absorptiometry Heyrovskg, Jaroslav, Nobel Prize winner . . . . High-frequency excitation of luminescence spectra . . High-frequency titration of acids in dimethylformamide . . Homogeneous solution, Precipitation of silver chloride from Hydrazine in acceleration of sulphide formation . . %Hydroxy-l-tetralone for fluorimetric determination of blood sugar
. 81 . 172 . 300
Inclusions in iron and steel . . . . . . Indicating magnesium perchlorate desiccant . . Indicators, Blocking of . . . . . . . Indicators, Metalfluorechromic . . . . Indicators, Redox, for argentometric titrations . . Indicators, Variamine Blue derivatives . . . Indicators, Variamine Blue sulphate . . Indicators, Xylenol Orange, Decomposition . . Indium, Partition chromatography . . . . . Infra-red spectra of the tetralin series . . . . Inorganic gases, Luminescence spectra . . . Ion-association complexes . . . . . . Iridium, Preparation of solutions . . . . . Iron and steel, Inclusions in . . . . . Iron, Solvent-extraction as ferroln iodide . . . . Iron, Spectrophotometric determination with Xylenol Orange Isomeric complexans . . . . . . . Luminiscence spectra from high-frequency
excitation
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131 172 364
191 175, 240 187 . 296 . 151
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97 107 91 370
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54 209 200 131 65 191 . 72 277 . 97 . 72 . 146 . 201
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191
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Magnesium perchlorate desiccant with indicator . . . 2-Mercaptoacetic acid for gravimetric determination of zirconium Mercury, Precipitation with thioacetamide . . . . Mercury fulminate, Cathode ray polarography . . . . Metalfluorechromic indicators . . . . . . Metals, Precipitation by thioacetamide . . . . Methoxide, Potassium, for conductometric titration . Methoxide, Alkali, for high-frequency titration . . Methylene blue for spectrophotometric determination of sulphur Molybdenum, Precipitation by thioacetamide . . . . Molybdenum, Spectrophotometric determination with 3 :3’:4’:5 :7-pentahydroxyflavonone Molybdicyanide oxidation for determination of cobalt . . . . . .
196
. 107 . 95 . 296 . 127 . 370 . . . . . .
296 249 240 232 296 272 346
Neothorone for spectrophotometric determination of thorium ...... Neuron-activation determination of silver ......... Nitrate, Argentometric determination .......... Nitrate, solutions, Determination of boron in ......... Nitro compounds, Argentometric determination ........ Nitrogen-containing organic compounds, Titrimetric determination ..... Nitroglycerine, Cathode ray polarography ......... Nobel Prize winner, Jaroslav Heyrovsk$ .......... NO group, Co-ordination ........... Non-aqueous titrations ............ Nucleation of silver chloride ........... Oxidation by potassium ferricyanide .......... Oxidation of bone ............. Oxinates, Conductome~ic titration with potassium methoxide
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Selenite, Titrimetric determination through bromocyanogen Selenocyanide, Xodometric determination . . . Separations, Radiochemical, by amalgam exchange . Silicates, Spectrochemical determination of minor elements Silver, Determination by neutron-activation . . SiIver, Precipitation by thioacetamide . . . Silver, chloride, Precipitation from homogeneous solution Silver chloride, Precipitation nucleus . . . Solutions of iridium, Preparation . . . . Solvent extraction of iron as ferroln iodide . . Solvent extraction of palla~um . . . . Solvent extraction of plating . . . . Solvent extraction of rhodium . . . .
34
6 3I 1 6 1 160 300 113 260,249 17.5, 187 261 41 249
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Palladium, Solvent extraction ........... Paper electrophoresis of complexone mixtures ......... Partition chromatography of aluminium, gallium, indium and thallium 3:3’:4’:5:7-Pentahydroxyflavanone for spectrophotometric determination Perchloric acid for wet oxidation of bone _. . . . . 1 :lO-Phenanthroline-iron for oxidation of cobalt . . . . Phenol, Spectrophotometric determination . . . . . Phospho-12-molybdate, Precipitation . . . . . . Platinum, Gravimetric determination with dimethylphenylbenzyIammonium Platinum, Solvent extraction . . . . . . Piatinum, oxide films on electrodes . . . . . Polarography of complexone mixtures . . . . Polaro~aphy of mercury fulminate . . . . Pol~offaphy of ni~oglycerine . . . . . Potentiometric titration of 3:Minitrobenzoate esters . Precipitation of ammonium phospho-1Zmolybdate . . Precipitation of silver chloride from homogeneous solution Pyridine thiocyanate complex of palladium . . . Pyridine thiocyanate complex of platinum . . . Pyridine thiocyanate complex of rhodium . . . Pyridine thiocyanate complex of ruthenium . . . Radiochemical separations by amalgam exchange Reaction kinetics at platinum eIectrodes . . Redox indicators for argentometric titrations . Redox indicators, Variamine Blue derivatives . Redox indicators, Variamine Blue sulphate . Rhodium, Solvent extraction . . . . Ruthenium, Solvent extraction . . .
155
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of molybdenum
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chloride
324, 330 47 . 131 . 272 . 41 . 103 . 318 . 219 . 364 . 330 . 335 . 47 . 127 . 160 . 307 219 175, 187 324,330 . 330 330 324, 330
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. 23 . 298 . 207 . 34
298 335
I,6 54 209 330 324
27, 31
in
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296 175, 187 . 187 . 277 72 324,330 . 330 . 330
Solvent extraction of ~theni~ . . . . . . . . . . S~trochemi~l deter~ation of minor elements in silicates . . . . . S~ophotometric dete~ination of boron with carminic acid . . . . . Spectrophotometric determination of boron with dianthrimide . . . . . Spectrophotometric determination of copper with ammonium pyrophosphate . . Spectrophotometric determination of hafnium with Xylenol Orange . . . . Spectrophotometric determination of iron with Xylenol Orange . . . . . Snectronhotometric determination of molybdenum with 3 :3’:4’:5 :7-pentahydroxyflavanone Spectrophotometric determination of palladium . . . _ , _. - . . Spectrophotometric determination of phenol . . . . , . . . Spectrophotometric determination of platinum. . . . . _ . . Spectrophotometric determination of rhodium . . . , . . . . Spectrophotometric determination of ruthenium . . . . . . . Spectrophotometric determination of thorium with o-~sonophenyl~~hromotropi~ acid S~trophotometri~ deter~nation of thorium with Neothrone . . . . . Stability, Thermal, of explosives . . . . . . . . . . Steel, Inclusions in . . . . . . . . . . . . Sulphate, Ion-exchange determination . . . . . . . . . Sulphides, Precipitation by thioacetamide . . . . . . . . Sulphur in iron, steel and cobalt . . . . . . . . . . Sulphur, Spectrophotometric determination as methylene blue . . . . . Ternary complexes . . . . . . , . . . Tetrabutylammonium hydroxide for titration of 3 :5-dinitrobenzoate esters . Tetralin series, Infra-red spectra . . . , . , . . Thallium, Partition chromatography . . . . . . . Thermal stability of explosives . . . . . . . . Thioacetamide for precipitation of metals . . . . . . Thioa~tamide for p~ipitation of zinc sulphide . . . . . Thioglycollic acid for gravimetric de~r~nation of zirconium , . . Thorium, Sp~~ophotome~~ dete~ination with o-a~onophenylazochromotropi~ Thorium, Spectrophotometric determination with Neothorone . . Tin, Precipitation with thioacetamide . . . . . . Titrations in non-aqueous solvents . . . . . . . Titrimetric determination of ammonia . . . . . . Titrimetric determination of ammonium ions . . . . Titrimetric determination of cobalt with molybdicyanide . . . Titrimetric determination of cobalt with 1 :lO-phenanthroline-iron . Titrimetric determination of 3:5-dinitrobenzoate derivatives . . Titrimetric determination of nitrate . . . . . . Titrimetric determination of nitro compounds . . . . . Titrimetric detonation of ni~ogen~ontaining organic substances . Titrimetric deter~nation of seIenite . . . . . . Ti~rne~c determination of selenocyanide . . . . . Titrimetric determination with ferricyanide . . . . .
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. . . . . . . . acid
. 324 . 207 I&, . . . .
311 208 351
81
146 272 324, 330 * 318 . 330 . 330 t 324 . 155 . 155 . 210 I 97 105 21;2,296 . 232 . 232
. 12 . 307 . 65 . 131 . 210 . 296 . 282 . .
95 155 . 155 . 296 240,249 1 1 . 346 . 103 . 307 6 6 I ‘27, 31 . 23 . 261
Uranyl nitrate solutions, Determination of boron in . Uranic acid materials, Variation in composition .
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Variamine Blue derivatives as indicators . Variamine Blue sulphate as redox indicator
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Xylenol Orange, Decomposition in aqueous solution . . Xylenol Orange for spectrophotometric determination of hafnium Xylenol Orange, for spectrophotometric determination of iron .
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Zinc sulphide, Precipitation by thioacetamide . . . . Z~conium, Gravimetric dete~ination with thioglycollic acid . Zirconium, Gravimetric det~ination with Z-mercaptoacetic acid Zone electrophoresis in analysis of complexone mixtures . .
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* 282 . 95 . 95 . 47
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: . . .
311 118 54 209 200. 81 147